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Application of a Modified Arrhenius Equation to Describe the Time-Temperature Equivalence in Relaxation Analysis of Metal Seals

  • For the application of the time-temperature superposition principle a suitable relation is needed to describe the time-temperature shift factor α. Therefore, the Arrhenius equation is widely used due to its simple form and often leads to suitable results. Where, the Arrhenius equation presents a linear relation for the temperature-dependent shift factor in logarithmic scale ln(α) with the absolute inverse temperature (1/ϑ). However, in cases with a large temperature range which eventually include more complex reaction processes, the functional relation between ln(α) and (1/ϑ) is nonlinear in the ‘Arrhenius plot’. In those cases, the monotone change of the nonlinear range in the ‘Arrhenius plot’ can be interpreted as a transient range between two approximately linear or constant regions. An extended application of the modified Arrhenius equation from Nakamura (1989) is presented in this study for this transient range. The introduced method was applied to describe the time-temperatureFor the application of the time-temperature superposition principle a suitable relation is needed to describe the time-temperature shift factor α. Therefore, the Arrhenius equation is widely used due to its simple form and often leads to suitable results. Where, the Arrhenius equation presents a linear relation for the temperature-dependent shift factor in logarithmic scale ln(α) with the absolute inverse temperature (1/ϑ). However, in cases with a large temperature range which eventually include more complex reaction processes, the functional relation between ln(α) and (1/ϑ) is nonlinear in the ‘Arrhenius plot’. In those cases, the monotone change of the nonlinear range in the ‘Arrhenius plot’ can be interpreted as a transient range between two approximately linear or constant regions. An extended application of the modified Arrhenius equation from Nakamura (1989) is presented in this study for this transient range. The introduced method was applied to describe the time-temperature equivalence in the relaxation analysis of restoring seal force of metal seals, which are used in lid-systems of transport and interim storage casks for radioactive materials. But, the method is widely valid and can be used for different objectives which are characterized by thermorheologically simple behavior with nonlinear sensitivity to inverse temperature.zeige mehrzeige weniger

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Metadaten
Autoren/innen:Linan Qiao, Sven Nagelschmidt, Uwe Herbrich
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Journal of Civil Engineering and Architecture
Jahr der Erstveröffentlichung:2017
Organisationseinheit der BAM:3 Gefahrgutumschließungen
3 Gefahrgutumschließungen / 3.4 Sicherheit von Lagerbehältern
Veröffentlichende Institution:Bundesanstalt für Materialforschung und -prüfung (BAM)
Verlag:David Publishing Company
Verlagsort:USA, NY 10989, Valley Cottage
Jahrgang/Band:11
Ausgabe/Heft:9
Erste Seite:853
Letzte Seite:861
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik
Freie Schlagwörter:Arrhenius equation; Metal seals; Non-linear Arrhenius behavior; Relaxation analysis; Seal force; TTS principle
Themenfelder/Aktivitätsfelder der BAM:Energie
Energie / Kerntechnische Entsorgung
DOI:https://doi.org/10.17265/1934-7359/2017.09.004
URN:urn:nbn:de:kobv:b43-446759
URL:http://www.davidpublisher.org/index.php/Home/Article/index?id=33931.html
ISSN:1934-7359
Verfügbarkeit des Dokuments:Datei für die Öffentlichkeit verfügbar ("Open Access")
Lizenz (Deutsch):License LogoCreative Commons - CC BY-ND - Namensnennung - Keine Bearbeitungen 4.0 International
Datum der Freischaltung:12.04.2018
Referierte Publikation:Nein
Schriftenreihen ohne Nummerierung:Wissenschaftliche Artikel der BAM