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Determination of perfluordecalin in consume care products by use of GF-HR-CS-MAS

  • The introduction of HR-CS-MAS instrumentation, as it is shown in Fig. 1, provides a new way for the determination of non-metals including fluorine via molecular absorption. We present a sensitive and fluorine-specific method for total fluorine determination in fifteen consume care products in which perfluordecalin were declared (nail polishes, eye shadows and body creams). After pyrohydrolytic digestion of samples, fluorine content was determined by GF-HR-CS-MAS. Calcium was used as a molecule forming element and the molecular absorption of calcium monofluoride (CaF) at the wavelength 606.440 nm was used for its quantification. No matrix effect was observed. Analytical signal depends only on the fluorine concentration and therefore pure sodium fluoride NaF was used as calibration standard. The use of zirconium oxide nanoparticles as permanent modifier improves the limit of detection (from 0.2 to 0.1 ng) and characteristic mass (from 0.10 to 0.05 ng) from a previous reported method.The introduction of HR-CS-MAS instrumentation, as it is shown in Fig. 1, provides a new way for the determination of non-metals including fluorine via molecular absorption. We present a sensitive and fluorine-specific method for total fluorine determination in fifteen consume care products in which perfluordecalin were declared (nail polishes, eye shadows and body creams). After pyrohydrolytic digestion of samples, fluorine content was determined by GF-HR-CS-MAS. Calcium was used as a molecule forming element and the molecular absorption of calcium monofluoride (CaF) at the wavelength 606.440 nm was used for its quantification. No matrix effect was observed. Analytical signal depends only on the fluorine concentration and therefore pure sodium fluoride NaF was used as calibration standard. The use of zirconium oxide nanoparticles as permanent modifier improves the limit of detection (from 0.2 to 0.1 ng) and characteristic mass (from 0.10 to 0.05 ng) from a previous reported method. These results were also compared with ISE method (standard DIN 51-084) and no significant difference was foundzeige mehrzeige weniger

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  • Poster_ABAD_MAS_Application_BremenFluorineDays2016.pdf
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Metadaten
Autor*innen:Carlos Enrique Abad AndradeORCiD
Koautor*innen:Sebastian Recknagel, Norbert Jakubowski, M. Huang, S. Florek, H. Becker-Ross
Dokumenttyp:Posterpräsentation
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2016
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Freie Schlagwörter:Consume care products; High resolution continuum source absorption spectrometry; Perfluordecalin
Veranstaltung:Bremen Flourine Days
Veranstaltungsort:Bremerhafen, Germany
Beginndatum der Veranstaltung:03.07.2016
Enddatum der Veranstaltung:07.07.2016
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:23.09.2016
Referierte Publikation:Nein
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