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Chemical effects in the formation of fs-laser-induced periodic surface structures

  • The processing of laser-induced periodic surface structures (LIPSS, ripples) on metals and semiconductors in ambient air is usually accompanied by superficial oxidation effects - widely neglected in the current literature. In this contribution, chemical, structural, and mechanical alterations in the formation of femtosecond LIPSS are characterized by a variety of surface analytical techniques, including energy dispersive X-ray analyses (EDX), X-ray photoelectron spectroscopy (XPS), micro Raman spectroscopy (µ-RS), and depth-profiling Auger electron microscopy (AEM). Alternative routes of electrochemical and thermal oxidation allow to qualify the relevance of superficial oxidation effects on the tribological performance in oil lubricated reciprocating sliding tribological tests (RSTT). It is revealed that the fs-laser processing of near-wavelength sized LIPSS on metals leads to the formation of a few hundreds of nanometer thick graded oxide layer, consisting mainly of amorphous oxides.The processing of laser-induced periodic surface structures (LIPSS, ripples) on metals and semiconductors in ambient air is usually accompanied by superficial oxidation effects - widely neglected in the current literature. In this contribution, chemical, structural, and mechanical alterations in the formation of femtosecond LIPSS are characterized by a variety of surface analytical techniques, including energy dispersive X-ray analyses (EDX), X-ray photoelectron spectroscopy (XPS), micro Raman spectroscopy (µ-RS), and depth-profiling Auger electron microscopy (AEM). Alternative routes of electrochemical and thermal oxidation allow to qualify the relevance of superficial oxidation effects on the tribological performance in oil lubricated reciprocating sliding tribological tests (RSTT). It is revealed that the fs-laser processing of near-wavelength sized LIPSS on metals leads to the formation of a few hundreds of nanometer thick graded oxide layer, consisting mainly of amorphous oxides. Regardless of its reduced hardness and limited thickness, this nanostructured surface layer can effciently prevent a direct metal-metal contact in the RSTT and may also act as an anchor layer for specific wear-reducing additives contained in the engine oil involvedzeige mehrzeige weniger

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Metadaten
Autor*innen:Jörn BonseORCiD
Koautor*innen:Sabrina V. Kirner, Thomas Wirth, Dirk Spaltmann, Jörg Krüger
Dokumenttyp:Vortrag
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2018
Organisationseinheit der BAM:6 Materialchemie
6 Materialchemie / 6.1 Oberflächen- und Dünnschichtanalyse
6 Materialchemie / 6.2 Material- und Oberflächentechnologien
9 Komponentensicherheit
9 Komponentensicherheit / 9.5 Tribologie und Verschleißschutz
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik
Freie Schlagwörter:Femtosecond; Laser-induced periodic surface structures, LIPSS; Oxidation; Tribology
Themenfelder/Aktivitätsfelder der BAM:Energie
Material
Veranstaltung:8th International LIPSS Workshop
Veranstaltungsort:Bochum, Germany
Beginndatum der Veranstaltung:27.09.2018
Enddatum der Veranstaltung:28.09.2018
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:01.10.2018
Referierte Publikation:Nein
Eingeladener Vortrag:Nein
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