TY - CONF A1 - Üstündag, Ömer A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael A1 - Churiaque, C. A1 - Sanchez-Amaya, J.M. T1 - High-power hybrid laser arc welding of thick materials with electromagnetic weld pool support N2 - In addition to the many advantages of deep penetration, increased welding speed and a low sensitivity to manufacturing tolerances such as gap and edge offset, the hybrid laser arc welding (HLAW) process is used increasingly in industrial applications such as shipbuilding or pipeline manufacturing. Nonetheless, thick-walled sheets with a wall thickness of 20 mm or more are still multi-pass welded using the arc welding process, due to increased process instability by increasing laser power. Welding at reduced speed, especially in a flat position, leads to an irregular formation of the root part such as dropping. The hydrostatic pressure exceeds the surface tension, which decreases with increasing seam width. In order to prevent gravity drop-outs, the use of a melt pool support is necessary. Usual weld pool supports such as ceramic or powder supports require time-consuming mechanical detachment. The electromagnetic weld pool support system, which is described in this study, operates without contact and based on generating Lorentz forces in the weld pool. An externally applied oscillating magnetic field induces eddy currents and generates an upward directed Lorentz force, which counteracts the hydrostatic pressure. This allows single-pass welds up to 30 mm by hybrid laser arc welding process with a 20-kW fibre laser. Moreover, it is favoured by the diminished welding speed the cooling rate which leads to an improvement of the mechanical-technological properties of the seams – the lower formation of martensite in the microstructure enables better Charpy impact toughness. The electromagnetic weld pool support extends the limitation of the laser hybrid welding process in the thick sheet area. By adapting the electromagnetic weld pool support to the laser and laser hybrid welding process, the application potential of these technologies for industrial implementation can be drastically increased. T2 - 23rd Technical Conference on Welding and Joining Technologies CY - Irun, Spain DA - 07.03.2023 KW - Laser hybrid welding KW - Thick-walled steel KW - Electromagnetic backing KW - High-power laser PY - 2023 AN - OPUS4-58613 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Üstündag, Ömer A1 - Bakir, Nasim A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Analysis of microstructure and mechanical properties of single-pass laser hybrid welded thick-walled steels up to 30 mm with contactless electromagnetic backing N2 - The study deals with the influence of the heat input on the thermal cycles, the microstructure and the mechanical properties for laser-hybrid welded steels of S355J2 with thicknesses up to 30 mm using a 20-kW high-power laser with contactless electromagnetic backing. The focus is on the change of the mechanical properties over the seam thickness. Therefore, the impact toughness and tensile strength were tested in different depths. Based on the experiments, a heat input of 1.3 kJ/mm - 1.6 kJ/mm, 2 kJ/mm - 2.4 kJ/mm and 3.7 kJ/mm were recommended when single-pass welding of 20 mm, 25 mm and 30 mm with a 20-kW laser in regard to the minimum requirements of the mechanical properties, respectively. Lower heat inputs led to undesired microstructure consisting of martensite, hardening and deteriorated impact toughness, where higher heat inputs led to grain-coarsening and even loss of impact strength due to the formation of retained-austenite on the grain boundaries. T2 - EMPOrIA 2023 - International Joint Conference CY - Aachen, Germany DA - 16.05.2023 KW - Laser hybrid welding KW - Electromagnetic backing KW - Thermal cycles KW - Charpy impact toughness KW - Thick-plate welding PY - 2023 AN - OPUS4-58614 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Üstündag, Ömer A1 - Kampffmeyer, D. A1 - Wolters, M. A1 - Bakir, Nasim A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Influence of shielding gas on filler wire mixing at laser hybrid welding of thick high strength steels N2 - The laser hybrid welding process offers many advantages during welding oft hick-walled steels, such as the increased penetration depth and, thus, reduced number of layers, reduced heat input and decreased distortion compared to arc-based welding processes. Especially, when welding high-strength steels (HSS), the reduced heat input plays an essential role. However, a major challenge when laser hybrid welding of thick-walled steels is the limited filler wire mixing over the entire seam thickness, which can lead to changed mechanical properties over the depth. To overcome this issue, the add of oxygen into the shielding gas and its influence on the filler wire mixing and finally to the mechanical properties were investigated within this work. Therefore, 20 mm thick S690QL steels were laser hybrid welded in a single-pass. A contactless electromagnetic backing was used to avoid sagging. The admixture of oxygen was performed by a gas mixer, where the oxygen content was varied between 0 % and 7.2 %. The experiments were also accompanied by laser beam welding tests in steel/glass configuration, where the melt pool geometry as well as the melt flow characteristics were captured by a high-speed camera. It can be concluded, that adding of 2 % to 4 % oxygen into the shielding gas had a positive effect on the filler wire mixing, were up to a depth of 18 mm elements of the filler wire could be observed. T2 - 19th Nordic Laser Material Processing Conference CY - Turku, Finland DA - 22.08.2023 KW - Laser hybrid welding KW - Electromagnetic backing KW - Shielding gas KW - Charpy impact toughness KW - Thick-plate welding KW - Filler wire mixing PY - 2023 AN - OPUS4-58615 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Üstündag, Ömer A1 - Bakir, Nasim A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Influence of heat input on cooling rates and mechanical properties of laser hybrid welded thick structural steels N2 - The laser hybrid welding process offers many advantages such as the high penetration depth and high welding speed, and it is characterized by its low heat input compared to the arc-based welding processes, which makes the laser hybrid welding process as a suitable alternative process when welding thick-walled steels. However, there are some challenges when using laser hybrid welding process for thick steels. Due to the uneven cooling conditions and the inhomogeneous filler wire mixing, a typical laser hybrid weld can be divided into two different zones over the depth: the arc-dominated zone on the upper part and the laser-dominated zone in the root part. This leads to different mechanical properties in a laser hybrid welded joint. Due to the high cooling rates and the lack of filler wire in the laser-dominated zone, this area is more critical regarding the mechanical properties, especially the Charpy impact toughness. A low heat input can lead to undesired microstructure consisting of martensite, hardening and deteriorated impact toughness due to the high cooling rate, where higher heat inputs can lead to grain-coarsening and even loss of impact strength. This study deals with the influence of the welding speed and resulting heat input on the cooling rates, the microstructure and the mechanical properties of single-pass laser hybrid welded steels of S355J2 with thickness up to 30 mm. The experiments were performed with a 20-kW fibre laser system and a contactless electromagnetic weld backing on up to 30 mm thick steels in butt-joint configuration in 1G welding position. The cooling time was measured in three different locations near to fusion lines corresponding to different heights of the seam using a special configuration with pyrometers, collimators, and optical fibres. The test specimens for the Charpy impact testing and tensile testing were extracted in up to three different depths. Based on the experiments, a heat input of 1.3 kJ/mm - 1.6 kJ/mm, 2 kJ/mm - 2.4 kJ/mm and 3.7 kJ/mm were recommended when single-pass laser hybrid welding of 20 mm, 25 mm and 30 mm thick structural steels in regard to the minimum requirements of the mechanical properties, respectively. The optical measurement of the cooling times in different depths could be carried out reproducibly. T2 - Advances in Welding and Metal Additive Manufacturing Technologies 2023 CY - Istanbul, Türkiye DA - 30.10.2023 KW - Laser hybrid welding KW - Electromagnetic backing KW - Charpy impact toughness KW - Thick-plate welding KW - Thermal cycles PY - 2023 AN - OPUS4-58942 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ávila Calderón, Luis Alexander A1 - Shakeel, Yusra A1 - Olbricht, Jürgen A1 - Aversa, Rossella A1 - Skrotzki, Birgit T1 - NFDI-MatWerk PP18 / IUC02 Reference Data: Creep Data of a single crystalline Ni-Base Alloy N2 - Reference datasets in the MSE domain represent specific material properties, e.g., structural, mechanical, … characteristics. A reference dataset must fulfill high-quality standards, not only in precision of measurement but also in a comprehensive documentation of material, processing, and testing history (metadata). This Infrastructure Use Case (IUC) of the consortium Materials Science and Engineering (MatWerk) of National Research Data Infrastructure (NFDI) aims to develop, together with BAM and other Participant Projects (PP), a framework for generating reference material datasets using creep data of a single crystal Ni-based superalloy as a best practice example. In a community-driven process, we aim to encourage the discussion and establish a framework for identifying reference material datasets. In this poster presentation, we highlight our current vision and activities and intend to stimulate the discussion about the topic reference datasets and future collaborations and work. T2 - All-Hands-on-Deck congress from the NFDI-MatWerk CY - Siegburg, Germany DA - 08.03.2023 KW - Referenzdaten KW - Reference data KW - Creep KW - Syngle Crystal alloy KW - Metadata schema PY - 2023 AN - OPUS4-57146 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ávila Calderón, Luis Alexander A1 - Hammerschmidt, T. A1 - Stotzka, R. A1 - Forti, M. A1 - Olbricht, Jürgen A1 - Skrotzki, Birgit A1 - Lenze, A. A1 - Gedsun, A. A1 - Hickel, Tilmann A1 - Tsybenko, H. A1 - Chmielowski, M. A1 - Hunke, S. A1 - Shakeel, Y. T1 - Demonstration of the Infrastructure Use Case 02: Framework for curation and distribution of reference datasets N2 - In our current view, reference datasets in the MSE domain represent specific material properties, e.g., structural, mechanical, … characteristics. A reference dataset must fulfill high-quality standards, not only in precision of measurement but also in a comprehensive documentation of material, processing, and testing history (metadata). This Infrastructure Use Case (IUC) aims to develop a framework for generating reference material datasets using creep data of a single crystal Ni-based superalloy as a best practice example. In a community-driven process, we aim to encourage the discussion and establish a framework for the creation and distribution of reference material datasets. In this poster presentation, we highlight our current vision and activities and intend to stimulate the discussion about the topic reference datasets and future collaborations and work. T2 - NFDI-MatWerk Conference CY - Siegburg, Germany DA - 27.06.2023 KW - Referenzdaten KW - Reference data KW - Creep KW - Metadata schema KW - Syngle Crystal alloy PY - 2023 AN - OPUS4-57924 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ávila Calderón, Luis Alexander A1 - Hammerschmidt, T. A1 - Gedsun, A. A1 - Forti, M. A1 - Olbricht, Jürgen A1 - Stotzka, R. A1 - Skrotzki, Birgit A1 - Shakeel, Y. A1 - Hunke, S. A1 - Tsybenko, H. A1 - Aversa, R. A1 - Chmielowski, M. A1 - Hickel, T. T1 - IUC02 Framework for Curation and Distribution of Reference Datasets using Creep Data of Ni-Base Superalloys as an Example N2 - In our current view, reference datasets in the MSE domain represent specific material properties, e.g., structural, mechanical, … characteristics. A reference dataset must fulfill high-quality standards, not only in precision of measurement but also in a comprehensive documentation of material, processing, and testing history (metadata). This Infrastructure Use Case (IUC) aims to develop a framework for generating reference material datasets using creep data of a single crystal Ni-based superalloy as a best practice example. In a community-driven process, we aim to encourage the discussion and establish a framework for the creation and distribution of reference material datasets. In this poster presentation, we highlight our current vision and activities and intend to stimulate the discussion about the topic reference datasets and future collaborations and work. T2 - NFDI-MatWerk Conference CY - Siegburg, Germany DA - 27.06.2023 KW - Referenzdaten KW - Reference data KW - Syngle Crystal alloy KW - Creep KW - Metadata schema PY - 2023 AN - OPUS4-57923 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zurcher, Theo A1 - Serrano-Munoz, Itziar A1 - Mishurova, Tatiana A1 - Abreu Faria, Guilherme A1 - Degener, Sebastian A1 - Fridrici, Vincent A1 - Charkaluk, Eric A1 - Bruno, Giovanni T1 - Sliding wear resistance and residual stresses of parts repaired by laser metal deposition JF - Journal of Material Science N2 - Large temperature gradients inherent to additive manufacturing (AM) processes induce large residual stress (RS) in the final part. Because RS can influence the tribological properties, this study focuses on the relationship between wear sliding properties and RS in IN718 coatings. Such coatings were deposited with a Laser metal deposition (LMD) machine using two different scanning strategies. The wear resistance and RS state were investigated after surface milling. RS were measured before and after wear tests on a reciprocating sliding test apparatus. Two different X-ray diffraction techniques were employed to measure the surface and subsurface state RS: Laboratory Energy Dispersive X-ray Diffraction (LEDXD) and Synchrotron X-ray Energy Dispersive Diffraction (SXEDD). Due to the milling process, the coatings show similar depth distributions of RS from 22 to 92 μm depth, but exhibit different magnitudes depending on the scanning strategy used. Reciprocating sliding wear tests induced high compressive residual stresses that erased the initial RS state, and a similar wear behavior was observed in the two samples. These samples possess similar texture and grain morphology. This demonstrates that the influence of RS on wear resistance is a second-order effect. Nevertheless, it was observed that RS can still impact the wear performance at the early testing stages of the repaired parts. KW - Additive manufacturing KW - Wear resistance KW - Residual stress PY - 2023 DO - https://doi.org/10.1007/s10853-023-09129-4 SN - 0022-2461 SP - 1 EP - 18 PB - Springer AN - OPUS4-59084 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zocca, Andrea A1 - Müller, Bernd R. A1 - Laquai, René A1 - Kupsch, Andreas A1 - Wieder, Frank A1 - Benemann, Sigrid A1 - Wilbig, Janka A1 - Günster, Jens A1 - Bruno, Giovanni T1 - Microstructural characterization of AP40 apatite-wollastonite glass-ceramic JF - Ceramics international N2 - The microstructure of an apatite-wollastonite (code name AP40) glass-ceramic is analyzed in this study by combining 2D microscopy, phase analysis, X-ray absorption and synchrotron X-ray refraction computed tomography (XCT and SXRCT, respectively). It is shown that this combination provides a useful toolbox to characterize the global microstructure in a wide scale range, from sub-micrometer to millimeter. The material displays a complex microstructure comprising a glassy matrix with embedded fluorapatite and wollastonite small crystals. In this matrix, large (up to 200 μm) spike-shaped structures are distributed. Such microstructural features are oriented around a central sphere, thereby forming a structure resembling a sea urchin. A unique feature of SXRCT, in contrast to XCT, is that internal interfaces are visualized; this allows one to show the 3D distribution of these urchins with exceptionally good contrast. Furthermore, it is revealed that the spike-shaped structures are not single crystals, but rather composed of sub-micrometric crystals, which are identified as fluorapatite and diopside phases by SEM-EDX analysis. KW - Glass-ceramic KW - X-ray refraction KW - Computed tomography KW - Microstructure PY - 2023 DO - https://doi.org/10.1016/j.ceramint.2022.12.130 SN - 0272-8842 VL - 49 IS - 8 SP - 12672 EP - 12679 PB - Elsevier Science CY - Amsterdam AN - OPUS4-57452 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zocca, Andrea A1 - Wilbig, Janka A1 - Günster, Jens T1 - An overview of ceramic AM with focus on bioceramics and powder bed technologies N2 - The presentation will start with an overview of ceramic additive manufacturing (AM) technologies and will discuss the potential of AM in the field of bioceramics. The presentation will then focus on two possible use cases of binder jetting technologies. In the first example, standard powder-based binder jetting is used to manufacture a porous implant design for large scale bone defects. The related challenges in the process chain will be discussed, from powder synthesis to sintering and characterization of the printed part. In the second example, the LSD-print slurry-based binder jetting technology is presented as a possibility to adapt powder-bed AM to produce dense ceramic parts. The use case will focus on an application in the field of dental ceramics, specifically for the manufacturing of patient individualized single tooth restorations (veneers, crowns) with a high throughput process chain. T2 - BioCAM - Additive Manufacturing Applied to Bioceramics CY - Mons, Belgium DA - 06.12.2023 KW - Additive Manufacturing KW - Bioceramic KW - Binder Jetting PY - 2023 AN - OPUS4-60053 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zocca, Andrea A1 - Günster, Jens T1 - A comparison of layerwise slurry deposition and (LSD-print) laser induced slip casting (LIS) for the additive manufacturing of advanced ceramics N2 - The presentation gives an overview of two slurry-based additive manufacturing (AM) technologies specifically developed for advanced ceramic materials. The “Layerwise Slurry Deposition” (LSD-print) is a modification of Binder Jetting making use of a ceramic slurry instead of a dry powder as a feedstock. In this process, a slurry is deposited layer-by-layer by means of a doctor blade and dried to achieve a highly packed powder layer, which is then printed by jetting a binder. The LSD-print technology combines the high-speed printing of binder jetting with the possibility of producing a variety of high-quality ceramics with properties comparable to those achieved by traditional processing. The Laser Induced Slip casting (LIS) technology follows a novel working principle by locally drying and selectively consolidating layer-by-layer a ceramic green body in a vat of slurry, using a laser as energy source. LIS combines elements of Vat Photopolymerization with the use of water-based feedstocks containing a minimal amount of organic additives. The resulting technology can be directly integrated into a traditional ceramic process chain by manufacturing green bodies that are sintered without the need of a dedicated debinding. Both technologies offer high flexibility in the ceramic feedstock used, especially concerning material and particle size. Advantages and disadvantages are briefly described to outline the specific features of LSD-print and LIS depending on the targeted application. T2 - AM Ceramics CY - Vienna, Austria DA - 27.09.2023 KW - Additive Manufacturing KW - Dental KW - Ceramics KW - Feldspar PY - 2023 AN - OPUS4-58468 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zocca, Andrea A1 - Schubert, Hendrik A1 - Günster, Jens A1 - Hoffman, Moritz A1 - Bogna Stawarczyk, Bogna T1 - Additive Manufacturing for dental restorations by layerwise slurry deposition (LSD-print) technology N2 - The growing market of custom-made dental restorations offers a major potential for an application of ceramic additive manufacturing (AM). The possibility to individualize patient specific design and to establish new efficient workflows, from model generation to manufacturing, can be fully exploited by AM technologies. However, for mass customization to be truly envisioned, ceramic AM needs to achieve a level of maturity, aesthetic quality, and productivity comparable to established manufacturing processes. In this presentation, the potential of the “layerwise slurry deposition” LSD-print technology for dental applications will be explored. It has been shown in the past years that the LSD-print can be applied to advanced ceramic materials such as alumina and silicon-infiltrated silicon carbide. For these materials, the LSD-print technology combines the high-speed printing of binder jetting with the possibility of producing a variety of high-quality ceramics. The current development deals with the challenges of applying this technology to a feldspar dental material, comparing the quality of AM restorations with the equivalent material for an established CAD/CAM workflow. Preliminary results not only indicate that the AM material produced by LSD-print can be competitive in terms of mechanical properties, but also that aesthetically satisfactory restorations can be manufactured for veneers, inlays and onlays as well as single unit fixed dental prostheses (FDPs). The presentation focuses on the material and technological challenges alongside the process chain, from the printing process, to debinding, firing and finishing the restorations. T2 - XVIIIth Conference of the European Ceramic Society CY - Lyon, France DA - 02.07.2023 KW - Additive Manufacturing KW - Layerwise slurry deposition KW - dental KW - ceramic PY - 2023 AN - OPUS4-58469 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zhu, Jiangchao A1 - Madia, Mauro A1 - Schurig, Michael A1 - Fedelich, Bernard A1 - Schlums, Hartmut A1 - Zerbst, Uwe T1 - Burst speed assessment of aero-engine turbine disk based on failure assessment diagram and global stability criterion JF - Engineering Fracture Mechanics N2 - Aero-engine turbine disks are safety-relevant components which are operated under high thermal and mechanical stress conditions. The actual part qualification and certification procedures make use of spin-tests conducted on production-similar disks. While these tests provide, on the one hand, a reliable definition of the critical conditions for real components, on the other hand they represent a relevant cost item for engine manufacturers. The aim of this work is to present two alternative burst speed assessment methods under development based on the Failure Assessment Diagram (FAD) and a global stability criterion, respectively. In the scope of the fracture mechanics assessment, the failure modes hoop-burst and rim-peeling are investigated with semicircular surface cracks modelled at the critical regions on the turbine disk. The comparison of the predicted critical rotational speed shows good agreement between the assessment methods. KW - Global stability criterion KW - Fracture mechanics KW - Burst KW - Turbine disk PY - 2023 DO - https://doi.org/10.1016/j.engfracmech.2022.109005 SN - 0013-7944 VL - 277 SP - 1 EP - 15 PB - Elsevier Ltd. AN - OPUS4-56736 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zhang, X. A1 - Shi, L. A1 - Wu, C. A1 - Yang, Chunliang A1 - Gao, S. T1 - Multi-phase modelling of heat and mass transfer during Ti/Al dissimilar friction stir welding process JF - Journal of Manufacturing Processes N2 - Friction stir welding (FSW) has the capacity to join the Al/Ti dissimilar structures with superior mechanical properties. The microstructures and mechanical characteristics of Al/Ti dissimilar FSW joints are determined by the heat and mass transfer during the welding process. However, a quantitative study of the Al/Ti dissimilar FSW process is lacking. Therefore, using the computational fluid dynamics (CFD) and volume of fluid (VOF) approach, a multi-phase model was constructed for quantitatively analyzing the heat and mass transfer behaviour in dissimilar FSW of TC4 titanium alloy and AA2024-T4 aluminium alloy. The mixed material was treated as a functionally graded material (FGM) to compute the thermophysical characteristics at the weld nugget zone (WNZ). Due to the vast disparity in the thermophysical characteristics of aluminum and titanium alloy, the temperature field in Al/Ti dissimilar FSW was severely asymmetric. The temperature of titanium alloy on the advancing side (AS) was higher than that of aluminium alloy on the retreating side (RS) at the same distance from the tool centre line near the tool shoulder, but it was lower than that of aluminium alloy on the RS without the influence of the shoulder. Due to the high flow stress of titanium alloy, plastic material flow mostly occurred on the RS of aluminium alloy in the Al/Ti dissimilar FSW, with its percentage exceeding 80%. This model was validated by experiment results. KW - Dissimilar friction stir welding KW - Al/Ti dissimilar joints KW - Temperature distribution KW - Heat generation KW - Plastic material flow PY - 2023 DO - https://doi.org/10.1016/j.jmapro.2023.03.037 SN - 2212-4616 VL - 94 SP - 240 EP - 254 PB - Elsevier Ltd. AN - OPUS4-57265 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zhang, K. A1 - Mezhov, Alexander A1 - Schmidt, Wolfram T1 - Effect of Polycarboxylate Superplasticizer in Ordinary Portland Cement and Sulfate Resistant Cement JF - Journal of Materials in Civil Engineering N2 - Polycarboxylate superplasticizers (PCE) are the most widely used admixtures in today’s cementitious construction materials. The molecular structure has a decisive influence on the effectiveness of PCE, which also can be tailored to serve in a different cementitious system. The current study investigates the influence of the backbone charge density of PCE on the rheology, hydration kinetics, and adsorption behavior of ordinary Portland cement (OPC) and sulfate-resistant cement (SRC). The results indicate that regardless of the PCE type, OPC requires a higher amount of PCE to be adsorbed to induce changing of rheological parameters and hydration kinetics. Regardless of the cement type, the PCE with a higher charge density exhibits higher adsorption behavior, corresponding to lower viscosity measurement. Compared to OPC, SRC is more sensitive to the introduction of both PCEs and has a lower saturation dosage, indicating that SRC generally provides better workability properties regardless of the PCE. KW - Polycarboxylate superplasticizers (PCE) KW - Sulfate resistant cement (SRC) KW - Rheological KW - Adsorption KW - Cement hydration PY - 2023 DO - https://doi.org/10.1061/JMCEE7.MTENG-15033 SN - 0899-1561 VL - 35 IS - 6 SP - 1 EP - 12 PB - ASCE Libary AN - OPUS4-58244 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zekhnini, Khalid A1 - Ebell, Gino A1 - Burkert, Andreas T1 - Corrosion at metallic offshore constructions – Bundesanstalt für Materialforschung und -prüfung (BAM) N2 - In the maritime context of offshore operation, corrosion, in combination with the materials used, poses a particular challenge to ensure safe operation over long indefinite periods and to minimise susceptibility to failure. Until today, only a few corrosion protection systems have proven themselves for the interaction of efficiency, installation, and maintenance in the offshore sector. In addition, available corrosion test methods sometimes have major deficits about conclusions of the durability. Therefore, there is more research and development needed. The flagship project H2Mare of the Federal Ministry of Education and Research aims to enable the production of green hydrogen and PtX products at high seas. Research is being driven forward by the partners in four individual projects, where BAM is involved in two. In PtX-Wind, major kinds of corrosion attacks at offshore constructions are characterized and investigated, and suitable corrosion protection measures determined. In TransferWind, attention focusses on transferring scientific results into standardization. This poster at the H2Mare Conference 2023 presents an overview of the investigation methods and contribution of the department “Corrosion and Corrosion Protection”. T2 - H2Mare Conference 2023 CY - Frankfurt/Main, Germany DA - 12.06.2023 KW - Atmospheric Corrosion KW - Sea Water KW - Corrosion Testing KW - Offshore KW - Laboratory Container KW - Corrosion protecting system PY - 2023 AN - OPUS4-57838 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zaytsev, D. A1 - Funk, Alexander T1 - On the crack evolutional in human dentin under uniaxial compression imaged by high resolution tomography JF - Materials physics and mechanics N2 - An observation of the fracture process in front of the crack tip inside a dentin sample by means of ex-situ X-ray computed tomography after uniaxial compression at different deformation values was carried out in this work. This ex-situ approach allowed the microstructure and fracturing process of human dentin to be observed during loading. No cracks are observed up to the middle part of the irreversible deformation in the samples at least visible at 0.4μm resolution. First cracks appeared before the mechanical stress reached the compression strength. The growth of the cracks is realized by connecting the main cracks with satellite cracks that lie ahead of the main crack tip and parallel its trajectory. When under the stress load the deformation in the sample exceeds the deformation at the compression strength of dentin, an appearance of micro-cracks in front of the main cracks is observed. The micro-cracks are inclined (~60°) to the trajectory of the main cracks. The further growth of the main cracks is not realized due to the junction with the micro-cracks; we assume that the micro-cracks dissipate the energy of the main crack and suppressed its growth. These micro-cracks serve as additional stress accommodations, therefore the samples do not break apart after the compression test, as it is usually observed under bending and tension tests. KW - Dentin KW - Crack evolution KW - Compression strength KW - Mechanical properties KW - Microstructure KW - Ex-situ X-ray computed tomography PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-594810 DO - https://doi.org/10.18149/MPM.5152023_5 SN - 1605-8119 VL - 51 IS - 5 SP - 38 EP - 51 PB - Advanced Study Center CY - St. Petersburg AN - OPUS4-59481 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zare Pakzad, S. A1 - Nasr Esfahani, M. A1 - Tasdemir, Z. A1 - Wollschläger, Nicole A1 - Li, T. A1 - Li, X. A1 - Yilmaz, M. A1 - Leblebici, Y. A1 - Erdem Alaca, B. T1 - Nanomechanical Modeling of the Bending Response of Silicon Nanowires JF - Applied Nano Materials N2 - Understanding the mechanical behavior of silicon nanowires is essential for the implementation of advanced nanoscale devices. Although bending tests are predominantly used for this purpose, their findings should be properly interpreted through modeling. Various modeling approaches tend to ignore parts of the effective parameter set involved in the rather complex bending response. This oversimplification is the main reason behind the spread of the modulus of elasticity and strength data in the literature. Addressing this challenge, a surface-based nanomechanical model is introduced in this study. The proposed model considers two important factors that have so far remained neglected despite their significance: (i) intrinsic stresses composed of the initial residual stress and surface-induced residual stress and (ii) anisotropic implementation of surface stress and elasticity. The modeling study is consolidated with molecular dynamics-based study of the native oxide surface through reactive force fields and a series of nanoscale characterization work through in situ threepoint bending test and Raman spectroscopy. The treatment of the test data through a series of models with increasing complexity demonstrates a spread of 85 GPa for the modulus of elasticity and points to the origins of ambiguity regarding silicon nanowire properties, which are some of the most commonly employed nanoscale building blocks. A similar conclusion is reached for strength with variations of up to 3 GPa estimated by the aforementioned nanomechanical models. Precise consideration of the nanowire surface state is thus critical to comprehending the mechanical behavior of silicon nanowires accurately. Overall, this study highlights the need for a multiscale theoretical framework to fully understand the size-dependent mechanical behavior of silicon nanowires, with fortifying effects on the design and reliability assessment of future nanoelectromechanical systems. KW - Silicon nanowires KW - Native oxide KW - Surface stress KW - Surface elasticity KW - Mechanical behavior PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-581676 DO - https://doi.org/10.1021/acsanm.3c02077 SP - 1 EP - 14 PB - ACS Publications AN - OPUS4-58167 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zaghdoudi, Maha A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar A1 - Albouy, P.-A. A1 - Häcker, Ralf A1 - Stock, Daniel T1 - Overview of ongoing research and future prospects on polyethylene neutron shielding materials at bam T2 - PATRAM22 N2 - The extension of the interim storage period of radioactive waste before disposal will cause additional challenges for the nuclear waste management in Germany, so that an extensive knowledge of the long-term performance of casks, including their components and inventories, will be required for future extended storage licenses. Ultra-high and high molecular weight polyethylenes ((U)HMW-PE) are used for neutron shielding purposes in casks for storage and transport of spent fuel and high-level waste due to their extremely high hydrogen content. During their service life of several decades as cask components, the PE materials are exposed to neutron and gamma radiation from the radioactive inventory of the casks, mechanical assembling stresses and temperature. All these combined effects affect the material properties of such components which in turn may be crucial for some possible accident scenarios. At the Bundesanstalt für Materialforschung und -prüfung (BAM), the effects of high temperature exposure in combination with subsequent or previous irradiation were investigated with a comprehensive aging program including thermal aging at 125 °C for different aging periods up to 5 years and irradiation with doses ranging from 50 to 600 kGy. This contribution provides an overview of the ongoing research related to the structural changes of (U)HMW-PE induced by gamma irradiation and high temperature exposure and focuses on current research perspectives at BAM with regard to the prediction of the dynamic behavior of the material during extended interim storage in case of an accident scenario. First results of the coupled effect of temperature, radiation and mechanical loading will be presented. The effect of microstructural changes induced by gamma irradiation and high temperature on the mechanical behavior of (U)HMW-PE will be assessed. T2 - PATRAM22 CY - Juan-Les-Pins, Antibes, France DA - 11.06.2023 KW - (U)HMWPE KW - Ageing KW - Irradiation KW - WAXD KW - SHPB PY - 2023 SP - 1 EP - 10 AN - OPUS4-57707 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zaghdoudi, Maha A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar T1 - Understanding the recovery behaviour and the degradative processes of EPDM during ageing JF - Polymer Testing N2 - Recovery is an important measure for seal applications representing to which extent the elastomer regains its initial shape after deformation and release of an applied force. Compression set (CS) indicates the degree of recovery. Ethylene propylene diene rubber (EPDM) was aged at 75 ◦C, 100 ◦C, 125 ◦C and 150 ◦C for different ageing times up to five years and compression set measurements were performed at different times after disassembly and after additional tempering. Short- and long-term recovery up to one year after release for samples aged at 125 ◦C and 150 ◦C was also studied. To assess the curvature in the Arrhenius diagram that may occur due to non-sufficiently aged specimens, a degradation-rate based model was fitted to the CS data after tempering. For each ageing temperature, two decay fit functions were proposed, each with an activation energy and a corresponding degradative process. The influence of ageing on the leak-tightness after fast small partial release is investigated and estimated through the analysis of the shift factors from time temperature superposition (TTS) of CS measurements at different times after disassembly. Shift factors of CS measurement after 1 s and after additional tempering are in good agreement. KW - Compression set KW - Ageing KW - Recovery KW - Degradative processes KW - Leakage rate PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-573699 DO - https://doi.org/10.1016/j.polymertesting.2023.107987 SN - 0142-9418 VL - 121 SP - 107987 PB - Elsevier Ltd. AN - OPUS4-57369 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -