TY - JOUR A1 - Stajanca, Pavol A1 - Topolniak, Ievgeniia A1 - Pötschke, Samuel A1 - Krebber, Katerina T1 - Solution-mediated cladding doping of commercial polymer optical fibers N2 - Solution doping of commercial polymethyl methacrylate (PMMA) polymer optical fibers (POFs) is presented as a novel approach for preparation of custom cladding-doped POFs (CD-POFs). The presented method is based on a solution-mediated diffusion of dopant molecules into the fiber cladding upon soaking of POFs in a methanol-dopant solution. The method was tested on three different commercial POFs using Rhodamine B as a fluorescent dopant. The dynamics of the diffusion process was studied in order to optimize the doping procedure in terms of selection of the most suitable POF, doping time and conditions. Using the optimized procedure, longer segment of fluorescent CD-POF was prepared and its performance was characterized. Fiber’s potential for sensing and illumination applications was demonstrated and discussed. The proposed method represents a simple and cheap way for fabrication of custom, short to medium length CD-POFs with various dopants. KW - Polymer optical fiber KW - Solution doping KW - Polymethyl methacrylate KW - Rhodamine B KW - Dye-doped fiber KW - Fluorescent optical fiber PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-441045 DO - https://doi.org/10.1016/j.yofte.2018.02.008 SN - 1068-5200 SN - 1095-9912 VL - 41 SP - 227 EP - 234 PB - Elsevier Inc. AN - OPUS4-44104 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stajanca, Pavol A1 - Mihai, L. A1 - Sporea, D. A1 - Negut, D. A1 - Sturm, Heinz A1 - Schukar, Marcus A1 - Krebber, Katerina ED - Webb, D. J. ED - Scully, P. ED - Sugden, K. T1 - Impacts of gamma irradiation on cytop plastic optical fibres N2 - Impact of gamma radiation on transmission of a commercial Cytop polymer optical fibre (Lucina, Asahi Glass Company) is investigated. Spectral dependence of radiation induced attenuation in the investigated fibre is measured in the VIS-NIR spectral region. Besides attenuation increase, radiation is found to increase fibre susceptibility to water as well. While pristine Cytop fibre is rather humidity insensitive, strong humidity related absorption in the NIR region is observed after fibre irradiation. Selective irradiation of separate fibre sections is proposed as a way of fibre humidity sensitization and quasi-distributed water detection is demonstrated using optical time domain reflectometry at 1310 nm. T2 - POF 2016: 25th International Conference on Plastic Optical Fibres CY - Birmingham, UK DA - 13.09.2016 KW - Polymer optical fibers KW - Cytop KW - Gamma radiation PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-403216 SN - 9781854494085 SP - 114 EP - 117 CY - Birmingham AN - OPUS4-40321 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hirsch, Philipp Daniel A1 - Kunji Purayil, Sruthi Krishna A1 - Lecompagnon, Julien A1 - Hassenstein, Christian A1 - Ziegler, Mathias T1 - Robotergestützte 3D-Scans und Laserthermografie zur Prüfung an komplexen Bauteilen auf Risse N2 - Die Integration von Automation und Robotik in die Prüfprozesse ermöglicht die Untersuchung komplexer Bauteile. Diese Studie präsentiert die robotergestützte Laserthermografie, um Risse in solchen Bauteilen zu identifizieren und analysieren. Diese Technik ermöglicht die automatisierte Rissprüfung welche im Vergleich zur Farbeindringprüfung auf viele, meist manuelle, Arbeitsschritte sowie die notwendigen Chemikalien verzichtet. Zusätzlich wird ein automatisiertes Einscannen der Bauteile mithilfe eines Linienscanners vorgestellt. Dieser Schritt ermöglicht eine detaillierte 3D-Rekonstruktion der Bauteilgeometrie und ermöglicht eine einfache Korrektur von Abweichungen in der Bauteilaufnahme und eröffnet Möglichkeiten zur adaptiven Bahnplanung bei Bauteilverformungen. Die Rückprojektion der gefundenen Risse auf die Oberfläche des Bauteils kann automatisiert erfolgen. Dieser Schritt erlaubt nicht nur die Identifikation der Risse, sondern auch eine genauere Analyse ihrer Geometrie und Lage am Bauteil. Die Kombination von robotergestützter Laserthermografie, automatisiertem 3DScanning und Rückprojektion der Risse auf die Bauteiloberfläche eröffnet neue Möglichkeiten in der zerstörungsfreien Prüfung von komplexen Bauteilen und erweitert damit mögliche Anwendungsfelder. T2 - Jahrestagung der Deutschen Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) 2024 CY - Osnabrück, Germany DA - 06.05.2024 KW - ZFP4.0 KW - Automatisierung KW - Thermografie KW - Laser KW - Roboter PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-604811 UR - https://www.ndt.net/?id=29520 VL - 182 SP - 1 EP - 8 PB - NDT.net AN - OPUS4-60481 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hauffen, J. C. A1 - Kästner, L. A1 - Ahmadi, Samim A1 - Jung, P. A1 - Caire, G. A1 - Ziegler, Mathias T1 - Learned block iterative shrinkage thresholding algorithm for photothermal super resolution imaging N2 - Block-sparse regularization is already well known in active thermal imaging and is used for multiple-measurement-based inverse problems. The main bottleneck of this method is the choice of regularization parameters which differs for each experiment. We show the benefits of using a learned block iterative shrinkage thresholding algorithm (LBISTA) that is able to learn the choice of regularization parameters, without the need to manually select them. In addition, LBISTA enables the determination of a suitable weight matrix to solve the underlying inverse problem. Therefore, in this paper we present LBISTA and compare it with state-of-the-art block iterative shrinkage thresholding using synthetically generated and experimental test data from active thermography for defect reconstruction. Our results show that the use of the learned block-sparse optimization approach provides smaller normalized mean square errors for a small fixed number of iterations. Thus, this allows us to improve the convergence speed and only needs a few iterations to generate accurate defect reconstruction in photothermal super-resolution imaging. KW - Thermography KW - Laser KW - Machine learning KW - Optimization KW - Non-destructive testing KW - NDT KW - Neural network KW - Defect reconstruction KW - Block-sparsity KW - Active thermal imaging KW - Regularization KW - Laser thermography PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-554598 DO - https://doi.org/10.3390/s22155533 SN - 1424-8220 VL - 22 IS - 15 SP - 1 EP - 15 PB - MDPI CY - Basel AN - OPUS4-55459 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ahmadi, Samim A1 - Burgholzer, P. A1 - Jung, P. A1 - Caire, G. A1 - Ziegler, Mathias T1 - Super resolution laser line scanning thermography N2 - In this paper we propose super resolution measurement and post-processing strategies that can be applied in thermography using laser line scanning. The implementation of these techniques facilitates the separation of two closely spaced defects and avoids the expected deterioration of spatial resolution due to heat diffusion. The experimental studies were performed using a high-power laser as heat source in combination with pulsed thermography measurements (step scanning) or with continuous heating measurements (continuous scanning). Our work shows that laser line step scanning as well as continuous scanning both can be used within our developed super resolution (SR) techniques. Our SR techniques make use of a compressed sensing based algorithm in post- processing, the so-called iterative joint sparsity (IJOSP) approach. The IJOSP method benefits from both - the sparse nature of defects in space as well as from the similarity of each measurement. In addition, we show further methods to improve the reconstruction quality e.g. by simple manipulations in thermal image processing such as by considering the effect of the scanning motion or by using different optimization algorithms within the IJOSP approach. These super resolution image processing methods are discussed so that the advantages and disadvantages of each method can be extracted. Our contribution thus provides new approaches for the implementation of super resolution techniques in laser line scanning thermography and informs about which experimental and post-processing parameters should be chosen to better separate two closely spaced defects. KW - Super resolution KW - Laser thermography KW - Compressed sensing KW - Laser scanning KW - Joint sparsity PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-509796 DO - https://doi.org/10.1016/j.optlaseng.2020.106279 SN - 0143-8166 VL - 134 SP - 106279 PB - Elsevier Ltd. AN - OPUS4-50979 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pauw, Brian Richard A1 - Smith, A. J. A1 - Snow, T. A1 - Shebanova, O. A1 - Sutter, J. P. A1 - Ilavsky, J. A1 - Hermida-Merino, D. A1 - Smales, Glen Jacob A1 - Terrill, N. J. A1 - Thünemann, Andreas A1 - Bras, W. T1 - Extending synchrotron SAXS instrument ranges through addition of a portable, inexpensive USAXS module with vertical rotation axes N2 - Ultra-SAXS can enhance the capabilities of existing synchrotron SAXS/WAXS beamlines. A compact ultra-SAXS module has been developed, which extends the measurable q-range with 0.0015 ≤ q (nm−1) ≤ 0.2, allowing structural dimensions in the range 30 ≤ D (nm) ≤ 4000 to be probed in addition to the range covered by a high-end SAXS/WAXS instrument. By shifting the module components in and out on their respective motor stages, SAXS/WAXS measurements can be easily and rapidly interleaved with USAXS measurements. The use of vertical crystal rotation axes (horizontal diffraction) greatly simplifies the construction, at minimal cost to efficiency. In this paper, the design considerations, realization and synchrotron findings are presented. Measurements of silica spheres, an alumina membrane, and a porous carbon catalyst are provided as application examples. KW - X-ray scattering KW - Microstructure KW - Instrumentation KW - SAXS KW - USAXS KW - Nanostructure KW - Combined techniques PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-524919 DO - https://doi.org/10.1107/S1600577521003313 SN - 1600-5775 VL - 28 IS - 3 SP - 824 EP - 833 PB - Wiley CY - Oxford AN - OPUS4-52491 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ahmadi, Samim A1 - Lecompagnon, Julien A1 - Hirsch, Philipp Daniel A1 - Burgholzer, P. A1 - Jung, P. A1 - Caire, G. A1 - Ziegler, Mathias T1 - Laser excited super resolution thermal imaging for nondestructive inspection of internal defects N2 - A photothermal super resolution technique is proposed for an improved inspection of internal defects. To evaluate the potential of the laser-based thermographic technique, an additively manufactured stainless steel specimen with closely spaced internal cavities is used. Four different experimental configurations in transmission, reflection, stepwise and continuous scanning are investigated. The applied image post-processing method is based on compressed sensing and makes use of the block sparsity from multiple measurement events. This concerted approach of experimental measurement strategy and numerical optimization enables the resolution of internal defects and outperforms conventional thermographic inspection techniques. KW - Super Resolution KW - Laser Thermography KW - Non Destructive Testing KW - Comressed Sensing KW - Inverse Problem KW - Thermography PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-519016 DO - https://doi.org/10.1038/s41598-020-77979-y VL - 10 IS - 1 SP - 22357 PB - Springer Nature AN - OPUS4-51901 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Unnikrishnakurup, Sreedhar A1 - Myrach, Philipp A1 - Polomski, Benjamin A1 - Le Claire, Elisabeth A1 - Vengara, N. A1 - Balasubramaniam, Krishnan A1 - Ziegler, Mathias T1 - Thermographic crack detection in hot steel surfaces N2 - The detection and characterization of surface cracks in steel specimens prior to damage is a technologically and economically highly significant task and is of utmost importance when it comes to safety-relevant structures. In steel production where steel billets at high temperatures have to be inspected while moving a number of well-established NDT methods cannot be applied. Laser thermography however is a promising candidate to serve as a fast, non-contact and remote tool in this case. We present a study that shows that the crack detection capabilities of laser thermography can be extended also to specimens at high temperature. A combination of inductive and laser heating allows to systematically study the contrast formation as well as the optimization of the important measurement parameters. The experiments are accompanied by FEM simulations that provide a better insight of the physical correlations and support the experimental developments. The aim of these studies is to develop a system with high inspection speed and detection performance to be in-line operated under the hostile environment of steel production lines. T2 - 19th World Conference on Non-Destructive Testing (WCNDT 2016) CY - Munich, Germany DA - 13.06.2016 KW - In-line Monitoring KW - Laser Infrared thermography KW - Cracks KW - Induction heating KW - Steel billets KW - FEM simulation PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-389161 UR - http://ndt.net/?id=19573 SN - 1435-4934 VL - 21 IS - 7 SP - 1 EP - 8 PB - NDT.net CY - Kirchwald AN - OPUS4-38916 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - You, Zengchao A1 - Winckelmann, Alexander A1 - Vogl, Jochen A1 - Recknagel, Sebastian A1 - Abad Andrade, Carlos Enrique T1 - Determination of calcium, iron, and selenium in human serum by isotope dilution analysis using nitrogen microwave inductively coupled atmospheric pressure plasma mass spectrometry (MICAP-MS) N2 - In this study, we demonstrate the applicability of nitrogen microwave inductively coupled atmospheric pressure mass spectrometry (MICAP-MS) for Ca, Fe, and Se quantification in human serum using isotope dilution (ID) analysis. The matrix tolerance of MICAP-MS in Na matrix was investigated, uncovering that high Na levels can suppress the signal intensity. This suppression is likely due to the plasma loading and the space charge effect. Moreover, 40Ca and 44Ca isotopic fractionation was noted at elevated Na concentration. Nine certified serum samples were analyzed using both external calibration and ID analysis. Overestimation of Cr, Zn, As, and Se was found in the results of external calibration, which might be resulted from C-induced polyatomic interference and signal enhancement, respectively. Further investigations performed with methanol showed a similar enhancement effect for Zn, As, and Se, potentially supporting this assumption. The mass concentrations determined with ID analysis show metrological compatibility with the reference values, indicating that MICAP-MS combined with ID analysis can be a promising method for precise Ca, Fe, and Se determination. Moreover, this combination reduces the influences of matrix effects, broadening the applicability of MICAP-MS for samples with complex matrix. KW - Selenium KW - Nitrogen microwave inductively coupled atmospheric pressure mass spectrometry KW - Isotope dilution KW - Human serum KW - Calcium KW - Iron PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-598664 DO - https://doi.org/10.1007/s00216-024-05274-0 SN - 1618-2642 SP - 3117 EP - 3125 PB - Springer CY - Berlin AN - OPUS4-59866 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krankenhagen, Rainer A1 - Ziegler, Mathias A1 - Maierhofer, Christiane ED - Maldague, X. T1 - Systematic errors in the evaluation of uncorrected data from thermographic lock-in measurements N2 - Lock-in thermography (LT) is based on the correct evaluation of phase differences between the temperature oscillations at different surface regions of the object under test during periodic heating. Since the usual heating procedures contain a DC component, the actual heating pattern achieved is not harmonic. This causes systematic deviations when phase differences are determined by means of harmonic analysis, e.g. with FFT analysis. The resulting errors depend clearly on the ratio between DC and AC amplitude, which is demonstrated at simulated and experimentally recorded temperature transients. Further experimental LT data obtained by different oscillating energy inputs showed a variety of possible shapes of transients with different DC components. T2 - 14th QIRT Conference CY - Berlin, Germany DA - 26.06.2018 KW - NDT KW - Lock-in Thermography KW - FFT PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-453768 SP - 539 EP - 547 PB - QIRT Council AN - OPUS4-45376 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maierhofer, Christiane A1 - Ziegler, Mathias A1 - Kunert, M. A1 - Goldammer, M. T1 - Entwicklung von Referenzprobekörpern für die Standardisierung der Blitzthermografie N2 - Die aktive Thermografie wird in der Industrie zunehmend in verschiedenen Bereichen zur Qualitätssicherung, Zustandsdiagnose und Zustandsüberwachung eingesetzt. Bestehende Normen zur Thermografie beschreiben die Grundlagen, Geräte und Begriffe. In diesem Beitrag wird über ein Projekt berichtet, dessen Ziel die Erarbeitung einer Prüfnorm zur Blitzthermografie ist. Diese sollte neben der Auswahl geeigneter Gerätekomponenten, der Auswertungsverfahren und der Vorgehensweise bei der Prüfung auch die Beschreibung geeigneter Referenzprobekörper enthalten, die eine Bewertung der Messapparatur und eine Qualitätssicherung der Prüfung ermöglichen. T2 - Thermographie-Kolloquium 2011 CY - Stuttgart, Germany DA - 29.09.2011 KW - Aktive Thermografie KW - Blitzanregung KW - Prüfnorm KW - Referenzprobekörper PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-246230 SN - 978-3-940283-36-8 VL - 130 SP - 1 EP - 7 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) CY - Berlin AN - OPUS4-24623 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlichting, Joachim A1 - Ziegler, Mathias A1 - Pelkner, Matthias A1 - Maierhofer, Christiane A1 - Kreutzbruck, Marc T1 - Kameragestütztes Flying-Spot-Verfahren zur Risserkennung N2 - In dieser Arbeit wird ein kameragestütztes Verfahren zur Flying- Spot-Thermografie vorgestellt. Die Anregung wird über einen Diodenlaser mit einem optischen Scanner realisiert. Bei der Auswertung kommt ein effizienter und robuster Algorithmus zum Einsatz, der direkt auf die mit der Kamera aufgenommene Thermografiesequenz angewendet werden kann, ohne auf eine Synchronisation zwischen Kamera und Lasersystem angewiesen zu sein. Daher eignet sich diese Herangehensweise besonders zur Nachrüstung bestehender Thermografiesysteme. Die prinzipielle Eignung dieser Methode wird anhand einer Messung an einem Schienenstück mit Rollkontaktermüdungsrissen gezeigt. Als Referenzverfahren werden die Magnetpulverprüfung und eine auf GMR (Giant Magnetoresistance)- Sensoren basierende Streufeldmessung herangezogen. Mit dem thermografischen Verfahren konnten sämtliche enthaltenen Fehler erkannt werden. Dabei wurden Risse im mm-Abstand getrennt nachgewiesen, was etwa der geometrischen Auflösung der eingesetzten Kamera entspricht. T2 - Thermographie-Kolloquium 2011 CY - Stuttgart, Germany DA - 29.09.2011 KW - Flying-Spot Thermografie KW - Diodenlaser KW - Rissortung KW - Magnetpulverprüfung KW - GMR-Sensoren PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-246220 SN - 978-3-940283-36-8 IS - DGZfP-BB 130 (Vortrag 09) SP - 1 EP - 6 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-24622 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Thummerer, G. A1 - Mayr, G. A1 - Hirsch, Philipp Daniel A1 - Ziegler, Mathias A1 - Burgholzer, P. T1 - Photothermal Image Reconstruction in Opaque Media with Virtual Wave Backpropagation N2 - Thermographic reconstruction of defects that lie in the bulk of a sample is a difficult task because entropy production during heat diffusion leads to information loss. To reconstruct defects one has to solve an inverse heat conduction problem. The quality of the reconstruction is closely related to the information content of the observed data set that is reflected by the decreasing ability to spatially resolve a defect with growing defect depth. In this work we show a 2D reconstruction of rectangular slots with different width-to-depth ratios in a metallic sample. For this purpose, we apply the virtual wave concept and incorporate positivity and sparsity as prior information to overcome the diffusion-based information loss partially. The reconstruction is based on simulated and experimental pulse thermography data. In the first reconstruction step, we compute a virtual wave field from the surface temperature data. This allows us, in the second step, to use ultrasonic backpropagation methods for image reconstruction. KW - Virtual wave concept KW - Thermography KW - Photothermal Technique KW - Image reconstruction PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-506166 DO - https://doi.org/10.1016/j.ndteint.2020.102239 VL - 112 SP - 102239 PB - Elsevier Ltd. CY - Netherlands AN - OPUS4-50616 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ziegler, Mathias A1 - Myrach, Philipp A1 - Schlichting, Joachim A1 - Maierhofer, Christiane A1 - Kreutzbruck, Marc T1 - Laser-Thermografie für die schnelle Prüfung auf mikroskopische Risse in reflektierenden metallischen Oberflächen N2 - Thermografische ZfP-Verfahren erlauben die Erkennung einer Vielzahl von Defekten in unterschiedlichsten Werkstoffen. Neue Ansätze unter Verwendung von Lasern ermöglichen darüber hinaus die Prüfung auf Oberflächenrisse. Wir stellen die neuesten Entwicklungen dieser vielversprechenden Technik vor und zeigen warum deren Einsatz potentiell die Standardprüfverfahren Magnetpulver- bzw. Eindringprüfung für eine Reihe von Prüfproblemen beerben könnte. Hierzu stellen wir die Prüfergebnisse zu unterschiedlichen metallischen Werkstoffen, Rissgrößen und -typen in Abhängigkeit der Prüfparameter vor. Die aktuelle Grenze der Nachweisempfindlichkeit für die mittels klassischer Thermografie schwer prüfbaren hochreflektierenden Metalloberflächen liegt mit Rissbreiten und -tiefen von weni-gen Mikrometern im Bereich der fluoreszierenden Magnetpulver- und Eindringprüfung. Dabei sind weder Verbrauchsmittel noch eine Oberflächenpräparation notwendig und eine Prüfung kann berührungslos und automatisiert über Entfernungen im Meter-Bereich erfolgen. T2 - DGZfP-Jahrestagung 2013 CY - Dresden, Germany DA - 06.05.2013 KW - Thermografie KW - Laser KW - Risse PY - 2013 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-288706 SN - 978-3-940283-49-8 IS - DGZfP-BB 141 (Di.2.A.4) SP - 1 EP - 8 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-28870 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Röllig, Mathias A1 - Steinfurth, Henrik A1 - Ziegler, Mathias T1 - Untersuchung von Hochleistungs-LEDs für den Einsatz in der zerstörungsfreien Prüfung mittels Thermografie N2 - Für die optische Erwärmung von Prüfteiloberflächen sind Blitz- und Halogenlampen Stand der Technik. Der Vorteil dieser Wärmequellen liegt in ihren relativ geringen Anschaffungskosten bei gleichzeitig hohen Leistungsdichten am Prüfobjekt. Nachteilig ist bei den Halogenlampen die Limitierung der möglichen Modulationsffequenz auf ca. 1 Hz für die Anwendung dieser Quelle in der Lockin-Thermografie. Blitzlampen bieten für gewöhnlich nur eine feste Blitzdauer bei einer geringen Taktrate. Beide Anregungsquellen müssen in Reflexionsanordnung mit Filtern betrieben werden um die entstehende thermische Eigenstrahlung als Störquelle zu eliminieren. Wir stellen Untersuchungen an Hochleistungs-LEDs für den Einsatz in der aktiven Thermografie vor. Diese Lichtquellen werden durch die rasante Entwicklung der möglichen Leistungsdichten nun auch für die thermografische ZfP interessant. Sie zeigen ähnlich dem Laser eine schmale und auf den Werkstoff abstimmbare spektrale Verteilung der Strahlungsleistung bei moderaten Kosten. Die zugrunde liegende Elektrolumineszenz generiert kaum Wärmestrahlung und ermöglicht dadurch die Prüfung während des Erwärmungsvorganges ohne größeren Aufwand. Modulationsfrequenzen über 100 Hz mit thermischen Eindringtiefen < 1 mm sind möglich. Dadurch qualifizieren sich die LEDs zur Anwendung in der Lockin-Thermografie von Metallen und zur oberflächennahen Prüfung von Schichtsystemen. Durch die fast verzögerungsffeie Reaktion der LED auf das steuernde Signal sind nahezu beliebige zeitliche Anregungsformen möglich. Mit solch flexiblen Anregungsformen ließen sich bereits bei den photothermischen Verfahren erfolgreich höhere Tiefenreichweiten und -auflösungen gegenüber den klassischen Methoden der monofrequenten Lockin - und energiereichen Kurzimpuls-Anregung erzielen. Untersuchungen dieser Möglichkeiten im praktischen Einsatz der HochleistungsLEDs werden vorgestellt und mit herkömmlichen Lichtquellen verglichen. T2 - Thermographie-Kolloquium 2013 CY - Leinfelden-Echterdingen, Germany DA - 2013-09-26 KW - Thermografie KW - Hochleistungsleuchtdioden KW - Hohe Prüfraten KW - Schnelle Modulationsfrequenzen PY - 2013 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-293975 SN - 978-3-940283-52-8 VL - DGZfP-BB 143 SP - Vortrag 3, 1 EP - 8 AN - OPUS4-29397 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Casperson, Ralf A1 - Heideklang, René A1 - Myrach, Philipp A1 - Onel, Yener A1 - Pelkner, Matthias A1 - Pohl, Rainer A1 - Stegemann, Robert A1 - Ziegler, Mathias A1 - Kreutzbruck, Marc T1 - Vergleich konventioneller und neuer Oberflächenprüfverfahren für ferromagnetische Werkstoffe N2 - Sicherheitsrelevante und zyklisch hoch belastete Bauteile erfordern zur Vermeidung von kostenintensiven Ausfällen besonders stabile Prozessparameter. Bereits sehr kleine Randzonenfehler können unter zyklischer Bauteilbelastung zu Risswachstum und letztendlich zum Bauteilversagen führen. Die frühzeitige Erkennung von Randzonenfehler in Hochleistungsbauteilen wie z.B. Zahnräder, Ritzelwellen und Kurbelwellen erfordert daher eine leistungsfähige zerstörungsfreie Oberflächenrissprüfung, die es ermöglicht in den hochbeanspruchten Funktionsflächen auch Härterisse, Schleifrisse oder Zundereinschlüsse zu detektieren. Hierzu sind in den letzten Jahren einige neue, innovative Oberflächenprüfverfahren wie die laserangeregte Thermografie und die Streuflussprüfung mit hochauflösenden GMR-Sensoren oder magnetooptischen Verfahren entwickelt worden. Zusätzlich zur hohen Empfindlichkeit zeichnen sich diese innovativen Verfahren durch einen schnellen und teils auch berührungslosen Einsatz aus. Da die noch relativ neu-en Verfahren naturgemäß noch nicht normativ verankert sind, wurden auch bereits erste Validierungen durchgeführt. Um die Leistungsfähigkeit der Verfahren eingehend zu untersuchen, erfolgten Testreihen an verschiedenen Testkörpern in Bezug auf Ortsauflösung, Empfindlichkeit, Automatisierung und Bewertung der Messsig-nale. Neben den neuen Verfahren und ihren ersten Schritten hin zur Validierung kamen als Referenz auch die „klassischen“ Verfahren der Magnetpulver- und Wirbelstromprüfung zum Einsatz, deren Leistungsfähigkeit durch angepasste Sondenentwicklung auch für sehr kleine Oberflächendefekte nochmals unter Beweis gestellt wurde. Zusätzlich wurde an einigen Testkörpern eine hochauflösende CT durchgeführt. Die Ergebnisse dieses Vergleiches werden vorgestellt und Möglichkeiten sowie Grenzen der einzelnen Verfahren herausgearbeitet. T2 - DACH-Jahrestagung 2015 CY - Salzburg, Austria DA - 11.05.2015 KW - Zerstörungsfreie Prüfung KW - Oberflächenprüfung KW - Vergleichskörper 1 KW - Sichtprüfung KW - Magnetpulverprüfung KW - Streuflussprüfung KW - Farbeindringprüfung KW - Wirbelstromprüfung KW - Thermografie KW - Radiografie PY - 2015 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-344262 SN - 978-3-940283-68-9 IS - DGZfP BB 152 SP - Mi.2.B.4, 1 EP - 11 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) AN - OPUS4-34426 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Cakir, Cafer Tufan A1 - Bogoclu, Can A1 - Emmerling, Franziska A1 - Streli, Christina A1 - Guilherme Buzanich, Ana A1 - Radtke, Martin T1 - Machine learning for efficient grazing-exit x-ray absorption near edge structure spectroscopy analysis: Bayesian optimization approach N2 - In materials science, traditional techniques for analyzing layered structures are essential for obtaining information about local structure, electronic properties and chemical states. While valuable, these methods often require high vacuum environments and have limited depth profiling capabilities. The grazing exit x-ray absorption near-edge structure (GE-XANES) technique addresses these limitations by providing depth-resolved insight at ambient conditions, facilitating in situ material analysis without special sample preparation. However, GE-XANES is limited by long data acquisition times, which hinders its practicality for various applications. To overcome this, we have incorporated Bayesian optimization (BO) into the GE-XANES data acquisition process. This innovative approach potentially reduces measurement time by a factor of 50. We have used a standard GE-XANES experiment, which serve as reference, to validate the effectiveness and accuracy of the BO-informed experimental setup. Our results show that this optimized approach maintains data quality while significantly improving efficiency, making GE-XANES more accessible to a wider range of materials science applications. KW - Machine Learning KW - GE-XANES KW - Bayesian Optimization PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-603955 DO - https://doi.org/10.1088/2632-2153/ad4253 VL - 5 IS - 2 SP - 1 EP - 12 PB - IOP Publishing AN - OPUS4-60395 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hildebrandt, R. A1 - Seifert, M. A1 - George, Janine A1 - Blaurock, S. A1 - Botti, S. A1 - Krautscheid, H. A1 - Grundmann, M. A1 - Sturm, C. T1 - Determination of acoustic phonon anharmonicities via second-order Raman scattering in CuI N2 - We demonstrate the determination of anharmonic acoustic phonon properties via second-order Raman scattering exemplarily on copper iodide single crystals. The origin of multi-phonon features from the second-order Raman spectra was assigned by the support of the calculated 2-phonon density of states. In this way, the temperature dependence of acoustic phonons was determined down to 10 K. To determine independently the harmonic contributions of respective acoustic phonons, density functional theory in quasi-harmonic approximation was used. Finally, the anharmonic contributions were determined. The results are in agreement with earlier publications and extend CuI’s determined acoustic phonon properties to lower temperatures with higher accuracy. This approach demonstrates that it is possible to characterize the acoustic anharmonicities via Raman scattering down to zero-temperature renormalization constants of at least 0.1 cm⁻¹. KW - Thermoelectrics KW - Thermal transport KW - Phonon interactions KW - Density functional theory KW - Phonons PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-593164 DO - https://doi.org/10.1088/1367-2630/ad1141 SN - 1367-2630 VL - 25 IS - 12 SP - 1 EP - 12 PB - IOP Publishing CY - London AN - OPUS4-59316 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Menzel, M. A1 - Scharf, O. A1 - Novak, S. A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Hischenhuber, P. A1 - Buzanich, Günter A1 - Meyer, A. A1 - Lopez, V. A1 - McIntosh, K. A1 - Streli, C. A1 - Havrilla, G. A1 - Fittschen, U. T1 - Shading in TXRF: calculations and experimental validation using a color X-ray camera N2 - Absorption effects in total reflection X-ray fluorescence (TXRF) analysis are important to consider, especially if external calibration is to be applied. With a color X-ray camera (CXC), that enables spatially and energy resolved XRF analysis, the absorption of the primary beam was directly visualized for mL-droplets and an array of pL-droplets printed on a Si-wafer with drop-on-demand technology. As expected, deposits that are hit by the primary beam first shade subsequent droplets, leading to a diminished XRF signal. This shading effect was quantified with enhanced precision making use of sub-pixel analysis that improves the spatial resolution of the camera. The measured absorption was compared to simulated results using three different model calculations. It was found they match very well (average deviation < 10%). Thus errors in quantification due to absorption effects can be accounted for in a more accurate manner. KW - absorption KW - X-ray Fluorescence analysis PY - 2015 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-359000 DO - https://doi.org/10.1039/C5JA00127G IS - 10 SP - 2184 EP - 2193 PB - Royal Society of Chemistry CY - Cambridge AN - OPUS4-35900 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kabelitz, Anke A1 - de Oliveira Guilherme Buzanich, Ana A1 - Joester, Maike A1 - Reinholz, Uwe A1 - Radtke, Martin A1 - Bienert, Ralf A1 - Schulz, K. A1 - Schmack, R. A1 - Kraehnert, R. A1 - Emmerling, Franziska T1 - Time-resolved in situ studies on the formation mechanism of iron oxide nanoparticles using combined fast-XANES and SAXS N2 - The reaction of iron chlorides with an alkaline reagent is one of the most prominent methods for the synthesis of iron oxide nanoparticles. We studied the particle formation mechanism using triethanolamine as reactant and stabilizing agent. In situ fast-X-ray absorption near edge spectroscopy and small-angle X-ray scattering provide information on the oxidation state and the structural information at the same time. In situ data were complemented by ex situ transmission electron microscopy, wide-angle X-ray scattering and Raman analysis of the formed nanoparticles. The formation of maghemite nanoparticles (γ-Fe2O3) from ferric and ferrous chloride was investigated. Prior to the formation of these nanoparticles, the formation and conversion of intermediate phases (akaganeite, iron(II, III) hydroxides) was observed which undergoes a morphological and structural collapse. The thus formed small magnetite nanoparticles (Fe3O4) grow further and convert to maghemite with increasing reaction time. KW - oxidation state KW - structural information KW - maghemite PY - 2015 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-351376 DO - https://doi.org/10.1039/C5CE01585E SN - 1466-8033 VL - 17 IS - 44 SP - 8463 EP - 8470 CY - London, UK AN - OPUS4-35137 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - de Oliveira Guilherme Buzanich, Ana A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Riesemeier, Heinrich A1 - Emmerling, Franziska T1 - Time- & spatial-resolved X-ray absorption fine structure (XAFS) spectroscopy in a single-shot – new analytical possibilities for in situ material characterization N2 - A new concept that comprises both time- and lateral-resolved X-ray absorption fine-structure information simultaneously in a single shot is presented. This uncomplicated set-up was tested at the BAMline at BESSY-II (Berlin, Germany). The primary broadband beam was generated by a double multilayer monochromator. The transmitted beam through the sample is diffracted by a convexly bent Si (111) crystal, producing a divergent beam. This, in turn, is collected by either an energy-sensitive area detector, the so-called color X-ray camera, or by an area-sensitive detector based on a CCD camera, in θ-2θ geometry. The first tests were performed with thin metal foils and some iron oxide mixtures. A time resolution of lower than 1 s together with a spatial resolution in one dimension of at least 50 µm is achieved. KW - Time resolution KW - Single-shot XAFS PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-370892 DO - https://doi.org/10.1107/S1600577516003969 SN - 1600-5775 IS - 23 SP - 769 EP - 776 PB - International Union of Crystallography CY - Chester, UK AN - OPUS4-37089 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Radtke, Martin A1 - Buzanich, Günter A1 - Curado, Jessica A1 - Reinholz, Uwe A1 - Riesemeier, Heinrich A1 - Scharf, O. T1 - Slicing - a new method for non destructive 3D elemental sensitive characterization of materials N2 - Recent advances in synchrotron sources and detector technology have led to substantial improvements in spatial resolution and detection limits for X-ray fluorescence analysis (XRF). However, the non-destructive three-dimensional elemental sensitive characterization of samples remains a challenge. We demonstrate the use of the so-called 'Color X-ray Camera' (CXC) for 3D measurements for the first time. The excitation of the sample is realized with a thin sheet-beam. The stepwise movement of the sample allows getting the elemental distribution for each layer with one measurement. These layers can be combined to a full 3D dataset for each element afterwards. Since the information is collected layer by layer, there is no need to apply reconstruction techniques, which quite often are the reason for artifacts in the results achieved by computed tomography (CT). The field of applications is wide, as the 3D elemental distribution of a material contains clues to processes inside the samples from a variety of origins. The technique is of special interest and well suited for biological specimens, because their light matrix minimizes restricting absorption effects. Measurement examples of a hornet and the teeth of a Sorex araneus are shown. KW - SR-microXRF KW - 3D KW - CXC PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-324330 DO - https://doi.org/10.1039/c4ja00085d SN - 0267-9477 SN - 1364-5544 VL - 29 IS - 8 SP - 1339 EP - 1344 PB - Royal Society of Chemistry CY - London AN - OPUS4-32433 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hachmöller, O. A1 - de Oliveira Guilherme Buzanich, Ana A1 - Aichler, M. A1 - Radtke, Martin A1 - Dietrich, D. A1 - Schwamborn, K. A1 - Lutz, L. A1 - Werner, M. A1 - Sperling, M. A1 - Walch, A. A1 - Karst, U. T1 - Elemental bioimaging and speciation analysis for the investigation of Wilsons disease using μXRF and XANES N2 - A liver biopsy specimen from a Wilson’s disease (WD) patient was analyzed by means of micro-X-ray fluorescence (mXRF) spectroscopy to determine the elemental distribution. First, bench-top mXRF was utilized for a coarse scan of the sample under laboratory conditions. The resulting distribution maps of copper and iron enabled the determination of a region of interest (ROI) for further analysis. In order to obtain more detailed elemental information, this ROI was analyzed by synchrotron radiation (SR)-based mXRF with a beam size of 4 mm offering a resolution at the cellular level. Distribution maps of additional elements to copper and iron like zinc and manganese were obtained due to a higher sensitivity of SR-mXRF. In addition to this, X-ray absorption near edge structure spectroscopy (XANES) was performed to identify the oxidation states of copper in WD. This speciation analysis indicated a mixture of copper(I) and copper(II) within the WD liver tissue. KW - progressive hepatolenticular degeneration KW - mXRF Micro-X-ray fluorescence spectroscopy KW - XANES X-ray absorption near edge structure spectroscopy PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-360811 DO - https://doi.org/10.1039/C6MT00001K SN - 1756-5901 SN - 1756-591X PB - Royal Society of Chemistry CY - Cambridge AN - OPUS4-36081 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - de O. Primo, J. A1 - Horsth, D.F. A1 - de S. Correa, J. A1 - Das, A. A1 - Bittencourt, C. A1 - Umek, P. A1 - de Oliveira Guilherme Buzanich, Ana A1 - Radtke, Martin A1 - Yusenko, Kirill A1 - Zanetta, C. A1 - Anaissi, F.J. T1 - Synthesis and Characterization of Ag/ZnO Nanoparticles for Bacteria Disinfection in Water N2 - n this study, two green synthesis routes were used for the synthesis of Ag/ZnO nanoparticles, using cassava starch as a simple and low-cost effective fuel and Aloe vera as a reducing and stabilizing agent. The Ag/ZnO nanoparticles were characterized and used for bacterial dis- infection of lake water contaminated with Escherichia coli (E. coli). Characterization indicated the formation of a face-centered cubic structure of metallic silver nanoparticles with no insertion of Ag into the ZnO hexagonal wurtzite structure. Physicochemical and bacteriological analyses described in “Standard Methods for the Examination of Water and Wastewater” were used to evaluate the efficiency of the treatment. In comparison to pure ZnO, the synthesized Ag/ZnO nanoparticles showed high efficiencies against Escherichia coli (E. coli) and general coliforms present in the lake water. These pathogens were absent after treatment using Ag/ZnO nanoparticles. The results indicate that Ag/ZnO nanoparticles synthesized via green chemistry are a promising candidate for the treatment of wastewaters contaminated by bacteria, due to their facile preparation, low-cost synthesis,and disinfection efficiency. KW - Synchrotron KW - BAMline PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-562440 DO - https://doi.org/10.3390/nano12101764 SN - 2079-4991 VL - 12 IS - 10 SP - 1 EP - 18 PB - MDPI CY - Basel AN - OPUS4-56244 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bernges, T. A1 - Hanus, R. A1 - Wankmiller, B. A1 - Imasato, K. A1 - Lin, S. A1 - Ghidiu, M. A1 - Gerlitz, M. A1 - Peterlechner, M. A1 - Graham, S. A1 - Hautier, G. A1 - Pei, Y. A1 - Hansen, M. R. A1 - Wilde, G. A1 - Snyder, G. J. A1 - George, Janine A1 - Agne, M T. A1 - Zeier, W. G. T1 - Considering the Role of Ion Transport in Diffuson-Dominated Thermal Conductivity N2 - Next-generation thermal management requires the development of low lattice thermal conductivity materials, as observed in ionic conductors. For example, thermoelectric efficiency is increased when thermal conductivity is decreased. Detrimentally, high ionic conductivity leads to thermoelectric device degradation. Battery safety and design also require an understanding of thermal transport in ionic conductors. Ion mobility, structural complexity, and anharmonicity have been used to explain the thermal transport properties of ionic conductors. However, thermal and ionic transport are rarely discussed in direct comparison. Herein, the ionic conductivity of Ag+ argyrodites is found to change by orders of magnitude without altering the thermal conductivity. Thermal conductivity measurements and two-channel lattice dynamics modeling reveal that the majority of Ag+ vibrations have a non-propagating diffuson-like character, similar to amorphous materials. It is found that high ionic mobility is not a requirement for diffuson-mediated transport. Instead, the same bonding and structural traits that can lead to fast ionic conduction also lead to diffuson-mediated transport. Bridging the fields of solid-state ionics and thermal transport, it is proposed that a vibrational perspective can lead to new design strategies for functional ionic conducting materials. As a first step, the authors relate the so-called Meyer-Neldel behavior in ionic conductors to phonon occupations. KW - Diffusons KW - DFT KW - Phonons KW - Thermoelectrics PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-547140 DO - https://doi.org/10.1002/aenm.202200717 SN - 1614-6832 VL - 12 IS - 22 SP - 1 EP - 13 PB - Wiley VHC-Verlag AN - OPUS4-54714 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Margreiter, R. A1 - Baumann, J. A1 - Mantouvalou, I. A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Strub, E. T1 - Investigations on fire-gilding N2 - Fire-gilding is a historic technique for the application of golden layers on a number of different base materials utilizing a gold amalgam. This technique leaves a significant amount of Hg in the golden layer, giving archeometrists a reliable indicator to identify firegildings. Recent findings on presumably fire-gilded objects have shown in several cases significantly lower Hg content than previously studied objects. This prompted a synchrotron-based X-ray fluorescence investigation into the Hg distribution along the material–gilding interface, as well as a series of measurements regarding the Hg content development in fire-gilded samples during artificial aging. This work presents findings on laboratory-prepared fire-gildings, indicating an Hg enrichment at the interface of firegilded silver samples. Notably, such an enrichment is missing in fire-gilded copper samples. Further, it is confirmed that fire-gilded layers typically do not undercut an Hg bulk content of 5%. In this light, it seems improbable that ancient samples that contain <5% Hg are fire-gilded. The results presented in this study might lead to a non-destructive method to identify the Hg enrichment at the interface. This might be obtained by a combination of different non-destructive measurements and might also work unambiguously in samples in which the gold top layer is altered. KW - BAMline KW - X-Ray Fluorescence KW - Gilding KW - Depth profile KW - Archaeometry PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-552885 DO - https://doi.org/10.1111/arcm.12797 SN - 0003-813X SP - 1 EP - 14 PB - Wiley online library AN - OPUS4-55288 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - de Oliveira Guilherme Buzanich, Ana A1 - Cakir, Cafer Tufan A1 - Radtke, Martin A1 - Haider, M. Bilal A1 - Emmerling, Franziska A1 - F. M. Oliveira, P. A1 - Michalchuk, Adam A. L. T1 - Dispersive x-ray absorption spectroscopy for time-resolved in situ monitoring of mechanochemical reactions N2 - X-ray absorption spectroscopy (XAS) provides a unique, atom-specific tool to probe the electronic structure of solids. By surmounting long-held limitations of powder-based XAS using a dynamically averaged powder in a Resonant Acoustic Mixer (RAM), we demonstrate how time-resolved in situ (TRIS) XAS provides unprecedented detail of mechanochemical synthesis. The use of a custom-designed dispersive XAS (DXAS) setup allows us to increase the time resolution over existing fluorescence measurements from ∼15 min to 2 s for a complete absorption spectrum. Hence, we here establish TRIS-XAS as a viable method for studying mechanochemical reactions and sampling reaction kinetics. The generality of our approach is demonstrated through RAM-induced (i) bottom-up Au nanoparticle mechanosynthesis and (ii) the synthesis of a prototypical metal organic framework, ZIF-8. Moreover, we demonstrate that our approach also works with the addition of a stainless steel milling ball, opening the door to using TRIS-DXAS for following conventional ball milling reactions. We expect that our TRIS-DXAS approach will become an essential part of the mechanochemical tool box. KW - In situ studies KW - Dipsersive XAS KW - Mechanochemistry KW - Time-resolved PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-567659 DO - https://doi.org/10.1063/5.0130673 SN - 1089-7690 VL - 157 IS - 21 SP - 1 EP - 12 PB - American Institute of Physics CY - Melville, NY AN - OPUS4-56765 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lecompagnon, Julien A1 - Ahmadi, Samim A1 - Hirsch, Philipp Daniel A1 - Rupprecht, C. A1 - Ziegler, Mathias T1 - Thermographic detection of internal defects using 2D photothermal super resolution reconstruction with sequential laser heating N2 - Thermographic photothermal super resolution reconstruction enables the resolution of internal defects/inhomogeneities below the classical limit, which is governed by the diffusion properties of thermal wave propagation. Based on a combination of the application of special sampling strategies and a subsequent numerical optimization step in post-processing, thermographic super resolution has already proven to be superior to standard thermographic methods in the detection of one-dimensional defect/inhomogeneity structures. In our work, we report an extension of the capabilities of the method for efficient detection and resolution of defect cross sections with fully two-dimensional structured laser-based heating. The reconstruction is carried out using one of two different algorithms that are proposed within this work. Both algorithms utilize the combination of several coherent measurements using convex optimization and exploit the sparse nature of defects/inhomogeneities as is typical for most nondestructive testing scenarios. Finally, the performance of each algorithm is rated on reconstruction quality and algorithmic complexity. The presented experimental approach is based on repeated spatially structured heating by a high power laser. As a result, a two-dimensional sparse defect/inhomogeneity map can be obtained. In addition, the obtained results are compared with those of conventional thermographic inspection methods that make use of homogeneous illumination. Due to the sparse nature of the reconstructed defect/inhomogeneity map, this comparison is performed qualitatively. KW - Thermography KW - Super resolution KW - NDT KW - Inspection KW - Internal defects PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-548351 DO - https://doi.org/10.1063/5.0088102 SN - 1089-7550 VL - 131 IS - 18 SP - 1 EP - 12 PB - AIP Publishing AN - OPUS4-54835 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Iro, M. A1 - Ingerle, D. A1 - Radtke, Martin A1 - de Oliveira Guilherme Buzanich, Ana A1 - Kregsamer, P. A1 - Streli, C. T1 - Investigation of polycapillary half lenses for quantitative confocal micro-X-ray fluorescence analysis N2 - The use of polycapillary optics in confocal micro-X-ray fluorescence analysis (CMXRF) enables the destruction-free 3D investigation of the elemental composition of samples. The energy-dependent transmission properties, concerning intensity and spatial beam propagation of three polycapillary half lenses, which are vital for the quantitative interpretation of such CMXRF measurements, are investigated in a monochromatic confocal laboratory setup at the Atominstitut of TU Wien, and a synchrotron setup on the BAMline beamline at the BESSY II Synchrotron, Helmholtz-Zentrum-Berlin. The empirically established results, concerning the intensity of the transmitted beam, are compared with theoretical values calculated with the polycap software package and a newly presented analytical model for the transmission function. The resulting form of the newly modelled energy-dependent transmission function is shown to be in good agreement with Monte Carlo simulated results for the complete energy regime, as well as the empirically established results for the energy regime between 6 keV and 20 keV. An analysis of possible fabrication errors was conducted via pinhole scans showing only minor fabrication errors in two of the investigated polycapillary optics. The energy-dependent focal spot size of the primary polycapillary was investigated in the laboratory via the channel-wise evaluation of knife-edge scans. Experimental results are compared with data given by the manufacturer as well as geometric estimations for the minimal focal spot size. Again, the resulting measurement points show a trend in agreement with geometrically estimated results and manufacturer data. KW - BAMline KW - Synchrotron KW - Capillary KW - confocal PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-562430 DO - https://doi.org/10.1107/S1600577522009699 SN - 1600-5775 VL - 29 SP - 1376 EP - 1384 PB - International Union of Crystallography CY - Chester AN - OPUS4-56243 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien A1 - Hirsch, Philipp Daniel A1 - Rupprecht, C. A1 - Ziegler, Mathias T1 - Hochaufgelöste thermografische Detektion eingeschlossener Defekte mit Hilfe von 2Dstrukturierten Beleuchtungsmustern N2 - Für die aktive Thermografie als zerstörungsfreie Prüfmethode galt lange Zeit die Faustformel, dass die Auflösung interner Defekte/Inhomogenitäten auf ein Verhältnis von Defekttiefe/Defektgröße ≤ 1 beschränkt ist. Die Ursache hierfür liegt in der diffusiven Natur der Wärmeleitung in Festkörpern. Sogenannte Super-Resolution-Ansätze erlauben seit Kurzem die Überwindung dieser physikalischen Grenze um ein Vielfaches. Damit ergibt sich die attraktive Möglichkeit die Thermografie von einem rein oberflächensensitiven Prüfverfahren hin zu einem Verfahren mit verbesserter Tiefenreichweite zu entwickeln. Wie weit diese Entwicklung getrieben werden kann, ist Gegenstand aktueller Forschung. Wir konnten bereits zeigen, dass diese klassische Grenze für 1D- und 2D Defektgeometrien mit Hilfe des Abscannens des Prüfkörpers mittels einzelner Laserspots und der anschließenden Anwendung von photothermischer Super-Resolution-Rekonstruktion überwunden werden kann. Bei dieser Methode wird eine Kombination aus sequenzieller räumlich strukturierter Beleuchtung und numerischen Optimierungsmethoden eingesetzt. Dies geschieht allerdings auf Kosten der experimentellen Komplexität, die zu einer langen Messdauer, großen Datensätzen und langwieriger numerischer Auswertung führt. In dieser Arbeit berichten wir über einen neuen experimentellen Ansatz, bei dem räumlich strukturierte 2D-Beleuchtungsmuster in Verbindung mit Compressed-Sensing und Computational-Imaging-Methoden verwendet werden, um die experimentelle Komplexität deutlich zu verringern und die Methode für die Untersuchung größerer Prüfflächen nutzbar zu machen. Der experimentelle Ansatz basiert dabei auf der wiederholten (blinden) photothermischen Anregung mit räumlich strukturierten 2D-Mustern unter Verwendung moderner Projektortechnik und eines Hochleistungslasers. In der anschließenden numerischen Rekonstruktion werden mehrere Messungen unter Ausnutzung der Joint-Sparsity der Defekte innerhalb des Prüfkörpers mittels nichtlinearer konvexer Optimierungsmethoden kombiniert. Als Ergebnis kann eine 2D-sparse Defekt-/Inhomogenitätskarte erstellt werden. T2 - DGZfP-Jahrestagung 2022 CY - Kassel, Germany DA - 23.05.2022 KW - Thermografie KW - Super resolution KW - NDT KW - ZfP KW - Eingeschlossene Defekte KW - Projektor PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-548945 SN - 978-3-947971-25-1 VL - 177 SP - 1 EP - 16 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung AN - OPUS4-54894 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bandow, Nicole A1 - Simon, Franz-Georg T1 - Significance of cadmium from artists' paints to agricultural soils and the food chain N2 - Background: An Annex XV restriction dossier for cadmium in artists’ paints was submitted by an EU member state to the European Chemicals Agency ECHA. By cleaning used brushes under the tap cadmium can enter the food chain via waste water treatment and subsequent agricultural application of the sewage sludge. It was estimated that 110 kg Cd per year is spread on agricultural land via this exposure route. Other sources of Cd amount to almost 120 tons per year. Results: The mobility of Cd from pigments was studied in a field-like scenario by leaching experiments using soil samples amended with sewage sludge and spiked with Cd pigments in percolation columns. The redox conditions were confirmed to be the decisive factor for the release of Cd. The release of Cd from artists’ paints was in most cases 1% or lower in the experiments performed. Conclusions: Application of sewage sludge containing Cd from artist paints does not increase the amount of Cd leached from this soils. Furthermore the quantity of Cd from artists’ paints calculated in the restriction dossier is negligible compared to other sources of Cd to agricultural soil. Therefore ECHA did not consider the proposed restriction to be the most appropriate EU wide measure to address the negligible level of risk. KW - REACH regulation KW - Sewage sludge KW - Fertilizer KW - Leaching test PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-358261 DO - https://doi.org/10.1186/s12302-016-0077-6 SN - 2190-4715 VL - 28 IS - 12 SP - 1 EP - 10 AN - OPUS4-35826 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlichting, S. A1 - Hönig, Gerald A1 - Müßener, J. A1 - Hille, P. A1 - Grieb, T. A1 - Westerkamp, S. A1 - Teubert, J. A1 - Schörmann, J. A1 - Wagner, M.R. A1 - Rosenauer, A. A1 - Eickhoff, M. A1 - Hoffmann, A. A1 - Callsen, G. T1 - Suppression of the quantum-confined Stark effect in polar nitride heterostructures N2 - Recently, we suggested an unconventional approach (the so-called Internal-Field-Guarded-Active-Region Design “IFGARD”) for the elimination of the quantum-confined Stark effect in polar semiconductor heterostructures. The IFGARD-based suppression of the Stark redshift on the order of electronvolt and spatial charge carrier separation is independent of the specific polar semiconductor material or the related growth procedures. In this work, we demonstrate by means of micro-photoluminescence techniques the successful tuning as well as the elimination of the quantum-confined Stark effect in strongly polar [000-1] wurtzite GaN/AlN nanodiscs as evidenced by a reduction of the exciton lifetimes by up to four orders of magnitude. Furthermore, the tapered geometry of the utilized nanowires (which embed the investigated IFGARD nanodiscs) facilitates the experimental differentiation between quantum confinement and Stark emission energy shifts. Due to the IFGARD, both effects become independently adaptable. KW - Nanophotonics KW - Photonic devices KW - Single photon and quantum effects PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-457884 DO - https://doi.org/10.1038/s42005-018-0044-1 SN - 2399-3650 VL - 1 SP - 1 EP - 8 PB - Springer Nature CY - London AN - OPUS4-45788 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Peters, Stefan A1 - Kunkel, Benny A1 - Cakir, Cafer Tufan A1 - Kabelitz, Anke A1 - Witte, Steffen A1 - Bernstein, Thomas A1 - Bartling, Stephan A1 - Radtke, Martin A1 - Emmerling, Franziska A1 - Abdel-Mageed, Ali Mohamed A1 - Wohlrab, Sebastian A1 - Guilherme Buzanich, Ana T1 - Time-, space- and energy-resolved in situ characterization of catalysts by X-ray absorption spectroscopy N2 - A novel setup for dispersive X-ray absorption spectroscopy (XAS) with simultaneous resolution of space, time and energy for in situ characterization of solid materials is demonstrated. KW - Dispersive XAS KW - Catalysis KW - In situ KW - Structure analysis PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-584924 DO - https://doi.org/10.1039/d3cc03277a SN - 1359-7345 SP - 1 EP - 4 PB - Royal Society of Chemistry (RSC) AN - OPUS4-58492 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - George, Janine A1 - Petretto, G. A1 - Naik, Aakash Ashok A1 - Esters, M. A1 - Jackson, A. J. A1 - Nelson, R. A1 - Dronskowski, R. A1 - Rignanese, G.-M. A1 - Hautier, G. T1 - Automated bonding analysis with crystal orbital Hamilton populuations N2 - Automated bonding analysis software has been developed based on Crystal Orbital Hamilton Populations to facilitate high-throughput bonding analysis and machine-learning of bonding features. This work presents the software and discusses its applications to simple and complex materials such as GaN, NaCl, the oxynitrides XTaO2N (X=Ca, Ba, Sr) and Yb14Mn1Sb11. KW - Chemical bonds KW - Automation KW - High-throughput PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-551641 DO - https://doi.org/10.1002/cplu.202200123 SN - 2192-6506 SP - 1 EP - 11 PB - Wiley-VCH CY - Weinheim AN - OPUS4-55164 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maierhofer, Christiane A1 - Röllig, Mathias A1 - Steinfurth, Henrik A1 - Ziegler, Mathias A1 - Heck, S.J. A1 - Scheuerlein, C. T1 - Aktive Thermografie zur zerstörungsfreien Prüfung von Lötverbindungen N2 - In diesem Beitrag werden die Möglichkeiten der Ortung von Fehlstellen in Cu Lötverbindungen unterhalb verschiedener Cu Blechdicken mit aktiver Thermografie demonstriert. Dabei wurden die Anregung mit Blitzlicht und die periodische Anregung mit der Lock-In Technik miteinander verglichen. Die Vor- und Nachteile der Anwendung unterschiedlicher IR-Kamerasysteme, einer gekühlten InSb-Quantendetektor IR-Kamera und einer Mikrobolometer IR-Kamera, werden dargestellt. Als objektives Kriterium wurde das SNR für unterschiedliche Fehlstellengrößen herangezogen. T2 - DGZfP-Jahrestagung 2011 CY - Bremen, Germany DA - 30.05.2011 KW - Aktive Thermografie KW - Blitzlichtanregung KW - Lock-In Anregung KW - Lötverbindung KW - Kupfer PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-249935 SN - 978-3-940283-33-7 IS - DGZfP-BB 127 (Di.1.C.1) SP - 1 EP - 8 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) AN - OPUS4-24993 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ziegler, Mathias A1 - Thiel, Erik A1 - Studemund, Taarna T1 - Laser-Thermografie – Von der flächigen zur strukturierten Anregung N2 - Im Bereich der optisch angeregten Thermografie haben sich Blitzlampen (impulsförmig-flächige Erwärmung) und Halogenlampen (moduliert-flächige Erwärmung) für die spezifischen Regime Impuls- und Lockin-Thermografie etabliert. Mittels eines rasternden fokussierten Lasers wird die Flying-spot Laserthermografie z.B. zur Risserkennung (Dauerstrichbetrieb) und die photothermische Materialcharakterisierung (hochfrequent moduliert)implementiert. Durch die Verfügbarkeit neuer Technologien (schnelle und hochauflösende IR-Kameras, brillante innovativer Lichtquellen und performante Datenakquisitions- und Verarbeitungstechnik) wird ein Paradigmenwechsel von den getrennt voneinander stehenden photothermischen und thermografischen Techniken hin zu einer einheitlichen quantitativen Mess-und Prüftechnik ermöglicht, die schneller und präziser ist. Ähnlich wie ein LED-Array, jedoch mit einer um zwei Größenordnungen höheren Bestrahlungsstärke, steht jetzt eine neuartige brillante Laserquelle, das VCSEL-Array (vertical-cavity surface-emitting laser) zur Verfügung, welches die starke Beschränkung der zeitlichen Dynamik der etablierten Lichtquellen aufhebt und gleichzeitig spektral sauber von der Detektionswellenlänge getrennt ist. Es vereint somit das schnelle zeitliche Verhalten eines Diodenlasers mit der hohen optischen Bestrahlungsstärke und dem großen Beleuchtungsbereich von Blitzlampen. Darüber hinaus kann die Erwärmung auch strukturiert vorgenommen werden, da einzelne Bereiche des VCSEL-Arrays unabhängig voneinander angesteuert werden können. Dieser neue Freiheitsgrad ermöglicht die Entwicklung ganz neuer thermografischer ZfP-Verfahren. T2 - Thermographie-Kolloquium 2017 CY - Berlin, Germany DA - 28.09.2017 KW - Thermografie KW - Laser KW - Zerstörungsfreie Prüfung KW - Lock-in KW - VCSEL KW - Photothermisch PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-431170 UR - https://www.dgzfp.de/Portals/thermo2017/BB/6.pdf SN - 978-3-940283-88-7 VL - 163 SP - 1 EP - 15 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) CY - Berlin AN - OPUS4-43117 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Puthiyaveettil, N. A1 - Kidangan, R. A1 - Unnikrishnakurup, Sreedhar A1 - Krishnamurthy, C. V. A1 - Ziegler, Mathias A1 - Myrach, Philipp A1 - Balasubramaniam, K. T1 - Numerical study of laser line thermography for crack detection at high temperature N2 - The detection of cracks before the failure is highly significant when it comes to safety-relevant structures. Crack detection in metallic samples at high surface temperature is one of the challenging situation in manufacturing industries. Laser thermography has already proved its detection capability of surface cracks in metallic samples at room temperature. In this work a continuous wave (CW) laser use to generate a laser, which is using to scan the metal surface with notch. The corresponding heat distribution on the surface monitored using infrared thermal (IR) camera. A simplified 3D model for laser thermography is developed and validated with experimental results. A dedicated image processing algorithm developed to improve the detectability of the cracks. To understand the dependency of surface temperature, laser power, laser scanning speed etc. in defect detection, we carried out parametric studies with our validated model. Here we Report the capability of laser thermography in crack detection at elevated temperature. T2 - 14th Quantitative InfraRed Thermography Conference CY - Berlin, Germany DA - 25.06.2018 KW - Thermal contrast KW - Laser Thermography KW - FEM KW - Surface cracks KW - NDT PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-499113 DO - https://doi.org/10.21611/qirt.2018.076 SN - 2371-4085 VL - 2018 SP - 685 EP - 686 AN - OPUS4-49911 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lapenna, Michela A1 - Tsamos, Athanasios A1 - Faglioni, Francesco A1 - Fioresi, Rita A1 - Zanchetta, Ferdinando A1 - Bruno, Giovanni T1 - Geometric deep learning for enhanced quantitative analysis of microstructures in X-ray computed tomography data N2 - Quantitative microstructural analysis of XCT 3D images is key for quality assurance of materials and components. In this paper we implement a Graph Convolutional Neural Network (GCNN) architecture to segment a complex Al-Si Metal Matrix composite XCT volume (3D image). We train the model on a synthetic dataset and we assess its performance on both synthetic and experimental, manually-labeled, datasets. Our simple GCNN shows a comparable performance, measured via the Dice score, to more standard machine learning methods, but uses a greatly reduced number of parameters (less than 1/10 of parameters), features low training time, and needs little hardware resources. Our GCNN thus achieves a cost-effective reliable segmentation. KW - Geometric deep learning KW - Segmentation KW - Microstructure KW - X-ray computed tomography KW - Al–Si metal matrix composites PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-602517 DO - https://doi.org/10.1007/s42452-024-05985-0 SN - 3004-9261 VL - 6 IS - 6 SP - 1 EP - 9 AN - OPUS4-60251 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Pittner, Andreas A1 - Fabry, Çağtay T1 - Abschlussbericht IGF 17.923 N: "Sensorgestütztes MSG-Engspaltschweißen von Feinkornstählen mit modifizierter Prozessführung im Dickblechbereich" N2 - Die im Forschungsvorhaben erzielten Ergebnisse zeigen konkrete technische Lösungen für die automatisierte Anwendung des MSG Engspaltschweißen, sowohl mittels optischer als auch prozessorientierter Sensorik, und sprechen damit ein breites Spektrum möglicher Anwender, insbesondere KMU, an. Die Seitenführung des Brenners auf Basis der optischen Messgrößen stellt eine robuste und einfach zu implementierende Möglichkeit zur Nahtverfolgung dar. Für die Höhenführung über der Schweißnaht wurde neben der Lösung mittels optischer Messverfahren zusätzlich eine direkt darauf aufbauende Möglichkeit zur Implementierung eines Lichtbogensensors abgeleitet. Das Vorgehen konnte sowohl für Sprühlichtbogenprozesse als auch bei Verwendung von Impulslichtbogenprozessen erfolgreich angewendet werden. Die zur Sicherstellung eines gleichmäßigen Flankeneinbrandes entwickelte Pendelregelung ist ebenfalls für unterschiedliche Lichtbogenarten einsetzbar und muss vom Anwender auch beim Einsatz einer großen Bandbreite unterschiedlicher Prozessparameter nahezu nicht konfiguriert werden. Neben der im Rahmen der Verfahrensprüfung untersuchten Pendelraupentechnik konnte die Übertragbarkeit des Vorgehens auch auf die Strichraupentechnik anhand von gezielten Schweißversuchen aufgezeigt werden. Die zunächst auf Basis der optischen Messwerte ausgelegte Füllgradregelung konnte die vorgesehenen Spaltvariationen von 18 bis 24 mm im Rahmen der durchgeführten Verfahrensprüfung ausgleichen. Die Ableitung eines äquivalenten Lichtbogensensors durch Kopplung beider Messprinzipien wurde am Laufzeitende des Vorhabens aufgezeigt, konnte jedoch durch zeitliche Beschränkung nicht für die Verfahrensprüfung berücksichtigt werden. In Absprache mit dem projektbegleitenden Ausschuss wurde die Entwicklung der Prozessregelung für das Vorhaben auf Schweißungen in Wannenlage und Grundwerkstoffe der Güte S355J2 beschränkt. Die Qualifizierung des Verfahrens unter Einsatz der beschriebenen Regelalgorithmen nach DIN EN ISO 15614-1 konnte für alle betrachteten Spaltbreiten zwischen 18 und 24 mm anhand einer 50 mm dicken Demonstratorprobe nachgewiesen werden. KW - Schutzgasschweißen KW - MSG-Engspaltschweißen KW - Prozesssteuerung KW - Lichtbogensensorik KW - Prozessregelung KW - GMAW KW - Narrow gap GMAW KW - GMAW control KW - Arc-sensing PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-390934 SP - 1 EP - 38 AN - OPUS4-39093 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Fabry, Çağtay A1 - Pittner, Andreas A1 - Hirthammer, Volker A1 - Rethmeier, Michael T1 - Recommendations for an Open Science approach to welding process research data N2 - The increasing adoption of Open Science principles has been a prevalent topic in the welding science community over the last years. Providing access to welding knowledge in the form of complex and complete datasets in addition to peer-reviewed publications can be identified as an important step to promote knowledge exchange and cooperation. There exist previous efforts on building data models specifically for fusion welding applications; however, a common agreed upon implementation that is used by the community is still lacking. One proven approach in other domains has been the use of an openly accessible and agreed upon file and data format used for archiving and sharing domain knowledge in the form of experimental data. Going into a similar direction, the welding community faces particular practical, technical, and also ideological challenges that are discussed in this paper. Collaboratively building upon previous work with modern tools and platforms, the authors motivate, propose, and outline the use of a common file format specifically tailored to the needs of the welding research community as a complement to other already established Open Science practices. Successfully establishing a culture of openly accessible research data has the potential to significantly stimulate progress in welding research. KW - Welding KW - Research data management KW - Open science KW - Digitalization KW - Weldx KW - Open source PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-529332 DO - https://doi.org/10.1007/s40194-021-01151-x SN - 1878-6669 SN - 0043-2288 SP - 1 EP - 9 PB - Springer CY - Heidelberg AN - OPUS4-52933 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tatzel, Michael A1 - Oelze, Marcus A1 - Frick, Daniel A. A1 - Di Rocco, Tommaso A1 - Liesegang, Moritz A1 - Stuff, Maria A1 - Wiedenbeck, Michael T1 - Silicon and oxygen isotope fractionation in a silicified carbonate rock N2 - Silicon isotope fractionation during silicification is poorly understood and impedes our ability to decipher paleoenvironmental conditions from Si isotopes in ancient cherts. To investigate isotope fractionation during silica-for-carbonate replacement we analyzed the microscale Si and O isotope composition in different silica phases in a silicified zebra dolostone as well as their bulk δ18O and Δ’17O compositions. The subsequent replacement of carbonate layers is mimicked by decreasing δ18O and δ30Si. The textural relationship and magnitude of Si and O isotope fractionation is best explained by near-quantitative silica precipitation in an open system with finite Si. A Rayleigh model for silicification suggests positive Ɛ30/28Si during silicification, conforming with predictions for isotope distribution at chemical equilibrium from ab-initio models. Application of the modelled Ɛ30Si-T relationship yields silicification temperatures of approx. 50°C. To reconcile the δ18Ochert composition with these temperatures, the δ18O of the fluid must have been between -2.5 and -4 ‰, compositions for which the quartz phases fall close to the oxygen equilibrium fractionation line in three-isotope space. Diagenetic silica replacement appears to occur in O and Si isotopic equilibrium allowing reconstructions of temperatures of silicification from Si isotopes and derive the δ18O composition of the fluid – a highly desired value needed for accurate reconstructions of the temperature- and δ18O histories of the oceans. KW - Silicon isotopes PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-603430 DO - https://doi.org/10.1016/j.chemgeo.2024.122120 SN - 0009-2541 VL - 658 SP - 1 EP - 13 PB - Elsevier B.V. AN - OPUS4-60343 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Häßler, Dustin A1 - Mund, Maximilian A1 - Daus, Lars-Hendrik A1 - Hothan, Sascha A1 - Schaumann, Peter A1 - Schartel, Bernhard T1 - Durability of intumescent coatings and recommendations for test concepts for a working life of more than 10 years N2 - It is an essential requirement for all building products to ensure durability of their fire safety. Throughout the working life of products, intumescent coatings are aged by certain climatic factors. To predict a lifetime of several years, generally the behaviour of the intumescent coating is extrapolated based on accelerated artificial ageing. The established German and European procedures to assess the durability assume a working life of at least 10 years. For a longer period, additional evidence is required; yet the procedure and the specifications to justify this are not described. In addition to addressing this formal lack, from a scientific point of view it is necessary to investigate the degradation of intumescent coatings in detail and to propose a reliable test concept to assess durability for more than 10 years. This paper summarises the existing knowledge about the ageing of intumescent coatings. The results of various demanding weathering approaches are presented for two intumescent coatings tested in a joint research project. Moreover, formulations with a reduced amount of functionally relevant components were analysed to gain insight into the associated effects. Derived from these research results and knowledge, recommendations are proposed to assess the durability of intumescent coatings for more than 10 years based on a combination of verifications. KW - Ageing KW - Fire protection KW - Intumescent coating KW - Steel construction KW - Working life PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-603852 DO - https://doi.org/10.1016/j.firesaf.2024.104173 SN - 0379-7112 VL - 146 SP - 1 EP - 10 PB - Elsevier B.V. AN - OPUS4-60385 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schuberth, Jens A1 - Ebert, Thomas A1 - Schlegel, Moritz-Caspar A1 - Rödig, Lisa A1 - Jepsen, Dirk A1 - Memelink, Robin A1 - Hauschke, Fynn T1 - The Front-Runner Approach - Facilitating Progressive Product Policy by Using Information from EU Product Databases N2 - The European Commission has recently announced two guiding principles for EU product policy: First, product policy shall ensure that the performance of front-runner products in terms of sustainability becomes the norm, and second, the effectiveness of the current Ecodesign legislative framework is going to be significantly improved. Within this paper, already existing front-runner approaches and recent and ongoing product policy-making processes were reviewed. Based on the results, an EU front-runner approach is outlined. The presented approach (i) refers to performance levels of the best products already available on the market, (ii) aggregates information in existing databases, and (iii) works semi-automated. Together, all three attributes have a high potential to facilitate and accelerate the specification of appropriate minimum requirements for products at the EU level. This way, EU policymakers can deliver on the core objectives of the Ecodesign legislative framework much better. The basic mechanism and its legal entrenchment of the approach are illustrated for the energy efficiency of energy-related products. In addition, the Front-Runner Approach can be applied to any product group in the scope of the upcoming Ecodesign for Sustainable Products Regulation and to a wide range of product-related minimum requirements, such as durability, reparability, or recycled content. The study’s objective is to suggest a tailor-made and dynamic approach to keep the EU product legislation up to date using innovative technology based on the investigation of current regulations and identify the gap. Experiences from three international case studies suggest that a front-runner approach to setting energy-performance standards can drive innovation and reduce energy consumption via promoting energy-efficient products; transparency about available products is one of the key factors and can be established by a database. The EU front-runner approach comprises extending the existing energy label database (or making use of the digital product passport) and introducing a legislative procedure that triggers changes in the energy efficiency requirements in the specific EU regulations if the database shows that a certain threshold value is reached. Challenges such as limited EU staff capacities and opportunities such as increased dynamic are discussed. KW - Ecodesign KW - ESPR KW - Energy labelling KW - EPREL KW - Policy making KW - Front-runner KW - Material efficiency KW - Resource efficiency KW - Energy efficiency PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595132 DO - https://doi.org/10.3390/en17020504 VL - 17 IS - 2 SP - 1 EP - 11 PB - MDPI AN - OPUS4-59513 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Guerra, M.F. A1 - Martinón-Torres, M. A1 - Lemasson, Q. A1 - Moignard, B. A1 - Pacheco, C. A1 - Pichon, L. A1 - Macdonald, L. A1 - Hess, M. A1 - Tissot, I. ED - Guerra, M. F. ED - Martinón-Torres, M. ED - Quirke, S. T1 - Analytical approaches to Egyptian goldwork N2 - The structure and composition of ancient gold objects retain information about their long history of manufacture, from the exploitation of the ore to the finishing touches, as well as evidence of their use, deposition, and degradation. By developing an efficient analytical strategy, it is possible to retrieve that information. This chapter sets the necessary foundation 131to explore fully the analytical results presented in the following chapters of this volume. The techniques employed in the analyses of the Egyptian jewellery are described and the analytical parameters provided. For more established techniques, only brief introductions are presented, while more recent developments are presented in greater detail. KW - Gold KW - Synchrotron KW - D2XRF KW - Egypt PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-586039 DO - https://doi.org/10.17863/CAM.99681 SP - 131 EP - 191 AN - OPUS4-58603 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Naik, Aakash A1 - Ertural, Christina A1 - Dhamrait, Nidal A1 - Benner, Philipp A1 - George, Janine T1 - A Quantum-Chemical Bonding Database for Solid-State Materials N2 - An in-depth insight into the chemistry and nature of the individual chemical bonds is essential for understanding materials. Bonding analysis is thus expected to provide important features for large-scale data analysis and machine learning of material properties. Such chemical bonding information can be computed using the LOBSTER software package, which post-processes modern density functional theory data by projecting the plane wave-based wave functions onto an atomic orbital basis. With the help of a fully automatic workflow, the VASP and LOBSTER software packages are used to generate the data. We then perform bonding analyses on 1520 compounds (insulators and semiconductors) and provide the results as a database. The projected densities of states and bonding indicators are benchmarked on standard density-functional theory computations and available heuristics, respectively. Lastly, we illustrate the predictive power of bonding descriptors by constructing a machine learning model for phononic properties, which shows an increase in prediction accuracies by 27% (mean absolute errors) compared to a benchmark model differing only by not relying on any quantum-chemical bonding features. KW - Bonding Analysis KW - DFT KW - High-throughput KW - Database KW - Phonons KW - Machine Learning PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-582892 DO - https://doi.org/10.1038/s41597-023-02477-5 VL - 10 IS - 1 SP - 1 EP - 18 AN - OPUS4-58289 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Naik, Aakash Ashok A1 - Ueltzen, Katharina A1 - Ertural, Christina A1 - Jackson, Adam J. A1 - George, Janine T1 - LobsterPy: A package to automatically analyze LOBSTERruns N2 - The LOBSTER (Deringer et al., 2011;Maintz et al., 2013 ,2016 ;Nelson et al., 2020 ) software aids in extracting quantum-chemical bonding information from materials by projecting the plane-wave based wave functions from density functional theory (DFT) onto an atomic orbital basis. LobsterEnv, a module implemented in pymatgen (Ong et al., 2013) by some of the authors of this package, facilitates the use of quantum-chemical bonding information obtained from LOBSTER calculations to identify neighbors and coordination environments. LobsterPy is a Python package that offers a set of convenient tools to further analyze and summarize the LobsterEnv outputs in the form of JSONs that are easy to interpret and process. These tools enable the estimation of (anti) bonding contributions, generation of textual descriptions, and visualization of LOBSTER computation results. Since its first release, both LobsterPy and LobsterEnv capabilities have been extended significantly. Unlike earlier versions, which could only automatically analyze Crystal Orbital Hamilton Populations (COHPs) (Dronskowski & Blöchl, 1993), both can now also analyze Crystal Orbital Overlap Populations (COOP) (Hughbanks & Hoffmann, 1983) and Crystal Orbital Bond Index (COBI) (Müller et al., 2021). Extracting the information about the most important orbitals contributing to the bonds is optional, and users can enable it as needed. Additionally, bonding-based features for machinelearning (ML) studies can be engineered via the sub-packages “featurize” and “structuregraphs”. Alongside its Python interface, it also provides an easy-to-use command line interface (CLI) that runs automatic analysis of the computations and generates a summary of results and publication-ready figures. LobsterPy has been used to produce the results in Ngo et al. (2023), Chen et al. (2024), Naik et al. (2023), and it is also part of Atomate2 (2023) bonding analysis workflow for generating bonding analysis data in a format compatible with the Materials Project (Jain et al., 2013) API. KW - Materials Science KW - Automation KW - Bonding Analysis KW - Materials Properties PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595809 DO - https://doi.org/10.21105/joss.06286 VL - 9 IS - 94 SP - 1 EP - 4 PB - The Open Journal AN - OPUS4-59580 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rosen, Andrew S. A1 - Gallant, Max A1 - George, Janine A1 - Riebesell, Janosh A1 - Sahasrabuddhe, Hrushikesh A1 - Shen, Jimmy-Xuan A1 - Wen, Mingjian A1 - Evans, Matthew L. A1 - Petretto, Guido A1 - Waroquiers, David A1 - Rignanese, Gian-Marco A1 - Persson, Kristin A. A1 - Jain, Anubhav A1 - Ganose, Alex M. T1 - Jobflow: Computational Workflows Made Simple N2 - We present Jobflow, a domain-agnostic Python package for writing computational workflows tailored for high-throughput computing applications. With its simple decorator-based approach, functions and class methods can be transformed into compute jobs that can be stitched together into complex workflows. Jobflow fully supports dynamic workflows where the full acyclic graph of compute jobs is not known until runtime, such as compute jobs that launch other jobs based on the results of previous steps in the workflow. The results of all Jobflow compute jobs can be easily stored in a variety of filesystem- and cloud-based databases without the data storage process being part of the underlying workflow logic itself. Jobflow has been intentionally designed to be fully independent of the choice of workflow manager used to dispatch the calculations on remote computing resources. At the time of writing, Jobflow workflows can be executed either locally or across distributed compute environments via an adapter to the FireWorks package, and Jobflow fully supports the integration of additional workflow execution adapters in the future. KW - Automation KW - Workflow KW - Computational Materials Science KW - Computations KW - Software PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-593104 DO - https://doi.org/10.21105/joss.05995 VL - 9 IS - 93 SP - 1 EP - 7 PB - The Open Journal AN - OPUS4-59310 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lecompagnon, Julien A1 - Hirsch, Philipp Daniel A1 - Rupprecht, C. A1 - Ziegler, Mathias T1 - Nondestructive thermographic detection of internal defects using pixel-pattern based laser excitation and photothermal super resolution reconstruction N2 - In this work, we present a novel approach to photothermal super resolution based thermographic resolution of internal defects using two-dimensional pixel pattern-based active photothermal laser heating in conjunction with subsequent numerical reconstruction to achieve a high-resolution reconstruction of internal defect structures. With the proposed adoption of pixelated patterns generated using laser coupled high-power DLP projector technology the complexity for achieving true two-dimensional super resolution can be dramatically reduced taking a crucial step forward towards widespread practical viability. Furthermore, based on the latest developments in high-power DLP projectors, we present their first application for structured pulsed thermographic inspection of macroscopic metal samples. In addition, a forward solution to the underlying inverse problem is proposed along with an appropriate heuristic to find the regularization parameters necessary for the numerical inversion in a laboratory setting. This allows the generation of synthetic measurement data, opening the door for the application of machine learning based methods for future improvements towards full automation of the method. Finally, the proposed method is experimentally validated and shown to outperform several established conventional thermographic testing techniques while conservatively improving the required measurement times by a factor of 8 compared to currently available photothermal super resolution techniques. KW - Thermography KW - Super resolution KW - NDT KW - Inspection KW - Internal defects KW - DMD KW - DLP PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-570551 DO - https://doi.org/10.1038/s41598-023-30494-2 SN - 2045-2322 VL - 13 SP - 1 EP - 13 PB - Nature Research AN - OPUS4-57055 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien A1 - Hirsch, Philipp Daniel A1 - Rupprecht, C. A1 - Ziegler, Mathias ED - Maldague, X. T1 - Detection of internal defects applying photothermal super resolution reconstruction utilizing two-dimensional high-power random pixel patterns N2 - In this work, we report on our progress for investigating a new experimental approach for thermographic detection of internal defects by performing 2D photothermal super resolution reconstruction. We use modern high-power laser projector technology to repeatedly excite the sample surface photothermally with varying spatially structured 2D pixel patterns. In the subsequent (blind) numerical reconstruction, multiple measurements are combined by exploiting the joint-sparse nature of the defects within the specimen using nonlinear convex optimization methods. As a result, a 2D-sparse defect/inhomogeneity map can be obtained. Using such spatially structured heating combined with compressed sensing and computational imaging methods allows to significantly reduce the experimental complexity and to study larger test surfaces as compared to the one-dimensional approach reported earlier. T2 - Quantitative Infrared Thermography 2022 CY - Paris, France DA - 04.07.2022 KW - Thermography KW - Super resolution KW - NDT KW - inspection KW - Internal defects KW - DMD KW - DLP PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-577795 DO - https://doi.org/10.21611/qirt.2022.1005 SN - 2371-4085 SP - 1 EP - 7 PB - QIRT Council AN - OPUS4-57779 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Smales, Glen Jacob A1 - Pauw, Brian Richard T1 - The MOUSE project - A meticulous approach for obtaining traceable, wide-range X-ray scattering information N2 - Herein, we provide a "systems architecture"-like overview and detailed discussions of the methodological and instrumental components that, together, comprise the "MOUSE" project (Methodology Optimization for UltrafineStructure Exploration). The MOUSE project provides scattering information on a wide variety of samples, with traceable dimensions for both the scattering vector (q) and the absolute scattering cross-section (I). The measurable scattering vector-range of 0.012≤ q (nm-1) ≤ 92, allows information across a hierarchy of structures with dimensions ranging from ca. 0.1 to 400 nm. In addition to details that comprise the MOUSE project, such as the organisation and traceable aspects, several representative examples are provided to demonstrate its flexibility. These include measurements on alumina membranes, the tobacco mosaic virus, and dual-source information that overcomes fluorescence limitations on ZIF-8 and iron-oxide-containing carbon catalyst materials. KW - X-ray scattering KW - MOUSE KW - Instrumentation KW - SAXS KW - Methodology KW - Traceability KW - Wide-range KW - Data curation KW - FAIR KW - Uncertainties KW - Nanomaterials KW - Nanometrology PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-528669 DO - https://doi.org/10.1088/1748-0221/16/06/P06034 VL - 16 IS - 6 SP - 1 EP - 50 PB - IOP CY - Bristol, UK AN - OPUS4-52866 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -