TY - CONF A1 - Bertin, Annabelle T1 - Upper critical solution temperature (UCST)-type thermoresponsive polymers from monomers with hydrogen-bonding interactions N2 - UCST-type thermoresponsive polymers (i.e. that phase separate from solution upon cooling) present a tremendous potential not only in aqueous media with applications in the field of drug delivery, diagnostic and microfluidic applications, but also in water/alcohol mixtures, where they can be used for instance in sensing systems for alcohol-soluble drugs. However, only a few thermoresponsive polymers have been reported that present an UCST in a relevant temperature range and “green” solvents such as water or ethanol. In this context, acrylamide-based monomers can be very useful building blocks for designing novel non-ionic UCST-type polymers because of their hydrophilic nature (with the appropriate side chain) and propensity to form hydrogen bonds. We will present our latest results on the UCST-type thermoresponsive behaviour of acrylamide- and/or 2,6-diaminopyridine-based homopolymers and copolymers in water or water/alcohol mixtures, and give some insights about the rational design of UCST polymers relying on H-bonding. T2 - 7. Jahrestreffen der Seniorexperten Chemie CY - Weimar, Germany DA - 02.05.2018 KW - Thermoresponsive polymer KW - UCST-type polymer KW - Polyacrylamide KW - Water/alcohol mixtures PY - 2018 AN - OPUS4-44845 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lüth, Peter T1 - CEQAT-DGHS Interlaboratory test programme for chemical safety - status and activities N2 - Safety experts, carriers or traders must be able to rely on the validity of the method and on correct results of safety tests and assessments in the laboratory. Bundesanstalt für Materialforschung und –prüfung (BAM), Berlin and Physikalisch-Technischen Bundesanstalt (PTB), Braunschweig have extensive experience in the field of testing and assessment of physical hazards of chemicals. Interlaboratory tests on different test methods have been performed by BAM and PTB during the last 10 years. Significant differences between the results of the participating laboratories were observed in all interlaboratory test. The deviations of the test results were not caused only by laboratory faults but also by deficiencies of the test method; i.e. many of the method descriptions are too ambiguous and allow divergences for interpretation. Therefore, it is necessary to know exactly how good the method is that is used to classify dangerous goods or hazardous substances or to determine safety-relevant parameters. A key criterion is the measurement uncertainty. One can choose simple methods with large error limits, but the measurement uncertainties should be known and always communicated together with the test results. This would allow safety specialists to be able to assess test results correctly and make well-founded decisions, e.g. for adequate protective measures. Interlaboratory tests play a decisive role in assessing the reliability of test results. Participation in interlaboratory tests is not only a crucial element of the quality assurance of laboratories; as such it is explicitly recommended in DIN EN ISO/IEC 17025. In addition, interlaboratory tests are also used to develop and validate test methods and can be used for the determination of the measurement uncertainty. Therefore, the BAM and PTB continue to support the further development of the interlaboratory test programme of CEQAT-DGHS (Centre for quality assurance for testing of dangerous goods and hazardous substances, www.ceqat-dghs.bam.de), established in 2007. This programme is run by BAM in collaboration with the PTB and the QuoData Gesellschaft für Qualitätsmanagement und Statistik mbH, Dresden. A new interlaboratory test for methods validation on the test method UN Test N.5 "Test method for substances which in contact with water emit flammable gases” is currently being prepared and will be carried out in 2018. Laboratories that specialise in this test are invited to participate in the interlaboratory test. Interested laboratories can check the details and register to participate in the interlaboratory test at the CEQAT-DGHS website. T2 - MEETINGS OF IGUS EOS GROUP CY - Shanghai, P. R. China DA - 09.04.2018 KW - Dangerous goods KW - Hazardous substances KW - Test methods validation KW - Quality assurance PY - 2018 AN - OPUS4-44858 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Manolov, Manol T1 - Bestimmung der Maschinennachgiebigkeit beim Einsatz sphärischer Indenter in der Instrumentierten Eindringprüfung N2 - Der Einfluss der Maschinennachgiebigkeit einschließlich der elastischen Verformung des Indenters ist bei der Bestimmung der entsprechenden Werkstoffcharakteristiken insbesondere beim Einsatz von sphärischen Indentern unter höheren Prüfkräften von Bedeutung. Mit zunehmender Prüfkraft wird die Maschinennachgiebigkeit kraftabhängig und kann im idealen Fall als Funktion von Prüfkraft und gemessener Eindringtiefe für vorgegebene Indenterradien dargestellt werden. Angegeben ist ein vereinfachtes Verfahren zur Bestimmung der Maschinennachgiebigkeit. T2 - Sensoren und Messsysteme CY - Nürnberg, Germany DA - 26.06.2018 KW - Maschinennachgiebigkeit KW - Instrumentierte Eindringprüfung KW - Sphärische Indenter KW - Vereinfachtes Verfahren KW - Kraftabhängige Funktion KW - Härtevergleichsplatten KW - Eindringmodul PY - 2018 AN - OPUS4-45390 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Falk, Florian A1 - Menneken, Martina T1 - Early oxidation and sulfidation of high temprature alloys: An EDXRD in-situ study N2 - P92 is one of the important steels for super heater tubes used in combustion plants. However, in fossil fuel fired environments the formation of oxides and sulfides are challenging the material. To understand early corrosion mechanisms, which are important for process prediction, high temperature in-situ ageing experiments of Fe-Cr-Mn alloys in SO2 and SO2+H2O atmosphere were performed, applying energy dispersive X-ray diffraction (EDXRD) analysis. T2 - Bessy usermeeting CY - Berlin, Germany DA - 05.12.2017 KW - Corrosion KW - In-situ KW - EDXRD PY - 2017 AN - OPUS4-45368 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lüth, Peter A1 - Brandes, E. A1 - Frost, K. A1 - Kurth, Lutz A1 - Schmidt, Martin A1 - Michael-Schulz, Heike A1 - Uhlig, S. T1 - CEQAT-DGHS Ringversuchsprogramm für die Chemikaliensicherheit -Methodenvalidierung N2 - Bei der Bewertung der Verlässlichkeit der im Labor gewonnenen Prüfergebnisse spielen Ringversuche eine entscheidende Rolle. Die Bundesanstalt für Materialforschung und –prüfung (BAM) unterstützt deshalb den weiteren Ausbau des Ringversuchsprogramms des im Jahr 2007 gegründeten Kompetenzzentrums zur Qualitätssicherung für Prüfungen von Gefahrgütern und Gefahrstoffen auf physikalische Gefahren (Centre for quality assurance for testing of dangerous goods and hazardous substances, CEQAT-DGHS). Bei allen bisher untersuchten Prüfmethoden besteht ein Verbesserungsbedarf. Die RV müssen daher zunächst auf die Methodenentwicklung, -verbesserung und -validierung und auf die Bestimmung der Messunsicherheit der jeweiligen Prüfmethode abzielen und nicht auf Leistungstests. T2 - Behörden-Erfahungsaustausch CY - Berlin, Germany DA - 4. Juni 2018 KW - Prüfmethode KW - Methodenvalidierung KW - Gefahrgut KW - Gefahrstoff KW - Qualitätssicherung PY - 2018 AN - OPUS4-45297 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wollschläger, N. A1 - Nützmann, Kathrin T1 - What happens during S-corrosion in Fe13Cr in the early stage? N2 - Ferritic alloys containing Cr form Cr5S6 precipitates along grain boundaries in hot SO2 environment. Grain boundary precipitates may influence the steel’s mechanical behavior. Cr5S6 precipitates were reconstructed three-dimensionally using FIB tomography analysis to determine the volume, number, and penetration depth. The volume growth of Cr5S6 precipitates increased only for the initial aging time of 3 h but became constant after 6 h. The number of precipitates increased linearly. T2 - Meeting on Focused Ion Beams in Berlin - FIBiB2017 CY - Berlin, HZB Wannsee Campus, Germany DA - 06.11.2017 KW - Grain boundary corrosion KW - 3D tomography KW - Sulfidation PY - 2017 AN - OPUS4-45061 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Szymoniak, Paulina T1 - Rigid amorphous fraction (RAF) in epoxy/Boehmite and epoxy/LDH nanocomposites N2 - The interphase between the inorganic filler and the polymer matrix is considered as one of the most important characteristics of inorganic/polymer nanocomposites. The segmental dynamics of this interphase is expected to be altered as compared to the pure matrix, which might percolate into the entire system. For instance, it was found that a so-called Rigid Amorphous Phase (RAF) is formed by adsorption of segments onto the nanoparticles yielding to its immobilization. The RAF is available from the decrease of the specific heat capacity Δcp in the glass transition region of the nanocomposites. Here, precise Temperature Modulated DSC (TMDSC) was employed to study Δcp of epoxy/Boehmite nanocomposites with different nanofiller concentrations. Surprisingly, the investigated system showed an increase of Δcp with increasing filler concentration up to 10 wt%. This implies an increased fraction of mobile segments, and is in accordance with the found decreased value of the glass transition temperature Tg. Although for higher filler contents Tg further slightly decreases, Δcp decreases in contrary, indicating a formation of RAF. This behavior was discussed as a competition of mobilization effects, due to an incomplete crosslinking reaction, and the formation of RAF. T2 - 15thLähnwitzseminar on Calorimetry 2018 CY - Rostock, Germany DA - 04.06.2018 KW - Nanocomposites KW - Rigid amorphous fraction KW - TMDSC KW - Boehmite PY - 2018 AN - OPUS4-45148 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hertwig, Andreas T1 - Calibration samples and the GUM-compliant determination of uncertainties in ellipsometry N2 - Ellipsometry is well known as a highly sensitive and reproducible surface analysis technique. However, in a context of metrological applications, the most important property of a measurement process is accuracy, relying on statistical precision, (reproducibility) and trueness (in an absolute sense versus a given standard). The latter is much more difficult to achieve. In this presentation, we discuss the possibility of establishing ellipsometry in a diverse metrological landscape by means of defining standard procedures and best practice methodologies for the measurement and for calibration purposes. The most important task of this approach is to determine the model-inherent uncertainty, originating from parameter coupling. We achieve this by means of sensitivity analysis of the parameters resulting from the fit process. We discuss the definition of reference materials by which accuracy can be made available for ellipsometry, passed along between ellipsometry laboratories and for other measurement techniques. The determination of uncertainty is presented in this work for a number of examples involving difficult analysis models employed for samples from different production environments. We present a standardization initiative with the goal to disseminate this work into an international standard alongside an inter-laboratory study comparing the results for complex samples gained by laboratories with different instrumentation. We also present the results gained within EURAMET projects focused on the metrology of materials with strong non-idealities used in photovoltaics and other energy technology. T2 - Workshop Ellipsometry 2018 CY - Chemnitz, Germany DA - 19.03.2018 KW - Ellipsometric metrology KW - Reference samples KW - Reference procedures KW - Standardization PY - 2018 AN - OPUS4-44674 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stephan-Scherb, Christiane T1 - Real time observation of crystallization and growth of corrosion products by energy dispersive X-ray diffraction N2 - Ferritic-martensitic high temperature alloys are widely used as boiler tube and heat exchanger materials in combustion based power plants. All technologies have in common that the applied materials are exposed to different temperatures, process pressures and reactive atmospheres which lead to a change of the material properties and a further degradation of the material. To date corrosion analytics mainly proceeds via the use of various microscopic techniques and the analysis of the corrosion products after the reaction is completed. Comprehensive efforts have been made to study high temperature corrosion by the use of environmental SEM’s or in-situ TEM technologies. The here presented work will show a different approach to study high temperature gas corrosion in a multiple gas atmosphere by energy dispersive X-ray diffraction (EDXRD). For this technique high energetic white X-ray radiation (10-100 keV) was used as radiation source instead of conventional monochromatic radiation. It enables us to study crystallization procedures on short and medium time scales (1 min < t < 24 h) and the collection of Bragg-Signals of the phases of interest as a function of process time. Their occurrence can directly be correlated with thermodynamic and kinetic parameters. A special designed corrosion reactor was used to combine high temperature gas corrosion experiments with the collection of diffraction patter. The crystallization and reaction paths for oxide and sulfide formation was followed in-situ on Fe-Cr and Fe-Cr-Mn model alloys in a hot SO2 containing (T=650 °C) atmosphere. T2 - Gordon Research Conference on High Temperature Corrosion and Protection of Materials CY - New London, NH, USA DA - 09.07.2017 KW - Corrosion KW - In situ diffraction KW - Crystallization PY - 2017 AN - OPUS4-44717 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Barnefske, Lena T1 - Self-healing silicone rubber for F-POF partial discharge sensors in HV cable accessories N2 - To avoid a catastrophic failure of insulation in high-voltage (HV) applications, a monitoring of partial discharges (PD) is necessary. Fluorescently labelled polymer optical fibres (F-POF) offer an electrically passive method for PD detection in HV facilities. F-POF could be embedded into HV cable insulation material, which are usually made of silicone rubber. Due to the difficult accessibility of HV cable accessories, a self-healing silicone rubber, based on incorporated capsules, with prolonged service life after PD detection represents an attractive material design for HV electrical insulation. T2 - 26th International Conference on Plastic Optical Fibres CY - Aveiro, Portugal DA - 13.09.2017 KW - Fluorescent polymer optical fibres KW - Partial discharge detection KW - High voltage cable accessories KW - Self-healing KW - Silicone rubber PY - 2017 AN - OPUS4-42511 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stajanca, Pavol T1 - Post-fabrication cladding doping of commercial PMMA polymer optical fiber N2 - Possibility of post-fabrication doping of commercial PMMA fibers using well-known solution doping technique is presented. The cladding of 1 mm PMMA fiber is doped with Rhodamine B with the help of methanol-mediated diffusion of the dye molecules into the fiber material. Doping of the fiber core was not possible even at extended doping times. The proposed method represents rather simple and cheap way for preparing custom cladding-doped POFs with high flexibility of dopant choice and fiber length. Produced cladding-doped fibers have potential for various sensing or lighting applications. T2 - 26th International Conference on Plastic Optical Fibres (POF 2017) CY - Aveiro, Portugal DA - 13.09.2017 KW - Polymer optical fibers KW - Fluorescent dyes KW - Solution doping KW - Polymethyl methacrylate PY - 2017 AN - OPUS4-42321 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rosemann, Paul T1 - Einfluss der Schweißnaht-Nachbehandlung auf die Korrosionsbeständigkeit von nichtrostenden Duplexstählen N2 - Der Duplexstahl 1.4062 (X2CrNiN22-2) hat sich im Bauwesen als Werkstoffalternative zu den nichtrostenden Austeniten etabliert. Die Korrosionsbeständigkeit von Schweißverbindungen wird, neben dem Grundwerkstoff, dem Schweißzusatzwerkstoff und dem Schweißverfahren, auch sehr stark von der Oberflächennachbehandlung der Schweißnaht beeinflusst. Je nach zukünftigem Anwendungsbereich und geforderter Optik sowie Korrosionsbeständigkeit wird der Schweißnahtbereich anschließend geschliffen, gebeizt, elektropoliert, oder gestrahlt, um die beim Schweißen entstehenden Zunderschicht zu entfernen. Gestrahlte Oberfläche sind in der industriellen Praxis häufig anzutreffen, da sie deutlich einfacher und kostengünstiger herzustellen sind als gebeizte oder elektropolierte Oberflächen. Die Auswahl des Strahlmittels bestimmt auch die Prozesskosten, wobei das Strahlen mit Korund effektiver als das Strahlen mit Glasperlen ist. In den letzten Jahren wurden bei nichtrostenden Stählen korrosionsanfällige Oberflächen beobachtet, wenn diese mit Korund geschliffen wurden. Daher wird nun auch beim Strahlen kritisch hinterfragt, ob das Strahlmittel die Korrosionsbeständigkeit verändert. Diese Fragestellung wird beantwortet indem geschliffene, gebeizte, mit Korund gestrahlte und mit Glasperlen gestrahlte Schweißverbindungen vergleichend untersucht werden. Die Ergebnisse der REM-Untersuchungen von den Strahlmitteln und den gestrahlten Oberflächen werden dazu mit den Ergebnissen verschiedener Korrosionsuntersuchungen (KorroPad-Indikatortest, Potentialmessungen und Bestimmung der kritischen Lochkorrosionspotentiale) korreliert und vorgestellt. T2 - Werkstoffwoche 2017 CY - Dresden, Germany DA - 27.09.2017 KW - Duplexstahl KW - Korrosion KW - Nichtrostender Stahl KW - Oberflächenbearbeitung KW - Schweißen KW - Strahlen PY - 2017 AN - OPUS4-42830 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Babutzka, Martin T1 - Einfluss von Korundschleifprozessen auf die Korrosionsbeständigkeit nichtrostender Stähle N2 - Das Poster stellt aktuelle Eregbnisse des AiF-Vorhabens 18823 N/1 zum Einfluss von Schleifprozessen auf die Korrosionsbeständigkeit nichtrostender Stähle vor. T2 - Jahrestagung 2017 der GfKORR CY - Frankfurt a. M., Germany DA - 07.11.2017 KW - Korrosion KW - Corrosion KW - Korundschleifen KW - Corundum grinding KW - Nichtrostende Stähle KW - Stainless Steels PY - 2017 AN - OPUS4-42773 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dieck, S. A1 - Ecke, M. A1 - Fritsch, S. A1 - Rosemann, Paul A1 - Wagner, M. A1 - Halle, T. T1 - SD effect in martensitic stainless steel under Q&P heat treatment condition N2 - The quenching and partitioning (Q&P) heat treatment enables a higher deformability of high strength martensitic steels. The Q&P heat treatment was applied on the martensitic stainless steel 1.4034 (X46Cr13) to study the influence of partitioning time. Therefore, extensive characterizations of the mechanical properties, focussing on the materials behaviour under different mechanical load scenarios, were performed. A comprehensive analysis of the microstructural evolution was per-formed for different heat treatment and mechanical loading states. A complete solution of chromium carbides was detected to be a first requirement for successful Q&P heat treatment. The comparison of common quenching and tempering with the Q&P heat treatment verifies the extensively enhanced materials strength whereat the formability is still acceptable. The microstructural reason was detected to be an increasing aus-tenite fraction due to austenite reversion at subgrain boundaries of martensite besides the stabilising of retained austenite. Further a distinctive strength differential effect was observed. T2 - 11th European Symposium on Martensitic Transformations CY - Metz, France DA - 27.08.2018 KW - Martensitic stainless steels KW - Heat treatment KW - EBSD KW - Quenching and partitioning KW - TRIP PY - 2018 AN - OPUS4-45803 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schulte, Petra T1 - Kritische Bewertung der Prüfergebnisse in chemikalienrechtlichen Verfahren: Wie agiert die Behörde? Welche Folgen haben die Ergebnisse für die Rechtsetzung? N2 - Mit nicht-konformen oder schlecht dokumentierten Prüfergebnissen können weder Behörden noch Unternehmen etwas anfangen. Belastbare und eindeutige Informationen aus den Registrierungsdossiers sind entscheidend, damit industrielle und gewerbliche Verwender der Stoffe das Gefahrenpotenzial einschätzen und ggf. Maßnahmen zum Schutz von Menschen und Umwelt treffen können. Darüber hinaus benötigen die Behörden verlässliche Daten aus den Registrierungen, um ihrer Verantwortung bei der Identifizierung regulierungsbedürftiger Stoffe nachkommen zu können. T2 - Behörden-Erfahrungsaustausch CY - Berlin, Germany DA - 04.06.2018 KW - Prüfmethode KW - Einstufung KW - REACH KW - CLP KW - IUCLID KW - ECHA KW - OECD PY - 2018 AN - OPUS4-45808 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Prager, Jens T1 - Efficient modelling of guided ultrasonic waves using the Scaled Boundary FEM towards SHM of composite pressure vessels N2 - The Scaled Boundary Finite Element Method (SBFEM) is a semi-analytical method that shows promising results in modelling of guided ultrasonic waves. Efficiency and low computational cost of the method are achieved by a discretisation of the boundary of a computational domain only, whereas for the domain itself the analytical solution is used. By means of the SBFEM different types of defects, e.g. cracks, pores, delamination, corrosion, integrated into a structure consisting of anisotropic and isotropic materials can be modelled. In this contribution, the SBFEM is used to analyse the propagation of guided waves in a structure consisting of an isotropic metal bonded to anisotropic carbon fibre reinforced material. The method allows appropriate wave types (modes) to be identified and to analyse their interaction with different defects. Results obtained are used to develop a structural health monitoring system for composite pressure vessels used in automotive and aerospace industries. T2 - 9th European Workshop on Structural Health Monitoring (EWSHM) CY - Manchester, UK DA - 10.07.2018 KW - Structural Health Monitoring KW - Pressure tanks KW - Hydrogen storage KW - Finite Element Modelling KW - Composites PY - 2018 AN - OPUS4-45486 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Piedade, M. F. M. T1 - Crystal Engineering through Solvent Mediated Control of Molecular Conformation: The Case of 5-Hydroxynicotinic Acid N2 - The importance of molecular conformation for polymorphism and its repercussions in terms of tight control over the industrial production of crystalline organic materials with highly reproducible physicochemical properties has long been recognized. Efforts to understand how a crystallization solvent can direct the formation of a polymorph containing a specific molecular conformation are, however, relatively scarce. Nicotinic acid (NA) and its hydroxyl derivatives (2-, 4-, 5-, and 6-hydroxynicotinic acids) are very good models for such studies. Indeed, regardless of the solvent, NA always crystallizes as a single polymorph with the molecule in the same neutral conformation. In contrast, the hydroxyl derivatives are prone to polymorphism and solvate formation and, depending on the crystallization conditions, the molecules in the crystal lattice can exhibit hydroxyl, oxo, or zwitterionic conformations. The present study focused on 5-hydroxynicotinicacid (5HNA) shows that by judicious selection of the solvent it is possible to obtain 1:1 solvates, where solvation memory is not completely lost and the tautomer preferred in solution persists in the crystalline state: zwitterionic in 5HNA·H2O and neutral in 5HNA·DMSO. Nevertheless, upon thermal desolvation the obtained materials evolve to the same unsolvated form where the molecule is in a zwitterionic conformation. The structures of 5HNA·H2O and 5HNA·DMSO obtained from single crystal-ray diffraction are discussed and compared with that of 5HNA solved from powder data. The energetics of the dehydration/desolvation process was also fully characterized by thermogravimetry (TG), differential scanning calorimetry (DSC) and Calvet microcalorimetry. T2 - BACG 2018 CY - Limerick, Ireland DA - 20.06.2018 KW - Crystal Engineering KW - 5-hydroxynicotinic acid KW - Molecular Conformation PY - 2018 AN - OPUS4-45519 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Falk, Florian T1 - Early oxidation and sulfidation of high temperature model alloys: An EDXRD in situ study N2 - The fundamental impact of sulfur and water on corrosion rates and potential failure of the exposed material is well known. However, the access to the related corrosion mechanism causing material degradation is often a problem to solve. This study investigates the effect of SO2 and water vapor in the initial stages of corrosion of an Fe9Cr0.5Mn model alloy at 650 °C in situ. The analysis was carried out under laboratory conditions using energy-dispersive X-ray diffraction (EDXRD). T2 - Dechema EFC Workshop CY - Frankfurt am Main, Germany DA - 26.09.2018 KW - Sulfidation KW - Model alloy KW - Oxidation PY - 2018 AN - OPUS4-46134 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wolter, Christian T1 - Metallsulfide als Reibungsstabilisatoren in Bremsbelägen - tribologische Untersuchungen an Modellsystemen N2 - Der Posterbeitrag handelt davon, wie das Reibverhalten und die Temperaturabhängikgeit durch den Einsatz von Metallsulfiden maßgeblich beeinflusst wird und zur Stabilität beiträgt. T2 - 59. Tribologie-Fachtagung CY - Goettingen, Germany DA - 24.09.2018 KW - Metallsulfide KW - Bremsbeläge KW - Tribologie PY - 2018 AN - OPUS4-46187 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pfretzschner, Beate T1 - Hydrogen in blistered iron visualized in 3D by neutron tomography N2 - Presented are neutron tomographies on hydrogen charged iron samples. T2 - RACIRI Summerschool CY - Sellin, Germany DA - 22.08.2015 KW - Eisen KW - Neutronenradiographie KW - Wasserstoff PY - 2014 AN - OPUS4-47786 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eisermann, R. T1 - Distributed acoustic/vibration sensing: Towards advanced transformer condition monitoring N2 - A novel method for transformer vibration monitoring using intensity-based distributed acoustic/vibration sensing (DAS/DVS) is presented. Fibre optic sensors were fully integrated into an oil-filled medium voltage distribution transformer. Opencircuit in-situ measurements were carried out using a single and three-phase supply with an electrical power of up to 30 kVA. Spectral analysis of the mechanical vibrations were performed by measuring the frequency response of the transformer using plain fibre- and transducer-based DVS approaches. The results were compared with the spectra of a microphone mounted on the outside of the transformer housing and the electrical measurements on the high voltage side. Using the fibre optic DVS based monitoring we were able to detect changes in operating power and frequency. Further it could be shown, that it is possible to identify anomalous behaviour such as electrical/mechanical noise sources using the determined vibration spectra. T2 - 2024 IEEE International Conference on High Voltage Engineering and Applications (ICHVE) CY - Berlin, Germany DA - 18.08.2024 KW - Distributed acoustic sensing KW - Condition monitoring KW - Transformer monitoring PY - 2024 AN - OPUS4-61799 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Blaeß, Carsten T1 - Binder jetting of crystallizing bioactive glass powders N2 - Customized artificial bone replacement implants made of resorbable bioactive glass (BG) have not yet become widely accepted in clinical use. This is mainly due to the contrariness of sintering ability and appropriate bioactivity. Concurrent crystallization often prevents the generation of dense sinter bodies, especially for additive manufactured 3D scaffolds. The presented study investigates the limits and advantages of crystallization of powder compacts manufactured by binder jetting and uniaxial pressing for different particle size fractions (psf) of two BGs. T2 - CeramicAM 2024 - 1º CY - Sao Paulo, Brasil DA - 19.09.2024 KW - Bioactive glass KW - Sintering KW - Crystallization KW - Additive manufacturing PY - 2024 AN - OPUS4-62594 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lapšanská, Ivana T1 - Thermographic detection and AI evaluation of leading-edge erosion N2 - The European Green Deal and the global fight against climate change call for more and larger wind turbines. To meet the increasing demand for maintenance and inspection, semi-autonomous methods of remote inspection are increasingly being developed in addition to industrial climbers performing the inspection [1, 2]. Rotor blades are exposed to extreme weather conditions throughout their lifetime causing leading edge erosion which changed the aerodynamic features of blades and can cause structural damages. The estimated annual energy production (AEP) losses caused by erosion damages are between 0.5% and 2% per year. The classification of the severity of the damage and the quantification of the resulting AEP losses are subject of scientific research. With such information, cost efficient repairs and maintenance efforts can improve the power production of wind turbines. Passive thermography presents a viable method for inspecting rotor blades, capable of identifying internal damage [3, 4] and surface erosion [5, 6]. An advantage of this method is that it not only detects rain erosion damage but also reveals temperature variations caused by resulting turbulence on the blade's surface. These turbulent effects reduce rotor blade efficiency, leading to losses in AEP. The inspection process takes approximately 10 minutes per turbine and is carried out while the turbine is fully operational, eliminating downtime and revenue losses typically associated with traditional blade inspections. This efficient inspection procedure is further enhanced by an automatic data analysis system, resulting in a substantial number of wind turbines being inspected within a specified timeframe. The automated evaluation of thermal images is executed using a fully convolutional network (FCN). The initial phase involved training an FCN using over 1500 thermal images. The primary objective was to accurately identify the thermal patterns associated with erosion damage at the leading edge. In the ongoing second phase, the emphasis is on integrating thermographic and visual images to assess the extent of the damage using an FCN. Additionally, this phase involves leveraging human factors in the FCN training process and providing a precise estimation of Annual Energy Production losses attributed to the identified rain erosion damages. T2 - EERA Deep Wind 2024 CY - Trondheim , Norway DA - 17.01.2024 KW - Wind KW - Turbulent flow KW - Thermography KW - Wind rotor blade KW - Inspection PY - 2024 UR - https://www.sintef.no/globalassets/project/eera-deepwind-2024/posters/operation-and-maintenance_ivana_lapsanska_thermographic-detection.pdf AN - OPUS4-62501 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Munsch, Sarah Mandy T1 - Ermittlung der Porosität von Sandsteinen - Vergleich von Quecksilberporosimetrie, Tauchwägung und NMR N2 - Die Porosität sowie die Porengrößenverteilung (PSD) eines Baustoffs sind wichtige petrophysikalische Eigenschaften, die Transportprozesse im Material beeinflussen und im direkten Zusammenhang mit der Schadensanfälligkeit stehen (Frost-Tau-Schäden, Schäden durch Salzeinträge und sauren Regen). Verfahren zur Ermittlung der Porosität stellen die Quecksilberporosimetrie (MIP), das Prinzip der Tauchwägung nach Archimedes (triple weighing method, TWM) und die Nuklear Magnetische Resonanz (NMR) dar. Das Hauptziel dieser Arbeit ist der Vergleich der drei Methoden für die Porositätsbestimmung. Als Untersuchungsmaterial wurde Sandstein gewählt. Als Baustoff wird Sandstein trotz einer teilweise geringen Festigkeit, aber aufgrund seiner Farbvielfalt häufig für Kulturbauten, Gehwegmaterial und Fassaden eingesetzt. Sandsteine weisen zudem meist eine hohe effektive Porosität (bis zu ca. 30 %) und teilweise breite Porengrößenspektren auf, wodurch Feuchte- und Ioneneinträge begünstigt werden und zu z. B. langfristigen Verfärbungen an Sandsteinfassaden führen können. Im Rahmen dieser Arbeit werden die Porositäten von 10 verschiedenen Sandsteinen aus Deutschland und Tschechien bestimmt. Für die Untersuchungen mittels TWM und NMR wurden für jede Sandsteinart zwei zylinderförmige Proben unter Unterdruck mit Leitungswasser aufgesättigt. Beim Vergleich der Verfahren liegt der Fokus insbesondere auf NMR und der verwendeten Gerätetechnik, die mit einer minimalen Echozeit von 50 µs ein Wasserstoffsignal in Sandsteinen aus bis zu ca. 2 nm kleine Poren erfassen kann. Darüber hinaus wird das Auflösungsvermögen von MIP und NMR bezüglich der Poren- bzw. Poreneingangsgrößen diskutiert. Für den Vergleich von NMR und MIP werden an ausgewählten Sandsteinproben ebenfalls die zusätzlich ermittelten PSD in Korrelation zueinander gebracht. Erste Ergebnisse zeigen eine gute Korrelation von NMR- und TWM-Daten, aber teilweise starke Abweichungen zu den mit MIP bestimmten Porositäten. Ergebnisse zu den PSD zeigen teilweise nahezu identische Kurvenverläufe. Jedoch ist die Abschätzung des Umrechnungsfaktors für die NMR-Daten ohne Hinzuziehen von zusätzlichen Referenzverfahren wie Röntgen-Computer-Tomographie oder Spektral Induzierte Polarisation teilweise sehr schwierig. T2 - Bauwerksdiagnose CY - Berlin, Germany DA - 13.02.2020 KW - NMR KW - Porosität KW - Sandsteine KW - Quecksilberporosimetrie KW - Tauchwägung PY - 2020 N1 - Geburtsname von Munsch, Sarah Mandy: Nagel, S. M. - Birth name of Munsch, Sarah Mandy: Nagel, S. M. AN - OPUS4-50405 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Beck, Matthias A1 - Rübner, Katrin A1 - Burkert, Andreas T1 - Einsatz der Quecksilberporosimetrie zur Charakterisierung von Feinkornbetonen für elektrochemische Untersuchungen N2 - Im Rahmen eines DFG-Forschungsvorhabens (FOR 537) wird ein Teilprojekt an der BAM bearbeitet. Ziel dieser Arbeit ist die quantitative Beschreibung und Bewertung des Korrosionsfortschrittes an Stahlproben mit kleinen Kathodenflächen (Eigenkorrosion) mittels elektrochemischer Messungen. Für die Untersuchungen wurden Betonproben mit eingebetteten Stahlelektroden hergestellt. Dabei wurden gezielt betontechnologische Parameter variiert. Dabei ist der Beton als Elektrolyt zu betrachten. Nach bestimmten Zeitintervallen werden die Betonproben aufgebrochen und die eingebetteten Stahlelektroden durch visuelle Inspektion und anschließende Bestimmung des Masseverlustes bewertet. Zur Charakterisierung des Betons (Elektrolyt) dient das Verfahren der Quecksilberporosimetrie. Mit dem Verfahren lassen sich die Zusammenhänge zwischen den betontechnologischen Parametern und der Porenstruktur aufzeigen und mittels der umfangreichen Variation der Betonparameter die Auswirkung auf den Korrosionsfortschritt nachweisen. T2 - XIII. Workshop über die Charakterisierung von feinteiligen und porösen Festkörpern CY - Bad Soden, Germany DA - 14.11.2006 PY - 2006 AN - OPUS4-14294 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Grunert, Wiebke T1 - ODYSSEUS N2 - Vorstellung des Forschungsprojekts ODYSSEUS und Darstellung der Aufgaben der BAM. Hierbei sollen neue Instrumente chemische Ausgangsstoffe zur Herstellung von Explosivstoffen und Bomben aufspüren, um zukünftig Anschläge zu verhindern. T2 - 46. Informationstagung Sprengtechnik CY - Siegen, Germany DA - 25.04.2025 KW - Home-made explosives KW - Anschläge KW - Bomben KW - Ausgangsstoffe PY - 2025 AN - OPUS4-62995 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lohrer, Christian T1 - Initiierungsvermögen von Anzündern (sonstige Pyrotechnik für Fahrzeuge) an Sekundärsprengstoffen N2 - Um eine schwere missbräuchliche Verwendung von Pyrotechnik zu verhindern, ist eine mögliche Initiierung von Sekundärsprengstoffen durch Pyrotechnik gemäß der wesentlichen Sicherheitsanforderungen der Richtlinie 2013/29/EU nicht zulässig. Aus diesem Grund müssen pyrotechnische Gegenstände auch in dieser Hinsicht bewertet werden. In einem pränormativen Forschungsansatz wurden leistungsfähige und für die Allgemeinheit vergleichsweise leicht verfügbare Anzünder aus dem Bereich der Fahrzeugpyrotechnik speziellen Prüfungen für die Bewertung dieser Auslösefähigkeit unterzogen. T2 - 46. Informationstagung Sprengtechnik CY - Siegen, Germany DA - 25.04.2025 KW - Sekundärsprengstoffe KW - Pyrotechnik KW - Konformuitätsbewertung PY - 2025 AN - OPUS4-62997 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weise, Frank A1 - Porzig, Ekkehard T1 - Zerstörungsarme Bauzustandsanalyse selbsttätig vorgespannter Stahlbetonfachwerkträger im Flughafen Berlin-Tempelhof N2 - - einer der größten zusammenhängenden Gebäudekomplexe in Europa - Anfang der dreißiger Jahre von Prof. Sagebiel geplant, 1936 Baubeginn, heute zu 70%fertiggestellt - steht heute wegen großer verkehrs- und baugeschichtlicher Bedeutung unter Denkmalschutz - in Abfertigungshalle befindliche Fachwerkträger mit selbsttätiger Vorspannung zeigen Anfang des Spannbetonbaus - ab 1997 Überarbeitung des Nutzungskonzeptes der Räume über den Fachwerkträgern durch Berliner Flughafengesellschaft - Erfordernis der Abschätzung der Tragfähigkeit der Fachwerkträger T2 - Fachtagung Bauwerksdiagnose - Praktische Anwendungen Zerstörungsfreier Prüfungen CY - Munich, Germany DA - 21.01.1999 KW - Fachwerkträger KW - Mechanische Kennwertermittlung KW - Vergleichsstahlproben PY - 1999 AN - OPUS4-36517 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hahn, Marc Benjamin T1 - Combined cell and nanoparticle models for TOPAS to study radiation dose enhancement by Monte-Carlo based particle scattering Simulations N2 - Dose enhancement by gold nanoparticles (AuNP) increases the biological effectiveness of radiation damage in biomolecules and tissue. To apply them effectively during cancer therapy their influence on the locally delivered dose has to be determined.[1] Hereby, the AuNP locations strongly influence the energy deposit in the nucleus, mitochondria, membrane and the cytosol of the targeted cells. To estimate these effects, particle scattering simulations are applied. In general, different approaches for modeling the AuNP and their distribution within the cell are possible. In this work, two newly developed continuous and discrete-geometric models for simulations of AuNP in cells are presented. [2] These models are applicable to simulations of internal emitters and external radiation sources. Most of the current studies on AuNP focus on external beam therapy. In contrast, we apply the presented models in Monte-Carlo particle scattering simulations to characterize the energy deposit in cell organelles by radioactive 198AuNP. They emit beta and gamma rays and are therefore considered for applications with solid tumors. Differences in local dose enhancement between randomly distributed and nucleus targeted nanoparticles are compared. Hereby nucleus targeted nanoparticels showed a strong local dose enhancement in the radio sensitive nucleus. These results are the foundation for ongoing experimental work which aims to obtain a mechanistic understanding of cell death induced by radioactive 198Au. T2 - #RSCposter 2023 CY - Online meeting DA - 28.02.2023 KW - AuNP KW - Beta decay KW - Brachytherapy KW - Cancer treatment KW - Clustered nanoparticles KW - DNA KW - DNA damage KW - Dosimetry KW - Energy deposit KW - Geant4 KW - Geant4-DNA KW - Gold Nanoparticles KW - LEE KW - Livermore model KW - Low energy electrons KW - MCS KW - Microdosimetry KW - Monte-Carlo simulation KW - NP KW - OH radical KW - Penelope model KW - Radiation damage KW - Radiation therapy KW - Radiationtherapy KW - Radiotherapy KW - Radioactive decay KW - Radiolysis KW - Simulation KW - TOPAS KW - TOPAS-nbio KW - beta particle KW - particle scattering PY - 2023 AN - OPUS4-57060 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hoell, A. T1 - On the usage of anomalous SAXS to analyzethe structure and composition of bimetallic nanoparticles and quantum dots N2 - Tailor-made nanoparticles are of increasing interest in e.g. catalysis, as sensor materials, analytical assays, or can have superior photophysical properties. A major issue concerning the preparation of high-quality and functional nanoparticles is a good control of particle size, shape, polydispersity, and composition. Small Angle X-ray Scattering (SAXS) is a non-destructive method for the analysis of nanostructures in a wide variety of materials. This method allows determining averaged structural parameters on a length scale from just above atomic sizes up to several 100 nanometers such as sizes, size distributions, volume fractions, and inner surface sizes. Moreover, anomalous Small Angle X-ray Scattering (ASAXS) exploits the anomalous dispersion of the scattering amplitudes near the X-ray absorption edges of the elements contained in the sample. These element sensitive contrast variations can be used to analyse average composition fluctuations on the nm scale. Two kinds of nanoparticles are chosen here to elaborate the advantages of ASAXS in the analysis of complex materials. A facile and efficient methodology is developed for the thermal synthesis of size-tunable, stable, and uniform bimetallic NiCu core–shell nanoparticles (NPs) for various application in catalysis. Their diameter can be tuned in a range from 6 nm to 30 nm and the Ni:Cu ratio is adjustable in a wide range from 1:1 to 30:1. The NPs are structurally characterized by a method combination of transmission electron microscopy, anomalous small-angle X-ray scattering (ASAXS), X-ray absorption fine structure, and X-ray photoelectron spectroscopy. Here, we focus on the ASAXS method and its ability to analyses nanostructure parts and their compositions at once. As a result, a NiCu alloyed core surrounded by a Ni enriched shell and an outer NiO shell was found. Semiconductor nanocrystals (quantum dots, QDs) are well known for their superior photophysical properties and enabled advancements in several key technologies of the 21st century and numerous technological applications like in photovoltaics, LED displays, photocatalysis, and biosensing. To achieve high photoluminescence quantum yields (PLQY) and enhanced photostability the QD core needs to be passivated by a second semiconductor, which possess a larger band gap to confine the charges within the QD core. An important parameter is thereby the lattice mismatch between the core and shell. To avoid strong lattice strain, which would alter the photophysical properties, an intermediary shell can be used as a lattice adapter between the core and the outer shell leading to core/shell/shell systems. These systems have shown to possess high PLQYs combined with a strong long-term stability and can be found in modern QLED displays. ASAXS was used here to better understand the core/shell/shell structure of InP/ZnSe/ZnS QDs to enable a correlation between their structural and photophysical properties. T2 - IUCr - International Union of Crystallography CY - Melbourne, Australia DA - 22.08.2023 KW - ASAXS KW - Quantum dot KW - Core/shell materials KW - Safer by design PY - 2023 AN - OPUS4-58812 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Herbst, Tristan T1 - Einsatzpotenzial und nachhaltige Verwertung von Hausmüllverbrennungsaschen als Gesteinskörnungen im Beton N2 - Im Hinblick auf eine nachhaltige Entwicklung sollen nach dem KrW/AbfG der Rohstoffeintrag und der Abfallaustrag in den Lebensphasen eines Bauwerks durch weitgehende Verwertung von Sekundärrohstoffen (Reststoffen) möglichst gering gehalten werden. Ein Einsatz von Reststoffen wie Hausmüllverbrennungsaschen (MV-Aschen) im Betonbau kann potenziell einen wesentlichen Beitrag zur nachhaltigen Entwicklung leisten. T2 - Tagung Bauchemie CY - Freiberg, Germany DA - 08.10.2009 PY - 2009 AN - OPUS4-22966 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Sebastian A1 - Meng, Birgit A1 - Selleng, Christian T1 - A new sample holder for fast xrd investigation on UHPC N2 - A new sample holder is described in this poster. It was developed in BAM for fast XRD investigation on UHPC (ultra high performance concrete). Results measuring solid, i.e. not pulverized, samples are shown. T2 - GeoBerlin 2015 CY - Berlin, Germany DA - 04.10.2015 KW - Building Materials KW - UHPC KW - X-ray diffractometry PY - 2015 AN - OPUS4-36949 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rübner, Katrin A1 - Haamkens, Frank A1 - Linde, O. T1 - Untersuchungen an Beton mit Hausmüllverbrennungsasche als Gesteinskörnung N2 - Hausmüllverbrennungsasche soll aufgrund ihrer chemisch-mineralogischen Eigenschaften als Gesteinskörnung zur Herstellung von Normalbetonen eingesetzt werden. Durch Bestandteile, wie Chloride, metallisches Aluminium und Altglasfragmente, entstehen aber in kürzester Zeit beträchtliche Betonschäden. Durch zusätzliche mechanische, chemische oder thermische Aufbereitungsschritte können diese betonschädigenden Inhaltsstoffe minimiert werden. Dadurch lässt sich die Qualität der Asche soweit verbessern, dass sie gut zur Betonherstellung verwendbar ist. T2 - GDCh-Fachtagung Bauchemie CY - Siegen, Germany DA - 27.09.2007 KW - Normalbeton KW - Chloride KW - Aluminium KW - Altglasfragmente KW - Betonschäden PY - 2007 AN - OPUS4-36506 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rübner, Katrin A1 - Fritz, Thomas T1 - Untersuchungen zur Präzision von Porositätsmessungen an Zementmörtel N2 - Ermittlung der Präzision des Messverfahrens Quecksilberporosimetrie für die Materialklasse Zementmörtel durch Ringversuche nach ISO 5725 T2 - 10. Workshop über die Charakterisierung von Feinteiligen und Porösen Festkörpern CY - Bad Soden, Germany DA - 14.11.2000 KW - Quecksilberporosimetrie KW - Ringversuche KW - ISO 5725 PY - 2000 AN - OPUS4-36512 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rübner, Katrin A1 - Rübner, J. A1 - Knölle, G. A1 - Tschritter, H. T1 - Porosität neuer anorganisch-organischer Nanoverbunde N2 - Kiefernholz wird durch Imprägnieren mit einem Vorkondensat aus organischen Disäuren und Glycerin, das kolloidale Kieselsäure enthält, sowie nachfolgende Ofenhärtung in Kieselsäure/Alkydharz/Holz-Verbunde umgewandelt. Diese Nanoverbunde haben eine geringere Porosität als Holz, da Teile der Holzzellen mit Harz und Kieselsäure ausgefüllt sind. Die kugelförmigen, etwa 60 nm großen (SiO1)x-Teilchen liegen in der Polymermatrix mikrophasensepariert vor. Der kolloidale Zustand der eingebrachten Polykieselsäure bleibt erhalten. Durch ihr günstiges Eigenschaftsprofil sind die Verbundmaterialien als modifizierter Holzbaustoff interessant. T2 - 3. Tagung Bauchemie CY - Würzburg, Germany DA - 27.09.2001 KW - Kiefernholz KW - Disäuren KW - Glycerin KW - Kieselsäure KW - Holzbaustoff PY - 2001 AN - OPUS4-36507 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Munsch, Sarah Mandy T1 - 1H NMR Relaxometry: A Reliable Tool for Predicting Durability Properties? N2 - Resistance to carbonation and chloride migration are critical durability properties in cementitious construction materials. The ingress of CO2 and chlorides can lead to concrete deterioration and reinforcement corrosion, underscoring the importance of ensuring high resistance to these durability-reducing factors. Traditional methods, such as determinating the carbonation coefficient using standard procedures, are time-consuming and resource-intensive. These tests typically require 42 days of preconditioning, followed by 70 days before the final results can be determined using a phenolphthalein test, for a total duration of 112 days. In addition, some test chambers can only accommodate four samples at a time. In this study, we investigate whether 1H NMR relaxometry can effectively predict not only the carbonation resistance, KAC,3%, but also the chloride migration coefficient, DRCM, and the compressive strength, fc, of concrete, providing a method that could potentially streamline and accelerate the material development process by directing us quickly to potentially well-suited formulations. We performed measurements on non-carbonated fully saturated concrete and mortar samples at 28, 56, and 92 days using the NMR tomograph at BAM (8.9 MHz). Notably, the NMR measurements taken at 28 days showed no significant differences, suggesting that this timeframe is sufficient for meaningful results. The samples analyzed were drill cores, each 70 mm in diameter and approximately 120 mm in height. The NMR features we focused on included the initial amplitude E0, the x and y values of the dominant T2 relaxation time, and the logarithmic mean of the T2 relaxation time distribution. Another key feature was the surface relaxivity, which was determined by comparing the NMR curves with results from mercury intrusion porosimetry. We examined the correlation of these NMR features with the aforementioned durability properties, which were determined in a laboratory on sister samples using standard procedures. No chloride migration tests were performed on the mortar samples, and the carbonation procedure was carried out unter atmospheric conditions. The preliminary results show that the correlation factors for the NMR features with the carbonation coefficients of concrete were particularly remarkable. The strongest correlations were observed for the dominant relaxation time and the logarithmic mean, with values approaching 1. The preliminary results also indicate that there are high correlations between the compressive strength and amplitude-related features. In contrast, no strong correlations are observed for the DRCM. Although the results related to the mortar samples are still being analyzed, these initial correlations suggest that 1H NMR relaxometry could be a valuable tool for early assessment of material properties. Furthermore, the rapid and non-destructive nature of NMR measurements, requiring only a few minutes per sample, suggests that this technique has the potential to significantly accelerate the process of evaluating durability properties in cementitious materials. This capability also paves the way for the use of NMR features as input for AI-driven predictive models. T2 - Magnetic Resonance in Porous Media 2024 CY - Tromso, Norway DA - 26.08.2024 KW - Nuclear magnetic resonance KW - SLAMD KW - Carbonation KW - Durability PY - 2024 AN - OPUS4-61058 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bahlmann, Stefanie A1 - Rübner, Katrin A1 - Meng, Birgit T1 - Untersuchungen zur Verwertung industrieller Reststoffe als Ersatz von Primärrohstoffen in Mörtel und Beton N2 - Um den Abbau primärer Rohstoffe zu reduzieren, wurden deponierte oder niederwertig eingesetzte industrielle Reststoffe hinsichtlich einer höherwertigen Verwendung im Betonbau untersucht. Zur Bewertung des Einsatzpotentials als Zementbestandteil oder Betonzusatzstoff erfolgte zunächst eine chemisch-mineralogische und betontechnologische Charakterisierung der Materialien. Reststoffe, die die normativen Anforderungen hinsichtlich der Zementzusammensetzung erfüllen, wurden anschließend zu verschiedenen Anteilen als Zementsubstitut in Mörtel eingesetzt. In vergleichenden Untersuchungen erfolgte die Ermittlung der Frisch- und Festmörteleigenschaften. Kalorimetrische Untersuchungen sollten die Auswirkungen der Reststoffe auf die Zementhydratation zeigen. Ausgewählte Untersuchungsergebnisse an Reststoffen aus der Industrieabwasseraufbereitung, dem Altpapierrecycling, der Biomasseverbrennung und der Metallurgie werden vorgestellt. T2 - 17. Internationale Baustofftagung IBAUSIL 2009 CY - Weimar, Germany DA - 23.09.2009 KW - Industrieabwasseraufbereitung KW - Altpapierrecycling KW - Biomasseverbrennung KW - Metallurgie PY - 2009 AN - OPUS4-36516 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wallau, Wilma T1 - Alkali-Kieselsäure-Reaktion in Beton - Entwicklung eines Prognoseverfahrens N2 - Zur Vermeidung der schädigenden Alkali-Kieselsäure-Reaktion in Betonbauwerken wird die Alkalireaktivität von Gesteinskörnungen im Vorhinein getestet. Der 60°C-Betonversuch ermöglicht eine vergleichsweise schnelle Einschätzung nach fünf-monatiger Testzeit. Dazu wird die Dehnung von Betonprüfkörpern, die mit der zu testenden Gesteinskörnung hergestellt wurden, manuell alle 28 Tage gemessen. Ein alternatives, an der BAM in den vergangen Jahren entwickeltes Verfahren setzt Dehnungssensoren ein, um kontinuierlich und online zu messen. Die Dehnungskurven sind eine gute Grundlage sowohl für die Prognose vom Expansionsverhalten während des Tests als auch für die Validierung von Expansionsmodellen. T2 - 3. Workshop im Themenfeld Material zu den Schwerpunktthemen "Laufende Projekte und neue Aktivitäten" CY - Berlin, Germany DA - 12.10.2016 KW - Baustoffe KW - Alkali-Kieselsäure-Reaktion PY - 2016 AN - OPUS4-40156 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stohl, Leonie T1 - Bioreceptivity of structured concrete panels N2 - Understanding the fundamentals of bioreceptivity enables the developement of functionalized materials. Concrete as the most used building material worldwide is of special interest as microbially greened panels may represent an alternative to classic façade greening with plants. � This project includes extensive outdoor experiments, in which eight differently structured concrete panels are weathered under different conditions, aiming to grow a stable biofilm of photosynthetic eukaryotic organisms. Documentation and data analysis of this experiment will be demonstrated using an example of one of the surfaces. T2 - Word Green Infrastructure Congress 2023 CY - Berlin, Germany DA - 27.06.2023 KW - Bioreceptivity KW - Concrete KW - Material design PY - 2023 AN - OPUS4-57919 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Höhne, Patrick T1 - Utilization of an ultra sound atomizer for spray granulation of oxide ceramic fine powder N2 - Spray drying based granulation processes aim for flowable granules neither containing voids nor hard shells thus leading to a homogenous microstructure in the green and sinter bodies without strength reducing large pores. The increase of the specific surface area due to the utilization of finer powders as raw materials makes the production of granules of demanded quality more sophisticated. Innovations regarding additives as well as process engineering are therefore required. While conventional spray granulation processes of ceramic materials are based on rotational, one stream or two stream nozzles for nebulization, the investigations in the ZIM project concentrate on the applicability of an ultra sound atomizer unit. A spray dryer comprised of the aforementioned ultra sound atomization unit implemented in a commercial spray dryer (Niro, Denmark) was used as test system. Potential advantages of the ultra sound nebulization are investigated for model systems of alumina, zirconia and a ZTA composite while focusing on solids content, yield, pressability and granule properties (size, size distribution, flowability, shape and microstructure) as well as the final sinter body properties (density, microstructure and flexural strength). First ultra sound spray drying experiments yielded granules with excellent processability. Spray drying of identical slurries, as before tested and optimized for a two stream nozzle atomization process, resulted in a more suitable size distribution for dry pressing (less particles below 20 µm) and a higher yield. Furthermore, sinter bodies produced of ultra sound granules seem to have less large pores and a more homogenous microstructure T2 - 92. Jahrestagung der deutschen keramischen Gesellschaft CY - Berlin, Germany DA - 20.03.2017 KW - Ceramics KW - Spray drying KW - Ultra sound KW - Atomization KW - Microstructure PY - 2017 AN - OPUS4-39588 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sentker, Kathirn A1 - Yildirim, Arda T1 - Fabrication of organic nanowires by melt infiltration of a discotic liquid crystal: A combined X-ray diffraction and optical birefringence study N2 - Optical polarimetry and angle dependent X-ray scattering in employed to study the structure of a discotic liquid crystal confined into nanochannels. The pore size dependence of the obtauned data are discussed in detail. T2 - DPG Spring Meeting 2017 CY - Dresden, Germany DA - 20.03.2017 KW - Discotic Liquid Crystals KW - Nanoconfinement PY - 2017 AN - OPUS4-39591 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yildirim, Arda T1 - Structure, Dynamics and Phase Behavior of a Discotic Liquid Crystal Confined in Nanoporous Anodic Aluminum Oxide Membranes N2 - The interest in porous anodic aluminum oxide (AAO) has been rapidly growing due to its numerous applications in separation, catalysis, energy generation and storage, electronics, and sensors. From the scientific point of view, AAO is a topical interest in soft matter fields. Spatial confinement of soft matter in nanoporous media influences its structure, thermodynamics, and mobility. Embedding polymers and liquid crystals into nanopores of AAO results in a 2D nanoconfinement of these materials. This confinement affects their properties, compared to the bulk, such as phase transition temperatures and enthalpies, molecular mobility, and architecture of the crystallization. On the other hand, discotic liquid crystals (DLCs) are a promising class of soft matter for electronic applications. This is due to their ability to organize and stack themselves into columns in a hexagonal columnar mesophase, a mesophase in between the plastic crystalline and isotropic phase, driven by the overlap of the π orbitals of their aromatic core. This leads to a high charge-carrier mobility along the column axis. Further, these columns could then be considered as “molecular nanowires”. In this study, 2,3,6,7,10,11 hexakis[hexyloxy] triphenylene (HAT6), a triphenylene based DLC, was confined into nanoporous AAO membranes. The structure, dynamics and the phase behavior of the confined HAT6 were investigated by broadband dielectric spectroscopy (BDS) and differential scanning calorimetry (DSC). HAT6 was embedded into nanoporous AAO membranes by melt infiltration in the isotropic phase under argon atmosphere. The membranes have parallel aligned cylindrical nanopores, with pore diameter of 10, 20, 25, 40, 80, 120 and 180 nm. The filling degree for each sample was checked by thermogravimetric analysis (TGA) in order to ensure complete filling. Bulk HAT6 forms a hexagonal columnar phase; in between the isotropic phase above 371 K and the plastic crystalline phase below 340 K. Unlike the bulk, the confined HAT6 split the plastic crystalline-to-hexagonal columnar phase transition in two, which might be interpret as two different phase structures; close to the wall and at the pore center. Moreover, the isotropic-to-columnar transition of the confined HAT6 shifted, with decreasing pore diameter, to lower temperatures. Furthermore, pore surfaces of a series of membranes were chemically modified, resulting in a more hydrophobic pore surface than the unmodified ones. HAT6 was embedded into the modified membranes by the same aforementioned preparation. The influence of the changed host-guest-interaction, on the structure, dynamics, and the phase behavior of HAT6 confined in the modified membranes, was also investigated by BDS and DSC. T2 - 9th International Conference on Porous Media & Annual Meeting CY - Rotterdam, The Netherlands DA - 08.05.2017 KW - Nanoporous media KW - Anodic Aluminum Oxide KW - Discotic Liquid Crystal PY - 2017 AN - OPUS4-40089 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schadow, Florian T1 - Sende-Empfangs-Prüfköpfe auf Ferroelektret-Basis für Luftultraschall-Anwendungen N2 - Leichtbaustrukturen aus Verbundwerkstoffen stellen einen immer größeren Anteil im Flugzeug- und Automobilbau dar. Hiermit steigt die Nachfrage nach zuverlässigen, zerstörungsfreien Prüfmethoden, welche an solche Strukturen angepasst sind. Besonders Luftultraschall (LUS) eignet sich für diese Aufgabe, da hier kein Koppelmedium benötigt wird. Derzeit wird für diese Methode jedoch oft ein beidseitiger Bauteilzugang für eine Prüfung in Durchschallung vorausgesetzt. Handelsübliche Prüfköpfe für Luftultraschallanwendungen nutzen zudem meist Anpassschichten um den Impedanzunterschied zwischen Schwinger und Luft zu reduzieren. Sowohl Signal-Rausch-Abstand als auch die Bandbreite der resultieren-den Prüfköpfe ist für viele Anwendungen jedoch nicht ausreichend. Durch den Einsatz von Ferroelektreten wie zellulärem Polypropylen (zPP) kann hingegen vollständig auf Anpassschichten verzichtet werden. Hierbei handelt es sich um polarisierte, zelluläre Polymerschichten mit sehr geringer Dichte, Steifigkeit und Schallgeschwindigkeit. In diesem Beitrag stellen wir drei verschiedene Sende-Empfangs-Prüfköpfe vor, welche auf zellulärem Polypropylen basieren. Anhand von Schallfeld, Signal-Rausch-Abstand und Sendepegel werden diese Prüfköpfe charakterisiert. Die Ergebnisse werden mit den Ergebnissen von Referenzprüfköpfen ohne Sende-Empfangs-Charakteristik verglichen. Bei den Referenzprüfköpfen werden sowohl handelsübliche LUS-Prüfköpfe, sowie bisher entwickelte Prüfköpfe aus zellulärem Polypropylen berücksichtigt. T2 - DGZFP Jahrestagung 2017 CY - Koblenz, Germany DA - 22.05.2017 KW - Sende-Empfangs Prüfkopf KW - Ferroelektret KW - Zelluläres Polypropylen KW - Charakterisierung KW - Luftultraschall PY - 2017 AN - OPUS4-40430 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Otremba, Frank T1 - Testing of pressurized vessels N2 - The results are based on data1. Figure 3 displays temperatures of the tank wall and of the gas phase over testing time. It can be seen that a complete coating strongly delayed the heating of tank wall and gas phase, whereas the partly coated tanks only had a minor influence on temperature development. There was no significant difference between a half coated and a thirdly coated tank measurable. Figure 4 shows the internal pressure of tanks over testing time. Only the fully coated tank enabled a low pressure over 90 min testing time. Hence, a complete coating is necessary to guarantee the fire safety of hazmat tanks and a partly coating is not sufficient. T2 - Annual Conference on Engineering and Information Technology CY - Nagoya - Japan DA - 29.03.2017 KW - Fire KW - Testing KW - Vessels KW - Dangerous goods PY - 2017 AN - OPUS4-39843 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlichting, S. A1 - Hönig, Gerald T1 - Tuning of the quantum-confined Stark effect in wurtzite [0001] nanostructures by the internal-field-guarded-active-region design N2 - In this work we eliminate the QCSE without having any special requirements on the growth procedure or the material. Hönig et al. developed the Internal-Field-Guarded-Active-Region Design (IFGARD), which we experimentally investigate in this work based on GaN/AlN nanodiscs (NDs). T2 - Compound Semiconductor Week 2017 CY - Berlin, Germany DA - 14.05.2017 KW - Halbleiterphysik KW - Nanophysik KW - Optoelektronik KW - Piezopolarisation KW - Spontane Polarisation PY - 2017 AN - OPUS4-40174 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schulz, Bärbel T1 - High-temperature stability of ceramic springs N2 - Metallic springs undergo oxidation and creep at elevated temperatures and their use is limited to temperature of about 650°C. Therefore, there is a need for stable materials which can easily withstand temperatures up to 1000°C for long periods in different atmospheres. Ceramic materials have been drawing attention due to their excellent properties. This work aimed at investigating the high-temperature stability of zirconia and alumina ceramic springs at elevated temperatures under different atmospheres (air, N2 and H2) in order to determine the limitation of use of these ceramic springs. T2 - DKG 2017 CY - Berlin, Germany DA - 20.03.2017 KW - Ceramic spring KW - High-temperature stability KW - Harsh environments KW - Spring constant PY - 2017 AN - OPUS4-40289 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Czarnecki, Sebastian T1 - Synthesis of hybrid inorganic/organic homopolymers via ATRP and RAFT: A practical comparison N2 - The synthesis of hybrid inorganic/organic copolymers, using reversible deactivation radical polymerization (RDRP) techniques, has been an intensively studied research topic over recent years. A plethora of hybrid inorganic/organic copolymers were synthesized, including hybrid inorganic/organic block copolymers as well as random copolymers,[1–4] that showed great potential in fabricating hybrid (nano)materials with tailored properties [5]. Two widely employed RDRP techniques to prepare such hybrid inorganic/organic copolymers are atom transfer radical polymerization (ATRP) [1,2] and reversible addition-fragmentation chain transfer (RAFT) polymerization [3,4]. In order, to afford hybrid inorganic/organic copolymers with narrow dispersity, high conversions and precise structures, it is required to choose proper reaction conditions. Due to the importance of both ATRP and RAFT in the preparation of such hybrid polymers, we aim to compare both RDRP techniques by preparing 2-acetoxyethyl methacrylate (AcEMA) and 3-(triethoxysilyl)propyl methacrylate (TESPMA) based homopolymers. For this purpose, AcEMA and TESPMA were polymerized in 1,4-dioxane at 60 °C mediated by CuBr/N,N,N',N'-pentamethyldiethylenetriamine (PMDETA) and 2-(2-carboxylethylsulfanylthiocarbonyl-sufanyl) propionic acid (TTC) as well as cumyl dithiobenzoate (CDB) to evaluate the suitability and reliability of ATRP and RAFT to prepare such hybrid (co)polymers. T2 - Berlin Chemie Symposium 2017 CY - TU Berlin, Berlin, Germany DA - 06.04.2017 KW - Hybrid inorganic/organic copolymers KW - ATRP KW - RAFT PY - 2017 UR - https://bcs.jcf-berlin.de/BCS2017/BoA2017.pdf AN - OPUS4-40280 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kotschate, Daniel T1 - Hochauflösende Reinheitsgradbestimmung – Fertigung von Referenzfehlern N2 - Regelwerke zur zerstörungsfreien Bestimmung des Reinheitsgrades wie das SEP 1927 und die ASTM E588 erreichen ihre Vergleichbarkeit unter Anwendung von - vergleichsweise einfachen - Referenzfehlern. Hinsichtlich Realisierbarkeit wird somit der Kompromiss zwischen Herstellung des Referenzfehlers und der erreichbaren Nachweisgrenze gefunden. Zur Weiterentwicklung über die Grenzen der SEP1927 hinaus, wurde der Versuch unternommen Fehler kleiner 500 μm herzustellen - welche aufgrund der geringen geometrischen Ausdehnung fertigungsbedingt schwierig zu realisieren sind. Bei den vergleichenden Untersuchungen kristallisierten sich zwei Fertigungsverfahren, Funkenerosion (EDM: electrical discharge maching) und die Fertigung der Bohrungen unter Verwendung eines Hochleistungslasers, als vielversprechend heraus. Zunächst wurden die Fehler mit beiden Verfahren in unterschiedlichen Größen (100, 250 und 100 μm) und Tiefen (1, 1,5 und 2 mm) unter Anwendung von computertomographischen Verfahren der Röntgenprüfung, die Geometrie der eingebrachten Fehlstellen und anschließend durch hochauflösende Tauchtechnikmessungen das Reflektionsverhalten charakterisiert. T2 - DGZfP Jahrestagung CY - Koblenz, Germany DA - 22.05.2017 KW - Materialcharakterisierung KW - Reinheitsgradbestimmung KW - Ultraschalltauchtechnik PY - 2017 AN - OPUS4-40353 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Woydt, Mathias T1 - Potentials of niobium carbide (NbC) as cutting tools and for wear protection N2 - Niobium is today largely available. NbC grades displayed lower dry sliding friction over WC grades. The softer Ni- and NiMo-bondes NbC1.0-grades have a higher abrasive wear resistance (ASTM G65), even with lower toughnesses, as the tougher WC-Co grades. T2 - 19. Plansee Seminar CY - Reutte, Austria DA - 29.05.2017 KW - Niobium carbide (NbC) KW - Cutting tools KW - Hardness PY - 2017 AN - OPUS4-40512 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wäsche, Rolf T1 - Colloidal processing of metal bonded niobium carbide (NbC-Ni) N2 - The manufacturing of NbC with Ni binder with addition of titanium carbide by using a colloidal process for blending the different powders without a milling step were investigated. The the sintering process and formation of the resulting microstructures, the phase relations and the hardness of the produced cermet materials are characterized. T2 - 19. Plansee Seminar CY - Reutte, Austria DA - 29.05.2017 KW - Niobium carbide (NbC) KW - Cermets KW - Hardness PY - 2017 AN - OPUS4-40513 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -