TY - JOUR A1 - Lorenzoni, Renata A1 - Fritsch, Tobias A1 - Kruschwitz, Sabine A1 - Bruno, Giovanni A1 - Schmidt, Wolfram T1 - Mechanical analysis of cement-biochar composites using in-situ X-ray microtomography and digital volume correlation N2 - This study addresses biochar as a potential carbon-sequestering filler in cement and examines its effect on mechanical properties using X-ray computed tomography (XCT) and digital volume correlation (DVC). DVC was reliably used to measure global displacement and has proven to be an effective method for correcting displacement data obtained from mechanical tests conducted without traditional instrumentation, such as extensometer. This made it possible to measure strain and Young’s modulus accurately. The results demonstrate that while 5 vol% biochar replacement had minimal effect on mechanical properties, a 25 vol% biochar replacement caused a 35 % reduction in Young’s modulus and 40 % reduction in the ultimate compressive strength. Additionally, DVC detected strain concentrations and predicted material failure locations even when cracks could not be quantified using XCT alone. Moreover, the study reveals that biochar particles, due to their sharp geometry, increase internal shear strain during uniaxial compression, unlike round phases such as pores. KW - Cementitious materials KW - Biochar KW - Mechanical proprieties KW - In-situ X-ray microtomography KW - Digital volume correlation PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-638065 DO - https://doi.org/10.1016/j.conbuildmat.2025.142511 SN - 1879-0526 VL - 490 PB - Elsevier Ltd. AN - OPUS4-63806 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mechtcherine, Viktor A1 - Muthukrishnan, Shravan A1 - Robens-Radermacher, Annika A1 - Wolfs, Rob A1 - Versteege, Jelle A1 - Menna, Costantino A1 - Ozturk, Onur A1 - Ozyurt, Nilufer A1 - Roupec, Josef A1 - Richter, Christiane A1 - Jungwirth, Jörg A1 - Miranda, Luiza A1 - Ammann, Rebecca A1 - Caron, Jean‑François A1 - de Bono, Victor A1 - Monte, Renate A1 - Navarrete, Iván A1 - Eugenin, Claudia A1 - Lombois‑Burger, Hélène A1 - Baz, Bilal A1 - Sinka, Maris A1 - Sapata, Alise A1 - Harbouz, Ilhame A1 - Zhang, Yamei A1 - Jia, Zijian A1 - Kruger, Jacques A1 - Mostert, Jean‑Pierre A1 - Štefančič, Mateja A1 - Hanžič, Lucija A1 - Kaci, Abdelhak A1 - Rahal, Said A1 - Santhanam, Manu A1 - Bhattacherjee, Shantanu A1 - Snguanyat, Chalermwut A1 - Arunothayan, Arun A1 - Zhao, Zengfeng A1 - Mai, Inka A1 - Rasehorn, Inken Jette A1 - Böhler, David A1 - Freund, Niklas A1 - Lowke, Dirk A1 - Neef, Tobias A1 - Taubert, Markus A1 - Auer, Daniel A1 - Hechtl, C. Maximilian A1 - Dahlenburg, Maximilian A1 - Esposito, Laura A1 - Buswell, Richard A1 - Kolawole, John A1 - Isa, Muhammad Nura A1 - Liu, Xingzi A1 - Wang, Zhendi A1 - Subramaniam, Kolluru A1 - Bos, Freek T1 - Mechanical properties of 3D printed concrete: a RILEM 304-ADC interlaboratory study – compressive strength and modulus of elasticity N2 - Traditional construction techniques, such as in-situ casting and pre-cast concrete methods, have well-established testing protocols for assessing compressive strength and modulus of elasticity, including specific procedures for sample preparation and curing. In contrast, 3D concrete printing currently lacks standardized testing protocols, potentially contributing to the inconsistent results reported in previous studies. To address this issue, RILEM TC 304-ADC initiated a comprehensive interlaboratory study on the mechanical properties of 3D printed concrete. This study involves 30 laboratories worldwide, contributing 34 sets of data, with some laboratories testing more than one mix design. The compressive strength and modulus of elasticity were determined under three distinct conditions: Default, where each laboratory printed according to their standard procedure followed by water bath curing; Deviation 1, which involved creating a cold joint by increasing the time interval between printing layers; and Deviation 2, where the standard printing process was used, but the specimens were cured under conditions different from water bath. Some tests were conducted at two different scales based on specimen size—“mortar-scale” and “concrete-scale”—to investigate the size effect on compressive strength. Since the mix design remained identical for both scales, the only variable was the specimen size. This paper reports on the findings from the interlaboratory study, followed by a detailed investigation into the influencing parameters such as extraction location, cold joints, number of interlayers, and curing conditions on the mechanical properties of the printed concrete. As this study includes results from laboratories worldwide, its contribution to the development of relevant standardized testing protocols is critical. KW - Additive manufacturing KW - Digital fabrication KW - Hardened concrete KW - Compressive strength KW - Young's modulus PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-634672 DO - https://doi.org/10.1617/s11527-025-02688-9 SN - 1871-6873 VL - 58 IS - 5 SP - 1 EP - 30 PB - Springer Nature AN - OPUS4-63467 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bos, Freek A1 - Menna, Constantino A1 - Robens-Radermacher, Annika A1 - Wolfs, Rob A1 - Roussel, Nicolas A1 - Lombois-Burger, Hélène A1 - Baz, Bilal A1 - Weger, Daniel A1 - Nematollahi, Behzad A1 - Santhanam, Manu A1 - Zhang, Yamei A1 - Bhattacherjee, Shantanu A1 - Jia, Zijian A1 - Chen, Yu A1 - Mechtcherine, Viktor T1 - Mechanical properties of 3D printed concrete: a RILEM TC 304-ADC interlaboratory study — approach and main results N2 - To show compliance to structural engineering codes and implement quality control measures, it is critical to obtain reliable mechanical properties of the materials in question. For conventional cast and precast concrete, the experimental procedures and relationships between mechanical properties, the material composition, and the production methods are globally known, but for 3D concrete printing (3DCP), these relations have not yet been established. Previous studies have shown little consistency in results, and the underlying experimental methods have not been established broadly. There is an urgent need to address these issues as the application of 3DCP in practice projects is growing rapidly. Therefore, RILEM TC 304-ADC: Assessment of Additively Manufactured Concrete Materials and Structures has set up a large interlaboratory study into the mechanical properties of 3D printed concrete. This paper presents key elements of the experimental approach detailed in the Study Plan and the supporting considerations. Furthermore, it reports on the response, consisting of 34 contributions from 30 laboratories, detailing global coverage, properties of the applied mixture designs and characteristics of the printing facilities that have been used. Subsequently, some fundamental results from compression, flexural, and E-modulus testing are presented and—considering cast specimens as a reference—discussed. On average, a reduction in strength was found in compression and E-modulus (all tested orientations). For flexure, on the other hand, an increase was found in two testing orientations, while a decrease was observed in the third orientation. Importantly, even though the applied experimental methods were found to be reasonably appropriate to obtain the required data, the differences found between individual contributions are significant and sometimes non-consistent, suggesting that testing on specific material-facility combinations is necessary to reliably determine the mechanical properties of objects produced from them. Furthermore, a theoretical framework needs to be developed to further explain the variations that were observed. Extensive analyses of all acquired data are out of the scope of this contribution, but presented in two associated papers, whereas a third presents the data management approach used to process the approximately 5,000 test results. KW - 3D printed concrete KW - 3DCP KW - Mechanical properties KW - Interlaboratory study PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-634631 DO - https://doi.org/10.1617/s11527-025-02686-x VL - 58 IS - 5 SP - 1 EP - 29 PB - Springer Nature AN - OPUS4-63463 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wolfs, Rob A1 - Versteegen, Jelle A1 - Santhanam, Manu A1 - Bhattacherjee, Shantanu A1 - Bos, Freek A1 - Robens-Radermacher, Annika A1 - Muthukrishnan, Shravan A1 - Menna, Costantino A1 - Ozturk, Onur A1 - Ozyurt, Nilufer A1 - Roupec, Josef A1 - Richter, Christiane A1 - Jungwirth, Jörg A1 - Miranda, Luiza A1 - Ammann, Rebecca A1 - Caron, Jean-François A1 - de Bono, Victor A1 - Monte, Renate A1 - Navarrete, Iván A1 - Eugenin, Claudia A1 - Lombois‑Burger, Hélène A1 - Baz, Bilal A1 - Sinka, Maris A1 - Sapata, Alise A1 - Harbouz, Ilhame A1 - Zhang, Yamei A1 - Jia, Zijian A1 - Kruger, Jacques A1 - Mostert, Jean‑Pierre A1 - Šter, Katarina A1 - Šajna, Aljoša A1 - Kaci, Abdelhak A1 - Rahal, Said A1 - Snguanyat, Chalermwut A1 - Arunothayan, Arun A1 - Zhao, Zengfeng A1 - Mai, Inka A1 - Rasehorn, Inken Jette A1 - Böhler, David A1 - Freund, Niklas A1 - Lowke, Dirk A1 - Neef, Tobias A1 - Taubert, Markus A1 - Auer, Daniel A1 - Hechtl, C. Maximilian A1 - Dahlenburg, Maximilian A1 - Esposito, Laura A1 - Buswell, Richard A1 - Kolawole, John A1 - Isa, Muhammad Nura A1 - Liu, Xingzi A1 - Wang, Zhendi A1 - Subramaniam, Kolluru A1 - Mechtcherine, Viktor T1 - Mechanical properties of 3D printed concrete: a RILEM TC 304-ADC interlaboratory study — flexural and tensile strength N2 - This paper discusses the flexural and tensile strength properties of 3D printed concrete, based on the results of a RILEM TC 304-ADC interlaboratory study on mechanical properties. These properties are determined using different testing techniques, including 3- and 4-point flexural tests, splitting tests, and uniaxial tension tests, on specimens extracted from large 3D printed elements in accordance with a prescribed study plan. The relationship between compressive and flexural or tensile strengths, cast or printed samples, different types of tests, and different loading orientations, are analysed to understand the influence of 3D printing. As expected, the strength can reduce significantly when the main tensile stress is acting perpendicular to the interface between layers. The role of deviations from the standard study procedure, in terms of the time interval between the placing of subsequent layers, or the adoption of a different curing strategy, are also assessed. While the increased time interval significantly impacts the strength in the critical direction, the use of variable curing conditions does not seem to have a clear-cut effect on the strength ratios of the printed to cast specimens. Additionally, the paper looks at the variability in the results for the printed specimens, in order to emphasize the need for multiple replicates for obtaining a proper result. An extensive insight into the aspects affecting the variability is presented in the paper. Finally, with the limited dataset available for specimens tested at a larger scale, it is difficult to arrive at a clear understanding of the role of specimen size (i.e., greater number of layers). KW - 3D concrete printing KW - Digital fabrication KW - Flexural strength KW - Tensile strength KW - Interlayer bond strength PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-634655 DO - https://doi.org/10.1617/s11527-025-02687-w SN - 1871-6873 VL - 58 IS - 5 SP - 1 EP - 33 PB - Springer Nature AN - OPUS4-63465 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Robens-Radermacher, Annika A1 - Kujath, Cezary A1 - Bos, Freek A1 - Mechtcherine, Viktor A1 - Unger, Jörg F. T1 - Mechanical properties of 3D printed concrete: a RILEM TC 304-ADC interlaboratory study-Design and implementation of a database system for querying, sharing, and analyzing experimental data N2 - Interlaboratory studies are essential for implementing standardized test methods for new innovative materials or technologies such as 3D concrete printing, certifying reference materials, and validating methods. They provide the basis for recommendations and design standards. Typically, the collected data are used only for one study and are published in paper form, without open access to the raw data files. However, preserving the collected data and analysis procedures in a shareable and reusable way leads to advantages for further usage. New data with the same structure can be added or the data can be analyzed by a new analysis procedure generating new knowledge. Additionally, resources are saved by avoiding the repetition of the same measurements. In line with the recent digitalization trend in material science and engineering, a database for the interlaboratory study on mechanical properties of 3D printed concrete conducted in RILEM Technical Committee 304-ADC is established. The challenges and experiences from defining the data structure, uploading the data, and using the database for evaluations are discussed. The openBIS software is used to create and fill the database, while an export method to an SQLite format is developed and discussed to generate a shareable and reusable database. With the exported database, querying the data is possible independently of a particular data management system. Additionally, examples of data processing with reusable workflows automating the analysis procedure are demonstrated. KW - Data management KW - Interlaboratory study KW - 3D concrete printing KW - Database KW - Reusability PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-634627 DO - https://doi.org/10.1617/s11527-025-02650-9 SN - 1871-6873 VL - 58 IS - 184 SP - 1 EP - 37 PB - Springer Nature AN - OPUS4-63462 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mundra, Shishir A1 - Provis, J. L. T1 - Mechanisms of passivation and chloride-induced corrosion of mild steel in sulfide-containing alkaline solutions N2 - The pore fluid within many concretes is highly alkaline and rich in reduced sulfur species, but the influence of such alkaline-sulfide solutions on the surface film formed on steel reinforcement is poorly understood. This study investigates the critical role of HS− in defining mild steel passivation chemistry. The surface film formed on the steel in alkaline-sulfide solutions contains Fe(OH)2 and Fe–S complexes, and the critical chloride concentration to induce corrosion increases at high sulfide concentration. However, this behavior is dependent on the duration of exposure of the steel to the electrolyte, and the nature of the sulfidic surface layer. KW - Alkali-activated materials KW - Steel corrosion KW - Sulfide KW - Chloride PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-528861 DO - https://doi.org/10.1007/s10853-021-06237-x VL - 56 IS - 26 SP - 14783 EP - 14802 PB - Springer Nature AN - OPUS4-52886 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rappsilber, Tim A1 - Yusfi, Nawar A1 - Krüger, Simone A1 - Hahn, S.-K. A1 - Fellinger, Tim-Patrick A1 - Krug von Nidda, Jonas A1 - Tschirschwitz, Rico T1 - Meta-analysis of heat release and smoke gas emission during thermal runaway of lithium-ion batteries N2 - Herein a meta-analysis of 76 experimental research papers from 2000 to 2021 is given about possible effects on the thermal runaway of lithium-ion battery cells. Data on the hazards of gas emissions and released heat are related to each other and differentiated by cell properties such as, cell geometry, cathode type or state of charge. Quantitative information on the total heat release in the range of 2.0–112.0 kJ Wh−1, the peak heat release rate in the range of 0.006–2.8 kW Wh−1and the smoke gas emission were extracted, normalized in terms of cell energy (Wh), combined in a data library and compared graphically. The total amount of gas emitted (3–48 mmol Wh−1) as well as the released amount of carbon monoxide (1–161 mg Wh−1) and hydrogen fluoride (2–197 mg Wh−1) were investigated as a function of the state of charge and cell geometry. The analysis reveals that the measured values are significantly influenced by the types of calorimeters and smoke gas analyzers used as well as by the type of thermal runaway trigger. This meta-analysis can serve as an important basis for any risk assessment of lithium-ion batteries. KW - Lithium-ion battery KW - Thermal runaway KW - Cathode active material KW - Heat release KW - Smoke gas emission PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-568071 DO - https://doi.org/10.1016/j.est.2022.106579 SN - 2352-152X VL - 60 SP - 1 EP - 15 PB - Elsevier CY - Amsterdam AN - OPUS4-56807 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hilgenfeldt, Verena A1 - Rübner, Katrin A1 - Hahn, Andreas A1 - Steinmetz, Heidrun T1 - Methodology for Assessing Phosphorus Adsorption Kinetics in Novel Constructed Wetland Materials N2 - Although various special materials have been studied for their potential for phosphorus removal in constructed wetlands, varying methodologies make direct comparisons of adsorption capacities observed in laboratory experiments difficult. This paper aims to establish a methodology for determining the optimal ratio of phosphate to material mass for different materials and for achieving the necessary contact time for adsorption isotherms. To minimise the number of experiments required, pretests over 24 h should be repeated to determine the phosphate-specific ratios until they show around 60% of the initial concentration. The tested materials included lava sand and expanded sand (ExS), which showed saturating kinetics curves after 24 to 48 h. However, aggregates containing calcium silicate hydrate (CSH) phases (autoclaved aerated concrete AAC, sand–lime brick SLB, and hydrothermal granules HTG) did not show saturating curves, complicating contact time determination. Consequently, adsorption velocity is proposed to identify the phase with the lowest adsorption rate, which is then used as the contact time in adsorption isotherm experiments. Using this method, adsorption times of 48 h were observed for HTG and SLB, while that for AAC was 24 h. This methodology is intended as an initial approach to establish a common basis for researchers investigating novel materials and make the results comparable. KW - CSH KW - Phosphate elimination KW - Material evaluation KW - Contact time experiments KW - Methodology development KW - Filter substrates PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-647443 DO - https://doi.org/10.3390/purification1020007 SN - 3042-6197 VL - 1 IS - 2 SP - 1 EP - 20 PB - MDPI AG CY - Basel, Switzerland AN - OPUS4-64744 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zorn, R. A1 - Szymoniak, Paulina A1 - Kolmangadi, Mohamed Aejaz A1 - Malpass-Evans, R. A1 - McKeown, N. A1 - Jalarvo, N. A1 - Tyagi, M. A1 - Böhning, Martin A1 - Schönhals, Andreas T1 - Microscopic molecular mobility of high-performance polymers of intrinsic microporosity revealed by neutron scattering – bend fluctuations and signature of methyl group rotation N2 - Polymers of intrinsic microporosity exhibit a combination of high gas permeability and reasonable permselectivity, which makes them attractive candidates for gas separation membrane materials. The diffusional selective gas transport properties are connected to the molecular mobility of these polymers in the condensed state. Incoherent quasielastic neutron scattering was carried out on two polymers of intrinsic microporosity, PIM-EA-TB(CH3) and its demethylated counterpart PIM-EA-TB(H2), which have high Brunauer–Emmett–Teller surface area values of 1030 m2 g-1 and 836 m2 g-1, respectively. As these two polymers only differ in the presence of two methyl groups at the ethanoanthracene unit, the effect of methyl group rotation can be investigated solely. To cover a broad dynamic range, neutron time-of-flight was combined with neutron backscattering. The demethylated PIM-EA-TB(H2) exhibits a relaxation process with a weak intensity at short times. As the backbone is rigid and stiff this process was assigned to bendand-flex fluctuations. This process was also observed for the PIM-EA-TB(CH3). A further relaxation process is found for PIM-EA-TB(CH3), which is the methyl group rotation. It was analyzed by a jump-diffusion in a three-fold potential considering also the fact that only a fraction of the present hydrogens in PIM-EATB(CH3) participate in the methyl group rotation. This analysis can quantitatively describe the q dependence of the elastic incoherent structure factor. Furthermore, a relaxation time for the methyl group rotation can be extracted. A high activation energy of 35 kJ mol-1 was deduced. This high activation energy evidences a strong hindrance of the methyl group rotation in the bridged PIM-EA-TB(CH3) structure. KW - Polymers of Intrinsic Microporosity KW - Neutron Scattering PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-604114 DO - https://doi.org/10.1039/d4sm00520a SP - 1 EP - 11 PB - RSC AN - OPUS4-60411 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Auersch, Lutz T1 - Mitigation of railway-induced ground vibration by soft support elements and a higher bending stiffness of the track N2 - The mitigation of train-induced ground vibrations by track solutions is investigated by calculations and measurements. The calculation by a wavenumber domain method includes the correct vehicle–track interaction and the correct track–soil interaction. Some theoretical results for elastic elements and an increased bending stiffness of the track are presented where the force transfer of the track and the vehicle–track interaction are calculated for the high-frequency dynamic mitigation, and the force distribution along the track is calculated for the low-frequency mitigation which is due to the smoother impulses from the passing static loads. Measurement results for the ground vibration near isolated and un-isolated tracks are given for several under-sleeper pads, for under-ballast mats, and for several under-ballast plates and ballast troughs. The elastic elements yield a resonance frequency of the vehicle–track–soil system and a high-frequency reduction of the dynamic axle loads which depends mainly on the softness of the pads or mats and which can be improved by a higher sleeper mass. In addition, all troughs and most of the soft elements show a low-frequency reduction which is attributed to the scattered impulses of the static axle loads. Besides this main contribution of the article, the problem of a soft reference section on a different soil is discussed and recommendations for better ground vibration measurements of mitigation effects are given. KW - Railway track KW - Elastic elements KW - Bending stiffness KW - Ground vibration KW - Mitigation KW - Lowfrequency reduction KW - Axle impulses PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-612568 DO - https://doi.org/10.3390/app14031244 VL - 14 IS - 3 SP - 1 EP - 14 PB - MDPI CY - Basel AN - OPUS4-61256 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Liao, Chun-Man ED - Zhang, Jian T1 - Modal and Wave Propagation Analysis of Vibration Tests on a Laboratory Building Model Before and After Damage N2 - Weakened structural stiffness is often a consequence of building damage, particularly after severe events such as earthquakes, where compromised structural performance can pose significant risks. To prevent immediate structural failure, an early warning system is essential, which requires inspection of local components. This research aims to achieve that by exploring the wave propagation analysis method, specifically seismic interferometry. Previous studies have applied this method to building structures, treating them as homogeneous layers of grouped floors. By analyzing the wave travel time along the height of these layers, the fundamental period of the building was estimated. However, this approach did not account for local damage or the variability of structural components, similar to the limitations of vibration‐based damage detection methods, which mainly identify global changes. Thus, the goal of this paper is to improve structural health monitoring by examining the sensitivity of wave screening, bridging the gap between nondestructive testing and vibration‐based damage detection. A half‐scale, seven‐story building model, characterized by vertical stiffness irregularity and transverse plan asymmetry, was tested in a laboratory setting. Two vertical sensor arrays were placed near corner columns of different sizes, representing both strong and weak structural areas. These arrays recorded floor accelerations in three directions. The study confirmed the effectiveness of wave propagation analysis for detecting damage along the sensor arrays before and after the earthquake. A transmissibility damage indicator was used to correlate changes in wave velocity, providing a quantitative assessment of damage levels along the wave propagation path. KW - Damage location KW - Laboratory test KW - Soft story KW - Stifness irregular structure KW - Structural health monitoring PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-624931 DO - https://doi.org/10.1155/stc/3453150 SN - 1545-2263 VL - 2025 IS - 1 SP - 1 EP - 17 PB - John Wiley & Sons Ltd. AN - OPUS4-62493 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Andrés Arcones, Daniel A1 - Weiser, M. A1 - Koutsourelakis, P.-S. A1 - Unger, Jörg F. T1 - Model bias identification for Bayesian calibration of stochastic digital twins of bridges N2 - Simulation-based digital twins must provide accurate, robust, and reliable digital representations of their physical counterparts. Therefore, quantifying the uncertainty in their predictions plays a key role in making better-informed decisions that impact the actual system. The update of the simulation model based on data must then be carefully implemented. When applied to complex structures such as bridges, discrepancies between the computational model and the real system appear as model bias, which hinders the trustworthiness of the digital twin and increases its uncertainty. Classical Bayesian updating approaches aimed at inferring the model parameters often fail to compensate for such model bias, leading to overconfident and unreliable predictions. In this paper, two alternative model bias identification approaches are evaluated in the context of their applicability to digital twins of bridges. A modularized version of Kennedy and O'Hagan's approach and another one based on Orthogonal Gaussian Processes are compared with the classical Bayesian inference framework in a set of representative benchmarks. Additionally, two novel extensions are proposed for these models: the inclusion of noise-aware kernels and the introduction of additional variables not present in the computational model through the bias term. The integration of these approaches into the digital twin corrects the predictions, quantifies their uncertainty, estimates noise from unknown physical sources of error, and provides further insight into the system by including additional pre-existing information without modifying the computational model. KW - Gaussian process KW - KOH KW - Bayesian updating KW - Digital twins KW - Uncertainty quantification PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-615519 DO - https://doi.org/10.1002/asmb.2897 SN - 1526-4025 N1 - This work was supported by “C07 - Data driven model adaptation for identifying stochastic digital twins of bridges” from the Priority Program (SPP) 2388/1 “Hundred plus” of the German Research Foundation (Deutsche Forschungsgemeinschaft, DFG) - Project number 501811638. VL - 417 IS - 3 SP - 1 EP - 26 PB - Wiley CY - Chichester AN - OPUS4-61551 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ji, Y. A1 - Pott, U. A1 - Mezhov, Alexander A1 - Rößler, Ch. A1 - Stephan, D. T1 - Modelling and experimental study on static yield stress evolution and structural build-up of cement paste in early stage of cement hydration N2 - Static yield stress is crucial for concrete, especially for 3D printed concrete, as it determines whether the bottom layer can support the load of the subsequent layers or withstand any potential impulses. A better understanding of the evolution of the static yield stress and its changing mechanism is therefore needed. Under the assumption that hydrate formation follows fractal patterns, this work proposes a model for simulating static yield stress that links the hydration process and bridging possibility. To validate the model, parameters were first obtained from the BNG (Boundary Nucleation Growth) equation fitted with calorimetry data, and the relation of associated hydration rates to sound speed variation rate was analyzed. Results showed that the proposed model predicts well the static yield stress obtained with a penetration test, under varying water-cement ratios and accelerator conditions. The fitted parameter β was found to correlate with size and morphology of the hydration products, suggesting that the model can not only simulate the static yield stress, but also capture the structural build-up information. Furthermore, the decrease in fractal-related β implies that more compact hydrates are formed during hydration. KW - Static yield stress KW - Fractal pattern KW - Hydration process KW - Bridging possibility PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-623503 DO - https://doi.org/10.1016/j.cemconres.2024.107710 SN - 1873-3948 VL - 187 SP - 1 EP - 15 PB - Elsevier Ltd. CY - Schweiz AN - OPUS4-62350 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schilling, Markus A1 - Marschall, Niklas A1 - Niebergall, Ute A1 - Böhning, Martin T1 - Modernizing FNCT data handling in polymer labs: Towards efficient management N2 - A streamlined Python-based workflow for transforming Full-Notch Creep Test (FNCT) data into organized, machine-actionable formats is presented. The workflow automates the conversion of raw FNCT data from classic CSV and Excel files into structured outputs that facilitate future semantic integration. Emphasizing practical data handling, the approach includes automation scripts for efficient data extraction, transformation, and storage, which culminate in well-ordered files. This transformation paves the way for potential semantic data integration and facilitates access for users with varying levels of digital experience to enhanced data management in polymer research and testing. KW - PE-HD KW - Full-Notch Creep Test (FNCT) KW - Environmental Stress Cracking (ESC) KW - Data Interoperability KW - FAIR Data KW - Semantic Data PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-637826 DO - https://doi.org/10.1016/j.commatsci.2025.114085 SN - 0927-0256 VL - 259 SP - 1 EP - 5 PB - Elsevier B.V. AN - OPUS4-63782 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Strangfeld, Christoph A1 - Stolpe, Heiko A1 - Wiehle, Philipp T1 - Moisture diffusion affected by the Knudsen effect in temporal changing pore networks N2 - Almost all building materials in civil engineering have an open porosity and interact with or are affected by the environmental conditions. Structures might suffer from effects such as moisture adsorption, carbonation, corrosion, penetration of salt ions and chemical substances, etc. In the hygroscopic range, these processes are mostly driven by diffusion. Due to the confinement of small pores (less than1 µm), the Knudsen effect reduces the molecular diffusion. This reduction can become more significant in case of temporal changing pore systems because of physisorption of water vapor, carbonation, or chemisorption. In this study, unstabilised earth blocks and earth masonry are investigated. In a first step, the pore size distribution of the blocks is measured and sorption isotherms are recorded in experiments. Besides the ordinary physisorption, the involved clay minerals undergo swelling or shrinking due to chemisorption. The following two effects must be considered: first, the reduction of the available pore space by the adsorbed water layer. For this, the Hillerborg sorption theory is used, which is a combination of the well-known Brunauer-Emmett-Teller sorption theory and the Kelvin equation. This allows the computation of adsorbed water layers even in curved pore geometries. Second, the variation of the initial pore size distribution due to chemisorption needs to be modelled. Based on these two models, the effective diffusion coefficient can be predicted. For validation, arrays of relative humidity sensors were embedded into a free-standing earth masonry wall. This monitoring was carried out over more than a year to have a broad variety of environmental conditions and was located in Berlin, Germany. The prediction of the effective diffusion coefficient can also be transferred to other processes and allows the investigation of materials having temporarily changing pore systems. Examples are the carbonation of cementitious materials, alkali silica reaction, calcium leaching of long-lasting structures, etc. These effects are prominent in the meso-pore range and might significantly alter the effective diffusion coefficient. KW - Earth material KW - Material moisture KW - Physisoprtion KW - Chemisorption PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-583811 DO - https://doi.org/10.1016/j.matpr.2023.09.034 SN - 2214-7853 SP - 1 EP - 8 PB - Elsevier Ltd. CY - Amsterdam, Niederlande AN - OPUS4-58381 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Emamverdi, Farnaz A1 - Huang, J. A1 - Mosane Razavi, Negar A1 - Bojdys, M. J. A1 - Forster, A. B. A1 - Budd, P. M. A1 - Böhning, Martin A1 - Schönhals, Andreas T1 - Molecular Mobility and Gas Transport Properties of Mixed Matrix Membranes Based on PIM‑1 and a Phosphinine Containing Covalent Organic Framework N2 - Polymers with intrinsic microporosity (PIMs) are gaining attention as gas separation membranes. Nevertheless, they face limitations due to pronounced physical aging. In this study a covalent organic framework containing λ5-phosphinine moieties, CPSF-EtO were incorporated as a nanofiller (concentration range 0-10 wt%) into a PIM-1 matrix forming dense films with a thickness of ca. 100 μm. The aim of the investigation was to investigate possible enhancements of gas transport properties and mitigating effects on physical aging. The incorporation of the nanofiller occurred on aggregate level with domains up to 100 nm as observed by T-SEM and confirmed by X-ray scattering. Moreover, the X-ray data show that the structure of the microporous network of the PIM-1 matrix is changed by the nanofiller. As the molecular mobility is fundamental for gas transport as well as for physical aging, the study includes dielectric investigations of pure PIM-1 and PIM-1/CPSF-EtO mixed matrix membranes to establish a correlation between the molecular mobility and the gas transport properties. Using the time-lag method the gas permeability and the permselectivity were determined for N2, O2, CH4 and CO2 for samples with variation in filler content. A significant increase in the permeability of CH4 and CO2 (50 % increase compared to pure PIM-1) was observed for a concentration of 5 wt% of the nanofiller. Furthermore, the most pronounced change in the permselectivity was found for the gas pair CO2/N2 at a filler concentration of 7 wt%. KW - Polymers of Intrinsic Microporosity KW - Nanocomposites PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595031 DO - https://doi.org/10.1021/acs.macromol.3c02419 SN - 0024-9297 VL - 57 IS - 4 SP - 1829 EP - 1845 PB - ACS Publications AN - OPUS4-59503 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Battig, Alexander A1 - Abdou-Rahaman Fadul, Naïssa A1 - Frasca, Daniele A1 - Schulze, Dietmar A1 - Schartel, Bernhard T1 - Multifunctional graphene nanofiller in flame retarded polybutadiene/chloroprene/carbon black composites N2 - To curtail flammability risks and improve material properties, flame retardants (FRs) and fillers are mixed into rubbers. High loadings of aluminum trihydroxide (ATH) and carbon black (CB) are the most used FRs and reinforcing additive, respectively, in rubbers. To reduce loading without losing mechanical properties, partial substitution of ATH as well as CB by low amounts of multilayer graphene (MLG) nanoparticles is investigated. The high aspect ratio MLG is made of ten graphene sheets. In polybutadiene/chloroprene (BR/CR) nanocomposites 3 phr MLG replaced 15 phr CB and/or 3 phr ATH. Material and mechanical properties as well as fire behavior of the nanocomposites are compared to BR/CR with 20 phr CB both with and without 50 phr ATH. MLG appears as a promising nanofiller to improve the functional properties: replacement of CB improved rheological, curing, and mechanical properties; substitution of ATH improved nanocomposite properties without affecting flame retardancy. KW - Nanocomposites KW - Rubber KW - Multilayer graphene KW - Carbon black KW - Polybutadiene/chloroprene KW - Graphene PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-523468 DO - https://doi.org/10.1515/epoly-2021-0026 SN - 1618-7229 VL - 21 IS - 1 SP - 244 EP - 262 PB - De Gruyter AN - OPUS4-52346 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Diercks, Philipp A1 - Veroy, K. A1 - Robens-Radermacher, Annika A1 - Unger, Jörg F. T1 - Multiscale modeling of linear elastic heterogeneous structures via localized model order reduction N2 - In this paper, a methodology for fine scale modeling of large scale linear elastic structures is proposed, which combines the variational multiscale method, domain decomposition and model order reduction. The influence of the fine scale on the coarse scale is modelled by the use of an additive split of the displacement field, addressing applications without a clear scale separation. Local reduced spaces are constructed by solving an oversampling problem with random boundary conditions. Herein, we inform the boundary conditions by a global reduced problem and compare our approach using physically meaningful correlated samples with existing approaches using uncorrelated samples. The local spaces are designed such that the local contribution of each subdomain can be coupled in a conforming way, which also preserves the sparsity pattern of standard finite element assembly procedures. Several numerical experiments show the accuracy and efficiency of the method, as well as its potential to reduce the size of the local spaces and the number of training samples compared to the uncorrelated sampling. KW - Multiscale methods KW - Variational multiscale method KW - Localized model order reduction KW - Domain decomposition methods PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-580671 DO - https://doi.org/10.1002/nme.7326 SN - 0029-5981 SP - 1 EP - 23 PB - Wiley online library AN - OPUS4-58067 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zinas, Orestis A1 - Papaioannou, Iason A1 - Schneider, Ronald A1 - Cuéllar, Pablo T1 - Multivariate Gaussian Process Regression for 3D site characterization from CPT and categorical borehole data N2 - Accurate prediction of subsurface stratigraphy and geotechnical properties, along with quantification of associated uncertainties, is essential for improving the design and assessment of geotechnical structures. Several studies have utilized indirect data from Cone Penetration Tests (CPTs) and employed statistical and Machine Learning methods to quantify the geological and geotechnical uncertainty. Incorporating direct borehole data can reduce uncertainties. This study proposes a computationally efficient multivariate Gaussian Process model that utilizes site-specific data and: (i) jointly models multiple categorical (USCS labels) and continuous CPT variables, (ii) learns a non-separable covariance structure leveraging the Linear Model of Coregionalization, and (iii) predicts a USCS based stratigraphy and CPT parameters at any location within the 3D domain. The results demonstrate that integrating geotechnical and geological data into a unified model yields more reliable predictions of subsurface stratification, enabling the parallel interpretation of both USCS classification and CPT profiles. Importantly, the model demonstrates its potential to integrate multiple variables from different sources and data types, contributing to the advancement of methodologies for the joint modeling of geotechnical, geological, and geophysical data. KW - Geotechnical site-characterization KW - Cone Penetration Tests KW - Stratigraphy prediction KW - Multivariate Gaussian process KW - Variational inference KW - Linear Model of Coregionalization PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-629456 DO - https://doi.org/10.1016/j.enggeo.2025.108052 SN - 1872-6917 VL - 352 SP - 1 EP - 19 PB - Elsevier B.V. AN - OPUS4-62945 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sano, Silvia Di A1 - Costa, Giancarlo A1 - Giordano, Pier Francesco A1 - Pregnolato, Maria A1 - Limongelli, Maria Pina T1 - Multi‐risk assessment for bridges: The application of the Italian Guidelines N2 - Bridges are essential elements in the built environment since they underpin the functioning of transportation systems. Nevertheless, they are vulnerable due to aggressive environment, demand beyond the design level, and other contingencies such as extreme events. The management of bridges represents a significant challenge for improving transport performance and ensure the safety of users. In Italy, bridge management is addressed by the recent “Guidelines for risk classification and management, safety evaluation and monitoring of existing bridges” which were issued by the Italian Ministry for Public Work in 2020. The guidelines propose an operational approach with distinctive characteristics: (i) risk‐based, i.e., based on the typical parameters of hazard, vulnerability, and exposure; (ii) multi‐level, i.e., they include six assessment levels (0‐5) of increasing complexity; and (iii) multi‐risk, i.e., they assess structural/foundation, seismic, hydrological and landslide risk. This paper presents a general overview of the 2020 Italian Guidelines and their application to a selected case study. Lessons from the application to the case study are drafted and possible criticalities highlighted. KW - Bridge management KW - Infrastructures KW - Italian guidelines KW - Structural safety KW - Risk assessment KW - Risk classification PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-653392 DO - https://doi.org/10.1002/cepa.2046 SN - 2509-7075 VL - 6 IS - 5 SP - 772 EP - 779 PB - Wiley CY - Berlin AN - OPUS4-65339 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -