TY - CONF A1 - Agasty, Amit T1 - A Preliminary Study on the Scaling of RC Structures under Blasting Loading N2 - Current capabilities for full-scale field blast testing are highly resource intensive. Reliable small-scale experiments are an effective alternative. Characterization of the dynamic response and damage of RC elements to scaled blast loads was investigated in scaled-down field experiments. Spatially resolved information on the dynamic structural response to blast loading was obtained using distributed fiber optic acoustic sensing (DAS), acceleration sensors as well as piezoelectric pressure sensors. T2 - 46. Informationstagung Sprengtechnik CY - Siegen, Germany DA - 25.04.2025 KW - Explosives KW - Blast and scaling effects KW - Concrete PY - 2025 AN - OPUS4-62994 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bell, Jérémy T1 - Embedded sensor for the detection of TNT in surface and marine waters N2 - In 1945, the Potsdam Conference led to the decision to destroy a significant amount of ammunition from the warring parties of WWII. Dumping was considered the cheapest, quickest, and safest solution to dispose of unused ammunition. However, thin barrels or containers often leak after 50 years, allowing explosives to escape into the marine environment. As the effects of weapons chemicals on ecosystems are well-documented, it is becoming increasingly important to detect, recover and dispose of old ammunition. Physical techniques such as magnetometry and sonar are used to detect ammunition in the sea, but they do not provide chemical information. Detecting leaking organic contaminants like TNT or other explosives in water or soil requires high-end laboratory equipment like HPLC or GC-MS, making remote water testing virtually impossible. As an alternative, a miniaturized method for the selective and sensitive indication of TNT using fluorescence light-up sensing was developed. The visual identification of TNT with a nucleophile that forms a strongly absorbing charge transfer complex (CTC) is a well-known method. This CTC is formed by the attraction of an electron from the donor molecule by the electron-deficient aromatic ring. In this work, a TNT-based CTC was selectively formed by the addition of tetraoctylammonium acetate in N,N-diethylformamide and, as expected, showed strong absorption. Surprisingly, at room temperature, the CTC can be converted into a fluorescent product with an emission band centred at 577 nm. For the detection of TNT in water, a microfluidic chip made of polydimethylsiloxane (PDMS) is used for both the extraction and reaction steps. In addition to miniaturising the experimental steps, the optical system (fluorometer) has been integrated into an autonomous smartphone assembly capable of catalysing the photoreaction and analysing the fluorescence response. Taking advantage of the light-up response, TNT was still easily detectable down to 9.4 ng with the CMOS camera. Further evaluation of this analytical tool consisted of analyses of unfiltered and untreated surface water samples spiked directly with increasing concentrations of TNT to reflect different levels of contamination. LODs of 21 and 40 ng were found for samples from the Teltow Canal in Berlin (DEU) and the Baltic Sea near Greifswald (DEU). Such an analytical tool could be used to monitor water quality in the field, as the release of organic pollutants from munitions into surface and marine waters will become increasingly problematic and concentrations will continue to rise over the coming decades. T2 - ANAKON 2025 CY - Leipzig, Germany DA - 10.03.2025 KW - Explosives KW - Microfluidics KW - Smartphone KW - Sprengstoffe KW - Mikrofluidik KW - Sensor PY - 2025 AN - OPUS4-62767 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hernández García, María Amparo T1 - SAF-based optical biosensor with 3D-printed free-form optics for targeted explosives immuno-detection N2 - Guaranteeing safety and security of citizens requires a significant effort and innovative tools from national and international agencies and governments, especially when it comes to the field of explosives detection. The need to detect Improvised Explosive Devices (IEDs) and Home-made Explosives (HMEs) at a point of suspicion, has grown rapidly due to the ease with which the precursors can be obtained and the reagents synthesised. The limited availability of immunoanalytical tools for HME detection presents an opportunity for the development of new devices, which enable a rapid detection and recognise the target analyte with high specificity and sensitivity. In this work, we introduce an optical biosensor for highly specific and sensitive HME detection. The immunoassay system is placed in a hydrogel environment permeable to the analyte and transparent to light interrogating the fluorescently labelled antibodies. The readout of the immunoanalytical system is realized with Supercritical Angle Fluorescence (SAF), an advanced microscopy technique. To accomplish this, we made use of recent, commercial high resolution (< 22 µm) Liquid Crystal Display 3D printers to fabricate a parabolic optical element with high refractive index (RI>1.5) and transmission values (>90%) from photo-resin. Aiming at a new generation of sensors, which not only can meet the requirements of trace detection, but can also be used for substance identification, the combination of immunoanalytical recognition with SAF detection offers a modularity and versatility that is principally well suitable for the measurements of target analytes at trace levels. T2 - 8th International conference in Biosensing Technology CY - Seville, Spain DA - 12.05.2024 KW - 3D printing KW - Biosensor KW - Fluorescence KW - Explosives PY - 2024 AN - OPUS4-60561 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rurack, Knut T1 - Sensitive and multiplexed assays for point-of-need applications: innovations for robust, reliable, and user-friendly diagnostics N2 - The development of portable analytical assays, particularly during the SARS-CoV-2 pandemic, has revolutionized diagnostics and expanded their use to areas such as food safety, environmental monitoring and forensics. These assays offer the advantage of rapid on-site decision making without the need for laboratory facilities. The omnipresence of mobile devices with advanced cameras and processing power further increases their usability. However, most current assays are limited to detecting single parameters. The challenge now is to develop robust multiplexed assays that can simultaneously detect multiple parameters with high sensitivity. This lecture will present generic approaches developed at BAM with a focus on supramolecular chemistry, luminescence detection, nanomaterials and miniaturization of devices. Examples include mesoporous nanomaterials, gated indicator systems, imprinted polymers, microfluidic devices, test strips and smartphone-based analysis. T2 - Kolloquium Optische Technologien der FH Münster CY - Steinfurt, Germany DA - 18.12.2024 KW - Rapid testing KW - Fluorescence KW - Explosives KW - Environmental contaminants KW - Multiplexing PY - 2024 AN - OPUS4-62322 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Léonard, Fabien A1 - Zhang, Zhen A1 - Krebs, Holger A1 - Bruno, Giovanni T1 - Structural and Morphological Quantitative 3D Characterisation of Ammonium Nitrate Prills by X-ray Computed Tomography N2 - The mixture of ammonium nitrate (AN) prills and fuel oil (FO), usually referred to as ANFO, is extensively used in the mining industry as a bulk explosive. One of the major performance predictors of ANFO mixtures is the fuel oil retention, which is itself governed by the complex pore structure of the AN prills. In this study, we present how X-ray computed tomography (XCT), and the associated advanced data processing workflow, can be used to fully characterise the structure and morphology of AN prills. We show that structural parameters such as volume fraction of the different phases and morphological parameters such as specific surface area and shape factor can be reliably extracted from the XCT data, and that there is a good agreement with the measured oil retention values. Importantly, oil retention measurements (qualifying the efficiency of ANFO as explosives) correlate well with the specific surface area determined by XCT. XCT can therefore be employed non-destructively; it can accurately evaluate and characterise porosity in ammonium nitrate prills, and even predict their efficiency. KW - ANFO KW - Explosives KW - Surface area KW - Porosity KW - XCT KW - Data processing PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-505395 DO - https://doi.org/10.3390/ma13051230 VL - 13 IS - 5 (Special Issue "Micro Non-Destructive Testing and Evaluation") SP - 1230 PB - MDPI AN - OPUS4-50539 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Léonard, Fabien A1 - Hasenfelder, Uta A1 - Krebs, Holger A1 - Bruno, Giovanni T1 - Assessment of shock tube systems by synchrotron X-ray computed tomography N2 - Shock tube systems are non-electric explosive fuses employed in blasting and demolition applications to trigger the detonation of explosive charges. Their working principle is based on the explosive reaction of a fine explosive powder on the tubing's inner surface, generating a shock wave traveling at a velocity of 2,100 m/s along the length of the tube, without destroying it. One of the key aspects of the manufacturing process of these shock tubes is the size and morphology of the explosive powder grains and their distribution on the inner wall of the tube, in order to propagate the shockwave efficiently and reliably. For the first time, synchrotron X-ray computed tomography has been used to characterize non-destructively the explosive powder grains, typically Al/HMX between 10 and 20 μm in size, in terms of morphology and 3D distribution but also to characterise the presence and location of defects within the shock tube walls. KW - Explosives KW - Nonel KW - Shock wave KW - Blasting KW - Energetic systems PY - 2017 UR - http://www.ndt.net/events/iCT2017/app/content/Paper/61_Leonard.pdf SP - 1 EP - 7 CY - Leuven, Belgium AN - OPUS4-39345 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -