Environmental and excitation power effects on the ratiometric upconversion luminescence based temperature sensing using nanocrystalline NaYF4:Yb3+,Er3+

  • The luminescence intensity ratio (LIR) of the green emissions of the near-infrared excited NaYF4:Yb3+,Er3+ nanocrystals is a promising method for temperature sensing. Here, the influence of excitation power density, excitation pulse length, excitation wavelength, silica shell, and solvent on the LIR and its temperature response is reported. The primary objective is to study the LIR mechanism and the impact of measurement and environmental parameters on the calibration and precision of the LIR. The LIR value is demonstrated to be unaffected by the excitation intensity in the studied range. This result is essential, considering the application feasibility of the LIR method as temperature sensor, where the effective excitation power density depends on the sample matrix and the distance excitation light travels in the sample. The pulsed excitation, however, results in an increase in the LIR value upon short pulse width. Silanization of bare nanocrystals has no effect on the LIR values, butThe luminescence intensity ratio (LIR) of the green emissions of the near-infrared excited NaYF4:Yb3+,Er3+ nanocrystals is a promising method for temperature sensing. Here, the influence of excitation power density, excitation pulse length, excitation wavelength, silica shell, and solvent on the LIR and its temperature response is reported. The primary objective is to study the LIR mechanism and the impact of measurement and environmental parameters on the calibration and precision of the LIR. The LIR value is demonstrated to be unaffected by the excitation intensity in the studied range. This result is essential, considering the application feasibility of the LIR method as temperature sensor, where the effective excitation power density depends on the sample matrix and the distance excitation light travels in the sample. The pulsed excitation, however, results in an increase in the LIR value upon short pulse width. Silanization of bare nanocrystals has no effect on the LIR values, but the local warming of H2O samples under laser exposure results in slightly increased LIR values compared to other solvents; D2O, oleic acid, and dimethyl sulfoxide. The thermal quenching of luminescence lifetimes of Er3+ emission is proved to be too weak for sensing applications.zeige mehrzeige weniger

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Metadaten
Autor*innen:I. Hyppänen, N. Perälä, Riika Arppe, Michael Schäferling, T. Soukka
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):ChemPhysChem
Jahr der Erstveröffentlichung:2017
Verlag:Wiley-VCH
Verlagsort:Weinheim
Jahrgang/Band:18
Ausgabe/Heft:6
Erste Seite:692
Letzte Seite:701
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Freie Schlagwörter:Excitation intensity; Luminescence intensity ratio; Photon upconversion; Temperature sensing
DOI:10.1002/cphc.201601355
URL:http://onlinelibrary.wiley.com/doi/10.1002/cphc.201601355/epdf
ISSN:1439-4235
ISSN:1439-7641
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:21.04.2017
Referierte Publikation:Ja
Datum der Eintragung als referierte Publikation:21.04.2017
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