Zitieren Sie bitte immer diesen URN: urn:nbn:de:kobv:b43-593664
In situ measurement of hydrogen concentration in steel using laser‑induced breakdown spectroscopy (LIBS)
- The ISO 3690 standard “Determination of hydrogen content in arc weld metal” requires a thermal activation of the diffusible hydrogen in a piece of weld metal for the subsequent ex situ concentration measurement by carrier gas hot extraction CGHE or thermal desorption spectroscopy (TCD). Laser-induced breakdown spectroscopy (LIBS) offers a time and spatially resolved, almost non-destructive, in situ measurement of hydrogen at surfaces without sample preparation. We measured hydrogen in steels, which were charged either electrochemically or by high-pressure hydrogen gas, and compared the results. Further, the feasibility of quantitative hydrogen line scan measurements with LIBS was demonstrated by measuring hydrogen at water jet cut surfaces. The hydrogen concentrations measured with the help of LIBS were compared with CGHE measurements. It was observed that hydrogen can be reliably measured with LIBS for concentrations larger than 2 wt.-ppm. The maximum hydrogen concentration achievedThe ISO 3690 standard “Determination of hydrogen content in arc weld metal” requires a thermal activation of the diffusible hydrogen in a piece of weld metal for the subsequent ex situ concentration measurement by carrier gas hot extraction CGHE or thermal desorption spectroscopy (TCD). Laser-induced breakdown spectroscopy (LIBS) offers a time and spatially resolved, almost non-destructive, in situ measurement of hydrogen at surfaces without sample preparation. We measured hydrogen in steels, which were charged either electrochemically or by high-pressure hydrogen gas, and compared the results. Further, the feasibility of quantitative hydrogen line scan measurements with LIBS was demonstrated by measuring hydrogen at water jet cut surfaces. The hydrogen concentrations measured with the help of LIBS were compared with CGHE measurements. It was observed that hydrogen can be reliably measured with LIBS for concentrations larger than 2 wt.-ppm. The maximum hydrogen concentration achieved using electrochemical charging was 85.1 ppm. The results show that LIBS is a promising technique for time- and spatially resolved measurements of hydrogen in steels.…
Autor*innen: | Lukas QuackatzORCiD, Axel Griesche, Jonathan Nietzke, Thomas Kannengießer |
---|---|
Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Welding in the World |
Jahr der Erstveröffentlichung: | 2024 |
Organisationseinheit der BAM: | 9 Komponentensicherheit |
9 Komponentensicherheit / 9.4 Integrität von Schweißverbindungen | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | Springer |
Erste Seite: | 1 |
Letzte Seite: | 9 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik |
Freie Schlagwörter: | Diffusible hydrogen; Hydrogen measurement; LIBS; Stainless steel; Welding |
Themenfelder/Aktivitätsfelder der BAM: | Energie |
Energie / Wasserstoff | |
Veranstaltung: | IIW Annual Assembly 2023 |
Veranstaltungsort: | Singapore |
DOI: | 10.1007/s40194-023-01677-2 |
URN: | urn:nbn:de:kobv:b43-593664 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 19.01.2024 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 05.02.2024 |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |