TY - CONF A1 - Schneider, M. A1 - Schlingmann, T. A1 - Schmidt, J. A1 - Bettge, Dirk A1 - Hilgenberg, Kai A1 - Binder, M. A1 - Klöden, B. T1 - A Round Robin Test To Investigate The Printing Quality Of PBF LB/M Processed AlSi10Mg N2 - When it comes to higher accuracies, new technologies and real applications in additive manufacturing, there is one topic which cannot be avoided: The material response on the chosen processing parameters and its agreement and correspondence with literature data of the wrought material grade counterpart. In industrial Additive Manufacturing (AM) standards in terms of printing parameters, protection gas atmospheres or powder handling instructions are not obligatory. Therefore, the question must be answered whether the AM process is reproducible and reliable over different printing companies. This was the motivation to realize a round robin test between 8 European printing companies and academic partners. The consortium had printed and tested fatigue and tensile testing bars under plant-specific conditions. A commonly used cast aluminum alloy, AlSi10Mg, was chosen as test material for the PBF-LB/M process. Differences of the results between the partners and the scatter itself were discussed in detail. T2 - World PM2022 CY - Lyon, France DA - 09.10.2022 KW - Additive manufacturing KW - AlSi10Mg KW - Laser powder bed fusion KW - Round robin KW - Reproducibility PY - 2022 AN - OPUS4-56303 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Werner, Tiago A1 - Madia, Mauro A1 - Hilgenberg, Kai A1 - Gärtner, F. A1 - Klassen, T. T1 - Structural integrity of cold spray repaired aerospace components N2 - Components in aircrafts are usually replaced when critical defects are present. An alternative approach is repairing using gas dynamic cold spraying: metal particles are shot at a surface at supersonic speeds to selectively rebuild damaged material. Compared to other material-deposition techniques, its advantage is the small thermal impact on the component, preserving its mechanical properties. Component-repair can save considerable amounts of energy and resources. However, its industrial application at large scale needs reproducible, good repair-material properties to guarantee a safe component life. The aim of this project is the development of safe, automatized repair-procedures considering the mechanical fatigue properties of the repair. T2 - ICEAF VII Conference 2023 CY - Spetses, Greece DA - 21.06.2023 KW - Cold Spray KW - Repair KW - Fatigue KW - Fatigue Crack Growth KW - Slow Strain Rate Testing PY - 2023 AN - OPUS4-57784 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ulbricht, Alexander A1 - Altenburg, Simon A1 - Sprengel, Maximilian A1 - Sommer, Konstantin A1 - Mohr, Gunther A1 - Fritsch, Tobias A1 - Mishurova, Tatiana A1 - Serrano Munoz, Itziar A1 - Evans, Alexander A1 - Hofmann, Michael A1 - Bruno, Giovanni T1 - Separation of the Formation Mechanisms of Residual Stresses in LPBF 316L N2 - Rapid cooling rates and steep temperature gradients are characteristic of additively manufactured parts and important factors for the residual stress formation. This study examined the influence of heat accumulation on the distribution of residual stress in two prisms produced by Laser Powder Bed Fusion (LPBF) of austenitic stainless steel 316L. The layers of the prisms were exposed using two different border fill scan strategies: one scanned from the centre to the perimeter and the other from the perimeter to the centre. The goal was to reveal the effect of different heat inputs on samples featuring the same solidification shrinkage. Residual stress was characterised in one plane perpendicular to the building direction at the mid height using Neutron and Lab X-ray diffraction. Thermography data obtained during the build process were analysed in order to correlate the cooling rates and apparent surface temperatures with the residual stress results. Optical microscopy and micro computed tomography were used to correlate defect populations with the residual stress distribution. The two scanning strategies led to residual stress distributions that were typical for additively manufactured components: compressive stresses in the bulk and tensile stresses at the surface. However, due to the different heat accumulation, the maximum residual stress levels differed. We concluded that solidification shrinkage plays a major role in determining the shape of the residual stress distribution, while the temperature gradient mechanism appears to determine the magnitude of peak residual stresses. T2 - MLZ User Meeting 2020 CY - Online meeting DA - 08.12.2020 KW - Computed tomography KW - Neutron diffraction KW - X-ray diffraction KW - Additive manufacturing KW - Residual stress KW - Thermography KW - LPBF KW - Laser Powder Bed Fusion PY - 2020 AN - OPUS4-51793 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ulbricht, Alexander A1 - Altenburg, Simon A1 - Mohr, Gunther T1 - µCT as Benchmark for Online Process Monitoring N2 - µCT is used to validate the capability of online monitoring for in-situ detection of defects during the L-PBF build process, which is a focus of the TF project ProMoAM. Our first experiments show that online monitoring using thermography and optical tomography cameras are able to detect defects in the built part. But further research is needed to understand root cause of the correlation. T2 - Workshop on Additive Manufacturing: Process, materials, simulation & implants CY - BAM, Berlin, Germany DA - 13.05.2019 KW - Computed tomography KW - Online Process Monitoring KW - Additive Manufacturing KW - Powder Bed Fusion KW - Selected Laser Melting PY - 2019 AN - OPUS4-48073 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ulbricht, Alexander A1 - Altenburg, Simon A1 - Mohr, Gunther T1 - The Influence of the Temperature Gradient on the Distribution of Residual Stresses in AM AISI 316L N2 - Steep temperature gradients and solidification shrinkage are the main contributors to the formation of residual stresses in additively manufactured metallic parts produced by laser beam melting. The aim of this work was to determine the influence of the temperature gradient. Diffraction results show a similar pattern for both specimens, indicating the shrinkage to be more dominant for the distribution of residual stresses than the temperature gradient. Thermography results imply that a higher energy input result in higher compressive residual stresses in the bulk. T2 - Workshop on Additive Manufacturing: Process, materials, simulation & implants CY - BAM, Berlin, Germany DA - 13.05.2019 KW - Computed tomography KW - Online Process Monitoring KW - Additive Manufacturing KW - Powder Bed Fusion KW - Selected Laser Melting KW - Neutron Diffraction PY - 2019 AN - OPUS4-48075 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hilgenberg, Kai A1 - Spranger, Felix T1 - Localized laser dispersing of titanium-di-boride with pulsed fiber laser N2 - In this paper, titanium-di-boride is dispersed on a cold-working tool steel by use of a pulsed fiber laser with high beam quality to produce separated and elevated surface features. The potential to adjust the geometry as well as the mechanical properties of the produced structures in dependence on the process parameters (pulse power, pulse duration) is described by means of metallographic and topographical investigations. It can be ascertained that very hard (hardness > 1000 HV1) surface features of different shape (spots and short lines) can be produced. They are characterized by a fine-grained microstructure resulting from a rapid solidification and finely dispersed TiB2 particles. Finally, the paper proposes different applications for this structuring technique. T2 - ICALEO 2017 - International congress on applications of lasers & electro-optics CY - Atlanta, GA, USA DA - 22.10.2017 KW - Laser dispersing KW - Titanium-di-boride KW - Surface structuring KW - Laser implantation PY - 2017 AN - OPUS4-42867 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Thiel, Erik A1 - Altenburg, Simon A1 - Myrach, P. A1 - Mohr, Gunther A1 - Gumenyuk, Andrey T1 - Crack detection in metal additive manufacturing with laser thermography N2 - BAM ensures and represents high standards for safety in technology and chemistry. Additive manufacturing (AM) changes the requirements for conventional non-destructive testing (NDT) as new processes of defect creation occur. Especially in safety critical areas, such as aerospace and automotive, new manufacturing processes and materials always require reliability tests and new standards which is a big challenge for NDT. T2 - Internationales Laser- und Fügesymposium CY - Dresden, Germany DA - 27.02.2018 KW - Laser Beam Melting KW - Laser Metal Deposition KW - Thermography KW - In-situ monitoring PY - 2018 AN - OPUS4-45619 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sprengel, Maximilian A1 - Ulbricht, Alexander A1 - Evans, Alexander A1 - Mohr, Gunther A1 - Kromm, Arne A1 - Bruno, Giovanni A1 - Kannengießer, Thomas T1 - Using Neutron Diffraction to Monitor Stress Relaxation in Additively Manufactured 316L N2 - The relaxation of residual stress in laser powder bed fused stainless steel 316L parts was monitored using monochromatic and time-of-flight neutron diffraction. T2 - ISIS student meeting CY - Online meeting DA - 26.10.2020 KW - Stainless Steel KW - Residual Stress KW - Additive Manufacturing PY - 2020 AN - OPUS4-51469 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yu, C.-H. A1 - Sprengel, Maximilian A1 - Schröder, Jakob A1 - Serrano Munoz, Itziar A1 - Mohr, Gunther A1 - Evans, Alexander A1 - Kromm, Arne A1 - Peng, R. L. A1 - Kannengießer, Thomas A1 - Bruno, Giovanni A1 - Moverare, J. T1 - Distribution of subsurface residual stress as a function of wall thickness in stainless steel 316L LPBF structures N2 - The subsurface residual stress in laser powder bed fused 316L structures was analyzed using X-ray diffraction (XRD) and layer removal. The influence of varying structure thicknesses was investigated. In this study the importance of combining surface roughness measurements with XRD was shown. Moreover, a clear relation between the structure thickness and the subsurface residual stress profiles was observed. T2 - The 11th International Conference on Residual Stress CY - Nancy, Frankreich DA - 28.03.2022 KW - AGIL KW - Residual Stress KW - X-ray Diffraction KW - Additive Manufacturing PY - 2022 AN - OPUS4-54581 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gawlitza, Kornelia A1 - Pérez-Padilla, Víctor A1 - Sun, Yijuan A1 - Valderrey, Virginia A1 - Bell, Jérémy A1 - Rurack, Knut T1 - On-Site Detection of PFAAs with Dual Fluorescent MIPs Coupled to a Miniaturized Microfluidics Platform N2 - Per- and polyfluoroalkyl substances (PFAS) represent a class of synthetic organofluorine chemicals extensively utilized in the manufacturing of various materials such as firefighting foams, adhesives, and stain- and oil-resistant coatings. In recent years, PFAS have been considered as emerging environmental contaminants, with particular focus on perfluoroalkyl carboxylic acids (PFCAs), the most prevalent type among PFAS. PFCAs are characterized by a fully fluorinated carbon backbone and a charged carboxylic acid headgroup. Notably, they have been designated as Substances of Very High Concern and added to the REACH Candidate List due to their persistence in the environment, non-biodegradability and toxicological effects. Conventional techniques for the analysis of PFCA, such as GC-MS, HRMS and HPLC-based methods, are laborious, not portable, costly and require skilled personnel. In contrast, fluorescence assays can be designed as easy-to-operate, portable and cost-effective methods with high sensitivity and fast response, especially when analyte binding leads to a specific increase of a probe’s emission. Integration of such probes with a carrier platform and a miniaturized optofluidic device affords a promising alternative for PFCA monitoring. Here, a novel guanidine BODIPY fluorescent indicator monomer has been synthesized, characterized, and incorporated into a molecularly imprinted polymer (MIP) for the specific detection of perfluorooctanoic acid (PFOA). The MIP layer was formed on tris(bipyridine)ruthenium(II) chloride doped silica core particles for optical internal reference and calibration-free assays. Such system allows selective and reliable detection of PFCA from surface water samples, with minimum interference by competitors, matrix effects and other factors. Integration of the assay into an opto-microfluidic setup resulted in a miniaturized and easy-to-operate detection system allowing for micromolar detection of PFOA in less than 15 minutes from surface water sample. T2 - MIP2024: The 12th International Conference on Molecular Imprinting CY - Verona, Italy DA - 18.06.2024 KW - Sensor KW - PFAS KW - Molecularly imprinted polymers KW - Guanidine receptor KW - BODIPY PY - 2024 AN - OPUS4-60438 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mrkwitschka, Paul A1 - Hodoroaba, Vasile-Dan A1 - Pellegrino, Francesco A1 - Rossi, Andrea A1 - Jones, Elliot T1 - Towards automated analysis of the lateral dimensions of graphene oxide flakes N2 - Graphene and graphene-oxide (GO) are advanced materials which – similar to other graphene-related 2D materials (GR-2M) - are already used for instance in catalysis processes, biomedical applications, in inks and resins, or as composite materials for the aviation industry. The lateral/structural characterization of graphene oxide (GO) flakes is a challenging task, with steps like sample preparation, representative image selection and exact determination of the particle size distribution of well-defined size and shape descriptors being crucial for an accurate analysis. To ensure that safe-by-design principles are met within the various application fields, the commercial material must be thoroughly characterized and specified through well-known and standardized procedures. GO flakes with different degrees of complexity were selected to assess the requirements for an accurate evaluation of their physico-chemical properties. These samples show inherent features with complex nanoscale characteristics such as porosity and edge roughness; further, the lateral size (quantified via equivalent circular diameter (ECD), minimum Feret and maximum Feret) of isolated and overlapping particles deposited on a substrate span over several orders of magnitude (nano to micron scale). The samples showed different degrees of agglomeration (and possible aggregation) with sizes ranging between submicron to a few tens of micrometers. One focus is the automated segmentation and evaluation of images obtained by electron microscopy. The GO samples appear translucent with well-defined contrast between single and overlapping flakes both with the secondary electron detector of type InLens as well as with SEM in the transmission mode (STEM) utilizing a dedicated sample holder. To this end it is of utmost importance for the accurate image segmentation to carefully select thresholds both manually and through semi-automatic approaches using well-known threshold algorithms such as “IsoData” and pre-defined segmentation applications such as the ParticleSizer software package. Further specific challenges in identifying and extracting key features of selected graphene oxide flakes are being discussed and approaches towards accurate and representative characterization are presented. T2 - E-MRS 2024 Spring Meeting CY - Strasbourg, France DA - 27.05.2024 KW - Graphene /-oxide KW - Morphology KW - Electron microscopy KW - Imaging KW - Advanced materials PY - 2024 AN - OPUS4-60435 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Matthews, Lauren A1 - Sahre, Mario A1 - Hesse, R. A1 - Schusterbauer, Robert A1 - Grant, M. A1 - Agudo Jacome, Leonardo A1 - Albrecht, T. A1 - Hodoroaba, Vasile-Dan T1 - Approaches to Surface Analysis of Modified Quartz Nanopipettes N2 - Nanopipettes are a type of solid-state nanopore with needle-like geometry. Their applications range from imaging, sensing, diagnostics, and use as injectors. The response of nanopipette sensors is highly dependent on the size, geometry and chemical properties of the sensing region. As they are increasingly tuned and modified for specific analytes, a better understanding of the surface chemistry and morphology of the inner channel is necessary. With the aim of developing a comprehensive approach for characterisation of such nanopipettes, this research focuses on combining surface-sensitive analysis methods with advanced sample preparation techniques. Quartz substrates were modified by gas phase silanization, a well-utilised technique in the field to enhance performance of nanopipettes, and further functionalised with a metal bis thiolate complex, to aid in chemical analysis. The sample characterisation involved scanning electron microscopy (SEM), low-energy dispersive x-ray spectroscopy (EDX), time-of-flight secondary ion mass spectrometry (ToF-SIMS) and Auger electron spectroscopy (AES). Using focused ion beam (FIB) milling under gentle conditions, the inner surface of quartz nanopipettes was exposed whilst preserving the integrity of the overall structure (see figure). Owing to the challenging analysis conditions, modification and analysis of flat quartz substrates has been performed in parallel for optimisation purposes. The results demonstrate the first steps towards full characterisation of nanopipettes at the nanoscale, notably with access to the inner channel. The methods used here can be applied to gain further understanding of the response of these sensors to complex analytes and allow for the study of different surface functionalisations at the all-important sensing region. T2 - European Conference on Applications of Surface and Interface Analysis (ECASIA 2024) CY - Gothenburg, Sweden DA - 09.06.2024 KW - Quartz nanopipettes KW - Nanopipette modification KW - Silanization KW - Surface analysis KW - Focussed ion beam PY - 2024 AN - OPUS4-60447 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Matthews, Lauren A1 - Sahre, Mario A1 - Hesse, R. A1 - Schusterbauer, Robert A1 - Grant, M. A1 - Agudo Jacome, Leonardo A1 - Albrecht, T. A1 - Hodoroaba, Vasile-Dan T1 - Approaches to Surface Analysis of Modified Quartz Nanopipettes N2 - Nanopipettes are a type of solid-state nanopore with needle-like geometry. Their applications range from imaging, sensing, diagnostics, and use as injectors. The response of nanopipette sensors is highly dependent on the size, geometry and chemical properties of the sensing region. As nanopipettes are increasingly tuned and modified for specific analytes, a better understanding of the surface chemistry and morphology of the inner channel is necessary. For exploring these effects, quartz nanopipettes were modified by gas phase silanization, a well-utilised technique in the field to enhance performance of nanopipettes, and further functionalised with a metal bis thiolate complex, to aid in chemical analysis. The inner channel of the sensing region was exposed with focused ion beam (FIB) milling as a dedicated sample preparation method for nanoscale surface analysis. The sample characterisation involved scanning electron microscopy (SEM), Auger electron spectroscopy (AES) and low-energy energy dispersive x-ray spectroscopy (EDX). The results demonstrate the first steps towards full characterisation of nanopipettes at the nanoscale, notably with access to the inner channel. The methods used here can be applied to gain further understanding of the response of these sensors to complex analytes, and allow for the study of different surface functionalisation at the all-important sensing region. T2 - 2024 Spring Meeting of the European Materials Research Society (E-MRS) CY - Strasbourg, France DA - 27.05.2024 KW - Nanopipettes KW - FIB KW - Surface analysis KW - Surface modification KW - Silanisation PY - 2024 AN - OPUS4-60449 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stegemann, Robert A1 - Pelkner, Matthias A1 - Sonntag, Nadja A1 - Kreutzbruck, Marc A1 - Skrotzki, Birgit T1 - Bewertung der magnetischen Mikrostruktur für die Schadensfrüherkennung N2 - Die Mikrostruktur ferromagnetischer Materialien hat einen maßgeblichen Einfluss auf deren magnetischen Eigenschaften. Gerade bei niedrigen Feldstärken zeigen sich Parameter wie Koerzitivität, Permeabilität und Verlustleistung hoch sensitiv. Wir zeigen am Beispiel des unlegierten Baustahls S235JR, dass die magnetische Mikrostruktur an der Probenoberfläche in hohem Maße mit inhomogenen Dehnungen übereinstimmt. Zur Detektion der Kleinststreufelder verwenden wir speziell designte GMR Sensorik, die Sensitivität (3mV/V/kA/m) mit hoher Ortsauflösung (180 µm) vereint. Infolgedessen können wir auf eine aktive magnetische Anregung verzichten. Wir nutzen allein die sich durch magneto-mechanische Prozesse ausbildende „spontane“ magnetische Mikrostruktur des Materials. Das hervorragende Signal-Rausch-Verhältnis unserer GMR-Sensorik für inhomogene Streufelder erlaubt, schon geringe und lokal abgegrenzte plastische Deformationen in Form und Position reproduzierbar zu visualisieren. Die zugehörigen Signale zeigen die typische Sequenz von erhöhten positiven und negativen Normalkomponenten wie sie bei einer Rissanzeige der aktiven Streuflussprüfung (MFL - Magnetic Flux Leakage) beobachtet wird. Magnetisch kann eine plastische Zone daher als Vorstufe eines Risses betrachtet werden, deren relative Permeabilität für den Riss als Grenzfall zu μr = 1 tendiert. T2 - DGZfP-Jahrestagung CY - Koblenz, Germany DA - 22.05.2017 KW - Baustahl KW - GMR-Sensorik KW - Heterogene plastische Deformation KW - Zugversuch PY - 2017 AN - OPUS4-40375 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Miliūtė, Aistė A1 - Bustamante, Joana A1 - Mieller, Björn A1 - Stawski, Tomasz A1 - George, Janine A1 - Knoop, F. T1 - High-quality zirconium vanadate samples for negative thermal expansion (NTE) analysis N2 - Zirconium vanadate (ZrV2O7) is a well-known negative thermal expansion (NTE) material which exhibits significant isotropic contraction over a broad temperature range (~150°C < T < 800°C). The linear thermal expansion coefficient of ZrV2O7 is −7.1×10-6 K-. Therefore, it can be used to create composites with controllable expansion coefficients and prevent destruction by thermal shock. Material characterization, leading to application, requires pure, homogenous samples of high crystallinity via a reliable synthesis route. While there is a selection of described syntheses in the literature, it still needs to be addressed which synthesis route leads to truly pure and homogenous samples. Here, we study the influence of the synthesis methods (solid-state, sol-gel, solvothermal) and their parameters on the sample's purity, crystallinity, and homogeneity. The reproducibility of results and data obtained with scanning electron microscopy (SEM), X-ray diffraction (XRD), differential scanning calorimetry, and thermogravimetric analysis (DSC/TGA) were analyzed extensively. The sol-gel method proves superior to the solid-state method and produces higher-quality samples over varying parameters. Sample purity also plays an important role in NTE micro and macro-scale characterizations that explain the impact of porosity versus structural changes. Moreover, we implement ab-initio-based vibrational computations with partially treated anharmonicity (quasi-harmonic approximation, temperature-dependent effective harmonic potentials) in combination with experimental methods to follow and rationalize the negative thermal expansion in this material, including the influence of the local structure disorder, microstructure, and defects. Khosrovani et al. and Korthuis et al., in a series of diffraction experiments, attributed the thermal contraction of ZrV2O7 to the transverse thermal motion of oxygen atoms in V-O-V linkages. In addition to previous explanations, we hypothesize that local disorder develops in ZrV2O7 crystals during heating. We are working on the experimental ZrV2O7 development and discuss difficulties one might face in the process as well as high-quality sample significance in further investigation. The obtained samples are currently used in the ongoing research of structure analysis and the negative thermal expansion mechanism. T2 - 4th International Symposium on Negative Thermal Expansion and Related Materials (ISNTE-4) CY - Padua, Italy DA - 04.07.2023 KW - NTE KW - Sol-gel KW - Solid-state KW - Ab-initio KW - TDEP PY - 2023 AN - OPUS4-58132 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bresch, Sophie A1 - Mieller, Björn A1 - Rabe, Torsten T1 - Optimization of Solid-State-Reactions of Calcium Cobaltite Ca3Co4O9 N2 - Calcium cobaltite is a promising p-type oxide thermoelectric material for high temperature applications due to its high figure of merit between 600 °C and 900 °C in air. The solid-state-reaction is well known for large scale powder synthesis of functional materials. As a high temperature process, the powder synthesis consumes a lot of energy. In different studies, different synthesis conditions were used for the preparation of calcium cobaltite powder. This study showed that a higher energy input (elevated temperatures, longer dwell times, or repeated calcinations) during powder synthesis does not increase but decrease the Seebeck coefficient and the electrical conductivity. The same correlation was determined for the densification. As a higher energy input leads to a larger grain size and therefore to a reduced sinter activity, it can be concluded that the thermoelectric properties are correlated with the sinter activity of the powder. These results can be used to minimize the energy demand for the powder synthesis of Ca₃Co₄ O₉. T2 - 14th European Conference on Thermoelectrics CY - Lisbon, Portugal DA - 20.09.2016 KW - Thermoelectrics KW - Solid-State-Reaction KW - Calcium cobaltite PY - 2016 AN - OPUS4-37543 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eddah, Mustapha A1 - Markötter, Henning A1 - Mieller, Björn A1 - Beckmann, Jörg A1 - Bruno, Giovanni T1 - Synchrotron Multi-energy HDR tomography for LTCC systems N2 - LTCCs (Low-temperature co-fired ceramics) consist of three-dimensionally distributed, hermetically bonded ceramic and metallic components with structure sizes within [10; 100] µm. A non-destructive imaging technique is needed that provides 3D, sharp, high-contrast resolution of these structures, as well as porosity and defect analysis, which is made difficult by the very different X-ray absorption coefficients of the individual components of the microstructure. A HDR method is being developed that allows a combination of different tomograms, each with X-ray energies adapted to individual materials. T2 - Bessy II User Meeting CY - Berlin, Germany DA - 22.06.2023 KW - LTCC KW - Synchrotron tomography KW - Data fusion KW - In-situ tomography PY - 2023 AN - OPUS4-57795 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -