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Influence of Plasma Treatment on the Molar Mass of Poly(ethylene terephthalate) Investigated by Different Chromatographic and Spectroscopic Methods

  • The influence of different types of low and atmospheric pressure plasma on poly(ethylene terephthalate) (PET) has been studied in terms of changes in molar mass and molar mass distribution. Apart from a variation of plasma gases (oxygen, helium) different types of plasma (microwave, radio frequency, corona discharge) were used for the plasma surface modification. The changes in molar mass and types of functional end groups of lower molar mass products were investigated by means of matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOFMS), whereas the high-molar mass fraction was analyzed by means of size-exclusion chromatography (SEC). The formation of crosslinked products during exposure to a helium plasma, which emits preponderately energy-rich and intense ultraviolet radiation, was proved by means of thermal field-flow fractionation (ThFFF). This method combined with a multiangle laser light scattering (MALLS) detector allows detection of weaklyThe influence of different types of low and atmospheric pressure plasma on poly(ethylene terephthalate) (PET) has been studied in terms of changes in molar mass and molar mass distribution. Apart from a variation of plasma gases (oxygen, helium) different types of plasma (microwave, radio frequency, corona discharge) were used for the plasma surface modification. The changes in molar mass and types of functional end groups of lower molar mass products were investigated by means of matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOFMS), whereas the high-molar mass fraction was analyzed by means of size-exclusion chromatography (SEC). The formation of crosslinked products during exposure to a helium plasma, which emits preponderately energy-rich and intense ultraviolet radiation, was proved by means of thermal field-flow fractionation (ThFFF). This method combined with a multiangle laser light scattering (MALLS) detector allows detection of weakly crosslinked polymers and microgels. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1639-1648, 1998zeige mehrzeige weniger

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Metadaten
Autor*innen:Steffen WeidnerORCiD, Gerhard Kühn, Renate Decker, D. Roessner, Jörg Florian Friedrich
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Journal of polymer science A, polymer chemistry
Jahr der Erstveröffentlichung:1998
Verlag:Wiley
Verlagsort:Hoboken, NJ
Jahrgang/Band:36
Ausgabe/Heft:10
Erste Seite:1639
Letzte Seite:1648
Freie Schlagwörter:PET; Plasma; Poly(ethylene terephthalate)
DOI:10.1002/(SICI)1099-0518(19980730)36:10<1639::AID-POLA17>3.0.CO;2-H
URL:http://www3.interscience.wiley.com/cgi-bin/abstract/36482/ABSTRACT
ISSN:0360-6376
ISSN:0887-624X
Verfügbarkeit des Dokuments:Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")
Bibliotheksstandort:ZJ 18A
Datum der Freischaltung:19.02.2016
Referierte Publikation:Ja
Datum der Eintragung als referierte Publikation:24.02.2005
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