TY - CONF A1 - Kästle, Emanuel A1 - Duffner, Eric A1 - Ghaznavi, Ali T1 - DAVID Project meeting 23.09.2025 N2 - Yearly report on the DAVID project, presented in front of the consortial partners. The report shows the progress achieved by the DAVID project team at BAM in terms of testing newly developed carbon-fiber reinforced pressure vessels of type IV. T2 - DAVID project meeting CY - Berlin, Germany DA - 23.09.2025 KW - Acoustic Emission KW - Pressure Vessels KW - DAVID project KW - Damage monitoring KW - Fiber reinforced polymers PY - 2025 AN - OPUS4-65289 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sander, Luise T1 - Linking material and electrode properties to the cell performance of commercially available sodium-ion cells N2 - As the first commercial sodium-ion-batteries (SIBs) are available for purchase, it is possible to investigate material composition. Gaining an insight into the material composition of these SIBs is of interest not only for the classification of possible safety risks and hazards, but also in regard to recycling. Herein we report the preliminary investigations of the chemical and structural composition of first commercial SIB-cells.[1,2] Two different SIB-cell types were compared in terms of electrode size, thickness, loading etc. Furthermore, the composition of the active materials and electrolyte was investigated and compared. Finally, the gained results were linked to the different data sheet performance of the two cell types. T2 - Batterieforum Deutschland 2026 CY - Berlin, Germany DA - 20.01.2026 KW - Electrochemical Energy Storage KW - Battery KW - Sodium-ion-battery KW - EES KW - Energy Storage PY - 2026 AN - OPUS4-65588 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dietzmann, Simon T1 - Between Homogenous and Heterogenous Catalysis: Single-Atom-Catalysts N2 - Catalysis is a very important process in chemistry as it lowers the energy barrier for chemical reactions. This saves energy and/or some reactions are only possible with a catalyst under the desired conditions (temperature and pressure). Catalysts can be roughly categorized depending on the phase they interact with the substrates in homogenous and heterogenous catalysis. T2 - 5. Deutsche Tagung für Forschung mit Synchrotronstrahlung, Neutronen und Ionenstrahlen an Großgeräten (SNI2022) CY - Berlin, Germany DA - 05.09.2022 KW - Single-atom-catalyst KW - Electrochemistry KW - Porous carbons PY - 2022 AN - OPUS4-61989 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sauer, Hannah A1 - Okpeke, Bright E. A1 - Dzielendziak, Agnieszka S. A1 - Eberwein, Robert A1 - Baetcke, Lars A1 - Ehlers, Sören T1 - Comparative life cycle assessment of vacuum insulation panel core materials for liquid hydrogen storage tanks – glass bubbles compared to conventional core materials N2 - The environmental performance of insulation materials for liquid hydrogen storage tank application is important to the development of sustainable supply chains. As new materials keep evolving, there is a need to assess their environmental impact. Therefore, this study investigates the environmental sustainability and circularity of cryogenic insulation concepts, namely vacuum insulation panels (VIPs), exclusively focussing on their core materials. Employing a cradle-to-grave life cycle assessment model, the VIP core materials are investigated with a special focus on glass bubbles. Based on the results, the global warming potential of the considered core materials, namely, glass bubbles, silica aerogel, fumed silica, expanded perlite, glass fibre, and polyurethane foam is 9.21∗10^−2, 7.00, 2.50∗10^−1, 3.63∗10^−2, 6.68∗10^−2, and 1.88 kg CO2 eq. per functional unit, respectively. In general, silica aerogel and polyurethane foam are the least environmentally friendly materials, while the most sustainable is expanded perlite, followed by glass fibre, glass bubbles, and fumed silica. KW - LH2 KW - Insulation KW - Cryogenic storage tank KW - Life Cycle Assessment PY - 2026 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-655445 DO - https://doi.org/10.1016/j.ijhydene.2026.153937 SN - 0360-3199 VL - 219 SP - 1 EP - 11 PB - Elsevier Ltd. AN - OPUS4-65544 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dietzmann, Simon T1 - Between Homogenous and Heterogenous Catalysis: Single-Atom-Catalysts N2 - Catalysis is a very important process in chemistry as it lowers the energy barrier for chemical reactions. This saves energy and/or some reactions are only possible with a catalyst under the desired conditions (temperature and pressure). Catalysts can be roughly categorized depending on the phase they interact with the substrates in heterougenous and heterogenous catalyst T2 - RÅC international summer school CY - Varberg, Sweden DA - 14.08.2022 KW - Single-atom-catalyst KW - Electrochemistry KW - Porous carbons PY - 2022 AN - OPUS4-61983 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dietzmann, Simon T1 - XAS for structural characterization of atomically dispersed materials N2 - metal and nitrogen enriched carbons (M-N-C) are promising electrocatalysts for small molecule activation. It is proposed that the nitrogen is forming a stabilizing N4-site for the catalytically active metal. This can be proven by XAS measurements to confirm the coordination sphere around the metal. T2 - Bessy User Meeting CY - Online meeting DA - 08.12.2024 KW - Single-atom-catalyst KW - Structural characterization KW - Porous carbons PY - 2022 AN - OPUS4-61994 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias T1 - Großbrandversuche von Elektrofahrzeugen zum Transport Gefährlicher Güter N2 - Der zunehmende Einsatz von batterieelektrischen Transportfahrzeugen (Battery Electric Transport Vehicles – BETVs) im Verkehrswesen wirft Sicherheitsfragen beim Transport gefährlicher Güter auf. Obwohl Batteriebrände auf Zell-, Modul- und Fahrzeugebene umfassend untersucht wurden, fehlen systematische Daten zu deren thermischen Auswirkungen auf Gefahrgutverpackungen. Um diese Lücke zu schließen, führt die Bundesanstalt für Materialforschung und -prüfung (BAM) auf ihrem Testgelände Technische Sicherheit (BAM-TTS) groß angelegte Brandtests durch, in denen konservative Unfallszenarien mit unterschiedlichen Zellchemien und -kapazitäten nachgestellt werden. Die Tests kombinieren fahrzeugbedingte Brandlasten mit standardisierten Propan-Referenzbränden und erfassen mittels hochauflösender Instrumente zentrale Messgrößen wie Wärmefluss, Temperatur und Strahlung. Der daraus entstehende Datensatz liefert erstmals eine direkte Quantifizierung der thermischen Auswirkungen von BETV-Bränden auf Verpackungen und unterstützt Expertengremien bei der Bewertung, ob bestehende regulatorische Anforderungen für alternative Antriebssysteme weiterhin angemessen sind. T2 - Informationsaustausch zur verkehrsrechtlichen Aufsicht bei der Beförderung radioaktiver Stoffe CY - Salzgitter, Germany DA - 03.02.2026 KW - Batteriebrand KW - IAEA KW - Gefahrgut KW - Transport PY - 2026 AN - OPUS4-65626 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wu, Shu-Han T1 - MOF-derived Synthetic Carbon Anode Materials for Sodium-Ion Batteries N2 - Metal-organic frameworks (MOFs), particularly the zeolitic imidazolate framework (ZIF) family, are attractive precursors for advanced energy-storage materials. Upon pyrolysis, ZIFs can be transformed into electrically conductive carbon materials while preserving their original particle morphology, which is crucial for achieving high-performance sodium-ion battery anodes. Despite these advantages, large-scale implementation remains challenging due to the need for synthesis routes that balance performance, cost, and sustainability. The present study addresses these challenges by developing environmentally benign and economically feasible strategies for the scalable production of ZIF-8-derived carbon anodes suitable for industrial applications. T2 - Batterieforum Deutschland 2026 CY - Berlin, Germany DA - 20.01.2026 KW - Sodium-ion battery KW - Negative electrode KW - Metalorganic frameworks PY - 2026 AN - OPUS4-65644 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Petitdemange, Eliot A1 - Zhu, Jinjie A1 - Pedersen, Angus A1 - Parker, Joseph A1 - Balaghi, Esmael A1 - Li, Shaohua A1 - Favero, Silvia A1 - Ignacio Martínez, José A1 - Haigh, Sarah A1 - Titirici, Maria-Magdalena A1 - Fischer, Anna A1 - Barrio, Jesús T1 - High-Yield Synthesis of Fe-NC Electrocatalysts Using Mg2+ Templating and Schiff-Base Porous Organic Polymers N2 - The decoupled synthesis of Fe-NC single-site electrocatalysts mediated by Lewis acids enables high active site density and utilization. However, current approaches often rely on small organic molecules and suffer from low synthesis yields due to the high Lewis acid-to-precursor ratios required to achieve highly porous carbons. Here, a porous organic polymer (POP) based on 2,4,6-Triaminopyrimidine (TAP) is utilized as a carbon-nitrogen-based scaffold for the synthesis of Fe─NC electrocatalysts. By tuning the amounts of MgCl2 ·6H2O used both as porogen and active site templating agent, synthetic yields exceeding 45% are achieved, a significant improvement compared to the 6% yield from the molecular analogue and the highest reported forMg2+ templated systems. Subsequent low-temperature exchange with Fe leads to atomically dispersed FeNx, minimizing Fe aggregation. The resulting materials exhibit high specific surface areas (>1000 m2 g−1) with micro-, meso-, and macropores, which promote mass transport and active site accessibility. Compared to Fe─NC synthesized via direct pyrolysis of Fe-coordinated POP, the decoupled method enables significantly higher catalytic activity in both alkaline and acidic media, and delivers 1 A cm−2 at 0.687 ± 0.004 VRHE in an alkaline gas diffusion electrode, highlighting its potential for practical oxygen reduction devices. KW - Porous Organic Polymers KW - Single Atom KW - Oxygen reduction PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-652618 DO - https://doi.org/10.1002/adfm.202518944 SN - 1616-3028 SP - 1 EP - 15 PB - Wiley-VCH GmbH AN - OPUS4-65261 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dietzmann, Simon A1 - Mehmood, Asad A1 - de Oliveira Guilherme Buzanich, Ana A1 - Emmerling, Franziska A1 - Fellinger, Tim-Patrick A1 - Thomas, A. T1 - Characterization of Solid-State Complexes by XAS N2 - Atomically dispersed metal-nitrogen doped carbons (M-N-C) are promising catalysts for the activation of small molecules such as O2 and CO2. These single atom catalysts (SAC) operate at the interface between homogenous and heterogenous catalysts. Currently, many examples of M-N-C are known with good oxygen reduction reaction activity but lacking a controlled synthesis of the specific active sites of the precatalyst. Recently, our group facilitated the synthesis of pure pyrrolic M-N4 sites using Zn ions as imprinters.[1] These amorphous materials obtained by active site imprinting method are characterized at the BAMline (Bessy II) by X-ray absorption spectroscopy (XAS). In-situ/operando measurements will be crucial in future work for a better understanding of the dynamic changes of the active site. T2 - InSynX Workshop 2023 CY - Sao Paulo, Brazil DA - 06.03.2023 KW - Solid-State Complexes PY - 2023 AN - OPUS4-58933 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Scholl, Juliane A1 - Scharpmann, Philippa A1 - Bagheri, Abbas A1 - Lisec, Jan A1 - Meiers, Emelie A1 - Jaeger, Carsten A1 - Leonhardt, Robert A1 - Haase, Hajo A1 - Koch, Matthias T1 - Beyond the lab: Real-world composition of commercial Li-ion battery electrolytes N2 - This study presents a systematic, characterization of electrolytes from commercial lithium-ion batteries (LIB), encompassing 90 batteries from leading global manufacturers across diverse formats and application sectors. An integrated, complementary mass spectrometric workflow combining LC–MS/MS, GC–MS, and high-resolution MS was employed. To ensure robust structural annotation, molecular identifications were assigned confidence levels following Schymanski et al. (2014). Across all formats, PF6− was confirmed as the dominant Li+ counterion, frequently coexisting with BF4−, PO2F2−, and bis(fluorosulfonyl)imide (FSI−), forming binary and ternary salt systems optimized for both conductivity and safety. Solvent systems revealed the widespread use of propylene carbonate (PC) combined with diverse carbonate mixtures, demonstrating trends in performance optimization specific to cell format. A variety of additives were identified, reflecting a clear shift towards multifunctional, synergistic additive packages and the gradual replacement of fluorinated species with environmentally safer alternatives. Cycling studies demonstrated that electrolyte degradation mechanisms are strongly influenced by electrode composition and additive chemistry, with oxidative degradation pathways dominating. Together, these findings provide rare empirical insight into the evolving formulation strategies of electrolytes in commercial LIB, still employing classic carbonates and LiPF6, but highlighting a trend toward safer, more robust, and sustainable electrolyte architectures by using synergistic multifunctional systems. KW - Mass Spectrometry KW - Lithium-ion batteries KW - Electrolyte degradation PY - 2026 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-656254 DO - https://doi.org/10.1016/j.jpowsour.2026.239739 SN - 0378-7753 VL - 673 SP - 1 EP - 13 PB - Elsevier B.V. AN - OPUS4-65625 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Werner, Jan A1 - Böttcher, Nils A1 - Soderer, Hannes T1 - Batterieelektrisch betriebene FL/AT-Fzg.-Vorschriften und Sicherheit N2 - Überblick über Vorschriftenlage, Technik der Batterien und aktuelle Forschung. Aufzeigen bestehender Unschärfen in der Rechtslage, Sicherheitsfragestellungen zu Batterietechnik sowie Interaktion mit Gefahrgut. T2 - E-Mobilität in der Chemielogistik CY - Duisburg, Germany DA - 04.03.2026 KW - Batterieelektrische Antriebe KW - Gefahrgut KW - ADR KW - Unfallfeuer KW - Wärmeübertragung KW - Lithium Ionen Batterien PY - 2026 AN - OPUS4-65663 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böttcher, Nils T1 - Kick-off LiBaTra - WP4: Safety Tests N2 - Die BAM ist Projektpartner im vom BMWE geförderten Verbundvorhaben LiBaTra („Lithium-Ionen-Batterie Transport und sichere Deaktivierung für das Recycling“). Weitere Projektpartner neben der BAM sind die Universität Braunschweig mit dem iPAT (Institut für Partikeltechnik) sowie die Firmen Siemens Energy SE sowie No Canary. Die BAM bearbeitet das Teilvorhaben „Risikobestimmung tiefenentladener Energiespeicher“ (FKZ: 03EI6145A-D). Die Präsentation gibt die wesentlichen Arbeitsinhalte des Teilvorhabens der BAM wieder. T2 - Kick-off Meeting des Verbundvorhabens LiBaTra CY - Online meeting DA - 17.02.2026 KW - Auswirkungsbetrachtungen KW - Elektrische Energiespeicher KW - Lithium-Ionen-Batterie KW - Stationäre Energiespeicher KW - Thermisches Durchgehen PY - 2026 AN - OPUS4-65657 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Ammerman, D. J. A1 - Bignell, J. L. A1 - Bjorkman, G. S. A1 - Breach, M. R. A1 - Broz, V. A. A1 - Jordan, J. A1 - Kuehner, S. A1 - Molitoris, D. P. A1 - Reinhardt, W. A1 - Rigato, A. B. A1 - Rosvall, E. S. A1 - Sakalaukus Jr., P. J. A1 - Shih, P. Y.-K. A1 - Siromani, D. A1 - Snow, S. D. A1 - Tso, C.-F. A1 - Yaksh, M. C. A1 - Zencker, Uwe A1 - Zhang, X. T1 - Guidance document - Use of explicit finite element analysis for the evaluation of radioactive material transport packages and storge casks in energy-limited impact events N2 - The purpose of this document is to provide guidance for developing quality finite element models to ensure, with reasonable certainty, that the model produces accurate results for comparison with the strain-based or stress-based acceptance criteria of Section III, Division 3 of the ASME Boiler and Pressure Vessel Code, but could be applicable to other Sections of the Code or other codes. Models developed following the guidance provided in this document meet the definition of a "Quality Model," as described in Paragraph EE 1240 of the Nonmandatory Appendix EE (Strain-Based Acceptance Criteria Definitions and Background Information). It cannot be emphasized enough, however, that the guidance supplied here does not constitute requirements. Rather, the intent of the guidance is to give practical direction to analysts (i.e., this is not a set of regulatory requirements). This guidance document is an "evolving" document. It will undergo revision as computing capability and FEA techniques progress, and as example problems are developed. KW - Computational modeling KW - Explicit dynamics PY - 2025 SN - 978-0-7918-7749-4 VL - NTB-6 SP - 1 EP - 153 PB - Americal Society of Mechanical Engineers (ASME) CY - New York, NY ET - 2025 AN - OPUS4-65759 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias A1 - Soderer, Hannes A1 - Wille, Frank T1 - Accident-Induced Battery and Hydrogen Fires: Challenges for the Safe Transport of Packages with Dangerous Goods N2 - The transport of radioactive material is subject to stringent safety requirements defined in the IAEA regulations SSR-6 [1]. These requirements, particularly the thermal and mechanical accident conditions of transport (ACT), are rooted in studies established in the 1960s and have remained largely unchanged, especially regarding thermal boundary conditions. For many decades, the type of propulsion technology used for transporting dangerous goods has remained unchanged. In recent years, however, alternative drive technologies have made their breakthrough and are becoming increasingly established on the market. Since then, the rapid adoption of battery-electric and hydrogen-powered vehicles in heavy-duty freight and dangerous goods transport is altering the conditions under which accidents may occur. This raises a central question: Are current regulatory tests, such as the 800°C and 30-minute thermal test, still sufficiently conservative for ACT involving vehicles with alternative propulsion technologies? Battery fires pose specific challenges due to the properties of lithium-ion cells and emerging chemistries such as NMC, LFP, and NCA/LTO. Their highly flammable electrolytes, potential for thermal runaway, release of toxic gases, and long-duration or reigniting fires differ markedly from conventional fuel fires. Such behavior questions whether existing thermal test specifications adequately reflect realistic accident conditions involving electric vehicles. Hydrogen-powered vehicles introduce additional hazards. Accidental releases can form explosive mixtures, and ignitions may produce intense jet fires or explosions with high radiative heat fluxes. Near a package, these events can create thermal loads and transient pressures not fully captured by current regulatory test envelopes. Beyond peak temperatures and exposure time, parameters emphasized in IAEA SSG-26 [2], such as emissivity, absorptivity, heat flux, and fuel energy density, are critical for determining net heat input and require assessment with respect to realistic scenarios. Addressing these gaps requires a research program focused on vehicle fire scenarios and their implications for the safety assessment of packages for radioactive material. This includes developing conservative accident scenarios for various battery chemistries and performing large-scale experiments with calorimetric reference packages and instrumented setups. Notably, there are currently no experimental investigations of accidents involving transport vehicles with alternative propulsion in which the dangerous goods - the package and its loading - have been the central focus rather than the vehicle itself. A necessary research project must aim to assess the relevance of the IAEA's existing transport testing requirements regarding these new risks and, if necessary, propose changes or supplementary measures. Its methods and datasets should also support assessments for other dangerous goods, ensuring that regulatory measures continue to provide robust protection in an evolving transport landscape. T2 - International Conference on the Safe and Secure Transport of Nuclear and Radioactive Material CY - Wien, Austria DA - 23.03.2026 KW - IAEA Regulations KW - Fire Test Stand KW - Accident Scenario KW - Fire Qualification PY - 2026 SP - 1 EP - 5 PB - International Atomic Energy Agency CY - Wien AN - OPUS4-65806 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias A1 - Tazefidan, Kutlualp A1 - Wille, Frank T1 - Ai-Enhanced Documentation Analysis in Regulatory Safety Assessment of Transport Packages N2 - The transport of radioactive material requires regulatory approval based on the package type, as defined by the regulations of the International Atomic Energy Agency (IAEA). These approvals rely on comprehensive Package Design Safety Reports that evaluate mechanical, thermal, shielding, criticality and transport requirements, supported by specifications, inspections, certificates, drawings, and other technical documentations. Such safety reports contain numerous interconnected documents, and even minor changes, such as component modifications, updated material properties or revised regulations, may affect multiple sections. Although all reports follow the same regulatory framework, each package has unique design features, making every safety assessment distinct. Most documentation exists in digital form but remains largely non–machine-interpretable, limiting automated analysis of dependencies across documents. The extended synopsis argues that overcoming these limitations requires moving from simple digitization toward structured knowledge representation. A multi-stage approach begins with foundational AI technologies, including Large Language Models (LLMs) and Retrieval-Augmented Generation (RAG), which improve information retrieval but cannot capture the full complexity of safety report interrelationships. Building Knowledge Graphs (KGs) offers the necessary next step by transforming heterogeneous, unstructured, and semi-structured documents into a connected, queryable network. KGs enable precise tracing and visualization of dependencies across datasheets, simulations, experimental results, standards, and regulatory requirements. Such structured representations would allow automatic detection of changes, propagation of effects across related documents and validation of conditions using AI-supported tools, reducing manual workload, and improving safety and consistency. Human error remains a significant factor in drafting and reviewing safety reports. A digital quality infrastructure could reduce the number of iterations and further streamline the overall process. Integrating AI into this workflow has the potential not only to optimize assessments but also to improve their robustness by increasing the interpretability of documentation and thereby enhancing overall safety. This preliminary study examines the readiness and requirements for intelligent documentation analysis systems that support regulatory compliance for transport package safety. By analysing current documentation workflows, it demonstrates how LLM-based tools can interpret complex safety reports and identify critical interdependencies, and why KG-based architectures are essential for managing these dependencies reliably. T2 - International Conference on the Safe and Secure Transport of Nuclear and Radioactive Material CY - Wien, Austria DA - 23.03.2026 KW - Knowledge Graph KW - AI KW - RAG KW - LLM PY - 2026 SP - 1 EP - 5 PB - International Atomic Energy Agency CY - Wien AN - OPUS4-65808 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias T1 - Accident-Induced Battery and Hydrogen Fires: Challenges for the Safe Transport of Packages with Radioactive Material N2 - The transport of radioactive material is subject to stringent safety requirements defined in the IAEA regulations SSR-6 [1]. These requirements, particularly the thermal and mechanical accident conditions of transport (ACT), are rooted in studies established in the 1960s and have remained largely unchanged, especially regarding thermal boundary conditions. For many decades, the type of propulsion technology used for transporting dangerous goods has remained unchanged. In recent years, however, alternative drive technologies have made their breakthrough and are becoming increasingly established on the market. Since then, the rapid adoption of battery-electric and hydrogen-powered vehicles in heavy-duty freight and dangerous goods transport is altering the conditions under which accidents may occur. This raises a central question: Are current regulatory tests, such as the 800°C and 30-minute thermal test, still sufficiently conservative for ACT involving vehicles with alternative propulsion technologies? Battery fires pose specific challenges due to the properties of lithium-ion cells and emerging chemistries such as NMC, LFP, and NCA/LTO. Their highly flammable electrolytes, potential for thermal runaway, release of toxic gases, and long-duration or reigniting fires differ markedly from conventional fuel fires. Such behavior questions whether existing thermal test specifications adequately reflect realistic accident conditions involving electric vehicles. Hydrogen-powered vehicles introduce additional hazards. Accidental releases can form explosive mixtures, and ignitions may produce intense jet fires or explosions with high radiative heat fluxes. Near a package, these events can create thermal loads and transient pressures not fully captured by current regulatory test envelopes. Beyond peak temperatures and exposure time, parameters emphasized in IAEA SSG-26 [2], such as emissivity, absorptivity, heat flux, and fuel energy density, are critical for determining net heat input and require assessment with respect to realistic scenarios. Addressing these gaps requires a research program focused on vehicle fire scenarios and their implications for the safety assessment of packages for radioactive material. This includes developing conservative accident scenarios for various battery chemistries and performing large-scale experiments with calorimetric reference packages and instrumented setups. Notably, there are currently no experimental investigations of accidents involving transport vehicles with alternative propulsion in which the dangerous goods - the package and its loading - have been the central focus rather than the vehicle itself. A necessary research project must aim to assess the relevance of the IAEA's existing transport testing requirements regarding these new risks and, if necessary, propose changes or supplementary measures. Its methods and datasets should also support assessments for other dangerous goods, ensuring that regulatory measures continue to provide robust protection in an evolving transport landscape. T2 - International Conference on the Safe and Secure Transport of Nuclear and Radioactive Material CY - Vienna, Germany DA - 23.03.2026 KW - Fire Test Stand KW - Accident Scenario KW - IAEA Regu-lations KW - Fire Qualification PY - 2026 AN - OPUS4-65807 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pedersen, Angus A1 - Zhu, Jinjie A1 - Barrio, Jesús A1 - Parker, Joseph A1 - Hunter, Robert D. A1 - Haigh, Sarah J. A1 - Fellinger, Tim-Patrick A1 - Stephens, Ifan E. L. A1 - Titirici, Maria-Magdalena T1 - Contribution of Mg-templated porosity to activity and durability in Fe–N–C O 2 reduction catalysts N2 - Atomically dispersed Fe in N-doped carbon (Fe–N–C) catalysts are leading platinum-group-metal-free candidates for the O2 reduction reaction in proton exchange membrane fuel cells (PEMFCs). Zeolitic imidazolate framework (ZIF-8) derived Fe–N–C present the most promising performance; however, they possess a narrow distribution of small micropores, which limits active site accessibility. Here, to induce hierarchical porosity in Fe–N–C, we report a systematic study on MgCl2·6H2O-templated ZIF-8-derived Fe–N–C catalysts for the O2 reduction reaction. MgCl2·6H2O addition induced complete Zn removal, collapse of the ZIF-8 framework, and formation of large micro- and mesopores, with graphene-like structures. N content was markedly reduced, with conversion from pyridinic to pyrrolic N species. Rotating disc electrode tests showed a progressive increase in O2 reduction activity with MgCl2·6H2O, which is strongly correlated (R2 = 0.98) to the formation of large micropores and small mesopores (1–4 nm). This introduces an indirect structure–activity design principle for Fe–N–Cs. The enhanced Fe–N–C porosity also leads to increased degradation rates under accelerated stress test conditions, which we attributed to the oxidation of disordered carbon domains and active Fe loss. This study highlights a key trade-off between porosity-driven O2 reduction activity and durability in Fe–N–C catalysts. KW - Porosity KW - Single atom KW - Oxygen reduction PY - 2026 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-657549 DO - https://doi.org/10.1039/d5ma01488c SN - 2633-5409 SP - 1 EP - 8 PB - Royal Society of Chemistry (RSC) AN - OPUS4-65754 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias T1 - Accident-Induced Battery and Hydrogen Fires: Challenges for the Safe Transport of Packages with Dangerous Goods N2 - The transport of radioactive material is subject to stringent safety requirements defined in the IAEA regulations SSR-6 [1]. These requirements, particularly the thermal and mechanical accident conditions of transport (ACT), are rooted in studies established in the 1960s and have remained largely unchanged, especially regarding thermal boundary conditions. For many decades, the type of propulsion technology used for transporting dangerous goods has remained unchanged. In recent years, however, alternative drive technologies have made their breakthrough and are becoming increasingly established on the market. Since then, the rapid adoption of battery-electric and hydrogen-powered vehicles in heavy-duty freight and dangerous goods transport is altering the conditions under which accidents may occur. This raises a central question: Are current regulatory tests, such as the 800°C and 30-minute thermal test, still sufficiently conservative for ACT involving vehicles with alternative propulsion technologies? Battery fires pose specific challenges due to the properties of lithium-ion cells and emerging chemistries such as NMC, LFP, and NCA/LTO. Their highly flammable electrolytes, potential for thermal runaway, release of toxic gases, and long-duration or reigniting fires differ markedly from conventional fuel fires. Such behavior questions whether existing thermal test specifications adequately reflect realistic accident conditions involving electric vehicles. Hydrogen-powered vehicles introduce additional hazards. Accidental releases can form explosive mixtures, and ignitions may produce intense jet fires or explosions with high radiative heat fluxes. Near a package, these events can create thermal loads and transient pressures not fully captured by current regulatory test envelopes. Beyond peak temperatures and exposure time, parameters emphasized in IAEA SSG-26 [2], such as emissivity, absorptivity, heat flux, and fuel energy density, are critical for determining net heat input and require assessment with respect to realistic scenarios. Addressing these gaps requires a research program focused on vehicle fire scenarios and their implications for the safety assessment of packages for radioactive material. This includes developing conservative accident scenarios for various battery chemistries and performing large-scale experiments with calorimetric reference packages and instrumented setups. Notably, there are currently no experimental investigations of accidents involving transport vehicles with alternative propulsion in which the dangerous goods - the package and its loading - have been the central focus rather than the vehicle itself. A necessary research project must aim to assess the relevance of the IAEA's existing transport testing requirements regarding these new risks and, if necessary, propose changes or supplementary measures. Its methods and datasets should also support assessments for other dangerous goods, ensuring that regulatory measures continue to provide robust protection in an evolving transport landscape. T2 - ASNR-BAM Workshop CY - Paris, France DA - 31.03.2026 KW - Fire Test Stand KW - Accident Scenario KW - IAEA Regu-lations KW - Fire Qualification PY - 2026 AN - OPUS4-65804 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias T1 - Ai-Enhanced Documentation Analysis in Regulatory Safety Assessment of Transport Packages N2 - The transport of radioactive material requires regulatory approval based on the package type, as defined by the regulations of the International Atomic Energy Agency (IAEA). These approvals rely on comprehensive Package Design Safety Reports that evaluate mechanical, thermal, shielding, criticality and transport requirements, supported by specifications, inspections, certificates, drawings, and other technical documentations. Such safety reports contain numerous interconnected documents, and even minor changes, such as component modifications, updated material properties or revised regulations, may affect multiple sections. Although all reports follow the same regulatory framework, each package has unique design features, making every safety assessment distinct. Most documentation exists in digital form but remains largely non–machine-interpretable, limiting automated analysis of dependencies across documents. The extended synopsis argues that overcoming these limitations requires moving from simple digitization toward structured knowledge representation. A multi-stage approach begins with foundational AI technologies, including Large Language Models (LLMs) and Retrieval-Augmented Generation (RAG), which improve information retrieval but cannot capture the full complexity of safety report interrelationships. Building Knowledge Graphs (KGs) offers the necessary next step by transforming heterogeneous, unstructured, and semi-structured documents into a connected, queryable network. KGs enable precise tracing and visualization of dependencies across datasheets, simulations, experimental results, standards, and regulatory requirements. Such structured representations would allow automatic detection of changes, propagation of effects across related documents and validation of conditions using AI-supported tools, reducing manual workload, and improving safety and consistency. Human error remains a significant factor in drafting and reviewing safety reports. A digital quality infrastructure could reduce the number of iterations and further streamline the overall process. Integrating AI into this workflow has the potential not only to optimize assessments but also to improve their robustness by increasing the interpretability of documentation and thereby enhancing overall safety. This preliminary study examines the readiness and requirements for intelligent documentation analysis systems that support regulatory compliance for transport package safety. By analysing current documentation workflows, it demonstrates how LLM-based tools can interpret complex safety reports and identify critical interdependencies, and why KG-based architectures are essential for managing these dependencies reliably. T2 - International Conference on the Safe and Secure Transport of Nuclear and Radioactive Material CY - Vienna, Austria DA - 23.03.2026 KW - AI KW - RAG KW - LLM KW - Knowledge Graph PY - 2026 AN - OPUS4-65809 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias T1 - AI-Enhanced Documentation Analysis in Regulatory Safety Assessment of Dangerous Goods Packages N2 - The transport of radioactive material requires regulatory approval based on the package type, as defined by the regulations of the International Atomic Energy Agency (IAEA). These approvals rely on comprehensive Package Design Safety Reports that evaluate mechanical, thermal, shielding, criticality and transport requirements, supported by specifications, inspections, certificates, drawings, and other technical documentations. Such safety reports contain numerous interconnected documents, and even minor changes, such as component modifications, updated material properties or revised regulations, may affect multiple sections. Although all reports follow the same regulatory framework, each package has unique design features, making every safety assessment distinct. Most documentation exists in digital form but remains largely non–machine-interpretable, limiting automated analysis of dependencies across documents. The extended synopsis argues that overcoming these limitations requires moving from simple digitization toward structured knowledge representation. A multi-stage approach begins with foundational AI technologies, including Large Language Models (LLMs) and Retrieval-Augmented Generation (RAG), which improve information retrieval but cannot capture the full complexity of safety report interrelationships. Building Knowledge Graphs (KGs) offers the necessary next step by transforming heterogeneous, unstructured, and semi-structured documents into a connected, queryable network. KGs enable precise tracing and visualization of dependencies across datasheets, simulations, experimental results, standards, and regulatory requirements. Such structured representations would allow automatic detection of changes, propagation of effects across related documents and validation of conditions using AI-supported tools, reducing manual workload, and improving safety and consistency. Human error remains a significant factor in drafting and reviewing safety reports. A digital quality infrastructure could reduce the number of iterations and further streamline the overall process. Integrating AI into this workflow has the potential not only to optimize assessments but also to improve their robustness by increasing the interpretability of documentation and thereby enhancing overall safety. This preliminary study examines the readiness and requirements for intelligent documentation analysis systems that support regulatory compliance for transport package safety. By analysing current documentation workflows, it demonstrates how LLM-based tools can interpret complex safety reports and identify critical interdependencies, and why KG-based architectures are essential for managing these dependencies reliably. T2 - ASNR-BAM Workshop CY - Paris, France DA - 31.03.2026 KW - AI KW - RAG KW - LLM KW - Knowledge Graph PY - 2026 AN - OPUS4-65802 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Morcillo, Dalia A1 - Winckelmann, Alexander A1 - Oelze, Marcus A1 - Leonhardt, Robert A1 - Schmidt, Anita A1 - Richter, Silke A1 - Recknagel, Sebastian A1 - Vogl, Jochen A1 - Panne, Ulrich A1 - Abad Andrade, Carlos Enrique T1 - Exploring Age-Induced Lithium Isotope Fractionation in Lithium-Ion Batteries using Microwave-Induced Cold Nitrogen Plasma Mass Spectrometry N2 - This study explores Microwave-Inductively Coupled Atmospheric-pressure Plasma Mass Spectrometry (MICAP-MS) as a cost-effective alternative to Multi-Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS) for analyzing lithium isotopic composition in lithium-ion batteries (LIBs). We investigate the performance of MICAP-MS in measuring Li isotope ratios in new and aged commercial lithium cobalt oxide (LCO) batteries. Our results show that MICAP-MS, operating under cold plasma conditions at 800 W with an 8 mm torch position, achieves results metrologically compatible with MC-ICP-MS, with a precision ranging from 0.6‰ to 3.4‰ for δ7Li values. MICAP-MS benefits from a dielectric resonator for uniform plasma, better ion velocity control, and higher energy efficiency. Optimal settings were identified with dwell times of 10 ms for 6Li and 1 ms for 7Li. The study of LIBs revealed that 6Li migrates towards the anode over multiple charge–discharge cycles, causing 7Li to accumulate in the cathode, a fractionation effect that becomes more pronounced with prolonged cycling. MICAP-MS provides a cost-effective, precise alternative to MC-ICP-MS, with lower operational costs and enhanced portability, advancing the study of isotopic fractionation and aging in lithium-ion batteries. KW - MICAP-MS KW - Lithium KW - Battery aging KW - Lithium isotopes KW - Nitrogen plasma KW - Isotope fractionation KW - lithium cobalt oxide KW - LCO PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-643777 DO - https://doi.org/10.1039/d4ja00324a SN - 0267-9477 SP - 1 EP - 11 PB - Royal Society of Chemistry (RSC) AN - OPUS4-64377 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Morcillo, Dalia T1 - High-resolution absorption isotopic spectrometry as a tool for aging studies of Li-ion batteries N2 - Lithium (Li) is the key element in the manufacturing of batteries. Isotopic study of Li may help to identify the causes of battery aging due to isotopic fractionation during charge/discharge cycles. Isotopic ratio determination is based on monitoring the isotopic components of lithium by their spin-orbit coupling and its isotopic shift of about 15 pm for the 22P←22S electronic transition around 670.788 nm. In this work, we propose improvements to our previous work [1] by using a higher-resolution double echelle modular spectrometer (HR-DEMON II) coupled to a continuum source graphite furnace atomic absorption spectrometer (HR-CS-GF-AAS) for the isotopic analysis of Li. The data analysis was carried out by using a decision-tree-based ensemble machine learning (ML) algorithm (XGBoost). A set of samples with 6Li isotope amount fractions ranging from 0.0004 to 0.99 mol mol-1 was used for the algorithm's training. Subsequently, the procedure was validated by a set of stock chemicals (Li2CO3, LiNO3, LiCl, and LiOH) and a BAM candidate reference material, a cathode material (NMC111). Finally, the ML model was applied to determine the isotope ratio of geological samples, including anorthosite, granite, soil, rhyolite, nepheline syenite, and basalt and battery samples. These samples were measured as digested without any further purification step. Improvements in the optical resolution resolve the lithium isotopic components of the atomic spectra. In the studied geological samples, were found δ7Li values between -0.5 and 4.5 ‰ with a precision range of 1 to 2 ‰. In addition, the proposed method was validated with multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), and these results are comparable and compatible. T2 - Caltech-BAM Meeting CY - Online meeting DA - 10.08.2022 KW - Lithium isotope KW - Machine learning KW - Battery KW - High-resolution absorption isotopic spectrometry PY - 2022 AN - OPUS4-56380 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sander, Luise T1 - Multi-Scale Analysis of Commercially Available Sodium-Ion Cells N2 - As the first commercial sodium-ion-batteries (SIBs) are available for purchase, it is possible to investigate material composition. Gaining an insight into the material composition of these SIBs is of interest not only for the classification of possible safety risks and hazards, but also in regards to recycling. Herein we report the preliminary investigations of the chemical and structural composition of first commercial SIB-cells. Two different SIB-cells with different specification were compared regarding electrode size, thickness and further parameters. Furthermore, the composition of the active materials and electrolyte was investigated and compared. T2 - Solid State Ionics (SSI) CY - London, United Kingdom DA - 15.07.2024 KW - Sodium Ion-Cells KW - Multi-Scale PY - 2024 AN - OPUS4-60764 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sander, Luise A1 - Liu, Bowen A1 - Kendrick, Emma T1 - Direct recycling of Nickel-Manganese-Iron Copper-Oxide cathode material of commercial SIBs via solid state resodiation N2 - The increasing demand for alkali-metal batteries, lithium and sodium, highlights the importance of recycling approaches. For batteries which encompass low-value components such as cobalt-free and sodium-ion, a requirement for low-cost and low-energy processes for recovery and reuse. In this respect, direct recycling, is preferred where the functional structure of active materials is preserved. In this study, a direct recycling route for sodium nickel-iron-manganese-copper oxide cathode material for sodium-ion batteries was investigated and preliminary results reveal the challenges in this direct recycling approach. Commercial sodium-ion battery cells were safely disassembled in a Glovebox and the positive electrode material was extracted via ice stripping. The recovered electrode material was structurally and compositionally characterised using scanning electron microscopy (SEM), X-ray diffraction (XRD), and inductive coupled plasma optical emission spectroscopy (ICP-OES) to assess morphology, crystallinity, and elemental stoichiometry. T2 - Direct Recycling Conference CY - Würzburg, Germany DA - 02.01.2026 KW - Battery KW - Electrochemical Energy Storage KW - Energy Storage KW - Sodium-Ion-Battery PY - 2026 AN - OPUS4-65835 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Cornelio, Andrea T1 - NASICON Electrolytes for Room-Temperature Sodium Batteries N2 - Solid electrolytes (SE) allow to employ alkali-metal negative electrodes (NE) in new cell concepts, increasing energy density and safety of batteries for stationary and portable applications. The aim of this research is to develop a novel NASICON (NA Super Ionic CONductor) electrolyte for room-temperature (RT) sodium-sulfur (Na-S) cells employing a liquid sodium-potassium (Na-K) alloy at the SE/NE interface. The Na-K alloy can improve the interfacial contact between the sodium-metal NE and the SE. T2 - Einweihung Berlin Battery Lab (BBL) CY - Berlin, Germany DA - 19.03.2026 KW - NASICON KW - Solid Electrolytes KW - Interface KW - Characterization KW - Na batteries KW - Electrochemisty KW - BBL PY - 2026 AN - OPUS4-65834 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -