TY - CONF A1 - Wille, Frank T1 - Transport nach Zwischenlagerung, Besonderheiten des letzten Transports N2 - Transportierbarkeit von Transport- und Lagerbehältern für radioaktive Stoffe, welche nach eine längerfristigen trockenen Zwischenlagerung transportiert werden müssen. Überblick über die aktuellen Regelwerke und Richtlinien sowie die Zeitpläne für das Finden eines Endlagers für hochradioaktive Stoffe und die damit verbundene verlängerte Zwischenlagerung. Des Weiteren werden das für die verlängerte Zwischenlagerung notwendige Alterungsmanagement und die noch erforderlichen Forschungstätigkeiten vorgestellt. T2 - BGZ Fachworkshop Zwischenlagerung CY - Berlin, Germany DA - 16.11.2021 KW - Transportbehälter KW - Radioaktive Stoffe KW - Transport KW - Zwischenlagerung KW - IAEA PY - 2021 AN - OPUS4-60505 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bonse, Jörn T1 - Laser-induced periodic surface structures: When electromagnetics drives hydrodynamics N2 - Laser-induced Periodic Surface Structures (LIPSS, ripples) are a universal phenomenon and can be generated in a contactless, single-step process on almost any material upon irradiation of solids with intense laser radiation. Nowadays processing rates of up to m^2/min are enabling new industrial applications in medicine, optics, tribology, biology, etc. Depending on the specific type of LIPSS, their structural sizes typically range from several micrometers down to less than 100 nanometers – far beyond the optical diffraction limit – while their orientations exhibit a clear correlation with the local polarization direction of the laser radiation. From a theoretical point of view, however, a vivid, controversial, and long-lasting debate has emerged during the last two decades, whether LIPSS originate from electromagnetic effects (seeded already during the laser irradiation) – or whether they emerge from matter reorganization processes (distinctly after the laser irradiation). This presentation reviews the currently existent theories of LIPSS. A focus is laid on the historic development of the fundamental ideas, their corresponding mathematical descriptions and numerical implementations, along with a comparison and critical assessment of the different approaches. T2 - 28th International Conference on Advanced Laser Technologies (ALT'21) CY - Online meeting DA - 06.09.2021 KW - Laser-induced periodic surface structures, LIPSS KW - Electromagnetic scattering KW - Matter reorganization PY - 2021 DO - https://doi.org/10.24412/cl-35039-2021-21-25-25 AN - OPUS4-53218 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Florian, Camilo T1 - Femtosecond laser-induced oxidation in the formation of periodic surface structures N2 - Laser-induced oxide graded layers may contribute to the formation of a new type of embedded low-spatial frequency LIPSS with an anomalous orientation parallel to the laser polarization. In this contribution, we explore this effect experimentally with femtosecond laser pulses and numerically by finite-difference time-domain (FDTD) calculations. T2 - 2021 Conference on Lasers and Electro-Optics/Europe – European Quantum Electronics Virtual Conferences CY - Online meeting DA - 21.06.2021 KW - Laser-induced periodic surface structures (LIPSS) KW - Surface oxidation KW - Femtosecond laser ablation KW - Finite-difference time-domain calculations PY - 2021 AN - OPUS4-52859 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Florian, Camilo T1 - Silicon surface amorphization and re-crystallization via single femtosecond laser pulses N2 - Silicon is the material responsible for most of the technological developments during the past century, making it one of the most studied materials along different disciplines. However, there are still unturned stones regarding its superficial re-solidification after femtosecond laser-induced local melting. In this presentation, we report irradiation experiments with single femtosecond pulses (790 nm, 30 fs) with a spatially Gaussian distribution on two different types of silicon with orientations <111> and <100>. The surface modifications were studied in detail via different techniques, including optical microscopy, atomic force microscopy, spectroscopic imaging ellipsometry, energy dispersive X-ray spectroscopy and high-resolution transmission electron microscopy. We quantitatively estimate the resulting radial amorphous layer depth profiles with maximum thicknesses around some tenths of nanometers for fluences in between the melting and ablation thresholds. In particular, spectroscopic imaging ellipsometry (SIE) allowed fast data acquisition using multiple wavelengths to provide experimental measurements for calculating the nanometric radial amorphous layer thickness profiles with micrometric lateral resolution based on a thin-film layer model. SIE proved to be capable of detecting and measuring nanometric structural and chemical modifications (oxidation) on the studied laser spots. The accuracy of the SIE-based calculations is verified experimentally by characterizing an in-depth material lamella via high-resolution transmission electron microscopy (HRTEM) and energy dispersive X-ray spectroscopy (STEM-EDX). For completeness, we present a mathematical modelling for the melt layer thickness considering different optical absorption processes including one photon absorption, two photon absorption and free-carrier absorption, highlighting the relevance of the latter one in the femtosecond laser-induced melting of silicon. T2 - 28th International Conference on Advanced Laser Technologies (ALT'21) CY - Online meeting DA - 06.09.2021 KW - Silicon KW - Femtosecond laser KW - Phase transitions KW - Spectroscopic imaging ellipsometry KW - Transmission electron microscopy PY - 2021 AN - OPUS4-53235 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bonse, Jörn T1 - Surface oxidation accompanying the formation of various types of femtosecond laser-generated surface structures on titanium alloy N2 - Different types of laser-generated surface structures, i.e., Laser-induced Periodic Surface Structures (LIPSS, ripples), Grooves, and Spikes are generated on titanium and Ti6Al4V surfaces by means of femtosecond (fs) laser scan processing (790 nm, 30 fs, 1 kHz) in ambient air. Morphological, chemical and structural properties of the different surface structures are characterized by various surface analytical techniques, including scanning electron microscopy (SEM), X-ray diffraction (XRD), Glow discharge optical emission spectroscopy (GD-OES), and depth-profiling Auger electron spectroscopy (AES). It is revealed that the formation of near-wavelength sized LIPSS is accompanied by the formation of a graded oxide extending several tens to a few hundreds of nanometers into depth. GD-OES performed on other superficial fs-laser generated structures produced at higher fluences and effective number of pulses per spot area such as periodic Grooves and irregular Spikes indicate even thicker graded oxide layers. These graded layers may be suitable for applications in prosthetics or tribology. T2 - E-MRS Spring Meeting 2021 CY - Online meeting DA - 31.05.2021 KW - Laser-induced periodic surface structures (LIPSS) KW - Titanium alloy KW - Oxidation KW - Glow-discharge optical emission spectroscopy PY - 2021 AN - OPUS4-52749 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bonse, Jörn T1 - The role of electromagnetic scattering in the formation of laser-induced periodic surface structures N2 - Laser-induced periodic surface structures (LIPSS) are a universal phenomenon that is accompanying laser materials processing. These surface nanostructures pave a simple way for surface functionalization with numerous applications in optics, fluidics, tribology, medicine, etc. During the last decade remarkable experimental and theoretical improvements in understanding of their formation mechanisms were obtained - all pointing toward polarization-dependent energy deposition by absorption of optical radiation that is scattered at the surface roughness and interfering with the laser beam. This contribution reviews the current state-of-the-art on the role of electromagnetic scattering in the formation of LIPSS by ultrashort laser pulses. Special attention is drawn to recent finite-difference time-domain (FDTD) calculations that allow to visualize the radiation patterns formed in the vicinity of the sample surface and to the impact of a thin superficial laser-induced oxidation layer. T2 - E-MRS Spring Meeting 2021 CY - Online meeting DA - 31.05.2021 KW - Laser-induced periodic surface structures (LIPSS) KW - Optical scattering KW - Oxidation KW - Femtosecond laser PY - 2021 AN - OPUS4-52729 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Angurel, L.A. T1 - Effects of laser surface processing under different atmospheres on the superconducting properties of pure niobium N2 - Niobium metal is the pure element with the highest superconducting critical temperature (T_c = 9.2 K), which is present in many applications. Particularly, in superconducting radio frequency (SRF) cavities of particle accelerators, the control of the surface characteristics of pure Nb is crucial, as the presence of defects may generate magnetic flux pinning that can increase by more than two orders of magnitude the surface critical current, ic. Several procedures such as chemical- or electro-polishing have been used aiming at cleaning surface contamination and decreasing its roughness. Sub-nanosecond lasers can be applied to generate a broad range of micro and nanostructures (e.g. Laser-Induced Periodic Surface Structures, LIPSS) that strongly modify the materials properties - as wettability, color, oxidation resistance or antibacterial behavior. In this work, we analyze a variety of surface structures generated on pure Nb sheets with different laser systems (UV, Vis and n-IR, fs and ps) by exploring a range of processing parameters. These include pulse overlap, irradiance or the effective number of pulses, under different atmospheres (air, N2, Ar, vacuum). The effects on Tc, critical currents and critical fields (Bc1, Bc2 and Bc3) have been obtained from magnetization, ac susceptibility and heat capacity measurements, revealing their dependence with the different surface nanostructures and the chemical changes generated with these laser treatments. T2 - E-MRS Spring Meeting 2021 CY - Online meeting DA - 31.05.2021 KW - Laser-induced periodic surface structures (LIPSS) KW - Femtosecond laser ablation KW - Niobium KW - Superconductivity PY - 2021 AN - OPUS4-52730 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Simon, P. A1 - Ihlemann, J. A1 - Bonse, Jörn T1 - Editorial: Special issue "Laser-generated periodic nanostructures" N2 - The study of laser-fabricated periodic nanostructures is one of the leading topics of today’s photonics research. Such structures on the surface of metals, semiconductors, dielectrics, or polymers can generate new material properties with special functionalities. Depending on the specific material parameters and the morphology of the structures, new devices such as microlasers, optical nanoswitches, optical storage devices, sensors or antifraud features can be realized. Furthermore, laser-generated surface textures can be used to improve the tribological properties of surfaces in contact and in relative motion—to reduce friction losses or wear, to modify the wettability or the cell and biofilm growth properties of surfaces through bioinspired laser engineering, for emerging medical applications, or as decoration elements for the refinement of precious goods. This Special Issue “Laser-Generated Periodic Nanostructures” focuses on the latest experimental and theoretical developments and practical applications of laser-generated periodic structures that can be generated in a “self-organized” way (laser-induced periodic surface structures, LIPSS, ripples) or via laser interference-based direct ablation (often referred to as direct laser interference patterning, DLIP). We aimed to attract both academic and industrial researchers in order to collate the current knowledge of nanomaterials and to present new ideas for future applications and new technologies. By 8 August 2021, 22 scientific articles have been published in the Special Issue, see www.mdpi.com/journal/nanomaterials/special_issues/laser-generated_periodic. KW - Laser-induced periodic surface structures (LIPSS) KW - Direct laser interference patterning (DLIP) KW - Surface functionalization KW - Laser ablation PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-530980 DO - https://doi.org/10.3390/nano11082054 SN - 2079-4991 VL - 11 IS - 8 SP - 1 EP - 7 PB - MDPI CY - Basel AN - OPUS4-53098 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schneider, Ronald T1 - SysPark: a software tool for system-wide adaptive planning of inspections of turbine support structures in offshore wind farms N2 - Fatigue is one of the main deterioration processes affecting the performance of welded steel support structures of wind turbines in offshore wind farms. In this contribution, we present a probabilistic physics-based fatigue deterioration model of a wind farm that accounts for the stochastic dependence among the fatigue behavior of different hotspots at turbine and wind farm level. The dependence exists because of uncertain common influencing factors such as similar material properties, fabrication qualities and load conditions. These system effects signify that an inspection of one hotspot provides indirect information of the condition of the remaining hotspots and thus enable an optimization of the inspection effort for a wind farm. The wind farm model consists of two levels: A turbine support structure (level 1 system model) is represented by its fatigue hotspots and their stochastic dependence. The fatigue performance of a hotspot is described by a probabilistic fracture mechanics (FM) fatigue model. The probabilistic model of the parameters of the FM fatigue model is calibrated based on design data and is thus directly linked to the design of the turbine support structures. Dependence among the fatigue performances of different hotspots in a turbine support structure is modeled by introducing correlations between the stochastic parameters of the FM fatigue models. A wind farm (level 2 system model) consists of different turbine support structures (level 1 system models). Additional correlations are introduced at wind farm level to account for the dependence among the fatigue behavior of hotspots belonging to different turbine support structures. The wind farm model enables the computation of (marginal) hotspot fatigue reliabilities, system fatigue reliabilities of individual turbine support structures and the system fatigue reliability of an entire wind farm. The probabilistic model of the parameters of the two-level system model can be consistently updated with inspection outcomes using Bayesian methods. The updated probabilistic model of the model parameters then forms the basis for updating the estimates of the fatigue reliabilities. We implement the wind farm model in a software tool named SysPark. The tool provides the means for planning inspections at wind farm level using an adaptive reliability-based threshold approach. In this approach, the first inspection campaign is planned in the year before the fatigue failure rates of the hotspots with the lowest fatigue reliabilities exceed a threshold failure rate. Once inspection results become available, the probabilistic model of the parameters of the wind farm model is updated. If repairs are performed, the wind farm model is additionally modified to describe the behavior of the repaired hotspots. The updated and modified model then enables the planning of the next inspection campaign and so on. The software tool is demonstrated in a case study considering a generic wind farm consisting of turbines with jacket support structures. T2 - Wind Energy Science Conference (WESC 2021) CY - Online Meeting DA - 25.05.2021 KW - Fatigue deterioration KW - Offshore wind farm KW - Inspection planning PY - 2021 AN - OPUS4-52767 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bonse, Jörn A1 - Gräf, S. T1 - Ten Open Questions about Laser-Induced Periodic Surface Structures N2 - Laser-induced periodic surface structures (LIPSS) are a simple and robust route for the nanostructuring of solids that can create various surface functionalities featuring applications in optics, medicine, tribology, energy technologies, etc. While the current laser technologies already allow surface processing rates at the level of m2/min, industrial applications of LIPSS are sometimes hampered by the complex interplay between the nanoscale surface topography and the specific surface chemistry, as well as by limitations in controlling the processing of LIPSS and in the long-term stability of the created surface functions. This Perspective article aims to identify some open questions about LIPSS, discusses the pending technological limitations, and sketches the current state of theoretical modelling. Hereby, we intend to stimulate further research and developments in the field of LIPSS for overcoming these limitations and for supporting the transfer of the LIPSS technology into industry. KW - Laser-induced periodic surface structures (LIPSS) KW - Industrial application KW - Functional properties KW - Surface functionalization KW - Modelling PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-539503 DO - https://doi.org/10.3390/nano11123326 SN - 2079-4991 VL - 11 IS - 12 SP - 1 EP - 21 PB - MDPI CY - Basel, Switzerland AN - OPUS4-53950 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN ED - Simon, P. ED - Ihlemann, J. ED - Bonse, Jörn T1 - Laser-generated periodic nanostructures N2 - This book is a reprint collection of articles from the Special Issue published online in the open access journal Nanomaterials. KW - Laser-induced periodic surface structures (LIPSS) KW - Direct laser-interference patterning (DLIP) KW - Applications KW - Numerical simulations PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-535146 UR - https://www.mdpi.com/books/pdfview/book/4426 SN - 978-3-0365-2027-8 SN - 978-3-0365-2028-5 DO - https://doi.org/10.3390/books978-3-0365-2028-5 SP - 1 EP - 328 PB - MDPI CY - Basel AN - OPUS4-53514 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weise, Frank A1 - Müller, U. A1 - Hüsken, Götz A1 - Gardei, Andre T1 - Begutachtung Berliner Tuffsteinfassaden - Turmruine der Kaiser-Wilhelm-Gedächtniskirche und Charlottenburger Tor N2 - Am Ende des 19. und zu Beginn des 20. Jahrhunderts wurden auch in Berlin vermehrt Bauwerke mit einer Fassadenverblendung aus Eifeler Tuffsteinen errichtet. Die Eifeler Tuffsteine zeichnen sich aufgrund ihrer hohen Porosität einerseits durch eine gute Verarbeitbarkeit aus. Andererseits sind sie nur schwach gebunden und besitzen deshalb eine geringe Verwitterungsbeständigkeit. T2 - Workshop Kulturguterhaltung - Vom Dampfkessel zu Nanomaterialien CY - Berlin, Germany DA - 17.11.2021 KW - Fassade KW - Tuffstein KW - Schalenbildung PY - 2021 SN - 2567-1251 VL - 3 SP - 107 EP - 123 PB - Druckerei G. Bohm CY - Berlin AN - OPUS4-54461 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - THES A1 - Kraus, David T1 - Ermüdungsverhalten von Glasfaser-Kunststoff-Verbunden unter thermomechanischer Beanspruchung N2 - Die Werkstoffgruppe der Faser-Kunststoff-Verbunde (FKV) hat sich aufgrund ihrer hervorragenden Leichtbaueigenschaften unter anderem im Sportgerätebau, in der Luft- und Raumfahrt und in der Windenergieindustrie etabliert. Die so hergestellten Strukturen sind in der Regel nicht nur mechanischen Belastungen, sondern auch thermischen Lasten in einem breiten Temperaturspektrum ausgesetzt. Dennoch ist die Auswirkung des Temperatureinflusses bei einer Kombination von thermischer und mechanischer Last auf die Lebensdauer von Strukturen aus FKV bisher nur wenig untersucht. Im Rahmen dieser Arbeit wird der Einfluss von Temperaturen zwischen 213 K und 343 K auf einen Glasfaser-Epoxidharz-Verbund experimentell untersucht. Das Material wird in diesem Temperaturbereich eingehend charakterisiert: Es werden sowohl die thermomechanischen Eigenschaften von Faser- und Matrixwerkstoff als auch die des Verbundes ermittelt. In einem weiteren Schritt wird dann der Einfluss der Temperatur auf die Schädigungsentwicklung im quasi-statischen Lastfall sowie unter schwingender Ermüdungsbeanspruchung bei verschiedenen FKV-Mehrschichtverbunden analysiert. Basierend auf den experimentellen Daten wird ein Zusammenhang zwischen der Schädigung und der Anstrengung der Matrix innerhalb der Einzelschicht demonstriert. Die Matrixanstrengung wird mithilfe eines mikromechanischen Modells unter Berücksichtigung der thermomechanischen Eigenspannungen analytisch berechnet. Bei Querzugbeanspruchung kann gezeigt werden, dass eine Vorhersage der Schädigung in Abhängigkeit der Volumenänderungsenergie innerhalb der Matrix getroffen werden kann. Mithilfe des Konzepts der Matrixanstrengung ist eine Vorhersage der Lebensdauer des Werkstoffs unter schwingender Ermüdungsbeanspruchung in Abhängigkeit der Einsatztemperatur möglich. N2 - Due to their superior lightweight properties, fiber reinforced polymer (FRP) materials are well established in various fields, such as sports equipment, aerospace or wind energy structures. These structures are not only subjected to mechanical loads, but also to a broad spectrum of thermal environments. However, the impact of temperature on the fatigue life of thermomechanically loaded FRP structures is barely investigated to-date. In the scope of this work, the influence of temperatures in a range of 213 K to 343 K on a glass fiber reinforced epoxy polymer is experimentally examined. An extensive thermo-mechanical characterization of the static properties of the material is performed. The neat resin and Fiber material are investigated, as well as the composite. In addition, the impact of thermal loads on the damage evolution under quasi-static as well as cyclic fatigue loading is investigated for different multi-angle laminates. Based on the experimental data, a correlation is shown between damage and matrix effort of the unidirectional layer. The matrix effort is calculated according to a micromechanical model considering thermal residual stresses. Particularly under transverse loading, the damage Evolution can be predicted as a function of the dilatational strain energy of the matrix. Using the concept of the matrix effort presented in this work, a prediction of the fatigue life of the investigated material at different ambient temperature conditions can be performed. T3 - BAM Dissertationsreihe - 169 KW - Ermüdung KW - Faser-Kunststoff-Verbund KW - GFK KW - Schädigung KW - Thermomechanik KW - Fatigue KW - Composite KW - Glas fibre reinforced polymer KW - Damage KW - Thermomechanics PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-530253 SN - 1613-4249 VL - 169 SP - 1 EP - 164 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-53025 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Bonse, Jörn A1 - Kirner, Sabrina V. A1 - Krüger, Jörg ED - Sugioka, K. T1 - Laser-Induced Periodic Surface Structures (LIPSS) N2 - Laser-induced periodic surface structures (LIPSS) are a universal phenomenon and can be generated on almost any material by irradiation with linearly polarized radiation. This chapter reviews the current state in the field of LIPSS, which are formed in a “self-ordered” way and are often accompanying materials processing applications. LIPSS can be produced in a single-stage process and enable surface nanostructuring and, in turn, adaption of optical, mechanical, and chemical surface properties. Typically, they feature a structural size ranging from several micrometers down to less than 100 nm and show a clear correlation with the polarization direction of the light used for their generation. Various types of LIPSS are classified, relevant control parameters are identified, and their material-specific formation mechanisms are analyzed for different types of inorganic solids, i.e., metals, semiconductors, and dielectrics. Finally, technological applications featuring surface functionalization in the fields of optics, fluidics, medicine, and tribology are discussed. KW - Laser-induced periodic surface structures (LIPSS) KW - Femtosecond laser KW - Laser ablation KW - Microstructures KW - Nanostrcutures PY - 2021 SN - 978-3-030-63646-3 (Print) SN - 978-3-030-63647-0 (Online) DO - https://doi.org/10.1007/978-3-030-63647-0_17 SP - 879 EP - 936 PB - Springer-Nature Switzerland AG CY - Cham ET - 1 AN - OPUS4-53728 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR ED - Simon, P. ED - Ihlemann, J. ED - Bonse, Jörn T1 - Special issue "Laser-generated periodic nanostructures" N2 - The study of laser-fabricated periodic nanostructures is one of the leading topics of today’s photonics research. Such structures on the surface of metals, semiconductors, dielectrics, or polymers can generate new material properties with special functionalities. Depending on the specific material parameters and the morphology of the structures, new devices such as microlasers, optical nanoswitches, optical storage devices, sensors or antifraud features can be realized. Furthermore, laser-generated surface textures can be used to improve the tribological properties of surfaces in contact and in relative motion—to reduce friction losses or wear, to modify the wettability or the cell and biofilm growth properties of surfaces through bioinspired laser engineering, for emerging medical applications, or as decoration elements for the refinement of precious goods. This Special Issue “Laser-Generated Periodic Nanostructures” focuses on the latest experimental and theoretical developments and practical applications of laser-generated periodic structures that can be generated in a “self-organized” way (laser-induced periodic surface structures, LIPSS, ripples) or via laser interference-based direct ablation (often referred to as direct laser interference patterning, DLIP). We aimed to attract both academic and industrial researchers in order to collate the current knowledge of nanomaterials and to present new ideas for future applications and new technologies. By 8 August 2021, 22 scientific articles have been published in the Special Issue. KW - Laser-induced periodic surface structures (LIPSS) KW - Direct laser-interference patterning (DLIP) KW - Surface functionalization KW - Laser processing KW - Applications PY - 2021 UR - https://www.mdpi.com/journal/nanomaterials/special_issues/laser-generated_periodic SN - 2079-4991 VL - 10(1)-11(8) SP - 147-1 EP - 2054-7 PB - MDPI CY - Basel AN - OPUS4-53099 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weise, Frank A1 - Patitz, G. A1 - Redmer, B. A1 - Hübner, M. T1 - Zerstörungsfreie Strukturaufklärung antiker Baudenkmäler des Pergamonmuseums N2 - Das Pergamonmuseum ist eines der am meisten besuchten Museen Berlins. Es wird seit etwa 20 Jahren im Rahmen des 1999 von der Stiftung Preußischer Kulturbesitz beschlossenen Masterplans Museumsinsel schrittweise grundhaft instandgesetzt und um einen weiteren Flügel ergänzt, der 2025 fertig gestellt sein soll. In diesem Kontext wurde auch kurz nach dem Beschluss des Masterplans eine Bauzustandsanalyse an den in Originalgröße in der Antikensammlung ausgestellten Baudenk¬ mälern durchgeführt. Allerdings stellte man dabei fest, dass herkömmliche Erkundungsverfahren wie die Bauaufnahme, die baugeschichtliche Untersu¬ chung, das Quellenstudium sowie die äußerliche Begutachtung nicht ausreichen, um die innere Struktur der antiken Baudenkmäler hinreichend zu charakterisieren. Deshalb wurde die BAM im Jahr 2003 von der ARGE Pfanner Pergamonmuseum beauftragt, in enger Zusammenarbeit mit zwei Ingenieurbüros, dem Ingenieurbüro Patitz (IGP) und der Gesellschaft für geophysikalische Unter¬ suchungen mbH (GGU) unter Hinzuziehung einer Restauratorin, die innere Struktur ausgewählter an¬ tiker Baudenkmäler zerstörungsfrei zu untersuchen. Das Ziel der zerstörungsfreien Strukturaufklärung zum inneren Aufbau der Bauteile war es, einerseits sicherheitsrelevante Informationen für die statische Nachweisführung bereitzustellen, sowie andererseits eine Planungsgrundlage für die eventuell erforder¬ liche Ertüchtigung der Baudenkmäler zu schaffen. Im Fokus der Untersuchungen standen dabei das Markttor von Milet und das Säulenjoch der Heiligen Halle am Markt von Priene1 • Im nachstehenden Beitrag werden exemplarisch die am Markttor von Milet durchgeführten Untersuchungen vorgestellt. T2 - Workshop Kulturguterhaltung - Vom Dampfkessel zu Nanomaterialien CY - Berlin, Germany DA - 17.11.2021 KW - Bauzustandsanalyse KW - Radar KW - Radiografie PY - 2021 SN - 2567-1251 VL - 3 SP - 47 EP - 57 PB - Druckerei G. Bohm CY - Berlin AN - OPUS4-54460 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael A1 - Kannengießer, Thomas T1 - Fügetechnik in Wasserstofftechnologien - Forschungsbedarf für die Branche (Kurzversion) N2 - Die Studie gibt einen kurzen Überblick über die jetzige Bedeutung der Fügetechnik in Wasserstofftechnologien und über zukünftige Forschungsbedarfe für die Branche in den einzelnen Technologiefeldern Wasserstofferzeugung, -speicherung, -transport und -nutzung. Fügetechnologien haben dabei wesentliche Bedeutung für die erfolgreiche Umsetzung von technischen Komponenten der Wasserstofftechnologien. Die Schwerpunkte bzw. Forschungsbedarfe ergeben sich bspw. durch die Erstellung neuer Infrastruktur für Wasserstoffspeicherung und -transport sowie durch Umnutzung der bestehenden Erdgasinfrastruktur. Bei der Wasserstofferzeugung und -anwendung wird z.B. die Entwicklung effiziente Massenproduktionsmethoden von Elektrolyseuren und Brennstoffzellen einen wichtigen Meilenstein bilden und laserbasierte Fügetechnologien sind hier zum Teil schon etabliert. Die additive Fertigung nimmt dabei eine Querschnittsposition ein und besitzt hohes Anwendungspotential für die Zukunft z.B. für die Fertigung von Komponenten in Gasturbinen. Aus den technischen Fragestellungen und Forschungsbedarfen ergeben sich zudem Herausforderungen für die notwendige Neu- und Weiterentwicklung von technischen Regelwerken und Normen und den Eingang in die Aus- und Weiterbildung von fügetechnischem Fachpersonal. T2 - DVS Congress 2021 CY - Online meeting DA - 14.09.2021 KW - Wasserstoff KW - Fügetechnik KW - Forschung KW - Werkstoff KW - Bedarf PY - 2021 SN - 978-3-96144-146-4 VL - 371 SP - 612 EP - 624 PB - DVS Media GmbH CY - Düsseldorf AN - OPUS4-53370 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zorn, R. A1 - Szymoniak, Paulina A1 - Kolmangadi, Mohamed Aejaz A1 - Malpass-Evans, R. A1 - McKeown, N. A1 - Tyagi, M. A1 - Böhning, Martin A1 - Schönhals, Andreas T1 - Low frequency vibrations and diffusion in disordered polymers bearing an intrinsic microporosity as revealed by neutron scattering N2 - The microscopic diffusion and the low frequency density of states (VDOS) of PIM-EATB(CH3) are investigated by inelastic and quasi-elastic neutron scattering where also the demethylated counterpart of PIM-EA-TB(H2) is considered. These intrinsic microporous polymers are characterized by large BET surface area values of several hundred m2/g and pore sizes between 0.5 and 2 nm. Detailed comparison is made to the archetype of polymers of intrinsic microporosity, PIM-1, and polynorbornenes also bearing a microporosity. Due to the wavelength of neutrons, the diffusion and vibrations can be addressed on microscopic length and time scales. From the inelastic neutron scattering experiments the low frequency density of states (VDOS) is estimated which shows excess contributions to the Debye-type VDOS known as Boson peak. It was found that the maximum frequency of the Boson peak decreases with increasing microporosity characterized by the BET surface area. However, besides the BET surface area, additional factors such as the backbone stiffness govern the maximum frequency of the Boson peak. Further the mean squared displacement related to microscopic motions was estimated from elastic fixed window scans. At temperatures above 175 K, the mean squared displacement PIM-EA-TB(CH3) is higher than that for the demethylated counterpart PIM-EA-TB(H2). The additional contribution found for PIM-EATB(CH3) is ascribed to the rotation of the methyl group in this polymer because the only difference between the two structures is that PIM-EA-TB(CH3) has methyl groups where PIM-EA-TB(H2) has none. A detailed comparison of the molecular dynamics is also made to that of PIM-1 and the microporous polynorbornene PTCNSi1. The manuscript focuses on the importance of vibrations and the localized molecular mobility characterized by the microscopic diffusion on the gas Transport in polymeric separation membranes. In the frame of the random gate model localized fluctuations can open or close bottlenecks between pores to enable the diffusion of gas molecules. KW - Polymer of intrisic microporosity KW - Neutron scattering KW - Boson peak KW - Methyl group rotation PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-538490 DO - https://doi.org/10.3390/cryst11121482 VL - 11 IS - 12 SP - 1 EP - 16 PB - MDPI CY - Basel AN - OPUS4-53849 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maiwald, Michael T1 - Messverfahren für Wasserstoff: Qualität durch Zertifizierung – Standortvorteile in Deutschland N2 - Die Veranstaltungsreihe "Neue Märkte erschließen – mit Normen und Standards hoch hinaus", die vom DIN gemeinsam mit der NOW GmbH organisiert wird, richtets sich vorwiegend an KMUs. Fokus der Veranstaltung sind Messverfahren für Wasserstoff. Der Beitrag der BAM führt sehr kurz die Rolle nationaler und internationaler Normung sowie weltweiter Metrologie im Rahmen der Meterkonvention bezüglich analytischer Qualitätssicherung und Zertifizierung von Gasen und Referenzmaterialien ein. Es werden aktuelle Beispiele für die Qualitätssicherung von Wasserstoff, mögliche dazu notwendige Ausrüstung und weiterführende Literaturquellen vorgestellt. T2 - Neue Märkte erschließen – mit Normen und Standards hoch hinaus CY - Online meeting DA - 18.03.2021 KW - Wasserstoff KW - Normung KW - Standortvorteil KW - Analytik KW - Wasserstoffanalytik KW - Wasserstoff Referenzmaterial KW - Gasanalytik PY - 2021 AN - OPUS4-52296 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tuma, Dirk A1 - Lozano-Martín, D. A1 - Vega-Maza, D. A1 - Moreau, A. A1 - Martín, M. C. A1 - Segovia, J. J. T1 - Speed of sound data, derived perfect-gas heat capacities, and acoustic virial coefficients of a calibration standard natural gas mixture and a low-calorific H2-enriched mixture N2 - This work aims to address the technical aspects related to the thermodynamic characterization of natural gas mixtures blended with hydrogen for the introduction of alternative energy sources within the Power-to-Gas framework. For that purpose, new experimental speed of sound data are presented in the pressure range between (0.1 up to 13) MPa and at temperatures of (260, 273.16, 300, 325, and 350) K for two mixtures qualified as primary calibration standards: a 11 component synthetic natural gas mixture (11 M), and another low-calorific H2-enriched natural gas mixture with a nominal molar percentage x(H2) = 3 %. Measurements have been gathered using a spherical acoustic resonator with an experimental expanded (k = 2) uncertainty better than 200 parts in 106 (0.02 %) in the speed of sound. The heat capacity ratio as perfect-gas gammapg, the molar heat capacity as perfect-gas Cp,m pg, and the second betaa and third gammaa acoustic virial coefficients are derived from the speed of sound values. All the results are compared with the reference mixture models for natural gas-like mixtures, the AGA8-DC92 EoS and the GERG-2008 EoS, with Special attention to the impact of hydrogen on those properties. Data are found to be mostly consistent within the model uncertainty in the 11 M synthetic mixture as expected, but for the hydrogen-enriched mixture in the limit of the model uncertainty at the highest measuring pressures. KW - Natural gas mixtures KW - Speed-of-sound measurements KW - Equations of state KW - Acoustic virial coefficients PY - 2021 DO - https://doi.org/10.1016/j.jct.2021.106434 SN - 0021-9614 VL - 158 SP - 106434 PB - Elsevier Ltd. CY - Amsterdam AN - OPUS4-52292 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lay, Vera A1 - Baensch, Franziska A1 - Johann, Sergej A1 - Sturm, Patrick A1 - Mielentz, Frank A1 - Prabhakara, Prathik A1 - Hofmann, Detlef A1 - Niederleithinger, Ernst A1 - Kühne, Hans-Carsten T1 - SealWasteSafe: materials technology, monitoring techniques, and quality assurance for safe sealing structures in underground repositories N2 - Within the project SealWasteSafe, we advance construction materials and monitoring concepts of sealing structures applied for underground disposal of nuclear or toxic waste. As these engineered barriers have high demands concerning integrity, an innovative alkali-activated material (AAM) is improved and tested on various laboratory scales. This AAM has low reaction kinetics related to a preferential slow release of the heat of reaction in comparison to alternative salt concretes based on Portland cement or magnesium oxychloride cements. Hence, crack formation due to thermally induced strain is reduced. After successful laboratory scale analysis (Sturm et al., 2021), the AAM is characterised on a larger scale by manufacturing test specimens (100–300 L). Conventional salt concrete (DBE, 2004) and the newly developed AAM are compared using two specimen geometries, i.e. cylindrical and cuboid. A comprehensive multisensor monitoring scheme is developed to compare the setting process of AAM and salt concrete for these manufactured specimens. The analysed parameters include temperature and humidity of the material, acoustic emissions, and strain variations. Passive sensor systems based on radiofrequency identification technology (RFID) embedded in the concrete, enable wireless access to temperature and humidity measurements and are compared to conventional cabled systems. Additionally, fibre-optic sensors (FOS) are embedded to record strain, but also have potential to record temperature and moisture conditions. Part of this project aims at demonstrating the high reliability of sensors and also their resistance to highly alkaline environments and to water intrusion along cables or at sensor locations. Further technical improvements were implemented so that first results clearly show the scalability of the setting process from previous small-scale AAM experiments and particularly the high potential of the newly developed approaches. Furthermore, ultrasonic methods are used for quality assurance to detect obstacles, potential cracks and delamination. On the one hand, both active and passive ultrasonic measurements complement the results obtained from the multisensor monitoring scheme for the produced specimens. On the other hand, the unique large aperture ultrasonic system (LAUS) provides great depth penetration (up to nearly 10 m) and can thus be applied at in situ sealing structures built as a test site in Morsleben by the Federal Company for Radioactive Waste Disposal (Bundesgesellschaft für Endlagerung, BGE) as shown by Effner et al. (2021). An optimised field lay-out identified from forward modelling studies and advanced imaging techniques applied to the measured data will further improve the obtained results. To characterise the inside of the test engineered barrier and achieve a proof-of-concept, an ultrasonic borehole probe is developed to enable phased arrays that can further improve the detection of potential cracks. Modelling results and first analysis of semispherical specimens confirmed the reliability of the directional response caused by the phased arrays of the newly constructed ultrasonic borehole probe. Overall, the project SealWasteSafe improves the construction material, multisensor monitoring concepts and ultrasonics for quality assurance. This will help to develop safe sealing structures for nuclear waste disposal. The outcomes are particularly valuable for salt as a host rock but partly also transferrable to alternative conditions. T2 - Safe ND Interdisciplinary research symposium on the safety of nuclear disposal practices CY - Berlin, Germany DA - 10.11.2021 KW - Borehole probe KW - SealWasteSafe KW - Engineered barrier KW - Materials technology KW - Monitoring KW - AAM KW - Ultrasound PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-539172 DO - https://doi.org/10.5194/sand-1-127-2021 VL - 1 SP - 127 EP - 128 PB - Copernicus AN - OPUS4-53917 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mielentz, Frank A1 - Stolpe, Heiko A1 - Effner, Ute A1 - Behrens, Matthias A1 - Bernstein, Thomas A1 - Niederleithinger, Ernst T1 - Entwicklung einer Bohrlochsonde für Ultraschalluntersuchungen an Abschlussbauwerken in Endlagern N2 - Für die Qualitätssicherung von Abschlusswerken für Endlager wird eine Ultraschall-Bohrlochsonde entwickelt. Mithilfe dieser Sonde, die aus einer Vielzahl von einzelnen koppelmittelfreien Ultraschall-Punktkontaktprüfköpfen besteht, soll die Rissfreiheit der Versuchsbauwerke überprüft werden. Ein erster Prototyp der Sonde wurde mit einem kommerziellen Ultraschallgerät betrieben und bestand aus 12 Transversalwellen-Punktkontaktprüfköpfen von denen jeweils sechs als Sender und sechs als Empfänger parallelgeschaltet waren. Um den erzeugten Schalldruck der Bohrlochsonde zu steigern, wurde bei der Neuentwicklung die Prüfkopfanzahl erhöht und zusätzlich die laufzeitgesteuerte Anregung der einzelnen Prüfköpfe vorgesehen. Für die Anregung der Prüfköpfe mit programmierten Zeitverzögerungen wurde ein neuartiger mehrkanaliger Sender für bipolare Rechtecksignale entwickelt. Durch die Entwicklung der Bohrlochsonde soll eine dynamische Anpassung der Prüfkopf-Apertur sowie eine Fokussierung des Schallfeldes in Abhängigkeit der zu untersuchenden Tiefe erfolgen. Mithilfe entsprechender Anregungsfunktionen kann das Schallfeld der Bohrlochsonde unterschiedlich geformt werden, z. B. ist auch ein Schwenken des fokussierten Schallbündels möglich. Dadurch wird das erfasste Prüfvolumen begrenzt und auf diese Weise das Signal-Störverhältnis der Empfangssignale verbessert. In Kombination mit SAFT-Rekonstruktionsrechnungen wird durch eine optimierte Abstrahlcharakteristik der Sonde mit einem hohen Schalldruck unter verschiedenen Winkeln eine verbesserte Signalqualität und damit eine erhöhte Aussagesicherheit der Ergebnisse in der Objektabbildung erwartet. T2 - DGZfP-Jahrestagung 2021 CY - Online meeting DA - 10.05.2021 KW - Abdichtbauwerk KW - Bohrlochsonde KW - Ultraschall-Echoverfahren KW - Verschlussbauwerk KW - Zerstörungsfreie Prüfung KW - Ultraschall-Messtechnik PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-526746 UR - https://jahrestagung.dgzfp.de/portals/jt2021/bb176/inhalt/poster.htm SN - 978-3-947971-18-3 VL - 176 SP - 1 EP - 7 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) CY - Berlin AN - OPUS4-52674 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Büttner, C. A1 - Niederleithinger, Ernst A1 - Buske, S. A1 - Friedrich, C. T1 - Ultrasonic Echo Localization Using Seismic Migration Techniques in Engineered Barriers for NuclearWaste Storage N2 - In the framework of non-destructive-testing advanced seismic imaging techniques have been applied to ultrasonic echo data in order to examine the integrity of an engineered test-barrier designed to be used for sealing an underground nuclear waste disposal site. Synthetic data as well as real multi-receiver ultrasonic data acquired at the test site were processed and imaged using Kirchhoff prestack depth migration reverse time migration (RTM). In general, both methods provide a good Image quality as demonstrated by various case studies, however deeper parts within the test barrier containing inclined reflectors were reconstructed more accurately by RTM. In particular, the image quality of a specific target reflector at a depth of 8 m in the test-barrier has been significantly improved compared to previous investigations using synthetic aperture Focusing technique, which justifies the considerable computing time of this method. KW - Radioactive waste disposal KW - Engineered barrier KW - Ultrasound KW - Imaging KW - Crack detection PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-537956 DO - https://doi.org/10.1007/s10921-021-00824-3 SN - 0195-9298 VL - 40 IS - 4 SP - 1 EP - 10 PB - Springer AN - OPUS4-53795 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eissel, A. T1 - Modification of Co Cr alloys to optimize of additively welded microstructures and subsequent surface finishing N2 - Cobalt chromium alloys are often used in turbine and plant construction. This is based on their high thermal and mechanical stress resistance as well as their high wear resistance to corrosive and abrasive loads. However, cobalt is a cost-intensive material that is difficult to machine. Moreover, increasingly complex structures and the optimisation of resource efficiency also require additive manufacturing steps for the production or repair of components in many sectors. Concerning inhomogeneity and anisotropy of the microstructure and properties as well as manufacturing-related stresses, a lot of knowledge is still necessary for the economic use of additive welding processes in SMEs. As a result of the high stresses on the components and requirements for a high surface quality, a complementary use of additive and machining manufacturing processes is necessary. Thereby, Co–Cr alloys are extremely challenging for machining with geometrically defined cutting edges because of their low thermal conductivity combined with high strength and toughness. An approach to solve this problem is to refine and homogenise the microstructure. This is achieved by modifying the alloy with elements zirconium and hafnium, which are added up to a maximum of 1 wt.-%. A reduction of the process forces and stresses on the tool and work piece surface is also achievable via hybrid milling processes. There are already studies on the combined use of additive and machining manufacturing processes based on laser technology. However, knowledge based on powder and wire-based arc processes is important, as these processes are more widespread. Furthermore, the effects on the surface zone of additively manufactured components by hybrid finish milling have not yet been a subject of research. The results show that the structural morphology could be significantly influenced with the addition of zirconium and hafnium. T2 - 74th IIW Annual Assembly CY - Online meeting DA - 12.07.2021 KW - Modification of structural morphology KW - Co–Cr-alloy KW - Plasma-transferred arc welding KW - Ultrasonic-assisted milling PY - 2021 AN - OPUS4-56670 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wilhelm, Eugen A1 - Mente, Tobias A1 - Rhode, Michael T1 - Waiting time before NDT of welded offshore steel grades under consideration of delayed hydrogen-assisted cracking N2 - Offshore wind turbines (OWT) are a major goal of the energy strategy of Germany encompassing the increase of the installed wind power. OWT components are manufactured from welded steel plates with thicknesses up to 200 mm. The underlying standards and technical recommendations for construction of OWTs encompass specifications of so-called minimum waiting time (MWT) before non-destructive testing of the weld joints is allowed. Reason is the increased risk of time-delayed hydrogen assisted cold cracking as hydrogen diffusion is very slow due to the very thick plates. The strict consideration of those long MWT up to 48 h during the construction of OWTs leads to significant financial burden (like disproportionately high costs for installer ships as well as storage problems (onshore)). In this study, weld joints made of S355 ML were examined in comparison with the offshore steel grade S460 G2+M. The aim was to optimize, i.e., reduce, the MWT before NDT considering varied heat input, hydrogen concentration and using self-restraint weld tests. This would significantly reduce the manufacturing time and costs of OWT construction. To quantify the necessary delay time until hydrogen-assisted cold cracks appear, acoustic emission analysis was applied directly after welding for at least 48 h. KW - Hydrogen KW - Welding KW - Cracking KW - Offshore KW - Steel PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-524959 DO - https://doi.org/10.1007/s40194-020-01060-5 SN - 0043-2288 VL - 65 SP - 947 EP - 959 PB - Springer Nature AN - OPUS4-52495 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Habib, Abdel Karim T1 - P2X: From production to application Safety issues around hydrogen N2 - For hazard Assessment purposes we need models to predict what would happen in case of an accident. The challenge in hazard assessment consists not only in choosing the right model, but beforehand to define the correct scenario. For hydrogen applications the validity of the models has to be checked, as well as the kind of scenario to assume for accidental releases of hydrogen. Open questions on these topics will be adressed and the newly founded competecne centre for Hydrogen Saftey at BAM will be presented. T2 - VDMA Webinar P2X: From production to application CY - Online Meeting DA - 18.05.2021 KW - Hydrogen KW - Hasard assessment KW - Modeling PY - 2021 AN - OPUS4-52678 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tuma, Dirk T1 - Thermophysical properties of hydrogen-containing mixtures for the extension of equation-of-state models for natural gas N2 - The decarbonization of the energy sector is driving the interest in hydrogen as an energy-storage medium. A practical alternative to transport and distribute H2 is using the existing infrastructure for natural gas. The GERG-2008 equation of state currently serves as the ISO standard (ISO 20765-2) for the calculation of thermodynamic properties of natural gas, but H2 appears only as a secondary component. The availability of consolidated data for mixtures with H2 available at the time of its constitution was very limited. The experimental characterization of the thermodynamic behavior of mixtures of H2 with the main components of natural gas is thus of great relevance to validate and improve the GERG-2008 equation of state for its use with H2-enriched natural gas. T2 - Thermodynamik-Kolloquium 2021 CY - Online meeting DA - 27.09.2021 KW - Hydrogen-containing mixtures KW - Density measurements KW - Equations of state PY - 2021 AN - OPUS4-53991 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schneider, Ronald T1 - Probabilistic approaches to the design and assessment of offshore foundations considering spatially varying site conditions N2 - In this presentation, we discuss the potential of probabilistic approaches to the design and assessment of offshore foundations. The potential is demonstrated in a numerical example considering a laterally loaded monopile. As an outlook, we present a concept for managing the risk associated with installing large monopiles. T2 - 3rd International Conference on Structural Integrity for Offshore Energy Industry (SI 2021) CY - Online meeting DA - 15.11.2021 KW - Offhore KW - Foundations KW - Probabilistic KW - Design KW - Assessment PY - 2021 AN - OPUS4-53748 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Baeßler, Matthias T1 - Numerical Modelling of Local Pile Deformations and Buckling incorporating the Pile-Soil-Interaction N2 - Pile Tip Buckling and Buckling of embedded piles both depend very much on the pile-soil-interaction and its modelling. The presentation gives an overview about current problems and research activities in the light of the development of numerical models. T2 - WESC Wind Energy Science Conference CY - Hannover, Germany DA - 25.05.2021 KW - Offshore Wind Energy Converter KW - Pile Foundation KW - Monopile Buckling KW - Pile Tip Buckling PY - 2021 AN - OPUS4-53033 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Hydrogen embrittlement of steels N2 - Hydrogen assisted cracking of metals is a serious issue in the safety of components, espcially in case of welding. The current presentation gives an overview on specialized testing procedures at Department 9 including the quantitative determination of hydrogen. T2 - HYDROGENIUS BAM Joint Hydrogen Symposium CY - Online meeting DA - 06.07.2021 KW - Hydrogen KW - Embrittlement KW - Degradation KW - Carrier gas hot extraction KW - Welding PY - 2021 AN - OPUS4-53049 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Nina T1 - Untersuchung des Erweichungsmechanismus beim Schweißen in der Wärmeeinflusszone mikrolegierter hochfester Stähle N2 - Für eine signifikante Festigkeitssteigerung von vergüteten hochfesten Feinkornbaustählen ist eine Zugabe von Mikrolegierungselementen wie Nb und Ti unerlässlich. Die Normvorgaben zur chemischen Zusammensetzung dieser Stähle gibt sehr breite Legierungsintervalle für die Hersteller vor, was eine Vorhersage bezüglich der Schweißeignung und des Tragverhaltens der Schweißverbindung erschwert. Zuzüglich kommen vermehrt moderne Schweißprozesse zum Einsatz, die durch ihre hohe Wärmeeinwirkung die Phasenumwandlung in der Wärmeeinflusszone negativ beeinflussen können. Eine unerwünschte Eigenschaft ist dabei die Erweichung (Festigkeitsverlust, engl.: softening) dieser Wärmeeinflusszone. T2 - BMDK CY - Online meeting DA - 17.06.2021 KW - WEZ-Erweichung KW - Vergüteter hochfester Feinkornbaustahl KW - Modifizierter Sprühlichtbogen KW - ThermoCalc KW - HAZ-Softening KW - MAG-Schweißen PY - 2021 AN - OPUS4-52846 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael A1 - Kannengießer, Thomas A1 - Schaupp, Thomas ED - Brockmann, S. ED - Krupp, U. T1 - Wasserstoffunterstützte Kaltrissbildung in Schweißnähten hochfester Stahlgüten - Anforderungen an die Prüfung N2 - Wasserstoff kann eine Rissbildung u.U. auch noch nach Tagen in der Schweißnaht bewirken. Dabei stellen höherfeste Stähle etablierte Kaltrissprüftests vor Herausforderungen. Generell nimmt die zur Rissvermeidung tolerierbare Wasserstoffkonzentration mit zunehmender Festigkeit der Werkstoffe ab. Zudem verändern weiterentwickelte Schweißverfahren die Nahtgeometrie und Wärmeeinbringung und die Ausbildung risskritischer Mikrostrukturen (z.B. Wärmeeinflusszone). Am Beispiel des Implant- und Tekken-Tests werden die Einsatz- u. Anwendungsgrenzen bewertet. Zu berücksichtigen ist, dass beim Schweißen eine äußere mechan. Beanspruchung durch bauteilspezifische Steifigkeitsverhältnisse wirksam ist. Zusätzlich werden weiterführende Prüfverfahren zur Bestimmung der Wasserstoffkonzentration und -diffusion in Schweißnähten vorgestellt, wie die Trägergasheißextraktion (TGHE) für die Ermittlung der Wasserstoffkonzentration (ISO 3690) oder Hochtemperaturdiffusionskoeffizienten. Diese Werte sind für die schweißtechnische Praxis von großer Bedeutung, um Haltezeiten z.B. für das Wasserstoffarmglühen abzuleiten. T2 - Tagung Werkstoffprüfung 2021 CY - Online meeting DA - 02.12.2021 KW - Wasserstoff KW - Kaltrissprüfung KW - Schweißen KW - Stahl KW - Hochfest PY - 2021 SN - 978-3-941269-98-9 SP - 15 EP - 20 PB - Stahlinstitut VDEh CY - Düsseldorf AN - OPUS4-53900 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Becker, Amadeus T1 - Determination of residual stress evolution during repair welding of high-strength steel components N2 - The sustainable and resource-efficient production of wind energy plants requires the use of modern high-strength fine-grain structural steels. This applies to both foundation and erection structures. During the assembly of steel structures, unacceptable defects can occasionally be found in the weld area. In most cases, the economical solution would be local thermal gouging of the affected areas and re-welding. Due to the high shrinkage restraint of the joint groove in the overall structure, the superposition of design and welding-induced residual stress can lead to crack formation and ultimately to component failure, particularly in interaction with the degradation of the microstructure and mechanical properties high-strength steels during the repair process. In this context, component-related investigations of S500MLO and S960QL (FOSTA-P1311/IGF-Nr. 20162 N) focusing on welding residual stress evolution during local thermal gouging and rewelding. In this study, repair welding of S500MLO is carried out using in-situ digital image correlation (DIC) and ex-situ X-ray diffraction methods (XRD) to analyse strains and stresses. Therefore, self-restrained specimens were systematically gouged and rewelded with defined welding heat control (heat input, working temperature) and parameters. By means of structural mechanics calculations, geometries of self-restrained specimens were identified, that represent defined rigidity conditions of repair welds of real components. It could be shown that with increasing restraint intensity significantly higher residual stresses occur in the weld metal and heat affected zone. Furthermore, it revealed that the transverse stresses along the weld seam decrease at the weld seam ends leading to different stress state during gouging and welding. XRD analysis of the local residual stresses after cooling to RT longitudinal and transverse to the weld direction showed a good comparability with global DIC analyses. T2 - 2nd International Conference on Advanced Joining Processes CY - Sintra, Portugal DA - 21.10.2021 KW - MAG-Schweißen KW - Eigenspannungen KW - Reparatur KW - Thermisches Ausfugen KW - Hochfester Stahl PY - 2021 AN - OPUS4-56700 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Becker, Amadeus T1 - Berücksichtigung konstruktiver Einflüsse für die beanspruchungsgerechte Reparatur hochfester Schweißverbindungen N2 - Bei der Montage von Stahlkonstruktionen kommt es trotz anforderungsgerechter schweißtechnischer Fertigung vereinzelt zur Detektion von unzulässigen Unregelmäßigkeiten im Schweißbereich. Die Verarbeitungsregelwerke empfehlen das lokale thermische Ausfugen betroffener Bereiche und erneutes Schweißen, geben aber aufgrund fehlender wissenschaftlich fundierter Untersuchungen kaum Informationen zu adäquaten Reparaturkonzepten. Dies betrifft insbesondere die Berücksichtigung und Optimierung resultierender schweißbedingter Beanspruchungen durch hohe Schrumpfbehinderungen der Ausfugenuten sowie der Gefügedegradation angrenzender Bereiche durch das Ausfugen und erneute Schweißen. Gerade bei hochfesten Stahlgüten ergeben sich dadurch häufig reduzierte mechanische Eigenschaften und zusätzliche schweißbedingte Beanspruchungen sowie erneut auftretende Nahtdefekte. Deshalb sind für das Forschungsvorhaben systematische bauteilrelevante Untersuchungen der schweißbedingten Beanspruchungen und Gefügeveränderungen reparierter Schweißnähte in Abhängigkeit von der Schrumpfbehinderung und Wärmeführung beim Schweißen und Ausfugen sowie von der Reparaturzyklenanzahl geplant, mit dem Ziel Empfehlungen für beanspruchungs- und werkstoffgerechte Reparaturkonzepte abzuleiten. Hierfür sind gerade Analysen an hochfesten Stahlgüten S500 für den Offshore-Bereich und S960QL für den Mobilkranbau interessant, die zur Errichtung und Fertigung hocheffizienter Konstruktionen wie Windenergieanlagen notwendig sind. Die Erkenntnisse bieten eine Grundlage für entsprechende Normen und Regelwerke. Damit können letztlich Schäden und zumeist teure Nacharbeiten verhindert und eine verbesserte Ausnutzung des hohen Festigkeitspotentials hochfester Stähle erreicht werden. Gerade auch KMU können mit Blick auf die Kosten für Fertigung, Schweißarbeit und Material von den Erkenntnissen beim Einsatz hochfester Stähle, die für eine effiziente Realisierung der Energiewende in Deutschland notwendig sind, profitieren. T2 - NA 092-00-05 GA (DVS AG Q 4/Q 4.1) CY - Online meeting DA - 10.03.2021 KW - Eigenspannungen KW - Gefügedegradation KW - Hochfester Feinkornbaustahl KW - Reparatur KW - Schweißen KW - Wärmeführung PY - 2021 AN - OPUS4-53316 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Becker, Amadeus T1 - Adequate repair concepts for high-strength steel weld joints for offshore support structures considering design influences N2 - The sustainable and resource-efficient production of wind energy plants requires the use of modern high-strength fine-grain structural steels. This applies to both foundation and erection structures. During the assembly of steel structures, unacceptable defects can occasionally be found in the weld area. In most cases, the economical solution would be local thermal gouging of the affected areas and re-welding. Due to the high shrinkage restraint of the joint groove in the overall structure, the superposition of global and local welding-induced stresses may lead to crack formation and component failure, particularly in interaction with the degradation of the microstructure and mechanical properties of high-strength steels during the repair process [1]. Corresponding standards hardly provide any information on adequate repair concepts, and there is no uniform scientific data on which to base such concepts. In this study, several relevant findings are discussed based on examples of structural engineering focusing on mechanical-technological properties and residual stresses, e.g. [1]. Further experimental and numerical work as conducted by [2] and weld tests under defined restraint conditions in special weld test-setups [3] show that an optimization of the welding-induced stresses of high-strength structural steels is achievable by means of an adapted heat control. The present research involves systematic investigations of influences of shrinkage restraint, the number of repair cycles and heat control during repair welding of a recently available high-strength offshore steel S500MLO (EN 10225-1). A quantification of the shrinkage restraint of repair weld joints is achievable by means of restraint intensity concept [4], analogous to previous studies [5]. Using structural mechanics calculations, geometries of self-restrained specimens are identified representing different defined rigidity conditions of repair welds considering actual high-strength steel components. Welding experiments with DIC analyses (digital image correlation) of the occurring strains during welding and XRD analyses (X-ray diffraction) of the resulting residual stresses after welding and cooling show increasing transient loads and significantly elevated residual stress profiles in the weld area with increasing restraint intensity. Especially in the heat affected zone, tensile residual stresses of up to 80 % of the nominal yield strength occur when welding under increased restraint conditions. In relation to the presented existing results, this indicates that a safe repair welding is primarily achievable by means of appropriate repair concepts and heat control taking into account the high welding stresses and special microstructures of high-strength steels. Finally, the aim of this research is to derive recommendations for repair concepts appropriate to the stresses and materials involved providing a basis for standards and guidelines, especially for SMEs, in order to avoid damage and, in most cases, expensive reworking and to improve the full utilization of the potential of high-strength steels. T2 - 74th IIW Annual Assembly and International Conference, C II-A CY - Online meeting DA - 07.07.2021 KW - High-strength structural steels KW - Welding KW - Repair KW - Residual stresses KW - Restraint PY - 2021 AN - OPUS4-53320 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scharf-Wildenhain, R. T1 - Einfluss der Wärmeführung auf die Eigenschaften und fertigungsbedingten Beanspruchungen additiv geschweißter hochfester Feinkornbaustähle N2 - Hochfeste Feinkornbaustähle verfügen über ein großes Potenzial für gewichtsoptimierte, effiziente Strukturen in vielen modernen Stahlkonstruktion. Weitere Effizienzsteigerungen können durch additives Fertigen sowie bionische Bauweisen erreicht werden. Kommerzielle hochfeste Zusatzwerkstoffe für additives MSG-Schweißen (engl.: Wire Arc Additive Manufacturing, WAAM) sind bereits von den Schweißzusatzherstellern lieferbar. Derzeit ist jedoch eine breite industrielle Anwendung insbesondere für KMU aufgrund fehlender quantitativer Erkenntnisse und Richtlinien bezüglich schweißbedingter Beanspruchungen und Bauteilsicherheit während der Herstellung und des Betriebs stark limitiert. In einem gemeinsamen Forschungsprojekt (FOSTA-P1380/IGF21162BG) der BAM und der TU Chemnitz werden die mit Eigenspannungsausbildung und der Gefahr einer Kaltrissbildung verbundenen prozess- und werkstoffbedingten sowie konstruktiven Einflüsse untersucht. Im Fokus dieser Analysen steht die Bestimmung der Wechselwirkungen zwischen WAAM-Prozessparametern bzw. der Wärmeführung auf das Gefüge und die Eigenspannungen. Hierfür werden Referenzproben als offene Hohlquader mit definierten Abmessungen vollautomatisiert mit einem speziellen, hochfesten WAAM-Massivdraht (Streckgrenze >790 MPa) geschweißt. Die gezielte Einstellung der geometrischen Eigenschaften erfolgt durch Schweißparameter und Nahtaufbau bei ca. 4 kg/h mittlerer Abschmelzleistung. Die Wärmeführung wird innerhalb eines statistischen Versuchsplanes mittels Streckenenergie (200 kJ/m bis 650 kJ/m) und Zwischenlagentemperatur (100 °C bis 300 °C) so variiert, dass die t8/5-Abkühlzeiten dem empfohlenen Verarbeitungsbereich entsprechen (ca. 5 s bis 20 s). Ziel ist es bei konstanten geometrisch-konstruktiven Randbedingungen, den Einfluss der Wärmeführung auf Gefüge und resultierende Eigenspannungen zu analysieren. Darüber hinaus erfolgt die Bestimmung des Einflusses der t8/5-Abkühlzeit auf die mechanisch-technologischen Eigenschaften des speziellen, hochfesten WAAM-Massivdrahts mithilfe von Dilatometeranalysen. Für die Streckenenergie können neben den Gefügeeinflüssen aufgrund der resultierenden Abkühlzeit deutliche Effekte insbesondere auf die lokalen Eigenspannungen im Bauteil belegt werden. Das Schweißen mit zu hoher Wärmeeinbringung bzw. Abschmelzleistung kann zu ungünstigen Gefüge- und Bauteileigenschaften führen, gleichzeitig jedoch niedrigere Zugeigenspannungsniveaus bewirken. Die Dilatometeranalysen zeigen für den untersuchten WAAM-Schweißzusatzwerkstoff eine großes t8/5-Zeitfenster mit einer vergleichsweise geringen Abnahme der Zugfestigkeit mit zunehmender t8/5-Abkühlzeit. Solche komplexen Wechselwirkungen gilt es letztlich mit diesen Untersuchungen zu klären, um leicht anwendbare Verarbeitungsempfehlungen und Normvorgaben für ein wirtschaftliches, anforderungsgerechtes und risssicheres WAAM von hochfesten Stählen den Anwendern zur Verfügung zu stellen. T2 - 42. Assistentenseminar Fügetechnik CY - Braunschweig, Germany DA - 06.10.2021 KW - MAG-Schweißen KW - Eigenspannungen KW - Additive Fertigung KW - Hochfester Stahl KW - Kaltrisssicherheit PY - 2021 AN - OPUS4-56691 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scharf-Wildenhain, R. A1 - Hälsig, A. A1 - Schröpfer, Dirk A1 - Wandtke, Karsten A1 - Kannengießer, Thomas T1 - Wire Arc Additive Manufacturing (WAAM) mit hochfesten Feinkornbaustählen N2 - Die additive Verarbeitung hochfester Feinkornbaustähle mittels Wire Arc Additive Manufacturing (WAAM) ist ein komplexes, aber zugleich auch effizientes Verfahren, bei dem Werkstoff, Bauteilgeometrie und Schweißprozess gezielt aufeinander abgestimmt sein müssen. Ziel dieser Studie war es, einen Zusammenhang zwischen den Prozessparametern und der generierten Schichtgeometrie zu ermitteln. Dazu wurden definierte Referenzkörper mit einem robotergestützten Schweißsystem additiv gefertigt und hinsichtlich Schichthöhe, Wandstärke und Mikrostruktur analysiert. Fokus der Untersuchung waren sowohl konventionelle als auch für die WAAM-Fertigung speziell entwickelte hochfeste Schweißzusatzwerkstoffe. Die geometrischen Eigenschaften additiv gefertigter Bauteile lassen sich insbesondere durch die Faktoren Drahtvorschubgeschwindigkeit und Schweißgeschwindigkeit gezielt einstellen. Jedoch können diese Parameter nicht beliebig variiert werden, auch aufgrund der rheologischen Eigenschaften der Zusatzwerkstoffe. Zu hohe Streckenenergien führen zu lokalen Überhitzungen und Fehlstellen in der generierten Schicht. Undefinierte Fließ- und Erstarrungsvorgänge im überhitzten Bereich erschweren die maßhaltige Fertigung. Deshalb wird bei speziellen WAAM-Schweißdrähten das Fließverhalten gezielt modifiziert, sodass es über einen größeren Temperaturbereich hinweg konstant ist. Erst die Kenntnis über die komplexen Zusammenhänge zwischen den Prozessparametern und der Bauteilgeometrie ermöglicht die Erzeugung exakter Schichtmodelle für die additive Fertigung. Dies bildet die Grundlage für die Bearbeitung weiterer Fragestellungen auf dem Gebiet der additiven Fertigung mit hochfesten Zusatzwerkstoffen und insbesondere deren Anwendung in modernen hochfesten Bauteilen. T2 - 41. Assistentenseminar Fügetechnik CY - Magdeburg, Germany DA - 03.09.2020 KW - MAG-Schweißen KW - Eigenspannungen KW - Additive Fertigung KW - Hochfester Stahl KW - Kaltrisssicherheit PY - 2021 SN - 978-3-96144-141-9 VL - 370 IS - 41 SP - 113 EP - 124 PB - DVS Media GmbH CY - Düsseldorf AN - OPUS4-56641 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reichardt, Adrian T1 - Introduction of an ageing management approach for packages for the transport of radioactive materials N2 - With integration of the new para 613A into SSR-6 [1] the consideration of ageing mechanisms is now obligatory for the design of packages and their approval. In addition, para 809(f) of SSR-6 [1] requires consideration of the effects of storage on ageing mechanisms, safety analyses and operation and maintenance instructions. German competent authorities Bundesanstalt für Materialforschung und -prüfung (BAM) and Bundesamt für die Sicherheit der nuklearen Entsorgung (BASE) are considering the aspect of ageing in approval procedures. Ageing assessment is mainly focused on dual purpose casks (DPC) package designs which are long-term stored in interim storage facilities. For these package designs, the evaluation of ageing management is now mandatory for the maintenance of the package design approvals with a validity period of 5 years and beyond. The ageing management includes amongst others a gap analysis, the assessment of ageing effects and operational experiences during operation and interim storage. BAM works on the compilation of a guideline for implementation of paras 613A, 809(f) and 809(k) for packages requiring competent authority approval at the application procedure in Germany. The paper describes essential items of ageing mechanisms and will give a foresight to the ageing management evaluation by BAM. T2 - INMM & ESARDA Joint Annual Meeting CY - Online Meeting DA - 30.08.2021 KW - Ageing KW - Dual purpose casks KW - Transport of radaioactive materials KW - Ageing mechanisms KW - Interim storage KW - SSR-6 PY - 2021 AN - OPUS4-53197 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schubert, Sven A1 - Reichardt, Adrian A1 - Wille, Frank A1 - Komann, Steffen A1 - Neumann, Martin T1 - Introduction of an ageing management approach for packages for the transport of radioactive materials N2 - With integration of the new para 613A into SSR-6 [1] the consideration of ageing mechanisms is now obligatory for the design of packages and their approval. In addition, para 809(f) of SSR-6 [1] requires consideration of the effects of storage on ageing mechanisms, safety analyses and operation and maintenance instructions. German competent authorities Bundesanstalt für Materialforschung und -prüfung (BAM) and Bundesamt für die Sicherheit der nuklearen Entsorgung (BASE) are considering the aspect of ageing in approval procedures. Ageing assessment is mainly focused on dual purpose casks (DPC) package designs which are long-term stored in interim storage facilities. For these package designs, the evaluation of ageing management is now mandatory for the maintenance of the package design approvals with a validity period of 5 years and beyond. The ageing management includes amongst others a gap analysis, the assessment of ageing effects and operational experiences during operation and interim storage. BAM works on the compilation of a guideline for implementation of paras 613A, 809(f) and 809(k) for packages requiring competent authority approval at the application procedure in Germany. The paper describes essential items of ageing mechanisms and will give a foresight to the ageing management evaluation by BAM. T2 - INMM & ESARDA Joint Annual Meeting CY - Online meeting DA - 30.08.2021 KW - Dual purpose casks KW - Ageing KW - SSR-6 KW - Interim storage KW - Ageing mechanisms KW - Transport of radaioactive materials PY - 2021 UR - https://www.abstractsonline.com/pp8/#!/10383/presentation/964 SP - 1 EP - 6 PB - Institute of Nuclear Materials Management (INMM) CY - Mount Laurel, NJ AN - OPUS4-53180 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Becker, Amadeus T1 - Konstruktive Einflüsse bei der beanspruchungsgerechten Reparatur geschweißter Bauteile aus hochfesten Feinkornbaustählen N2 - Für eine nachhaltige und ressourceneffiziente Fertigung von Windkraftanlagen ist der Einsatz moderner hochfester Feinkornbaustähle vielfach notwendig. Bei der Montage hochfester Stahlkonstruktionen kommt es trotz anforderungsgerechter schweißtechnischer Fertigung vereinzelt zur Detektion von unzulässigen Unregelmäßigkeiten im Schweißbereich. Derzeitige Normen und Verarbeitungsrichtlinien geben hierbei kaum Informationen zu adäquaten Reparaturkonzepten, insbesondere für hochfeste Stähle. Vor diesem Hintergrund werden an der Bundesanstalt für Materialforschung und -prüfung (BAM) bauteilrelevante Untersuchungen zu den schweißbedingten Beanspruchungen und Gefügeveränderungen bei der schweißtechnischen Reparatur durch lokales thermisches Ausfugen und erneutes Schweißen durchgeführt. Hierzu werden einige wesentliche Ergebnisse an Beispielen des Ingenieurbaus, mit Blick auf die mechanisch-technologischen Eigenschaften und Eigenspannungen erörtert. In einem aktuellen Vorhaben (FOSTA P1311, IGF 20162N) sind darauf aufbauend die Einflüsse durch die Schrumpfbehinderung und Wärmeführung beim Reparaturschweißen hochfester Feinkornbaustähle (S500MLO, S960QL) sowie die Reparaturzyklenanzahl Fokus systematischer Untersuchungen. Mittels strukturmechanischer Berechnungen ließen sich hierzu selbstbeanspruchende Probenformen identifizieren, die unterschiedliche definierte Steifigkeitsverhältnisse von Reparaturschweißnähten realer Bauteile abbilden. Schweißnähte an diesen bauteilähnlichen Proben weisen signifikant erhöhte schweißbedingte Beanspruchungen mit zunehmenden (Biege-)Einspanngraden auf. Im Vergleich mit bisherigen Erkenntnissen wird gezeigt, dass eine sichere Reparatur solcher Schweißnähte nur mittels optimaler Reparaturkonzepte und Wärmeführung gelingt, um diesen hohen Beanspruchungen und auch den speziellen Gefügen hochfester Stähle Rechnung zu tragen. Ziel der Untersuchungen ist es letztlich, Empfehlungen für beanspruchungs- und werkstoffgerechte Reparaturkonzepte gerade für KMU abzuleiten, um Schäden und zumeist teure Nacharbeiten zu vermeiden. T2 - 4. Niedersächsisches Symposium Materialtechnik CY - Online meeting DA - 25.02.2021 KW - Feinkornbaustähle KW - Hochfest KW - Reparaturschweißen KW - Eigenspannungen PY - 2021 AN - OPUS4-52562 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ghafafian, Carineh A1 - Popiela, Bartosz A1 - Trappe, Volker T1 - Failure Mechanisms of GFRP Scarf Joints under Tensile Load N2 - A potential repair alternative to restoring the mechanical properties of lightweight fiberreinforced polymer (FRP) structures is to locally patch these areas with scarf joints. The effects of such repair methods on the structural integrity, however, are still largely unknown. In this paper, the mechanical property restoration, failure mechanism, and influence of fiber orientation mismatch between parent and repair materials of 1:50 scarf joints are studied on monolithic glass fiber-reinforced polymer (GFRP) specimens under tensile load. Two different parent orientations of [-45/+45]2S and [0/90]2S are exemplarily examined, and control specimens are taken as a baseline for the tensile strength and stiffness property recovery assessment. Using a layer-wise stress analysis with finite element simulations conducted with ANSYS Composite PrepPost to support the experimental investigation, the fiber orientation with respect to load direction is shown to affect the critical regions and thereby failure mechanism of the scarf joint specimens. KW - Scarf joint KW - Glass fiber reinforced polymers KW - Failure mechanisms PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-523952 DO - https://doi.org/10.3390/ma14071806 VL - 14 IS - 7 SP - 1806 PB - MDPI CY - Basel, Switzerland AN - OPUS4-52395 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lu, Xin A1 - Schukar, Marcus A1 - Großwig, S. A1 - Weber, U. A1 - Krebber, Katerina T1 - Monitoring acoustic events in boreholes using wavelengthscanning coherent optical time domain reflectometry in multimode fiber N2 - A distributed acoustic sensor (DAS) based on wavelength-scanning coherent optical time domain reflectometer (WS-COTDR) is tested in an underground gas storage based on a multimode fiber for the first time to the best of our knowledge. The WS-COTDR acquires the reflection spectrum by scanning the wavelength of the laser and uses the spectra to calibrate strain. It overcomes the fading problem which is common for all DAS systems, and possesses the advantage of simple configuration and low-cost. The working principle of the system is well explained and the measurement results are presented. Various artificial and natural acoustic events have been successfully detected by the WS-COTDR. Such a sensor demonstrates several advantages over the traditional DAS systems, so it is supposed to be widely used in the oil and gas industry. T2 - EAGE GeoTech 2021 Second EAGE Workshop on Distributed Fibre Optic Sensing CY - Online meeting DA - 01.03.2021 KW - Leakage detection KW - Distributed acoustic sensing KW - Distributed fiber optic sensing PY - 2021 DO - https://doi.org/10.3997/2214-4609.202131010 SP - Paper 10, 1 PB - European Association of Geoscientists & Engineers CY - Houten, Niederlande AN - OPUS4-52248 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Heuser, Lina T1 - Sintering of silver‑alkali zinc borate glass‑composites N2 - Since decades electric contacts based on silver metallization pastes are key components of photovoltaics and advanced microelectronics. For the metallization of commercial Si solar cells, high conductive silver glass pastes are cost effectively applicated by screen printing. Nevertheless, silver pastes are still one of the most crucial and expensive none Si materials in solar cells. Ever shorter time to market as well as increasing demands on reduced Ag consumption and line width require the targeted development of silver-glass-pastes with increased sinter ability and electrical conductivity. As a main difficulty, however, the liquid phase sintering of silver glass pastes is poorly understood so far. In the present study, the influence of different network modifier in alkali-zinc-borate paste glasses on liquid phase sintering of silver-glass-pastes was investigated. Low melting X2O-ZnO-B2O3 glasses with X = Na, Li and Rb (abbr. LZB, NZB, and RZB) were utilized to prepare silver-glass-composites containing 30 %Vol glass. Shrinkage behavior of the silver-glass-composites compared with that of pure silver and pure glass powder compacts was studied with heating microscopy. The powder compacts were uniaxially pressed and heated at 5 K/min to the glass softening temperature. Glass transformation temperature and viscosity of the glasses were respectively measured with dilatometry and rotational viscometry. The thermal behavior of the pure glasses was analyzed with thermal analysis. Additionally, the contact angle of glass on pure silver foil was determined by means of heating microscopy between room temperature and 830 °C. Thermal analysis of the alkali-zinc-borate-glasses under study has shown transformation temperatures between 450 °C (RZB), 460 °C (LZB) and 465 °C (NZB). For all glasses crystallization was found to start approximately at about 550 °C. However, different peak areas hint on a different degree of crystallization. Conformingly, the sintering behavior, measured in terms of area shrinkage, significantly differed for the silver-pastes under study. For silver-pastes with NZB or LZB-glass, sintering starts at 464 °C for NZB Ag pastes and at 451 °C for LZB Ag pastes and ends at 597 °C for NZB Ag paste and at 594 °C for LZB Ag paste. The sintering of the RZB Ag paste proceeds between 426 °C and 703 °C. The final densification was retarded possibly due to crystallization or swelling. The low sinter onset at 426 °C seems to correlate with the good wetting behavior of the RZB glass. Thus, the lowest apparent contact angle between the just densified powder compact sintered at a silver substrate was found for this glass. Moreover, microstructure analyses of the various composites indicate differences in silver dissolution and reprecipitation. T2 - Technology Crossover Extravaganza, HiTEC/CICMT/APEPS CY - Online meeting DA - 26.04.2021 KW - Silver-glass-metallization-paste KW - Sintering KW - Crystallization KW - Alkali ions KW - Sintering atmosphere PY - 2021 AN - OPUS4-52872 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wang, Bin A1 - Mair, Georg W. A1 - Islam, F. T1 - Evaluation methods for estimation of Weibull parameters used in Monte Carlo simulations for safety analysis of pressure vessels N2 - The test data for static burst strength and load cycle fatigue strength of pressure vessels can often be well described by Gaussian normal or Weibull distribution functions. There are various approaches which can be used to determine the parameters of the Weibull distribution function; however, the performance of these methods is uncertain. In this study, six methods are evaluated by using the criterion of OSL (observed significance level) from Anderson-Darling (AD) goodness of Fit (GoF), These are: a) the norm-log based method, b) least squares regression, c) weighted least squares regression, d) a linear approach based on good linear unbiased estimators, e) maximum likelihood estimation and f) method of moments estimation. In addition, various approaches of ranking function are considered. The results show that there are no outperforming methods which can be identified clearly, primarily due to the limitation of the small sample size of the test data used for Weibull analysis. This randomness resulting from the sampling is further investigated by using Monte Carlo simulations, concluding that the sample size of the experimental data is more crucial than the exact method used to derive Weibull parameters. Finally, a recommendation is made to consider the uncertainties of the limitations due to the small size for pressure vessel testing and also for general material testing. KW - Safety assessment KW - Weibull distribution parameters KW - Randomness KW - Sample size KW - Monte Carlo simulation PY - 2021 DO - https://doi.org/10.1515/mt-2020-0058 VL - 63 IS - 4 SP - 279 EP - 385 PB - De Gruyter AN - OPUS4-53105 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mair, Georg W. T1 - Markthochlauf von Wasserstoff - probabilistische Sicherheitsbewertung von Speichern und Normen N2 - Der Foliensatz beginnt mit der Kurzvorstellung des Kompetenzzentrums H2Safety@BAM und weiteren Informationen zum Kompetenzfeld MatCom. Danach werden die Erwartungen der EU zum Wasserstoffverbrauch vorgestellt und visualisiert, wie Risikosteuerung bei stark wachsender Technik funktionieren kann, und welchen zeitlichen Vorlauf man für die Einführung von neuen Zulassungsanforderungen benötigt. Der Begriff Sicherheit wird über den Risikobegriff definiert und am Beispiel quantifiziert. Danach werden verschiedene Werkzeuge vorgestellt, die dazu geeignet sind, die Risikosteuerung im Markthochlauf zu realisieren: Die statistische Bewertung von Stichproben, die probabilistische Bewertung von Populationen, die Lebensdauervorhersage von Populationen. Dies führt weiter zum Gedanken eines probabilistischen Zulassungsansatzes und zum Potential Monte-Carlo-Experimentes in der Bewertung der Wirkung von deterministischen Baumusterprüfkriterien. All dies sind Themen, die nach Meinung des Vortragenden Zukunftsprojekte der Normung sein sollten, um ein Werkzeug zu erhalten, das auch weitgehend ohne produktspezifische Erfahrung geeignet ist, Sicherheit in einer H2-Gesellschaft zu gewährleisten. T2 - Beirat des DIN-Normenausschusses Materialprüfung (NMP) CY - Online meeting DA - 23.03.2021 KW - H2Safety@BAM KW - Monte-Carlo-Experiment KW - Lebensdauervorhersage KW - Statistische Bewertung KW - Risikosteuerung PY - 2021 AN - OPUS4-54613 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mair, Georg W. T1 - Markthochlauf von Wasserstoff probabilistische Sicherheitsbewertung von Speichern und Normen N2 - Der Foliensatz beginnt mit den Erwartungen der EU zum Wasserstoffverbrauch und der Visualisierung, wie Risikosteuerung bei stark wachsender Technik funktionieren kann, und welchen zeitlichen Vorlauf man für die Einführung von neuen Zulassungsanforderungen benötigt. Der Begriff Sicherheit wird über den Risikobegriff definiert und am Beispiel quantifiziert. Danach werden verschiedene Werkzeuge vorgestellt, die dazu geeignet sind, die Risikosteuerung im Markthochlauf zu realisieren: Die statistische Bewertung von Stichproben, die probabilistische Bewertung von Populationen, die Lebensdauervorhersage von Populationen. Dies führt weiter zum Gedanken eines probabilistischen Zulassungsansatzes und zum Potential Monte-Carlo-Experimentes in der Bewertung der Wirkung von deterministischen Baumusterprüfkriterien. All dies sind Themen, die nach Meinung des Vortragenden Zukunftsprojekte der Normung sein sollten, um ein Werkzeug zu erhalten, das auch weitgehend ohne produktspezifische Erfahrung geeignet ist, Sicherheit in einer H2-Gesellschaft zu gewährleisten. T2 - Beirat des DIN-Normenausschusses Druckgasanlagen (NDG) CY - Online meeting DA - 23.02.2021 KW - Wasserstoffspeicher KW - Monte-Carlo-Experiment KW - Lebensdauervorhersage KW - Zuverlässigkeit KW - Streuung KW - Zulassungskriterium PY - 2021 AN - OPUS4-54610 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst T1 - PREDIS: Innovative ways for pre disposal treatment and monitoring of low and medium radioactive waste N2 - The EURATOM PREDIS project (http://www.predis-h2020.eu, last access:TS1) targets the development and implementation of activities for predisposal treatment of radioactive waste streams other than nuclear fuel and high-level radioactive waste. It started on 1 September 2020 with a 4 year duration. The consortium includes 47 partners from 17 member states. The overall budget of the project is EUR23.7 million, with EC contribution of EUR 14 million. The PREDIS project develops and increases the technological readiness level (TRL) of treatment and conditioning methodologies for wastes for which no adequate or industrially mature Solutions are currently available, including metallic materials, liquid organic waste and solid organic waste. The PREDIS project also develops innovations in cemented waste handling and predisposal storage by testing and evaluating. The technical work packages align with priorities formulated within the Roadmap Theme 2 of EURAD (https://www.ejp-eurad.eu/TS2), Nugenia Global Vision (https://snetp.eu/nugenia/TS3) and with those identified by the project’s industrial end users group (EUG). The PREDIS will produce tools guiding decision making on the added value of the developed technologies and their impact on the design, safety and economics of waste management and disposal. Four technical work packages are focusing on specific waste types: metallic, liquid organic, solid organic, and cemented wastes. For the first three, the main aim lies in processing, stabilizing, and packaging the different waste streams, e.g. by using novel geopolymers, to deliver items which are in line with national and international waste acceptance criteria. In contrast, the fourth technical work package has a different focus. To provide better ways for a safe and effective monitoring of cemented waste packages including prediction tools to assess the future integrity development during predisposal activities, several digital tools are evaluated and improved. Safety enhancement (e.g. less exposure of testing personnel) and cost-effectiveness are part of the intended impact. The work includes but is not limited to inspection methods, such as muon imaging, wireless sensors integrated into waste packages as well as external package and facility monitoring, such as remote Fiber optic sensors. The sensors applied will go beyond radiation monitoring and include proxy parameters important for long-term integrity assessment (e.g. internal pressure). Sensors will also be made cost-effective to allow the installation of many more sensors compared to current practice. The measured data will be used in digital Twins of the waste packages for specific simulations (geochemical, integrity) providing a prediction of future behavior. Machine learning techniques trained by the characterization of older waste packages will help to connect the models to the current data. All data (measured and simulated) will be collected in a joint database and connected to a decision framework to be used at actual facilities. The presentation includes detailed information about the various tools under consideration in the Monitoring of cemented waste packages, their connection and first results of the research. T2 - Safety of Nuclear Waste Disposal CY - Berlin, Germany DA - 10.11.2021 KW - Radioactive waste disposal KW - RFID KW - Monitoring KW - Cemented waste PY - 2021 AN - OPUS4-54157 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Effner, Ute T1 - Entwicklung einer Bohrlochsonde für Ultraschalluntersuchungen an Abschlussbauwerken in Endlagern N2 - Für die Qualitätssicherung von Abschlusswerken für Endlager wird eine Ultraschall-Bohrlochsonde entwickelt. Mithilfe dieser Sonde, die aus einer Vielzahl von einzelnen koppelmittelfreien Ultraschall-Punktkontaktprüfköpfen besteht, soll die Rissfreiheit der Versuchsbauwerke überprüft werden. Ein erster Prototyp der Sonde wurde mit einem kommerziellen Ultraschallgerät betrieben und bestand aus 12 Transversalwellen-Punktkontaktprüfköpfen von denen jeweils sechs als Sender und sechs als Empfänger parallelgeschaltet waren. Um den erzeugten Schalldruck der Bohrlochsonde zu steigern, wurde bei der Neuentwicklung die Prüfkopfanzahl erhöht und zusätzlich die laufzeitgesteuerte Anregung der einzelnen Prüfköpfe vorgesehen. Für die Anregung der Prüfköpfe mit programmierten Zeitverzögerungen wurde ein neuartiger mehrkanaliger Sender für bipolare Rechtecksignale entwickelt. Durch die Entwicklung der Bohrlochsonde soll eine dynamische Anpassung der Prüfkopf-Apertur sowie eine Fokussierung des Schallfeldes in Abhängigkeit der zu untersuchenden Tiefe erfolgen. Mithilfe entsprechender Anregungsfunktionen kann das Schallfeld der Bohrlochsonde unterschiedlich geformt werden, z. B. ist auch ein Schwenken des fokussierten Schallbündels möglich. Dadurch wird das erfasste Prüfvolumen begrenzt und auf diese Weise das Signal-Störverhältnis der Empfangssignale verbessert. In Kombination mit SAFT-Rekonstruktionsrechnungen wird durch eine optimierte Abstrahlcharakteristik der Sonde mit einem hohen Schalldruck unter verschiedenen Winkeln eine verbesserte Signalqualität und damit eine erhöhte Aussagesicherheit der Ergebnisse in der Objektabbildung erwartet. T2 - DGZfP-Jahrestagung 2021 CY - Online meeting DA - 10.05.2021 KW - Abdichtbauwerk KW - Zerstörungsfreie Prüfung KW - Ultraschall-Echoverfahren KW - Bohrlochsonde KW - Verschlussbauwerk PY - 2021 UR - https://jahrestagung.dgzfp.de/portals/jt2021/bb176/inhalt/poster.htm AN - OPUS4-52657 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst T1 - Ultraschallprüfung von Verschlussbauwerken im Salinar N2 - Zu jedem Endlager gehört die Entwicklung eines Verschlusskonzept. Im Endlager Morsleben und an anderer Stelle werden in Abhängigkeit vom Wirtsgestein verschiedene Materialien und Bauweisen für Streckenverschlüsse entwickelt und in großem Maßstab erprobt. Hierzu gehören auch Maßnahmen der Qualitätssicherung, die Informationen über Ausführung und Zustand der Versuchsbauwerke liefern. Hierzu werden von der Bundesanstalt für Materialforschung und -prüfung (BAM) für verschiedene Forschungsvorhaben und Prüfaufträge Methoden und Geräte getestet, verbessert und vor Ort unter Tage eingesetzt Die hier beschriebenen Verfahren lassen sich auch zu Untersuchungen im Wirtsgestein anwenden. T2 - Tage der Standortauswahl CY - Freiberg/S., Germany DA - 11.02.2021 KW - Endlager KW - Verschlussbauwerke KW - Qualitätssicherung KW - Ultraschall PY - 2021 AN - OPUS4-54166 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst T1 - Towards digital tools for waste package and facility monitoring and prediction N2 - The workpackage 7 of the EC funded project PREDIS deals with cemented low and intermediate level radioactive waste. The focus is on NDT/monitoring technologies, digiutal twins and data/decision frameworks to optimize facilitay and waste package management. The talk describes the project setup and planned activities. T2 - DigiDecom 2021 CY - Online meeting DA - 22.03.2021 KW - Nuclear waste KW - Waste package KW - Predisposal KW - storage KW - monitoring PY - 2021 AN - OPUS4-52334 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst T1 - Towards digital tools for waste package and facility monitoring and prediction N2 - To provide better means for a safe and effective monitoring of cemented waste packages including prediction tools to assess the future integrity development during pre-disposal activities, several digital tools are evaluated and improved in the frame of the EC funded project PREDIS. Safety enhancement (e. g. less exposure of testing personnel) and cost effectiveness are part of the intended impact. The work includes but is not limited to inspection methods such as muon imaging, wireless sensors integrated into waste packages as well as external package and facility monitoring such as remote fiber optical sensors. The sensors applied will go beyond radiation monitoring and include Proxy parameters important for long term integrity assessment (e. g. internal pressure). Sensors will also be made cost effective to allow the installation of much more sensors compared to current practice. The measured data will be used in digital twins of the packages for specific simulations (geochemical, integrity) providing a prediction of future behavior. Machine Learning techniques trained by the characterization of older packages will help to connect the models to the actual data. All data (measured and simulated) will be collected in a joint data base and connected to a decision framework to be used at actual facilities. The presentation includes detailed information about the various tools under consideration, their connection and first results of our research. T2 - DigiDecom 2021 DIGITAL – Online event focusing on innovation within nuclear decommissioning CY - Online Meeting DA - 23.03.2021 KW - Radioactive waste KW - Waste package KW - Monitoring KW - Digital twin PY - 2021 AN - OPUS4-52622 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lozano-Martín, D. A1 - Tuma, Dirk A1 - Vega-Maza, D. A1 - Martín, M. C. A1 - Chamorro, C. R. T1 - Thermodynamic characterization of the (CO2+ O2) binary system for the development of models for CCS processes: Accurate experimental (p, rho, T) data and virial coefficients N2 - Continuing our study on (CO2 + O2) mixtures, this work reports new experimental (p, rho, T) data for two oxygen-rich mixtures with mole fractions x(O2) = (0.50 and 0.75) mol·mol−1, in the temperature range T = (250–375) K and pressure range p = (0.5–20) MPa, using a single-sinker densimeter. Experimental density data were compared to two well-established equation-of-state models: EOS-CG and GERG-2008. In the p, T-range investigated, the EOS-CG gave a better reproduction for the equimolar mixture (x(O2) = 0.5), whereas the GERG-2008 performed significantly better for the oxygen-rich mixture (x(O2) = 0.75). The EOS-CG generally overestimates the density, while the GERG-2008 underestimates it. This complete set of new experimental data, together with previous measurements, is used to calculate the virial coefficients B(T, x) and C(T, x), as well as the second interaction virial coefficient B12(T) for the (CO2+ O2) system. KW - Binary mixtures CO2 + O2 KW - Density measurements KW - Equations of state KW - Virial coefficients PY - 2021 DO - https://doi.org/10.1016/j.supflu.2020.105074 SN - 0896-8446 VL - 169 SP - 5074 PB - Elsevier B. V. CY - Amsterdam AN - OPUS4-51670 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Günzel, Stephan T1 - Safety assessment of hydrogen gas storage systems N2 - In this lecture, the safety assessment of hydrogen gas storage systems is presented using the example of composite pressure vessels. The main element is a probabilistic approval approach based on five steps. Firstly, the testing and evaluation of properties at the beginning of life are shown. Secondly, methods for artificial aging and the effect on the residual strength are presented. Thirdly, testing against dedicated accidents is introduced. Fourthly, effects on the surveillance of production quality are discussed. Finally, degradation and the end of life are estimated. Background information and examples are given for each step. The assessment presented is a method applicable for many safety-related systems. T2 - Joint European Summer School 2021 on Fuel Cell, Electrolyser, and Battery Technologies CY - Online meeting DA - 12.09.2021 KW - Safety KW - Hydrogen KW - Wasserstoff KW - Bewertung KW - Assessment PY - 2021 AN - OPUS4-59905 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schönhals, Andreas A1 - Szymoniak, Paulina A1 - Kolmangadi, Mohamed Aejaz A1 - Böhning, Martin A1 - Zamponi, M. A1 - Frick, B. A1 - Appel, M. A1 - Günther, G. A1 - Russina, M. A1 - Alentiev, D. A1 - Bermeshev, M. A1 - Zorn, R. T1 - Microscopic dynamics of highly permeable super glassy polynorbornenes revealed by quasielastic neutron scattering N2 - The molecular dynamics of addition-type poly(tricyclononenes) with Si-substituted bulky side groups has been investigated by a combination of neutron time-of-flight and neutron backscattering spectroscopy methods on a time scale from 0.1 ps to ca. 3 ns. The investigated poly(tricyclononenes) PTCNSi1 and PTCNSi2g both bear a high microporosity which makes them promising candidates for active separation layers for gas separation membranes. At least for larger gas molecules it is assumed that the pathways for diffusion require an enlargement of pre-existing micropores in terms of an activated zone. A low temperature relaxation process was found for both polymers by the performed neutron scattering experiments. This process was assigned to the methyl group rotation. It was analysed in terms of a jump diffusion in a three-fold potential. The analysis of the dependence of the elastic incoherent structure factor on the scattering vector yields the number of methyl groups which might be immobilized. For PTCNSi1 (3 methyl groups in the monomeric unit) it was found that all methyl groups take part in the methyl group rotation whereas for PTCNSi2g (6 methyl groups in monomeric unit) a considerable number of methyl groups are blocked in their rotation. This immobilization of methyl groups is due to the sterically demanding arrangement of the methyl groups in PTCNSi2g. This conclusion is further supported by the result that the activation energy for the methyl group rotation is three times higher for PTCNSi2g than that of PTCNSi1. KW - Highly permeably polynorbornenes KW - Polymers of intrinsic microporosity KW - Gas separation membranes KW - Quasielastic neutron scattering PY - 2021 DO - https://doi.org/10.1016/j.memsci.2021.119972 SN - 0376-7388 VL - 642 PB - Elesevier B.V. AN - OPUS4-53508 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -