TY - JOUR
A1 - Bonse, Jörn
A1 - Sokolowski‐Tinten, Klaus
T1 - Probing Laser‐Driven Structure Formation at Extreme Scales in Space and Time
N2 - Irradiation of solid surfaces with high intensity, ultrashort laser pulses triggers a variety of secondary processes that can lead to the formation of transient and permanent structures over a large range of length scales from mm down to the nano‐range. One of the most prominent examples are LIPSS – Laser‐Induced Periodic Surface Structures. While LIPSS have been a scientific evergreen for of almost 60 years, experimental methods that combine ultrafast temporal with the required nm spatial resolution have become available only recently with the advent of short pulse, short wavelength free electron lasers. Here, the current status and future perspectives in this field are discussed by exploiting the unique possibilities of these 4th‐generation light sources to address by time‐domain experimental techniques the fundamental LIPSS‐question, namely why and how laser irradiation can initiate the transition of a “chaotic” (rough) surface from an aperiodic into a periodic structure.
KW - Laser-induced periodic surface structures (LIPSS)
KW - Free electron laser
KW - Pump-probe experiments
KW - Time-resolved scattering
KW - Capillary waves
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595048
DO - https://doi.org/10.1002/lpor.202300912
SN - 1863-8899
VL - 18
SP - 1
EP - 11
PB - Wiley-VCH GmbH
CY - Weinheim
AN - OPUS4-59504
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Keshmiri, Hamid
A1 - Cikes, Domagoj
A1 - Samalova, Marketa
A1 - Schindler, Lukas
A1 - Appel, Lisa-Marie
A1 - Urbanek, Michal
A1 - Yudushkin, Ivan
A1 - Slade, Dea
A1 - Weninger, Wolfgang J.
A1 - Peaucelle, Alexis
A1 - Penninger, Josef
A1 - Elsayad, Kareem
T1 - Brillouin light scattering anisotropy microscopy for imaging the viscoelastic anisotropy in living cells
N2 - Maintaining and modulating mechanical anisotropy is essential for biological processes. However, how this is achieved at the microscopic scale in living soft matter is not always clear. Although Brillouin light scattering (BLS) spectroscopy can probe the mechanical properties of materials, spatiotemporal mapping of mechanical anisotropies in living matter with BLS microscopy has been complicated by the need for sequential measurements with tilted excitation and detection angles. Here we introduce Brillouin light scattering anisotropy microscopy (BLAM) for mapping high-frequency viscoelastic anisotropy inside living cells. BLAM employs a radial virtually imaged phased array that enables the collection of angle-resolved dispersion in a single shot, thus enabling us to probe phonon modes in living matter along different directions simultaneously. We demonstrate a precision of 10 MHz in the determination of the Brillouin frequency shift, at a spatial resolution of 2 µm. Following proof-of-principle experiments on muscle myofibres, we apply BLAM to the study of two fundamental biological processes. In plant cell walls, we observe a switch from anisotropic to isotropic wall properties that may lead to asymmetric growth. In mammalian cell nuclei, we uncover a spatiotemporally oscillating elastic anisotropy correlated to chromatin condensation. Our results highlight the role that high-frequency mechanics can play in the regulation of diverse fundamental processes in biological systems. We expect BLAM to find diverse applications in biomedical imaging and material characterization.
KW - Optical and magnetic materials
KW - Atomic and molecular physics and optics
KW - Electronic
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595125
DO - https://doi.org/10.1038/s41566-023-01368-w
SN - 1749-4885
SN - 1749-4893
VL - 18
IS - 3
SP - 276
EP - 285
PB - Nature Publ. Group
CY - London
AN - OPUS4-59512
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Schuberth, Jens
A1 - Ebert, Thomas
A1 - Schlegel, Moritz-Caspar
A1 - Rödig, Lisa
A1 - Jepsen, Dirk
A1 - Memelink, Robin
A1 - Hauschke, Fynn
T1 - The Front-Runner Approach - Facilitating Progressive Product Policy by Using Information from EU Product Databases
N2 - The European Commission has recently announced two guiding principles for EU product policy: First, product policy shall ensure that the performance of front-runner products in terms of sustainability becomes the norm, and second, the effectiveness of the current Ecodesign legislative framework is going to be significantly improved. Within this paper, already existing front-runner approaches and recent and ongoing product policy-making processes were reviewed. Based on the results, an EU front-runner approach is outlined. The presented approach (i) refers to performance levels of the best products already available on the market, (ii) aggregates information in existing databases, and (iii) works semi-automated. Together, all three attributes have a high potential to facilitate and accelerate the specification of appropriate minimum requirements for products at the EU level. This way, EU policymakers can deliver on the core objectives of the Ecodesign legislative framework much better. The basic mechanism and its legal entrenchment of the approach are illustrated for the energy efficiency of energy-related products. In addition, the Front-Runner Approach can be applied to any product group in the scope of the upcoming Ecodesign for Sustainable Products Regulation and to a wide range of product-related minimum requirements, such as durability, reparability, or recycled content. The study’s objective is to suggest a tailor-made and dynamic approach to keep the EU product legislation up to date using innovative technology based on the investigation of current regulations and identify the gap. Experiences from three international case studies suggest that a front-runner approach to setting energy-performance standards can drive innovation and reduce energy consumption via promoting energy-efficient products; transparency about available products is one of the key factors and can be established by a database. The EU front-runner approach comprises extending the existing energy label database (or making use of the digital product passport) and introducing a legislative procedure that triggers changes in the energy efficiency requirements in the specific EU regulations if the database shows that a certain threshold value is reached. Challenges such as limited EU staff capacities and opportunities such as increased dynamic are discussed.
KW - Ecodesign
KW - ESPR
KW - Energy labelling
KW - EPREL
KW - Policy making
KW - Front-runner
KW - Material efficiency
KW - Resource efficiency
KW - Energy efficiency
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595132
DO - https://doi.org/10.3390/en17020504
VL - 17
IS - 2
SP - 1
EP - 11
PB - MDPI
AN - OPUS4-59513
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Slotyuk, Lyubov
A1 - Part, Florian
A1 - Schlegel, Moritz-Caspar
A1 - Akkerman, Floris
T1 - Life Cycle Assessment of the Domestic Micro Heat and Power Generation Proton Exchange Membrane Fuel Cell in Comparison with the Gas Condensing Boiler Plus Electricity from the Grid
N2 - The energy demand of private households contributes globally to 36.5% of the total CO2 emissions. To analyze the emissions reduction potential, we conducted a comparative life cycle assessment of a proton exchange membrane fuel cell in a residential application and a conventional system with a stand-alone gas condensing boiler and electricity from a grid mix. The period under review was referred to as the service life of the PEMFC and is assumed to be 10 years (83,038 h of PEMFC). The applicability of this in a single-family house built between 1991 and 2000 under German climatic conditions was investigated. The functional unit is set to the thermal energy demand of 16,244 kWh/a and electricity demand of 4919 kWh/a of a single-family house. The impact assessment method “CML 2001–August 2016” was used in this investigation. The manufacturing phase of the proton exchange membrane fuel cell showed disadvantages, whereby the use phase had significant advantages in most of the environmental impact categories as compared to the conventional energy supply system. Considering the whole life cycle, the advantages from the use phase could outperform the disadvantages from the manufacturing phase in most of the impact categories, except for ADP elements and TETP.
KW - Sustainability
KW - Circular Economy
KW - Comparative life cycle assessment
KW - Proton exchange membrane fuel cell
KW - Gas condensing boiler
KW - Micro heat and power generation
KW - Residential application
KW - Single-family house energy supply system
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-598134
DO - https://doi.org/10.3390/su16062348
VL - 16
IS - 6
SP - 1
EP - 16
PB - MDPI AG
AN - OPUS4-59813
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Turski Silva Diniz, Analice
A1 - Schartel, Bernhard
T1 - The effects of property variation on the dripping behaviour of polymers during UL94 test simulated by particle finite element method
N2 - The dripping behaviour of polymers is often observed experimentally through the UL94 flammability standard test. In this work, polymeric dripping under fire is investigated numerically using particle finite element method. A parametric analysis was carried out to observe the influence of a single property on overall dripping behaviour via a UL94 vertical test model. Surrogates and property ranges were defined for variation of the following parameters: glass transition temperature (Tg), melting temperature (Tm), decomposition temperature (Td), density (ρ), specific heat capacity (Cp), apparent effective heat of combustion of the volatiles, char yield (μ), thermal conductivity (k), and viscosity (η). Polyamide, poly(ether ether ketone), poly(methyl methacrylate), and polysulfone were used as benchmarks. Simulated results showed that specific heat capacity, thermal conductivity, and char yield allied with viscosity were the properties that most influenced dripping behaviour (starting time and occurrence).
KW - Dripping
KW - PFEM
KW - UL 94
KW - Simulation
KW - Fire behaviour
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-597449
DO - https://doi.org/10.1515/epoly-2023-0194
SN - 1618-7229
VL - 24
IS - 1
PB - De Gruyter
AN - OPUS4-59744
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Temgoua, Ranil C.T.
A1 - Dontsi, Fabiola T.
A1 - Lebègue, Estelle
A1 - Thobie-Gautier, Christine
A1 - Tonlé, Ignas K.
A1 - Boujtita, Mohammed
T1 - Understanding the behavior of phenylurazole-tyrosine-click electrochemical reaction using hybrid electroanalytical techniques
N2 - In this work, the electrochemical behavior of 4-phenylurazole (Ph-Ur) was studied and the latter was used as a molecular anchor for the electrochemical bioconjugation of tyrosine (Y). Cyclic voltammetry (CV) and controlled potential coulometry (CPC) allowed the in-situ generation of the PTAD (4-phenyl-3 H-1,2,4-triazole-3,5(4 H)-dione) species from phenylurazole on demand for tyrosine electrolabeling. The chemoselectivity of the reaction was studied with another amino acid (lysine, Lys) and no changes in Lys were observed. To evaluate the performance of tyrosine electrolabeling, coulometric analyses at controlled potentials were performed on solutions of phenylurazole and the phenylurazole-tyrosine mixture in different proportions (2:1, 1:1, and 1:2). The electrolysis of the phenylurazole-tyrosine mixture in the ratio (1:2) produced a charge of 2.07 C, very close to the theoretical value (1.93 C), with high reaction kinetics, a result obtained here for the first time. The products obtained were identified and characterized by liquid chromatography coupled to high-resolution electrospray ionization mass spectrometry (LC-HRMS and LC- HRMS2). Two products were formed from the click reactions, one of which was the majority. Another part of this work was to study the electrochemical degradation of the molecular anchor 4-phenylazole (Ph-Ur). Four stable degradation products of phenylurazole were identified (C7H9N2O, C6H8N, C6H8NO, C14H13N4O2) based on chromatographic profiles and mass spectrometry results. The charge generated during the electrolysis of phenylurazole (two-electron process) (2.85 C) is inconsistent with the theoretical or calculated charge (1.93 C), indicating that secondary/parasitic reactions occurred during the electrolysis of the latter. In conclusion, the electrochemically promoted click phenylurazole-tyrosine reactions give rise to click products with high reaction kinetics and yields in the (1:2) phenylurazole-tyrosine ratios, and the presence of side reactions is likely to affect the yield of the click phenylurazole-tyrosine reaction.
KW - Clinical Biochemistry
KW - Spectroscopy
KW - Drug Discovery
KW - Pharmaceutical Science
KW - Analytical Chemistry
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-599267
DO - https://doi.org/10.1016/j.jpba.2024.116147
VL - 245
SP - 1
EP - 8
PB - Elsevier BV
AN - OPUS4-59926
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Zuffa, Caterina
A1 - Cappuccino, Chiara
A1 - Casali, Lucia
A1 - Emmerling, Franziska
A1 - Maini, Lucia
T1 - Liquid reagents are not enough for liquid assisted grinding in the synthesis of [(AgBr)(n-pica)]n
N2 - This study investigates the mechanochemical reactions between AgBr 3-picolylamine and 4-picolylamine. The use of different stoichiometry ratios of the reagents allows [(AgBr)(n-pica)]n and [(AgBr)2(n-pica)]n to be obtained, and we report the new structures of [(AgBr)2(3-pica)]n and [(AgBr)2(4-pica)]n which are characterized by the presence of the following: (a) infinite inorganic chains, (b) silver atom coordinated only by bromide atoms and (c) argentophilic interactions. Furthermore, we studied the interconversion of [(AgBr)(n-pica)]n/[(AgBr)2(n-pica)]n by mechanochemical and thermal properties. The in situ experiments suggest that [(AgBr)(3-pica)]n is kinetically favoured while [(AgBr)2(3-pica)]n is converted into [(AgBr)(3-pica)]n only with a high excess of the ligand. Finally, the liquid nature of the ligands is not sufficient to assist the grinding process, and the complete reaction is observed with the addition of a small quantity of acetonitrile.
KW - Mechanochemistry
KW - Complex
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-594755
DO - https://doi.org/10.1039/d3cp04791a
SN - 1463-9076
SP - 1
EP - 10
PB - Royal Society of Chemistry (RSC)
AN - OPUS4-59475
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Asna Ashari, Parsa
A1 - Blind, Knut
T1 - The effects of hydrogen research and innovation on international hydrogen trade
N2 - Climate change and the pressure to decarbonize, as well as energy security concerns, have drawn the attention of policymakers and the industry to hydrogen energy. To ad-vance the hydrogen economy at a global scale, research and innovation progress is of significant importance, among others. However, previous studies have provided only lim-ited quantitative evidence of the effects of research and innovation on the formation of a global hydrogen market. Instead, they postulate rather than empirically support this rela-tionship. Therefore, this study analyzes the effects of research and innovation measured by scientific publications, patents, and standards on bilateral hydrogen trade flows for 32 countries between 1995 and 2019 in a gravity model of trade, using regression analyses and Poisson Pseudo Maximum Likelihood (PPML) estimation. The main results of the PPML estimation show that research and innovation progress is indeed associated with increased trade, especially with patenting and (international) standardization enhancing hydrogen export volumes. As policy implications, we derive that increased public R&D funding can help increase the competitiveness of hydrogen energy and boost market growth, along with infrastructure support and harmonized standards and regulations.
KW - Hydrogen supply
KW - Global hydrogen market
KW - Research and innovation
KW - Push and pull effects
KW - Hydrogen policies
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-594875
DO - https://doi.org/10.1016/j.enpol.2023.113974
SN - 0301-4215
VL - 186
SP - 1
EP - 15
PB - Elsevier B.V.
AN - OPUS4-59487
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Andreoli, A. F.
A1 - Fantin, Andrea
A1 - Kasatikov, S.
A1 - Bacurau, V. P.
A1 - Widom, M.
A1 - Gargarella, P.
A1 - Mazzer, E. M.
A1 - Woodcock, T. G.
A1 - Nielsch, K.
A1 - Coury, F. G.
T1 - The impact of chemical short-range order on the thermophysical properties of medium- and high-entropy alloys
N2 - The unusual behavior observed in the coefficient of thermal expansion and specific heat capacity of CrFeNi, CoCrNi, and CoCrFeNi medium/high-entropy alloys is commonly referred to as the K-state effect. It is shown to be independent of the Curie temperature, as demonstrated by temperature-dependent magnetic moment measurements. CoCrFeNi alloy is chosen for detailed characterization; potential reasons for the K-state effect such as texture, recrystallization, and second-phase precipitation are ruled out. An examination of the electronic structure indicates the formation of a pseudo-gap in the Density of States, which suggests a specific chemical interaction between Ni and Cr atoms upon alloying. Hybrid Monte Carlo/Molecular Dynamic (MC/MD) simulations indicate the presence of non-negligible chemical short-range order (CSRO). Local lattice distortions are shown to be negligible, although deviations around Cr and Ni elements from those expected in a fully disordered structure are experimentally observed by X-ray absorption spectroscopy. The determined bonding distances are in good agreement with MC/MD calculations. A mechanism is proposed to explain the anomalies and calorimetric experiments and their results are used to validate the mechanism.
KW - Mechanical Engineering
KW - Mechanics of Materials
KW - General Materials Science
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595869
DO - https://doi.org/10.1016/j.matdes.2024.112724
SN - 0264-1275
VL - 238
SP - 1
EP - 15
PB - Elsevier B.V.
AN - OPUS4-59586
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - von Törne, Wipert Jannik
A1 - Steinhäuser, Lorin
A1 - Klyk-Seitz, Urszula-Anna
A1 - Piechotta, Christian
T1 - High-resolution mass spectrometric elucidation of electron ionization induced fragmentation pathways of methylated warfarin and selected hydroxylated species
N2 - The plant secondary metabolite families of coumarin and 4-hydroxy coumarin have a broad pharmacological spectrum ranging from antibacterial to anticancer properties. One prominent member of this substance class is the synthetic but naturally inspired anticoagulant drug and rodenticide warfarin (coumadin). A vast number of publications focus on the identification of warfarin and its major cytochrome P450-mediated phase I metabolites by liquid chromatography (LC) with mass spectrometry (MS) and tandem mass spectrometric (MS/MS) detection techniques. For the first time, electron ionization (EI) induced high-resolution quadrupole time-of-flight mass spectrometric (HR-qToF-MS) data of in-liner derivatized warfarin and selected hydroxylated species is provided in this study as an alternative to LC-MS/MS approaches. Furthermore, the characteristic fragments and fragmentation pathways of the analyzed methyl ethers are concluded. The obtained data of analytical standards, specific deuterated and 13C-labeled compounds prove inductive cleavage of the acyl or acetonyl side chain, methyl migration, and H-migration, along with consequential inductive cleavage as predominant fragmentation routes. Based on the HR-spectral data, commonalities and differences between the analyzed compounds and fragment groups were evaluated with future applicability in structure elucidation and spectra prediction of related compounds.
KW - High-resolution mass spectrometry
KW - Warfarin
KW - Hydroxy warfarin
KW - Fragmentation pathway
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-596025
DO - https://doi.org/10.1016/j.ijms.2024.117220
SN - 1387-3806
VL - 499
SP - 1
EP - 7
PB - Elsevier B.V.
AN - OPUS4-59602
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - von Törne, Wipert Jannik
A1 - Klyk-Seitz, Urszula-Anna
A1 - Piechotta, Christian
T1 - Developing a GC-EI-MS/MS method for quantifying warfarin and five hydroxylated metabolites generated by the Fenton reaction
N2 - AbstractSince the 1950s, Warfarin has been used globally as both a prescription drug and a rodenticide. Research has shown that warfarin and other rodenticides are present in the environment and food chain. However, emerging contaminants are subject to degradation by biotic and abiotic processes and advanced oxidation processes. In some cases, detecting the parent compound may not be possible due to the formation of structurally changed species. This approach aims to identify hydroxylated transformation products of warfarin in a laboratory setting, even after the parent compound has undergone degradation. Therefore, the Fenton reaction is utilized to insert hydroxylation into the parent compound, warfarin, by hydroxyl and hydroperoxyl radicals generated by Fe2+/Fe3+ redox reaction with hydrogen peroxide. Using multiple reaction monitoring, a GC–MS/MS method, incorporating isotopically labeled reference compounds, is used to quantify the expected derivatized species. The analytes are derivatized using trimethyl-3-trifluoromethyl phenyl ammonium hydroxide, and the derivatization yield of warfarin is determined by using isotopically labeled reference compounds. The method has a linear working range of 30 to 1800 ng/mL, with detection limits ranging from 18.7 to 67.0 ng/mL. The analytes are enriched using a C18-SPE step, and the recovery for each compound is calculated. The Fenton reaction generates all preselected hydroxylated transformation products of warfarin. The method successfully identifies that 4′-Me-O-WAR forms preferentially under the specified experimental conditions. By further optimizing the SPE clean-up procedures, this GC–MS-based method will be suitable for detecting transformation products in more complex matrices, such as environmental water samples. Overall, this study provides a better understanding of warfarin’s degradation and offers a robust analytical tool for investigating its transformation products.
KW - Health, Toxicology and Mutagenesis
KW - Pollution
KW - Environmental Chemistry
KW - General Medicine
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595737
DO - https://doi.org/10.1007/s11356-024-32133-3
SN - 0944-1344
VL - 31
SP - 16986
EP - 16994
PB - Springer Science and Business Media LLC
AN - OPUS4-59573
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Lu, Xin
A1 - Hicke, Konstantin
A1 - Krebber, Katerina
T1 - Distributed acoustic sensing to monitor ground motion/movement at multi-frequency bands
N2 - A novel distributed acoustic sensing technique is proposed that exploits both phase and amplitude of the Rayleigh backscattered light to quantify the environmental variation. The system employs a wavelength-scanning laser and an imbalanced Mach-Zehnder interferometer to acquire the reflection spectra and the phase of the detected light, respectively. Fading-free and low-frequency measurements are realized via the crosscorrelation of the reflection spectra. The discrete crosscorrelation is used to circumvent the nonlinear frequency sweeping of the laser. Based on the phase of the backscattered light, it is possible to quantify fast environmental variations. The whole system requires no hardware modification of the existing system and its functionality is experimentally validated. The proposed system has the potential to monitor ground motion/movement at very low frequency band like subsidence around mining areas and at high frequency band like earthquakes and vibrations induced by avalanches.
KW - Distributed acoustic sensing
KW - DAS
KW - Distributed fiber optic sensing
KW - Ground motion detection
KW - Subsidence monitoring
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-596129
DO - https://doi.org/10.1109/JLT.2024.3358495
VL - 42
IS - 18
SP - 1
EP - 8
PB - Optical Society und IEEE Photonics Society
AN - OPUS4-59612
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Kornev, Roman
A1 - Gornushkin, Igor B.
A1 - Shabarova, Lubov
A1 - Kadomtseva, Alena
A1 - Mochalov, Georgy
A1 - Rekunov, Nikita
A1 - Romanov, Sergey
A1 - Medov, Vitaly
A1 - Belousova, Darya
A1 - Maleev, Nikita
T1 - Plasma-Chemical Disposal of Silicon and Germanium Tetrachlorides Waste by Hydrogen Reduction
N2 - The processes of hydrogen reduction of silicon and germanium chlorides under the conditions of high-frequency (40.68 MHz) counteracted arc discharge stabilized between two rod electrodes are investigated. The main gas-phase and solid products of plasma-chemical transformations are determined. Thermodynamic analysis of SiCl4 + H2 and GeCl4 + H2 systems for optimal process parameters was carried out. Using the example of hydrogen reduction of SiCl4 by the method of numerical modeling, gas-dynamic and thermal processes for this type of discharge are investigated. The impurity composition of gas-phase and solid reaction products is investigated. The possibility of single-stage production of high-purity Si and Ge mainly in the form of compact ingots, as well as high-purity chlorosilanes and trichlorogermane, is shown.
KW - High-frequency arc discharge
KW - Hydrogen reduction
KW - Silicon chlorides
KW - Germanium chlorides
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-594454
DO - https://doi.org/10.3390/sci6010001
VL - 6
IS - 1
SP - 1
EP - 12
PB - MDPI AG
AN - OPUS4-59445
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Hupp, Vitus
A1 - Schartel, Bernhard
A1 - Flothmeier, K.
A1 - Hartwig, A.
T1 - Fire Behavior of Pressure-sensitive Adhesive Tapes and Bonded Materials
N2 - Pressure-sensitive adhesive tapes are used in several industrial applications such as con-struction, railway vehicles and the automotive sector,where the burning behavior is ofcrucial importance. Flame retarded adhesivetapes are developed and provided, however,often without considering the interaction of adhesive tapes and the bonded materialsduring burning nor the contribution of the tapes to fire protection goal of the bondedcomponents in distinct fire tests. This publication delivers an empirical comprehensiveknowledge how adhesive tapes and their flame retardancy effect the burning behaviorof bonded materials. With a special focus on the interaction between the single compo-nents, one flame retarded tape and one tapewithout flame retardant are examined inscenarios of emerging and developing fires, along with their bonds with the commonmaterials wood, zinc-plated steel, mineral wool, polycarbonate, and polymethylmethacry-late. The flame retardant significantly improved the flame retardancy of the tape as afree-standing object and yielded a V-2 rating in UL 94 vertical test and raised the OxygenIndex by 5 vol.%. In bonds, or rather laminates, the investigations prove that the choiceof carrier and substrates are the factors with the greatest impact on the fire propertiesand can change the peak of heat release rate and the maximum average rate of heatemission up to 25%. This research yielded a good empirical overall understanding of thefire behavior of adhesive tapes and bonded materials. Thus, it serves as a guide for tapemanufacturers and applicants to develop tapes and bonds more substrate specific.
KW - Adhesives
KW - Cone calorimeter
KW - Flame retardancy
KW - Laminates
KW - Phosphorus flame retardants
KW - Pressure-sensitive adhesive
KW - Tapes
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-593207
DO - https://doi.org/10.1002/fam.3171
SN - 0308-0501
SN - 1099-1018
VL - 48
IS - 1
SP - 114
EP - 127
PB - Wiley
CY - New York, NY
AN - OPUS4-59320
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Bayerlein, Bernd
A1 - Schilling, Markus
A1 - Birkholz, Henk
A1 - Jung, Matthias
A1 - Waitelonis, Jörg
A1 - Mädler, Lutz
A1 - Sack, Harald
T1 - PMD Core Ontology: Achieving semantic interoperability in materials science
N2 - Knowledge representation in the Materials Science and Engineering (MSE) domain is a vast and multi-faceted challenge: Overlap, ambiguity, and inconsistency in terminology are common. Invariant (consistent) and variant (context-specific) knowledge are difficult to align cross-domain. Generic top-level semantic terminology often is too abstract, while MSE domain terminology often is too specific. In this paper, an approach how to maintain a comprehensive MSE-centric terminology composing a mid-level ontology–the Platform MaterialDigital Core Ontology (PMDco)–via MSE community-based curation procedures is presented. The illustrated findings show how the PMDco bridges semantic gaps between high-level, MSE-specific, and other science domain semantics. Additionally, it demonstrates how the PMDco lowers development and integration thresholds. Moreover, the research highlights how to fuel it with real-world data sources ranging from manually conducted experiments and simulations with continuously automated industrial applications.
KW - Ontology
KW - Materials science and engineering
KW - Knowledge representation
KW - Reproducibility
KW - Semantic interoperability
KW - Semantic data integration
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-592948
DO - https://doi.org/10.1016/j.matdes.2023.112603
SN - 0264-1275
VL - 237
SP - 1
EP - 12
PB - Elsevier
CY - Amsterdam
AN - OPUS4-59294
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Flierl, Lukas
A1 - Rienitz, Olaf
A1 - Vogl, Jochen
A1 - Pramann, Axel
T1 - An advancement of the gravimetric isotope mixture method rendering the knowledge of the spike purity superfluous
N2 - The gravimetric isotope mixture method is the primary method to determine absolute isotope ratios. This method, however, depends on the existence of suitable spike materials and knowledge of their purities. Determining the purity of the spikes can be tedious and labour-intensive. In this publication, an advancement of the gravimetric isotope mixture method, rendering the determination of the purity of the spike materials unnecessary, is presented. The advancement combines mass spectrometry and ion chromatography leading to an approach being independent of the purity of the spike materials. In the manuscript the mathematical background and the basic idea of the novel approach are described using a two-isotope system like copper or lithium.
KW - Isotope amount ratios
KW - Metrology
KW - Mass spectrometry
KW - Ion chromatography
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-608726
DO - https://doi.org/10.1007/s00216-024-05465-9
SP - 5325
EP - 5333
PB - Springer Science and Business Media LLC
AN - OPUS4-60872
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Stolar, Tomislav
A1 - Pearce, Ben K.D.
A1 - Etter, Martin
A1 - Truong, Khai-Nghi
A1 - Ostojić, Tea
A1 - Krajnc, Andraž
A1 - Mali, Gregor
A1 - Rossi, Barbara
A1 - Molčanov, Krešimir
A1 - Lončarić, Ivor
A1 - Meštrović, Ernest
A1 - Užarević, Krunoslav
A1 - Grisanti, Luca
T1 - Base-pairing of uracil and 2,6-diaminopurine: from cocrystals to photoreactivity
N2 - We show that the non-canonical nucleobase 2,6-diaminopurine (D) spontaneously base pairs with uracil (U) in water and the solid state without the need to be attached to the ribose-phosphate backbone. Depending on the reaction conditions, D and U assemble in thermodynamically stable hydrated and anhydrated D-U base-paired cocrystals. Under UV irradiation, an aqueous solution of D-U base-pair undergoes photochemical degradation, while a pure aqueous solution of U does not. Our simulations suggest that D may trigger the U photodimerization and show that complementary base-pairing modifies the photochemical properties of nucleobases, which might have implications for prebiotic chemistry.
KW - Mechanochemistry
KW - In situ monitoring
KW - Cocrystals
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-608622
DO - https://doi.org/10.1016/j.isci.2024.109894
VL - 27
IS - 6
SP - 1
EP - 14
PB - Elsevier Inc.
AN - OPUS4-60862
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Davison, Nathan
A1 - Hemingway, Jack M.
A1 - Wills, Corinne
A1 - Stolar, Tomislav
A1 - Waddell, Paul G.
A1 - Dixon, Casey M.
A1 - Barron, Luke
A1 - Dawson, James A.
A1 - Lu, Erli
T1 - Mechanochemical Synthesis of a Sodium Anion Complex [Na+(2,2,2-cryptand)Na–] and Studies of Its Reactivity: Two-Electron and One-Electron Reductions
N2 - Group 1 metal molecular chemistry is dominated by a +1 oxidation state, while a 0 oxidation state is widespread in the metals. A more exotic, yet still available, oxidation state of group 1 metal is −1, i.e., alkalide. Reported as early as the 1970s, the alkalides appear in every modern inorganic chemistry textbook as an iconic chemical curiosity, yet their reactivity remains unexplored. This is due to their synthetic hurdles. In this work, we report the first facile synthesis of the archetypical alkalide complex, [Na+(2,2,2-cryptand)Na–], which allows us to unveil a versatile reactivity profile of this once exotic species.
KW - Mechanochemistry
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-608632
DO - https://doi.org/10.1021/acs.inorgchem.4c02914
VL - 63
IS - 32
SP - 15247
EP - 15258
PB - American Chemical Society (ACS)
AN - OPUS4-60863
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Giv, Ali Nemati
A1 - Asante, Bright
A1 - Yan, Libo
A1 - Kasal, Bohumil
T1 - Shear performance and durability of adhesively bonded spruce wood-concrete composite joints: Effects of indoor and outdoor environmental conditions, mechanical load, and their coupled effect
N2 - A long-term study was conducted on double-lap spruce wood-concrete joints to investigate their shear strength and stiffness over a 12-month period. These joints were manufactured using both wet and dry processes, each incorporating two adhesive types for bonding the wood to the concrete: a brittle epoxy and a ductile polyurethane (PUR). The experimental design exposed the joints to three specific long-term environments: (1) outdoor exposure, (2) indoor conditions with applied load, and (3) outdoor conditions with applied load. The wood concrete joints exposed to outdoor conditions were subjected to destructive shear testing at intervals of 0 (serving as the reference sample), 2, 4, 6, and 12 months, respectively. For joints subjected to both indoor and outdoor conditions with shear loading, the shear deformation of joints was monitored continuously over the 12 months before performing the destructive tests. A gradual reduction in the shear stiffness and strength of dry joints (produced using the dry bond method) exposed to outdoor conditions was observed over a 12-month period, primarily due to bond failure at the concrete-adhesive interface. The wet joints exhibited no degradation in shear stiffness and strength across long-term conditions over the same period. The bond failure observed in dry joints was predominantly associated with stresses arising from dimensional changes in the wood. No degradation was found in the cross-linking density of the adhesive or in the concrete’s compressive stiffness and strength.
KW - Adhesively bonded joints
KW - Long-term study
KW - Ductile PUR
KW - Brittle epoxy
KW - Outdoor condition
KW - Mechanical load
KW - Indoor condition
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-608878
DO - https://doi.org/10.1016/j.conbuildmat.2024.136905
VL - 436
SP - 1
EP - 22
PB - Elsevier BV
AN - OPUS4-60887
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Wegner, Karl David
A1 - Hildebrandt, N.
T1 - Near infrared quantum dots for biosensing and bioimaging
N2 - Quantum dots (QDs) possess unique optoelectronic properties, which make them very attractive to be used as optical probes in biosensing and bioimaging applications. The strong absorbance and light scattering of biological compounds like tissue and blood in the visible range pose a problem. However, if optical probes emitting in the near-infrared (NIR) range are used, scattering, absorption, and autofluorescence of biological components are strongly reduced. This allows for an increased light penetration depth and higher spatial and temporal resolution for the investigation of biological processes. The synthesis and application of NIR emitting QDs is a fast-growing research field and the benefits of using QDs were demonstrated for a variety of applications, such as photoelectrochemical biosensor, in vivo vascular imaging, and fluorescence-guided surgery. This article reviews the state-of-the-art developments in the preparation of NIR/IR QDs and highlights the latest research about their utilization in biosensing and bioimaging applications.
KW - Quantum dots
KW - Near-infrared
KW - Biosensing
KW - Bioimaging
KW - NIR-II / SWIR
KW - Advanced nanomaterials
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-609708
SN - 0165-9936
DO - https://doi.org/10.1016/j.trac.2024.117922
VL - 180
SP - 1
EP - 19
PB - Elsevier B.V.
AN - OPUS4-60970
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Sunder, S.
A1 - Jauregui Rozo, Maria
A1 - Inasu, S.
A1 - Schartel, Bernhard
A1 - Ruckdäschel, H.
T1 - A systematic investigation of the transfer of polyphosphate/inorganic silicate flame retardants from epoxy resins to layered glass fiber-reinforced composites and their post-furnace flexural properties
N2 - The systematic transfer of solvent-free, additive flame retardant (FR) formulations from epoxy resins to glass fiber-reinforced epoxy composites (GFRECs) through prepregs is difficult. Additionally, obtaining data on their post-fire mechanics is often challenging. Utilizing melamine polyphosphate (MPP), ammonium polyphosphate (APP), and silane-coated ammonium polyphosphate (SiAPP) FRs with low-melting inorganic silicates (InSi) in an 8:2 proportion and 10% loading by weight in a diglycidyl ether of bisphenol A (DGEBA) resin, a systematic investigation of the processing properties, room-temperature mechanics, and temperature-based mechanics of the systems was performed. The resin was cured with a dicyandiamide hardener (DICY) and a urone accelerator. The results revealed no substantial impact of these FRs at the current loading on the resin's glass transition temperature or processability. However, the fire residues from cone calorimetry tests of the composites containing FRs were found to be only 15-20% of the thickness of the resins, implying a suppression of intumescence upon transfer. At room temperature, the decrease in the flexural modulus for the composites containing FRs was negligible. Exposure of the composites in a furnace at 400°C as a preliminary study before ignition tests was shown to cause significant flexural moduli reductions after 2.5 min of exposure and complete delamination after 3 min making further testing unviable. This study emphasizes the need for future research on recovering modes of action upon transfer of FR formulations from resins to composites. Based on the challenges outlined in this investigation, sample adaptation methods for post-fire analysis will be developed in a future study.
KW - DGEBA
KW - Prepregs
KW - Glass fiber-reinforced composites
KW - Post-fire testing
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-605239
DO - https://doi.org/10.1002/pc.28416
SN - 1548-0569
SN - 0272-8397
VL - 45
IS - 10
SP - 9389
EP - 9406
PB - Wiley
AN - OPUS4-60523
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Simon, Franz-Georg
A1 - Scholz, Philipp
T1 - Sequential Extraction of Incineration Bottom Ash: Conclusions Regarding Ecotoxicity
N2 - The classification of incineration bottom ash (IBA) as hazardous or non-hazardous according to ecotoxic hazard property HP14 is still under debate. In this context, only the compounds of Zn and Cu with the hazard statement code H410 are of relevance. With an approach based on the grouping of substances, it was shown that such substances are either readily water-soluble or slightly and sparingly soluble. The concentrations of readily soluble Cu and Zn compounds in IBA are far below the cut-off value of 0.1%. Slightly and sparingly soluble Zn and Cu compounds could be quantified in the first fraction of a four-step sequential extraction procedure. With the results from the complete sequence, the dimensionless synthesis toxicity index (STI) was calculated and was in the range of 494 to 1218 for the four investigated IBA samples. It was concluded that IBA can usually be classified as non-hazardous.
KW - Incineration bottom ash
KW - Hazard properties
KW - Ecotoxicity
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-605262
DO - https://doi.org/10.3390/app14135541
SN - 2076-3417
VL - 14
IS - 13
SP - 1
EP - 12
PB - MDPI
CY - Basel
AN - OPUS4-60526
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Rockel, Daniel
A1 - Sanchez Olivares, G.
A1 - Schartel, Bernhard
T1 - Improving the Flame Retardancy of Aluminium Trihydroxide in Thermoplastic Starch Biocomposites Using Waste Fibers and Silicon-Based Synergists
N2 - The synergistic behavior of different silicon compounds is investigated in flame retardant biocomposites with aluminum trihydroxide (ATH) as the main flame retardant. The paper shows a new approach towards sustainable biocomposites through the implementation of thermoplastic starch (TPS), leather fibers from industrial waste streams, and non-hazardous flame retardants and synergists. In these multicomponent systems, the different components address different modes of action in the fire scenario. When ATH is partially substituted by glass frits or layered silicates, fire performance is enhanced without changing the total amount of filler in the polymer. In a biocomposite with 25 phr of fiber and 90 phr of ATH, substituting 5 phr of ATH for layered silicates increased the LOI from 31.5 vol % to 34.8 vol %, decreased the peak of heat release by 20%, and increased the UL 94 rating from V-1 to V-0.
KW - Biocomposites
KW - Sustainability
KW - Waste streams
KW - Flame retardancy
KW - Synergism
KW - Modes of action
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-605711
DO - https://doi.org/10.1021/acssusresmgt.4c00053
SN - 2837-1445
VL - 1
IS - 6
SP - 1131
EP - 1145
PB - ACS
AN - OPUS4-60571
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Scales, B. S.
A1 - Hasenrück, C.
A1 - Moldaenke, L.
A1 - Hassa, J.
A1 - Rückert-Reed, C.
A1 - Rummel, C.
A1 - Völkner, C.
A1 - Rynek, R.
A1 - Busche, T.
A1 - Kalinowski, J.
A1 - Jahnke, A.
A1 - Schmitt-Jansen, M.
A1 - Wendt-Potthoff, K.
A1 - Oberbeckmann, Sonja
T1 - Hunting for pigments in bacterial settlers of the Great Pacific Garbage Patch
N2 - The Great Pacific Garbage Patch, a significant collection of plastic introduced by human activities, provides an ideal environment to study bacterial lifestyles on plastic substrates. We proposed that bacteria colonizing the floating plastic debris would develop strategies to deal with the ultravioletexposed substrate, such as the production of antioxidant pigments. We observed a variety of pigmentation in 67 strains that were directly cultivated from plastic pieces sampled from the Garbage Patch. The genomic analysis of four representative strains, each distinct in taxonomy, revealed multiple pathways for carotenoid production. These pathways include those that produce
less common carotenoids and a cluster of photosynthetic genes. This
cluster appears to originate from a potentially new species of the Rhodobacteraceae family. This represents the first report of an aerobic anoxygenic photoheterotrophic bacterium from plastic biofilms. Spectral analysis showed that the bacteria actively produce carotenoids, such as betacarotene and beta-cryptoxanthin, and bacteriochlorophyll a. Furthermore, we discovered that the genetic ability to synthesize carotenoids is more common in plastic biofilms than in the surrounding water communities. Our findings suggest that plastic biofilms could be an overlooked source of bacteria-produced carotenoids, including rare forms. It also suggests that photoreactive molecules might play a crucial role in bacterial biofilm communities in surface water.
KW - Microplastics
KW - Biofilm
KW - Pigment
KW - Microorganisms
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-605725
DO - https://doi.org/10.1111/1462-2920.16639
SN - 1462-2912
VL - 26
IS - 6
SP - e16639
PB - John Wiley & Sons Ltd.
AN - OPUS4-60572
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Baláž, Matej
A1 - Birinci, Mustafa
A1 - Şentürk, Kader
A1 - Achimovičová, Marcela
A1 - Baláž, Peter
A1 - Tampubolon, Imelda Octa
A1 - Stolar, Tomislav
A1 - Bienert, Ralf
A1 - Emmerling, Franziska
A1 - Erdemoğlu, Sema
A1 - Sis, Hikmet
A1 - Erdemoğlu, Murat
T1 - Utilizing Taguchi method and in situ X-ray powder diffraction monitoring to determine the influence of mechanical activation conditions on the physico-chemical properties and Al leachability of K-feldspar
N2 - K-feldspar represents an important natural resource of potassium and aluminum. Within the framework of this study, the K-feldspar was mechanically activated in a planetary ball mill under different conditions planned according to 43 Taguchi orthogonal array experimental design. As outputs, specific surface area (SBET), median particle size (d50), amorphization degree of mineral phases , and Al recovery were used. It was found that the initial d50 value of 293 μm could be reduced to 6.7 μm and the SBET value of 4.7 m2/g could be increased up to 32.5 m2/g upon milling. Both microcline KAl3SiO8, and albite NaAl3SiO8 could be almost completely amorphized, whereas quartz SiO2 still maintained some crystallinity even under the most intensive conditions. Increasing SBET and decreasing the d50 values did not lead to a significant improvement in Al leach recovery, whereas a clear relationship between the amorphization of microcline and the recovered aluminum was found. Analysis of Variance (ANOVA) showed that increasing ball-to-powder ratio is the most beneficial for the improvement in Al recovery. In situ powder X-ray diffraction monitoring performed in an oscillation ball mill under synchrotron irradiation has shown very rapid amorphization of microcline phase at the beginning. However, amorphization of microcline was only partial after two hours of the treatment in this mill, apart from almost complete process in the planetary ball mill. In the end, regressions for the calculation of Al recovery by knowing the values of input parameters were calculated. In general, by just using mechanical activation without the subsequent roasting process that is commonly used to boost metal recoveries, it was possible to quantitatively recover aluminum from K-feldspar.
KW - Mechanochemistry
KW - Mechanical activation
KW - Design of experiments
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-611059
DO - https://doi.org/10.1016/j.jmrt.2024.08.156
SN - 2238-7854
VL - 32
SP - 3886
EP - 3895
PB - Elsevier B.V.
AN - OPUS4-61105
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Bacurau, V. P.
A1 - Moreira, P. A. F. P.
A1 - Bertoli, G.
A1 - Andreoli, A. F.
A1 - Mazzer, E.
A1 - de Assis, F. F.
A1 - Gargarella, P.
A1 - Koga, G.
A1 - Stumpf, G. C.
A1 - Figueroa, S. J. A.
A1 - Widom, M.
A1 - Kaufman, M.
A1 - Fantin, Andrea
A1 - Cao, Y.
A1 - Freitas, R.
A1 - Miracle, D.
A1 - Coury, F. G.
T1 - Comprehensive analysis of ordering in CoCrNi and CrNi2 alloys
N2 - Chemical Short-Range Order (CSRO) has attracted recent attention from many researchers, creating intense debates about its impact on material properties.
The challenges lie in confirming and quantifying CSRO, as its detection proves exceptionally demanding, contributing to conflicting data in the literature regarding its true effects on mechanical properties. Our work uses highprecision calorimetric data to unambiguously prove the existence and, coupled with atomistic simulations, quantify the type of CSRO. This methodology allows us to propose a mechanism for its formation and destruction based on the heat evolution during thermal analysis and facilitates a precise identification of local ordering in CoCrNi alloys. Samples of CoCrNi (Co33Cr33Ni33) and CrNi2 (Cr33Ni66) alloys are fabricated in varying ordered states, extensively characterized via synchrotron X-ray diffraction, X-ray absorption spectroscopy, and transmission electron microscopy. Samples with considerably different ordered states are submitted to tensile tests with in-situ synchrotron X-ray diffraction. We demonstrate, despite inducing varied CSRO levels in CoCrNi, no significant alterations in overall mechanical behavior emerge.
However, the CrNi2 alloy, which undergoes long-range ordering, experiences significant shifts in yield strength, ultimate tensile stress and ductility.
KW - Mechanical properties
KW - Short-range ordering
KW - Calorimetry
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-611075
DO - https://doi.org/10.1038/s41467-024-52018-w
VL - 15
IS - 1
SP - 1
EP - 11
PB - Springer Science and Business Media LLC
AN - OPUS4-61107
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Chronakis, Michail Ioannis
A1 - Meermann, Björn
A1 - von der Au, Marcus
T1 - The evolution of data treatment tools in single-particle and single-cell ICP-MS analytics
N2 - Single-particle inductively coupled plasma-mass spectrometry (sp-ICP-MS) is one of the most powerful tools in the thriving field of nanomaterial analysis. Along the same lines, single-cell ICP-MS (sc-ICP-MS) has become an invaluable tool in the study of the variances of cell populations down to a per-cell basis. Their importance and application fields have been listed numerous times, across various reports and reviews. However, not enough attention has been paid to the immense and ongoing development of the tools that are currently available to the analytical community for the acquisition, and more importantly, the treatment of single-particle and single-cell-related data. Due to the ever-increasing demands of modern research, the efficient and dependable treatment of the data has become more important than ever. In addition, the field of single-particle and single-cell analysis suffers due to a large number of approaches for the generated data—with varying levels of specificity and applicability. As a result, finding the appropriate tool or approach, or even comparing results, can be challenging. This article will attempt to bridge these gaps, by covering the evolution and current state of the tools at the disposal of sp-ICP-MS users.
Graphical Abstract
KW - Trend Article
KW - spICP-MS
KW - Data Tools
KW - scICP-MS
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-610539
DO - https://doi.org/10.1007/s00216-024-05513-4
SP - 1
EP - 7
PB - Springer Science and Business Media LLC
AN - OPUS4-61053
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Sunder, S.
A1 - Jauregui Rozo, Maria
A1 - Inasu, S.
A1 - Schartel, Bernhard
A1 - Ruckdäschel, H.
T1 - Investigating the changing dynamics of processing, temperature-based mechanics, and flame retardancy in the transfer of ammonium polyphosphate/inorganic silicate flame retardants from epoxy resins to glass fiber composites
N2 - Although numerous investigations study the improvement of flame retardancy of epoxy resins using additives, maintaining the flame retardant (FRs) modes of action present in the resins upon transfer to composites is challenging. In this study, ammonium polyphosphate (APP) and inorganic silicate (InSi) are loaded at 10%, 30%, and 50% by weight, in a diglycidyl ether of bisphenol A (DGEBA) resin cured with dicyandiamide and transferred to bidirectional (BD) glass fiber (GF) composites. Although a 50% loading of the FRs impacts the curing kinetics of the resin system, the effect on the glass transition temperature of the resin system remains negligible compared to reactive FRs in the state of the art integrated into the resin's chemical structure. Increasing the FR content improved the heat release characteristics in both the resins and composites. However, the charring mode of action is completely suppressed in the formulation with 10% APP + InSi. A 30% concentration of the FRs restored the charring action in the composite and the GFs provide increased protective layer action upon transfer to the composites. This study highlights the importance of accounting for the changing dynamics related to processing and flame retardancy upon transferring FRs from resins to composites.
KW - Composites
KW - Flame retardance
KW - Resins
KW - Synthesis and processing techniques
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-610484
DO - https://doi.org/10.1002/app.55988
SN - 1097-4628
VL - 141
IS - 39
SP - 1
EP - 18
PB - Wiley
CY - New York, NY
AN - OPUS4-61048
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Golian, M. J.
A1 - Friedman, D. A.
A1 - Harrison, M.
A1 - McMahon, Dino Peter
A1 - Buellesbach, J.
T1 - Chemical and transcriptomic diversity do not correlate with ascending levels of social complexity in the insect order Blattodea
N2 - AbstractEusocial insects, such as ants and termites, are characterized by high levels of coordinated social organization. This is contrasted by solitary insects that display more limited forms of collective behavior. It has been hypothesized that this gradient in sociobehavioral sophistication is positively correlated with chemical profile complexity, due to a potentially increased demand for diversity in chemical communication mechanisms in insects with higher levels of social complexity. However, this claim has rarely been assessed empirically. Here, we compare different levels of chemical and transcriptomic complexity in selected species of the order Blattodea that represent different levels of social organization, from solitary to eusocial. We primarily focus on cuticular hydrocarbon (CHC) complexity, since it has repeatedly been demonstrated that CHCs are key signaling molecules conveying a wide variety of chemical information in solitary as well as eusocial insects. We assessed CHC complexity and divergence between our studied taxa of different social complexity levels as well as the differentiation of their respective repertoires of CHC biosynthesis gene transcripts. Surprisingly, we did not find any consistent pattern of chemical complexity correlating with social complexity, nor did the overall chemical divergence or transcriptomic repertoire of CHC biosynthesis genes reflect on the levels of social organization. Our results challenge the assumption that increasing social complexity is generally reflected in more complex chemical profiles and point toward the need for a more cautious and differentiated view on correlating complexity on a chemical, genetic, and social level.
KW - Chemical ecology
KW - Ecological genetics
KW - Entomology
KW - Evolutionary ecology
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-608260
DO - https://doi.org/10.1002/ece3.70063
SN - 2045-7758
VL - 14
IS - 8
SP - 1
EP - 13
PB - Wiley
AN - OPUS4-60826
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Hellemans, S.
A1 - Rocha, M. M.
A1 - Wang, M.
A1 - Romero Arias, J.
A1 - Aanen, D. K.
A1 - Bagnères, A.-G.
A1 - Buček, A.
A1 - Carrijo, T. F.
A1 - Chouvenc, T.
A1 - Cuezzo, C.
A1 - Constantini, J. P.
A1 - Constantino, R.
A1 - Dedeine, F.
A1 - Deligne, J.
A1 - Eggleton, P.
A1 - Evans, T. A.
A1 - Hanus, R.
A1 - Harrison, Mark C.
A1 - Harry, M.
A1 - Josens, G.
A1 - Jouault, C.
A1 - Kalleshwaraswamy, C. M.
A1 - Kaymak, E.
A1 - Korb, J.
A1 - Lee, C.-Y.
A1 - Legendre, F.
A1 - Li, H.-F.
A1 - Lo, N.
A1 - Lu, T.
A1 - Matsuura, K.
A1 - Maekawa, K.
A1 - McMahon, Dino Peter
A1 - Mizumoto, N.
A1 - Oliveira, D. E.
A1 - Poulsen, M.
A1 - Sillam-Dussès, D.
A1 - Su, N.-Y.
A1 - Tokuda, G.
A1 - Vargo, E. L.
A1 - Ware, J. L.
A1 - Šobotník, J.
A1 - Scheffrahn, R. H.
A1 - Cancello, E.
A1 - Roisin, Y.
A1 - Engel, M. S.
A1 - Bourguignon, T.
T1 - Genomic data provide insights into the classification of extant termites
N2 - The higher classification of termites requires substantial revision as the Neoisoptera, the most diverse termite lineage, comprise many paraphyletic and polyphyletic higher taxa. Here, we produce an updated termite classification using genomic-scale analyses. We reconstruct phylogenies under diverse substitution models with ultraconserved elements analyzed as concatenated matrices or within the multi-species coalescence framework. Our classification is further supported by analyses controlling for rogue loci and taxa, and topological tests. We show that the Neoisoptera are composed of seven family-level monophyletic lineages, including the Heterotermitidae Froggatt, Psammotermitidae Holmgren, and Termitogetonidae Holmgren, raised from subfamilial rank. The species-rich Termitidae are composed of 18 subfamily-level monophyletic lineages, including the new subfamilies Crepititermitinae, Cylindrotermitinae, Forficulitermitinae, Neocapritermitinae, Protohamitermitinae, and Promirotermitinae; and the revived Amitermitinae Kemner, Microcerotermitinae Holmgren, and Mirocapritermitinae Kemner. Building an updated taxonomic classification on the foundation of unambiguously supported monophyletic lineages makes it highly resilient to potential destabilization caused by the future availability of novel phylogenetic markers and methods. The taxonomic stability is further guaranteed by the modularity of the new termite classification, designed to accommodate as-yet undescribed species with uncertain affinities to the herein delimited monophyletic lineages in the form of new families or subfamilies.
KW - Termite
KW - Taxonomy
KW - Evolution
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-608276
DO - https://doi.org/10.1038/s41467-024-51028-y
VL - 15
IS - 1
SP - 1
EP - 17
PB - Springer Science and Business Media LLC
AN - OPUS4-60827
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - CONF
A1 - El Moutaouakil, H.
A1 - Fuchs, C.
A1 - Savli, E.
A1 - Heimann, Jan
A1 - Prager, Jens
A1 - Moll, J.
A1 - Tschöke, K.
A1 - Márquez Reyes, O.
A1 - Schackmann, O.
A1 - Memmolo, V.
A1 - Schneider, T.
T1 - Acquiring a Machine Learning Data Set for Structural Health Monitoring of Hydrogen Pressure Vessels at Operating Conditions using Guided Ultrasonic Waves
N2 - Hydrogen is an energy source of increasing importance. As hydrogen is very reactive to air and needs to be stored under high pressure, it is crucial to provide safe transportation and storage. Therefore, structural health monitoring, based on guided ultrasonic waves and machine learning methods, is used for Composite Overwrapped Pressure Vessels (COPVs) containing hydrogen. To acquire data that allows robust detection of COPV defects, there are two main process parameters to consider. These are the pressurization of the vessel and the temperature conditions at the vessel. This paper will focus on the derivation of a design of experiment (DoE) from the needs of various validation scenarios (e.g. concerning pressure, temperature or excitation frequency). Practical limitations must be considered as well. We designed experiments with multiple reversible damages at different positions. A network of 25 transducers, structured as five rings with five sensors in one line, is installed on a vessel. Guided ultrasonic waves are used via the pitch-catch procedure, which means that the transducers act pairwise as transmitter and receiver in order to measure all transmitterreceiver combinations. This leads to 600 signal paths, recorded by a Verasonics Vantage 64 LF data acquisition system. Finally, the influences of temperature and pressure within the acquired data set are going to be visualized.
T2 - 11th European Workshop on Structural Health Monitoring
CY - Potsdam, Germany
DA - 10.06.2024
KW - Composite Overwrapped Pressure Vessel
KW - Hydrogen
KW - Guided Ultrasonic Waves
KW - Data Acquisition
KW - Pressurization
KW - Machine Learning
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-607472
DO - https://doi.org/10.58286/29754
SN - 1435-4934
SP - 1
EP - 8
AN - OPUS4-60747
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Kadri, Lena
A1 - Casali, Lucia
A1 - Emmerling, Franziska
A1 - Tajber, Lidia
T1 - Mechanochemical comparison of ball milling processes for levofloxacin amorphous polymeric systems
N2 - This study aimed to investigate the amorphization capabilities of levofloxacin hemihydrate (LVXh), a fluoroquinolone drug, using a polymer excipient, Eudragit® L100 (EL100). Ball milling (BMing) was chosen as the manufacturing process and multiple mill types were utilized for comparison purposes. The product outcomes of each mill were analyzed in detail. The solid-state of the samples produced was comprehensively characterized by Powder X-ray Diffraction (PXRD), In-situ PXRD, Differential Scanning Calorimetry (DSC), Solid-State Fourier Transform Infrared Spectroscopy (FT-IR), and Dynamic Vapor Sorption (DVS). The crystallographic planes of LVXh were investigated by in-situ PXRD to disclose the presence or absence of weak crystallographic plane(s). The mechanism of LVXh:EL100 system formation was discovered as a two-step process, first involving amorphization of LVXh followed by an interaction with EL100, rather than as an instantaneous process. DVS studies of LVXh:EL100 samples showed different stability properties depending on the mill used and % LVXh present. Overall, a more sustainable approach for achieving full amorphization of the fluoroquinolone drug, LVXh, was accomplished, and advancements to the fast-growing world of pharmaceutical mechano- and tribo-chemistry were made.
KW - Levofloxacin
KW - Eudragit® L100
KW - Mechanochemistry
KW - Phase transformation
KW - In situ monitoring
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-611129
DO - https://doi.org/10.1016/j.ijpharm.2024.124652
SN - 0378-5173
VL - 665
SP - 1
EP - 16
PB - Elsevier B.V.
AN - OPUS4-61112
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Schneider, Beate
A1 - Pfeiffer, Friedhelm
A1 - Remus, Daniela
A1 - Dyall-Smith, Mike
A1 - Kunte, Hans-Jörg
ED - Klepac-Ceraj, Vanja
T1 - Genome sequence of Pseudomonas silesiensis strain G3, a member of a bacterial consortium capable of polyethylene degradation
N2 - A consortium of landfill bacteria including strain G3 can break down polyethylene, a long-lasting plastic that accumulates in the environment. The complete genome sequence of strain G3 was determined by PacBio and Nanopore sequencing and consists of three circular replicons. Genome-based classification assigned strain G3 to the species Pseudomonas silesiensis.
KW - PE degradation
KW - Polyethylene
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-611618
DO - https://doi.org/10.1128/mra.00138-24
SN - 2576-098X
VL - 13
IS - 11
SP - 1
EP - 3
PB - American Society for Microbiology
AN - OPUS4-61161
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Breuninger, Esther S.
A1 - Tolu, Julie
A1 - Aemisegger, Franziska
A1 - Thurnherr, Iris
A1 - Bouchet, Sylvain
A1 - Mestrot, Adrien
A1 - Ossola, Rachele
A1 - McNeill, Kristopher
A1 - Tukhmetova, Dariya
A1 - Vogl, Jochen
A1 - Meermann, Björn
A1 - Sonke, Jeroen E.
A1 - Winkel, Lenny H. E.
T1 - Marine and terrestrial contributions to atmospheric deposition fluxes of methylated arsenic species
N2 - Arsenic, a toxic element from both anthropogenic and natural sources, reaches surface environments through atmospheric cycling and dry and wet deposition. Biomethylation volatilizes arsenic into the atmosphere and deposition cycles it back to the surface, affecting soil-plant systems. Chemical speciation of deposited arsenic is important for understanding further processing in soils and bioavailability. However, the range of atmospheric transport and source signature of arsenic species remain understudied. Here we report significant levels ofmethylated arsenic in precipitation, cloudwater and aerosols collected under free tropospheric conditions at Pic du Midi Observatory (France) indicating long-range transport, which is crucial for atmospheric budgets. Through chemical analyses andmoisture source diagnostics, we identify terrestrial and marine sources for distinct arsenic species. Estimated atmospheric deposition fluxes of methylated arsenic are similar to reported methylation rates in soils, highlighting atmospheric deposition as a significant, overlooked source of potentially bioavailable methylated arsenic
species impacting plant uptake in soils.
KW - Arsenic
KW - Speciation
KW - Fluxes
KW - Marine
KW - Terrestrial
KW - Sulfur isotopes
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-615551
DO - https://doi.org/10.1038/s41467-024-53974-z
SN - 2041-1723
VL - 15
IS - 1
SP - 1
EP - 13
PB - Springer Science and Business Media LLC
AN - OPUS4-61555
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Yagdjian, H.
A1 - Lecompagnon, Julien
A1 - Hirsch, Philipp Daniel
A1 - Ziegler, Mathias
A1 - Gurka, M.
T1 - Application of the thermal shock response spectrum (TSRS) methodology to various forms of heat sources by pulse thermography and comparison by using a rotating line scan contour search algorithm
N2 - In this paper, we propose a novel contour search algorithm (CSA) for image processing. Its efficacy is evaluated through a comparative analysis with established techniques such as Canny Edge and Snakes: Active contour models, utilizing infrared thermography (IRT) images. Based on the new CSA, we investigate the influence of different pulse shapes on the IRT post-processing methodology, particularly focusing on the thermal shock response spectrum (TSRS), using two different heat sources: xenon flash lamps and a laser. Moreover, this allows for a more precise quantitative comparison of the TSRS with existing IRT post-processing techniques, including pulse phase thermography and thermal signal reconstruction, concerning the detection of defects in composite materials, particularly in carbon fiber-reinforced polymer. A quantitative comparison was performed using the Tanimoto criterion and signal-to-noise ratio. A more detailed analysis is conducted to identify inherent limitations and potential benefits of the new TSRS methodology. We further investigate and experimentally confirm our previous finding on the qualitative correlation between the one-dimensional thermal N-layer model and test data from the TSRS optimization process for defect determination. This correlation can eliminate the time-consuming optimization step, making TSRS a more attractive alternative to common IRT methods and enhancing the quantitative description of defects.
KW - Thermography
KW - Non-destructive testing
KW - NDT
KW - Defect identification
KW - Laser
KW - Contour search
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-615056
DO - https://doi.org/10.1063/5.0232015
SN - 1089-7550
VL - 136
IS - 175101
SP - 1
EP - 20
PB - AIP Publishing
AN - OPUS4-61505
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Abed, Jehad
A1 - Bai, Yanh
A1 - Persaud, Daniel
A1 - Kim, Jiheon
A1 - Witt, Julia
A1 - Hattrick.Simpers, Jason
A1 - Sargent, Edward
T1 - AMPERE: automated modular platform for expedited and reproducible electrochemical testing
N2 - Rapid and reliable electrochemical screening is critical to accelerate the development of catalysts for sustainable energy generation and storage. This paper introduces an automated and modular platform for expedited and reproducible electrochemical testing (AMPERE), designed to enhance the efficiency and reliability of multivariate optimization. The platform integrates a liquid-handling robot with custommade modular array reactors, offering sample preparation and electrochemical testing in the same platform. Additionally, we use offline inductively coupled plasma optical emission spectroscopy (ICPOES) to measure metal concentrations in the electrolyte after the reaction, which serves as a proxy for assessing the electrochemical stability. We use the platform to conduct 168 experiments continuously in less than 40 hours to examine the influence of catalyst ink formulation on the performance of Ir, Ru, IrO2, and RuO2 for the oxygen evolution reaction (OER) in acid. We specifically investigate the role of solvent type and concentration, catalyst concentration, and binder content on the performance. We find that Ru/RuO2 catalysts show improvements in activity that are not directly linked to improvements in the electrochemical surface area or inversely correlated to Ru dissolution. This suggests a complex interplay between the catalytic performance of the drop-casted catalyst film and ink formulation. AMPERE simplifies catalyst preparation and testing at large scale, making it faster, more reliable, and accessible for
widespread use.
KW - Electrochemical screening
KW - Automated platform
KW - Catalysis
KW - Energy generation and storage
KW - Oxygen evolution reaction (OER)
KW - MAPz@BAM
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-614724
DO - https://doi.org/10.1039/d4dd00203b
SP - 1
EP - 10
PB - Royal Society of Chemistry (RSC)
AN - OPUS4-61472
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Jauregui Rozo, Maria
A1 - Sunder, S:
A1 - Ruckdäschel, H.
A1 - Schartel, Bernhard
T1 - Char, gas, and action: Transfer of the flame-retardant modes of action in epoxy resins and their fiber-reinforced composites
N2 - Flame retardants are often developed for epoxy resins and then transferred into their fiber-reinforced composites with uncertain results. Understanding this transfer in detail represents a critical scientific challenge. This study systematically compares epoxy resins with their glass-fiber reinforced composites, focusing on bisphenol A diglycidyl ether with the hardener dicyandiamide, the flame retardants melamine polyphosphate, ammonium polyphosphate, and silane ammonium polyphosphate, along with inorganic silicate. The research investigates changes in pyrolysis (thermogravimetry), flammability (UL 94, limiting oxygen index), and fire behavior (cone calorimeter) while also examining the flame-retardant modes of action and overall fire performance. The findings reveal that alterations in the amount of fuel, thermal properties, melt flow, and protective layer significantly impact ignition, flammability, and fire load, with a critical reduction in carbonaceous char within the composites preventing intumescence. This study quantifies the effects and provides a fundamental scientific understanding of the complex transfer process of flame retardants from resins to composites, offering essential insights that are of major importance for developing more effective flame-retardant materials.
KW - Glas fibers
KW - Epoxy resins
KW - Fire behavior
KW - Flammability
KW - Composites
KW - Flame retardants
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-615371
DO - https://doi.org/10.1016/j.polymertesting.2024.108610
SN - 0142-9418
SN - 1873-2348
VL - 140
PB - Elsevier Ltd.
AN - OPUS4-61537
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Chaudhuri, Somsubhro
A1 - Stamm, Michael
A1 - Lapšanská, Ivana
A1 - Lançon, Thibault
A1 - Osterbrink, Lars
A1 - Driebe, Thomas
A1 - Hein, Daniel
A1 - Harendt, René
T1 - Infrared Thermography of Turbulence Patterns of Operational Wind Turbine Rotor Blades Supported With High‐Resolution Photography: KI‐VISIR Dataset
N2 - With increasing wind energy capacity and installation of wind turbines, new inspection techniques are being explored to examine wind turbine rotor blades, especially during operation. A common result of surface damage phenomena (such as leading edge erosion) is the premature transition of laminar to turbulent flow on the surface of rotor blades. In the KI-VISIR (Künstliche Intelligenz Visuell und Infrarot Thermografie—Artificial Intelligence-Visual and Infrared Thermography) project, infrared thermography is used as an inspection tool to capture so-called thermal turbulence patterns (TTPs) that result from such surface contamination or damage. To complement the thermographic inspections, high-resolution photography is performed to visualise, in detail, the sites where these turbulence patterns initiate. A convolutional neural network (CNN) was developed and used to detect and localise turbulence patterns. A unique dataset combining the thermograms and visual images of operational wind turbine rotor blades has been provided, along with the simplified annotations for the turbulence patterns. Additional tools are available to allow users to use the data requiring only basic Python programming skills.
KW - Thermography
KW - Thermografie
KW - Wind energy
KW - Leading edge erosion
KW - KI
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-615772
DO - https://doi.org/10.1002/we.2958
IS - e2958
SP - 1
EP - 9
PB - Wiley
AN - OPUS4-61577
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Vo, P. H.N.
A1 - Vogel, Christian
A1 - Nguyen, H. T.M.
A1 - Hamilton, B. R.
A1 - Thai, P. K.
A1 - Roesch, Philipp
A1 - Simon, Franz-Georg
A1 - Mueller, J. F.
T1 - µ-X-ray fluorescence (XRF) and fluorine K-edge µ-X-ray absorption near-edge structure (XANES) spectroscopy for detection of PFAS distribution in the impacted concrete
N2 - An improved understanding of the distribution of per- and polyfluoroalkyl substances (PFAS) in PFAS-impacted concrete is important for risk management and decontamination of PFAS. This study incorporates µ-X-ray fluorescence (µ-XRF) and fluorine K-edge µ-X-ray absorption near-edge structure (µ-XANES) spectroscopy to gain non-destructive insights into PFAS distribution in the impacted concrete. The μ-XRF and μ-XANES spectroscopy provided additional details on the detection of PFAS, which were not detected by the desorption electrospray ionization (DESI) imaging method conducted previously. The shorter chain PFAS were found on the top part of the concrete core (0.5 cm), and longer chain PFAS were mostly at the bottom part of the concrete core (5 cm). The inorganic fluorine fraction was also detected, and it likely hampered the detection of organic fluorine such as PFAS in the concrete. Thus, this non-destructive technique is an complementary approach to detect PFAS in contaminated concrete.
KW - Beton
KW - Per- and Polyfluoroalkyl substances (PFAS)
KW - XANES spectroscopy
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-616711
DO - https://doi.org/10.1016/j.hazl.2024.100134
SN - 2666-9110
VL - 5
SP - 1
EP - 5
PB - Elsevier B.V.
AN - OPUS4-61671
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Zweigle, J.
A1 - Schmidt, A.
A1 - Bugsel, B.
A1 - Vogel, Christian
A1 - Simon, Fabian
A1 - Zwiener, C.
T1 - Perfluoroalkyl acid precursor or weakly fluorinated organic compound? A proof of concept for oxidative fractionation of PFAS and organofluorines
N2 - Organofluorine mass balance approaches are increasingly applied to investigate the occurrence of per- and polyfluoroalkyl substances (PFAS) and other organofluorines in environmental samples more comprehensively. Usually, complex samples prevent the identification and quantification of every fluorine-containing molecule. Consequently, large unidentified fractions between fluorine sum parameters such as extractable organic fluorine (EOF) and the sum of quantified analytes are frequently reported. We propose using oxidative conversion to separate (unidentified) weakly fluorinated compounds (e.g., pesticides, pharmaceuticals) from PFAA-precursors (perfluoroalkyl chain lengths ≥ C6). We show with three organofluorine model substances (flufenamic acid, diflufenican, pantoprazole) that CF3-groups or aromatic fluorine can be quantitatively converted to inorganic fluoride and trifluoroacetic acid (TFA) by applying PhotoTOP oxidation (UV/TiO2). The principle of fluorine separation in mixtures is demonstrated by the oxidation of the three weakly fluorinated compounds together with the PFAA-precursor 6:2/6:2 fluorotelomer mercaptoalkyl phosphate diester (FTMAP). After oxidation, the products F− and TFA were separated from PFCAs ( C4) by SPE, and the fractions were analyzed individually. Closed mass balances both with and without the addition of organic matrix were achieved. Eventually, the fluorine balance was verified by total fluorine measurements with combustion ion chromatography (CIC). The proposed methods should be considered a proof of concept to potentially explain unidentified fractions of the EOF, especially if compounds with low fluorine content such as pesticides, pharmaceuticals, and their transformation products contribute largely to the EOF. Future studies are needed to show the applicability to the complexity of environmental samples.
Graphical Abstract
KW - Combustion Ion Chromatography
KW - Per- and Polyfluoroalkyl substances (PFAS)
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-613429
DO - https://doi.org/10.1007/s00216-024-05590-5
SP - 1
EP - 10
PB - Springer Science and Business Media LLC
AN - OPUS4-61342
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Yagdjian, H.
A1 - Lecompagnon, Julien
A1 - Hirsch, Philipp Daniel
A1 - Gurka, M.
T1 - Optimization of thermal shock response spectrum as infrared thermography post-processing methodology using Latin hypercube sampling and analytical thermal N-layer model
N2 - In this work, we continue to develop and investigate the Thermal Shock Response Spectrum (TSRS) method as an alternative data processing method for infrared thermography (IRT). We focus on improving the current TSRS algorithm and present an optimization methodology for finding the optimal thermal Q-factor and characteristic frequency pair, which is based on the widely applied random sampling method. We show the qualitative relationship between the determined optimal characteristic frequency and the corresponding maximum difference in diffusion length between reference and defective models, as calculated by selecting a specific one-dimensional thermal N-layer model. The investigations were performed on an inhomogeneous plate made of carbon fiber reinforced polymer (CFRP) with artificial square defects at different depths. Furthermore, two different heat sources were used: a xenon flash lamp and a laser. These sources are not only distinct by their underlying physics but also generate inherently different pulse shapes. To quantitatively estimate the contrast between defect and non-defect areas, and to compare these results with commonly used infrared thermography (IRT) data postprocessing methods such as Pulse Phase Thermography (PPT) and Thermographic Signal Reconstruction (TSR), the Tanimoto criterion (TC) and signal-to-noise ratio (SNR) were used.
KW - infrared thermography
KW - Composite materials
KW - TSRS optimization
KW - Defect identification
KW - Heat source shape
KW - N-layers model
KW - Latin Hypercube Sampling
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-614283
DO - https://doi.org/10.1016/j.infrared.2024.105582
SN - 1350-4495
VL - 143
SP - 1
EP - 15
PB - Elsevier B.V.
AN - OPUS4-61428
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Bianchi, M.
A1 - Cascavilla, A.
A1 - Clavell Diaz, J.
A1 - Ladu, Luana
A1 - Palacino Blazquez, Barbara
A1 - Menger, Pierre
A1 - Staffieri, Eleonora
A1 - Yilan, Gülsah Yilan
T1 - Circular bioeconomy: A review of empirical practices across implementation scales
N2 - The European Commission has endorsed the transition to a circular bioeconomy as a crucial initiative to achieve a sustainable and climate-neutral European Union. However, this transition is inherently complex, as it involves environmental and social risks, physical limitations, and trade-offs between different dimensions of sustainability. In this context, effective monitoring and modelling of the bioeconomy are essential tools to inform decision-making at various implementation scales. This article reviews empirical research on the monitoring and modelling of the bioeconomy and their implications for decision-making across three main implementation scales: macro (national-global level); meso (regional-city level); and micro (single product, company level). The contribution of this research is twofold: First, it explores existing gaps in the field through the lens of policy implementation levels. Research gaps include the uneven distribution of indicators among sustainability pillars, the lack of standardised monitoring frameworks at the meso and micro levels, and attribution issues in bioeconomy modelling. Second, the article outlines a comprehensive research agenda, indicating specific research lines and their relevance to different implementation scales. Key research avenues, significant at all implementation scales, include enhancing the life cycle perspective, visualising trade-offs and synergies between Sustainable Development Goals, monetising externalities, and further delving into social aspects.
KW - Bioeconomy
KW - Circular Economy
KW - Sustainable Transition
KW - Bioeconomy Monitoring Framework
KW - Bioeconomy Indicators
KW - Life cycle management
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-612357
DO - https://doi.org/10.1016/j.jclepro.2024.143816
VL - 477
SP - 1
EP - 16
PB - Elsevier
AN - OPUS4-61235
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - D'Agostino, Giancarlo
A1 - Oelze, Marcus
A1 - Vogl, Jochen
A1 - Ghestem, Jean-Philippe
A1 - Lafaurie, Nicolas
A1 - Klein, Ole
A1 - Pröfrock, Daniel
A1 - Di Luzio, Marco
A1 - Bergamaschi, Luigi
A1 - Jaćimović, Radojko
A1 - Oster, Caroline
A1 - Irrgeher, Johanna
A1 - Lancaster, Shaun T.
A1 - Walch, Anna
A1 - Röthke, Anita
A1 - Michaliszyn, Lena
A1 - Pramann, Axel
A1 - Rienitz, Olaf
A1 - Sara-Aho, Timo
A1 - Cankur, Oktay
A1 - Kutan, Derya
A1 - Noireaux, Johanna
T1 - Development and application of reference and routine analytical methods providing SI-traceable results for the determination of technology-critical elements in PCB from WEEE
N2 - The recovery and reprocessing of technology-critical elements (TCE) present in printed circuit boards (PCB) from electrical and electronic waste is essential both for recycling valuable materials subject to supply risk and for reducing the environmental impact. Although the quantitative knowledge of TCE amounts in endof- life PCB plays a key role, there are neither matrix certified reference materials nor harmonized analytical methods available to establish the traceability of the results to the International System of Units. To fill these gaps, we developed and applied five reference analytical methods based on ICP-MS standard addition calibrations and INAA k0- and relative calibrations suitable to certify reference materials. In addition, we developed and tested six analytical methods based on more commonly used ICP-MS external standard calibrations to provide industry with routine analysis methods. Twenty TCE (Ag, Au, Co, Cu, Dy, Ga, Gd, Ge, In, La, Li, Nd, Ni, Pd, Pr, Pt, Rh, Sm, Ta and Ti) were selected as target analytes and a batch of powdered PCB was used as measurement material. An overall mutual agreement was observed among data collected by reference methods at a few percent relative uncertainty levels. Moreover, all but one of the methods developed for routine analysis demonstrated their suitability in industrial applications by producing data within ± 20% of the values established with reference methods.
KW - Technology critical elements
KW - Electronic waste
KW - Printed circuit boards
KW - Traceability
KW - Uncertainty
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-612416
DO - https://doi.org/10.1039/d4ja00235k
SN - 1364-5544
VL - 39
IS - 11
SP - 2809
EP - 2823
PB - Royal Society of Chemistry (RSC)
AN - OPUS4-61241
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Lancaster, Shaun T.
A1 - Sahlin, Eskil
A1 - Oelze, Marcus
A1 - Ostermann, Markus
A1 - Vogl, Jochen
A1 - Laperche, Valérie
A1 - Touze, Solène
A1 - Ghestem, Jean-Philippe
A1 - Dalencourt, Claire
A1 - Gendre, Régine
A1 - Stammeier, Jessica
A1 - Klein, Ole
A1 - Pröfrock, Daniel
A1 - Košarac, Gala
A1 - Jotanovic, Aida
A1 - Bergamaschi, Luigi
A1 - Di Luzio, Marco
A1 - D’Agostino, Giancarlo
A1 - Jaćimović, Radojko
A1 - Eberhard, Melissa
A1 - Feiner, Laura
A1 - Trimmel, Simone
A1 - Rachetti, Alessandra
A1 - Sara-Aho, Timo
A1 - Roethke, Anita
A1 - Michaliszyn, Lena
A1 - Pramann, Axel
A1 - Rienitz, Olaf
A1 - Irrgeher, Johanna
T1 - Evaluation of X-ray fluorescence for analysing critical elements in three electronic waste matrices: A comprehensive comparison of analytical techniques
N2 - As the drive towards recycling electronic waste increases, demand for rapid and reliable analytical methodology to analyse the metal content of the waste is increasing, e.g. to assess the value of the waste and to decide the correct recycling routes. Here, we comprehensively assess the suitability of different x-ray fluorescence spectroscopy (XRF)-based techniques as rapid analytical tools for the determination of critical raw materials, such as Al, Ti, Mn, Fe, Co, Ni, Cu, Zn, Nb, Pd and Au, in three electronic waste matrices: printed circuit boards (PCB), light emitting diodes (LED), and lithium (Li)-ion batteries. As validated reference methods and materials to establish metrological traceability are lacking, several laboratories measured test samples of each matrix using XRF as well as other independent complementary techniques (instrumental neutron activation analysis (INAA), inductively coupled plasma mass spectrometry (ICP-MS) and ICP optical emission spectrometry (OES)) as an inter-laboratory comparison (ILC). Results highlighted key aspects of sample preparation, limits of detection, and spectral interferences that affect the reliability of XRF, while additionally highlighting that XRF can provide more reliable data for certain elements compared to digestion-based approaches followed by ICP-MS analysis (e.g. group 4 and 5 metals). A clear distinction was observed in data processing methodologies for wavelength
dispersive XRF, highlighting that considering the metals present as elements (rather than oxides) induces overestimations of the mass fractions when compared to other techniques. Eventually, the effect of sample particle size was studied and indicated that smaller particle size (<200 μm) is essential for reliable determinations.
KW - XRF
KW - WEEE
KW - PCB
KW - Battery
KW - LED
KW - Recycling
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-614060
DO - https://doi.org/10.1016/j.wasman.2024.10.015
VL - 190
SP - 496
EP - 505
PB - Elsevier B.V.
AN - OPUS4-61406
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Lengas, Nikolaos
A1 - Müller, Karsten
A1 - Schlick‐Hasper, Eva
A1 - Neitsch, Marcel
A1 - Johann, Sergej
A1 - Zehn, Manfred W.
T1 - Drop Test Simulation of Packaging for Dangerous Goods: An Investigation of Appropriate Drop Height Adjustment in Case of Deviating Packaging Gross Mass
N2 - In the approval process of dangerous goods packagings, drop tests onto a flat, essentially unyielding surface are used to assess resistance against mechanical damage. International adopted regulations like ADR and RID define filling good dependent drop heights and filling degrees whilst the user needs to define the maximum gross mass to be tested and approved. Maximum packaging gross mass is defined conservatively and not reached in practice. To meet the defined gross mass in testing, using additives is permitted. However, in some cases, additives are not desirable due to packaging design or filling substance properties. This leads to deviations from the initial gross mass definition. Hence, a certain drop height adjustment is necessary to achieve the required impact loading. Laboratories frequently adjust drop height assuming a perfectly elastic collision that is inaccurate. Appropriate adjustment is not trivial due to energy conversion processes, for example, plastic deformation. In this work, a test stand
KW - Corrugated fibreboard box
KW - Dangerous goods packagings
KW - Drop test
KW - Impact target
KW - Mechanical response
KW - Structural dynamics
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-614138
DO - https://doi.org/10.1002/pts.2858
SP - 1
EP - 18
PB - Wiley
AN - OPUS4-61413
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Cios, G.
A1 - Winkelmann, A.
A1 - Nolze, Gert
A1 - Tokarski, T.
A1 - Jany, B. R.
A1 - Bala, P.
T1 - EBSD and TKD analyses using inverted contrast Kikuchi diffraction patterns and alternative measurement geometries
N2 - Electron backscatter diffraction (EBSD) patterns can exhibit Kikuchi bands with inverted contrast due to anomalous absorption. This can be observed, for example, on samples with nanoscale topography, in case of a low tilt backscattering geometry, or for transmission Kikuchi diffraction (TKD) on thicker samples. Three examples are discussed where contrast-inverted physics-based simulated master patterns have been applied to find the correct crystal orientation. As first EBSD example, self-assembled gold nanostructures made of Au fcc and Au hcp phases on single-crystal germanium were investigated. Gold covered about 12% of the mapped area, with only two thirds being successfully interpreted using standard Hough-based indexing. The remaining third was solved by brute force indexing using a contrast-inverted master pattern. The second EBSD example deals with maps collected at a non-tilted surface instead of the commonly used 70◦ tilted one. As TKD example, a jet-polished foil made of duplex stainless steel 2205 was examined. The thin part close to the hole edge producing normal-contrast patterns were standard indexed. The areas of the foil that become thicker with increasing distance from the edge of the hole produce contrast-inverted patterns. They covered three times the evaluable area and were successfully processed using the contrast-inverted master pattern. In the last example, inverted patterns collected at a non-tiled sample were mathematically inverted to normal contrast, and Hough/Radon-based indexing was successfully applied.
KW - EBSD
KW - TKD
KW - Contrast inversion
KW - Topography
KW - Kikuchi diffraction
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-613862
VL - 267
SP - 1
EP - 8
PB - Elsevier
CY - Amsterdam
AN - OPUS4-61386
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - CONF
A1 - Weichert, Dorina
A1 - Kister, Alexander
A1 - Houben, Sebastian
A1 - Link, Patrick
A1 - Ernis, Gunar
ED - Kiyavash, Negar
ED - Mooij, Joris M.
T1 - Robust Entropy Search for Safe Efficient Bayesian Optimization
N2 - The practical use of Bayesian Optimization (BO) in engineering applications imposes special requirements: high sampling efficiency on the one hand and finding a robust solution on the other hand. We address the case of adversarial robustness, where all parameters are controllable during the optimization process, but a subset of them is uncontrollable or even adversely perturbed at the time of application. To this end, we develop an efficient information-based acquisition function that we call Robust Entropy Search (RES). We empirically demonstrate its benefits in experiments on synthetic and real-life data. The results show that RES reliably finds robust optima, outperforming state-of-the-art algorithms.
T2 - UAI 2024
CY - Barcelona, Spain
DA - 15.07.2024
KW - Bayesian Optimization
KW - Gaussian process
KW - Active learning
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-613523
UR - https://proceedings.mlr.press/v244/weichert24a.html
SN - 2640-3498
VL - 244
SP - 3711
EP - 3729
PB - Proceedings of Machine Learning Research
AN - OPUS4-61352
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Schilling, Markus
A1 - Bruns, Sebastian
A1 - Bayerlein, Bernd
A1 - Kryeziu, Jehona
A1 - Schaarschmidt, Jörg
A1 - Waitelonis, Jörg
A1 - Dolabella Portella, Pedro
A1 - Durst, Karsten
T1 - Seamless Science: Lifting Experimental Mechanical Testing Lab Data to an Interoperable Semantic Representation
N2 - The scientific landscape is undergoing rapid transformations with the advent of the digital age which revolutionizes research methodologies. In materials science and engineering, an adoption of modern data management techniques is desirable to maximize the efficiency and accessibility of research efforts. Traditional practices in testing laboratories are usually inadequate for efficient data acquisition and utilization as they lead to local storage and difficulty in publication and correlation with other results. Electronic laboratory notebooks (ELNs) are promising prospects in this respect. Semantic concepts and ontologies enhance interoperability by standardizing experimental data representation. An in‐laboratory pipeline seamlessly integrating an ELN with transformation scripts to convert experimental into interoperable data in a machine‐actionable format is created in this study as a proof of concept. Tensile test results and the corresponding tensile test ontology are used exemplary. Linking ELN data to semantic concepts enriches the stored information while improving interpretability and reusability. Involving undergraduate students builds a bridge between theory and practice during their training and promotes their digital skills. This study underscores the potential of ELNs and knowledge representations as beneficial means toward improved data management practices that enhance collaborative research and education while ensuring compatibility with evolving standards and technologies.
KW - Semantic Data
KW - Data Integration
KW - Tensile Test Ontology
KW - Electronic Lab Notebook
KW - Wissensrepräsentation
KW - Education
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-618251
DO - https://doi.org/10.1002/adem.202401527
SP - 1
EP - 13
PB - Wiley VHC-Verlag
AN - OPUS4-61825
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Gregório, Bruno J.R.
A1 - Ramos, Inês I.
A1 - Marques, Sara S.
A1 - Barreiros, Luísa
A1 - Magalhães, Luís M.
A1 - Schneider, Rudolf
A1 - Segundo, Marcela A.
T1 - Microcarrier-based fluorescent yeast estrogen screen assay for fast determination of endocrine disrupting compounds
N2 - The presence of endocrine-disrupting compounds (EDCs) in water poses a significant threat to human and animal health, as recognized by regulatory agencies throughout the world. The Yeast Estrogen Screen (YES) assay is an excellent method to evaluate the presence of these compounds in water due to its simplicity and capacity to assess the bioaccessible forms/fractions of these compounds. In the presence of a compound with estrogenic activity, Saccharomyces cerevisiae cells, containing a lacZ reporter gene encoding the enzyme β-galactosidase, are induced, the enzyme is synthesised, and released to the extracellular medium. In this work, a YES-based approach encompassing the use of a lacZ reporter gene modified strain of S. cerevisiae, microcarriers as solid support, and a fluorescent substrate, fluorescein di-β-D-galactopyranoside, is proposed, allowing for the assessment of EDCs’ presence after only 2 h of incubation. The proposed method provided an EC50 of 0.17 ± 0.03 nM and an LLOQ of 0.03 nM, expressed as 17β-estradiol. The assessment of different EDCs provided EC50 values between 0.16 and 1.2 × 103 nM. After application to wastewaters, similar results were obtained for EDCs screening, much faster, compared to the conventional 45 h spectrophotometric procedure using a commercial kit, showing potential for onsite high-throughput screening of environmental contamination.
KW - Biosensoren
KW - YES assay
KW - Endokrine Disruptoren
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-602315
DO - https://doi.org/10.1016/j.talanta.2024.125665
VL - 271
SP - 1
EP - 7
PB - Elsevier B.V.
CY - Amsterdam
AN - OPUS4-60231
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -
TY - JOUR
A1 - Braymer, Joseph J.
A1 - Stehling, Oliver
A1 - Stümpfig, Martin
A1 - Rösser, Ralf
A1 - Spantgar, Farah
A1 - Blinn, Catharina M.
A1 - Mühlenhoff, Ulrich
A1 - Pierik, Antonio J.
A1 - Lill, Roland
T1 - Requirements for the biogenesis of [2Fe-2S] proteins in the human and yeast cytosol
N2 - The biogenesis of iron–sulfur (Fe/S) proteins entails the synthesis and trafficking of Fe/S clusters, followed by their insertion into target apoproteins. In eukaryotes, the multiple steps of biogenesis are accomplished by complex protein machineries in both mitochondria and cytosol. The underlying biochemical pathways have been elucidated over the past decades, yet the mechanisms of cytosolic [2Fe-2S] protein assembly have remained ill-defined. Similarly, the precise site of glutathione (GSH) requirement in cytosolic and nuclear Fe/S protein biogenesis is unclear, as is the molecular role of the GSH-dependent cytosolic monothiol glutaredoxins (cGrxs). Here, we investigated these questions in human and yeast cells by various in vivo approaches. [2Fe-2S] cluster assembly of cytosolic target apoproteins required the mitochondrial ISC machinery, the mitochondrial transporter Atm1/ABCB7 and GSH, yet occurred independently of both the CIA system and cGrxs. This mechanism was strikingly different from the ISC-, Atm1/ABCB7-, GSH-, and CIA-dependent assembly of cytosolic–nuclear [4Fe-4S] proteins. One notable exception to this cytosolic [2Fe-2S] protein maturation pathway defined here was yeast Apd1 which used the CIA system via binding to the CIA targeting complex through its C-terminal tryptophan. cGrxs, although attributed as [2Fe-2S] cluster chaperones or trafficking proteins, were not essential in vivo for delivering [2Fe-2S] clusters to either CIA components or target apoproteins. Finally, the most critical GSH requirement was assigned to Atm1-dependent export, i.e. a step before GSH-dependent cGrxs function. Our findings extend the general model of eukaryotic Fe/S protein biogenesis by adding the molecular requirements for cytosolic [2Fe-2S] protein maturation.
KW - Biokorrosion
KW - Hydrogenasen
KW - Microbially Induced Corrosion
PY - 2024
UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-602328
DO - https://doi.org/10.1073/pnas.2400740121
SN - 0027-8424
VL - 121
IS - 21
SP - 1
EP - 12
PB - Proceedings of the National Academy of Sciences
CY - Washington D.C.
AN - OPUS4-60232
LA - eng
AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER -