TY - CONF A1 - Wille, Frank T1 - Verkehrsrechtliche Betrachtungen Transport- und Lagerbehälter - Wo geht die Reise hin? N2 - Transportierbarkeit von Transport- und Lagerbehältern für radioaktive Stoffe, welche nach eine längerfristigen trockenen Zwischenlagerung transportiert werden müssen. Überblick über die aktuellen Regelwerke und Richtlinien sowie die Zeitpläne für das Finden eines Endlagers für hochradioaktive Stoffe und die damit verbundene verlängerte Zwischenlagerung. Des Weiteren werden das für die verlängerte Zwischenlagerung notwendige Alterungsmanagement und die noch erforderlichen Forschungstätigkeiten vorgestellt. T2 - 10. Symposium Lagerung und Transport radioaktiver Stoffe CY - Hannover, Germany DA - 05.09.2023 KW - Transportbehälter KW - Radioaktive Stoffe KW - Transport KW - Zwischenlagerung KW - IAEA PY - 2023 AN - OPUS4-60506 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schneider, Ronald T1 - Modeling in support of offshore wind farm end-of-life decision making N2 - The EU member states have set out ambitious long-term goals for deploying offshore wind energy. The installed offshore wind capacity is set to increase from 14.6 GW in 2021 to around 320 GW in 2050. This signifies the role of offshore wind energy as a major contributor to reaching the EU’s climate and energy goals. To ensure that the defined targets are met, a significant number of new wind farms has to be installed and existing wind farms reaching the end of their planned life need to be reused efficiently. Some of the relevant reuse alternatives are lifetime extension, repowering based on the existing support structures and repowering with new turbines. As a basis of the decision-making regarding the reuse of existing offshore wind farm, the expected utility of each relevant option should be determined based on the associated expected rewards, costs and risks. The optimal concept maximizes the utility of the decision-maker and fulfills the existing constraints and requirements. To facilitate such a quantitative decision-making, models and methods have to be developed. In particular, models are required that enable predictions of (a) the condition and performance of the turbines and support structures and (b) the renumeration, costs and consequences of adverse events. These predictions have to consider (a) the governing uncertainties, (b) the available information from the planning, construction, installation and operating phase, (b) potential repair, retrofitting and strengthening schemes and (c) possible monitoring, inspection and maintenance regimes for the future operating phase. Over the past years, several models, methods and tools have been developed at the Bundesanstalt für Materialforschung und -prüfung (BAM) to support the structural integrity management of offshore wind turbine substructures. These include: (a) a prototype for reliability-based, system-wide, adaptive planning of inspections of welded steel structures in offshore wind farms, (b) a method for monitoring and risk-informed optimization of inspection and maintenance strategies for jacket structures subject to fatigue, and (c) a probabilistic cost model of inspection and maintenance of welded steel structures in offshore wind farms. This contribution provides an overview on these works and discusses how they can be adapted and extended to support the decision-making regarding lifetime extensions and repowering of offshore wind farms. T2 - 12th International Forum on Engineering Decision Making (12th IFED) CY - Stoos, Switzerland DA - 05.12.2023 KW - Windenergie KW - Offshore Wind KW - Lifetime Extension KW - Repowering PY - 2023 AN - OPUS4-60430 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schwarz, Irina A1 - Rieck, Arielle T1 - Valorization of carbon dioxide by electrocatalytic reduction coupled to acetogens via multiple electron carriers (Ecat-acetogens) N2 - For the realization of a sustainable energy economy, it is of great importance to develop CO2 -neutral methods producing multi-carbon organic chemicals used as feedstock as well as carbon-neutral fuels by CO2 capture and conversion. In this work, a bio-electrocatalytical system (BES) consisting of a bioreactor coupled to a CO2 electrolysis cell is established. CO2 is first electrochemically converted to CO in electrolysis cell which is then directly fed to bacteria (acetogens) to further metabolize it to valuable carbon compounds such as acetate. The objective of this study is to develop cost-efficient, biocompatible and high activity electrocatalysts that can selectively convert CO2 to CO. Porous nitrogen-doped carbons containing atomically dispersed Ni and Co (Ni or Co-N-Cs) are prepared by active-site imprinting approach. First, synthesis of Mg- or Zn-N-C was carried out through pyrolysis of precursors in a salt melt followed by exchange with Ni or Co. N2-sorption porosimetry of the materials reveal a micro-mesoporous structure with high surface areas (> 1000 m2 g-1) and a mass-transport enabling pore system. Extended X-ray absorption fine structure (EXAFS) reveal the existence of single atom sites with no formation of nanoparticles. A variety of Ni-N-Cs and Co-N-Cs were tested for CO2R activity in a rotating disc electrode (RDE) setup, showing high activity (Tafel slopes range from 77 – 130 mV/decade) and selectivity towards CO2R versus the competing HER. Before operation in the BES, first tests were performed in a single cell. Significantly increased current was detected in the CO2R test in CO2-saturated electrolyte vs. in N2 -saturated electrolyte indirectly proving formation of carbon monoxide (CO). Transfer of the electrolysis cell operation into the BES proved to be successful. For biotic operation, the BES was inoculated with Clostridium ragsdalei. Partial pressures pCO reached a maximum of 5.7 mbar and pH2 was 2.7 mbar after 30h. The reduction of partial pressures is interpreted as the consumption of the gases by C.ragsdalei. We report a specific exponential growth rate of 0.16 h-1, acetate formation rate of 1.8 mg L-1 h-1 and an acetate concetration of 0.103 g L-1 corresponding to acetate formation rate of 0.73 mmol d-1.In this work we successfully demonstrated an integrated bio-electrocatalytic system (BES) to convert CO2 into value-added chemicals. The usage of a Co- and Ni-N-Cs as the reduction catalyst within the BES allowed production of CO and H2 with relative selectivity for CO resulting in the growth of Clostridium ragsdalei and acetate production. T2 - Joint SPP Conference CY - Jena, Germany DA - 06.11.2023 KW - Bioelectrocatalytical system PY - 2023 AN - OPUS4-61995 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schwarz, Irina A1 - Rieck, Arielle T1 - Valorization of carbon dioxide by electrocatalytic reduction coupled to acetogens via multiple electron carriers (Ecat-acetogens) N2 - To alleviate CO2 emissions and their impact on climate change, converting carbon dioxide into valuable products such as multi-carbon organic chemicals is of great importance. CO2 can be converted via different pathways such as electrochemical, photo-electrochemical and biological etc. Each approach offers distinct merits but also certain challenges in terms of process efficiency, product selectivity and implementation at scale etc. Therefore, developing coupled CO2 conversion systems, for instance bioelectrochemical reactors, can potentially address some of those challenges.[1] In this work, the focus is on developing cost-efficient, biocompatible, and high activity porous M-N-C catalysts with M = Ni and Co that are atomically dispersed as NiN4 and CoN4 active sites in porous carbon matrix. Ni- and Co-N-Cs are prepared by active-site imprinting approach using Mg as an imprinter.[2][3] Pyrolysis of Mg-N-C is carried out in a salt-melt at high temperatures (≥ 800 oC) and followed by an exchange with Ni or Co at low temperatures. N2-sorption of the materials reveal a micro-mesoporous structure with high surface areas (> 1000 m2 g-1) and a mass-transport enabling pore system. Extended X-ray absorption fine structure (EXAFS) reveal the existence of atomically dispersed single atom active sites with defined active site structure. A variety of Ni-N-Cs and Co-N-Cs were tested for CO2R activity in a rotating disc electrode (RDE) setup, showing high activity and selectivity towards CO2R versus the competing HER. Subsequently, these catalysts were implemented in a home-made bio-electrocatalytical system (BES) consisting of a bioreactor coupled to a CO2 electrolysis cell. Here, CO2 is first electrochemically converted to CO in the electrolysis cell which is then directly fed to bacteria (Clostridium ragsdalei) in bioreactor who further metabolize it to valuable carbon compounds such as acetate. In the BES, partial pressures of CO reached a maximum of 5.7 mbar and that of hydrogen was 2.7 mbar after 30 h. A specific exponential bacterial growth rate of 0.16 h-1 was observed with acetate formation rate of 1.8 mg L-1 h-1 and an acetate concentration of 0.103 g L-1 corresponding to acetate formation rate of 0.73 mmol d-1. As will be discussed in greater details in this talk, we have successfully demonstrated the validity of a coupled bio-electrocatalytical system concept operating with Co- and Ni-N-C catalysts for CO2 conversion. T2 - eBiotech Workshop Week + Status Seminar CY - Jena, Germany DA - 19.03.2023 KW - Bioelectrocatalytical system PY - 2023 AN - OPUS4-61997 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ratkovac, Mirjana T1 - Perspectives on Wind and Wave Load Reconstruction from SHM Data for Offshore Wind Turbines N2 - As many wind turbines approach the end of their design lifetime, from a technical point of view, comprehensive fatigue analysis of all critical parts is necessary to decide what comes after – continued operation, repowering, or decommissioning. Typically, it is a two-stage evaluation process consisting of a physical inspection of the structure and an analytical part to compare the design and actually experienced loading conditions. Structural health monitoring helps to reduce the uncertainties in the estimations by providing insight into deviations between the designed and the built structure. Furthermore, it allows the evaluation of the consumed fatigue lifetime by analyzing the strain measurements that mirror the actual structural response to experienced environmental and operational conditions. However, the measurement values are limited to a sparse number of instrumented spots on the structure, and further extrapolation to the non-instrumented (critical) sections is required to perform a complete fatigue assessment. One known approach is the external force reconstruction, which has only scarcely been considered for application in offshore wind turbines. In order to extend the previously developed thrust force reconstruction framework, this work discusses the possibilities and challenges of wind and wave loading reconstruction in offshore wind turbine support structures. T2 - 4th International Conference on Health Monitoring of Civil & Maritime Structures (HeaMES 2023) CY - Online meeting DA - 12.06.2023 KW - Wind turbines KW - Force reconstruction KW - Structural Health Monitoring PY - 2023 AN - OPUS4-57687 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Asna Ashari, Parsa A1 - Blind, K. A1 - Koch, Claudia T1 - Knowledge and technology transfer via publications, patents, standards: Exploring the hydrogen technological innovation system N2 - Clean technologies play a crucial role in reducing greenhouse gas emissions and protecting the climate. Hydrogen is a promising energy carrier and fuel that can be used in many applications. We explore the global hydrogen technological innovation system (TIS) by analyzing the three knowledge and technology transfer channels of publications, patents, and standards. Since the adoption of hydrogen technologies requires trust in their safety,this study specifically also focuses on hydrogen safety. Our results show that general and hydrogen safety research has increased significantly while patenting experienced stagnation. An analysis of the non-patent literature in safety patents shows little recognition of scientific publications. Similarly, publications are underrepresented in the analyzed 75 international hydrogen and fuel cell standards. This limited transfer of knowledge from published research to standards points to the necessity for greater involvement of researchers in standardization. We further derive implications for the hydrogen TIS and recommendations for a better and more impactful alignment of the three transfer channels. KW - Technological innovation system KW - Hydrogen safety KW - Knowledge and technology transfer KW - Publications KW - Patents KW - Standards PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-564250 DO - https://doi.org/10.1016/j.techfore.2022.122201 SN - 0040-1625 VL - 187 SP - 1 EP - 14 PB - Elsevier Inc. AN - OPUS4-56425 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Thiele, Marc T1 - Detection and monitoring of the fatigue crack growth on welds – Application-oriented use of NDT methods N2 - Early detection of fatigue cracks and accurate measurements of the crack growth play an important role in the maintenance and repair strategies of steel structures exposed to cyclic loads during their service life. Observation of welded connections is especially of high relevance due to their higher susceptibility to fatigue damage. The aim of this contribution was to monitor fatigue crack growth in thick welded specimens during fatigue tests as holistically as possible, by implementing multiple NDT methods simultaneously in order to record the crack initiation and propagation until the final fracture. In addition to well-known methods such as strain gauges, thermography, and ultrasound, the crack luminescence method developed at the Bundesanstalt für Materialforschung und -prüfung (BAM), which makes cracks on the surface particularly visible, was also used. For data acquisition, a first data fusion concept was developed and applied in order to synchronize the data of the different methods and to evaluate them to a large extent automatically. The resulting database can ultimately also be used to access, view, and analyze the experimental data for various NDT methods. During the conducted fatigue tests, the simultaneous measurements of the same cracking process enabled a comprehensive comparison of the methods, highlighting their individual strengths and limitations. More importantly, they showed how a synergetic combination of different NDT methods can be beneficial for implementation in large-scale fatigue testing but also in monitoring and inspection programs of in-service structures - such as the support structures of offshore wind turbines. T2 - Fatigue Design 2023 CY - Senlis, France DA - 29.11.2023 KW - Crack growth KW - Fatigue KW - NDT KW - Welded PY - 2023 AN - OPUS4-62374 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Asna Ashari, Parsa T1 - Drivers and Barriers to the Adoption of Hydrogen Technologies in Germany and the Republic of Korea - A Multidimensional Stakeholder Analysis N2 - This presentation was held at the Eu-SPRI 2023 Conference and provides a comparative analysis of the hydrogen economies in Germany and the Republic of Korea, highlighting similarities and differences. Thereupon, the presentation delves into the requirements for the development of a hydrogen economy, including recommendations for policymaking. T2 - The Eu-SPRI Annual Conference 2023 CY - Brighton, UK DA - 14.06.2023 KW - Country comparison KW - Hydrogen economy KW - Technological innovation system KW - Multidimensional hydrogen technology adoption PY - 2023 AN - OPUS4-57716 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bonse, Jörn T1 - Single Femtosecond Laser Pulse induced Amorphization, Re-crystallization and Native Oxide Removal at Silicon Wafer Surfaces N2 - Single femtosecond laser pulse induced amorphization, re-crystallization and native oxide layer removal at silicon wafer surfaces of different crystal orientation is studied via spectroscopic imaging ellipsometry, atomic force microscopy, and high-resolution transmission electron microscopy. T2 - 2023 Conference on Lasers and Electro-Optics/Europe – European Quantum Electronics Conferences CY - Munich, Germany DA - 26.06.2023 KW - Femtosecond laser KW - Laser-induced amorphization KW - Spectroscopic imaging ellipsometry KW - Transmission electron microscopy KW - Native oxide layer PY - 2023 AN - OPUS4-57829 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bonse, Jörn A1 - Krüger, Jörg T1 - Structuring of thin films by ultrashort laser pulses N2 - Modern life and global communication would not be possible without technologically tailored thin films; they are omnipresent in daily life applications. In most cases, the films are deposited entirely at the carrying substrates in a specific processing step of the device or sample. In some cases, however, removal or modification must be performed locally, i.e., site-controlled and material selective through an additional laser processing step. For that ultrashort laser pulses with durations in the femtosecond and picosecond range can provide unique advantages and capabilities in industrially scalable schemes. This article reviews the current state of the research and corresponding industrial transfer related to the structuring of thin films by ultrashort pulsed lasers. It focuses on the pertinent historic developments, reveals the relevant physical and chemical effects, explores the ultimate limits, and discusses selected industrial and scientific applications. KW - Thin films KW - Laser processing KW - Ultrashort lasers KW - Laser damage KW - Femtosecond laser ablation PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-565732 DO - https://doi.org/10.1007/s00339-022-06229-x SN - 0947-8396 SN - 1432-0630 VL - 129 IS - 1 SP - 1 EP - 38 PB - Springer CY - Berlin AN - OPUS4-56573 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Costache, F. A1 - Valette, S. A1 - Bonse, Jörn T1 - Editorial: Special Issue “Dynamics and Processes at Laser-Irradiated Surfaces—A Themed Issue in Honor of the 70th Birthday of Professor Jürgen Reif” N2 - The Special Issue “Dynamics and Processes at Laser-irradiated Surfaces” is dedicated to the 70th birthday of Jürgen Reif, retired full professor, former Chair of Experimental Physics II of the Faculty of Physics of the Brandenburg University of Technology Cottbus—Senftenberg in Germany. KW - Laser ablation KW - Laser-induced periodic surface structures (LIPSS) KW - Surface functionalization KW - Femtosecond laser PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-569482 DO - https://doi.org/10.3390/nano13030611 SN - 2079-4991 VL - 13 IS - 3 SP - 1 EP - 3 PB - MDPI CY - Basel AN - OPUS4-56948 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wolff, M. A1 - Wonneberger, R. A1 - Freiberg, K.E. A1 - Hertwig, Andreas A1 - Bonse, Jörn A1 - Giebeler, L. A1 - Koitzsch, A. A1 - Kunz, C. A1 - Weber, H. A1 - Hufenbach, J.K. A1 - Müller, F.A. A1 - Gräf, S. T1 - Formation of laser-induced periodic surface structures on Zr-based bulk metallic glasses with different chemical composition N2 - Bulk metallic glasses (BMG) are amorphous metal alloys known for their unique physical and mechanical properties. In the present study, the formation of femtosecond (fs) laser-induced periodic surface structures (LIPSS) on the Zr-based BMGs Zr46Cu46Al8, Zr61Cu25Al12Ti2, Zr52.5Cu17.9Al10Ni14.6Ti5 (Vit105) and Zr57Cu15.4Al10Ni12.6Nb5 (Vit106) was investigated as a function of their different chemical composition. For this purpose, LIPSS were generated on the sample surfaces in an air environment by fs-laser irradiation (λ = 1025 nm, τ = 300 fs, frep = 100 kHz). The surface topography was characterized by scanning electron microscopy and atomic force microscopy. Moreover, the impact of LIPSS formation on the structure and chemical surface composition was analyzed before and after fs-laser irradiation by X-ray diffraction and X-ray photoelectron spectroscopy as well as by transmission electron microscopy in combination with energy dispersive X-ray spectroscopy. Despite the different chemical composition of the investigated BMGs, the fs-laser irradiation resulted in almost similar properties of the generated LIPSS patterns. In the case of Zr61Cu25Al12Ti2, Vit105 and Vit106, the surface analysis revealed the preservation of the amorphous state of the materials during fs-laser irradiation. The study demonstrated the presence of a native oxide layer on all pristine BMGs. In addition, fs-laser irradiation results in the formation of laser-induced oxide layers of larger thickness consisting of an amorphous ZrAlCu-oxide. The precise laser-structuring of BMG surfaces on the nanoscale provides a versatile alternative to thermoplastic forming of BMG surfaces and is of particular interest for the engineering of functional material surfaces. KW - Bulk metallic glasses KW - Femtosecond laser KW - Laser-induced periodic surface structures (LIPSS) KW - Chemical analysis KW - Oxidation PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-581799 DO - https://doi.org/10.1016/j.surfin.2023.103305 SN - 2468-0230 VL - 42 SP - 1 EP - 11 PB - Elsevier B.V. AN - OPUS4-58179 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Baeßler, Matthias T1 - OWEC repowering from a structural engineering and research perspective N2 - A significant number of new wind farms has to be installed and, at the same time, existing wind farms reaching the end of their planned life need to be reused efficiently to ensure that the ambitous goals for deploying offshore wind are met. Some relevant reuse alternatives for offshore wind farms are lifetime extension, repowering utilizing existing substructures and full replacement. In this presentation - starting from experience gained from extending the lifetime of the of the U1 metro viaduct in Berlin - we discuss end-of-life decision making in offshore wind. We focus particularly on issues concerning substructures and highlight existing challenges and opprtunities in research and development. T2 - RWE RePowering Event CY - Wilhelmshaven, Germany DA - 10.10.2023 KW - Offshore wind KW - End-of-life decision making KW - Repowering KW - Substructures PY - 2023 AN - OPUS4-58632 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Karapanagiotis, Christos A1 - Krebber, Katerina T1 - Machine Learning Approaches in Brillouin Distributed Fiber Optic Sensors N2 - This paper presents reported machine learning approaches in the field of Brillouin distributed fiber optic sensors (DFOSs). The increasing popularity of Brillouin DFOSs stems from their capability to continuously monitor temperature and strain along kilometer-long optical fibers, rendering them attractive for industrial applications, such as the structural health monitoring of large civil infrastructures and pipelines. In recent years, machine learning has been integrated into the Brillouin DFOS signal processing, resulting in fast and enhanced temperature, strain, and humidity measurements without increasing the system’s cost. Machine learning has also contributed to enhanced spatial resolution in Brillouin optical time domain analysis (BOTDA) systems and shorter measurement times in Brillouin optical frequency domain analysis (BOFDA) systems. This paper provides an overview of the applied machine learning methodologies in Brillouin DFOSs, as well as future perspectives in this area. KW - Distributed fiber optic sensors KW - BOTDA KW - BOFDA KW - Machine learning KW - Strain and temperature measurements KW - Artificial neural networks PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-580145 DO - https://doi.org/10.3390/s23136187 VL - 23 IS - 13 SP - 1 EP - 26 PB - MDPI AN - OPUS4-58014 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Greenblatt, D. A1 - Müller-Vahl, H. A1 - Strangfeld, Christoph T1 - Laminar separation bubble bursting in a surging stream N2 - The effect of high-amplitude harmonic surging on airfoil laminar separation bubbles, at small angles of attack, was investigated experimentally in a dedicated surging-flow wind tunnel. A generalized pressure coefficient was developed that accounts for local static pressure variations due to surging. This critical generalization facilitated direct comparisons between surging and quasisteady pressure coefficients, and thus unsteady effects could be distinguished from Reynolds number effects. A momentum-integral boundary layer analysis was implemented to determine movement of the bubble separation point, and movement of the transition point was extracted from experimental surface pressure coefficients. The most significant finding was that bubble bursting occurs, counterintuitively, during early imposition of the favorable temporal pressure gradient, because the favorable pressure gradient rapidly drives the bubble aft, rendering it unable to reattach. This surge-induced dynamic stall mechanism resulted in large lift and form-drag coefficient oscillations. Furthermore, failure to implement the generalized pressure coefficient definition resulted in temporal form-drag coefficient errors of up to 400 counts. KW - Aerodynamics KW - Boundary layer receptivity, stability & separation KW - Boundary layers PY - 2023 DO - https://doi.org/10.1103/PhysRevFluids.8.L012102 SN - 2469-990X VL - 8 IS - 1 SP - 1 EP - 11 PB - American Physical Society AN - OPUS4-56860 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - de Camargo, Andrea Simone Stucchi T1 - Luminescent multifunctional nanostructures for sensing and theranostics applications N2 - The research carried out at the Laboratory of Spectroscopy of Functional Materials at IFSC/USP, in Brazil, is focused on the synthesis and structural-property correlation of luminescent materials including rare-earth (RE) doped glasses, ceramics and hybrid host-guest materials. For the past five years, we have been particularly interested in the development of single- and multifunctional nanosystems based on core-shell upconversion nanoparticles (UCNP) associated with dyes, organometallic complexes and other organic molecules, for biophotonic and sensing applications. In these systems, we take advantage of energy transfer between the UCNPs and the molecules to either supress or enhance luminescent response. Examples include the possibility of bioimaging and photodynamic therapy of bacteria and cancer cells, simultaneous magnetothermia and thermometry, localized O2 sensing, fast detection and quantification of biological markers (e.g. kidney disease) and microorganisms. On what concerns the development of luminescent sensors - a recently started project, our aim is to develop paper-based platforms for point-of-care devices. In this presentation, an overview of our contributions for the past years and our future aims will be presented with several examples. T2 - ICL2023 - 20th International Conference on Luminescence CY - Paris, France DA - 27.08.2023 KW - Upconversion KW - Sensing KW - Theranostics KW - Nanoparticles KW - Photodynamic therapy PY - 2023 AN - OPUS4-60362 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Eichner, Lukas A1 - Schneider, Ronald A1 - Baeßler, Matthias T1 - Optimal vibration sensor placement for jacket support structures of offshore wind turbines based on value of information analysis N2 - Information on the condition and reliability of an offshore jacket structure provided by a vibration-based structural health monitoring system can guide decisions on inspection and maintenance. When selecting the sensor setup, the designer of the monitoring system must assess its overall benefit compared to its costs before installation. The potential benefit of continuously monitoring the dynamic response of a jacket structure can be formally quantified through a value of information analysis from Bayesian decision theory. In this contribution, we present a framework for optimizing the placement of vibration sensors on offshore jacket structures by maximizing the value of information of the monitoring system. To solve the resulting discrete optimization problem, we adapt a genetic algorithm. The framework is demonstrated in a numerical example considering a redundant jacket-type steel frame. The numerical study shows that monitoring the vibration response of the frame is beneficial. Good sensor setups consist of relatively few sensors located towards the upper part of the frame. The adapted genetic algorithm performs similarly well as established sequential sensor placement algorithms and holds substantial promise for application to real jacket structures. KW - Optimal sensor placement KW - Value of information KW - Jacket support structure KW - Offshore wind turbine KW - Monitoring-informed inspection and maintenance planning PY - 2023 DO - https://doi.org/10.1016/j.oceaneng.2023.115407 SN - 0029-8018 VL - 288 IS - 2 PB - Elsevier Ltd. CY - Amsterdam AN - OPUS4-58725 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kühnel, Alena A1 - Stelzner, Ludwig A1 - Weise, Frank T1 - Measurement and analysis of concrete pavement surface textures using hand-held 3D laser scanning technology N2 - Concrete pavement surface textures are divided by means of their dimension into four categories: microtexture, macrotexture, megatexture and roughness. They influence the most important performance characteristics of road surfaces, such as friction (also referred to as “skid resistance”), tire/pavement noise, evenness and surface drainage. These properties are relevant for driving safety, comfort and environmental aspects. Up to now, research in Germany has focused on monitoring these characteristics by tire/pavement noise and skid resistance measurements. However, the topography of surface textures has not been sufficiently investigated and evaluated until now. The development and availability of high-performance, hand-held 3D scanning systems during the last years enable measurements of the microtexture and macrotexture of concrete pavement surfaces at short measuring times and high resolution. This paper shows the ability of modern laser-based technology to record three-dimensional data of different concrete pavement surface textures in situ. For this purpose, a special measuring frame has been developed. The presented results were primarily obtained within the framework of a research project commissioned by the German Federal Highway Research Institute (BASt) and processed by the Federal Institute for Materials Research and Testing. Various concrete pavement surface textures by means of diamond grinding and hybrid of diamond grinding and grooving were investigated in situ. In addition, exposed aggregate concretes (EAC), which were introduced as a standard type of concrete for motorway pavements in Germany in 2006, have been analyzed. Based on the gathered 3D data, evaluation routines for qualitative and quantitative analysis have been developed and applied. The aim was to derive the statistical parameters such as the relative and cumulative frequency distribution of the profile depth as well as the roughness coefficient for diamond ground pavements and EAC. Also, the “mean profile depth” (MPD) as a common texture-related parameter was determined. T2 - 14th International Symposium on Concrete Roads CY - Krakow, Poland DA - 25.06.2023 KW - Concrete pavement surface textures KW - 3D Laser Scanning KW - Diamond Grinding KW - Exposed aggregate concrete KW - Data analysis KW - Surface characteristics PY - 2023 SP - 1 EP - 14 AN - OPUS4-57893 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Mezera, Marek A1 - Florian, C. A1 - Römer, G.-W. A1 - Krüger, Jörg A1 - Bonse, Jörn ED - Stoian, R. ED - Bonse, Jörn T1 - Creation of Material Functions by Nanostructuring N2 - Surface nanostructures provide the possibility to create and tailor surface functionalities mainly via controlling their topography along with other chemical and physical material properties. One of the most appealing technologies for surface functionalization via micro- and nanostructuring is based on laser processing. This can be done either via direct contour-shaping of the irradiated material using a tightly focused laser beam or in a self-ordered way that allows employing larger laser beam diameters along with areal scanning to create a variety of laser-induced periodic surface structures (LIPSS). For the latter approach, particularly ultrashort pulsed lasers have recently pushed the borders across long-lasting limitations regarding the minimum achievable feature sizes and additionally boosted up the production times. This chapter reviews the plethora of recently investigated applications of LIPSS—for example, via imposing diffractive or plasmonic structural colors, the management of liquids and surface wetting properties, biomedical and bioinspired functionalities, beneficial effects in tribology for reducing friction and wear, the manipulation of optical scattering and absorption in photovoltaics, or the modification of magnetic or superconducting surface properties in other energy applications. The footprint of the LIPSS-based technology is explored in detail regarding the current state of industrialization, including an analysis of the market and associated LIPSS production costs. KW - Laser-induced periodic surface structures, LIPSS KW - Surface functionalization KW - Nanostructures KW - Microstructures KW - Laser processing PY - 2023 SN - 978-3-031-14751-7 SN - 978-3-031-14752-4 DO - https://doi.org/10.1007/978-3-031-14752-4_23 VL - 239 SP - 827 EP - 886 PB - Springer Nature Switzerland AG CY - Cham, Switzerland AN - OPUS4-57295 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Sokolowski-Tinten, K. A1 - Bonse, Jörn A1 - Barty, A. A1 - Chapman, H.N. A1 - Bajt, S. A1 - Bogan, M.J. A1 - Boutet, S. A1 - Cavalleri, A. A1 - Düsterer, S. A1 - Frank, M. A1 - Hajdu, J. A1 - Hau-Riege, S. A1 - Marchesini, S. A1 - Stojanonovic, N. A1 - Treusch, R. ED - Stoian, R. ED - Bonse, Jörn T1 - In-Situ Observation of the Formation of Laser-Induced Periodic Surface Structures with Extreme Spatial and Temporal Resolution N2 - Irradiation of solid surfaces with intense ultrashort laser pulses represents a unique way of depositing energy into materials. It allows to realize states of extreme electronic excitation and/or very high temperature and pressure and to drive materials close to and beyond fundamental stability limits. As a consequence, structural changes and phase transitions often occur along unusual pathways and under strongly nonequilibrium conditions. Due to the inherent multiscale nature—both temporally and spatially—of these irreversible processes, their direct experimental observation requires techniques that combine high temporal resolution with the appropriate spatial resolution and the capability to obtain good quality data on a single pulse/event basis. In this respect, fourth-generation light sources, namely, short wavelength and short pulse free electron lasers (FELs), are offering new and fascinating possibilities. As an example, this chapter will discuss the results of scattering experiments carried out at the FLASH free electron laser at DESY (Hamburg, Germany), which allowed us to resolve laser-induced structure formation at surfaces on the nanometer to submicron length scale and in temporal regimes ranging from picoseconds to several nanoseconds with sub-picosecond resolution. KW - Laser-induced periodic surface structures, LIPSS KW - Capillary waves KW - Time-resolved scattering KW - Pump-probe experiments KW - Free electron laser PY - 2023 SN - 978-3-031-14751-7 SN - 978-3-031-14752-4 DO - https://doi.org/10.1007/978-3-031-14752-4_6 VL - 239 SP - 257 EP - 276 PB - Springer Nature Switzerland AG CY - Cham, Switzerland AN - OPUS4-57297 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gerards-Wünsche, Paul T1 - A framework for assessing the reliability of crack luminescence – an automated fatigue crack detection system N2 - The new crack luminescence method offers the possibility of making fatigue surface cracks in metallic materials more visible during inspections through a special coating system. This coating system consists of two layers, whereby the first layer has fluorescent properties and emits visible light as soon as it is irradiated by UV light. The top layer is black and is designed to prevent the fluorescent layer from emitting if no crack develops in the underlying material. The technique proved particularly useful in a wide variety of fatigue tests of steel components under laboratory conditions. Moreover, it has the potential to be used in various industrial applications. To enable industrial deployment and integration into maintenance strategies, a concept study is developed in this contribution, resulting in a qualification framework that can serve as a foundation for determining the reliability of the crack luminescence system in terms of a probability of detection curve. Within this study, factors causing measurement variability and uncertainty are being determined and their influences assessed. Due to the extension of the system by a moving computer vision system for automated crack detection using artificial intelligence, additional long-term effects associated with structural health monitoring systems need to be incorporated into an extended probability of detection study as part of the technical justification. Finally, important aspects and findings related to design of experiments are discussed, and a framework for reliability assessment of a new optical crack monitoring method is presented, emphasizing the influence of various uncertainty parameters, including long-term effects such as system ageing. T2 - SPIE Conference Smart Structures + Nondestructive Evaluation 2023 CY - Long Beach, CA, USA DA - 24.03.2023 KW - Structural Health Monitoring KW - Non-Destructive Evaluation KW - Probability of Detection KW - Reliability KW - Artificial Intelligence KW - Computer Vision KW - Crack Luminescence PY - 2023 AN - OPUS4-57245 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Karapanagiotis, Christos ED - Krebber, Katerina T1 - Machine learning for strain, temperature and humidity discrimination in Brillouin optical frequency domain analysis N2 - We propose to our knowledge for the first time an ensemble of probabilistic machine learning models for strain, temperature and humidity discrimination in Brillouin optical frequency domain analysis (BOFDA) applying a two-fiber configuration. T2 - 28th International Conference on Optical Fiber Sensors CY - Hamamatsu, Japan DA - 20.11.2023 KW - Multiparameter sensing KW - Machine learning KW - Fiber optic sensors KW - Structural health monitoring PY - 2023 SP - 1 EP - 4 PB - Optica Publishing Group AN - OPUS4-59397 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Reliable hydrogen determination in metallic materials and their weld joints: Parameters and challenges N2 - In the course of tomorrow's hydrogen-based energy transition, the construction of the corresponding infrastructure will play a central role. The majority of materials used to date are typically welded for component fabrication. In that context, steels are widely applied and can be prone to hydrogen embrittlement. This includes the classical delayed cold cracking during welding processing as well as embrittlement phenomena during operation. For the evaluation of any hydrogen effect on, for example, the mechanical properties of a welded metallic material, the hydrogen content must be precisely determined. In the case of welds, for example, according to ISO 3690, this is the isothermal carrier gas hot extraction (CGHE). CGHE is based on accelerated hydrogen degassing due to thermal activation of hydrogen at elevated temperatures. In addition to the pure quantification of hydrogen, thermal desorption analysis (TDA) with varied heating rates can be used to determine and evaluate the bonding state at microstructural defects in the material. For both techniques, experimental and measurement influences have to be considered, which have a great effect on the result. For CGHE, for example, ISO 3690 suggests different sample geometries as well as minimum extraction times. The present study summarizes results and experiences of numerous investigations with different sample temperatures and geometries (ISO 3690 type B and cylindrical TDA samples) regarding: the influence of the sample surface (polished/welded), measurement accuracies depending on the sample volume as well as the insufficient monitoring of the effect of the PI controller on the extraction temperature. In particular, a deviating extraction temperature to the set temperature, can significantly falsify the measurement results. Based on the results, methods are shown to quickly reach the desired extraction temperature without having to physically interfere with the measurement equipment. This serves to substantially improve the reliability of hydrogen measurement through increased signal stability and accelerated hydrogen desorption. In general, an independent temperature measurement with dummy samples for the selected heating procedure is advisable to exclude possible unwanted temperature influences already before the measurement. In addition (and way more important), the methods described can be transferred directly to industrial applications. T2 - 47th MPA-Seminar CY - Stuttgart, Germany DA - 10.10.2023 KW - Hydrogen assisted cracking KW - Carrier gas hot extraction KW - Welding KW - ISO 3690 KW - Metals PY - 2023 AN - OPUS4-58677 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Engelking, Lorenz T1 - Herstellung beanspruchungsgerechter Oberflächen durch Kombination innovativer additiver und abtragender Fertigungsschritte an hochbelasteten Komponenten N2 - In vielen Anwendungen werden aufgrund zunehmender Anforderungen an den Widerstand gegenüber hohen, kombinierten mechanischen, tribologischen, thermischen und korrosiven Beanspruchungen Hochleistungsle¬gierungen eingesetzt. Den vielfach komplexen Bauteilstrukturen, herausfordernden Fertigungseigenschaften und der Erhöhung der Ressourceneffizienz lässt sich heute mit der additiven Fertigung (AM) begegnen, dem oftmals noch unzureichende Kenntnisse über die resultierende Homogenität und Anisotropie der speziellen Gefüge und den damit verbundenen Eigenschaften entgegensteht. Viele Anwendungen benötigen zudem definierte Oberflächen mit hohen Anforderungen an die Oberflächenintegrität, dem durch komplementären Einsatz von additiven und abtragenden Fertigungsschritten Rechnung getragen wird. Hochleistungslegierungen auf der Basis von Nickel oder Kobalt sind infolge der niedrigen Wärmeleitfähigkeit verbunden mit hoher Festigkeit und Zähigkeit äußerst herausfordernd mit Blick auf eine wirtschaftliche Zerspanung mit geometrisch bestimmter Schneide. Ein Vorhaben (IGF-Nr. 20.979 N/DVS-Nr. 1.3211) der BAM und TU Clausthal/ISAF befasst sich mit der Lösung dieser Problemstellung durch gezielte Beeinflussung des Gefüges mittels Modifikation der Schweißzusatzwerkstoffe und den Einsatz des ultraschallunterstützten Fräsens (US), bei gleichzeitiger Sicherstellung der geforderten Eigenschaften der untersuchten Werkstoffe. Es werden die Ergebnisse der Mikrostruktur und der Zerspanbarkeit der Modifikationen der MSG-Schweißung der FeNi36-Referenzlegierung mit 0,4 Gew.-% Zr und der Modifikationen der MSG-Schweißung der CoCr-Referenzlegierung mit 1 Gew.-% Zr sowie Hf vorgestellt. Abschließend werden aus den Ergebnissen Handlungsempfehlungen abgeleitet. T2 - Sitzung der Arbeitsgruppe (AG) V 12 „Additive Fertigung“ CY - Online meeting DA - 15.11.2023 KW - Legierungsmodifikation KW - Ultraschallunterstütztes Fräsen KW - Additive Fertigung KW - Oberflächenintegrität PY - 2023 AN - OPUS4-58859 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hübner, Martin T1 - Hybrider Einsatz von LTT-Schweißzusatzwerkstoffen N2 - LTT (Low Transformation Temperature) - Schweißzusätze stellen eine Alternative zur Verfügung, um die Schwingfestigkeit in Schweißnähten zu erhöhen. Ziel dieses Vortages ist es zum einem die Thematik der LTT - Schweißzusätze, insbesondere in hybrider Ausführung zu erläutern, Zum anderen werden die Ergebnisse der Vorversuche präsentiert. T2 - BMDK CY - Magdeburg, Germany DA - 25.10.2023 KW - LTT (Low Transformation Temperature) KW - Martensitstarttemperatur KW - Baustähle KW - Eigenspannungen KW - Aufmischung PY - 2023 AN - OPUS4-58690 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reichardt, Adrian A1 - Komann, Steffen T1 - Experience regarding ageing management and maintenance of transport packages in Germany N2 - The presentation gives an overview about the current experiences of BAM regarding ageing management of transport packages in Germany. The concept of the BAM-GGR 023 for ageing management of transport packagings will be described. The fundamentals of BAM-GGR 023 will be shown, including the following key aspects: -the organization of an Ageing Management System (AMS), -the issue of an Ageing Management Plan (AMP), -the ageing evaluation as a part of the AMP, -the Ageing Surveillance Program (ASP) as a part of the AMP, -the Ageing Management Documentation (AMD). T2 - First Consultancy Meeting on Drafting the Safety Guide on Ageing Management and Maintenance of Radioactive Material Transport Packages CY - Vienna, Austria DA - 20.11.2023 KW - Ageing Management KW - Dual Purpose Cask KW - BAM-GGR 023 PY - 2023 AN - OPUS4-58863 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Quercetti, Thomas A1 - Wille, Frank A1 - Neumann, Martin A1 - Linnemann, Konrad T1 - Full-scale drop testing with a heavy-weight package for radioactive waste N2 - Packages for the transport of radioactive materials shall fulfil the requirements of the IAEA regulations for the safe transport. The requirements define mechanical and thermal test conditions including criteria ensuring the package design’s ability to withstand severe accidents and provide a high level of technical safety. Different methods can be used for safety demonstration showing compliance with the regulations. The central part of a safety demonstration which is presented in this paper was a comprehensive drop test program with a full-scale model of a transport package accompanied by pre- and post-test FE analyses. Using full-scale drop test models allow the benefit that similarity and scaling issues become a significant smaller issue, additional material investigations can be limited and analyses for transferring test results to the original package design are reduced. Additionally, experience for the future serial packaging manufacturing and handling procedures can be collected in a very early state of the design approval process. The pre-test finite element analyses derived and justified the drop test program consisting of several drop sequences with different drop orientations of the specimen. The performance and the results of the drop test sequences shows the manageability and the advantage e.g., in view of the direct availability of test results for the package licensing. On the other hand, the drop test performance shows the difficulties during handling and the need for additional equipment during preparation of the specimen. The package presented was intended for the transport and storage of compacted radioactive waste from reprocessing of spent nuclear fuel assemblies - designed and applied for approval by the AGC consortium. The project ended in 2021. The package design was characterized by a cask body made of a forged thick stainless-steel shell, a bolted double lid system with metallic gaskets and wood filled shock absorbers at both ends. The total mass of the entire transport package including content was 120,000 kg, the total length was about 7000 mm and the diameter approximately 3000 mm, both measures include the shock absorbers. The paper provides an insight into the performance of a full-scale drop testing campaign within the package safety evaluation and shows some selected test results. T2 - 20th International Symposium on the Packaging and Transportation of Radioactive Materials (PATRAM 22) CY - Juan-Les-Pins, France DA - 11.06.2023 KW - Full-scale KW - Drop testing KW - Package KW - Radioactive materials transport PY - 2023 SP - 1 EP - 10 AN - OPUS4-57732 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Neumann, Martin A1 - Gleim, Tobias A1 - Gradt, Thomas T1 - Friction coefficients for wood-wood and wood-steel high pressure contact under temperatures between -40 °C and 90 °C N2 - Wood is widely used in impact limiters of Transport casks for radioactive material. Encapsulated by an outer and inner Steel structure, spruce wood is offen applied in layers of altemating direction. The friction at the interfaces between these layers is of crucial importance for the impact and energy absorption e.g., at an accidental impact of a cask against a hard component. In order to get detailed Information for corresponding numerical calculations, in this study the friction coefficient for the combinations wood-wood and wood-steel was measured in the temperature ränge between -40 °C and 90 °C according to the relevant stress conditions for such casks. Results show decreasing friction with increasing temperature, ranging from 0.43 at -40 °C to 0.22 for 90 °C for wood-steel combinations and from 0.3 at -40 °C to 0.24 at 90 °C to for a wood-wood combination. KW - Wood KW - Friction KW - Transport cask KW - Radioactive material PY - 2023 DO - https://doi.org/10.24053/TuS-2023-0007 SN - 0724-3472 VL - 70 IS - 2 SP - 5 EP - 12 PB - expert verlag AN - OPUS4-57787 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schubert, Sven A1 - Reichardt, Adrian A1 - Müller, Lars A1 - Neumann, Martin A1 - Komann, Steffen A1 - Wille, Frank T1 - Introduction of the German ageing management guide for packages for transport of radioactive materials N2 - The consideration of ageing mechanisms is with integration of the new para 613A into IAEA SSR-6 (Rev. 1) now obligatory for the design of transport packages. In addition, para 809(f) requires for packages intended to be used for shipment after storage the consideration of the effects of ageing mechanisms during storage in safety analyses and the implementation of corresponding instructions for operation and maintenance. Para 503(e) requires that all packaging components and radioactive contents have been maintained during storage in a manner that all requirements specified in IAEA SSR-6 (Rev.1) and in the applicable certificates of approval have been fulfilled. The evaluation of ageing mechanisms and their effects including monitoring are part of BAM’s authority assessment tasks related to the mechanical and thermal package design and quality assurance aspects. BAM has compiled a guideline for the implementation of ageing assessment and of the measures for ageing management of the approval procedure based on requirements of IAEA SSR-6 (Rev.1). The guideline is applicable only for packages requiring a competent authority approval. The paper aims to describe the structure of the guideline and the general approach for ageing management requirements. The type and amount of measures for ageing management depend mainly on the use of the package and on the ageing effects for the component, which result from relevant ageing mechanisms during package operation time. The implementation of measures for ageing management is divided into three levels – systemic measures, package design related measures and documentation. The systemic measures are attributed to the general management system and define the whole activities for organization of ageing management like structure, responsibilities, documentation, reports and evaluation. The package design related measures are defined in an ageing management plan (AMP). These measures shall ensure that the anticipated changes of the package design under consideration of ageing effects still complies with the design approval specification. Therefore, an ageing surveillance program (ASP) and, if necessary, a gap analysis program shall be developed. The ageing management documentation (AMD) ensures the continuous documentation of the compliance of a specific package to the approved package design, comprising mainly records resulting from operation and surveillance. T2 - PATRAM22 - 20th International Symposium on the Packaging and Transportation of Radioactive Materials CY - Juan-les-Pins, France DA - 11.06.2023 KW - Guide KW - Ageing KW - Mechanism KW - Package KW - Management PY - 2023 SP - 1 EP - 10 PB - World Nuclear Transport Institute (WNTI) CY - London AN - OPUS4-57770 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neumann, Martin A1 - Quercetti, Thomas A1 - Wille, Frank A1 - Gröke, Carsten A1 - Neumeyer, Tino T1 - Design assessment, approval of management systems and ageing aspects of transport packages for radioactive material not requiring competent authority approval of design N2 - Most transports of radioactive materials are carried out with packages not requiring competent authority approval of design. These encompass – in accordance with the IAEA SSR-6 regulations – packages of the classification excepted, Industrial packages Type 1, 2 and 3 and Type A packages. Currently an upsurge in number and variation of these package designs can be seen in Germany, resulting from the phase out of nuclear energy in Germany as well as e. g. increased use of radioactive material for medical purposes. A design assessment regarding the package safety is required in the international IAEA SSR-6 regulations. BAM operates facilities for the performance of all regulatory tests required such as drop towers for a wide range of package masses and dimensions, fire test, leak tightness measurements and pressure test facilities. Experiences with several package types are shown. Additionally, IAEA SSR-6 requires the establishment of a management system for design, manufacture, maintenance, and repair of the packaging as well as for the preparation, consigning, loading, carriage, unloading and receipt of the package. Relevant for Germany, BAM has published guidance material on the process of management system acceptance in the technical guide BAM-GGR 016. The requirements encompass quality management plans for the manufacturing of packages including independent manufacturing surveillance and specific instructions for operation, maintenance, and repair of packagings. Examples for management system specifics and requirements are given. Since the latest edition of the IAEA SSR-6 regulations an ageing evaluation including systematic ageing management measures are required for all kind of package types. BAM is going to update the guidance material BAM-GGR 016 to support the stakeholders with relevant information to fulfil the ageing aspect for packages not requiring competent authority approval. The paper explains how the ageing aspect may be included in the safety evaluation process and the management system measures and will give an outlook for the future guidance material. T2 - 20th International Symposium on the Packaging and Transportation of Radioactive Materials (PATRAM 22) CY - Juan-Les-Pins, Antibes, France DA - 11.06.2023 KW - Typ KW - Radioactive material KW - Non-approved PY - 2023 SP - 1 EP - 8 AN - OPUS4-57703 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Quackatz, Lukas T1 - Measurement of hydrogen concentration in steel using Laser-induced Breakdown spectroscopy (LIBS) N2 - Currently, the ISO 3690 standard requires a thermal activation of the diffusible hydrogen in weld metal for the subsequent ex situ concentration measurement by TDS. Laser-induced breakdown spectroscopy (LIBS) would offer a time and spatially resolved, almost non-destructive, measurement of hydrogen at surfaces. We could already show that this analysis technique allows for highly accurate in situ measurements of chemical compositions of e.g. Mn, Cr and Ni during welding e.g. in the melt pool, the weld metal or the heat affected zone. For quantitative LIBS measurements of hydrogen in steel, certified reference materials with different hydrogen concentrations were used for calibration. There is a significant problem in welding steels: A critical combination of diffusible hydrogen, hardness microstructure and weld residual stresses can cause cold cracks to form in the weld microstructure. We investigated hydrogen in steels, which was loaded either electrochemically or with high-pressure hydrogen gas. Subsequently, various experiments were conducted to verify the feasibility of hydrogen measurements with LIBS. For example, depth profiles of hydrogen distribution could be obtained. Furthermore, samples were water jet cut and a line scan was made over the cross section to obtain a spatially resolved representation of the hydrogen. Total hydrogen concentrations were determined using carrier gas hot extraction. Our results show that LIBS is a promising technique for time and spatially resolved measurement of hydrogen in steels. T2 - IIW Annual Assembly 2023 CY - Singapore DA - 16.07.2023 KW - LIBS KW - Hydrogen measurement KW - Welding KW - Stainless steel PY - 2023 AN - OPUS4-57989 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schubert, Sven T1 - Introduction of the German Ageing Management Guide for Packages for Transport of Radioactive Materials – BAM-GGR 023 N2 - BAM-GGR 023 was published in June 2022 BAM-GGR 023 gives guidance to applicants regarding ageing management for competent authority approved package designs Ageing management with evaluation of ageing mechanisms according to para 613A of IAEA SSR-6 (Rev. 1) and their effects are part of the general management system. Essential items are: AMS (systemic-related), AMP (package design-related) and AMD (package-related) There are different requirements for organization and extent of ageing management depending on type of use There are also different requirements for ageing evaluation depending on type of use for packaging/package, classification of components and their accessibility and replaceability T2 - PATRAM22 CY - Juan-les-Pins, France DA - 11.06.2023 KW - Package KW - Ageing KW - Mechanism KW - Management KW - Guide PY - 2023 AN - OPUS4-57821 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kromm, Arne T1 - Increasing the Significance of Varestraint Tests through Improved Crack Evaluation N2 - The contribution describes a newly developed software tool for crack identification and selection in Modified Varestraint Transvarestraint (MVT) testing. From the digital crack information, in addition to the classical results, such as Total Crack Length (TCL) and Maximum Crack Length (MCL), advanced evaluations can be applied, taking into account the loading and welding parameters. A numerical parameter study is conducted to demonstrate how the isolated variation of individual welding and loading parameters, affects the crack lengths that can potentially be expected based on the machine specifics. An alternative crack criterion is presented that evaluates the crack formation in relation to the machine behavior. Some examples demonstrate the possibilities and limitations of the approach. The criterion can be used to compare and transfer the results of different varestraint test variants. T2 - IIW Annual Assembly, Comission II-C CY - Singapore DA - 17.07.2023 KW - Solidification cracking KW - Varestraint-Test PY - 2023 AN - OPUS4-57984 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Heimann, Jan A1 - Yilmaz, Bengisu A1 - Charmi, Amir A1 - Duffner, Eric A1 - Schukar, Marcus A1 - Prager, Jens T1 - Structural Health Monitoring (SHM) for continuous monitoring of hydrogen pressure vessels N2 - While hydrogen is one of the most promising energy carriers, the safety of hydrogen storage technology remains one of the most important factors for technological and societal approval. While the engineering safety factors of the pressure vessels are kept high, the periodic inspection and the limited lifetime are making the application very costly considering manpower, time, money, and material waste. The development of an integrated structural health monitoring system can allow an easy transition from the current situation to cost-effective predictive maintenance. Hence, we propose to integrate three different SHM systems into hydrogen pressure vessels, namely guided wave ultrasonics, acoustic emission, and fibre optic sensing, to continuously monitor the condition and integrity. In this work, we evaluated the condition of a Type IV composite overwrapped pressure vessel using ultrasonic guided wave propagation. We mounted fifteen piezo-electric wafers on the composite cylinder by shaping three rings containing five sensors each. We acquired data from the sensor network following different boundary conditions with artificial damages on the selected locations. The data were evaluated with guided wave tomography techniques using ultrasonic features (amplitude, frequency, etc.) as well as artificial intelligence (AI). The results suggest that both traditional guided wave fusion techniques and AI-based characterization methods can detect artificial damages. In future work, it is planned to integrate acoustic emission and fibre optic sensing. Moreover, the measurement and the test results will be implemented into a digital twin to derive trends and make predictions on the damage propagation as well as the remaining useful lifetime. This work has received funding from German Ministry of Economic Affairs and Climate Actions within the QI-Digital initiative (www.qi-digital.de). T2 - SCHALL 23 CY - Wetzlar, Germany DA - 21.03.2023 KW - Structural Health Monitoring KW - Ultrasonic Guided Waves KW - Composite Overwrapped Pressure Vessel KW - Hydrogen PY - 2023 AN - OPUS4-58026 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Popiela, Bartosz T1 - PhD Topic 5: Summer School Update. Influence of manufacturing process related residual stresses in wound composite material on the operational safety of H2 pressure vessels N2 - The presentation is an update on the progress of the PhD Project. It focuses on the residual stress induction during the winding process of type 4 composite pressure vessels. Moreover, an overview of the experimental study is given, with focus on the manufacturing of composite pressure vessels. T2 - Summer School 2023 - BTU-BAM Graduate School "Trustworthy Hydrogen" CY - Berlin, Germany DA - 04.09.2023 KW - Residual stress KW - Composite KW - Pressure vessel KW - Hydrogen PY - 2023 AN - OPUS4-58239 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kolditz, O. A1 - Jacques, D. A1 - Claret, F. A1 - Bertrand, J. A1 - Churakov, S. V. A1 - Debayle, C. A1 - Diaconu, D. A1 - Fuzik, K. A1 - Garcia, D. A1 - Graebling, N. A1 - Grambow, B. A1 - Holt, E. A1 - Idiart, A. A1 - Leira, P. A1 - Montoya, V. A1 - Niederleithinger, Ernst A1 - Olin, M. A1 - Pfingsten, W. A1 - Prasianakis, N. I. A1 - Rink, K. A1 - Sampier, J. A1 - Szöke, I. A1 - Szöke, R. A1 - Theodon, L. A1 - Wendling, J. T1 - Digitalisation for nuclear waste management: predisposal and disposal N2 - Data science (digitalisation and artificial intelligence) became more than an important facilitator for many domains in fundamental and applied sciences as well as industry and is disrupting the way of research already to a large extent. Originally, data sciences were viewed to be well-suited, especially, for data-intensive applications such as image processing, pattern recognition, etc. In the recent past, particularly, data-driven and physics-inspired machine learning methods have been developed to an extent that they accelerate numerical simulations and became directly usable for applications related to the nuclear waste management cycle. In addition to process-based approaches for creating surrogate models, other disciplines such as virtual reality methods and high-performance computing are leveraging the potential of data sciences more and more. The present challenge is utilising the best models, input data and monitoring information to integrate multi-chemical-physical, coupled processes, multi-scale and probabilistic simulations in Digital Twins (DTw) able to mirror or predict the performance of its corresponding physical twins. Therefore, the main target of the Topical Collection is exploring how the development of DTw can benefit the development of safe, efficient solutions for the pre-disposal and disposal of radioactive waste. A particular challenge for DTw in radioactive waste management is the combination of concepts from geological modelling and underground construction which will be addressed by linking structural and multi-physics/chemistry process models to building or tunnel information models. As for technical systems, engineered structures a variety of DTw approaches already exist, the development of DTw concepts for geological systems poses a particular challenge when taking the complexities (structures and processes) and uncertainties at extremely varying time and spatial scales of subsurface environments into account. KW - Data science KW - Digitalization KW - Nuclear waste KW - Disposal KW - Predisposal PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-569387 DO - https://doi.org/10.1007/s12665-022-10675-4 SN - 1866-6280 VL - 82 IS - 1 SP - 1 EP - 11 PB - Springer AN - OPUS4-56938 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Gook, Sergej A1 - El-Batahgy, Abdel-Monem A1 - Gumenyuk, Andrey A1 - Biegler, Max A1 - Rethmeier, Michael T1 - Application of Hybrid Laser Arc Welding for Construction of LNG Tanks Made of Thick Cryogenic 9% Ni Steel Plates N2 - Hybrid laser-arc welding (HLAW) was applied for butt welding of 14.5 mm thick plates of ferritic cryogenic steel X8Ni9 containing 9% Ni, which is used for manufacturing storage and transport facilities of liquefied natural gas (LNG). The weld seam formation and the achievable metallurgical and mechanical properties of the hybrid welds were investigated experimentally for two types of filler wire, an austenitic wire dissimilar to the base metal (BM) and an experimentally produced matching ferritic wire. Safe penetration and uniform distribution of the austenitic filler metal in the narrow hybrid weld could only be achieved in the upper, arcdominated part of the weld. The pronounced heterogeneous distribution of the austenitic filler metal in the middle part and in the root area of the weld could not ensure sufficient notched impact toughness of the weld metal (WM). As a result, a decrease in the impact energy down to 17±3 J was observed, which is below the acceptance level of ≥34 J for cryogenic applications. In contrast, the use of a matching ferritic filler wire resulted in satisfactory impact energy of the hybrid welds of up to 134±52 J at the concerned cryogenic temperature of -196 °C. The obtained results contribute to an important and remarkable conversion in automated manufacturing of LNG facilities. In other words, the results will help to develop a new laser-based welding technology, where both quality and productivity are considered.The efficiency of the developed welding process has been demonstrated by manufacturing a prototype where a segment of the inner wall of large size LNG storage tank was constructed. In this concern, hybrid laser arc welding was conducted in both horizontal (2G) and vertical (3G) positions as a simulation to the actual onsite manufacturing. The prototype was fabricated twice where its quality was confirmed based on non-destructive and destructive examinations. KW - Hardness KW - Hybrid Laser arc Welding KW - 9% Ni Steel KW - Fusion zone size KW - Microstructure KW - Tensile Strength KW - Impact Absorbed Energy PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-586080 DO - https://doi.org/10.1007/s40516-023-00229-2 SP - 1 EP - 22 PB - Springer Nature AN - OPUS4-58608 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Lay, Vera A1 - Effner, Ute A1 - Niederleithinger, Ernst A1 - Arendt, J. A1 - Hofmann, M. A1 - Kudla, W. T1 - Correction: Lay et al. Ultrasonic quality assurance at magnesia shotcrete sealing structures. Sensors 2022, 22, 8717 N2 - The authors wish to correct the following errors in the original paper Lay, V.; Effner, U.; Niederleithinger, E.; Arendt, J.; Hofmann, M.; Kudla, W. Ultrasonic Quality Assurance at Magnesia Shotcrete Sealing Structures. Sensors 2022, 22, 8717, https://doi.org/10.3390/s22228717. PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-584969 DO - https://doi.org/10.3390/s23187966 SN - 1424-8220 VL - 23 IS - 18 SP - 1 EP - 3 PB - MDPI CY - Basel AN - OPUS4-58496 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Morichi, M. A1 - Fanchini, E. A1 - Bruggemann, C. A1 - Perot, B. A1 - Ricard, D. A1 - Niederleithinger, Ernst T1 - Developments and experiences of the CHANCE, MICADO and PREDIS projects in radioactive waste characterization N2 - Characterization is a very important step in dealing with materials and waste streams generated during the operational and decommissioning phases of nuclear installations, including nuclear power plants. Characterization allows differentiation between materials that can be released from regulatory control and those that require further treatment and conditioning to become a stable waste form suitable for future storage and final disposal according to its waste classification. Characterization is also needed in the pre-disposal stages of radioactive waste management to demonstrate compliance with the waste acceptance criteria of the facilities that will accept the different waste forms. This work will present the strategies developed and implemented by the three projects for in-depth and accurate waste characterization and investigation of the different radioactive waste packages considered. CHANCE, MICADO, and PREDIS will present their goals, the methods developed, the technologies used and the (preliminary) results contributing to the improvement of the safety and the data and information quality of the waste packages analyzed at the different stages of the waste management process. Special emphasis will also be given to complementary approaches highlighting the usability of the technologies, the accessibility of the data, and the problem-solving of the three projects within the European panorama. KW - Waste management KW - Radioactive waste KW - Waste chracterization PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-571872 DO - https://doi.org/10.1051/epjn/2022052 SN - 2491-9292 VL - 9 IS - 12 SP - 1 EP - 11 PB - EPJ Nuclear Sci. Technol. AN - OPUS4-57187 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lay, Vera A1 - Mielentz, Frank A1 - Prabhakara, Prathik A1 - Baensch, Franziska A1 - Johann, Sergej A1 - Hofmann, Detlef A1 - Sturm, Patrick A1 - Stamm, Michael A1 - Niederleithinger, Ernst T1 - Multi-sensory monitoring and ultrasound for quality assurance at underground sealing structures N2 - Within the safety concepts of underground disposal sites of nuclear waste, engineered barriers play an important role. As these sealing structures have high demands concerning integrity, we aim at advancing the available construction materials, monitoring, and inspection techniques within the project SealWasteSafe. A specifically developed alkali-activated material is compared to classical salt concrete. A comprehensive multi-sensory monitoring scheme is used at 150-340 l specimens to monitor setting and hardening of both materials. All sensors are demonstrated to resist the highly alkaline environments. Besides cabled and wireless temperature and humidity of the materials, strain variations using fibre optic sensors and acoustic emissions are recorded over periods of at least 28 days, partly for more than eight months. After hardening of the specimens, further nondestructive evaluations using ultrasonic echo and thermographic measurements are conducted. Preliminary results proof the suitability of the tested sensors and clearly highlight differences between the tested materials. Particularly, the newly developed alkali-activated material shows lower acoustic emission activity indicating less cracking activity. Additionally, unique ultrasonic methods will enable better images of potential internal objects and cracks at in-situ sealing structures. A largescale ultrasonic system is optimised to reliably detect objects at a depth exceeding 9 m while still obtaining a good resolution. Modelling studies show the potential of further increasing the distance between individual transducer arrays. Additionally, a new ultrasonic borehole probe using phased arrays allowing for beam focussing is constructed and tested. Laboratory measurements at a halfcylindrical concrete specimen coincide well with the previous modelling. In total, the presented safe materials, detailed monitoring approaches and ultrasonic quality assurance methods will help to obtain safe sealing structures within salt as a host rock. The concepts can partly be transferred to sealing structures in alternative host rocks and will also be valuable for non-nuclear waste repositories. T2 - NDE NucCon CY - Espoo, Finland DA - 25.01.2023 KW - SealWasteSafe KW - Engineered barriers KW - Monitoring KW - Embedded sensors KW - Ultrasonic imaging PY - 2023 SP - 2 EP - 10 AN - OPUS4-56928 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Asna Ashari, Parsa T1 - Drivers and Barriers to the Adoption of Hydrogen Technologies in Germany and the Republic of Korea - A Multidimensional Stakeholder Analysis N2 - The presentation provides a comparative analysis of the hydrogen economies in Germany and the Republic of Korea, highlighting similarities and differences. Thereupon, the presentation delves into the requirements for the development of a hydrogen economy, including the political and regulatory framework. T2 - Colloquium of the Research Institute for Sustainability (RIFS) Helmholtz Centre Potsdam - Research Group "Geopolitics of Transitions in Energy and Industry" CY - Online meeting DA - 05.06.2023 KW - Hydrogen economy KW - Technological innovation system KW - Country comparison PY - 2023 AN - OPUS4-57606 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gerards-Wünsche, Paul A1 - Ratkovac, Mirjana A1 - Schneider, Ronald A1 - Hille, Falk A1 - Baeßler, Matthias T1 - A framework for assessing the reliability of crack luminescence – an automated fatigue crack detection system N2 - The new crack luminescence method offers the possibility of making fatigue surface cracks in metallic materials more visible during inspections through a special coating system. This coating system consists of two layers, whereby the first layer has fluorescent properties and emits visible light as soon as it is irradiated by UV light. The top layer is black and is designed to prevent the fluorescent layer from emitting if no crack develops in the underlying material. The technique proved particularly useful in a wide variety of fatigue tests of steel components under laboratory conditions. Moreover, it has the potential to be used in various industrial applications. To enable industrial deployment and integration into maintenance strategies, a concept study is developed in this contribution, resulting in a qualification framework that can serve as a foundation for determining the reliability of the crack luminescence system in terms of a probability of detection curve. Within this study, factors causing measurement variability and uncertainty are being determined and their influences assessed. Due to the extension of the system by a moving computer vision system for automated crack detection using artificial intelligence, additional long-term effects associated with structural health monitoring systems need to be incorporated into an extended probability of detection study as part of the technical justification. Finally, important aspects and findings related to design of experiments are discussed, and a framework for reliability assessment of a new optical crack monitoring method is presented, emphasizing the influence of various uncertainty parameters, including long-term effects such as system ageing. T2 - SPIE Conference Smart Structures + Nondestructive Evaluation 2023 CY - Long Beach, CA, USA DA - 24.03.2023 KW - Structural Health Monitoring KW - Non-Destructive Evaluation KW - Probability of Detection KW - Reliability KW - Artificial Intelligence KW - Computer Vision KW - Crack Luminescence KW - Wind PY - 2023 SN - 978-1-5106-6086-1 DO - https://doi.org/10.1117/12.2658390 SP - 1 EP - 15 AN - OPUS4-57244 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Balscheit, Hagen A1 - Victor, A. A1 - Thiele, Marc A1 - Cuéllar, Pablo A1 - Baeßler, Matthias A1 - Lüddecke, F. T1 - Experimental Investigation on Buckling Behavior of soil-embedded Piles N2 - Monopiles are currently the predominant foundation type for offshore wind turbines in Europe. Due to the increasing dimensions of the turbines, pile diameters beyond 10m become necessary. A design-relevant failure mode of monopiles is the local buckling of the pile wall in the embedded sections. Relevant buckling guidelines do not consider the soil-structure interaction specifically, although the embedment may allow for a reduction of wall thickness. However, Eurocode-based design concepts require a validation with comparative buckling cases for validation, either in terms of buckling curve parameters for both the algebraic stress-based and semi-numerical LBA/MNA design concept or as a calibration factor kGMNIA for fully numerical GMNIA calculations. These parameters are not yet available for embedded shells. To close this gap, we have conducted experiments on piles embedded in sand to investigate local buckling under soil-structure-interaction. The results will be used to calibrate numerical models. This research was carried out as part of the VERBATIM research project, funded by PTJ/BMWK and supported by the Carbon Trust's Offshore Wind Accelerator consortium. T2 - EUROSTEEL 2023 CY - Amsterdam, The Netherlands DA - 11.09.2023 KW - Wind KW - Wind Energy KW - Shell Buckling KW - Offshore KW - Soil-Structure-Interaction PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-583641 DO - https://doi.org/10.1002/cepa.2313 SN - 2509-7075 VL - 6 IS - 3-4 SP - 1729 EP - 1734 PB - Ernst & Sohn Gmb AN - OPUS4-58364 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bernardy, Christopher T1 - Wärmestrahlung von Freistrahlflammen N2 - Wasserstoff als Energieträger gewinnt zunehmend an Bedeutung. Die Untersuchung von Störfallauswirkungen mit Wasserstoff rückt somit stärker in den Fokus. Da Wasserstoff meist unter Druck gelagert und transportiert wird, ist ein zu betrachtendes Szenario die Freisetzung aus einer Leckage mit anschließender Zündung. Die daraus resultierende Freistrahlflamme (Jet Flame) muss hinsichtlich der in die Umgebung emittierten Wärmestrahlung charakterisiert werden. In der Literatur existieren bereits verschiedene Modelle ([1], [2]), welche jedoch vermehrt auf Daten aus Kohlenwasserstoffflammen mit geringem Impuls basieren. Zur Überprüfung dieser Modelle wird im Zuge des BAM internen H2 Jet Flame Projektes die sicherheitstechnische Untersuchung von impulsbehafteten Wasserstoff Freistrahlflammen vorgenommen. Hierfür finden Versuche im Realmaßstab auf dem Testgelände Technische Sicherheit der BAM (BAM-TTS) statt. Gegenstand der Untersuchungen ist die Beurteilung der Auswirkungen von realistischen Freisetzungsszenarien hinsichtlich der Flammengeometrie und der freigesetzten Wärmestrahlung. Dabei werden Parameter wie Freisetzungswinkel, Leckagedurchmesser (z.Zt. 1 mm bis 10 mm), Druck (z.Zt. bis max. 250 bar) und Massenstrom (bis max. 0,5 kg/s) variiert. Zusätzlich können auch Einflüsse wie Art der Zündung, Zündort sowie Zündung mit zeitlichem Verzug untersucht werden. Gewonnene Erkenntnisse werden mit den Ergebnissen bereits vorhandener Modelle verglichen und diese im Bedarfsfall weiterentwickelt. Insbesondere wird der Fokus auf die Modellierung der freigesetzten Wärmestrahlung von Wasserstoffflammen gelegt. Herausforderung dabei stellt die IR-Vermessung und Modellierung von Sichtmodellen der Flammen dar. Die Visualisierung der Flammengeometrie wird mit Hilfe mehrerer Infrarot Kamerasystemen (aus mindestens zwei Blickwinkeln) vorgenommen. Bisherige Messungen, die in der Literatur zu finden sind, basieren meist auf instationären Auströmbedingungen. Der hier verwendete Versuchsaufbau ermöglicht ein stationäres Ausströmen für mehrere Minuten und somit eine direkte Vergleichbarkeit mit den existierenden (stationären) Modellen. Weiterhin ist der Versuchsstand umrüstbar für Vergleichsmessungen mit Kohlenwasserstoffen (Methan etc.) sowie Mischungen aus Wasserstoff und Kohlenwasserstoffen. T2 - DECHEMA - Fachgruppe Auswirkungen von Stoff- und Energiefreisetzungen CY - Online meeting DA - 08.11.2023 KW - Freistrahlflamme KW - Wärmestrahlung KW - Wasserstoff KW - Methan PY - 2023 AN - OPUS4-60513 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Chamorro, C. R. T1 - Thermodynamic (p, ρ, T) characterization of H2-enriched natural gases N2 - Hydrogen-enriched natural gas, H2NG is a mixture of natural gas and H2 that can be used on existing natural gas infrastructure with little or even no modification to be applied H2NG is thus an option in the transition from fossil fuels to a hydrogen economy, as it can reduce greenhouse gas emissions and can accelerate the adoption of H2 from renewable sources. Theoretically, H2 can be mixed with NG in any ratio, but H2NG mixtures with up to 20 vol-% of H2 represent the most realistic near term option due to technical and economic reasons. The addition of H2 to natural gas alters the thermodynamic properties of the mixture, which affects its transport, storage, and combustion characteristics. In this work, we present experimental density measurements for different H2NG mixtures, performed with a high-precision single sinker densimeter from 250 to 350 K and up to 20 MPa. The mixtures were prepared gravimetrically according to ISO 6142-1 for maximum precision in their composition. T2 - The 22nd European Conference on Thermophysical Properties ECTP 2023 CY - Venice, Italy DA - 10.09.2023 KW - Hydrogen-enriched natural gas KW - Single-sinker densimeter KW - High-pressure density KW - Equations of state PY - 2023 AN - OPUS4-60473 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina A1 - Rhode, Michael A1 - Kannengießer, Thomas T1 - Mikrolegierungseinfluss auf das Ausscheidungsverhalten und die mechanischen Eigenschaften geschweißter hochfester Baustähle N2 - Mikrolegierungselemente, wie Nb und Ti, sind für die signifikante Festigkeitssteigerung von vergüteten, hochfesten Feinkornbaustählen mit einer Nominalstreckgrenze ≥ 690 MPa unerlässlich. Normvorgaben zur chemischen Zusammensetzung geben dabei nur obere Grenzwerte für die Hersteller vor. Weiterhin wirken sich bereits kleine Abweichungen in der Legierungsroute teilweise drastisch auf die mechanischen Eigenschaften aus. Somit wird eine adäquate Vorhersage der Schweißeignung und der Integrität der Schweißverbindung aufgrund der variierenden Mikrogefüge erschwert bis unmöglich. Unerwünschte Nebeneffekte sind die mögliche Erweichung der Wärmeeinflusszone (WEZ) als auch der gegenteilige Effekt der Aufhärtung. Vor diesem Hintergrund werden erstmals systematisch die unterschiedlichen Mikrolegierungsrouten mit variierenden Ti und Nb-Gehalten an Versuchsschmelzen untersucht. Die Stahlgüte S690QL bildet dabei die Grundlage der chemischen Zusammensetzung sowie der entsprechenden Wärmebehandlung. Zur Untersuchung der jeweiligen Schweißeignung wurden Dreilagen-Schweißungen mittels moderner MAG-Hochleistungsschweißprozesse durchgeführt und kritische Gefügebereiche mit hoher Erweichung/Aufhärtung identifiziert. Der Fokus der analytischen Betrachtungen lag hier auf der Identifikation der Phasenumwandlungen beim Abkühlen und auf dem metallurgischen Ausscheidungsverhalten. Zusätzlich wurden isotherme und nicht-isotherme Phasenberechnungen mit der Software Thermo-Calc durchgeführt. Mechanisch-technologische Untersuchungen zur Kerbschlagzähigkeit mittels Kerbschlagbiegeversuchen durchgeführt wurden, bestätigen dabei die Ergebnisse der thermodynamischen Simulation bezüglich des Ausscheidungsverhaltens während der Temperatur-Zeit Schweißzyklen. Daraus lässt sich der Einfluss der Wärmeeinwirkung beim Schweißen auf die Gefügeausbildung in der WEZ und der korrespondierenden mechanischen Eigenschaften qualitativ beschreiben. T2 - DVS Congress 2023 Große Schweißtechnische Tagung CY - Essen, Germany DA - 11.09.2023 KW - WEZ-Erweichung KW - Mikrolegierungseinflüsse KW - Hochfester Feinkornbaustahl KW - Kerbschlagzähigkeit PY - 2023 SN - 978-3-96144-230-0 VL - 389 SP - 218 EP - 225 PB - DVS Media GmbH CY - Düsseldorf AN - OPUS4-59419 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina T1 - Einfluss unterschiedlicher Mikrolegierungsrouten eines S690QL auf das Ausscheidungsverhalten in der WEZ N2 - Mikrolegierungselementen, wie Nb und Ti sind für eine signifikante Festigkeitssteigerung von vergüteten, hochfesten Feinkornbaustählen mit einer Nominalstreckgren-ze ≥ 690 MPa unerlässlich. Normvorgaben zur chemischen Zusammensetzung dieser Stähle geben zur Erzielung der vorgeschriebenen Eigenschaften dabei oft nur Grenzgehalte für die Hersteller vor. Die Wirkung der Mikrolegierungselemente bzw. ihrer Karbide und/oder Nitride ist teilweise komplett konträr, insbesondere bei Auflösung und Wiederausscheidung in der WEZ bei identischem Schweißzusatz. Somit wird eine adäquate Vorhersage der Chargenabhängigkeit hinsichtlich der Schweißeignung und des Tragverhaltens der Schweißverbindung erschwert. Eine unerwünschte Eigenschaft ist dabei die Erweichung der WEZ, wie auch u.U. der gegenteilige Effekt der Aufhärtung. T2 - 5. Symposium Materialtechnik CY - Clausthal-Zellerfeld, Germany DA - 23.02.2023 KW - Divergente Ausbildung der Wärmeeinflusszone KW - Hochfester vergüteter Feinkornbaustahl KW - Thermodynamische Simulation KW - Mikrolegierungseinfluss PY - 2023 AN - OPUS4-58004 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kromm, Arne T1 - Increasing the Significance of Varestraint Tests through Improved Crack Evaluation N2 - It was found that there is a systematic dependence of the crack growth on the welding parameters as well as on the load. Decreasing welding speeds with simultaneously higher heat input promote crack formation with increasing strain rate. Based on the results, a new crack criterion was finally selected which allows an extended assessment of the material behavior during the MVT-test. The threshold introduced can quantify the dependencies of the crack formation on the welding and testing parameters, which could not be comprehensively described with the conventional evaluation. In principle, the evaluation routine can also be transferred to other Varestraint or externally loaded hot cracking tests. T2 - IIW Intermediate Meeting Comission II-c CY - Garching, Germany DA - 06.03.2023 KW - Solidification cracking KW - Varestraint-Test PY - 2023 AN - OPUS4-57131 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröpfer, Dirk T1 - Residual stress formation in DED-arc manufactured high strength steel components N2 - Additive manufacturing (AM) processes enable the efficient production of advanced constructions. New developments in topology optimization are leading to weight-optimized designs of increasing complexity. Direct energy deposition processes (DED) such as wire and arc-based additive manufacturing are an important method of additive manufacturing. The wire filler metals enable a wide range of materials, while the arc process provides a high deposition rate compared to laser and powder-based processes. Combined with the use of high-strength steels, the thickness of walls or components can be significantly reduced in the context of lightweight construction, which results in significant savings in energy, costs, time and resources. Suitable high-strength steel filler metals are commercially available for DED-arc AM processes. However, guidelines and quantitative knowledge about welding stresses and cold cracking issues during component production and service are lacking. This limits the industrial application considerably. In a joint project of BAM and Chemnitz University of Technology, the main influences and complex interactions of material, production process, design and processing steps on the residual stress level are investigated. The aim is to develop processing recommendations and a cold cracking test for economical processing and stress-related design of high-strength steels with DED-arc. This study focuses on residual stress analysis by neutron diffraction (ND) and X-ray diffraction (XRD) on defined test specimens. The ND analysis were performed at the Paul Scherrer Institute- Villigen, Switzerland (PSI) and the XRD analysis at BAM. The study shows a quantitative and qualitative comparison of the residual stress magnitudes and distribution between the component bulk (ND) and surface (XRD) analyses. The ND analysis reveals that in DED-arc AM walls the residual stresses dominate in the direction of welding and are negligibly small in each case transverse to the direction of welding. The topology of the analyzed residual stresses shows almost identical residual stress maps compared to XRD. In addition, the residual stresses are significantly influenced by the solid phase transformation of the material due to low cooling times and less post heat treatment cycles of following AM layers in the area of the top layer. T2 - IIW Intermediate Meeting C-II/CIX CY - Munich, Germany DA - 06.03.2023 KW - Additive manufacturing KW - High strength steel KW - Residual stress PY - 2023 AN - OPUS4-59307 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Eissel, A. A1 - Engelking, Lorenz A1 - Gustus, R. A1 - Treutler, K. A1 - Wesling, V. A1 - Schröpfer, Dirk A1 - Kannengießer, Thomas T1 - Alloy modification for additive manufactured Ni alloy components—part I: effect on microstructure and hardness of Invar alloy N2 - Alloy 36 (1.3912), also known as “Invar,” is an alloy with 36% nickel. The alloy has a remarkably low thermal expansion coefficient in certain temperature ranges. This peculiarity is called the invar effect, which was discovered in 1896 by the Swiss physicist Charles Édouard Guillaume. Therefore, it is used in applications in which dimensional stability is critical, such as molding tools for composite materials in aerospace, automotive applications, or liquified natural gas (LNG) cargo tanks. Moreover, increasingly complex structures and the optimization of resource efficiency also require additive manufacturing steps for the production or repair of components. Additively manufactured components have a heterogeneous microstructure and anisotropic mechanical properties. In addition, the manufactured components require subsequent machining surface finishing, like finish milling, to achieve their final contour. Nickel iron alloys are difficult to machine. Additionally, inhomogeneous microstructure may lead to unstable cutting forces and conditions. In part I of this investigation, the initial alloy 36 is modified with the elements Ti, Zr, and Hf up to a maximum of 0.33 wt.-%. The influence of the modification elements on the microstructure as well as on the hardness of the AM components is examined. Furthermore, one modification is applied to metal arc welding process and investigated. Part II focuses on the effect of the alloy modifications on machinability as well as on the surface integrity of plasma-transferred-arc-welded (PTA) and finish milled invar components. T2 - 75th IIW Annual Assembly CY - Tokyo, Japan DA - 17.07.2022 KW - Alloy modification KW - Alloy 36 KW - Plasma-transferred arc welding PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-571777 DO - https://doi.org/10.1007/s40194-023-01510-w SN - 0043-2288 SP - 1 EP - 9 PB - Springer CY - Heidelberg AN - OPUS4-57177 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Engelking, Lorenz A1 - Eissel, A. A1 - Schröpfer, Dirk A1 - Treutler, K. A1 - Kannengießer, Thomas A1 - Wesling, V. T1 - Optimisation of surface residual stresses using ultrasonic‑assisted milling for wire‑arc additive manufactured Ni alloy components N2 - Nickel alloys are cost intensive materials and generally classified as difficult-to-cut material. However, machining of these materials is needed especially in case of alloy 36 (1.3912), which is commonly used in mould construction for the production of fibre-reinforced composites. With regard to repair, modification and manufacturing of such components, additive manufacturing offers significant economic advantages. Nevertheless, subsequent machining steps are needed to achieve the final component contour and defined surface conditions. Dependent on the material and machining process conditions, detrimental tensile residual stresses may be the result on the machined surface, having negative impact on the component performance and safety. In this investigation, machining experiments were carried out on wire arc additive manufactured components made of alloy 36, varying the cutting speed and the feed rate. In addition, the conventional milling process (CM) was compared with a modern, hybrid machining process, the ultrasonic-assisted milling (US). The cutting forces and the surface-near residual stresses were analysed using X-ray diffraction. A significant improvement of the machinability as well as the surface integrity by using the ultrasonic assistance was observed, especially at low cutting speeds. The CM induced mainly tensile residual stresses, the US mainly compressive residual stresses. KW - Surface integrity KW - Ultrasonic-assisted milling KW - Additive manufacturing KW - Ni alloy KW - Alloy 36 PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-575246 DO - https://doi.org/10.1007/s00170-023-11326-z SN - 1433-3015 VL - 126 IS - 9 SP - 4191 EP - 4198 PB - Springer Nature AN - OPUS4-57524 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rhode, Michael A1 - Kromm, Arne A1 - Mente, Tobias A1 - Brackrock, Daniel A1 - Czeskleba, Denis A1 - Kannengießer, Thomas T1 - Component test for the assessment of delayed hydrogen-assisted cracking in thick-walled SAW joints for offshore applications N2 - Offshore wind turbines continuously increase in size and weight and demand adequate offshore foundations concepts like monopiles, tripods, or jackets. These components are typically constructed using submerged arc welding (SAW) with high-strength thick steel plates like the S420ML. During welding, the occurrence of delayed hydrogen-assisted cracking (HAC) must be anticipated. HAC is a critical combination of the local hydrogen concentration within a susceptible microstructure under certain mechanical load, i.e., the occurring (welding) residual stresses. The welding sequence of the thick-walled plates complicates the residual stress distribution due to the necessary repeated thermal cycling, i.e., welding seam/layer deposition to fill the joint. For that purpose, SAW with two-wire-technique was used to weld a specially designed and prototype-like mock-up of a real component with a thickness of 50 mm, filled with over 20 passes and a seam length of 1000 mm. Additional welded stiffeners simulated the effect of a high restraint, to achieve critical HAC conditions. The necessity of a minimum waiting time (MWT) before the NDT can be conducted (to exclude HAC) was critically verified by the application of ultrasonic testing of the welded joint at different time-steps of the NDT of up to 48 h after the completion welding. The residual stresses were determined by a robot XRD goniometer. Tensile residual stresses up to the yield limit are found both in the weld metal and in the heat-affected zone. Numerical modeling allowed the qualitative estimation of the hydrogen diffusion in the weld. No noticeable HAC occurrence was identified and confirms the high cracking resistance of the investigated material. Finally, the applicability of the MWT concept should be critically discussed. KW - Hydrogen KW - Cold cracking KW - Minimum Waiting Time KW - Offshore steel grade KW - Component test PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-591981 DO - https://doi.org/10.1007/s40194-023-01658-5 SP - 1 EP - 15 PB - Springer Science and Business Media LLC AN - OPUS4-59198 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schröder, Nina A1 - Rhode, Michael A1 - Kannengießer, Thomas T1 - Thermodynamic prediction of precipitations behaviour in HAZ of a gas metal arc welded S690QL with varying Ti and Nb content N2 - For a significant increase in the strength of high-strength fine-grained structural steels with a nominal yield strength ≥690 MPa, the addition of microalloying elements such as Nb and Ti is required. The standard specifications for the chemical composition of these steels (e.g., in EN 10025-6) often only give the manufacturer limit contents to achieve the defined properties. The effect of the alloying elements in the heat affected zone (HAZ) is sometimes completely contrary. This makes it difficult to adequately predict the batch dependency regarding weldability and the load-bearing behaviour of the welded joint. Three different micro-alloyed steels of the grade S690QL were produced on a laboratory scale, focusing on different Nb and Ti contents. To investigate the tempering effect, these were gas metal arc welded in three layers. In addition to metallographic investigations of individual HAZ areas, thermodynamic phase calculations were carried out using Thermo-Calc, following variations in the chemical composition. This provides an understanding of phase transformation, precipitation growth, and dissolution during welding as a function of temperature and cooling conditions. The results show a divergent metallurgical behaviour in the HAZ of the three different micro-alloyed steels. Thereby, the Ti micro-alloyed grade showed a strong softening of the HAZ in contrast to the Nb micro-alloyed grade. This can be attributed to a contrary precipitation behaviour during welding. KW - High-strength structural steel KW - Gas metal arc welding KW - HAZ-softening KW - Microalloying influences KW - Thermodynamic simulation PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-579988 DO - https://doi.org/10.1007/s40194-023-01550-2 SN - 0043-2288 SP - 1 EP - 10 PB - Springer AN - OPUS4-57998 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Wandtke, Karsten A1 - Schröpfer, Dirk A1 - Scharf-Wildenhain, R. A1 - Hälsig, A. A1 - Kromm, Arne A1 - Kannengießer, Thomas A1 - Hensel, J. T1 - Fertigungsbedingte Beanspruchungen und Kaltrisssicherheit in generativ gefertigten Bauteilen aus hochfesten Feinkornbaustählen - Kurzdarstellung der Projektergebnisse, FOSTA P1380 N2 - Die Verwendung hochfester Feinkornbaustähle hat für viele Anwendungen des Stahlbaus ein großes Potenzial für gewichtsoptimierte, effiziente Strukturen mit ho-her mechanischer Beanspruchbarkeit. Weitere Zugewinne an Effizienz sind durch generative Fertigungsschritte sowie bionische Bauweisen erzielbar. Hierzu stehen bereits kommerzielle hochfeste drahtförmige Zusatzwerkstoffe für formgebendes MSG-Schweißen zur Verfügung. Dem Einsatz stehen noch fehlende quantitative Aussagen zu den fertigungsbedingten Beanspruchungen und der Bauteilsicherheit während Herstellung und Betrieb im Wege. Dies betrifft insbesondere prozess- sowie materialbedingte Einflüsse und die konstruktive Schrumpfbehinderung verbunden mit der Ausbildung hoher Zugeigenspannungen und damit zusammenhängenden Kaltrissbildung. Hierfür wurden im Projekt detaillierte und anwenderbezogene Kenntnisse zu den komplexen Wechselwirkungen zwischen Schweißprozess und Wärmeführung während der Fertigung, der metallurgischen Vorgänge und insbesondere der vorliegenden konstruktiven Einflüsse auf die entstehenden Eigenspannungen erarbeitet, um ein frühzeitiges Bauteilversagen aufgrund eines hohen fertigungsbedingten Beanspruchungsniveaus bis hin zu einer Rissbildung während der Fertigung sicher zu vermeiden. Gleichzeitig wurden die Einflüsse auf die mechanisch-technologischen Gütewerte systematisch analysiert. Zudem wurden die Auswirkungen trennender Verfahren durch Entfernen der Substratplatte sowie durch die spanende Bearbeitung der Vorformlinge zu Endbauteilgeometrien geklärt, da diese unmittelbar den Eigenspannungszustand beeinflussen und deutlichen Verzug der Bauteile auslösen. Für das generative Schweißen konnten Verarbeitungsempfehlungen sowie Normenvorgaben erarbeitet werden. Dies hilft insbesondere KMU eine wirtschaftliche, beanspruchungsgerechte und risssichere generative Fertigung von Bauteilen aus hochfesten Feinkornbaustählen zu ermöglichen. KW - MAG-Schweißen KW - Additive Fertigung KW - Eigenspannungen KW - Kaltrisssicherheit KW - Hochfester Stahl PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-582198 N1 - Das IGF-Vorhaben IGF-Nr. 21162 BG (P 1380) "Fertigungsbedingte Beanspruchungen und Kaltrisssicherheit in generativ gefertigten Bauteilen aus hochfesten Feinkornbaustählen" der Forschungsvereinigung Stahlanwendung e. V. wurde über die AiF im Rahmen des Programms zur Förderung der Industriellen Gemeinschaftsforschung (IGF) vom Bundesministerium für Wirtschaft und Klimaschutz aufgrund eines Beschlusses des Deutschen Bundestages gefördert. SP - 1 EP - 2 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-58219 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hübner, Martin T1 - Hybrid use of LTT welding filler N2 - Through a hybrid use of Low Transforamtion Temperature welding filler, fatigue strength of welds should be increased. Through the hybrid use of LTT welding filler the Integrity of a weld will be less affected. By creating several variants of LTT weld geometries an idea of the optimum residual stress reduction is given. T2 - European Academy of Wind Energy (EAWE) CY - Hannover, Germany DA - 06.09.2023 KW - Welding KW - LTT (Low Transformation Temperature) KW - Fatigue strength KW - High-strength steels KW - Residual stress PY - 2023 AN - OPUS4-58362 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Liepold, Philipp T1 - Anwendung von Convolutional Neural Networks (CNNs) bei der Erkennung von Rissen im Modifizierten Varestraint-Transvarestraint-Heißrisstest (MVT-Test) N2 - Der MVT-Test ist die an der BAM entwickelte und genutzte Version des Varestraint-Tests der weltweit für die Charakterisierung der Erstarrungsrissanfälligkeit von Schweißzusätzen und Legierungen eingesetzt wird. Die Auswertung solcher Tests erfolgt klassisch unter dem Lichtmikroskop. Durch Automatisierung des Auswerteprozesses mit KI kann der Informationsgehalt des Tests besser ausgeschöpft und eine höhere Vergleichbarkeit zwischen Testergebnissen gewährleistet werden. T2 - DVS-Congress CY - Essen, Germany DA - 10.09.2023 KW - MVT KW - Varestraint KW - KI KW - Neuronales Netzwerk KW - Semantic Segmentation PY - 2023 AN - OPUS4-58313 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Engelking, Lorenz A1 - Schröpfer, Dirk A1 - Kannengießer, Thomas A1 - Eissel, A. A1 - Treutler, K. A1 - Wesling, V. T1 - Herstellung beanspruchungsgerechter Oberflächen durch Kombination innovativer additiver und abtragender Fertigungsschritte an hochbelasteten Komponenten N2 - Die additive Fertigung (AM) durch schweißtechnische Verfahren eröffnet vielfach ökonomische Vorteile für eine ressour-ceneffiziente Bauteilherstellung. Gerade hinsichtlich der Homogenität und Anisotropie der resultierenden Schweißgefüge und den damit verbundenen Eigenschaften gibt es noch offene Fragestellungen. Die Einstellung der finalen Bauteilgeo-metrie und Oberflächengüte erfordert den komplementären Einsatz abtragender Fertigungsschritte. Hochleistungslegie-rungen auf der Basis von Nickel oder Kobalt sind aufgrund ihrer niedrigen Wärmeleitfähigkeit verbunden mit hoher Festigkeit und Zähigkeit schwer spanbar. Eine gezielte Gefügebeeinflussung mittels Modifikation der AM-Schweißzusatz-werkstoffe und der Einsatz des ultraschallunterstützten Fräsens (US) bietet das Potential insgesamt die Zerspanungssi-tuation zu verbessern. Dieser Lösungsansatz unter Gewährleistung des Erhalts der geforderten Werkstoff- bzw. Bauteileigenschaften ist Untersuchungsgegenstand eines Gemeinschaftsvorhabens (IGF-Nr. 20.979 N/DVS-Nr. 1.3211) der BAM und TU Clausthal/ISAF. Der vorliegende Beitrag stellt Ergebnisse für die beiden untersuchten FeNi- und CoCr-Legierungen sowie wesentliche Zusammenhänge zwischen Legierungsmodifikation, entstehender Gefügemorphologie und Zerspanungseigenschaften der mittels MAG additiv gefertigter Proben vor. Das größte Potential für die Modifikation zeigten Zr und Hf. Die Zulegierung in das Schweißgut erfolgte durch Beschichtung von Massivdrähten sowie durch Her-stellung von Fülldrähten. T2 - DVS Congress - GST CY - Essen, Germany DA - 11.09.2023 KW - Legierungsmodifikation KW - Ultraschallunterstütztes Fräsen KW - Additive Fertigung KW - Oberflächenintegrität PY - 2023 SN - 978-3-96144-230-0 VL - 389 SP - 697 EP - 703 PB - DVS Media GmbH CY - Düsseldorf AN - OPUS4-58380 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael A1 - Kannengießer, Thomas A1 - Mente, Tobias T1 - Zuverlässige Wasserstoff Bestimmung in Metallen und ihren Schweißverbindungen: Parameter, Einflüsse, Grenzen N2 - Im Zuge der wasserstoffbasierten Energiewirtschaft von morgen, kommt der Errichtung der dementsprechenden Infrastruktur die zentrale Rolle zu. Der überwiegende Teil bisher eingesetzter und meist geschweißter Werkstoffe, wie Stähle, kann unter bestimmten Bedingungen zur Wasserstoffversprödung neigen. Dies umfasst die klassische verzögerte Kaltrissbildung während der Schweißverarbeitung als auch Versprödungsphänomene während des Betriebs. Für die Bewertung eines jeden Wasserstoffeffektes auf bspw. die mechanischen Eigenschaften eines geschweißten metallischen Werkstoffes, muss der Wasserstoffgehalt präzise bestimmt werden, Im Fall von Schweißnähten ist die beispielsweise nach der ISO 3690, die klassische isotherme Trägergas-Heißextraktion (TGHE). Die TGHE basiert dabei auf der beschleunigten Wasserstoffentgasung aufgrund der thermischen Aktivierung des Wasserstoffs bei erhöhten Temperaturen. Neben der reinen Quantifizierung des Wasserstoffs, kann über die thermische Desorptionsanalyse (TDA) mit variierten Heizraten, der Bindungszustand an mikrostrukturellen Defekten im Material festgestellt und bewertet werden. Für beide Techniken sind experimentelle und messtechnische Einflüsse zu beachten, die großen Effekt auf das Ergebnis haben. Für die TGHE schlägt die ISO 3690 schlägt beispielswiese verschiedene Probengeometrien sowie Mindestextraktionszeiten vor. Die vorliegende Studie fasst Ergebnisse und Erfahrungen zahlreicher Untersuchungen an der Bundesanstalt für Materialforschung und -prüfung (BAM) mit unterschiedlichen Probentemperaturen und Geometrien (ISO 3690 Typ B und zylindrische TDA-Proben) zusammen hinsichtlich: Einfluss der Probenoberfläche (poliert/geschweißt), Messgenauigkeiten in Abhängigkeit des Probenvolumens sowie die unzureichende Überwachung des Effektes des PI-Reglers auf die Extraktionstemperatur. Insbesondere eine abweichende Extraktionstemperatur zur eingestellten Temperatur, kann die Messergebnisse wesentlich verfälschen. Basierend auf den Ergebnissen werden Methoden aufgezeigt, um schnell die gewünschte Extraktionstemperatur zu erreichen, ohne physisch in das Messequipment eingreifen zu müssen. Dies dient der wesentlichen Verbesserung der Zuverlässigkeit der Wasserstoffmessung durch erhöhte Signalstabilität und beschleunigte Wasserstoffdesorption. Im Allgemeinen ist eine unabhängige Temperaturmessung mit Dummy-Proben für die gewählte Heizprozedur angeraten, um mögliche unerwünschte Temperatureinflüsse bereits vor der Messung auszuschließen. Die beschriebenen Methoden können ohne großen Aufwand direkt in die industrielle Anwendung überführt werden. T2 - DVS Congress 2023 CY - Essen, Germany DA - 11.09.2023 KW - Wasserstoff KW - Schweißen KW - Forschung KW - ISO 3690 PY - 2023 SN - 978-3-96144-230-0 VL - 389 SP - 435 EP - 442 PB - DVS Media GmbH CY - Düsseldorf AN - OPUS4-58309 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schilling, O. A1 - Neumann, Martin T1 - System of Quality Assurance Measures in Manufacturing and Operation of Dual Purpose Casks for Spent Nuclear Fuel and High Level Waste in Germany N2 - German spent nuclear fuel and high level waste is stored in dry conditions in interim storage facilities until a final repository will be ready for operation in the future. Dual purpose casks are used for the packaging of the materials to ensure transportability at any time during long-term interim storage and fulfilling both requirements from interim storage as well as transport. Germany’s 2011 decision to phase out utilization of nuclear energy has led to a high demand for casks for decommissioning power plants as quickly as possible. Cask serial production will continue at a high level for the next few years. In the process, a system of quality assurance measures ensures that every cask reliably complies with design specification according the transport approval certificate and storage license. When the first casks were manufactured in Germany about 40 years ago, quality assurance was oriented towards pressure vessel and general nuclear manufacturing. The system was continuously adapted to the state of the art. In particular serial production, globalization of manufacturing and deep supplier chains had to be taken into account. The system of quality assurance measures applied today for cask manufacturing shall be presented here. The quality assurance measures can be categorized as system-related and design-related. With respect to transport regulations for example, they are independently approved and monitored by the competent authority BAM and its authorized inspection experts. The qualification of the applicant is reviewed first in the context of the design approval procedure and then periodically. The qualification of component and cask manufacturers is also checked at the start of manufacturing and then periodically. Before the start of manufacturing documents such as quality plans are pre-assessed. Manufacturing and inspection are then performed according to the pre-assessed documents. Cask manufacturing is completed by a final inspection before commissioning. Periodic inspections during operation ensure preservation of the properties specified in the approval certificate over package life time. The type and the time interval of periodic inspections depend on the use of the package. For transport after interim storage a system of specific tests and inspections is prescribed. T2 - 20th International Symposium on the Packaging and Transportation of Radioactive Materials (PATRAM 22) CY - Juan-les-Pins, France DA - 11.06.2023 KW - Radioactive material KW - Quality Assurance Measures KW - Dual Purpose Casks KW - Independent Surveillance PY - 2023 AN - OPUS4-57705 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kromm, Arne T1 - Influence of Residual Stresses on Stress Relief Cracking of Thick-Walled Creep-Resistant Steel Welds N2 - Controlling the residual stress level during welding of creep-resistant Cr-Mo-V steels is crucial to avoid so called stress relief cracking (SRC) during post weld heat treatment (PWHT) of large-scale components. In the present study, a laboratory scale test specimen (400 mm x 400 mm x 25 mm) was used to simulate thick-walled component welds made of 13CrMoV9-10. The aim was to identify the level and distribution of residual stresses to evaluate the suitability of the specimen for laboratory based SRC testing. High restraint was ensured by the specimen geometry with a narrow welding gap in the center. This gap was filled by submerged arc welding in a multi-layer technique. Two specimens were welded with identical parameters and compared in the as-welded state and after PWHT (705 °C for 10 h). Neutron diffraction was used to determine the residual stresses in the weld metal, the heat-affected zone (HAZ) and the base material at different depths longitudinal, transverse, and normal to the welding direction. The experiments were performed on the instrument E3 of the research reactor BERII of HZB Berlin, Germany. Complementarily, laboratory X-ray diffraction was applied to characterize the surface residual stresses. In the welded state, especially in the weld metal and the adjacent HAZ, the residual stress can reach the yield strength of the untreated material. The highest levels occur in the longitudinal direction. The transverse and normal directions are characterized by residual stress of lower magnitude. As expected, the residual stress is almost completely relieved after PWHT. T2 - AJP 2023 3rd International Conference on Advanced Joining Processes CY - Braga, Portugal DA - 19.10.2023 KW - Residual stress KW - Creep-resistant steel KW - Stress relief cracking KW - Neutron diffraction PY - 2023 AN - OPUS4-58646 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Large scale hydrogen assisted cracking test for thick walled SAW joints for offshore applications N2 - Offshore wind turbines continuously increase in size and weight and demand adequate offshore foundations concepts like monopiles, tripods or jackets. These components are typically submerged arc welded (SAW) high-strength thick steel plates like the S420ML. During welding, the occurrence of delayed hydrogen assisted cracking (HAC) must be anticipated. HAC is a critical combination of the local hydrogen concentration within a susceptible microstructure under certain mechanical load, i.e., the occurring (welding) residual stresses. The welding sequence of the thick-walled plates complicate the residual stress distribution due to the necessary repeated thermal cycling, i.e., welding seam / layer deposition to fill the joint. For that purpose, SAW with two-wire-technique was used to weld a specially designed and prototype-like mock-up of a real component with a thickness of 50 mm, filled with 22 passes and a seam length of 1,000 mm. Additional welded stiffeners simu-lated the effect of a high restraint, to stimulate critical HAC conditions. The necessity of a minimum waiting time (MWT) before the NDT can be conducted (to exclude HAC) was critically verified by the application of ultrasonic testing of the welded joint at different time-steps of the NDT of 48 h after welding. The residual stresses were determined by a robot XRD goniometer. Tensile residual stresses up to the yield limit are found both in the weld metal and in the heat-affected zone. Numerical modelling allowed the qualitative estimation of the hydrogen diffusion in the weld. A remarkable HAC occurrence was not identified and proves both, a certain resistance of the weld joint to HAC and the (questionable) duration of the MWT. T2 - IIW Annual Assembly, Meeting of Commission II-C CY - Singapore DA - 19.07.2023 KW - Mock-up KW - Hydrogen assisted cracking KW - Submerged arc welding KW - Offshore KW - Steel PY - 2023 AN - OPUS4-57977 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kromm, Arne T1 - Einfluss der Schweiß- und Prüfparameter bei der Heißrissbewertung hochfester Schweißzusatzwerkstoffe N2 - Die Heißrissneigung beim Schweißen kann mittels einer ganzen Reihe von Prüfverfahren ermittelt werden. Eine etablierte Methode ist die sogenannte Varestraint-Prüfung, welche auch an der Bundesanstalt für Materialforschung und -prüfung (BAM) als modifizierter Varestraint/Transvarestraint-Test (MVT) zum Einsatz kommt. Die Ergebnisse von Varestraint-Prüfungen hängen jedoch stets in unterschiedlichem Maße von der individuellen Prüfmaschinenauslegung und den verwendeten Prüfparametern ab. Dies kann zu einer uneinheitlichen Bewertung des Rissverhaltens führen, wenn die Risslänge konventionell als Kriterium für die Rissneigung herangezogen wird. Scheinbare Abhängigkeiten von Prozessparametern erschweren dann die Interpretation der Ergebnisse. Eine neuartige Bewertungsmethodik entkoppelt den Maschineneinfluss vom Materialverhalten und verwendet die Dehnrate als Risskriterium in Analogie zu Prokhorovs Heißrissmodell. Die neue Auswertung wird anhand einer Studie hochfester Schweißzusatzwerkstoffe vorgestellt, deren Rissverhalten in Abhängigkeit der chemischen Zusammensetzung und der Schweißparameter bewertet wird. T2 - 5. Symposium Materialtechnik CY - Clausthal-Zellerfeld, Germany DA - 23.02.2023 KW - Heißrisse KW - Varestraint-Test KW - Materialprüfung PY - 2023 AN - OPUS4-57070 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wandtke, Karsten A1 - Schröpfer, Dirk A1 - Scharf-Wildenhain, R. A1 - Hälsig, A. A1 - Kannengießer, Thomas A1 - Kromm, Arne A1 - Hensel, J. T1 - Influence of the WAAM process and design aspects on residual stresses in high-strength structural steels N2 - Wire arc additive manufacturing (WAAM) enables the efficient production of weight-optimized modern engineering structures. Further increases in efficiency can be achieved by using high-strength structural steels. Commercial welding consumables for WAAM are already available on the market. Lack of knowledge and guidelines regarding welding residual stress and component safety during production and operation leads to severely limited use for industry applications. The sensitive microstructure of high-strength steels carries a high risk of cold cracking; therefore, residual stresses play a crucial role. For this reason, the influences of the material, the WAAM process, and the design on the formation of residual stresses and the risk of cold cracking are being investigated. The material used has a yield strength of over 800 MPa. This strength is adjusted via solid solution strengthening and a martensitic phase transformation. The volume expansion associated with martensite formation has a significant influence on the residual stresses. The focus of the present investigation is on the additive welding parameters and component design on their influence on hardness and residual stresses, which are analyzed by means of X-ray diffraction (XRD). Reference specimens (hollow cuboids) are welded fully automated with a systematic variation of heat control and design. Welding parameters and AM geometry are correlated with the resulting microstructure, hardness, and residual stress state. Increased heat input leads to lower tensile residual stresses which causes unfavorable microstructure and mechanical properties. The component design affects heat dissipation conditions and the intensity of restraint during welding and has a significant influence on the residual stress. KW - DED-arc KW - Additive manufacturing KW - High-strength steel filler metal KW - Residual stress PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-572698 DO - https://doi.org/10.1007/s40194-023-01503-9 SN - 1878-6669 VL - 67 IS - 4 SP - 987 EP - 996 PB - Springer CY - Berlin AN - OPUS4-57269 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina A1 - Rhode, Michael A1 - Kannengießer, Thomas T1 - Einfluss unterschiedlicher Mikrolegierungsrouten eines S690QL auf das Ausscheidungsverhalten in der Wärmeeinflusszone N2 - Mikrolegierungselementen, wie Nb und Ti sind für eine signifikante Festigkeitssteigerung von vergüteten, hochfesten Feinkornbaustählen mit einer Nominalstreckgrenze ≥ 690 MPa unerlässlich. Normvorgaben zur chemischen Zusammensetzung dieser Stähle geben zur Erzielung der vorgeschriebenen Eigenschaften dabei oft nur Grenzgehalte für die Hersteller vor. Die Wirkung der Mikrolegierungselemente bzw. ihrer Karbide und/oder Nitride ist teilweise komplett konträr, insbesondere bei Auflösung und Wiederausscheidung in der WEZ bei identischem Schweißzusatz. Somit wird eine adäquate Vorhersage der Chargenabhängigkeit hinsichtlich der Schweißeignung und des Tragverhaltens der Schweißverbindung erschwert. Eine unerwünschte Eigenschaft ist dabei die Erweichung der WEZ, wie auch u.U. der gegenteilige Effekt der Aufhärtung. Vor diesem Hintergrund werden im Rahmen eines DFG-Vorhabens systematisch Mikrolegierungs-routen mit variierenden Ti- und Nb-Gehalten des hochfesten und vergüteten Feinkornbaustahls S690QL untersucht. Dazu wird das MAG-Schweißen mit modifizierten Sprühlichtbogen verwendet, welches durch hohe Abschmelzleistung gekennzeichnet ist und schmalere Nahtöffnungswinkel (α = 30°) ermöglicht. An Dreilagen-Schweißungen wird der Effekt der metallurgischen Zusammensetzung in Kombination mit hoher Wärmeeinwirkung auf die Ausbildung einer kritischen WEZ-Gefügezone mit Erweichung und/oder exzessiver Aufhärtung untersucht. Ein besonderes Augenmerk wird auf die Phasenumwandlungen und das Ausscheidungsverhalten im Gefüge der Wärmeeinflusszone gelegt. Neben umfangreichen metallographischen Untersuchungen einzelner WEZ-Bereiche wurden, unter Variation der chemischen Zusammensetzung, thermodynamische Phasenberechnungen mittels Thermo-Calc durchgeführt. Hierdurch wird ein Verständnis zur Phasentransformation und Ausscheidungswachstum und -auflösung während des Schweißens in Abhängigkeit von Temperatur und Abkühlbedingungen geschaffen. Das Ziel ist es, den Einfluss der Wärmeeinwirkung auf die Gefügeausbildung in der WEZ und dessen mechanischer Eigenschaften zu analysieren. Insbesondere wird hier auf die Auswirkung der unterschiedlichen Mikrolegierungskonzepte (Ti oder Nb) geachtet. T2 - 5. Symposium Materialtechnik CY - Clausthal-Zellerfeld, Germany DA - 23.02.2023 KW - WEZ Erweichung KW - Thermodynamische Simulation KW - Mikrolegierungseinfluss KW - Schweißen von hochfesten FKB PY - 2023 SN - 978-3-8440-9105-2 VL - 12 SP - 332 EP - 343 PB - Shaker Verlag AN - OPUS4-58006 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina T1 - Schweißen von hochfesten Feinkornbaustählen N2 - Das Schweißen von hochfesten Feinkornbaustählen erfordert aufgrund der Sicherstellung der Gütewerte des Grundwerkstoffes (Zähigkeit, Festigkeit) auch in der Schweißverbindung, die Einhaltung von engen Grenzen bei der Auswahl von Schweißparametern. Die Reproduzierbarkeit von beanspruchungsgerechten hochfesten Schweißverbindungen hängt vom Schweißverfahren und der damit einhergehenden komplexen Gefügeausbildung ab. Hierbei müssen hochfeste Schweißverbindungen mindestens die gleichen Festigkeitsanforderungen erfüllen wie der eingesetzte Grundwerkstoff. In diesem Vortrag werden speziell die Herausforderungen wie der Empfindlichkeit gegenüber der wasserstoffunterstützen Kaltrissbildung beim Schweißen von hochfesten Feinkornbaustählen und dem Mikrolegierungseinfluss auf die divergente Ausbildung der Wärmeeinflusszone thematisiert. T2 - Jahresmitgliederversammlung DVS BV Berlin CY - Berlin, Germany DA - 03.05.2023 KW - Herausforderungen beim Schweißen hochfester FKB KW - Wasserstoffunterstütze Kaltrissbildung KW - TEKKEN Test KW - Mikrolegierungseinfluss KW - Wärmeeinflusszone PY - 2023 AN - OPUS4-57995 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina T1 - Mikrolegierungseinfluss beim Schweißen hochfester Feinkornbaustähle N2 - Mikrolegierungselemente, wie Nb und Ti, sind für die signifikante Festigkeitssteigerung von vergüteten, hochfesten Feinkornbaustählen mit einer Nominalstreckgrenze ≥ 690 MPa unerlässlich. Normvorgaben zur chemischen Zusam-mensetzung geben dabei nur obere Grenzwerte für die Hersteller vor. Weiterhin wirken sich bereits kleine Abwei-chungen in der Legierungsroute teilweise drastisch auf die mechanischen Eigenschaften aus. Somit wird eine adä-quate Vorhersage der Schweißeignung und der Integrität der Schweißverbindung aufgrund der variierenden Mikro-gefüge erschwert bis unmöglich. Unerwünschte Nebeneffekte sind die mögliche Erweichung der Wärmeeinflusszone (WEZ) als auch der gegenteilige Effekt der Aufhärtung. T2 - DVS BV Potsdam, Mitglieder Weiterbildungsveranstaltung CY - Groß Kreutz (Havel), Germany DA - 31.05.2023 KW - WEZ Erweichung KW - WEZ Aufhärtung KW - Mikrolegierungseinfluss KW - Schweißen von hochfesten FKB PY - 2023 AN - OPUS4-57996 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Witte, Julien A1 - Hübler, Daniela A1 - Schröpfer, Dirk A1 - Börner, Andreas A1 - Kannengießer, Thomas ED - Hanke, S. T1 - Wear behavior of innovative niobium carbide cutting tools in ultrasonic-assisted finishing milling N2 - The resources of niobium exceed the ones of tungsten by an order of magnitude. With 92%, Brazil is today the main global producer of niobium. Hence, niobium carbides (NbC) are a sustainable and economic alternative to conventionally used cutting materials, especially tungsten carbides (WC). Moreover, NbC can be used in Ni alloy matrix and thus offer significant advantages by substituting WC in Co matrix as cutting materials in terms of health risks and raw material price and supply risk. Based on recent studies which found an increased performance of NbC compared to WC cutting tools in machining higher strength steels, the composition NbC12Ni4Mo4VC was chosen for finish machining of a high-strength steel S960QL in this study. The experiments were carried out on an ultrasonic-assisted 5-axis milling machine using NbC tools specially made to benchmark them with commercially available coated WC cutting inserts. In addition, the influence of a coating system for the NbC inserts is tested and evaluated for its performance in the cutting process. Tool wear and cutting force analyses are implied to identify optimal parameter combinations as well as tool properties for the novel NbC tool. Together with the oscillation of ultrasonic-assisted milling, the loads on the component surface and the tool can be reduced and the wear behavior of the novel NbC tool can be refined. These milling tests are accompanied by standardized wear tests, i.e., pin-on-disc, between the aforementioned material combinations, and the results are correlated with each other. Finally, the behavior when using hard-to-cut materials such as Ni alloys, or innovative materials such as iron aluminide is also being tested, as these are constantly in the focus of machining optimization. With this strategy, comprehensive knowledge is achievable for future efficient application of NbC for milling tools, which have already been researched for decades using WC. T2 - 24th International Conference on Wear of Materials CY - Banff, Canada DA - 16.04.2023 KW - Niobium carbide KW - Cutting tool KW - Ultrasonic-assisted milling KW - Tool wear PY - 2023 DO - https://doi.org/10.1016/j.wear.2023.204722 SN - 0043-1648 VL - 522 SP - 1 EP - 7 PB - Elsevier B.V. AN - OPUS4-57561 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina T1 - Influence of Microalloying on Precipitation Behavior and Notched Impact Strength of Welded High Strength Structural Steels N2 - Microalloying elements, such as Nb and Ti, are essential for significantly increasing the strength of quenched and tempered, high-strength structural steels with a nominal yield strength ≥ 690 MPa and their welded joints. The standard specifications (e.g., EN 10025-6) for the chemical composition are only tolerated limit contents within which the steel manufacturers operate. The standard composition, however, says nothing per se about the properties of the material. Even small deviations in the alloy route can have a drastic effect on the mechanical properties. This makes it difficult or even impossible to adequately predict the weldability and integrity of the welded joint. An undesirable side effect is the possible softening of the heat-affected zone (HAZ), as well as the opposite hardening.Mechanical-technological investigations of the notched impact strength confirm the results of the simulation regarding the development of different microalloy routes in the welded state. From this, the influence of the heat effect of welding on the microstructure formation in the HAZ and the corresponding mechanical properties can be described qualitatively. T2 - 76th IIW Annual Assembly and International Conference on Welding and Joining CY - Singapore DA - 16.07.2023 KW - High-strength structural steel KW - Notched impact strength KW - HAZ-softening KW - Microalloying influences PY - 2023 AN - OPUS4-57997 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina T1 - Mikrolegierungseinfluss auf das Ausscheidungsverhalten und die mechanischen Eigenschaften geschweißter hochfester Baustähle N2 - Mikrolegierungselemente, wie Nb und Ti, sind für die signifikante Festigkeitssteigerung von vergüteten, hochfesten Feinkornbaustählen mit einer Nominalstreckgrenze ≥ 690 MPa unerlässlich. Normvorgaben zur chemischen Zusammensetzung geben dabei nur obere Grenzwerte für die Hersteller vor. Weiterhin wirken sich bereits kleine Abweichungen in der Legierungsroute teilweise drastisch auf die mechanischen Eigenschaften aus. Somit wird eine adäquate Vorhersage der Schweißeignung und der Integrität der Schweißverbindung aufgrund der variierenden Mikrogefüge erschwert bis unmöglich. Unerwünschte Nebeneffekte sind die mögliche Erweichung der Wärmeeinflusszone (WEZ) als auch der gegenteilige Effekt der Aufhärtung. Vor diesem Hintergrund werden erstmals systematisch die unterschiedlichen Mikrolegierungsrouten mit variierenden Ti- und Nb-Gehalten an Versuchsschmelzen untersucht. Die Stahlgüte S690QL bildet dabei die Grundlage der chemischen Zusammensetzung sowie der entsprechenden Wärmebehandlung. Zur Untersuchung der jeweiligen Schweißeignung wurden Dreilagen-Schweißungen mittels moderner MAG-Hochleistungsschweißprozesse durchgeführt und kritische Gefügebereiche mit hoher Erweichung/Aufhärtung identifiziert. Mechanisch-technologische Untersuchungen zur Kerbschlagzähigkeit mittels Kerbschlagbiegeversuchen durchgeführt wurden, bestätigen dabei die Ergebnisse der thermodynamischen Simulation bezüglich des Ausscheidungsverhaltens während der Temperatur-Zeit Schweißzyklen. Daraus lässt sich der Einfluss der Wärmeeinwirkung beim Schweißen auf die Gefügeausbildung in der WEZ und der korrespondierenden mechanischen Eigenschaften qualitativ beschreiben. T2 - DVS CONGRESS 2023 CY - Essen, Germany DA - 11.09.2023 KW - WEZ-Erweichung KW - Digital Image Correlation KW - Mikrolegierungseinfluss KW - Hochfester Feinkornbaustahl KW - Kerbschlagzähigkeit PY - 2023 AN - OPUS4-58354 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina A1 - Kadoke, Daniel A1 - Kruse, Julius T1 - Investigation of the local strain behavior by digital image correlation and transverse tensile tests on welded differently microalloyed high strength structural steel N2 - Der Einsatz von hochfesten niedriglegierten Stählen (HSLA) ist in vielen Industriesektoren, wie dem allgemeinen Bauwesen, Offshore Strukturen, Mobilkranbau usw. unumgänglich geworden. Die steigende Nachfrage an Stählen mit einer hohen Festigkeit und gleichzeitig hervorragenden Zähigkeit stellt ein ökonomisches und ökologisches Potential dieser Stähle in Vordergrund. Aktuell gültige Normvorgaben (EN ISO 10025-6) geben den Stahlherstellern Vorgaben bezüglich der chemischen Zusammensetzung, um die geforderten mechanischen Eigenschaften erreichen zu können. Die Legierungsrouten variieren jedoch von Hersteller zu Hersteller. In Betracht der Schweißeignung dieser Stähle zeigt sich das Problem, dass diese bereits bei geringen Nb- und Ti-Mikrolegierungsunterschieden im Grundwerkstoff ein divergentes metallurgisches Verhalten in der Wärmeeinflusszone (WEZ) aufweisen. In diesem Vortrag werden die schweiß-metallurgischen Unterschiede zwischen verschieden mikrolegiertem hochfestem Feinkornbaustahl S690QL thematisiert. Zur Prüfung der Schweißnahtfestigkeit wurden mittels eines instrumentierten DIC (ARAMIS) Systems Querzugversuche an Schweiß-Querflachzugproben durchgeführt. T2 - AJP 2023 3rd International Conference on Advanced Joining Processes CY - Braga, Portugal DA - 19.10.2023 KW - WEZ-Erweichung KW - Hochfester Feinkornbaustahl KW - Digital Image Correlation KW - Querzugversuch KW - Mikrolegierungseinfluss PY - 2023 AN - OPUS4-58721 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Giese, Marcel T1 - Investigation of the influence of PWHT heating rate and global stress conditions on the stress relief cracking mechanism of CrMoV steel SAW joints N2 - This presentation summarizes the latest research results of the influence of the post weld heat treatment (PWHT) rate and the global mechanical stress conditions on the stress relief cracking (SRC) susceptibility of low-alloyed and creep-resistant CrMoV steel submerged arc weld joints. It was found that a certain effect of very low heating rates could be confirmed. In addition, the interlinking of SRC susceptibility increasing effects during the PWHT and the ex-post indentification in metallographic cross-section via microstructure characterization is very complex. T2 - IIW Intermediate meeting of Commission II-A CY - Garching, Germany DA - 06.03.2023 KW - Creep-resistant steel KW - Submerged arc welding KW - Stress relief cracking KW - Heating rate KW - Microstructure characterization PY - 2023 AN - OPUS4-57116 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Quercetti, Thomas T1 - Full-scale drop testing with a heavy-weight package for radioactive waste N2 - Packages for the transport of radioactive materials shall fulfil the requirements of the IAEA regulations for the safe transport. The requirements define mechanical and thermal test conditions including criteria ensuring the package design’s ability to withstand severe accidents and provide a high level of technical safety. Different methods can be used for safety demonstration showing compliance with the regulations. The central part of a safety demonstration which is presented in this paper was a comprehensive drop test program with a full-scale model of a transport package accompanied by pre- and post-test FE analyses. Using full-scale drop test models allow the benefit that similarity and scaling issues become a significant smaller issue, additional material investigations can be limited and analyses for transferring test results to the original package design are reduced. Additionally, experience for the future serial packaging manufacturing and handling procedures can be collected in a very early state of the design approval process. The pre-test finite element analyses derived and justified the drop test program consisting of several drop sequences with different drop orientations of the specimen. The performance and the results of the drop test sequences shows the manageability and the advantage e.g., in view of the direct availability of test results for the package licensing. On the other hand, the drop test performance shows the difficulties during handling and the need for additional equipment during preparation of the specimen. The package presented was intended for the transport and storage of compacted radioactive waste from reprocessing of spent nuclear fuel assemblies - designed and applied for approval by the AGC consortium. The project ended in 2021. The package design was characterized by a cask body made of a forged thick stainless-steel shell, a bolted double lid system with metallic gaskets and wood filled shock absorbers at both ends. The total mass of the entire transport package including content was 120,000 kg, the total length was about 7000 mm and the diameter approximately 3000 mm, both measures include the shock absorbers. The paper provides an insight into the performance of a full-scale drop testing campaign within the package safety evaluation and shows some selected test results. T2 - 20th International Symposium on the Packaging and Transportation of Radioactive Materials (PATRAM 22) CY - Juan-Les-Pins, France DA - 11.06.2023 KW - Full-scale KW - Drop testing KW - Package KW - Radioactive waste PY - 2023 AN - OPUS4-57731 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Component test for the assessment of hydrogen assisted cracking susceptibility of thick-walled submerged arc welded offshore steels N2 - Offshore wind turbines (OWT) are a key factor of the sustainable energy generation of tomorrow. The continuously increasing installation depths and weight of the OWTs require suitable foundation concepts like monopiles or tripods. Typically, mild steels like the S420ML are used with plate thicknesses up to several hundreds of mm causing high restraints in the weld joints. Due to the large plate thickness, submerged arc welding (SAW) with multiple wires is the state-of-the-art welding procedure. As a result of the very high stiffness of the construction, a certain susceptibility for time-delayed hydrogen-assisted cracking (HAC) may occur. The evaluation of crack susceptibility is very complex due to the component size and stiffness of real offshore structures. For this purpose, a near-component test geometry was developed to transfer the real stiffness conditions to laboratory (i.e., workshop) scale. The investigated mock-up, weighing 350 kg, comprised heavy plates (thickness 50 mm, seam length 1,000 m) joined by a 22-pass submerged arc weld. Additional stiffeners simulated the effect of high restraint or shrinkage restraint of the weld. Extreme scenarios of hydrogen absorption during welding were simulated via the use of welding fluxes in dry (HD < 5 ml/100g Fe) and moisture condition (HD > 15 ml/100g Fe). The residual stresses were determined by a robot X-ray diffractometer. Areas of critical tensile residual stress (at the level of the yield strength) were found in the weld metal and heat affected zone. To identify possible delayed cracking, the welds were tested by phased array ultrasonic testing (PAUT) after 48 h. Summarized, no significant occurrence of HAC was detected, indicating the high crack resistance of the welded joint, i.e., a suitable combination of base material, welding consumable and welding parameters. T2 - AJP 2023: 3rd International Conference on Advanced Joining Processes 2023 CY - Braga, Portugal DA - 19.10.2023 KW - Hydrogen assisted cracking KW - Submerged arc welding KW - Component test KW - NDT KW - Waiting time PY - 2023 AN - OPUS4-58672 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Popiela, Bartosz T1 - Influence of manufacturing process related residual stresses in wound composite material on the operational safety of H2 pressure vessels: PhD Topic Introduction N2 - Short introduction of the PhD Topic 5 in the BTU-BAM Graduate School "Trustworthy Hydrogen". Description of the objectives, deliverables and expected added value of the thesis. T2 - Introduction Week - BTU-BAM Graduate School "Trustworthy Hydrogen" CY - Berlin, Germany DA - 16.01.2023 KW - Residual stress KW - Composite KW - Pressure vessel KW - Hydrogen PY - 2023 AN - OPUS4-56882 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Chierici, Andrea A1 - Ciolini, Riccardo A1 - Lo Frano, Rosa A1 - D’Onofrio, Antonio A1 - Sabbarese, Carlo A1 - Pandalone, Antonio A1 - Romoli, Mauro A1 - di Meo, Paolo A1 - Finocchiaro, Paolo A1 - Conti, Enrico A1 - Gonella, Franco A1 - Andreetto, Paolo A1 - Checchia, Paolo A1 - Niederleithinger, Ernst A1 - d’Errico, Francesco T1 - Innovative Non-Destructive Techniques for Radioactive Waste Packages Monitoring N2 - A monitoring and surveillance system is a mandatory element to ensure that a radioactive waste disposal facility provides and meets the required level of safety during both its operational and closure periods. In this study an innovative approach for the identification and monitoring of the structural integrity of stored radioactive drums is presented. The activities were carried out in the context of the European Project PREDIS, whose goal is the development of a robust and reliable sensing technology for monitoring and long-term storage of radioactive waste packaging systems. Specifically, the focus was set on the development of innovative and smart sensor technologies, non-destructive examination tools, and/or devices capable to improve the safety of the storage by minimizing the number of interventions of cemented waste packages. Both conventional and innovative techniques, such as muon-tomography, SiLiF neutron and SciFi gamma detection, or contactless and smart radio transceiver technology provided with radiation monitoring sensors, have been considered and adapted for the use under repository conditions. Indeed, gamma and neutron detection techniques exploit the radiological information coming from inside the drums, while imaging techniques proved to be effective in spotting high density objects embedded inside the concrete: together, they allow to improve safety and security and can provide an early alert on behavioral changes hinting at anomalies in the drums. T2 - ASME 2023 International Conference on Environmental Remediation and Radioactive Waste Management CY - Stuttgart, Germany DA - 03.10.2023 KW - Radioactive waste KW - Waste packages KW - Radiation monitoring KW - Muon tomography KW - Integrity testing PY - 2023 SN - 978-0-7918-8753-0 DO - https://doi.org/10.1115/ICEM2023-110990 SP - 1 EP - 10 PB - American Society of Mechanical Engineers AN - OPUS4-60218 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mair, Georg W. A1 - Günzel, Stephan T1 - Der sichere Wasserstofftransport - Eine Rechtsänderung in der Vorschau N2 - Das Bundesverkehrsministerium hat seit 2008 in drei Stufen jeweils auf Vorschlag der BAM einen Antrag zur Einführung bzw. Regulierung von Bergungsdruckgefäßen bei den Vereinten Nationen eingebracht. Die Anträge führten jeweils nach der Delegation in eine Arbeitsgruppe unter der Leitung des Vortragenden zu neuen Vorschriften im internationalen Gefahrguttransportrecht. Zuletzt hat das UN-Subcommittee der Experten für den Transport gefährlicher Güter der Einführung einer Druck-Volumen-Begrenzung für Druckgefäße zugestimmt. Mit dieser Begrenzung wurde die bisherige Volumenbegrenzung für Bergungsdruckgefäße ersetzt, wodurch nun das Spektrum der Bergungsdruckgefäße gestaltet werden kann, das notwendig wäre, um defekte Druckgefäße transportieren zu können. Das zentrale Kriterium für die Begrenzung des Druck-Volumen-Produktes (pV) fand bereits in den Landverkehrsvorschriften ADR/RID bis zu ihrer Neustrukturierung auch als Konsequenzmaß Verwendung. Damit soll sichergestellt werden, dass sich aus Wasserstofftransporten in Druckgefäßen keine Konsequenz entwickeln kann, die nach den Kriterien für stationäre Anlagen, einer Katastrophe gleichkommen würde. Hierzu hatte eine Arbeitsgruppe der Vereinten Nationen seit 2020 auf Vorschlag der BAM eine Kette aufeinander aufbauende Kriterien diskutiert, die im Vortrag vorgestellt werden: Einfluss der Druckwellen auf den menschlichen Körper (ohne Splitterwirkung oder Umsetzung der chemischen Energie) – Zusammenhang von Druckwelle und Fläche – Druckwellenberechnung – Bevölkerungsdichte – Grenzwerte für eine Katastrophe – resultierendes pV-Produkt. Das Ergebnis wurde mit herausragenden Großunfällen und Katastrophen aus dem Gefahrguttransport und Gefahrstoffbereich verglichen. Außerdem wurden noch die Effekte des Temperatureinflusses auf den maximalen Betriebsdruck diskutiert. Zuletzt wurde bei den UN darauf hingewiesen, dass mit Blick auf die Auswirkungsbetrachtung der Wassersoff das Gas mit den geringsten Konsequenzen bei gegeben Druk-Volumen-Produkt ist, was zu restriktiveren Obergrenzen für z.B. Erdgas führen könnte. Als letzter Punkt im Vortrag wird erläutert, dass in den kommenden UN-Sitzungen über nachfolgende Änderungen im Recht, wie z.B. der Kennzeichnung des pV-Produktes, diskutiert werden wird. Außerdem muss ein neuer Einstieg für die bei ISO in der Normung befindliche Umschließungen mit einem größeren pV-Produkt gefunden werden, wozu aber Transportland-spezifische Risikoanalysen in Verbindung mit massiven Fahrwegsbeschränkungen zu erwarten sind. T2 - 32. Erfahrungsaustausch für Gefahrgutbeauftragte (ERFA-T) des IGV CY - Berlin, Germany DA - 08.11.2023 KW - pV-Produkt KW - Quantitative Risikoanalyse KW - Konsequenzbegrenzung KW - Katastrophe KW - Druckgefäße PY - 2023 AN - OPUS4-58832 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maiwald, Michael T1 - Metrology for Advanced Hydrogen Storage Solutions (MefHySto) – Overviewand Tangible Results N2 - The European project MefHySto addresses the need of large-scale energy storage, which is required for a shift to renewable energy supply. The project is funded by the European Metrology Programme on Innovation and Research (EMPIR) and consists of 14 consortium partners from all over Europe (www.mefhysto.eu). It is demonstrated, how MefHySto is contributing to the EMN for Energy Gases aiming at prioritisation of the measurement gaps and challenges interacting with the EMN stakeholders. T2 - European Metrology Network Energy Gases “Measurement Solutions for Energy Gases” Workshop CY - Lisbon, Portugal DA - 21.03.2023 KW - MefHySto KW - EMPIR KW - Hydrogen Storage KW - Hydrogen Metrology KW - Hydrogen Purity KW - Geological Storage PY - 2023 AN - OPUS4-57193 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kipphardt, Heinrich T1 - Introduction to Metrology in Chemistry N2 - Measurements are an important fundament of natural science in general and of chemical analysis in particular. Metrology is the science (and art) of performing measurements. The basic concepts and terms of metrology and their practical implementation are introduced. The very special peculiarities of chemical measurements that are absent in physical measurements are discussed. T2 - 7th PhD Seminar of the German Working Group for Analytical Spectroscopy (DAAS) in the GDCh Division of Analytical Chemistry CY - Berlin, Germany DA - 15.11.2023 KW - Metrology KW - Chemical Analysis PY - 2023 AN - OPUS4-58868 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Winckelmann, Alexander T1 - How does solid microanalysis profit from innovations in EUV research N2 - Research into new sources for EUV lithography is driving advancements in experimental methods tailored for this short wavelength range. This progress enables the exploration of spectroscopic techniques aimed at monitoring electronic transitions within this energy spectrum. Laser-induced breakdown spectroscopy (LIBS) serves as a rapid tool for elemental analysis, primarily established in the UV-vis range. However, LIBS encounters challenges such as limited repeatability precision and elevated background noise resulting from continuum radiation. In parallel, laser-induced extreme UV spectroscopy (LIXS) delves into the initial stages of plasma evolution, characterized by the emergence of soft X-ray and extreme UV radiation. The method benefits from a fast timeframe and constrained plasma confinement, leading to better precision. Nevertheless, LIXS encounters convoluted spectra arising from unresolved transition arrays (UTA), particularly pronounced for heavier elements. This complexity renders conventional univariate data analysis impractical, demanding the adoption of a multivariate data analysis approach. Multiple cathode samples, each coated with varying stoichiometries of lithium nickel manganese cobalt oxide (NMC), were prepared and used for calibration purposes. Through the application of Partial Least Squares (PLS) regression, a robust correlation with an R2 value exceeding 0.97 was achieved. The LIXS technique underwent a comparative evaluation against UV-vis LIBS. Furthermore, a comparison between univariate and multivariate analysis approaches was conducted, incorporating validation through y-randomization to mitigate overfitting risks. The viability of this approach was confirmed through the testing of an NMC reference material. The results showed metrological compatibility with reference values, underscoring the potential capability of the proposed methodology. T2 - 322. PTB Seminar 2023 - VUV and EUV Metrology CY - Berlin, Germany DA - 14.11.2023 KW - Laser induced XUV spectroscopy KW - Lithium-ion batteries KW - Solid microanalysis PY - 2023 UR - https://www.euv2023.ptb.de/ AN - OPUS4-58834 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kipphardt, Heinrich T1 - MefHySto - Metrology for Advanced Hydrogen Storage Solutions N2 - An overview on the almost completed EMPIR-MefHySto-Project is given. T2 - Workshop on Green Hydrogen CY - Montevideo, Uruguay DA - 12.10.2023 KW - MefHySto KW - Hydrogen storage KW - Metrology PY - 2023 AN - OPUS4-58650 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ziel, Ruben P. A1 - Zalewska, Ewelina A1 - van der Veen, Adriaan M. H. A1 - Kipphardt, Heinrich A1 - Tuma, Dirk A1 - Esteban, Andres Rojo A1 - Fernandez Vicente, Teresa Esperanza A1 - Mace, Tatiana A1 - Sutour, Christophe A1 - Marioni, Fabrice A1 - Fükö, Judit A1 - Szücs, László A1 - Büki, Tamás A1 - Szilágyi Nagyné, Zsófia A1 - Cieciora, Dariusz A1 - Ochman, Grzegorz A1 - Romanowski, Przemysław A1 - Lis, Anna A1 - Garnuszek, Magdalena A1 - Valkova, Miroslava A1 - Ackermann, Andreas A1 - Pascale, Celine A1 - Niederhauser, Bernhard A1 - Tarhan, Tanil A1 - Boztepe, Aylin A1 - Beránek, Jan A1 - Bárta, Miroslav T1 - International comparison EURAMET.QM-K3.2019 - Automotive exhaust gases N2 - EURAMET.QM-K3.2019 was a repeat of the key comparison EURAMET.QM-K3 on the composition of automotive exhaust gases. New in EURAMET.QM-K3.2019 was the addition of the amount fraction oxygen to the programme. The key comparison reference values were obtained independently, using static gravimetry and appropriate corrections from purity analysis and are linked to those of CCQM-K3.2019. The key comparison results show equivalence between the measurement standards maintained by the participating national metrology institutes. The demonstrated equivalence can be used to underpin services related to automotive exhaust gases as well as generically through the flexible scheme ("track A"). KW - CCQM KW - Automotive gases PY - 2023 DO - https://doi.org/10.1088/0026-1394/60/1A/08030 SN - 1681-7575 VL - 60 IS - 1A SP - 1 EP - 63 PB - IOP Publishing CY - Bristol AN - OPUS4-58904 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lozano-Martín, D. A1 - Tuma, Dirk A1 - Kipphardt, Heinrich A1 - Khanipour, Peyman A1 - Chamorro, C. R. T1 - Thermodynamic characterization of the (H2 + C3H8) system significant for the hydrogen economy: Experimental (p, rho, T) determination and equation-of-state modelling N2 - For the gradual introduction of hydrogen in the energy market, the study of the properties of mixtures of hydrogen with typical components of natural gas (NG) and liquefied petroleum gas (LPG) is of great importance. This work aims to provide accurate experimental (p, rho, T) data for three hydrogen-propane mixtures with nominal compositions (amount of substance, mol/mol) of (0.95 H2 + 0.05 C3H8), (0.90 H2 + 0.10 C3H8), and (0.83 H2 + 0.17 C3H8), at temperatures of 250, 275, 300, 325, 350, and 375 K, and pressures up to 20 MPa. A single-sinker densimeter was used to determine the density of the mixtures. Experimental density data were compared to the densities calculated from two reference equations of state: the GERG-2008 and the AGA8-DC92. Relative deviations from the GERG-2008 EoS are systematically larger than those from the AGA8-DC92. They are within the ±0.5% band for the mixture with 5% of propane, but deviations are higher than 0.5% for the mixtures with 10% and 17% of propane, especially at low temperatures and high pressures. Finally, the sets of new experimental data have been processed by the application of two different statistical equations of state: the virial equation of state, through the second and third virial coefficients, B(T, x) and C(T, x), and the PC-SAFT equation of state. KW - Hydrogen-containing gas mixture KW - Density data KW - Equation of state KW - Virial coefficients PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-570056 DO - https://doi.org/10.1016/j.ijhydene.2022.11.170 SN - 0360-3199 VL - 48 IS - 23 SP - 8645 EP - 8667 PB - Elsevier B. V. CY - Amsterdam AN - OPUS4-57005 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eiben, Mario T1 - Die Aufgaben der BAM als zuständige Behörde im Gefahrgutbereich in Deutschland N2 - Die BAM ist zuständige Behörde in Deutschland für bestimmte Aufgaben im Gefahrgutbereich, die u. a. in § 8 der Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt (GGVSEB) und § 12 der Gefahrgutverordnung See (GGVSee) aufgeführt sind und hauptsächlich von den Abteilungen 2 und 3 wahrgenommen werden. So ist die BAM bspw. die in Deutschland für die Zulassung von Verpackungen und Tanks oder auch die Einstufung bestimmter gefährlicher Güter zuständige Stelle. Die BAM arbeitet des Weiteren als Kompetenzbehörde national und international in den entsprechenden Gremien mit und berät das BMDV in der Rechtsfortentwicklung der internationalen Vorschriften für den Gefahrguttransport. Dies geschieht u. a. durch die Mitarbeit im Ständigen Ausschuss Gefahrgutbeförderung (AGGB) des Gefahrgut-Verkehrs-Beirats beim BMDV und den zugehörigen Arbeitsgruppen, oder auch das Erstellen von Anträgen für Rechtsänderungen in den internationalen Vorschriften der Vereinten Nationen (UN) bzw. der Wirtschaftskommission für Europa der UN (UNECE) im Auftrag des BMDV. Die Beratung der betroffenen Wirtschaft und die Normungsarbeit sind weitere wichtige Themen. Die Expertise der BAM wird insbesondere durch Forschung im Gefahrgutbereich erhalten und weiter ausgebaut. Im Rahmen des Vortrags werden drei Forschungsbereiche vorgestellt, von denen zwei für die Energiewende von großer Bedeutung sind. T2 - 10. Deutsche Gefahrgut-Sicherheitstage CY - Nürburg, Germany DA - 13.09.2023 KW - Gefahrgut KW - Zuständige Behörde KW - Transport gefährlicher Güter KW - Gremienarbeit KW - Normung KW - Forschung KW - Gesetzliche Aufgaben PY - 2023 AN - OPUS4-58350 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mair, Georg W. T1 - Entwicklungen rings um Gase als Energieträger N2 - Dr. Mair erläutert, welcher Anwuchs an H2-Bedarf zu erwarten ist, wo er weltweit erzeugt werden könnte und in welcher Form auf grünem Wasserstoff basierende Energieträger transportiert werden können. Es wird deutlich, dass das Transportaufkommen von H2 erheblich anwachsen wird und dass sich alle Seiten, die Regelsetzer und die Industrie darauf vorbereiten müssen. Danach wird mit Blick auf die Normungsroadmap H2 des DIN der probabilistische Ansatz mit seinem Potenzial, Normen und Vorschriften in ihrer Wirkung zu simulieren und zu bewerten kurz vorgestellt. Der dritte Block des Vortrages beginnt mit der Definition von Sicherheit, zeigt kurz das mikromechanische Prinzip der Alterung von Composite und greift dann ein Thema auf, dass Dr. Mair bereits 2018 und 2019 in dieser Runde dargelegt hat: Der Aufwand für die klassische Wiederkehrende Prüfung ist enorm und bringt nur wenig Erkenntnis. Es werden graphisch das 5-Jahres 100%-Prooftesting, der Ansatz nach GGR 022 mit seiner zerstörend geprüften Stichprobe und der mögliche Ansatz für eine ergebnisgesteuerte Stichprobenprüfung auf ZfP-Basis miteinander verglichen. Die Unterschiede im Aufwand-zu-Nutzen-Verhältnis sind enorm. Dabei ist der aufwändigste Ansatz zudem der mit der geringsten Erkenntnistiefe. Jeder Ansatz, der von einer 100%-Prüfung in einem maximalen Zeitrahmen von 10 Jahren abweicht, also z.B. der Verzicht auf eine 100%-Prüfung während des Betriebes, würde eine Änderung des Regelwerkes erfordern, die zeitnah angestoßen werden müsste. Da es sich hierbei primär um eine Ressourcenoptimierung und nicht um eine Verbesserung der Sicherheit handelt, liegt der Ball bei den Verbänden. Als eine Idee für das Herangehen mit einer Begrenzung auf Druckgefäße, die nach der EN 17339 zulassungsfähig sind (fest montiert, H2 und nur CFK), verweist Dr. Mair auf die SV 674 in Verbindung mit 6.2.3.5.3/.4 ADR/RID. Bei dem absehbaren Anwachsen des Bestandes an H2-Batteriefahrzeugen, ist hier nicht nur ein Optimierungsaspekt, sondern auch ein Kapazitätsproblem in der wiederkehrenden Prüfung zu lösen. Es würde aber auch ein Mehrwert für die Sicherheit entstehen. T2 - 30. BAM-DIN-IGV-DVFG Treffen CY - Berlin, Germany DA - 22.02.2023 KW - Wasserstoffspeicher KW - Markthochlauf KW - Sicherheit KW - Wiederkehrende Prüfung KW - Schallemissionsanalyse PY - 2023 AN - OPUS4-57041 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mair, Georg W. A1 - Duffner, Eric A1 - Günzel, Stephan T1 - Die Zukunft der Betriebsüberwachung von Gasspeichern aus Composite N2 - Im Vortrag wird zunächst erläutert, dass auch im Fall der Wasserstoffversorgung die Schadensanalyse, -vermeidung und die wiederkehrende Prüfung von Speichern in engem Zusammenhang stehen. Der Wasserstofftransport in Deutschland hat bereits deutlich zugenommen und wird in den nächsten Jahren weiter erheblich zunehmen. Dies führt zu einem stärkeren Fokus auf die wirtschaftlichen Aspekte im Transport und der wiederkehrenden Prüfung. Letztere droht, ohne neue technische Ansätze zum Flaschenhals in der Verfügbarkeit vorhandener Transportkapazitäten zu werden. Das gegenwärtige System der Wasserdruckprüfung bis zum sog. Prüfdruck mit Innen- und Außenbesichtigung etc., die im Normalfall alle 5 Jahre durchzuführen ist, führt zu jeweils etwa 8 Wochen Stillstand. Das Aufwendige dabei sind die Trocknungs- und Spülprozesse, die notwendig sind, um wieder entsprechend reinen Wasserstoff abfüllen zu können. Auf Basis der BAM GGR‘n 021 und 022 lässt sich beim Nachweis entsprechender, probabilistischer Restzuverlässigkeiten diese Frist in Deutschland auf 10 Jahre ausdehnen. Diesen Weg sind in den letzten Jahren viele Betreiber gegangen. Mit Blick auf die derzeit fast exponentielle Zunahme von Transporteinheiten kann auch diese Verlängerung der Prüffristen das Problem nicht lösen. Auch das Umschwenken von hydraulischer, auf die heute bereits genehmigungsfähige Gasdruckprüfung bis zum Prüfdruck bringt zwar eine Verkürzung der Stillstandzeiten, erfordert aber erhebliches Investment in Schutzmaßnahmen. Als hinreichend zielführendes Konzept für Transporteinheiten mit vielen Elementen wird im Vortrag eine Mischung aus probabilistischem Ansatz und zerstörungsfreien Prüfungen erläutert und bzgl. Aufwand und Nutzen im Vergleich zu den üblichen Verfahren visualisiert. Voraussetzung für diesen vorgestellten Ansatz sind die Weiterentwicklung und Qualifizierung der Schallemissionsanalyse als Ersatz für die derzeitig zerstörenden Prüfungen und auch eine durchgängig digitale Lebenslaufakte, die eine lückenlose Zuordnung von Baumusterprüfung, Herstellungslos, Betreiber und Betriebsdaten erlaubt. Für Transporteinheiten mit wenigen, sehr großen Elementen wird dagegen das sog. Online-Monitoring mit fest installierter und permanent messender Technik gesehen. Für die Anwendung beider Lösungsansätze sind umfangreiche Änderungen im Recht erforderlich. T2 - 49. VDI-Jahrestagung Schadensanalyse 2023: Schadensprävention bei Druckwasserstoff und Schadensprävention für Kunststoff- und Elastomerprodukte CY - Würzburg, Germany DA - 18.10.2023 KW - ATR Anerkanntes Technisches Regelwerk KW - Probabilistik KW - Zerstörungsfreie Prüfung KW - Online-Monitoring KW - Schallemissionsanalyse KW - Gasdruckprüfung PY - 2023 AN - OPUS4-58838 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Günzel, Stephan T1 - Safety assessment of hydrogen gas storage systems N2 - In this lecture, the safety assessment of hydrogen gas storage systems is presented using the example of composite pressure vessels. The main element is a probabilistic approval approach based on five steps. Firstly, the testing and evaluation of properties at the beginning of life are shown. Secondly, methods for artificial aging and the effect on the residual strength are presented. Thirdly, testing against dedicated accidents is introduced. Fourthly, effects on the surveillance of production quality are discussed. Finally, degradation and the end of life are estimated. Background information and examples are given for each step. The assessment presented is a method applicable for many safety-related systems. T2 - Masterstudiengang Wasserstofftechnologie - Modul 8: Safety and Public Acceptance – Sicherheitsaspekte, Akzeptanz und werkstofftechnische Herausforderungen des Wasserstoffs CY - Online meeting DA - 25.08.2023 KW - Safety KW - Hydrogen KW - Wasserstoff KW - Bewertung KW - Assessment PY - 2023 AN - OPUS4-59899 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Günzel, Stephan T1 - Safety assessment of hydrogen gas storage systems N2 - In this lecture, the safety assessment of hydrogen gas storage systems is presented using the example of composite pressure vessels. The main element is a probabilistic approval approach based on five steps. Firstly, the testing and evaluation of properties at the beginning of life are shown. Secondly, methods for artificial aging and the effect on the residual strength are presented. Thirdly, testing against dedicated accidents is introduced. Fourthly, effects on the surveillance of production quality are discussed. Finally, degradation and the end of life are estimated. Background information and examples are given for each step. The assessment presented is a method applicable for many safety-related systems. T2 - Joint European Summer School 2023, Hydrogen Safety CY - Online meeting DA - 17.09.2023 KW - Safety KW - Hydrogen KW - Wasserstoff KW - Bewertung KW - Assessment PY - 2023 AN - OPUS4-59903 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Balderas-Xicohtencatl, R. A1 - Villajos Collado, José Antonio A1 - Casabán, J. A1 - Wong, D. A1 - Maiwald, Michael A1 - Hirscher, M. T1 - ZIF‑8 Pellets as a Robust Material for Hydrogen Cryo-Adsorption Tanks N2 - Cryoadsorption on the inner surface of porous materials is a promising solution for safe, fast, and reversible hydrogen storage. Within the class of highly porous metal−organic frameworks, zeolitic imidazolate frameworks (ZIFs) show high thermal, chemical, and mechanical stability. In this study, we selected ZIF-8 synthesized mechanochemically by twin-screw extrusion as powder and pellets. The hydrogen storage capacity at 77 K and up to 100 bar has been analyzed in two laboratories applying three different measurement setups showing a high reproducibility. Pelletizing ZIF-8 increases the packing density close to the corresponding value for a single crystal without loss of porosity, resulting in an improved volumetric hydrogen storage capacity close to the upper limit for a single crystal. The high volumetric uptake combined with a low and constant heat of adsorption provides ca. 31 g of usable hydrogen per liter of pellet assuming a temperature−pressure swing adsorption process between 77 K − 100 bar and 117 K − 5 bar. Cycling experiments do not indicate any degradation in storage capacity. The excellent stability during preparation, handling, and operation of ZIF-8 pellets demonstrates its potential as a robust adsorbent material for technical application in pilot- and full-scale adsorption vessel prototypes. KW - Hydrogen adsorption storage KW - Metal−organic frameworks KW - ZIF-8 KW - Cryoadsorption KW - Hydrogen Storage KW - MefHySto PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-569473 DO - https://doi.org/10.1021/acsaem.2c03719 SN - 2574-0962 SP - 1 EP - 8 PB - ACS Publications CY - Washington DC AN - OPUS4-56947 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT ED - Tuma, Dirk ED - Weide, T. ED - Rasmusson, H. T1 - MefHySto - Metrology for advanced hydrogen storage solutions N2 - The “Metrology for Advanced Hydrogen Storage Solutions” (MefHySto) project is a European initiative addressing the need for large-scale energy storage solutions, that is crucial for the successful transition to renewable energy sources. The main objective of this project was to develop and provide metrological standards and validated techniques for the storage and utilization of hydrogen. Hydrogen is increasingly recognized as an important component in the future energy system due to its ability to store and supply energy during peak demand periods when renewable sources, such as solar and wind, are not generating power. KW - Water electrolysis KW - Thermophysical properties KW - Fuel cell KW - Hydrogen storage PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-625952 DO - https://doi.org/10.5281/zenodo.12684898 SP - 1 EP - 40 PB - ERIG European Research Institute for Gas and Energy Innovation a.i.s.b.l. CY - Bruxelles AN - OPUS4-62595 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lay, Vera T1 - Material research and multi-sensory monitoring for concrete sealing structure in rock salt underground repositories N2 - Within the project SealWasteSafe, we advance construction materials and non-destructive monitoring concepts of sealing structures applied for underground disposal of nuclear waste. As these engineered barriers have high demands regarding structural integrity, an innovative alkali-activated material (AAM) that is highly suitable for the application in salt as a host rock is improved and tested on two laboratory scales. This AAM has a low heat evolution due to the reaction mechanism in comparison to common salt concretes based on Portland cement or magnesium oxychloride binders. Hence, crack formation due to thermally induced stress during the hardening process is reduced. After successful laboratory tests with small specimens (height ~5 cm), comparably manufactured large cubic (edge length 70 cm) and cylindrical specimens (height 120 cm, diameter 40 cm) are equipped with sensing technologies to demonstrate the sensors´ technical capabilities. A comprehensive multi-sensory monitoring scheme is developed and investigated to characterize and compare the different material behaviour during the setting and hardening process of two materials: (1) the newly developed AAM-based mortars with salt aggregate, and (2) a blended Portland cement-based salt concrete as reference. The analysed parameters include temperature and humidity of the material, acoustic emissions, and strain variations recorded by fiber optic cables. Passive sensor systems based on radiofrequency identification technology (RFID) embedded in the concrete provide an interface for the wireless readout of various sensors. In parallel to the embedded RFID sensors, conventional cabled systems to read out the temperature and humidity measurements are installed for comparison. Additionally, a detailed inspection of the two large cubic specimens after a monitoring period of more than six months has been undertaken. Active thermography and ultrasonic echo measurements are used to reveal potentially occurring inner cracks from the surface. To verify the non-invasive results, a core sample (diameter 2 cm) was extracted from each of the investigated cubic specimens and analysed in detail with X-ray computed tomography. Furthermore, ultrasonic methods are used for quality assurance to detect obstacles, cracks, and delamination at in-situ scale sealing structures. Experimental layout and applied imaging techniques are optimised to enhance the image quality for measurements from the front side of the engineered barrier. To characterize the inside of the test sealing structure and to improve the detection of potentially existing cracks, an ultrasonic borehole probe using the phased array technique is developed. First analyses at a half-spherical specimen coincide with modelling results and prove the reliability of the directional response caused by the phased array technique of the newly constructed ultrasonic borehole probe. Overall, the project SealWasteSafe helps to characterize construction materials and improves multi-sensory monitoring concepts and ultrasonic equipment for the sake of quality assurance. Particularly for salt as a host rock, this will help to design safe sealing structures for nuclear waste disposal. T2 - EGU General Assembly 2023 CY - Vienna, Austria DA - 23.04.2023 KW - SealWasteSafe KW - Engineered barriers KW - Salt concrete KW - Quality assurance KW - Ultrasound KW - CT KW - Thermography PY - 2023 DO - https://doi.org/10.5194/egusphere-egu23-11582 AN - OPUS4-57500 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lay, Vera T1 - Untersuchung eines Spritzbeton-Probekörpers unter Tage mit Ultraschall N2 - Für die sichere Endlagerung nuklearer Abfälle sind im Salzgestein Verschlussbauwerke aus Salzbeton als geotechnischen Barrieren vorgesehen. Um die Integrität der Bauwerke im Rahmen einer Qualitätssicherung nachzuweisen, eignet sich eine zerstörungsfreie Prüfung (ZfP) mit Ultraschall-Verfahren. Potenziell auftretende Risse oder Ablösungen sowie Einbauteile können detektiert werden. Um die Möglichkeiten und Grenzen der Ultraschall-Echo-Messungen sowie der Auswertemethoden zu untersuchen, wurden in einem aus Spritzbeton hergestellten Testbauwerk in der Grube Teutschenthal (bei Halle, Deutschland) verschiedene Störkörper während der Betonage eingebettet. Die Störkörper (Breite 3 cm bis ~8 cm) liegen in Tiefen von etwa 30 cm bis 80 cm und repräsentieren Hohlräume, Risse oder Inhomogenitäten des Betons. Von der Oberfläche führten wir Ultraschall-Echo-Messungen auf einer Fläche von etwa 100x150 cm² in einem 3D Modus durch. Die Auswertung erfolgte zunächst mithilfe der in der ZfP etablierten Synthetic-Aperture-Focusing Technique (SAFT), die der Kirchhoff Migration ähnelt. Insgesamt wird eine Vielzahl von Reflektoren im Bauwerk abgebildet, die jedoch nur in wenigen Fällen den eingebauten Störkörpern zugeordnet werden konnten, so dass auch die Grenzen des Verfahrens bei dieser Bauweise deutlich werden. Allerdings konnte eine ungeplante großflächige (>30 cm) Ablösung nachgewiesen und durch anschließende Bohrungen verifiziert werden. Um das strukturelle Abbild des Bauwerksinneren trotz des stark streuenden Spritzbetons zu verbessern, wenden wir fokussierende Migrationsverfahren an. Erste Ergebnisse zeigen, dass eine klarere Abbildung einzelner Reflektoren erreicht werden kann. Dies erleichtert die Detektion einzelner Objekte. Das hier präsentierte Experiment mit bekannten Reflektoren unter realen Bedingungen mit Spritzbeton unter Tage bietet hervorragende Möglichkeiten zur Überprüfung von methodischen Weiterentwicklungen im Bereich der Ultraschallanalyse. Durch die Verbesserung der Auswertemethodik und der darauf basierenden ultraschallbasierten Qualitätssicherungskonzepte werden insgesamt sicherere Verschlussbauwerke für nukleare Endlager ermöglicht. T2 - 83. Jahrestagung der Deutschen Geophysikalischen Gesellschaft (DGG) CY - Bremen, Germany DA - 06.03.2023 KW - Ultraschall KW - Spritzbeton KW - Qualitätssicherung KW - Abbildungsverfahren PY - 2023 AN - OPUS4-57136 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lay, Vera T1 - Multi-sensory monitoring and ultrasound for quality assurance at underground sealing structures N2 - Within the safety concepts of underground disposal sites of nuclear waste, engineered barriers play an important role. As these sealing structures have high demands concerning integrity, we aim at advancing the available construction materials, monitoring and inspection techniques within the project SealWasteSafe. After successful laboratory analysis on the cm-scale, cylindrical and cuboid specimens on the m-scale are produced from classical salt concrete and a specifically developed alkali-activated material. A comprehensive multi-sensory monitoring scheme is applied to compare the setting process of both materials and to demonstrate the sensors’ resistance to highly alkaline environments. Besides temperature and humidity of the materials, strain variations using fibre optic sensors and acoustic emissions are recorded over periods of at least 28 days, partly for more than 8 months. Passive sensor systems based on radiofrequency identification technology (RFID) embedded in the concrete allow for wireless access to temperature and humidity measurements and are compared to conventional cabled systems. After hardening and removal of the outer casings of the specimens, further non-destructive evaluations using ultrasonic echo and thermographic measurements are conducted. Preliminary results clearly highlight differences between the tested materials, particularly showing lower acoustic emission activity for the newly developed alkali-activated material potentially indicating less phase changes or cracks. Complementary, ultrasonic methods are improved to be used for quality assurance to detect obstacles, potential cracks and delamination at in-situ sealing structure scale. A unique large aperture ultrasonic system (LAUS) with depth penetration as large as 9 m has already successfully been applied at the test site in Morsleben, Germany, of the federal company for radioactive waste disposal (BGE). Modelling studies help to further optimize the measurement layout. Advanced imaging techniques applied to the modelled and measured data will further improve the obtained images of internal structures. Additionally, an ultrasonic borehole probe is developed and constructed using phased arrays to further enhance the detection of potential cracks. Modelling and preliminary results from laboratory specimens prove the feasibility and potential of the directional response even in heterogeneous material such as concrete. Final investigations under in-situ conditions at the test site of the sealing structure are planned. Overall, the project SealWasteSafe improves the construction material, multi-sensory monitoring, and ultrasound for quality assurance to allow for the development of safe nuclear sealing structures. Although the techniques are tailored for sealing structures within salt as a host rock, they are transferrable to a wider field of applications and alternative disposal conditions. T2 - NDE NucCon CY - Espoo, Finland DA - 25.01.2023 KW - SealWasteSafe KW - Engineered barriers KW - Monitoring KW - Embedded sensors KW - Ultrasonic imaging PY - 2023 AN - OPUS4-56927 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst T1 - Nuclear concrete, and how to live with it more easy using NDE N2 - This keynote presentation compiles the specialities of civil engineering compared to other disciplines, of NDT in civil engineering compared to other filds of NDT and the specific challenges of applications in the nuclear energy and disposal sector. T2 - NucCon 2023 CY - Espoo, Finland DA - 25.01.2023 KW - NDT KW - Concrete KW - Nuclear PY - 2023 AN - OPUS4-56912 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Fügetechnik in Wasserstofftechnologien: Erzeugung, Transport, Speicherung, Nutzung N2 - Der Vortrag gibt einen kurzen Überblick über die Bedeutung der Fügetechnik in Wasserstofftechnologien und über zukünftige FuE-Bereiche. Fügetechnologien haben dabei wesentliche Bedeutung für die Umsetzung von technischen Komponenten der Wasserstofftechnologien. Forschungsschwerpunkte ergeben sich insbesondere für die Erzeugung und den Transport des Wasserstoffs. T2 - Vortragsreihe des DVS Bezirksverbandes Berlin CY - Berlin, Germany DA - 22.02.2023 KW - Wasserstoff KW - Fügetechnik KW - Forschung KW - Review PY - 2023 AN - OPUS4-57040 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Babutzka, Martin A1 - Zekhnini, Khalid A1 - Seifert, Lando A1 - Le, Quynh Hoa A1 - Grabowski, Sven T1 - Schlussbericht zum Forschungsvorhaben „Verbundvorhaben: "KKS-Gründung" - Korrosionsmonitoring und aktiver kathodischer Korrosionsschutz von Offshore-Gründungsstrukturen - Teilvorhaben: Korrosionsprüfungen im Laborcontainer“ in der Fördermaßnahme „Anwendungsorientierte nichtnukleare FuE im 6. Energieforschungsprogramm“ im Förderbereich „Windenergie“ N2 - Das Ziel des Verbundforschungsvorhabens KKS-Gründung war die Entwicklung eines Monitoringsystems zur Erfassung von Korrosion an Gründungsstrukturen im Labormaßstab. Dafür war eine umfassende Bewertung und Beschreibung korrosionsbeeinflussender Faktoren und der Korrosionssysteme notwendig. Im Vorhaben KKS-Gründung wurde die Gründungsstruktur unterhalb der Wasserlinie betrachtet bis hin zum anaeroben Bereich im Sediment. Insbesondere der Sedimentbereich wurde bisher nur unzureichend betrachtet. Da die komplexen Mechanismen in der Sedimentzone noch nicht ausreichend wissenschaftlich untersucht wurden, mussten Möglichkeiten entwickelt werden, um diese zu bewerten. Im Verbundforschungsvorhaben KKS-Gründung agierte die Bundesanstalt für Materialforschung und -prüfung (BAM) als Forschungsstelle. Die Hauptziele des Teilvorhabens der BAM waren die Bereitstellung einer Messumgebung für das von den Partnern entwickelte Monitoringsystem, die umfassende wissenschaftliche Beschreibung der Korrosionssysteme im Unterwasserbereich und Sediment sowie die Gewinnung von Messdaten zur Verifizierung und Überführung in die Simulation. Als Forschungsstelle war die BAM der Ansprechpartner für die Verbundpartner bei wissenschaftlichen Fragestellungen. Die Hauptziele des Vorhabens wurden erreicht und es wurden grundlegende Erkenntnisse zum Korrosionsverhalten von Offshore-Stahl im Unterwasser und Sedimentbereich gewonnen. Darüber hinaus wurden wichtige Erkenntnisse zum Betrieb eines Laborcontainers und zur Nachstellung von Korrosionssystemen in Meerwasserbecken bei Verwendung von künstlichem Meerwasser und Sand als Sediment gewonnen. Eine Beschreibung und Bewertung der Korrosivität und ablaufender Reaktionen in den einzelnen Belastungszonen wurde mittels elektrochemischer und gravimetrischer Verfahren vorgenommen. KW - Korrosionsschutz KW - KKS KW - Korrosionsmonitoring KW - Offshore-Windenergieanlagen KW - Meerwasser KW - Sediment PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-569252 SP - 1 EP - 74 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-56925 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wandtke, Karsten T1 - Residual stress formation in DED-arc manufactured high strength steel components N2 - Additive manufacturing (AM) processes enable the efficient production of advanced constructions. New developments in topology optimization are leading to weight-optimized designs of increasing complexity. Direct energy deposition processes (DED) such as wire and arc-based additive manufacturing are an important method of additive manufacturing. The wire filler metals enable a wide range of materials, while the arc process provides a high deposition rate compared to laser and powder-based processes. Combined with the use of high-strength steels, the thickness of walls or components can be significantly reduced in the context of lightweight construction, which results in significant savings in energy, costs, time and resources. Suitable high-strength steel filler metals are commercially available for DED-arc AM processes. However, guidelines and quantitative knowledge about welding stresses and cold cracking issues during component production and service are lacking. This limits the industrial application considerably. In a joint project of BAM and Chemnitz University of Technology, the main influences and complex interactions of material, production process, design and processing steps on the residual stress level are investigated. The aim is to develop processing recommendations and a cold cracking test for economical processing and stress-related design of high-strength steels with DED-arc. This study focuses on residual stress analysis by neutron diffraction (ND) and X-ray diffraction (XRD) on defined test specimens. The ND analysis were performed at the Paul Scherrer Institute- Villigen, Switzerland (PSI) and the XRD analysis at BAM. The study shows a quantitative and qualitative comparison of the residual stress magnitudes and distribution between the component bulk (ND) and surface (XRD) analyses. The ND analysis reveals that in DED-arc AM walls the residual stresses dominate in the direction of welding and are negligibly small in each case transverse to the direction of welding. The topology of the analyzed residual stresses shows almost identical residual stress maps compared to XRD. In addition, the residual stresses are significantly influenced by the solid phase transformation of the material due to low cooling times and less post heat treatment cycles of following AM layers in the area of the top layer. T2 - IIW Intermediate Meeting C-XIII CY - Online meeting DA - 20.04.2023 KW - Additive Manufacturing KW - High strength steel KW - Residual Stress PY - 2023 AN - OPUS4-59308 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Konert, Florian T1 - Evaluation of the tensile properties of X65 pipeline steel in compressed gaseous hydrogen using hollow specimens N2 - Hydrogen has great potential into the decarbonization process of the energy and transport sectors, thus helping to mitigate the urgent issue of global warming. It can be sustainably produced through water electrolysis with potentially zero emissions, and efficiently used in fuel cell systems. Despite its environmental advantages, hydrogen is an extremely flammable substance and its interaction with most metallic materials could result in their mechanical properties degradation to an extent that could make them inherently unsafe. Extensive material testing under realistic operating conditions is required to determine the criteria under which hydrogen-induced damage is to be expected. In-situ slow strain rate tensile (SSRT) test is an option that allow the quantification of the behavior of metals in hydrogenated environments. The standardized procedure for testing in-situ the pressurized gaseous hydrogen effect on metals consists of the utilization of an autoclave as a containment volume. Testing inside an autoclave is difficult, expensive, and time-consuming, and requires specialized equipment and trained personnel. A relatively recent method to circumvent these issues and provide affordable and reliable test results consists in using hollow specimens as the gas containment volume, thus applying the hydrogen pressure inside rather than outside the specimen. This experimental setup allows us to minimize the volume of hydrogen and perform the tests safely and effectively. This study focuses on the evaluation of tensile properties of X65 pipeline steel, which was in vervice for natural gas transport, tested in a high-pressure hydrogen environment using hollow specimens. A constant nominal strain rate of 1ꞏ10-6 s-1 is applied. Tests are performed with different manufacturing techniques for the drilling process, which results in difeerent surface conditions. The effect of the roughness on the HE was investigated. For the evaluation the effect on the reduced area at fracture (RA) and the elongation loss were determined. Further fractographic analysis were performed. In this way, this study provides insights on the applicability of novel, reliable, and safer testing method which can be used to assess HE, particularly in relation with hydrogen-induced loss of ductility in metallic material. T2 - ICSI 2023 | 5th International Conference on Structural Integrity CY - Funchal, Portugal DA - 29.8.2023 KW - Hydrogen KW - Hollow-specimen KW - SSRT KW - Ferritic steel KW - Hydrogen embrittlement PY - 2023 AN - OPUS4-58141 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Balscheit, Hagen T1 - Experimental Investigation on Buckling Behavior of soil-embedded Piles N2 - Monopile-Gründungen sind die mit Abstand am häufigsten verwendete Gründungskonstruktion für Offshore-Windenergieanlagen. Ein wesentliches Problem bei der Bemessung ist das lokale Beulen des Gründungspfahls, welches typischerweise im Bereich der Bettung auftritt. Aufgrund der Nichtlinearität der Bettungsrandbedingung sind klassische Bemessungsansätze nicht anwendbar, so dass der Bemessungsingenieur auf eine vollständig numerische Berechnung zurückgreifen muss. In diesem Vortrag wird eine experimentelle Versuchskampagne zur Erzeugung von Kalibrierungsdaten für solche numerischen Modelle vorgestellt. Eine ausführlichere Darstellung findet sich im gleichnamigen Artikel. T2 - EUROSTEEL 2023 CY - Amsterdam, Netherlands DA - 11.09.2023 KW - Wind KW - Wind Energy KW - Offshore KW - Shell Buckling KW - Soil-Structure-Interaction PY - 2023 AN - OPUS4-58365 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Schröpfer, Dirk A1 - Becker, Amadeus A1 - Kannengießer, Thomas T1 - Beanspruchungsgerechte Reparatur von Schweißverbindungen bei der Fertigung von Bauteilen aus hochfesten Feinkornbaustählen N2 - Bei der Montage von Stahlkonstruktionen kommt es trotz anforderungsgerechter schweißtechnischer Fertigung vereinzelt zur Detektion von unzulässigen Unregelmäßigkeiten im Schweißbereich. Die Verarbeitungsregelwerke empfehlen das lokale thermische Ausfugen betroffener Bereiche und erneutes Schweißen, geben aber aufgrund fehlender wissenschaftlich fundierter Untersuchungen kaum Informationen zu adäquaten Reparaturkonzepten. Dies betrifft insbesondere die Berücksichtigung und Optimierung resultierender schweißbedingter Beanspruchungen durch hohe Schrumpfbehinderungen der Ausfugenuten sowie der Gefügedegradation angrenzender Bereiche durch das Ausfugen und erneute Schweißen. Gerade bei hochfesten Stahlgüten ergeben sich dadurch häufig reduzierte mechanische Eigenschaften und zusätzliche schweißbedingte Beanspruchungen sowie erneut auftretende Nahtdefekte. Deshalb wurden für das Forschungsvorhaben systematische bauteilrelevante Untersuchungen der schweißbedingten Beanspruchungen und Gefügeveränderungen reparierter Schweißnähte in Abhängigkeit von der Schrumpfbehinderung und Wärmeführung beim Schweißen und Ausfugen sowie von der Reparaturzyklenanzahl durchgeführt. Die Untersuchungsergebnisse zeigen auf, welche Faktoren sich für eine Beanspruchungsreduzierung auch bei hohen Einspannbedingungen eignen und wie eine Degradation des Gefüges und der Eigenschaften der Schweißnaht sowie wiederholte Schweißnahtdefekte in der Reparaturnaht vermieden werden können. Insbesondere können mittels adaptiver Wärmeführung geringere schweißbedingte Beanspruchungen in den Reparaturschweißnähten bewirkt werden. Bauteilversuche sichern zudem die Übertragbarkeit der Schweißexperimente in die Praxis ab. Aufgrund der Erkenntnisse konnten Empfehlungen für beanspruchungs- und werkstoffgerechte Reparaturkonzepte abgeleitet und ausgesprochen werden. Die Analysen wurden an den hochfesten Stahlgüten S500MLO für den Offshore-Bereich und S960QL für den Mobilkranbau realisiert. Damit wird insbesondere der wirtschaftlichen Fertigung hocheffizienter Konstruktionen für Windenergieanlagen und hochfester Strukturen, die für deren Errichtung notwendig sind, Rechnung getragen. So bieten die Forschungsergebnisse eine wesentliche Grundlage für die Weiterentwicklung entsprechender Normen und Regelwerke. Damit können letztlich Schäden und zumeist teure Nacharbeiten verhindert und eine verbesserte Ausnutzung des hohen Festigkeitspotentials hochfester Stähle erreicht werden. Gerade auch KMU können mit Blick auf die Kosten für Fertigung, Schweißarbeit und Material von den Erkenntnissen beim Einsatz hochfester Stähle, die für eine effiziente Realisierung der Energiewende in Deutschland notwendig sind, profitieren. KW - MAG-Schweißen KW - Hochfester Stahl KW - Reparatur KW - Kaltrisssicherheit KW - Reparaturschweißen KW - Wärmeführung KW - Windenergie PY - 2023 UR - https://matplus.shop/produkt/p-1311-beanspruchungsgerechte-reparatur-von-schweissverbindungen-bei-der-fertigung-von-bauteilen-aus-hochfesten-feinkornbaustaehlen SN - 978-3-96780-146-0 N1 - Schlussbericht vom 18.07.2022 zu dem über die Arbeitsgemeinschaft industrieller Forschungsvereinigungen "Otto von Guericke" (AiF) im Rahmen des Programms zur Förderung der Industriellen Gemeinschaftsforschung und -entwicklung (IGF) vom Bundesministerium für Wirtschaft und Energie (BMWi) aufgrund eines Beschlusses des Deutschen Bundestages geförderten Vorhaben Nr. 20162 N (Berichtszeitraum 01.07.2019 - 28.02.2022) VL - P 1311 SP - 1 EP - 156 PB - Verlag und Vertriebsgesellschaft CY - Düsseldorf AN - OPUS4-59260 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kromm, Arne T1 - Large scale hydrogen assisted cracking test for thick walled SAW joints for offshore applications N2 - Offshore wind turbines continuously increase in size and weight and demand adequate offshore foundations concepts like monopiles, tripods or jackets. These components are typically submerged arc welded (SAW) high-strength thick steel plates like the S420ML. During welding, the occurrence of delayed hydrogen assisted cracking (HAC) must be anticipated. HAC is a critical combination of the local hydrogen concentration within a susceptible microstructure under certain mechanical load, i.e., the occurring (welding) residual stresses. The welding sequence of the thick-walled plates complicate the residual stress distribution due to the necessary repeated thermal cycling, i.e., welding seam / layer deposition to fill the joint. For that purpose, SAW with two-wire-technique was used to weld a specially designed and prototype-like mock-up of a real component with a thickness of 50 mm, filled more than 20 passes and a seam length of 1,000 mm. Additional welded stiffeners simulated the effect of a high restraint, to stimulate critical HAC conditions. The necessity of a minimum waiting time (MWT) before the NDT can be conducted (to exclude HAC) was critically verified by the application of ultrasonic testing of the welded joint at different time-steps of the NDT of 48 h after welding. The residual stresses were determined by a robot XRD goniometer. Tensile residual stresses up to the yield limit are found both in the weld metal and in the heat-affected zone. Numerical modelling allowed the qualitative estimation of the hydrogen diffusion in the weld. A remarkable HAC occurrence was not identified and proves both, a certain resistance of the weld joint to HAC and the (questionable) duration of the MWT. T2 - IIW Intermediate Meeting of Commission II-A CY - Garching, Germany DA - 06.03.2023 KW - Hydrogen assisted cracking KW - Submerged arc welding KW - Offshore wind turbine KW - High-strength steel KW - Component test PY - 2023 AN - OPUS4-57100 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -