TY - CONF A1 - Kolmangadi, Mohamed Aejaz T1 - Side Chain length dependent dynamics and conductivity of Ionic Liquid crystals N2 - We investigate the molecular dynamics and electrical conductivity for a homologous series of linear shaped guanidinium based cyclic ILCs that vary in alkyl chain length, CLCRs (R = 8, 10, 12, 14, 16) by employing broadband dielectric spectroscopy (BDS), and calorimetry comprised of Fast Scanning Calorimetry (FSC) and temperature modulated FSC (TMFSC). Besides conductivity at high temperatures, the dielectric dispersion reveals two relaxation modes: the fast γ and the slow α1 relaxation. The former is assigned to the localized fluctuations while the latter is due to segmental dynamics of the alkyl chains. The γ mode slows down for long chain length CLCs (12,14,16) compared to their shorter analogues. Calorimetric investigation reveals one process, the α2 process, for all ILCs. The α2 process for CLC10, 12, and 14 has a similar temperature dependence as the dielectric α1 relaxation, while for the CLC8 and 10, it's shifted to a higher temperature. For all CLCRs, the absolute values of DC conductivity increase by 4 orders of magnitude at the transition from the plastic crystalline to hexagonal columnar phase. This increase is due to the change in the underlying conduction mechanism from delocalized electron hopping in the crystalline phase to one-dimensional ion mobility in the columnar phase. The glassy dynamics shifts to higher temperatures with increasing alkyl chain length. Conversely, the DC conductivity drops by 3 orders of magnitude from CLC8 to CLC16. T2 - APS March Meeting 2022 CY - Chicago, IL, USA DA - 13.03.2022 KW - Glass transition KW - Conductivity KW - Fast Scanning Calorimetry KW - Dynamics PY - 2022 AN - OPUS4-54760 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Baensch, Franziska T1 - Charakterisierung von Salzbeton und alkali-aktivierten Material basierend auf der Schallemissionsanalyse N2 - Nach einer kurzen Einführung in die Schallemissionsprüfung und -Analyse wird ein Versuchsstand vorgestellt, der im Rahmen des Themenfeldprojektes Seal Waste Safe installiert wurde. Schwerpunkt des Vortrages sind die Schallemissionsmessungen an einem 150 l Demonstrator aus Salzbeton und einem weiteren aus alkali-aktiviertem Material. Neben der konventionellen Schallemissionsanaylse mit Aktivitäts- und Intensitätsparametern der Zeitsignale, werden auch frequenzbasierte Parameter zur Analyse andiskutiert. N2 - After a brief introduction to acoustic emission testing and analysis, an experimental test setup is presented, which was part of the Seal Waste Safe project (internal BAM project 2019-2022). Herein, the acoustic emission measurements of a 150 l demonstrator made of salt concrete and another one made of alkali-activated material are focused. In addition to the conventional acoustic emission analysis regarding the activity and intensity parameters of the detected time signals, also frequency-based parameters were discussed for analysis. T2 - Dauerhafte Verschlussbauwerke für Endlager CY - Online meeting DA - 14.2.2022 KW - Acoustic Emission KW - Schallemission KW - Salzbeton KW - Alkali aktiviertes Material KW - Geopolymer PY - 2022 AN - OPUS4-54937 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kuchenbecker, Petra T1 - Bestimmung der Partikelgrößenverteilung mittels Zentrifugen-Sedimentationsverfahren nach ISO 13318-2 (Küvette) N2 - Im Vortrag werden das Messprinzip des Zentrifugen-Sedimentationsverfahrens erläutert und die Anforderungen der zugrundeliegenden Normen diskutiert. Es schließen sich umfangreiche Ausführungen zur praktischen Durchführung der Messung, insbesondere auch zu den vorbereitenden Arbeiten, sowie zur Auswertung der Rohdaten an. Gezeigt werden die Validierung sowie ein Beispiel zur regelmäßigen Verifizierung des Verfahrens. Nach Beispielen und Vergleichen zu Ergebnissen mit anderen Messverfahren, wird das Verfahren in einer Zusammenfassung bewertet. T2 - Seminar Rheologie und Stabilität von dispersen Systemen CY - Potsdam, Germany DA - 09.05.2022 KW - Nano powder KW - Cetrifugal Liquid Sedimentation CLS KW - Particle size determination PY - 2022 AN - OPUS4-54863 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Frunza, L. A1 - Zgura, I A1 - Ganea, C. P. A1 - Schönhals, Andreas T1 - Molecular dynamics of alkyl benzoate liquid crystals in the bulk state and in the surface layer of their composites with oxide nanopowders N2 - This paper presents the results concerning monotropic nematic liquid crystals 4-pentylphenyl 40-alkyl benzoate (5PnB) (n = 3 or 5 carbon atoms in the alkyl chain). Their mesophase properties were supported by images of the polarized optical microscopy. Molecular dynamics in the bulk samples or in the composites prepared with aerosil A380 was investigated by broadband dielectric spectroscopy in a large temperature range, appropriately chosen. Thermo gravimetric and infrared investigations were additionally performed. The data were compared with those of structurally related nematics like cyanophenyl pentyl benzoates, which have a cyan group instead of the pentyl chain. The dielectric spectra of the bulk 3P5B and 5P5B demonstrate a dielectric behavior with several relaxation processes as expected for nematic liquid crystals. The temperature dependence of the relaxation rates (and of the dielectric strength) seems to have two distinguished regimes. Thus, in the isotropic state, at higher temperatures the data obey the Vogel–Fulcher–Tammann law, whereas an Arrhenius law is fitted at lower temperature, in a close similarity to the behavior of a constrained dynamic glass transition. Samples with a high density of silica (larger than 7 g aerosil/1 g of 5PnB) were prepared to observe a thin layer adsorbed on the particle surface; it was estimated that almost each guest 5PnB molecule interacts with the aerosil surface. For the composites only one main relaxation process is observed at frequencies much lower than those for the corresponding bulk, which was assigned to the dynamics of the molecules in the surface layer. Infrared spectroscopy shows that these molecules interact with the surface by the ester carbonyl group leading to the monolayer self-assembly at liquid–solid interface. We note once more the importance of the functional unit(s) for the interaction with the hydroxyl groups on the aerosil surface. KW - Liquid crystals PY - 2022 DO - https://doi.org/10.1016/j.molliq.2022.119374 SN - 0167-7322 VL - 359 SP - 1 EP - 11 PB - Elsevier B.V. AN - OPUS4-54867 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ehlers, Henrik T1 - Hochauflösende Online Wirbelstromprüfung von PBF LB/M Bauteilen mit GMR Arrays N2 - In den letzten Jahren haben additive Fertigungstechnologien an Bedeutung gewonnen. Für komplexe Funktionsbauteile oder die Produktion von Werkstücken in kleinen Stückzahlen kann das Laser-Pulverbettschmelzen eingesetzt werden. Hohe Sicherheitsanforderungen, z. B. in der Luft- und Raumfahrt, erfordern eine umfassende Qualitätskontrolle. Daher werden nach der Fertigung zerstörungsfreie Offline-Prüfverfahren wie die Computertomographie eingesetzt. In jüngster Zeit wurden zur Verbesserung der Rentabilität und Praktikabilität zerstörungsfreie Online-Prüfverfahren wie die optische Tomographie entwickelt. In diesem Beitrag wird die Anwendbarkeit der Wirbelstromprüfung mit GMR Sensoren für die online Prüfung von PBF-LB/M Teilen demonstriert. Die Ergebnisse einer online Wirbelstromprüfung mit GMR Sensoren und einer Ein-Draht-Anregung werden gezeigt. Während des Produktionsprozesses wird für jede Lage eine Wirbelstromprüfung durchgeführt. Trotz hochauflösender Arrays mit 128 Elementen wird durch eine angepasste Hardware die Prüfdauer geringgehalten. So kann die Messung während des Beschichtungsvorgangs durchgeführt werden, ohne den Fertigungsprozess signifikant zu verlangsamen. Eine online Wirbelstromprüfung eines stufenförmigen Testkörpers aus Haynes282 über 184 Lagen zeigt, dass die Kanten nicht nur in der aktuellen Lage detektiert werden können, sondern auch in einer Tiefe von 400 µm, wenn eine Anregungsfrequenz von 1,2 MHz gewählt wird. T2 - DGZfP Jahrestagung 2022 CY - Kassel, Germany DA - 23.05.2022 KW - Wirbelstrom KW - Additive Fertigung KW - GMR KW - PBF PY - 2022 AN - OPUS4-54899 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Guillaume, F. A1 - Knorr, Annett A1 - Rotureau, P. T1 - First QSPR models to predict the thermal stability of potential self-reactive substances N2 - Self-reactive substances are unstable chemical substances which can easily decompose and may lead to explosion in transport, storage, or process situations. For this reason, their thermal stability properties are required to assess possible process safety issues and for classification purpose. In this study, the first quantitative structure–property relationships (QSPR) dedicated to this class of compounds were developed to predict the heat of decomposition of possible self-reactive substances from their molecular structures. The database used to develop and validate the models was issued from a dedicated experimental campaign on 50 samples using differential scanning calorimetry in homogeneous experimental conditions. QSPR models were derived using the GA-MLR methods (using a genetic algorithm and multi-linear regressions) using molecular descriptors calculated by Dragon software based on two types of inputs: 3D molecular structures determined using the density functional theory (DFT), allowing access to three-dimensional descriptors, and from SMILES codes, favoring the access to simpler models, requiring no preliminary quantum chemical calculations. All models respected the OECD validation guidelines for regulatory ac ceptability of QSPR models. They were tested by internal and external validation tests and their applicability domains were defined and analyzed. KW - Self-reactive substances KW - Quantitative Structure-Property Relationships KW - Thermal stability KW - Genetic algorithm PY - 2022 DO - https://doi.org/10.1016/j.psep.2022.05.017 SN - 0957-5820 VL - 163 SP - 191 EP - 199 PB - Elsevier Ltd. AN - OPUS4-55631 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tang, Chi-Long T1 - Proposal of a standard test method for the quantification of particulate matter during 3D printing and the systematic ranking of filament materials N2 - The diversity of fused filament fabrication (FFF) filaments continues to grow rapidly as the popularity of FFF-3D desktop printers for the use as home fabrication devices has been greatly increased in the past decade. Potential harmful emissions and associated health risks when operating indoors have induced many emission studies. However, the lack of standardization of measurements impeded an objectifiable comparison of research findings. Therefore, we designed a chamber-based standard method, i.e., the strand printing method (SPM), which provides a standardized printing procedure and quantifies systematically the particle emission released from individual FFF-3D filaments under controlled conditions. Forty-four marketable filament products were tested. The total number of emitted particles (TP) varied by approximately four orders of magnitude (1E9 ≤ TP ≤ 1E13), indicating that origin of polymers, manufacturer-specific additives, and undeclared impurities have a strong influence. Our results suggest that TP characterizes an individual filament product and particle emissions cannot be categorized by the polymer type (e.g., PLA or ABS) alone. The user's choice of a filament product is therefore decisive for the exposure to released particles during operation. Thus, choosing a filament product awarded for low emissions seems to be an easily achievable preemptive measure to prevent health hazards. T2 - 11th International Aerosol Conference CY - Athens, Greece DA - 04.09.2022 KW - Ultrafine particles KW - FFF-3D-Printer KW - Indoor emission KW - Emission test chamber KW - Test method KW - Exposure risk PY - 2022 AN - OPUS4-55666 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Valet, Svenja T1 - Determination of the corrosion product layer resistance on zinc samples by using gel electrolytes N2 - Crash barriers, railings, lamp posts, waste glass containers - these are just a few of the many examples of galvanized surfaces. They withstand wind and weather for decades, which is possible thanks to a protective layer made of corrosion products. When designing the atmospheric durability of galvanized components, a linear corrosion loss is assumed. In the past 30 years, however, the surrounding atmosphere has changed a lot. Due to the restriction of sulfur exhaust air, acid rain completely disappeared in Europe and Germany, which has a direct influence on the type and protective effect of the corrosion products. Under the influence of current atmospheric conditions, zinc layers are significantly more resistant and no longer show any linear corrosion loss. The established test methods cannot correctly map this change in neither short-term nor long-term tests and thus provide incorrect results. In order to solve this problem, a new measurement method was developed at BAM that can assess the protective effect of the formed surface layers in a minimally invasive manner without damaging the sample and in short test times. For this new method, gel electrolytes are used and the so-called corrosion product layer resistance RL, which is made up of various surface resistances, is measured electrochemically. As a single measurement, the surface layer resistance can provide information about the existing corrosion protection, while time-dependent measurements assess the stability of the layer. Thus, it is possible again to evaluate the corrosion protection layer. Furthermore, this method can also be used for field measurements on real components. T2 - EUROCORR 2022 CY - Berlin, Germany DA - 28.08.2022 KW - Corrosion KW - Corrosion Testing KW - Gel electrolytes KW - Zinc and galvanized samples KW - Corrosion product layer PY - 2022 AN - OPUS4-55688 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Franz-Georg T1 - Product testing and performance N2 - Geosynthetic materials are applied in measures for coastal protection. Weathering or any damage of constructions, as shown by a field study in Kaliningrad Oblast (Russia), could lead to the littering of the beach or the sea (marine littering) and the discharge of possibly harmful additives into the marine environment. The ageing behavior of a widely used geotextile made of polypropylene was studied by artificial accelerated ageing in water-filled autoclaves at temperatures of 30 to 80° C and pressures of 10 to 50 bar. Tensile strength tests were used to evaluate the progress of ageing, concluding that temperature rather than pressure was the main factor influencing the ageing of geotextiles. Using a modified Arrhenius equation, it was possible to calculate the half-life for the loss of 50% of the strain, which corresponds to approximately 330 years. T2 - EuroGeo-7, Session Geosynthetics, Sustainability and Current Industry Challenges CY - Warschau, Poland DA - 04.09.2022 KW - Geosynthetics KW - Ageing KW - Autoclave tests PY - 2022 AN - OPUS4-55671 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schönhals, Andreas T1 - Multiple glassy dynamics of a homologous series of triphenylene-based columnar liquid crystals – A study by broadband dielectric spectroscopy, advanced calorimetry and Neutron Scattering N2 - Hexakis(n-alkyloxy)triphenylene) (HATn) consisting of an aromatic triphenylene core and alkyl side chains are model discotic liquid crystal (DLC) systems forming a columnar mesophase. In the mesophase, the molecules of HATn self-assemble in columns, which has one-dimensional high charge carrier mobility along the columns. Here, a homologous series of HATn with different length of the alkyl chain (n=5,6,8,10,12) is investigated using differential scanning calorimetry (DSC), broadband dielectric spectroscopy (BDS) and advanced calorimetric techniques including fast scanning calorimetry (FSC) and specific heat spectroscopy (SHS). The investigation of the phase behavior was done utilizing DSC experiments and the influence of the alkyl chain length on the phase behavior was revealed. By the dielectric investigations probing the molecular mobility, a γ-relaxation due to localized fluctuations as well as two glassy dynamics the αcore and αalkyl relaxation were observed in the temperature range of the plastic crystalline phase. Moreover, the observed glassy dynamics were further studied employing advanced calorimetry. All observed relaxation processes are attributed to the possible specific molecular fluctuations and discussed in detail. From the results a transition at around n=8 from a rigid constrained (n=5,6) to a softer system (n=10,12) on a molecular lenght scale was revealed with increasing alkyl chain length. A counterbalance of two competing effects of a polyethylene like behavior of the alkyl chains in the intercolumnar domains and self-organized confinement is discussed in the context of a hindered glass transition. T2 - 11th Conferenz on Broadband Dielectric Spectroscopy and its Applications CY - San Sebastian, Spain DA - 04.09.2022 KW - Discotic Liquid Crystals PY - 2022 AN - OPUS4-55672 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schönhals, Andreas T1 - Inelastic and Quasielastic Neutron Scattering Experiments on Mircroporous Membranes for Green Separation processes N2 - Polymers with intrinsic microporosity are promising candidates for the active separation layer in gas separation membranes. These polymers are characterized by a high permeability and reasonable permselectivity. The latter point is somehow surprising because for microporous systems a more Knudson-like diffusion is expected then a size dependent temperature activated sieving process. It was argued in the framework of a random gate model that molecular fluctuations on a time scale from ps to ns are responsible for the permselectivity. Her a series of microporous polynorbornenes with bulky Si side groups and a rigid backbone are considered which have different microporosity characterized by BET surface area values. First inelastic time-of-flight neutron scattering measurements were carried out to investigate the low frequency density of state (VDOS). The measured data show the characteristic low frequency excess contribution to the VDOS above the Debye sound wave level, generally known as the Boson peak in glass-forming materials. It was found the maximum position of the Boson peak correlates with the BET surface area value. For two selected comparable polynorbornenes elastic scans as well as QENS measurements by a combination of neutron time-of-flight and backscattering are carried out. A low temperature relaxation process was found for both polymers. This process was assigned to the methyl group rotation. It was analysed in terms of a jump diffusion in a three-fold potential. The analysis of the dependence of the elastic incoherent structure factor on the scattering vector yields the number of methyl groups which might be immobilized. T2 - MLZ Conference 2022: Neutrons for mobility CY - Lengries, Germany DA - 31.05.2022 KW - Polymers of intrinsic Microporosity PY - 2022 AN - OPUS4-55674 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Deumer, J. A1 - Pauw, Brian Richard A1 - Marguet, S. A1 - Skroblin, D. A1 - Taché, O. A1 - Krumrey, M. A1 - Gollwitzer, C. T1 - Small-angle X-ray scattering: characterization of cubic Au nanoparticles using Debye’s scattering formula N2 - A versatile software package in the form of a Python extension, named CDEF (computing Debye’s scattering formula for extraordinary form factors), is proposed to calculate approximate scattering profiles of arbitrarily shaped nanoparticles for small-angle X-ray scattering (SAXS). CDEF generates a quasi-randomly distributed point cloud in the desired particle shape and then applies the open-source software DEBYER for efficient evaluation of Debye’s scattering formula to calculate the SAXS pattern (https://github.com/j-from-b/CDEF). If self-correlation of the scattering signal is not omitted, the quasi-random distribution provides faster convergence compared with a true-random distribution of the scatterers, especially at higher momentum transfer. The usage of the software is demonstrated for the evaluation of scattering data of Au nanocubes with rounded edges, which were measured at the four-crystal monochromator beamline of PTB at the synchrotron radiation facility BESSY II in Berlin. The implementation is fast enough to run on a single desktop computer and perform model fits within minutes. The accuracy of the method was analyzed by comparison with analytically known form factors and verified with another implementation, the SPONGE, based on a similar principle with fewer approximations. Additionally, the SPONGE coupled to McSAS3 allows one to retrieve information on the uncertainty of the size distribution using a Monte Carlo uncertainty estimation algorithm. KW - X-ray scattering KW - SAXS KW - Non-spherical nanoparticles KW - Nanoparticles KW - Nanomaterials KW - Debye scattering equation KW - Simulation KW - Data fitting PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-557652 DO - https://doi.org/10.1107/S160057672200499X VL - 55 IS - Pt 4 SP - 993 EP - 1001 PB - International Union of Crystallography CY - Chester, England AN - OPUS4-55765 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schönauer-Kamin, Daniela T1 - Powder-Aerosol deposited (PAD) calcium manganate as n-type thermoelectric material N2 - Currently, calcium manganate CaMnO3 and calcium cobaltite Ca3Co4O9 are being investigated as n-type resp. p-type semiconducting materials as oxidation- and temperature-resistant thermoelectric materials for oxide multilayer thermoelectric generators (TEGs). In order to manufacture multilayer TEGs, pressure-assisted sintering processes at high temperatures are necessary to achieve optimal thermoelectric material properties. To realize TEGs in planar film technology, another method to obtain dense ceramic layers directly from the synthesized starting powders without a subsequent high temperature step is emerging recently: the powder aerosol deposition (PAD) method. In the present work, it is investigated whether PAD is suitable to produce dense ceramic films from Sm-doped CaMnO3 and Ca3Co4O9 powders. The resulting thermoelectric properties are characterized as a function of temperature. CaMnO3 powder could successfully be processed by PAD with resulting layer thicknesses of 5- 6 µm without any high-temperature sintering steps of the films. The electrical conductivity and the Seebeck coefficient of the films were determined in-plane from room temperature to 600 °C in air. The results show a Seebeck coefficient of around -200 µV/K, which is comparable to results of pressed and sintered bars. At 400 °C, the electrical conductivity corresponds to the conductivity of the bar. At higher temperatures the conductivity is better than with the reference. Below 400°C, the electrical conductivity is somewhat lower than that of the reference sample, a mild thermal treatment of the PAD layer improves it. It is expected that the thermal conductivity of the PAD film will be lower compared to the bars due to the nano-crystalline film morphology. This should result in a significantly increased ZT value for the PAD layers and a higher efficiency of the TEG. The work shows that both CaMnO3 and Ca3Co4O9 can be successfully processed by PAD, and the PAD films show comparable thermoelectric properties. T2 - 18th European Conference on Thermoelectrics CY - Barcelona, Spanien DA - 14.09.2022 KW - Film depositition KW - Calcium cobaltite PY - 2022 AN - OPUS4-55771 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Babutzka, Martin T1 - Vorstellung des Konzeptes und der Ziele des Arbeitskreises „Atmosphärische Korrosion“ N2 - Der Vortrag wurde im Rahmen der konstituierenden Sitzung des Arbeitskreises "Atmosphärische Korrosion" der GfKORR - Gesellschaft für Korrosionsschutz e.V. gehalten. Er stellt die zur Diskussion stehenden Fragestellungen und Herausforderungen im Bereich der atmosphärischen Korrosion zusammen, denen sich der neue Arbeitskreis widmen wird. T2 - Konstituierende Sitzung des GfKORR-Arbeitskreises „Atmosphärische Korrosion“ CY - Frankfurt a. M., Germany DA - 19.09.2022 KW - Atmosphärische Korrosion KW - Korrosion KW - Korrosionsschutz PY - 2022 AN - OPUS4-55772 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schwarz, Silke T1 - Elektrostatische Empfindlichkeit von Explosivstoffen: Grundlagen, Messprinzip und erste Ergebnisse mit dem X-Spark-10 N2 - Der Vortrag stellt die neuesten Entwicklungen an der BAM zur Bestimmung der elektrostatischen Empfindlichkeit von Explosivstoffen dar. Ausgehend von der Motivation unsererseits diese Thematik wieder intensiver zu bearbeiten werden ein neues Messgerät und erste Ergebnisse vorgestellt. Lücken im sicherheitstechnischen Regelwerk zur Einstufung von Explosivstoffen hinsichtlich ihrer elektrostatischen Empfindlichkeit und daraus abgeleiteter Schutzmaßnahmen in der Industrie werden dargestellt. T2 - BG RCI Erfahrungsaustausch "Explosivstoff-Industrie" CY - Bremerhaven, Germany DA - 22.09.2022 KW - Explosivstoffe KW - elektrostatische Empfindlichkeit PY - 2022 AN - OPUS4-55750 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Junge, P. A1 - Stargardt, Patrick A1 - Kober, D. A1 - Greinacher, M. A1 - Rupprecht, C. T1 - Thermally Sprayed Al2O3 Ceramic Coatings for Electrical Insulation Applications N2 - Thermal spraying enables a fast and propelling way to additively deposit various ceramics as electric insulators, which are used in conditions where polymers are not suitable. Alumina (Al2O3) is among the most employed materials in the coating industry since it exhibits good dielectric properties, high hardness, high melting point while still being cost-effective. Various parameters (e.g. feedstock type, plasma gas mixture, plasma power) significantly influence the resulting coating in terms of microstructure, porosity, crystallinity, and degree of un-or molten particles. As a consequence, these parameters need to be investigated to estimate the impact on the electrical insulating properties of thermally sprayed alumina. This study focuses on the development of a novel electric insulation coating from Al2O3 feedstock powders deposited via atmospheric plasma spray (APS). The microstructure, porosity, and corresponding crystallographic phases have been analyzed with optical microscopy, XRD, and SEM images. To achieve an understanding of the parameters influencing the electrical insulation performance of the manufactured coatings, an in-depth analysis of the fundamental dielectric parameters e.g., DC resistance, breakdown strength, dielectric loss tangent, permittivity is presented. T2 - International Thermal Spray Conference and Exposition 2022 CY - Vienna, Austria DA - 04.05.2022 KW - Thermal Spray KW - Alumina KW - Dielectric properties PY - 2022 SP - 1 EP - 8 AN - OPUS4-55821 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kotula, Stefan T1 - Zinkbeizen nach alter ISO 8407 N2 - Der Vortrag beschäftigt sich mit der Problemstellung der Entfernung von Korrosionsprodukten auf Zinkoberflächen zur Bewertung des Masseverlustes. Er diskutiert die Diskrepanzen zwischen der alten Version der ISO 8407 und der aktuellen Version. T2 - Sitzung des DIN-Gemeinschaftsarbeitskreises NA 062 01 77 01 GAK CY - Online Meeting DA - 22.09.2022 KW - Atmosphärische Korrosion KW - Deckschichtbildung KW - ISO 8407 KW - Korrosion PY - 2022 AN - OPUS4-55807 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bonse, Jörn T1 - Laser-induced Periodic Surface Structures (LIPSS): Mechanisms, Applications, and unsolved Problems N2 - Laser-induced Periodic Surface Structures (LIPSS, ripples) are a universal phenomenon and can be generated in a contactless, single-step process on almost any type of solid upon irradiation with intense laser pulses. They represent a (quasi-)periodic modulation of the surface topography in the form of a linear grating and are typically formed in a “self-ordered” way in the focus of a laser beam. Thus, they are often accompanying laser material processing applications. The structural sizes of LIPSS typically range from several micrometers down to less than 100 nanometers – far beyond the optical diffraction limit – while their orientations exhibit a clear correlation with the local polarization direction of the laser radiation. From a theoretical point of view, a controversial debate has emerged during the last decades, whether LIPSS originate from electromagnetic effects (seeded already during the laser irradiation) – or whether they emerge from matter-reorganization processes (distinctly after the laser irradiation). From a practical point of view, however, LIPSS represent a simple and robust way for the nanostructuring of solids that allows creating a wide range of different surface functionalities featuring applications in optics, tribology, medicine, energy technologies, etc. While the currently available laser and scanner technology already allows surface processing rates at the m^2/min level, industrial applications of LIPSS are sometimes limited by the complex interplay between the nanoscale surface topography and the specific surface chemistry. This typically manifests in difficulties to control the processing of LIPSS and in limitations to ensure the long-term stability of the created surface functions. This presentation reviews the currently existent theories of LIPSS. A focus is laid on the historic development of the fundamental ideas behind the LIPSS, their corresponding mathematical descriptions and numerical implementations, along with a comparison and critical assessment of the different approaches. Moreover, some unsolved scientific problems related to LIPSS are identified and the pending technological limitations are discussed. Hereby, it is intended to stimulate further research and developments in the field of LIPSS for overcoming these limitations and for supporting the transfer of the LIPSS technology into industry T2 - 10th International LIPSS Workshop 2022 CY - Orléans, France DA - 21.09.2022 KW - Laser-induced periodic surface structures (LIPSS) KW - Surface functionalization KW - Femtosecond laser processing KW - Time-resolved coherent scattering PY - 2022 AN - OPUS4-55814 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Singh, S. A1 - Palani, I. A. A1 - Paul, C. P. A1 - Funk, Alexander A1 - Gokuldoss, P. K. T1 - Wire Arc Additive Manufacturing of NiTi 4D Structures: Influence of Interlayer Delay N2 - Shape memory alloy structures for actuator and vibration damper applications may be manufactured using wire arc additive manufacturing (W AAM), which is one of the additive manufacturing technologies. Multilayer deposition causes heat accumulation during W AAM, which rises the preheat temperature of the previously created layer. This leads to process instabilities, which result in deviations from the desired dimensions and mechanical properties changes. During W AAM deposition of the wall structure, a systematic research is carried out by adjusting the interlayer delay from 10 to 30 s. When the delay period is increased from 10 to 30 s, the breadth decreases by 45% and the height increases by 33%. Grain refinement occurs when the interlayer delay duration is increased, resulting in better hardness, phase transformation temperature, compressive strength, and shape recovery behavior. This study shows how the interlayer delay affects the behavior of W AAM-built nickel-titanium alloy (NiTi) structures in a variety of applications. KW - Wire are additive manufacturing KW - Shape memory alloy KW - Nitinol KW - Interlayer delay PY - 2022 DO - https://doi.org/10.1089/3dp.2021.0296 SN - 2329-7662 SP - 1 EP - 11 PB - Liebert CY - New Rochelle, NY AN - OPUS4-55795 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mehri, S. A1 - Kolmangadi, Mohamed Aejaz A1 - Dyre, J.C. A1 - Ingebrigtsen, T.S. T1 - Lines of invariant physics in the isotropic phase of the discotic Gay-Berne model N2 - The Gay-Berne model is studied numerically with a choice of parameters allowing for the formation of a discotic liquid crystal at low temperatures. We show that the model has strong virial potential-energy correlations in the isotropic phase at high temperatures, i.e., it obeys the criterion for the existence of isomorphs, which are curves of approximately invariant structure and dynamics. These properties are demonstrated to be approximately invariant in reduced units along the isomorph studied. The isomorph is described well by the constant density-scaling exponent 11.5, a number that is significantly larger than the density-scaling exponents of various Lennard-Jones models that are always below 6. KW - Liquid Crystal KW - Molecular Dynamics PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-547611 DO - https://doi.org/10.1016/j.nocx.2022.100085 VL - 14 SP - 1 EP - 7 PB - Elsevier B.V. AN - OPUS4-54761 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishmastnehi, Moslem A1 - Stawski, Tomasz T1 - Crystals of Gypsum in Hands of Masters N2 - The microstructure of most Seljuk and Ilkhanid stucco decorations consists of micrometer-sized crystals of gypsum. The stucco-masters of these periods (neither nowadays stucco-masters) were not able to directly control the properties of these tiny crystals with their hands or centimeter-sized tools. There are, however, traces of chaîne opératoire accumulated in the materialistic body of these pieces, some of which could be explored through an interdisciplinary approach. Such an investigation requires very careful in situ observation of the macrostructure, and scientific analyses of the material to discover part of the production process for each body of stucco. Furthermore, there are deterioration factors, some of which are not yet fully understood, and should be identified using modern analytical instruments. These damaging factors could easily affect the micro and macro structure of a stucco decoration, influencing our interpretation. The concept of chaîne opératoire reframes our questions about the production process and probable dating technique of Seljuk and Ilkhanid stuccoes, while analyses of labmade replicas and historic materials enhance our understanding and interpretation of these materials. Here we present the results of such a study for a large body of Seljuk and Ilkhanid stucco decorations at various sites in Iran, and present the potential of this approach as a new perspective in this field of research. T2 - Stucco in the Architecture of Iran and Neighbouring Lands CY - Bamberg, Germany DA - 04.05.2022 KW - Gypsum KW - Stuccos KW - Crystallization PY - 2022 AN - OPUS4-54782 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Epperlein, Martin T1 - Eine digital gestützte Qualitätssicherung für die additive Fertigung N2 - Die additive Fertigung (ugs. „3D-Druck“) ist bei der Herstellung von hochkomplexen metallischen Bauteilen, bionisch inspiriertem Leichtbau oder Prototypen nicht mehr wegzudenken. Für die konventionelle Fertigung hat sich das bestehende System der Qualitätsinfrastruktur (QI) bewährt. Die additive Fertigung vergrößert den gestalterischen Spielraum von möglichen Bauteilgeometrien und Prozessfehlern jedoch erheblich. Hier gerät die QI an ihre Grenzen, sodass die Fertigung und Zulassung sicherheitsrelevanter Bauteile sehr zeit- und kostenintensive Versuche erfordern. Eine moderne digitale QI erlaubt eine effizientere Qualitätssicherung für additiv gefertigte Bauteile. Dies erfordert eine durchgängig digitale Abbildung des physischen Materialflusses. T2 - Werner-von-Siemens Centre for Industry and Science - AM Querschnittstreffen CY - Online meeting DA - 21.06.2022 KW - Additive Fertigung KW - Qualitätssicherung KW - Digitalisierung PY - 2022 AN - OPUS4-55127 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Svetlov, I. L. A1 - Epishin, A. I. A1 - Petrushin, N. V. A1 - Gerstein, G. A1 - Nolze, Gert A1 - Maier, H. J. T1 - Creep of Directionally Solidified Eutectics Ni/Ni3 Al–NbC under Thermal Cycling N2 - A nickel-based eutectic alloy with a γ/γ'-NbC structure was directionally solidified with a planar front. The specimens were tested for creep under sawtooth thermal cycling in the temperature range from 600 to 1100°C. It has been established that the lifetime under the conditions of thermal cycling is about five times shorter than it is predicted by the linear damage accumulation rule on the basis of results of isothermal creep tests. Faster creep under thermal cycling is caused by the rapid coarsening of the γ/γ' microstructure due to the periodic partial dissolution and reprecipitation of the γ' phase in heating and cooling half-cycles. KW - High temperature nickel-based eutectic alloys KW - γ/γ' matrix KW - Carbide phase NbC KW - In-situ composites KW - Creep under thermal cycling PY - 2022 DO - https://doi.org/10.1134/S2075113322040347 SN - 2075-1133 VL - 13 IS - 4 SP - 1099 EP - 1108 PB - Springer Science + Business Media CY - Dordrecht AN - OPUS4-55163 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zhu, Jiangchao T1 - Burst behaviours of aero-engine turbine disk at overspeed conditions N2 - This presentation focuses on the basic ideas and current status of the development of an arithmetical method to predict the failure rotational speed of turbine disks. The certification specification requires that a gas turbine aero-engine must hold 5 minutes at overspeed conditions without critical failure. Therefore, instead of experimental proof from spin-tests using test-disks similar to engine components, it is considered to use simple specimen with similar test conditions compared to real overspeed scenarios. These test conditions, or stress fields are determined using arithmetical method, e.g. finite element method, with consideration of fracture mechanics under quasi-static conditions with a given rotational speed. Failure modes like hoop burst and rim peeling are considered during determination of stress fields. Various crack-tip parameters are used to explore the similarity of stress field between simple specimen and real overspeed scenarios. Additionally, probabilistic aspects and the implementation of a global stability criterion for overspeed analysis are also considered. T2 - 43rd Materials Mechanics Seminar CY - Sani, Chalkidiki, Greece DA - 06.06.2022 KW - Structural integrity KW - Fracture mechanics KW - Turbine disk KW - Overspeed PY - 2022 AN - OPUS4-55081 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zhu, Jiangchao T1 - Fracture mechanics-based structural integrity assessment of aero-engine turbine disks under overspeed conditions N2 - Aero-engine turbine disks are safety-relevant components which are operated under high thermal and mechanical stress conditions. The actual part qualification and certification procedures make use of spin-tests conducted on production-similar disks. While these tests provide, on the one hand, a reliable definition of the critical conditions for real components, on the other hand they represent a relevant cost item for engine manufacturers. The aim of this work is to present part of a fracture mechanics-based procedure under development which aims at replacing the tests on production-similar disks with lab tests on fracture mechanics specimens. In particular, the rim-peeling failure mode is considered as case study. A semi-circular surface crack is modelled at the most stressed region at the diaphragm of a turbine disk, with the crack plane perpendicular to the radial direction. The crack is therefore subjected to a biaxial stress state and grows under increasing rotational speed until it triggers the rim-peeling failure. The finite element simulation of the cracked disk considers the real thermal and mechanical loading conditions. In order to design a lab representative specimen, beside the crack driving force, expressed in terms of J-integral, also the constraint to plastic deformation e.g., stress triaxiality, at the crack-tip must be similar for the same crack in the specimen and in the disk. This has been achieved and as expected, both the highest J-integral and constraint factor are calculated at the same location along the crack front for both disk and specimen. The results of the structural integrity assessment in the form of a Failure Assessment Diagram (FAD) show good agreement between designed specimen and disk both in terms of expected failure mode and value of the critical speed. Probabilistic aspects are also considered in the calculations. T2 - Turbo Expo 2022 CY - Rotterdam, Netherlands DA - 13.06.2022 KW - Structural integrity KW - Fracture mechanics KW - Turbine disk KW - Overspeed PY - 2022 AN - OPUS4-55082 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bresch, Sophie T1 - Oxidkeramische Werkstoffe und Folien für thermoelektrische Multilayergeneratoren N2 - Thermoelektrische Effekte beschreiben die direkte Verknüpfung von thermischer Energie und elektrischer Energie in Festkörpern. Durch Thermodiffusionsströme entsteht direkt, ohne beweg¬liche Teile, ein elektrisches Feld als Folge einer Temperaturdifferenz. Diese Material-eigenschaft wird durch den Seebeckkoeffizienten beschrieben. Je nach Art der Ladungs¬träger sind die indu¬zierte Spannung und der Seebeckkoeffizient positiv (p-Typ) oder negativ (n-Typ). Thermo¬elek¬trische Effekte lassen sich beispielsweise in Thermo¬elementen zur Temperatur-messung, in Pel¬tierelementen zum Kühlen oder Heizen und in thermo¬elektrischen Generatoren zur Umwandlung von thermischer Energie in elektrische Energie nutzen. In thermoelektrischen Generatoren werden Schenkel aus p-Typ- und n-Typ-Materialien elek-trisch in Reihe und thermisch parallel verschaltet. Konventionell werden einzelne Schenkel aus Bismut¬tellurid auf ein metallisiertes Substrat gelötet. Man spricht vom π-Typ-Design. Aufgrund auf¬wendiger Fertigung und nicht optimaler Flächennutzung stellt dieses Design nicht die best-mög¬liche Lösung dar. Neben Telluriden gibt es noch andere vielversprechende thermoelektrische Material¬systeme wie die oxidischen Thermoelektrika. Im Temperatur¬bereich oberhalb von 700 °C können oxidische thermoelektrische Materialien mit nichtoxidischen konkurrieren. Zudem sind sie oxidationsbeständig und können aus weniger toxischen und besser verfügbaren Rohstoffen her¬ge¬stellt werden. Da es sich um keramische Materialien handelt, können unter Nutzung der Multi¬layer¬technologie (auch Vielschicht- oder Mehrlagentechnik) Generatoren im Multilayer¬design hergestellt werden. Keramische Multi¬layer¬generatoren sind aufgrund der höheren Leis¬tungs¬dichte, der Möglichkeit der gezielten Texturierung und des hohen möglichen Auto¬mati¬sierungs¬grades des Herstellungs¬prozesses eine viel¬versprechende Alternative zu konven¬tionellen π-Typ-Generatoren. Alle Lagen werden in einem Schritt co-gesintert. Die beiden zum jetzigen Zeit¬punkt wohl viel¬versprechendsten oxi¬dischen Thermoelektrika sind Calcium-cobaltit Ca3Co4O9 als p-Typ und Calciummanganat CaMnO3 als n-Typ. Die Sinter¬tem¬peratur von Ca3Co4O9 ist durch eine Phasenumwandlung bei 926 °C beschränkt. Texturiertes, dichtes Ca3Co4O9 mit einer hohen Festigkeit kann nur über Hei߬pressen hergestellt werden. Das Co-Sintern von Ca3Co4O9 und CaMnO3 war wegen der Tem¬pera¬tur¬differenz von 350 K zwischen den jeweiligen Sinterintervallen bisher nicht möglich. Ziel dieser Arbeit war deshalb die Ent¬wick¬lung von kompatiblen oxidkeramischen Werkstoffen und Folien für thermoelektrische Multilayer-generatoren auf der Basis von Ca3Co4O9 und CaMnO3. Daraus resultieren vier wesentliche Arbeitspakete. Zunächst die Materialentwicklungen von Ca3Co4O9 (p-Typ) und CaMnO3 (n-Typ) für ein Co-Sintern bei 900 °C mit akzeptablen thermoelek¬trischen Eigenschaften, dann die Entwicklung der weiteren im Generator benötigten Kompo¬nenten wie der Isolationsschicht und abschließend die Fertigung und Bewertung von Demonstra¬toren im Multi¬layer¬design. Foliengießen und druckunterstütztes Sintern ermöglichen die Herstellung von dichtem, tex-turier¬tem Ca3Co4O9 mit hoher Festigkeit und hohem Leistungsfaktor. Letzterer ist das Produkt der elek¬trischen Leitfähigkeit und dem Quadrat des Seebeckkoeffizienten. Für die elektrische Leit¬fähigkeit zeigte sich in dieser Arbeit ein kombinierter Einfluss von Sinterdichte und Textur. Die thermo¬elektrischen Eigen¬schaften lassen sich somit über die Einstellung der Mikrostruktur gezielt steuern. Durch die Optimierung der Pulversynthese, die Einführung des Sinteradditives CuO und die Kombi¬nation mit dem druckunterstützten Sintern (7,5 MPa) konnte die Sintertemperatur des CaMnO3 bei gleichbleibendem Leistungsfaktor von 1250 °C auf 950 °C gesenkt werden. Druck-unter¬stütztes Sintern von CaMnO3 ist bei 900 °C möglich, führt aber zu einem Werkstoff mit geringerem Leistungsfaktor, geringerer Dichte und ungenügender Festigkeit. Zur elektrischen Isolation der beiden thermoelektrischen Materialien wurde ein Glas-Keramik-Kompo¬sit mit hohem Volumenwiderstand und angepasstem Wärmeausdehnungs¬koef¬fizienten ent¬wickelt. Aus den zu Folien vergossenen thermoelektrischen Materialien, der siebgedruckten Iso¬lations-schicht und der siebgedruckten Metallisierung wurden mittels Multilayertech¬nologie De¬mons-tratoren hergestellt. Neben dem pn-Generator aus Ca3Co4O9 und CaMnO3 wurden auch Unileg-generatoren aus Ca3Co4O9 gefertigt. Bei Unileggeneratoren wird die Komplexität des Aufbaus durch die Verwendung von nur einem thermoelektrischen Material verringert. Die Simulation der Demonstratoren zeigte, dass der pn-Generator aus Ca3Co4O9 und CaMnO3 keine höheren Leis-tungsdichten erbringt als der aus nur Ca3Co4O9 bestehende Unileg¬generator. Auf¬grund des ge-ringen Leistungsfaktors und der geringen Festigkeit des bei 900 °C gesinterten CaMnO3 er¬scheint die Fertigung von pn-Multilayer¬generatoren aus Ca3Co4O9 und CaMnO3 derzeit nicht sinn¬voll. Die Unileg¬generatoren aus Ca3Co4O9 erreichen mit sehr hoher Reproduzier¬barkeit 2 mW/cm² bei einer Temperaturdifferenz von 230 K, dies entspricht 80 % der simulierten elektrischen Leistung. Es handelt sich hierbei um den ersten Machbarkeits¬nachweis zur Herstellung von Multilayer-generatoren auf Basis von texturiertem Ca3Co4O9 mit hohem thermoelektrischem Leistungsfaktor, hoher Dichte und hoher Festigkeit. Solch thermoelektrische Multilayergeneratoren könnten zukünftig Systeme mit geringen elek-trischen Leistungsanforderungen wie Sensoren autark und nachhaltig mit elektrischer Energie ver¬sorgen. T2 - Promotionskolloquium CY - Bayreuth, Germany DA - 25.04.2022 KW - Calciumcobaltit KW - Calciummanganat KW - Foliengießen KW - Sintertemperatur PY - 2022 AN - OPUS4-54726 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Riechers, Birte A1 - Roed, L. A1 - Mehri, S. A1 - Ingebrigtsen, T. A1 - Hecksher, T. A1 - Dyre, J. A1 - Niss, K. T1 - Predicting nonlinear physical aging of glasses from equilibrium relaxation via the material time N2 - The noncrystalline glassy state of matter plays a role in virtually all fields of materials science and offers complementary properties to those of the crystalline counterpart. The caveat of the glassy state is that it is out of equilibrium and therefore exhibits physical aging, i.e., material properties change over time. For half a century, the physical aging of glasses has been known to be described well by the material-time concept, although the existence of a material time has never been directly validated. We do this here by successfully predicting the aging of the molecular glass 4-vinyl-1,3-dioxolan-2-one from its linear relaxation behavior. This establishes the defining property of the material time. Via the fluctuation-dissipation theorem, our results imply that physical aging can be predicted from thermal-equilibrium fluctuation data, which is confirmed by computer simulations of a binary liquid mixture. KW - Physical aging KW - Equilibrium relaxation KW - Glass PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-546015 DO - https://doi.org/10.1126/sciadv.abl9809 SN - 2375-2548 VL - 8 IS - 11 SP - 1 EP - 8 PB - American Association for the Advancement of Science CY - Washington, DC AN - OPUS4-54601 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Erning, Johann Wilhelm T1 - Hygienic assessment of SLM-printed stainless steel N2 - Elektrochemische Messungen zur hygienischen Bewertung additiv gefertigter Bauteile werden diskutiert. Die Bewertung und Details des Werkstoffs werden beschrieben, Anwendungsbeispiele gezeigt. T2 - Kormat 2022 CY - Online meeting DA - 26.04.2022 KW - Korrosion KW - Trinkwasser KW - Hygienische Bewertung KW - Additive Fertigung PY - 2022 AN - OPUS4-54709 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lohrer, Christian T1 - Normung Explosivstoffe & Pyrotechnik - Quo vadis? N2 - Vorstellung der aktuellen Normungstätigkeiten mit Bezug zu Explosivstoffen und pyrotechnischen Gegenstände. T2 - 43. Informationstagung Sprengtechnik CY - Siegen, Germany DA - 22.04.2022 KW - Normung KW - Zünder KW - Explosivstoffe KW - Pyrotechnik KW - Feuerwerk PY - 2022 AN - OPUS4-54690 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Gook, S. A1 - El-Sari, B. A1 - Biegler, M. A1 - Rethmeier, Michael A1 - Lichtenthäler, F. A1 - Stark, M. T1 - Multiple-wire submerged arc welding of high-strength fine-grained steels N2 - Ensuring the required mechanical-technological properties of welds is a critical issue in the application of multi-wire submerged arc welding processes for welding high-strength fine-grained steels. Excessive heat input is one of the main causes for microstructural zones with deteriorated mechanical properties of the welded joint, such as a reduced notched impact strength and a lower structural robustness. A process variant is proposed which reduces the weld volume as well as the heat input by adjusting the welding wire configuration as well as the energetic parameters of the arcs, while retaining the advantages of multiwire submerged arc welding such as high process stability and production speed. KW - Submerged arc welding KW - High-strength fine-grained steels KW - Mechanical properties of the joints KW - Energy parameters of the arc PY - 2022 DO - https://doi.org/10.37434/tpwj2022.01.02 SN - 0957-798X IS - 1 SP - 9 EP - 13 PB - Paton Publishing House CY - Kiev AN - OPUS4-54701 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lohrer, Christian T1 - Misuse of pyrotechnics - a hazard assessment N2 - The contribution focuses on intentional misuse of pyrotechnic articles, which are for the EU-market CE-marked and tested according to an intended use as declared by the manufacturer. Specific properties of the articles and associated hazards in view of the intended use and - in comparison - the illegal use are presented. Moreover, the basic concepts of the conformity assessment procedures and selected standard requirements for the articles concerned are described. T2 - Security of Explosives pan-European Specialists Network — EXERTER, Virtual Conference - Year 4, topic: “Criminal use of explosives” CY - Online meeting DA - 06.04.2022 KW - Misuse KW - Pyrotechnics KW - Explosives KW - Intended use PY - 2022 AN - OPUS4-54614 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stawski, Tomasz A1 - Van Driessche, A. E. S. T1 - Editorial for special issue "Formation of sulfate minerals in natural and industrial environments" N2 - Sulfate is abundant in the environment and, as a result, sulfate-containing minerals constitute a large and important focus of research. These minerals play an important role in many geochemical and industrial processes, including the sulfur cycle, the construction industry (e.g., plaster of Paris), fault tectonics, acid mine drainage, and even rare biominerals. Important to note are the abundant amounts of sulfate (minerals) located on the surface of Mars, and in meteorites, extending the relevance of this mineral group beyond the realm of our planet. In geological systems, sulfate minerals such as barite are also important for indicating certain sedimentation environments. In this regard, sulfate deposits can be used to evaluate the redox state of ancient oceans during early Earth time periods. KW - Calcium sulfate KW - Sulfates PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-546794 DO - https://doi.org/10.3390/min12030299 SN - 2075-163X VL - 12(3) IS - Special issue "Formation of sulfate minerals in natural and industrial environments" SP - 1 EP - 3 PB - MDPI CY - Basel AN - OPUS4-54679 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lohrer, Christian T1 - Fachbereich 2.5 Konformitätsbewertung Explosivstoffe/Pyrotechnik N2 - Vorstellung der aktuellen Aufgaben und Tätigkeiten des FB 2.5 Konformitätsbewertung Explosivstoffe/Pyrotechnik T2 - 43. Informationstagung Sprengtechnik CY - Siegen, Germany DA - 22.04.2022 KW - Benannte Stelle KW - Konformitätsbewertung KW - Normung KW - FE KW - Beratung Behörden/Ministerien PY - 2022 AN - OPUS4-54688 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lohrer, Christian T1 - Forschungsschwerpunkte im Fachbereich 2.5 Konformitätsbewertung Explosivstoffe/Pyrotechnik N2 - Vorstellung der aktuellen Forschungsthemen mit Bezug zu Explosivstoffen und pyrotechnischen Gegenstände T2 - 43. Informationstagung Sprengtechnik CY - Siegen, Germany DA - 22.04.2022 KW - Alterung von Pyrotechnik KW - Sprengplattieren KW - Fallhammer KW - Zünder PY - 2022 AN - OPUS4-54689 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krüger, Jörg T1 - X-ray hazards and radiation protection aspects in ultrashort laser processing N2 - Ultrashort pulse laser micromachining at repetition rates of several hundreds of kHz allows a cost-effective high precision manufacturing, which makes this method attractive for many industrial applications. Upon exceeding a critical laser intensity, hard X-ray radiation is generated as a side effect. Even if the emitted X-ray dose per laser pulse is low, for currently available high-repetition-rate laser systems the accumulated X-ray dose becomes significant and radiation safety must be considered. Influences of the processing parameters are discussed and radiation protection aspects will be outlined T2 - AKL’22 – International Laser Technology Congress CY - Aachen, Germany DA - 04.05.2022 KW - Ultrashort pulse laser processing KW - X-ray emission KW - Radiation protection PY - 2022 AN - OPUS4-54805 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Chambers, M. S. A1 - Hunter, R. D. A1 - Hollamby, M. J. A1 - Pauw, Brian Richard A1 - Smith, A. J. A1 - Snow, T. A1 - Danks, A. E. A1 - Schnepp, Z. T1 - In Situ and Ex Situ X‑ray Diffraction and Small-Angle X‑ray Scattering Investigations of the Sol−Gel Synthesis of Fe3N and Fe3C N2 - Iron nitride (Fe3N) and iron carbide (Fe3C) nanoparticles can be prepared via sol−gel synthesis. While sol−gel methods are simple, it can be difficult to control the crystalline composition, i.e., to achieve a Rietveld-pure product. In a previous in situ synchrotron study of the sol−gel synthesis of Fe3N/Fe3C, we showed that the reaction proceeds as follows: Fe3O4 → FeOx → Fe3N → Fe3C. There was considerable overlap between the different phases, but we were unable to ascertain whether this was due to the experimental setup (side-on heating of a quartz capillary which could lead to thermal gradients) or whether individual particle reactions proceed at different rates. In this paper, we use in situ wide- and small-angle X-ray scattering (wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS)) to demonstrate that the overlapping phases are indeed due to variable reaction rates. While the initial oxide nanoparticles have a small range of diameters, the size range expands considerably and very rapidly during the oxide−nitride transition. This has implications for the isolation of Rietveld-pure Fe3N, and in an extensive laboratory study, we were indeed unable to isolate phasepure Fe3N. However, we made the surprising discovery that Rietveld-pure Fe3C nanoparticles can be produced at 500 °C with a sufficient furnace dwell time. This is considerably lower than the previous reports of the sol−gel synthesis of Fe3C nanoparticles. KW - Small-angle X-ray Scattering KW - SAXS KW - Diffraction KW - XRD KW - Scattering KW - Sol-gel KW - Iron nitride KW - Nanoparticles KW - Iron carbide KW - Catalyst KW - In-situ KW - Ex-situ KW - Synthesis KW - Synchrotron PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-548226 DO - https://doi.org/10.1021/acs.inorgchem.1c03442 VL - 61 IS - 18 SP - 6742 EP - 6749 PB - ACS Publications CY - Washington AN - OPUS4-54822 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Erning, Johann Wilhelm T1 - Hygienische Eigenschaften von additiv gefertigtem 1.4404 in Trinkwasser N2 - Elektrochemische Messungen zur hygienischen Bewertung additiv gefertigter Bauteile werden diskutiert. Die Bewertung und Details des Werkstoffs werden beschrieben, Anwendungsbeispiele gezeigt. T2 - 3. Fachtagung Werkstoffe und Additive Fertigung CY - Dresden, Germany DA - 11.05.2022 KW - Korrosion KW - Trinkwasser KW - Hygiene KW - Additive Fertigung PY - 2022 AN - OPUS4-54829 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scheuschner, Nils T1 - In-situ Prozessüberwachung in der additiven Fertigung von Metallen (PBF-LB /M) mittels TT und ET N2 - Durch die additive Fertigung ergeben sich durch die nun mögliche wirtschaftliche Fertigung hochgradig individueller und komplexer metallischer Bauteile in kleinen Stückzahlen bis hinunter zum Einzelstück für viele Industriebereiche ganz neue Möglichkeiten. Gleichzeitig entstehen jedoch neue Herausforderungen im Bereich der Qualitätssicherung, da sich auf statistischen Methoden beruhende Ansätze nicht anwenden lassen, ohne wiederum die Vorteile der Fertigung massiv einzuschränken. Eine mögliche Lösung für dieses Problem liegt in der Anwendung verschiedener In-situ-Überwachungstechniken während des Bauprozesses. Jedoch sind nur wenige dieser Techniken kommerziell verfügbar und noch nicht so weit erforscht, dass die Einhaltung strenger Qualitäts- und Sicherheitsstandards gewährleistet werden kann. In diesem Beitrag stellen wir die Ergebnisse einer Studie über mittels L-PBF gefertigte Probekörper aus der Nickelbasis-Superlegierung Haynes 282 vor, bei denen die Bildung von Defekten durch lokale Variationen der Prozessparameter wie der Laserleistung provoziert wurde. Die Proben wurden in-situ mittels Thermographie, optischer Tomographie, Schmelzbadüberwachung und Wirbelstromprüfung sowie ex-situ mittels Computertomographie (CT) überwacht, mit dem Ziel, die Machbarkeit und die Aussichten der einzelnen Methoden für die zuverlässige Erkennung der Bildung relevanter Defekte zu bewerten. T2 - DGZfP Jahrestagung 2022 CY - Kassel, Germany DA - 23.05.2022 KW - Additive Manufacturing KW - Thermografie KW - Additive Fertigung KW - Thermography PY - 2022 AN - OPUS4-55851 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scheuschner, Nils T1 - In-situ Monitoring of PBF-LB/M by thermography, optical tomography, melt-pool-monitoring and eddy current N2 - The formation of defects such as keyhole pores is a major challenge for the production of metal parts by Laser Powder Bed Fusion (LPBF). The LPBF process is characterized by a large number of influencing factors which can be hard to quantify. Machine Learning (ML) is a prominent tool to predict the outcome of complex processes on the basis of different sensor data. In this study, a ML model for defect prediction is created using thermographic image features as input data. As a reference, the porosity information calculated from an x-ray Micro Computed Tomography (µCT) scan of the produced specimen is used. Physical knowledge about the keyhole pore formation is incorporated into the model to increase the prediction accuracy. From the prediction result, the quality of the input data is evaluated and future demands on in-situ monitoring of LPBF processes are formulated. T2 - AM Bench 2022 CY - Bethesda, Washingthon DC, USA DA - 15.08.2022 KW - Additive Manufacturing KW - Thermography KW - Additive Fertigung KW - Thermografie PY - 2022 AN - OPUS4-55854 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Burkert, Andreas A1 - Lehmann, Jens T1 - Einfach und echt schnell - Der KorroPad Test N2 - In diesem dritten Teil wird die KorroPad Prüfmethode vorgestellt und erläutert. T2 - ISER Kursleiterfortbildung 2022 CY - Düsseldorf, Germany DA - 26.09.2022 KW - Korrosion KW - nichtrostender Stahl KW - KorroPad KW - Korrosionsprüfung KW - Schnelltest PY - 2022 AN - OPUS4-55858 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kröll, Mirco T1 - Benefits of novel tools open to Industry from Open Innovation Testbeds. Effects of harmonised procedures in (digital) Tribology N2 - The work on Tribology, digitalisation, and the harmonised procedures developed in i-TRIBOMAT Open Innovation Testbed was presented. The project develops procedures and shares ideas on how to deal with characterisation techniques and provide services to end users in different places and locations, which is realised by adopting a common and widely agreed procedures. i-TRIBOMAT is active also via YouTube platform to enhance communication and spread the word amongst the interested parties and society. T2 - Workshop of NanoMECommons project: "Materials characterisation challenges to support the industry transition in the digital era" CY - Online meeting DA - 13.12.2021 KW - Tribology KW - i-TRIBOMAT KW - Characterisation KW - Digitalisation KW - Interoperability KW - Harmonisation KW - Green Deal PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-548909 DO - https://doi.org/10.5281/zenodo.6339985 SP - 14 EP - 17 AN - OPUS4-54890 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Heßmann, Jennifer T1 - Meeting the challenge of thermal joining of steel and aluminum using a new approach based on melt displacement by electromagnetic forces N2 - Environmental protection, resource conservation and CO2 reduction require new joining concepts for effective multi-material design in automotive lightweight construction. The thermal joining of dissimilar materials, especially the combination of aluminum alloys and steel, is associated with difficulties. Different material properties, such as melting point and coefficient of thermal expansion, complicate joining processes. Furthermore, the insolubility between these materials results in the formation of intermetallic phases. These brittle phases reduce the load-bearing capacity and quality of the joints. The thickness of the intermetallic phases should not reach the critical value of 10 μm to ensure good mechanical properties of the joint. It is known that a two-phase reaction layer consisting of Al5Fe2 and Al3Fe (also known as Al13Fe4) forms at the interface between solid steel and liquid aluminum. Due to high cooling rates, as it is the case in laser beam welding, metastable intermetallic compounds can form different from the equilibrium state. The formation of the intermetallic reaction layer is a diffusion-controlled process. So, it is only possible to control the growth of these phases. This problem has led to use joining methods that do not require the melting of both joining partners. A promising joining method is laser beam welding-brazing, whereby only one joining partner is melted and wets the solid joining partner. Conventional laser beam welding-brazing only results in material-fit joints and often requires the use of expensive filler materials. An additional form-fit could optimize the mechanical performance of the joint. For this reason, a new joining method for overlap configurations of dissimilar materials was developed. A laser beam melts the lower joining partner through a cavity of the upper joining partner. The created melt pool is moved upwards into the cavity of the upper joining partner due to contactless induced Lorentz forces of an AC-magnetic system. The displaced melt creates a form- and material-fit joint after solidification. The advantage of this joining technology is the absence of filler materials, flux agents and expensive auxiliary joining elements. T2 - 5th International Conference Hybrid 2022 - Materials and Structures CY - Leoben, Austria DA - 20.07.2022 KW - Joining dissimilar materials KW - Laser beam welding KW - Electromagnetic forces KW - Steel and aluminium PY - 2022 AN - OPUS4-55534 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Räpke, Toni T1 - Geometrie- und Prozesseinflüsse auf lokale Bauteileigenschaften in der metallischen additiven Fertigung mittels Laserstrahlschmelzen N2 - Die mechanischen Eigenschaften und die Standardparametersätze werden im additiven Fertigungsverfahren Laser Powder Bed Fusion (L-PBF) zumeist an Körpern ermittelt, die unter festen Randbedingungen gefertigt werden. In der Literatur wird allerdings von verschiedenen Autoren auf einen Einfluss von Geometrie und Prozess auf die resultierenden Eigenschaften hingewiesen [1, 2, 3]. Aufgrund des häufig großen Komplexitätsgrads von L-PBF Bauteilen und Prozessen, ist eine Abweichung angenommener Eigenschaften daher nicht auszuschließen. Das kann besonders für tragende und sicherheitsrelevante Komponenten kritisch sein und ist eine Herausforderung für die Qualitätssicherung. Aufwendige Trial-and-Error Versuche sind zumeist die Folge. Ein einheitliches und umfassendes Verständnis der Einflussfaktoren auf die resultierenden Eigenschaften im L-PBF Prozess ist zum aktuellen Stand nicht vorhanden. In diesem Vortrag werden erste Ergebnisse einer Studie vorgestellt, in der systematisch die Bandbreite möglicher Defekt- und Mikrostrukturvariationen in L-PBF Bauteilen am Beispiel der Nickelbasislegierung Haynes 282 untersucht wird. Aufbauend auf einer modellbasierten Beschreibung des lokalen Wärmehaushalts wurden Versuchspläne entwickelt, die eine Vielzahl möglicher Prozess- und Geometriekonfigurationen realer Anwendungen abbilden können. Zur Untersuchung des Geometrieeinflusses wurden typische Geometrieelemente komplexer Strukturen und deren Ausprägungen identifiziert. Prozessseitig wurden die Position im Bauraum, Schwankungen der Laserleistung, die Zwischenlagenzeit und die Belichtungsstrategie innerhalb der Schicht als typische Faktoren berücksichtigt. Die Zwischenlagenzeit bildet dabei Variationen im Bauraumfüllgrad ab. Die Belichtungsstrategie untersucht Effekte wie die Zwischenvektorzeit (engl. inter vector time, IVT) oder die lokale Vektorlänge. Die verschiedenen Konfigurationen wurden metallografisch bewertet. Die bisherigen Ergebnisse können einen Einfluss der Geometrie und des Prozesses auf die Defektbildung und die Mikrostruktur in L-PBF Bauteilen aufzeigen. Durch prozessbegleitende thermografische in situ Messungen konnte außerdem eine Abhängigkeit von lokalen und globalen Temperaturfeldern identifiziert werden. Die Erkenntnisse zeigen zudem, dass der geometrische Einfluss auf den lokalen Wärmehaushalt von Anordnung, Gestalt und Dimensionen der zweidimensionalen Belichtungsbereiche über die Aufbauhöhe abhängt. Das gewonnene Verständnis soll in die Entwicklung von Konstruktionsrichtlinien und Prüfkörpern einfließen, um Variationen lokaler Bauteileigenschaften in der zukünftigen Bauteil- und Prozessauslegung berücksichtigen zu können. T2 - 3. Fachtagung Werkstoffe und Additive Fertigung 2022 CY - Dresden, Germany DA - 11.05.2022 KW - Additive Fertigung KW - L-PBF PY - 2022 AN - OPUS4-55516 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Heuser, Lina A1 - Nofz, Marianne T1 - Alkali and alkaline earth zinc and lead borate glasses: Structure and properties N2 - Low melting Li2O-PbO-B2O3, Me2O-ZnO-B2O3, Me = Li, Na, K, Rb and CaO-ZnO-B2O3 glasses were studied with Raman and infrared spectroscopies to advance the structural understanding of zinc borate glasses as potential candidates for substitution of lead containing glasses. Although the effect of type of alkali ions on the number (N4) of fourfold coordinated boron (B4) in the glasses is small, the alkali ions direct the type of borate groups, i.e., pentaborate in lithium, sodium, and calcium zinc borate glasses, as well as diborate in potassium and rubidium containing ones. Both groups were simultaneously found in Li2O-PbO-B2O3. Alkali ions are mainly responsible for the formation of B4-units and metaborate. Zinc ions favorably compensate non-bridging oxygen and partially form ZnO4. With decreasing N4 and field strength of the alkali ions the atomic packing density, glass transition temper ature and Young’s Modulus also decrease. The coefficient of thermal expansion increases with decreasing N4. KW - Raman spectroscopy KW - IR spectroscopy KW - Alkali zinc borate glasses KW - Lead borate glasses KW - Physical properties KW - Young’s Modulus PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-556109 DO - https://doi.org/10.1016/j.nocx.2022.100109 SN - 2590-1591 VL - 15 SP - 1 EP - 12 PB - Elsevier CY - Amsterdam AN - OPUS4-55610 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Thekkeppat, N. P. A1 - Bhattacharya, Biswajit A1 - Tothadi, S. A1 - Ghosh, S. T1 - Mechanically flexible crystals of styryl quinoline derivatives N2 - Herein, we report three crystals of styryl quinoline derivatives. All these three crystals are mechanically flexible crystals, isostructural and also all of them comply with the common underlying features for elas- tic flexibility like absence of slip plane, criss-cross packing arrangement of neighbouring tapes, presence of weak and dispersive interactions such as halogen bonds, hydrogen bonds etc. The interactions facilitate easy movement of molecules under application of pressure thereby imparting elasticity. Further, the crys- tals were found to be blue light emitting making them promising candidates for optical waveguides. The optical properties were combined with flexibility by using crystal engineering approach towards achiev- ing various applications such as flexible OLEDs, optical waveguides, flexible optoelectronics etc. KW - Mechanical flexibility KW - Halogen bond KW - Fluorescence PY - 2022 DO - https://doi.org/10.1016/j.molstruc.2022.133293 SN - 0022-2860 VL - 1265 SP - 1 EP - 7 PB - Elsevier CY - Amsterdam AN - OPUS4-55549 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tran, T. A1 - Kodisch, C. A1 - Schöttle, M. A1 - Pech May, Nelson Wilbur A1 - Retsch, M. T1 - Characterizing the thermal diffusivity of single, micrometer-sized fibers via high-resolution lock-in thermography N2 - Many advanced materials consist of fibers. They are used as nonwovens, fabrics, or in composite materials. Characterization of individual fibers allows us to predict resulting material properties. We present a measurement setup and analysis software to characterize individual, micrometer-sized fibers fast and reliably. The setup is based on the lock-in thermography principle. Thermal diffusivity values of seven reference samples agree very well with previously reported values. We use our setup to investigate critical measurement parameters like excitation frequency, excitation power, pixel size, and fiber orientation. Our results show that fibers with subpixel diameters can be measured even if they are not aligned. However, special care has to be taken to choose an adequate excitation power. Measurements at high intensities can underestimate thermal diffusivity even though the raw data looks reasonable. By automatically measuring at different excitation powers, our setup solves this issue. KW - Surfaces, coatings and films KW - Physical and theoretical chemistry KW - General energy KW - Electronic, optical and magnetic materials PY - 2022 DO - https://doi.org/10.1021/acs.jpcc.2c04254 SN - 1932-7455 VL - 126 IS - 32 SP - 14003 EP - 14010 PB - American Chemical Society (ACS) CY - Washington, DC AN - OPUS4-58128 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gradt, Thomas T1 - Reibungszahlen von Holz-Holz- und Holz-Stahl-Kontakten für Stoßdämpfer von CASTOR-Behältern N2 - Holz wird vielfach in Stoßdämpfern von Transportbehältern für radioaktives Material eingsetzt. Dafür wird oftmals Fichtenholz verwendet. Die Reibung zwischen den dabei entstehenden Grenzflächen ist von entscheidender Bedeutung. Die Ergebnisse hierzu zeigen eine gleichmäßige, mit steigender Temperatur abfallende Reibung. T2 - 63. Tribologie Fachtagung CY - Göttingen, Germany DA - 26.09.2022 KW - Reibung KW - Hokz-Holz-Kontakte KW - Holz-Stahl-Kontakte KW - CASTOR-Behälter KW - Stoßdämpfer PY - 2022 AN - OPUS4-56018 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gradt, Thomas A1 - Martin, Martin A1 - Gleim, Tobias T1 - Reibungszahlen von Holz-Holz- und Holz-Stahl-Kontakten für Stoßdämpfer von CASTOR-Behältern N2 - Holz wird vielfach in Stoßdämpfern von Transportbehältern für radioaktives Material eingesetzt. Dafür wird oftmals Fichtenholz verwendet, das in mehreren Lagen und senkrecht zueinander liegender Faserrichtung zwischen einer inneren und einer äußeren Stahlhülle eingebaut wird. Die Reibung zwischen den dabei entstehenden Grenzflächen ist von entscheidender Bedeutung für die Stoß- und Energieabsorption, z. B. bei einem Aufprall des Behälters auf eine harte Unterlage. Um detaillierte Informationen für entsprechende numerische Simulationen zu bekommen, wurden in dieser Arbeit die Reibungszahlen von Holz-Holz- und Holz-Stahl-Paarungen bei für derartige Behälter relevanten Beanspruchungsbedingungen im Temperaturbereich zwischen -40°C und 90°C gemessen. Die Ergebnisse zeigen eine gleichmäßige, mit steigender Temperatur abfallende Reibung, wobei die Werte für Holz-Stahl-Paarungen zwischen 0,43 bei -40°C und 0,22 bei 90°C sowie für Holz-Holz-Kontakte zwischen 0,3 bei -40°C und 0,24 bei 90°C liegen. T2 - 63. Tribologie-Fachtagung 2022 CY - Göttingen, Germany DA - 26.09.2022 KW - Reibung KW - Holz-Holz-Kontakte KW - Holz-Stahl-Kontakte KW - CASTOR-Behälter KW - Stoßdämpfer PY - 2022 SN - 978-3-9817451-7-7 SP - 23/1 EP - 23/4 AN - OPUS4-56021 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gradt, Thomas T1 - Tribologisches Verhalten von a-C:H- und ta-C-Schichten in Methan- und Wasserstoffumgebung N2 - Verschleißfeste Kohlenstoffschichten mit niedriger Reibung sind hervorragend für Anwendungen in der Erdgas- und Wasserstofftechnologie geeignet. Einige Varianten versagen jedoch in inerter Umgebung, was für die praktische Anwendung sehr nachteilig ist. Im Vortrag werden Beispiele aus Modellversuchen für verschiedene Varianten, auch für Flüssigmethan-Umgebung gezeigt. T2 - Workshop: Nachhaltigkeit durch Tribologische Schichten CY - Karlsruhe, Germany DA - 17.05.2022 KW - Reibung KW - Kohlenstoffschichten KW - Methan KW - Wasserstoff KW - Tribologie PY - 2022 AN - OPUS4-56014 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Raute, J. A1 - Biegler, M. A1 - Rethmeier, Michael T1 - Untersuchung zur Herstellung von Cu-Strukturen mittels Wire Electron Beam Additive Manufacturing N2 - Das Additive Manufacturing gewinnt zunehmend an Bedeutung für die Fertigung metallischer Bauteile im industriellen Umfeld. Hierbei wird zunehmend auch auf drahtförmige Ausgangswerkstoffe gesetzt, da diese Vorteile im Handling bieten, bereits in der Industrie etabliert sind und sich in der Regel durch geringere Beschaffungskosten auszeichnen. In den letzten Jahren entwickelte sich neben den bereits im großen Umfeld untersuchten Wire-DED-Verfahren auch eine Prozessvariante unter Nutzung des Elektronenstrahls zur industriellen Marktreife. Dabei zeigt die als Wire Electron Beam Additive Manufacturing bezeichnete Technologie besondere Vorteile gegenüber anderen, zumeist Laser- oder Lichtbogen-basierten DED-Prozessen. Das Verfahren bietet vor allem Potenzial für die Verarbeitung von hochleitfähigen, reflektierenden oder oxidationsgefährdeten Werkstoffen. Insbesondere für die Herstellung von Bauteilen aus Kupferlegierungen zeigt sich der Elektronenstrahl als besonders geeignet. Um das Verfahren einem breiten Anwenderkreis in der Industrie zugänglich zu machen, fehlen jedoch übergreifende Daten zu Leistungsfähigkeit, Prozessgrenzen und Anwendungsmöglichkeiten. Die vorliegende Untersuchung beschäftigt sich mit dieser Problemstellung am Beispiel zweier Cu-Werkstoffe. Dabei werden ein korrosionsbeständiger Werkstoff aus dem maritimen Bereich sowie eine Bronze mit guten Verschleißeigenschaften aus dem Anlagenbau getestet. Über mehrstufige Testschweißungen wurden die physikalisch möglichen Prozessgrenzen ermittelt und Rückschlüsse über die Eignung der Parameter zum additiven Aufbau gezogen. Hierfür wurden zunächst optimale Bereiche für den Energieeintrag anhand von Volumenenergie sowie mögliche Schweißgeschwindigkeiten untersucht. Anschließend wurde die Skalierbarkeit des Prozesses anhand von Strahlstrom und Drahtvorschub getestet. Als wesentliche Zielgrößen wurden dabei Spurgeometrie, Aufmischung und Härte herangezogen. Die Eignung der ermittelten Parameter wurde im letzten Schritt exemplarisch anhand einer additiven Testgeometrie in Form eines Zylinders nachgewiesen. T2 - DVS Congress 2022 Große Schweißtechnische Tagung DVS CAMPUS CY - Koblenz, Germany DA - 19.09.2022 KW - WEBAM KW - Electron beam KW - EBAM KW - Wire electron beam additive manufacturing PY - 2022 SN - 978-3-96144-189-1 VL - 382 SP - 446 EP - 454 PB - DVS Media AN - OPUS4-56058 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -