TY - JOUR A1 - Voigt, Marieke A1 - von Werder, Julia A1 - Meng, Birgit T1 - Investigation of the zonation of thermally treated ultra high performance concrete JF - Construction and Building Materials N2 - Ultra high performance concrete (UHPC) is characterised by its high compressive strength of more than 120 MPa and its high durability. With thermal treatment at 90°C, hydration is accelerated and a strength comparable to the 28-day strength can be achieved immediately after the treatment. In applying Optimum process conditions, the strength can be even further increased by up to 30%. Previous Research showed that thermal treatment can lead to inhomogeneities in form of a visible zonation within the cross-section, if the UHPC is not protected sufficiently from desiccation. This led to the question, to what extent the related changes in mechanical properties, microstructure and phase composition are of relevance for the performance of the UHPC. First investigations of small specimens thermally treated without protection exhibited a decrease of compressive strength, indicating that the zonation aspect requires further research. In this study the zonation of UHPC treated thermally at 90°C is investigated after applying four different procedures of treatment and curing in comparison. The samples are characterized with respect to their chemistry, mineral composition and microstructure to allow an assessment on durability and strength development, with focus on potential depth dependent changes associated with the zonation. The measurements reveal the formation of a visible zonation in case of unprotected treatment, if followed by immersion in water. The compressive strength is not significantly impaired, but a decrease in bending strength gives reason for concern. Further results allow clear correlation with changes in pore structure, whereas the interpretation of relationships with phase distribution, degree of hydration, microchemistry is more complex and therefore, provides only partial clarification. KW - UHPC KW - Thermal treatment KW - Zonation KW - Desiccation KW - Microstructure KW - Durability PY - 2020 DO - https://doi.org/10.1016/j.conbuildmat.2020.119187 VL - 254 SP - 119187 PB - Elsevier Ltd. AN - OPUS4-50828 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bruno, Giovanni T1 - Brittle Materials in Mechanical Extremes JF - Editorial materials N2 - The goal of the Special Issue “Brittle Materials in Mechanical Extremes” was to spark a discussion of the analogies and the differences between different brittle materials, such as, for instance, ceramics and concrete. Indeed, the contributions to the Issue spanned from construction materials (asphalt and concrete) to structural ceramics, reaching as far as ice. The data shown in the issue were obtained by advanced microstructural techniques (microscopy, 3D imaging, etc.) and linked to mechanical properties (and their changes as a function of aging, composition, etc.). The description of the mechanical behavior of brittle materials under operational loads, for instance, concrete and ceramics under very high temperatures, offered an unconventional viewpoint on the behavior of brittle materials. This is not at all exhaustive, but a way to pave the road for intriguing and enriching comparisons. KW - Microcracking KW - Ceramics KW - Concrete KW - Asphalt KW - Mechanicalproperties KW - Microstructure KW - Strength PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-514558 DO - https://doi.org/10.3390/ma13204610 VL - 13 IS - 20 SP - 4610 PB - MDPI CY - Basel AN - OPUS4-51455 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Scheuerlein, C. A1 - Andrieux, J. A1 - Michels, M. A1 - Lackner, F. A1 - Chiriac, R. A1 - Hagner, M. A1 - Di Michiel, M. A1 - Meyer, Christian A1 - Toche, F. ED - Foley, C. P. T1 - Effect of the fabrication route on the phase and volume changes during the reaction heat treatment of Nb3Sn superconducting wires JF - Superconductor Science and Technology N2 - Accelerator magnets that can reach magnetic fields well beyond the Nb-Ti performance limits are presently being built and developed, using Nb3Sn superconductors. This technology requires reaction heat treatment (RHT) of the magnet coils, during which Nb3Sn is formed from its ductile precursor materials (a “wind and react” approach). The Nb3Sn microstructure and microchemistry are strongly influenced by the conductor fabrication route, and by the Phase changes during RHT. By combining in situ differential scanning calorimetry, high Energy synchrotron x-ray diffraction, and micro-tomography experiments, we have acquired a unique data set that describes in great detail the phase and microstructure changes that take place during the processing of restacked rod process (RRP), powder-in-tube (PIT), and internal tin (IT) Nb3Sn wires. At temperatures below 450 ° the phase evolutions in the three wire types are similar, with respectively solid state interdiffusion of Cu and Sn, Cu6Sn5 formation, and Cu6Sn5 peritectic transformation. Distinct differences in phase evolutions in the wires are found when temperatures exceed 450 °C. The volume changes of the conductor during RHT are a difficulty in the production of Nb3Sn accelerator magnets. We compare the wire diameter changes measured in situ by dilatometry with the phase and void volume evolution of the three types of Nb3Sn wire. Unlike the Nb3Sn wire length changes, the wire diameter evolution is characteristic for each Nb3Sn wire type. The strongest volume increase, of about 5%, is observed in the RRP wire, where the main diameter increase occurs above 600 °C upon Nb3Sn formation. KW - Nb3Sn KW - Microstructure KW - Phase transformations KW - Volume changes KW - X-ray diffraction KW - Differential scanning calorimetry KW - Synchrotron micro-tomography PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-505128 DO - https://doi.org/10.1088/1361-6668/ab627c VL - 33 IS - 3 SP - 034004 PB - IOP Publishing CY - Bristol (UK) AN - OPUS4-50512 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rhode, Michael A1 - Richter, Tim A1 - Mayr, P. A1 - Nitsche, A. A1 - Mente, Tobias A1 - Böllinghaus, Thomas T1 - Hydrogen diffusion in creep-resistant 9% Cr P91 multi-layer weld metal JF - Welding in the World N2 - Welded components of P91 9% Cr steel demand for careful welding fabrication with necessary post weld heat treatment (PWHT). Before the PWHT, a hydrogen removal heat treatment is necessary for avoidance of hydrogen assisted cracking (HAC). In this context, the microstructure and temperature-dependent hydrogen diffusion is important, and reliable diffusion coefficients of P91 weld metal are rare. For that reason, the diffusion behavior of P91 multi-layer weld metal was investigated for as-welded (AW) and PWHT condition by electrochemical permeation experiments at room temperature and carrier gas hot extraction (CGHE) from 100 to 400 °C. Hydrogen diffusion coefficients were calculated, and the corresponding hydrogen concentration was measured. It was ascertained that both heat treatment conditions show significant differences. At room temperature the AW condition showed significant hydrogen trapping expressed by to seven times lower diffusion coefficients. A preferred diffusion direction was found in perpendicular direction expressed by high permeability. The CGHE experiments revealed lower diffusion coefficients for the AW condition up to 400 °C. In this context, a hydrogen concentration of approximately 21 ml/100 g was still trapped at 100 °C. For that reason, a certain HAC susceptibility of as-welded P91 weld metal cannot be excluded, and hydrogen removal should be done before PWHT. KW - Creep resisting materials KW - Diffusion KW - Hydrogen KW - Weld metal KW - Post weld heat treatment KW - Microstructure PY - 2020 DO - https://doi.org/10.1007/s40194-019-00828-8 SN - 0043-2288 VL - 64 IS - 2 SP - 267 EP - 281 PB - Springer AN - OPUS4-50471 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - El-Batahgy, A. A1 - Saiyah, A. A1 - Khafagi, S. A1 - Gumenyuk, Andrey A1 - Gook, S. A1 - Rethmeier, Michael T1 - Shielded metal arc welding of 9%Ni steel using matching ferritic filler metal JF - Science and Technology of Welding and joining N2 - Motivated by the tensile strength loss of 9%Ni steel arc welded joints made using Ni-based austenitic filler metals, the feasibility of maintaining the tensile strength using matching ferritic filler metal has been demonstrated. In comparison with shielded metal arc welded joint made using Ni-based austenitic electrode ENiCrMo-6, higher tensile strength comparable to that of the base metal was obtained using matching ferritic electrode. Besides, sufficient impact toughness energies with much lower mismatch were obtained for weld metal and heat-affected zone. Welded joint with a lower mechanical mismatching is of considerable importance for achieving acceptable combination of tensile strength and impact toughness.Abetter combination of These mechanical properties is ensured by applying a post weld heat treatment. KW - Mechanical mismatching KW - Mechanical properties KW - Microstructure KW - Austenitic welding electrode KW - Matching ferritic welding electrode PY - 2020 DO - https://doi.org/10.1080/13621718.2020.1846936 SN - 1362-1718 SP - 1 EP - 7 PB - Taylor & Francis AN - OPUS4-51835 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Üstündag, Ö. A1 - Gook, S. A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Hybrid laser arc welding of thick high-strength piepline steels of grade X120 with adapted heat input JF - Journal of Materials Processing Tech. N2 - The influence of heat input and welding speed on the microstructure and mechanical properties of single-pass hybrid laser arc welded 20mm thick plates of high-strength pipeline steel X120 were presented. The heat Input was varied in the range of 1.4 kJ mm−1 to 2.9 kJ mm−1, while the welding speed was changed between 0.5m min−1 and 1.5m min−1. A novel technique of bath support based on external oscillating electromagnetic field was used to compensate the hydrostatic pressure at low welding velocities. A major advantage of this technology is, that the welding speed and thus the cooling time t8/5 can be variated in a wide parameter window without issues regarding the weld root quality. The recommended welding thermal cycles for the pipeline steel X120 can be met by that way. All tested Charpy-V specimens meet the requirements of API 5 L regarding the impact energy. For higher heat inputs the average impact energy was 144 ± 37 J at a testing temperature of −40 °C. High heat Input above 1.6 kJ mm−1 leads to softening in the weld metal and heat-affected-zone resulting in loss of strength. The minimum tensile strength of 915 MPa could be achieved at heat inputs between 1.4 kJ mm−1 and 1.6 kJ mm−1. KW - High-strength low-alloy steel KW - Hybrid laser-arc welding KW - Mechanical-technological properties KW - Microstructure KW - Toughness KW - Pipeline steel of grade X120 PY - 2020 DO - https://doi.org/10.1016/j.jmatprotec.2019.116358 SN - 0924-0136 VL - 275 SP - 116358 PB - Elsevier B.V. AN - OPUS4-50008 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kempf, A. A1 - Hilgenberg, Kai T1 - Influence of sub-cell structure on the mechanical properties of AlSi10Mg manufactured by laser powder bed fusion JF - Materials Science & Engineering A N2 - AlSi10Mg is one of the most applied alloys for laser powder bed fusion (LPBF) technology, due to its great possibilities for implementing new lightweight concepts such as in automotive industries. For the component design it is necessary to know about the mechanical properties and the mechanical behaviour. The many published strength properties of LPBF processed AlSi10Mg show significant differences up to approximately 225 MPa in ultimate tensile strength (UTS) and 195 MPa in yield strength (YS). To understand these varying properties, a ring trial was carried out manufacturing specimens on 6 LPBF machines with different parameters and build-up strategies. They were studied in the as-built (AB) condition and after heat treatment at 300 °C for 30 min, respectively. For examining the mechanical properties, tensile tests and hardness measurements were carried out. The microstructure was characterized by optical light microscopy (OM), field emission scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and electron backscatter diffraction (EBSD). The identified differences in strength properties were discussed based on the 4 strengthening mechanism known for metallic materials and at the background of material defects. It was found that the size of the typical sub-cell structure of LPBF AlSi10Mg affected substantially the mechanical properties in the AB condition, in which with decreasing sub-cell size strength increased. If heat treatment was applied, the strength properties decreased and did not differ anymore. Since annealing led to coarsened sub-cells, whereas the grains itself did not change in size, the influence of sub-cell structure on strength was further confirmed. In addition, acicular precipitates in the AB condition were observed at specimens from one LPBF machine showing the lowest tensile elongation. KW - Laser powder bed fusion KW - AlSi10Mg KW - Mechanical properties KW - Microstructure PY - 2020 DO - https://doi.org/10.1016/j.msea.2020.138976 VL - 776 SP - Paper 138976, 12 PB - Elsevier B.V. AN - OPUS4-50316 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - El-Batahgy, A. A1 - Saiyah, A. A1 - Khafagi, S. A1 - Gumenyuk, Andrey A1 - Gook, Sergej A1 - Rethmeier, Michael T1 - Shielded metal arc welding of 9%Ni steel using matching ferritic filler metal JF - Science and Technology of Welding and Joining N2 - Motivated by the tensile strength loss of 9%Ni steel arc welded joints made using Ni-based austenitic filler metals, the feasibility of maintaining the tensile strength using matching ferritic filler metal has been demonstrated. In comparison with shielded metal arc welded joint made using Ni-based austenitic electrode ENiCrMo-6, higher tensile strength comparable to that of the base metal was obtained using matching ferritic electrode. Besides, sufficient impact toughness energies with much lower mismatch were obtained for weld metal and heat-affected zone. Welded joint with a lower mechanical mismatching is of considerable importance for achieving acceptable combination of tensile strength and impact toughness. A better combination of These mechanical properties is ensured by applying a post weld heat treatment. KW - 9%Ni steel KW - Ni-based austenitic welding electrode KW - Matching ferritic welding electrode KW - Mechanical properties KW - Mechanical mismatching KW - Microstructure KW - SMAW PY - 2020 DO - https://doi.org/10.1080/13621718.2020.1846936 VL - 26 IS - 2 SP - 116 EP - 122 PB - Taylor & Francis AN - OPUS4-52025 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -