TY - CONF A1 - Pfennig, Anja A1 - Kranzmann, Axel T1 - Impact of saline aquifer water on surface and shallow pit corrosion of martensitic stainless steels during exposure to CO2 environment (CCS) N2 - Pipe steels suitable for carbon capture and storage technology (CCS) require resistance against the corrosive environment of a potential CCS-site, e.g. heat, pressure, salinity of the aquifer, CO2-partial pressure. Samples of different mild and high alloyed stainless injection-pipe steels partially heat treated: 42CrMo4, X20Cr13, X46Cr13, X35CrMo4 as well as X5CrNiCuNb16-4 were kept at T=60 °C and ambient pressure as well as p=100 bar for 700 h - 8000 h in a CO2-saturated synthetic aquifer environment similar to possible geological on-shore CCS-sites in the northern German Basin. Main corrosion products are FeCO3 and FeOOH. Corrosion rates obtained at 100 bar are generally much lower than those measured at ambient pressure. Highest surface corrosion rates are 0.8 mm/year for 42CrMo4 and lowest 0.01 mm/year for X5CrNiCuNb16-4 in the vapour phase at ambient pressure. At 100 bar the highest corrosion rates are 0.01 mm/year for 42CrMo4, X20Cr13 (liquid phase), X46Cr13 and less than 0.01 mm/year for X35CrMo4 and X5CrNiCuNb16-4 after 8000 h of exposure with no regard to atmosphere. Martensitic microstructure offers good corrosion resistance. T2 - 8th International Conference on Future Environment and Energy (ICFEE 2018) CY - Phuket, Thailand DA - 10.01.2018 KW - CCS KW - CO2 corrosion KW - Pipeline PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-465896 DO - https://doi.org/10.1088/1755-1315/150/1/012012 VL - 150 SP - 81 EP - 90 PB - IOP Publ. AN - OPUS4-46589 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mekonnen, Tessema Fenta A1 - Panne, Ulrich A1 - Koch, Matthias T1 - New photodegradation products of the fungicide fluopyram: Structural elucidation and mechanism identification N2 - Identifying the fate of agrochemicals is important to understand their potential risk for living organisms. We report here new photodegradation products (PPs) of the fungicide fluopyram. The PPs were produced by irradiating a fluopyram standard in 0.1% acetonitrile aqueous media by a 150-W medium pressure Hg-lamp that emits wavelengths between 200–280 nm. The structural elucidation of PPs was achieved by combining the retention time, isotopic pattern, targeted fragmentation, and accurate mass measurements using liquid chromatography-tandem mass spectrometry (LC-MS/MS) and high resolution-MS (HRMS). In addition to previously known PPs, seven new PPs of fluopyram were identified in this work: mainly dihydroxyl and hydroxylimide fluopyram as well as mono, di, and trihydroxyl lactam. Additionally, two PPs were found to be formed by rearrangement after the loss of H2C=CH2. Hence, the results of the work contribute to extending the current knowledge regarding the photoinduced fate of agrochemicals, and fluopyram in particular. KW - Photodegradation KW - Transformation products KW - LC-MS/MS KW - HRMS KW - Fungicide PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-466347 DO - https://doi.org/10.3390/molecules23112940 SN - 1420-3049 VL - 23 IS - 11 SP - 2940, 1 EP - 13 PB - MDPI CY - Basel AN - OPUS4-46634 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ivanov, Sergei A1 - Artinov, Antoni A1 - Valdaytseva, Ekaterina A1 - Stankevich, Stanislav A1 - Andreevich, Gleb T1 - A simplified model for numerical simulation of laser metal deposition process with beam oscillation N2 - A model of laser metal deposition with beam oscillation has been developed. The proposed model consists of two coupled sub-models calculating the heat transfer in the deposited part and the free surface of the molten pool, respectively. The heat transfer simulation of the deposited part solves a three-dimensional quasi-stationary heat conduction problem. The free surface of the molten pool are determined by solving the Laplace-Young equation. The developed model enables the layer-by-layer prediction of the shape of the deposited part and the resulting temperature field. It is shown that for an oscillation amplitude equal to the beam radius the peak value of the heat flux decreases by about 53% and 73% in the case of lateral oscillation and circular oscillation, respectively. Lateral oscillating laser beam results in a higher penetration depth due to the higher thermal efficiency. The amplitude of the laser beam oscillation effects the shape of the deposited wall and the deposition rate. A good correlation between the numerically calculated and experimentally observed results is obtained. KW - Laser metal deposition KW - Beam oscillation KW - Numerical modelling PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-467081 DO - https://doi.org/10.1088/1742-6596/1109/1/012006 SN - 1742-6588 SN - 1742-6596 VL - 1109 SP - 012006, 1 EP - 8 PB - IOP Publ. CY - Bristol AN - OPUS4-46708 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bakir, Nasim A1 - Pavlov, V. A1 - Zavjalov, S. A1 - Volvenko, S. A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Novel metrology to determine the critical strain conditions required for solidification cracking during laser welding of thin sheets N2 - This paper represents the results for proposed optical flow method based on the Lucas-Kanade (LK) algorithm applied to two different problems. The following observations can be made: - The estimated strain and displacement for conducted tensile test are generally very close to those measured with conventional DIC-technique. - The LK technique allows measurement of strain or displacement without special selection of a region of interest. Using a novel optical measurement technique together with the optical flow algorithm, a twodimensional deformation analysis during welding was conducted. This technique is the first to provide a measurement of the full strain field locally in the immediate vicinity of the solidification front. Additionally, the described procedure of the optical measurement allows the real material-dependent values of critical strain characterizing the transition to hot cracking during laser welding processes to be determined. T2 - Beam Technologies and Laser Application CY - Sankt Petersburg, Russia KW - Hot cracking test KW - Local critical strain KW - Solidification cracking KW - Laser beam welding KW - Novel metrology PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-467226 DO - https://doi.org/10.1088/1742-6596/1109/1/012047 SN - 1742-6596 VL - 1109 IS - 012047 SP - 1 EP - 9 PB - IOP Publ. CY - Bristol AN - OPUS4-46722 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Maiwald, Michael T1 - Voll integrierte und vernetzte Systeme und Prozesse - Perspektive: Smarte Sensorik, Aktorik und Kommunikation T1 - Fully integrated distributed systems and processes – Perspective: Smart sensors, actuators, and communication N2 - Unternehmen der chemischen Industrie müssen neuen Pfade beschreiten, um in einem veränderten Umfeld erfolgreich bestehen zu können. Dazu gehört insbesondere, das Potenzial digitaler Technologien zu nutzen. Die volle Integration und intelligente Vernetzung von Systemen und Prozessen kommt allerdings nur zögerlich voran. Dieser Beitrag ist ein Loblied auf die Feldebene. Er möchte dazu ermutigen, die Digitalisierung der Prozessindustrie auf Basis smarter Sensorik, Aktorik und Kommunikation ganzheitlicher zu denken und informiert über aktuelle technische Perspektiven, wie das Ein-Netzwerk-Paradigma, Ad-hoc-Vernetzungen, Edge-Computing, FPGAs, virtuelle Maschinen oder Blockchain. Diese geben smarter Sensorik, Aktorik und Kommunikation eine völlig neue Perspektive. N2 - Chemical companies must find new paths to success in a changing environment. In particular, this will involve exploiting the potential of digital technologies. However, the full integration and intelligent interconnection of systems and processes is only making slow progress. This contribution aims to encourage the more comprehensive use of digitization in the process industry based on smart sensors, actuators, and communications, and informs about current technical possibilities such as the “one-network paradigm”, ad-hoc connections, edge computing, FPGAs, virtual machines and blockchain. These offer a new scope for smart sensors, actuators, and communications. KW - Smarte Sensoren KW - Smarte Aktoren KW - Digitalisierung der Prozessindustrie KW - Prouess-Sensoren 4.0 KW - Smart sensors KW - Smart actuators KW - Digitization of process industry KW - Process sensors 4.0 PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-466642 DO - https://doi.org/10.17560/atp.v60i10.2376 SN - 2364-3137 VL - 60 IS - 10 SP - 70 EP - 85 PB - Vulkan Verlag CY - Essen AN - OPUS4-46664 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Geoerg, Paul A1 - Polzin, Robert Malte A1 - Schumann, Jette A1 - Holl, Stefan A1 - Hofmann-Böllinghaus, Anja T1 - Small-scale studies on evacuation characteristics of pedestrians with physical, mental or age-related disabilities N2 - Evaluation of evacuation process is common separated by two phases: pre-movement and movement-phase. Individual capabilities of pedestrians have an impact on both and therefore on the time required for safe escape. In view of evaluating the evacuation process, characteristics of realistic movements of pedestrians involved are needed, but so far such data are mainly available for individuals with unrestricted evacuation capabilities only. Due to the lack of available data, parameter studies in an assisted living for people with disabilities were performed to explore the movement during evacuation. Preparation times for assistance (n = 10), unimpeded walking speeds (n = 34) depending on the assistance devices in the plane as well as walking speeds on stairs (n = 11) were focussed. Time to prepare an assistance device for utilisation depends significantly on the kind of device type. Further on, practical experience in handling the devices for assistance has an impact on the preparation time. In contrast to the results of the preparation times, any relation on assistance devices were investigated for the unimpeded walking speed in the plane. A remarkable decrease of walking speed on stairs was observed which is independent from the utilised assistance device. The presented data improve and extend the insufficient engineering data base and raised up questions regarding the complexity of considering pedestrians movement with impairments in evacuation planning. T2 - 3rd European Symposium on Fire Safety Science CY - Nancy, France DA - 12.09.2018 KW - Human behaviour KW - Egress KW - Evacuation KW - Pedestrians with disabilities KW - Engineering data PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-466463 DO - https://doi.org/10.1088/1742-6596/1107/7/072006 SN - 1742-6596 VL - 1107 IS - 072006 SP - 1 EP - 6 PB - IOP Publ. CY - Bristol AN - OPUS4-46646 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kotthoff, Lisa A1 - Keller, Julia A1 - Lörchner, Dominique A1 - Mekonnen, Tessema F. A1 - Koch, Matthias T1 - Transformation products of organic contaminants and residues - Overview of current simulation methods N2 - The formation of transformation products (TPs) from contaminants and residues is becoming an increasing focus of scientific community. All organic compounds can form different TPs, thus demonstrating the complexity and interdisciplinarity of this topic. The properties of TPs could stand in relation to the unchanged substance or be more harmful and persistent. To get important information about the generated TPs, methods are needed to simulate natural and manmade transformation processes. Current tools are based on metabolism studies, photochemical methods, electrochemical methods, and Fenton's reagent. Finally, most transformation processes are based on redox reactions. This review aims to compare these methods for structurally different compounds. The groups of pesticides, pharmaceuticals, brominated flame retardants, and mycotoxins were selected as important residues/contaminants relating to their worldwide occurrence and impact to health, food, and environmental safety issues. Thus, there is an increasing need for investigation of transformation processes and identification of TPs by fast and reliable methods. KW - Transformation product KW - Electrochemistry KW - Photochemistry KW - Fenton’s reagent PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-474108 DO - https://doi.org/10.3390/molecules24040753 SN - 1420-3049 VL - 24 IS - 4 SP - 753, 1 EP - 23 PB - MDPI CY - Basel AN - OPUS4-47410 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Koch, Claudia ED - Mangelsdorf, Axel ED - Weiler, Petra T1 - Normung für neue Technologien am Beispiel Additiver Fertigung N2 - Der Beitrag beleuchtet die Normung für neue Technologien am Beispiel Additiver Fertigung im Hinblick auf ihren Beitrag zur Diffusion in den Markt KW - Additive Fertigung KW - Innovation KW - Normen KW - Standards PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-473812 UR - https://www.degruyter.com/view/books/9783110629057/9783110629057-003/9783110629057-003.xml SN - 978-3-11062-905-7 DO - https://doi.org/10.1515/9783110629057 VL - 2019 SP - 18 EP - 36 PB - De Gruyter CY - Berlin, Boston ET - 1 AN - OPUS4-47381 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Mirtsch, Mona ED - Mangelsdorf, Axel ED - Weiler, Petra T1 - Konformitätsbewertung im Bereich Cybersicherheit N2 - Das Ziel dieses Kapitels besteht darin, die Rolle von Konformitätsbewertung für die Erhöhung der Cybersicherheit von Produkten, Dienstleistungen und Prozessen zu betrachten. Dazu wird der Begriff Cybersicherheit beleuchtet sowie ausgewählte Cybersicherheitsnormen kurz vorgestellt. Im Folgenden wird der regulative europäische Rahmen für die Konformitätsbewertung aus ordnungspolitischer Sicht sowie der aktuelle Verordnungsentwurf zum Cybersecurity Act dargestellt und kritsch beleuchtet. KW - Cybersicherheit KW - Konformitätsbewertung KW - Cybersecurity Act KW - Normen PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-473829 UR - https://www.degruyter.com/downloadpdf/books/9783110629057/9783110629057-009/9783110629057-009.pdf SN - 978-3-11062-905-7 DO - https://doi.org/10.1515/9783110629057 SP - 141 EP - 164 PB - De Gruyter CY - Berlin, Boston ET - 1 AN - OPUS4-47382 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Jürgens, Maria A1 - Olbricht, Jürgen A1 - Fedelich, Bernard A1 - Skrotzki, Birgit T1 - Low Cycle Fatigue and Relaxation Performance of Ferritic–Martensitic Grade P92 Steel N2 - Due to their excellent creep resistance and good oxidation resistance, 9–12% Cr ferritic–martensitic stainless steels are widely used as high temperature construction materials in power plants. However, the mutual combination of different loadings (e.g., creep and fatigue), due to a “flexible” operation of power plants, may seriously reduce the lifetimes of the respective components. In the present study, low cycle fatigue (LCF) and relaxation fatigue (RF) tests performed on grade P92 helped to understand the behavior of ferritic–martensitic steels under a combined loading. The softening and lifetime behavior strongly depend on the temperature and total strain range. Especially at small strain amplitudes, the lifetime is seriously reduced when adding a hold time which indicates the importance of considering technically relevant small strains. KW - Ferritic–martensitic steel KW - P92 KW - Low cycle fatigue KW - Relaxation fatigue KW - Cyclic softening PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-473905 DO - https://doi.org/10.3390/met9010099 VL - 9 IS - 1 SP - 99, 1 EP - 25 PB - MDPI AN - OPUS4-47390 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Domonov, D.P. A1 - Pechenyuk, S.I. A1 - Semushina, Y.P. A1 - Yusenko, Kirill T1 - Solid state transformation in inner coordination sphere of [Co(NH3)6][Fe(C2O4)3]·3H2O as a route to access catalytically active Co-Fe materials N2 - Thermal decomposition of [Co(NH₃)₆][Fe(C₂O₄)₃]∙3H₂O in argon atmosphere, at a low heating rate (3°/min), and in large amounts of the initial complex (~0.1 mole), has been studied. It was possible to distinguish four decomposition steps upon heating: In the temperature range of 50⁻100 °C-the loss of crystal water; 100⁻190 °C-stability region of dehydrated complex; 230⁻270 °C-the range of stability of intermediate phase with the formula CoFe(NH₃)₂(C₂O₄)₂; 270⁻350 °C-thermal decomposition of the intermediate with the formation of metallic products and further air oxidation with the formation of Co1.5Fe1.5O₄. Catalytic properties of thermolysis products were tested in the decomposition reaction of H₂O₂ (inactive), oxidation of acetone (average activity), and decomposition of ammonium perchlorate (highly active). KW - Double complex salts KW - Catalysts KW - Single-source precursors PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-474014 DO - https://doi.org/10.3390/ma12020221 SN - 1996-1944 VL - 12 IS - 2 SP - 221, 1 EP - 10 PB - mdpi CY - Zürich AN - OPUS4-47401 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Thiede, Tobias A1 - Mishurova, Tatiana A1 - Evsevleev, Sergei A1 - Serrano Munoz, Itziar A1 - Gollwitzer, Christian A1 - Bruno, Giovanni T1 - 3D shape analysis of powder for laser beam melting by synchrotron X-ray CT N2 - The quality of components made by laser beam melting (LBM) additive manufacturing is naturally influenced by the quality of the powder bed. A packing density <1 and porosity inside the powder particles lead to intrinsic voids in the powder bed. Since the packing density is determined by the particle size and shape distribution, the determination of these properties is of significant interest to assess the printing process. In this work, the size and shape distribution, the amount of the particle’s intrinsic porosity, as well as the packing density of micrometric powder used for LBM, have been investigated by means of synchrotron X-ray computed tomography (CT). Two different powder batches were investigated: Ti–6Al–4V produced by plasma atomization and stainless steel 316L produced by gas atomization. Plasma atomization particles were observed to be more spherical in terms of the mean anisotropy compared to particles produced by gas atomization. The two kinds of particles were comparable in size according to the equivalent diameter. The packing density was lower (i.e., the powder bed contained more voids in between particles) for the Ti–6Al–4V particles. The comparison of the tomographic results with laser diffraction, as another particle size measurement technique, proved to be in agreement. KW - Additive manufacturing KW - Laser beam melting KW - Synchrotron computed tomography KW - Powder analysis KW - Imaging PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-474070 DO - https://doi.org/10.3390/qubs3010003 SN - 2412-382X VL - 3 IS - 1 SP - 3, 1 EP - 12 PB - MDPI AN - OPUS4-47407 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Le, Quynh Hoa A1 - Bäßler, Ralph A1 - Bettge, Dirk T1 - On the corrosion mechanism of CO2 transport pipeline steel caused by condensate: Synergistic effects of NO2 and SO2 N2 - To study the effects of condensed acid liquid, hereafter referred to as condensate, on the CO2 transport pipeline steels, gas mixtures containing a varying concentration of H2O, O2, NO2, and SO2, were proposed and resulted in the condensate containing H2SO4 and HNO3 with the pH ranging from 0.5 to 2.5. By exposing the pipeline steel to the synthetic condensate with different concentration of acidic components, the corrosion kinetic is significantly changed. Reaction kinetic was studied using electrochemical methods coupled with water analysis and compared with surface analysis (scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffractometry (XRD)) of corroded coupons. The results showed that, although the condensation of NO2 in the form of HNO3 causes faster general corrosion rate, it is the condensation of SO2 in the form of H2SO4 or the combination of SO2 and NO2 that may cause much more severe problems in the form of localized and pitting corrosions. The resulting corrosion forms were depended on the chemical nature of acids and their concentration at the same investigated pH. The effects of changing CO2 flow rate and renewing condensate on pitting corrosion were further studied. KW - Carbon capture, utilization and storage technology KW - CCUS KW - Corrosion KW - Condensate KW - Electrochemical characterisation KW - Pitting corrosion KW - Impurities KW - Carbon steel PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-473685 UR - https://www.mdpi.com/1996-1944/12/3/364 DO - https://doi.org/10.3390/ma12030364 SN - 1996-1944 VL - 12 IS - 3 SP - 364, 1 EP - 17 PB - MDPI CY - Basel AN - OPUS4-47368 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Redfern, J. A1 - Tucker, J. A1 - Simmons, L. A1 - Askew, P. A1 - Verran, J. A1 - Stephan, Ina T1 - Environmental and experimental factors affecting efficacy testing on nonporous plastic antimicrobial surfaces N2 - Test methods for efficacy assessment of antimicrobial coatings are not modelled on a hospital environment, and instead use high humidity (>90%) high temperature (37 ◦C), and no airflow. Therefore, an inoculum will not dry, resulting in an antimicrobial surface exhibiting prolonged antimicrobial activity, as moisture is critical to activity. Liquids will dry quicker in a hospital ward, resulting in a reduced antimicrobial efficacy compared to the existing test, rendering the test results artificially favourable to the antimicrobial claim of the product. This study aimed to assess how hospital room environmental conditions can affect the drying time of an inoculum, and to use this data to inform test parameters for antimicrobial efficacy testing based on the hospital ward. The drying time of different droplet sizes, in a range of environmental conditions likely found in a hospital ward, were recorded (n = 630), and used to create a model to inform users of the experimental conditions required to provide a drying time similar to what can be expected in the hospital ward. Drying time data demonstrated significant (p < 0.05) variance when humidity, temperature, and airflow were assessed. A mathematical model was created to select environmental conditions for in vitro antimicrobial efficacy testing. Drying time in different environmental conditions demonstrates that experimental set-ups affect the amount of time an inoculum stays wet, which in turn may affect the efficacy of an antimicrobial surface. This should be an important consideration for hospitals and other potential users, whilst future tests predict efficacy in the intended end-use environment. KW - Method development KW - Standardisation KW - Antimicrobial test KW - Environmental conditions KW - Hospital premises PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-472699 DO - https://doi.org/10.3390/mps1040036 SN - 2409-9279 VL - 1 IS - 4 SP - 36, 1 EP - 10 PB - MDPI CY - Internet open accsess AN - OPUS4-47269 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Oesch, Tyler A1 - Weise, Frank A1 - Meinel, Dietmar A1 - Gollwitzer, Christian T1 - Quantitative in-situ analysis of water transport in concrete completed using X-ray computed tomography N2 - This paper describes a novel methodology for quantitative in-situ moisture measurement without tracking agents using X-ray computed tomography (XCT). The high levels of grey-scale precision required for the measurement of moisture without tracking agents resulted in the need for an additional image calibration procedure to correct for water-related X-ray scattering and for equipment-variability related artefacts arising during in-situ testing. This calibration procedure was developed on the basis of existing principles of XCT image cor-rection. Resulting images of moisture distribution exhibit a high level of agreement with expected material behaviour. This research demonstrated that XCT can be successfully used to measure both moisture-front movement over time and changes in 3D moisture distribution within samples. This approach to moisture measurement lays the groundwork for the planned future investigation of the interaction between cracking induced by varying chemical and mechanical processes and water transport in concrete. KW - X-ray computed tomography (XCT) KW - In-situ testing KW - Water transport KW - Quantitative moisture measurement KW - Concrete PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-474395 DO - https://doi.org/10.1007/s11242-018-1197-9 SN - 1573-1634 VL - 127 IS - 2 SP - 371 EP - 389 PB - Springer Netherlands AN - OPUS4-47439 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ewert, Uwe A1 - Zscherpel, Uwe A1 - Vogel, Justus A1 - Zhang, F. A1 - Long, N.X. A1 - Nguyen, T.P. T1 - Visibility of Image Quality Indicators (IQI) by Human Observers in Digital Radiography in Dependence on Measured MTFs and Noise Power Spectra N2 - Digital radiographic images were analysed to predict the visibility of image quality indicators (IQI), based on normalized noise power spectra (NNPP) and modulation transfer function (MTF) measurements. The fixed pattern noise of some digital detectors result in different noise spectra, which influence the visibility of different IQIs, depending on the hole diameter. Studies, based on measurement of basic spatial resolution and contrast to noise ratio were performed together with presampled MTF measurements and the NNPS in dependence on the spatial frequency. Plate hole IQIs, step hole IQIs, and equivalent penetrameter sensitivity (EPS) IQIs based on ASTM E 746 were measured to verify the influence of the different parameters. Modelling of digital images was used to verify the applied numeric tools. A study has been performed for imaging plates and digital detector arrays to analyse differences. Formulas for the prediction of the visibility functions for hole type IQIs are derived. In consequence the standards for characterization and classification of computed radiography (ASTM E 2446) and radiography with DDAs (ASTM E 2597) need to be revised. T2 - 12th ECNDT 2018 CY - Gothenburg, Sweden DA - 11.06.2018 KW - Image evaluation KW - Computed radiography (CR) KW - Digital Detector Array (DDA) KW - Detail detection PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-473486 UR - www.ndt.net/?id=22967 SN - 1435-4934 VL - 23 IS - 8 SP - 1 EP - 7 PB - NDT.net CY - Kirchwald AN - OPUS4-47348 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ewert, Uwe A1 - Zscherpel, Uwe A1 - Zhang, F. A1 - Long, N.X. A1 - Phong, N. T1 - Essentielle Parameter zur numerischen Abschätzung der Sichtbarkeit von Bildgüteprüfkörpern in der digitalen Radiographie N2 - Die Voraussetzungen für die Vorhersage der Sichtbarkeit von Bildgüteprüfkörpern (BPK) wurden seit Beginn der kommerziellen Anwendung der technischen Radiographie diskutiert und in diversen nationalen und internationalen Standards festgeschrieben. Diese Fragen werden nach Einführung der digitalen Radiographie und der CT wieder neu diskutiert. Draht BPKs wurden in Deutschland seit 1935 (DIN 1915: 1935) und später in den meisten europäischen Ländern benutzt. In den USA und Frankreich wurden vorzugsweise BPKs mit Löchern verwendet (ASTM E 1025 seit 1984 oder E 1742 seit 1992 bzw. die Vorgängernorm MIL STD-543 seit 1962). Jetzt werden auch die Umrechnungsnormen zur Erkennbarkeit von Draht zu Loch-BPKs in Frage gestellt. ISO 19232-3, der französische RCCM-Kode einerseits und ASTM E 747 und ASME BPVC Section V Tab. T-276 andererseits unterscheiden sich erheblich bei den Anforderungen im Bereich hoher Wandstärken (Hochenergieradiographie). Untersuchungen dazu werden vorgestellt. Mit Einführung der digitalen Detektoren ändern sich auch die Rauschspektren. Durch die Herstellung werden insbesondere bei Speicherfolien "Rauschmuster" eingeprägt, die bei hohen Belichtungsdosen sichtbar werden. Diese veränderten Rauschspektren ergeben auch veränderte Erkennungsparameter für menschliche Bildauswerter. Hierzu wurden an ausgewählten Detektoren MTFs (presampled) und normierte Rauschspektren gemessen. Erweiterte Erkennbarkeits-Formeln zur Vorhersage der Sichtbarkeit von BPKs für Bildauswerter und erste Ergebnisse werden vorgestellt. T2 - DGZfP-Jahrestagung 2018 CY - Leipzig, Germany DA - 07.05.2018 KW - Image quality KW - Computed radiography (CR) KW - Digital Detector Array (DDA), KW - Sichtbarkeit von Anzeigen PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-473496 UR - www.ndt.net/?id=23069 VL - 2018 SP - 1 EP - 14 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-47349 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Brückner, B. A1 - Zscherpel, Uwe T1 - Spektroskopie gepulster Röntgenquellen N2 - Spektren von gepulsten Röntgenquellen wie Blitzröhren, Linearbeschleuniger (LINACs) oder Betatrons lassen sich in der Literatur nicht finden. Eine gängige Lehrmeinung ist, dass sich solche Spektren nicht messen lassen. Deshalb wurden in Zusammenarbeit mit der Goethe-Universität Frankfurt und neuester Messtechnik diese Problematik untersucht. Es wurde ein CeBr3-Szintillator-Kristall mit einem klassischen Photoelektronenvervielfacher (PMT) und einer analogen Übertragungskette verwendet, der über Stunden Integrationszeit nur einen sehr geringen Untergrund detektiert. Als kritischter Punkt stellte sich die geeignete Kollimierung von Quelle und Detektor bei möglichst großem Abstand heraus. Zu diesem Zweck wurde das verwendete 7 MeV-Betatron in einen 3t-Bleibunker betrieben, der ein Austrittsloch von 1 mm für die erzeugte Röntgenstrahlung besaß. Der Detektor wurde mit einem Densimet-Zylinder abgeschirmt. Damit konnte die Bedingung für die Spektroskopie gepulster Quellen erreicht werden: pro Puls darf nur 1 Photon den Detektorkristall erreichen, damit ohne Pile-up seine Energie vermessen werden kann. Trotz schnellster Elektronik war es nicht möglich, mehere Photonen pro Röntgenpuls (beim Betatron ca. 1 Mikrosekunde) spektral richtig aufzulösen. Die gemessenen Spektren zeigen die erwartete Form, wie sie z.B. mit aRTist simuliert werden können. T2 - DGZfP-Jahrestagung 2018 CY - Leipzig, Germany DA - 07.05.2018 KW - Spektroskopie KW - Betatron KW - Röntgenblitzröhre PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-473505 SP - 1 EP - 2 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-47350 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ghasem Zadeh Khorasani, Media A1 - Elert, Anna Maria A1 - Hodoroaba, Vasile-Dan A1 - Agudo Jácome, Leonardo A1 - Altmann, Korinna A1 - Silbernagl, Dorothee A1 - Sturm, Heinz T1 - Short- and long-range mechanical and chemical interphases caused by interaction of Boehmite (γ-AlOOH) with anhydride-cured epoxy resins N2 - Understanding the interaction between boehmite and epoxy and the formation of their interphases with different mechanical and chemical structures is crucial to predict and optimize the properties of epoxy-boehmite nanocomposites. Probing the interfacial properties with atomic force microscopy (AFM)-based methods, especially particle-matrix long-range interactions, is challenging. This is due to size limitations of various analytical methods in resolving nanoparticles and their interphases, the overlap of interphases, and the effect of buried particles that prevent the accurate interphase property measurement. Here, we develop a layered model system in which the epoxy is cured in contact with a thin layer of hydrothermally synthesized boehmite. Different microscopy methods are employed to evaluate the interfacial properties. With intermodulation atomic force microscopy (ImAFM) and amplitude dependence force spectroscopy (ADFS), which contain information about stiffness, electrostatic, and van der Waals forces, a soft interphase was detected between the epoxy and boehmite. Surface potential maps obtained by scanning Kelvin probe microscopy (SKPM) revealed another interphase about one order of magnitude larger than the mechanical interphase. The AFM-infrared spectroscopy (AFM-IR) technique reveals that the soft interphase consists of unreacted curing agent. The long-range electrical interphase is attributed to the chemical alteration of the bulk epoxy and the formation of new absorption bands. KW - Nanocomposites KW - Interphase KW - Intermodulation AFM KW - Electron microscopy KW - Infrared nano AFM PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-483672 UR - https://www.mdpi.com/2079-4991/9/6/853/htm DO - https://doi.org/10.3390/nano9060853 SN - 2079-4991 VL - 9 IS - 6 SP - 853, 1 EP - 20 PB - MDPI AN - OPUS4-48367 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Munsch, Sarah Mandy A1 - Strangfeld, Christoph A1 - Kruschwitz, Sabine ED - Kärger, J. ED - Heitjans, P. T1 - Determining the pore size distribution in synthetic and building materials using 1D NMR N2 - NMR is gaining increasing interest in civil engineering applications for the use of microstructure characterization as e.g. pore size determination and monitoring of moisture transport in porous materials. In this study, the use of NMR as a tool for pore size characterization was investigated. For our study we used screed and synthetic materials at partial and full saturation. A successful determination could be achieved when having a reference or calibration method, although partly diffusion effects have been registered. Due to these diffusion effects, for the determination of pore size distributions of synthetic materials another NMR device was needed. Finally, the determination of the surface relaxivity of screed (50 μm/s) led to a higher value than first expected from literature. T2 - 14th International Bologna Conference on Magnetic Resonance in Porous Media CY - Gainesville, FL, USA DA - 18.02.2018 KW - NMR relaxometry KW - Pore size distribution KW - Building materials KW - Porous materials KW - Surface relaxivity PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-483680 UR - https://diffusion.uni-leipzig.de/pdf/volume31/diff_fund_31(2019)02.pdf SN - 1862-4138 N1 - Geburtsname von Munsch, Sarah Mandy: Nagel, S. M. - Birth name of Munsch, Sarah Mandy: Nagel, S. M. VL - 31 IS - 2 SP - 1 EP - 9 PB - University of Leipzig CY - Leipzig AN - OPUS4-48368 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Genath, A. A1 - Hofmann, Michael A1 - Tiebe, Carlo A1 - Einspanier, R. T1 - Proof-of-concept trial of the portable electronic nose PEN3 for detection of formic acid concentration in the beehive N2 - Formic acid (FA) treatment as measure against the ectoparasitic mite, Varroa destructor, which infests the western honey bee, Apis mellifera, is usually performed twice a year. Although the therapeutic index is very narrow and the success of FA-treatment is highly dependent on various external factors, little is known about the local FA concentrations occuring in the hive. In this study we examined whether a commercially available odour measuring device (“electronic nose”) is suitable for measurements of high FA concentrations, as present during treatment. As measuring systems, two different setups were prepared for detection of FA concentrations in gas mixtures: A polymethyl methacrylate (PMMA) box was used to investigate whether the electronic nose is able to distinguish between different FA concentrations and a two-storied Segeberger hive to test under realistic conditions during bee-keeping. In both experimental systems, the signals from the same sensor components (sensor type no. 1, 6, 7, 8 and 9) showed an increased sensitivity towards the presence of FA in the gas mixture. Principle component analysis (PCA) and linear discriminant analysis (LDA) allowed for identification of specific patterns in the measurement signals and showed clear correlations between the signals and the present FA concentration. These results indicate that the introduced commercial multi gas sensor system is suitable for detection of high FA concentrations, and therefore could be a starting point developing a detection method of FA. The future aim is to successfully monitor the efficiency and effectiveness of this anti-varroa-treatment. T2 - 20. GMA/ITG-Fachtagung Sensoren und Messsysteme 2019 CY - Nuremberg, Germany DA - 25.06.2019 KW - Apis mellifera KW - Varroa destructor KW - Formic Acid KW - Metal-Oxide Gas Sensor Array PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-483812 UR - https://www.ama-science.org/proceedings/details/3430 DO - https://doi.org/10.5162/sensoren2019/P3.10 VL - 2019 SP - 794 EP - 799 AN - OPUS4-48381 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tarantini, A. A1 - Wegner, Karl David A1 - Dussert, F. A1 - Sarret, G. A1 - Beal, D. A1 - Mattera, L. A1 - Lincheneau, C. A1 - Proux, O. A1 - Truffier-Boutry, D. A1 - Moriscot, C. A1 - Gallet, B. A1 - Jouneau, P.-H. A1 - Reiss, P. A1 - Carriere, M. T1 - Physicochemical alterations and toxicity of InP alloyed quantum dots aged in environmental conditions: A safer by design evaluation N2 - Due to their unique optical properties, quantum dots (QDs) are used in a number of optoelectronic devices and are forecasted to be used in the near future for biomedical applications. The most popular QD composition consists of cadmium selenide (CdSe) or cadmium telluride (CdTe), which has been shown to pose health risks due to the release of toxic cadmium (Cd) ions. Due to similar optical properties but lower intrinsic toxicity, indium phosphide (InP) QDs have been proposed as a safer alternative. Nevertheless, investigations regarding their safety and possible toxicological effects are still in their infancy. The fate and toxicity of seven different water-dispersible indium (In) based QDs, either pristine or after ageing in a climatic chamber, was evaluated. The core of these QDs was composed of indium, zinc and phosphorus (InZnP) or indium, zinc, phosphorus and sulfur (InZnPS). They were assessed either as core-only or as core-shell QDs, for which the core was capped with a shell of zinc, selenium and sulfur (Zn(Se,S)). Their Surface was functionalized using either penicillamine or glutathione. In their pristine form, these QDs showed essentially no cytotoxicity. The particular case of InZnPS QD showed that core-shell QDs were less cytotoxic than core-only QDs. Moreover, surface functionalization with either penicillamine or glutathione did not appreciably influence cytotoxicity but affected QD stability. These QDs did not lead to over-accumulation of reactive oxygen species in exposed cells, or to any oxidative damage to cellular DNA. However, accelerated weathering in a climatic chamber led to QD precipitation and degradation, together with significant cytotoxic effects. Ageing led to dissociation of IneP and ZneS bonds, and to complexation of In Zn ions with carboxylate and/or phosphate moieties. These results show that InZnP and InZnPS alloyed QDs are safer alternatives to CdSe QDs. They underline the necessity to preserve as much as possible the structural integrity of QDs, for instance by developing more robust shells, in order to ensure their safety for future applications. KW - Indium phosphide KW - Safe by design KW - Toxicity KW - EXAFS PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-483070 DO - https://doi.org/10.1016/j.impact.2019.100168 VL - 14 SP - 100168-1 EP - 100168-13 PB - Elsevier AN - OPUS4-48307 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - de Souza Machado, A. A. A1 - Lau, C. W. A1 - Kloas, W. A1 - Bergmann, J. A1 - Bachelier, J. B. A1 - Faltin, E. A1 - Becker, Roland A1 - Görlich, A. S. A1 - Rillig, M. C. T1 - Microplastics can change soil properties and affect plant performance N2 - Microplastics can affect biophysical properties of the soil. However, little is known about the cascade of events in fundamental levels of terrestrial ecosystems, i.e., starting with the changes in soil abiotic properties and propagating across the various components of soil−plant interactions, including soil microbial communities and plant traits. We investigated here the effects of six different microplastics (polyester fibers, polyamide beads, and four fragment types: polyethylene, polyester terephthalate, polypropylene, and polystyrene) on a broad suite of proxies for soil health and performance of spring onion (Allium fistulosum). Significant changes were observed in plant biomass, tissue elemental composition, root traits, and soil microbial activities. These plant and soil responses to microplastic exposure were used to propose a causal model for the mechanism of the effects. Impacts were dependent on particle type, i.e., microplastics with a shape similar to other natural soil particles elicited smaller differences from control. Changes in soil structure and water dynamics may explain the observed results in which polyester fibers and polyamide beads triggered the most pronounced impacts on plant traits and function. The findings reported here imply that the pervasive microplastic contamination in soil may have consequences for plant performance and thus for agroecosystems and terrestrial biodiversity. KW - Mikroplastik KW - Boden KW - Pflanzenwachstum PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-484181 DO - https://doi.org/10.1021/acs.est.9b01339 SN - 0013-936X SN - 1520-5851 VL - 53 IS - 10 SP - 6044 EP - 6052 PB - ACS AN - OPUS4-48418 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Huang, J. A1 - Tarábek, J. A1 - Kulkarni, R. A1 - Wang, Cui A1 - Dračínský, M. A1 - Smales, Glen Jacob A1 - Pauw, Brian Richard A1 - Resch-Genger, Ute A1 - Bojdys, M. J. T1 - A π-conjugated, covalent phosphinine framework N2 - Structural modularity of polymer frameworks is a key advantage of covalent organic polymers, however, only C, N, O, Si and S have found their way into their building blocks so far. Here, we expand the toolbox available to polymer and materials chemists by one additional nonmetal, phosphorus. Starting with a building block that contains a λ⁵‐phosphinine (C₅P) moiety, we evaluate a number of polymerisation protocols, finally obtaining a π‐conjugated, covalent phosphinine‐based framework (CPF‐1) via Suzuki‐Miyaura coupling. CPF‐1 is a weakly porous polymer glass (72.4 m2 g‐1 N2 BET at 77 K) with green fluorescence (λmax 546 nm) and extremely high thermal stability. The polymer catalyzes hydrogen evolution from water under UV and visible light irradiation without the need for additional co‐catalyst at a rate of 33.3 μmol h‐¹ g‐¹. Our results demonstrate for the first time the incorporation of the phosphinine motif into a complex polymer framework. Phosphinine‐based frameworks show promising electronic and optical properties that might spark future interest in their applications in light‐emitting devices and heterogeneous catalysis. KW - Phosphinine KW - Fully aromatic frameworks KW - Suzuki-Miyaura coupling KW - Polymers KW - Fluorescence KW - Small-angle scattering PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-485330 DO - https://doi.org/10.1002/chem.201900281 SP - 2 EP - 10 PB - Wiley VCH-Verlag CY - Weinheim AN - OPUS4-48533 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Belenguer, A. A1 - Michalchuk, Adam A1 - Lampronti, G A1 - Sanders, J T1 - Understanding the unexpected effect of frequency on the kinetics of a covalent reaction under ball-milling conditions N2 - We here explore how ball-mill-grinding frequency affects the kinetics of a disulfide exchange reaction. Our kinetic data show that the reaction progress is similar at all the frequencies studied (15–30 Hz), including a significant induction time before the nucleation and growth process starts. This indicates that to start the reaction an initial energy accumulation is necessary. Other than mixing, the energy supplied by the mechanical treatment has two effects: (i) reducing the crystal size and (ii) creating defects in the structure. The crystal-breaking process is likely to be dominant at first becoming less important later in the process when the energy supplied is stored at the molecular level as local crystal defects. This accumulation is taken here to be the rate-determining step. We suggest that the local defects accumulate preferentially at or near the crystal surface. Since the total area increases exponentially when the crystal size is reduced by the crystal-breaking process, this can further explain the exponential dependence of the onset time on the milling frequency. KW - Mechanochemistry KW - Kinetics KW - Diffraction PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-483361 DO - https://doi.org/10.3762/bjoc.15.120 SN - 2195-951X VL - 15 SP - 1226 EP - 1235 PB - Beilstein-Institut zur Förderung der Chemischen Wissenschaften CY - Frankfurt, M. AN - OPUS4-48336 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hahn, Marc Benjamin T1 - Temperature in micromagnetism: Cell size and scaling effects of the stochastic Landau-Lifshitz equation N2 - The movement of the macroscopic magnetic moment in ferromagnetic systems can be described by the Landau-Lifshitz (LL) or Landau-Lifshitz-Gilbert (LLG) equation. These equations are strictly valid only at absolute zero temperature. To include temperature effects a stochastic version of the LL or LLG equation for a spin density of one per unit cell can be used instead. To apply the stochastic LL to micromagnetic simulations, where the spin density per unit cell is generally higher, a conversion regarding simulation cell size and temperature has to be established. Based on energetic considerations, a conversion for ferromagnetic bulk and thin film systems is proposed. The conversion is tested in micromagnetic simulations which are performed with the Object Oriented Micromagnetic Framework (OOMMF). The Curie temperatures of bulk Nickel, Cobalt and Iron systems as well as Nickel thin-film systems with thicknesses between 6.3 mono layer (ML) and 31ML are determined from micromagnetic simulations. The results show a good agreement with experimentally determined Curie temperatures of bulk and thin film systems when temperature scaling is performed according to the presented model. KW - Micromagnetism KW - LLG KW - LL equation KW - Landau Lifshitz equation KW - Landau Lifshitz Gilbert equation KW - Stochastic Landau Lifshitz equation KW - Stochastic Landau Lifshitz Gilbert equation KW - Curie temperature KW - Magnetic Nanoparticles KW - Thin film systems KW - Temeprature scaling KW - Phase transition KW - Magnet coupling KW - Ferromagnetism KW - Superparamagnetism KW - Paramagnetism KW - Ni KW - Co KW - Fe KW - Steel KW - Nickel KW - Cobalt KW - Iron KW - Temperature effects KW - Cell size KW - Damping factor KW - Gamma KW - Alpha KW - Spin KW - Magnetic moment KW - Magnetic interacion KW - Magnetization dynamics KW - Domain wall KW - Exchange length KW - temeprature dependent exchange length KW - Bloch wall KW - Neel wall KW - Exchange interaction KW - Magnetic anisotropy KW - Simulation KW - OOMMF KW - Object oriented micromagnetic framework PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-484610 DO - https://doi.org/10.1088/2399-6528/ab31e6 VL - 3 IS - 7 SP - 075009-1 EP - 075009-8 PB - IOPscience CY - England AN - OPUS4-48461 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Joseba Ayerdi, J. A1 - Slachciak, Nadine A1 - Llavori, I. A1 - Zabala, A. A1 - Aginagalde, A. A1 - Bonse, Jörn A1 - Spaltmann, Dirk T1 - On the role of a ZDDP in the tribological performance of femtosecond laser-induced periodic surface structures on titanium alloy against different counterbody materials N2 - Laser-induced periodic surface structures (LIPSS, ripples) with ~500–700 nm period were produced on titanium alloy (Ti6Al4V) surfaces upon scan processing in air by a Ti:sapphire femtosecond laser. The tribological performance of the surfaces were qualified in linear reciprocating sliding tribological tests against balls made of different materials using different oilbased lubricants. Extending our previous work, we studied the admixture of the additive 2-ethylhexyl-zinc-dithiophosphate to a base oil containing only anti-oxidants and temperature stabilizers. The presence of this additive along with the variation of the chemical composition of the counterbodies allows us to explore the synergy of the additive with the laseroxidized nanostructures. KW - Additives KW - Surface structures KW - Wear KW - Friction PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-488458 DO - https://doi.org/10.3390/lubricants7090079 SN - 2075-4442 VL - 7 SP - 79, 1 EP - 13 PB - MDPI AN - OPUS4-48845 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Gili, A. A1 - Bischoff, B. A1 - Simon, U. A1 - Schmidt, Franziska A1 - Kober, D. A1 - Görke, O. A1 - Bekheet, M. A1 - Gurlo, A. T1 - Ceria-based dual-phase membranes for high-temperature Carbon dioxide separation: Effect of iron doping and pore generation with MgO template N2 - Dual-phase membranes for high-temperature carbon dioxide Separation have emerged as promising technology to mitigate anthropogenic greenhouse gases emissions, especially as a pre- and post-combustion separation technique in coal burning power plants. To implement These membranes industrially, the carbon dioxide permeability must be improved. In this study, Ce_(0.8) Sm_(0.2) O_(2-d) (SDC) and Ce_(0.8)Sm_(0.19)Fe_(0.01)O_(2-d) (FSDC) ceramic powders were used to form the skeleton in dual-Phase membranes. The use of MgO as an environmentally friendly pore generator allows control over the membrane porosity and microstructure in order to compare the effect of the membrane’s ceramic phase. The ceramic powders and the resulting membranes were characterized using ICP-OES, HSM, gravimetric analysis, SEM/EDX, and XRD, and the carbon dioxide flux density was quantified using a high-temperature membrane permeation setup. The carbon dioxide permeability slightly increases with the addition of iron in the FSDC membranes compared to the SDC membranes mainly due to the reported scavenging effect of iron with the siliceous impurities, with an additional potential contribution of an increased crystallite size due to viscous flow sintering. The increased permeability of the FSDC system and the proper microstructure control by MgO can be further extended to optimize carbon dioxide permeability in this membrane system. KW - Samarium doped ceria KW - SDC KW - FSDC KW - CO2 separation membranes KW - Scavenging effect of iron KW - Permeability PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-488612 DO - https://doi.org/10.3390/membranes9090108 SN - 2077-0375 VL - 9 IS - 9 SP - 108, 1 EP - 15 PB - MDPI AN - OPUS4-48861 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kricheldorf, H. R. A1 - Weidner, Steffen A1 - Scheliga, F. T1 - Synthesis of cyclic poly(l-lactide) catalyzed by Bismuth salicylates-A combination of two drugs N2 - l‐lactide was polymerized in bulk at 160 or 180°C with mixtures of bismuth subsalicylate (BiSub) and salicylic (SA) as catalysts. The SA/Bi ratio and the monomer/Bi ratio were varied. The highest molecular weights (weight average, Mw) were achieved at a SA/Bi ratio of 1/1 (Mw up to 92 000 g mol−1). l‐Lactide was also polymerized with combinations of BiSub and silylated SA, and Mw values up to 120 000 g mol−1 were achieved at 180°C. MALDI‐TOF mass spectrometry and Mark‐Houwink‐Sakurada measurements proved that under optimized reaction conditions the resulting polylactides consist of cycles. KW - Polylactide KW - MALDI-TOF MS KW - Cyclization KW - Catalyst KW - Salicylate PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-488622 DO - https://doi.org/10.1002/pola.29473 SN - 0887-624X SN - 1099-0518 SP - 29473 PB - Wiley AN - OPUS4-48862 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Palantöken, Sinam A1 - Bethke, K. A1 - Zivanovic, V. A1 - Kneipp, Janina A1 - Rademann, Klaus A1 - Kalinka, Gerhard T1 - Cellulose hydrogels physically crosslinked by glycine: Synthesis, characterization, thermal and mechanical properties N2 - Biopolymers are very efficient for significant applications ranging from tissue engineering, biological devices to water purification. There is a tremendous potential value of cellulose because of ist being the most abundant biopolymer on earth, swellability, and functional groups to be modified. A novel, highly efficient route for the fabrication of mechanically stable and natural hydrogels is described in which cellulose and glycine are dissolved in an alkaline solution of NaOH and neutralized in an acidic solution. The dissolving temperature and the glycine amount are essential parameters for the self-assembly of cellulose chains and for Tuning the morphology and the aggregate structures of the resulting hydrogels. Glycine plays the role of a physical crosslinker based on the Information obtained from FTIR and Raman spectra. Among the prepared set of hydrogels, CL5Gly30 hydrogels have the highest capacity to absorb water. The prepared CL5Gly30 gels can absorb up to seven times their dry weight due to its porous 3-D network structure. CL5Gly10 hydrogel exhibits 80% deformation under 21 N force executed. The method developed in this article can contribute to the application of heavy metal adsorption in aqueous solutions for water purification and waste management. KW - Biopolymer KW - Cellulose KW - Hydrogel KW - Natural KW - Synthesis PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-486845 DO - https://doi.org/10.1002/APP.48380 SN - 1097-4628 SN - 0021-8995 VL - 136 SP - 48380, 1 EP - 11 PB - Wiley CY - USA AN - OPUS4-48684 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kullolli, Borana A1 - Cuéllar, Pablo A1 - Baeßler, Matthias A1 - Stutz, H. H. T1 - Modelling and calibration for cyclic soil-structure interface behaviour N2 - The structural performance of many geotechnical systems (e.g. axially-loaded pile foundations), depends on the shearing resistance at the soil interface, which may govern the load bearing capacity of the foundation. Experimental investigations have shown that this interaction is mainly localised within a narrow shear band next to the structure. Under cyclic loading, a contraction of the soil at the interface may arise (net volume loss), possibly leading to a stress relaxation and thus to a reduction of the load bearing capacity (the so-called friction fatigue). Based on the constitutive similarities between soil continua and interfaces, we propose here the adaption of a Generalized Plasticity model for sandy soils for the numerical analysis of interface problems. In this contribution, the results of an experimental campaign for the parameter calibration of the constitutive model are presented. The tests have been conducted with a ring shear device involving different normal stresses, roughness of the steel plates as well as cyclic loading. The new modelling approach shows promising results and has the additional practical advantage that the interface zone and the soil continuum can both be described with the same constitutive model in general boundary value problems. T2 - Konferenz 7th International Symposium on Deformation Characteristics of Geomaterials CY - Glasgow, Scotland DA - 26.06.2019 KW - Soil-structure interaction KW - Offshore foundations PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-489096 DO - https://doi.org/10.1051/e3sconf/20199213007 VL - 92 SP - 13007 EP - 13013 PB - EDP Sciences CY - Glasgow, Scotland AN - OPUS4-48909 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Provis, J. L. A1 - Arbi, K. A1 - Bernal, S. A. A1 - Bondar, D. A1 - Buchwald, A. A1 - Castel, A. A1 - Chithiraputhiran, S. A1 - Cyr, M. A1 - Dehghan, A. A1 - Dombrowski-Daube, K. A1 - Dubey, A. A1 - Ducman, V. A1 - Gluth, Gregor A1 - Nanukuttan, S. A1 - Peterson, K. A1 - Puertas, F. A1 - van Riessen, A. A1 - Torres-Carrasco, M. A1 - Ye, G. A1 - Zuo, Y. T1 - RILEM TC 247-DTA round robin test: mix design and reproducibility of compressive strength of alkali-activated concretes N2 - The aim of RILEM TC 247-DTA ‘Durability Testing of Alkali-Activated Materials’ is to identify and validate methodologies for testing the durability of alkali-activated concretes. To underpin the durability testing work of this committee, five alkali-activated concrete mixes were developed based on blast furnace slag, fly ash, and flash-calcined metakaolin. The concretes were designed with different intended performance levels, aiming to assess the capability of test methods to discriminate between concretes on this basis. A total of fifteen laboratories worldwide participated in this round robin test programme, where all concretes were produced with the same mix designs, from single-source aluminosilicate precursors and locally available aggregates. This paper reports the mix designs tested, and the compressive strength results obtained, including critical insight into reasons for the observed variability in strength within and between laboratories. KW - Alkali-activated materials KW - Alkali-activated slag KW - Compressive strength KW - Concrete KW - Mix-design PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-489131 DO - https://doi.org/10.1617/s11527-019-1396-z SN - 1359-5997 SN - 1871-6873 VL - 52 IS - 5 SP - Article Number 99 PB - Springer Nature AN - OPUS4-48913 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hüsken, Götz A1 - Shamsuddoha, Md A1 - Thiele, Marc A1 - Baeßler, Matthias A1 - Kühne, Hans-Carsten T1 - Comparison of cracks formed in scaled grouted connection of offshore energy structures under static and cyclic loads N2 - Global energy consumption will increase in the future necessitating both fossil fuels and renewable energy choices - especially wind energy. Such high energy demand requires installation of offshore energy structures, rigs, platforms and towers, which are susceptible to adverse environmental conditions along with maintenances. Due to their large size and remote locations, cylindrical grouted joints are often adopted between substructure and foundation in these offshore platforms and wind structures such as monopiles. However, these connections are composite structures with exterior sleeve, interior pile and infill mortar. Degradation and settlements were reported inside similar connections, which were installed in last three decades. Besides, grouting in the offshore sites were proven difficult to obtain ideal load bearing capacity. In-situ loading conditions were also found to be affecting the failure mechanism inside such connections. This study aims at characterizing the nature of cracks generated in these grouted connections under both static and cyclic loading. Scaled grouted joints were manufactured using a novel reusable mold, and connections were loaded to failure to visualize the main failure patterns. An assessment between failure under these two types of load is drawn along with comparison to previously available literature. T2 - 5th International Conference on Smart Monitoring, Assessment and Rehabilitation of Civil Structures CY - Potsdam, Germany DA - 27.08.2019 KW - Grouted connection KW - Crack formation KW - Crack pattern KW - Static load KW - Cyclic load PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-487961 SP - Th.2.A.1-1 EP - Th.2.A.1-9 AN - OPUS4-48796 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Babutzka, Martin T1 - Investigation of the salinization in marine and offshore environment - test methods and challenges N2 - Salinization and contamination of metal surfaces by chloride-containing aerosols is of great importance with regard to corrosion phenomena in the maritime sector and in offshore applications. Especially Offshore Wind Turbines are exposed to extreme corrosive conditions due to high chloride concentrations in the atmosphere and the resulting high chloride deposition rates. It is of great importance to evaluate to what extent salinization of the surface influences the corrosion protection of coatings and pitting occurrence on stainless steels under atmospheric conditions to evaluate the durability of metallic building structures in offshore and marine environments. The evaluation of the scientific literature and regulatory guidelines has shown that there are still many open questions regarding the contamination of metal surfaces by chlorides. This contribution will discuss how salinization of metal surfaces is evaluated and monitored according to current standards and guidelines. Future challenges concerning test methods and the application of evaluated salinization values and deposition rates will be discussed. T2 - 5th International Conference on Smart Monitoring, Assessment and Rehabilitation of Civil Structures CY - Potsdam, Germany DA - 27.08.20019 KW - Maritime Atmosphäre KW - Versalzung KW - Maritime atmosphere KW - Salinization PY - 2019 SP - Th.2.A.5, 1 EP - 8 PB - SMAR 2019 AN - OPUS4-48905 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hussels, Maria-Teresa A1 - Chruscicki, Sebastian A1 - Arndt, Detlef A1 - Scheider, Swen A1 - Prager, Jens A1 - Homann, Tobias A1 - Habib, Abdel Karim T1 - Localization of transient events threatening pipeline integrity by fiber-optic distributed acoustic sensing N2 - Pipe integrity is a central concern regarding technical safety, availability, and environmental compliance of industrial plants and pipelines. A condition monitoring system that detects and localizes threats in pipes prior to occurrence of actual structural failure, e.g., leakages, especially needs to target transient events such as impacts on the pipe wall or pressure waves travelling through the medium. In the present work, it is shown that fiber-optic distributed acoustic sensing (DAS) in conjunction with a suitable application geometry of the optical fiber sensor allows to track propagating acoustic waves in the pipeline wall on a fast time-scale. Therefore, short impacts on the pipe may be localized with high fidelity. Moreover, different acoustic modes are identified, and their respective group velocities are in good agreement with theoretical predications. In another set of experiments modeling realistic damage scenarios, we demonstrate that pressure waves following explosions of different gas mixtures in pipes can be observed. Velocities are verified by local piezoelectric pressure transducers. Due to the fully distributed nature of the fiber-optic sensing system, it is possible to record accelerated motions in detail. Therefore, in addition to detection and localization of threatening events for infrastructure monitoring, DAS may provide a powerful tool to study the development of gas explosions in pipes, e.g., investigation of deflagration-to-detonation-transitions (DDT). KW - Distributed acoustic sensing (DAS) KW - Distributed vibrations sensing (DVS) KW - Fiber-optic sensing KW - Condition monitoring KW - Pipeline integrity KW - Gas explosion PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-488555 DO - https://doi.org/10.3390/s19153322 SN - 1424-8220 VL - 19 IS - 15 SP - 3322, 1 EP - 20 PB - MDPI CY - Basel, CH AN - OPUS4-48855 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Liehr, Sascha A1 - Münzenberger, Sven A1 - Krebber, Katerina T1 - Wavelength-scanning distributed acoustic sensing for structural monitoring and seismic applications N2 - We introduce wavelength-scanning coherent optical time domain reflectometry (WS-COTDR) for dynamic vibration sensing along optical fibers. The method is based on spectral shift computation from Rayleigh backscatter spectra. Artificial neural networks (ANNs) are used for fast and high-resolution strain computation from raw measurement data. The applicability of the method is demonstrated for vibration monitoring of a reinforced concrete bridge. We demonstrate another application example for quasi-static and dynamic measurement of ground deformation and surface wave propagation along a dark fiber in a telecommunication cable. T2 - 7th International Symposium on Sensor Science CY - Napoli, Italy DA - 09.05.2019 KW - Optical fiber sensor KW - Distributed acoustic sensor (DAS) KW - Optical time domain reflectometry KW - Rayleigh scattering KW - Artificial neural networks KW - Structural health monitoring KW - Seismic measurement PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-487733 DO - https://doi.org/10.3390/proceedings2019015030 SN - 2504-3900 VL - 15 SP - Paper 30, 1 EP - 5 PB - MDPI CY - Basel AN - OPUS4-48773 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schwarz, W. A1 - Wilsch, Gerd A1 - Pichelhöfer, A. A1 - Ebell, Gino A1 - Völker, Tobias T1 - Galvanic chloride extraction by an embedded zinc anode: Ion distribution mapped by laser induced breakdown spectroscopy (LIBS) N2 - An important aspect with regard to the service life of zinc based galvanic anodes and the durability of the corrosion protection of steel in concrete is the “galvanic chloride extraction”. Chloride ions move in the electric field generated by the current, flowing between the galvanic anode and the cathodic steel. Migration leads to an accumulation of anions, e.g. chloride ions, at the anode and depletion of chlorides near the steel rebar surface. The ion migration was studied on steel reinforced concrete specimens admixed with 3 wt.% chloride/wt. cement and galvanically protected by a surface applied embedded zinc anode (EZA). The zinc anode was embedded and glued to the concrete surface by a geo-polymer based chloride free binder. The EZA was operated over a period of 1 year and the ion distribution between anode (EZA) and cathode (steel reinforcement) was studied by laser induced breakdown spectroscopy (LIBS) after 5 months, 7 months and 12 months. The results show that chloride ions efficiently migrate in the direction of the zinc-anode and accumulate there. Chloride distribution in the EZA correlates with the distribution of zinc ions generated by the anodic dissolution of the zinc anode in the binder matrix. The microstructure of the binder matrix and its interface to the zinc-anode are studied by REM/EDX – preliminary results will be reported. T2 - Concrete Solutions 2019 CY - Cluj Napoca, Romania DA - 30.09.2019 KW - Galvanic corrosion KW - Corrosion KW - Chloride extraction PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-488189 DO - https://doi.org/10.1051/matecconf/201928903010 VL - 289 SP - 03010, 1 EP - 5 PB - MATEC Web of Conferences AN - OPUS4-48818 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Priebe, Nsesheye Susan A1 - Gluth, Gregor A1 - Sturm, Patrick A1 - Vogler, Nico A1 - Kühne, Hans-Carsten T1 - Comparison of calcined illitic clays (brick clays) and low-grade kaolinitic clays as supplementary cementitious materials N2 - The use of calcined clays as supplementary cementitious materials (SCMs) has been identified as a viable option to decrease the CO2 emissions related to cement production. However, while extensive data is available about kaolinitic clays in this context, other clays such as illitic clays appear to be under-studied. Therefore, in the present study, two illitic clays were compared to two low-grade kaolinitic clays in terms of transformations in the calcination temperature range 650–900 °C, and performance of the calcined clays in blended cement pastes as measured by strength evolution, heat release, hydrated phase formation and portlandite consumption. The illitic clays required a higher calcination temperature for complete dehydroxylation of their illite than what is necessary for dehydroxylation of kaolinite. These higher calcination temperatures also led to particle sintering, significantly decreasing the specific surface area of the illitic clays, particularly for the clay with the higher Fe2O3 content. Nevertheless, while the kaolinitic clays generally exhibited the best performance as SCM, the illitic clay with lower Fe2O3 content performed similar to the kaolinitic clays when calcined at optimum temperature and applied at a moderate substitution rate. These findings demonstrate that several different clays have the potential to be used as SCM and indicate possible routes to identify suitable deposits for this purpose. KW - Blended cement KW - Calcined clay KW - Brick clay KW - Illite KW - Kaolinite PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-488195 DO - https://doi.org/10.1617/s11527-019-1393-2 SN - 1359-5997 SN - 1871-6873 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. VL - 52 IS - 5 SP - Article Number 94 PB - Springer Nature AN - OPUS4-48819 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stroh, Julia A1 - Feiler, Torvid A1 - Ali, N. Z. A1 - Minas da Piedade, M. E. A1 - Emmerling, Franziska T1 - Mechanistic Insights into a Sustainable Mechanochemical Synthesis of Ettringite N2 - Mechanochemistry offers an environmentally benign and facile synthesis method for a variety of cement paste constituents. In addition, these methods can be used to selectively tune the properties of cement components. The mineral ettringite is an important component of cementitious materials and has additional technological potential due to its ion exchange properties. Synthesis of ettringite via mechanochemistry is an environmentally friendly alternative to conventional wet-chemical synthesis established in industry. This contribution explores the mechanism of a two-step mechanochemical synthesis of ettringite, which was previously found to greatly improve the reaction conversion as compared with one-pot synthesis. The crystallinity of Al(OH)3 was found to decrease during the first stage of this mechanochemical synthesis. This was correlated to a significant decrease in the particle size of Al(OH)3 in this stage. No other significant changes were found for the other components, suggesting that mechanochemical activation of Al(OH)3 is responsible for the enhanced formation of ettringite by the two-step approach. The environmentally friendly approach developed for ettringite synthesis offers a versatile synthetic strategy, which can be applied to synthesise further cementitious materials. KW - Ettringite KW - Mechanochemistry KW - Sustainability KW - X-ray diffraction PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-489172 DO - https://doi.org/10.1002/open.201900215 VL - 8 IS - 7 SP - 1012 EP - 1019 PB - ChemPubSoc AN - OPUS4-48917 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Borzekowski, Antje A1 - Anggriawan, R. A1 - Auliyati, M. A1 - Kunte, Hans-Jörg A1 - Koch, Matthias A1 - Rohn, S. A1 - Karlovsky, P. A1 - Maul, Ronald T1 - Formation of Zearalenone Metabolites in Tempeh Fermentation N2 - Tempeh is a common food in Indonesia, produced by fungal fermentation of soybeans using Rhizopus sp., as well as Aspergillus oryzae, for inoculation. Analogously, for economic reasons, mixtures of maize and soybeans are used for the production of so-called tempeh-like products. For maize, a contamination with the mycoestrogen zearalenone (ZEN) has been frequently reported. ZEN is a mycotoxin which is known to be metabolized by Rhizopus and Aspergillus species. Consequently, this study focused on the ZEN transformation during tempeh fermentation. Five fungal strains of the genera Rhizopus and Aspergillus, isolated from fresh Indonesian tempeh and authentic Indonesian inocula, were utilized for tempeh manufacturing from a maize/soybean mixture (30:70) at laboratory-scale. Furthermore, comparable tempeh-like products obtained from Indonesian markets were analyzed. Results from the HPLC-MS/MS analyses show that ZEN is intensely transformed into its metabolites alpha-zearalenol (alpha-ZEL), ZEN-14-sulfate, alpha-ZEL-sulfate, ZEN-14-glucoside, and ZEN-16-glucoside in tempeh production. alpha-ZEL, being significantly more toxic than ZEN, was the main metabolite in most of the Rhizopus incubations, while in Aspergillus oryzae fermentations ZEN-14-sulfate was predominantly formed. Additionally, two of the 14 authentic samples were contaminated with ZEN, alpha-ZEL and ZEN-14-sulfate, and in two further samples, ZEN and alpha-ZEL, were determined. Consequently, tempeh fermentation of ZEN-contaminated maize/soybean mixture may lead to toxification of the food item by formation of the reductive ZEN metabolite, alpha-ZEL, under model as well as authentic conditions. KW - Modified mycotoxins KW - Zearalenone sulfate KW - a-zearalenol KW - Food fermentation KW - Rhizopus and Aspergillus oryzae PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-491126 DO - https://doi.org/10.3390/molecules24152697 VL - 24 IS - 15 SP - 2697 PB - MDPI AN - OPUS4-49112 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nöller, Renate A1 - Feldmann, Ines A1 - Kasztovszky, Z. A1 - Szőkefalvi-Nagy, Z. A1 - Kovács, I. T1 - Characteristic Features of Lapis Lazuli from Different Provenances, Revised by µXRF, ESEM, PGAA and PIXE N2 - The objective of this study is to find out, to what extent the geochemical characteristics of lapis lazuli can be utilized in respect to its provenance. A wide range of variables is taken into consideration depending on the quantity of samples analysed from a specific geological region and the methods applied. In order to provide evidence, a multi-technique analytical approach using µXRF, ESEM, PGAA and PIXE is applied to samples from the most famous deposits of lapis lazuli. Special elements determined as fingerprints are compared in relation to the forming conditions obvious in textural features. The results and statistical output allow a differentiation that enables an optimized local classification of the blue stone. An absolute requirement for all geo-tracing performed on blue colored cultural objects of unknown provenance is awareness of the limits of analysis. The possible sources of lapis lazuli are tested by analysing the blue pigment used as paint on murals and ink on manuscripts from the Silk Road. KW - Lapis lazuli KW - Micro-XRF KW - ESEM KW - PGAA KW - PIXE KW - Pigment analyses KW - Provenance studies PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-491181 DO - https://doi.org/10.17265/2328-2193/2019.02.003 SN - 2328-2193 VL - 7 IS - 2 SP - 57 EP - 69 PB - David CY - New York, NY AN - OPUS4-49118 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wosniok, Aleksander A1 - Jansen, R. A1 - Chen, L. A1 - Toet, P. A1 - Doppenberg, E. A1 - De Jong, W. A1 - Chruscicki, Sebastian T1 - Static load monitoring of a concrete bridge using a high-precision distributed fiber optic sensor system N2 - In the present study, the impact of static traffic loading on the slight deflection effects in the concrete structure of an existing bridge has been investigated using distributed fiber optic sensors. In the face of increasing traffic density and severe traffic loading, the results of the load tests on the Amsterdam bridge 705 make an important contribution to the understanding of its structural behavior. The concept of the static loading was based on the use of two 36-ton trucks stopped on the bridge at multiple pre-determined locations. The load applied in this way led to location-dependent small deflection effects recorded as longitudinal strain of the sensing fiber embedded at the underside of the bridge. The measurements were performed with a commercially-available solution based on Tunable Wavelength Coherent Optical Time Domain Reflectometry with the measurement accuracy in the range of 0.5 µm/m. T2 - 5th International Conference on Smart Monitoring, Assessment and Rehabilitation of Civil Structures CY - Potsdam, Germany DA - 27.08.2019 KW - Bridge monitoring KW - Distributed fiber optic sensing KW - Static load monitoring KW - TW-COTDR PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-490408 SP - 1 EP - 8 AN - OPUS4-49040 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Beckmann, Jörg ED - Spranger, Holger T1 - Synthetische Aperturfokussierung für die Terahertzspektroskopie N2 - Die zeitaufgelöste THz-Spektroskopie (THz-TDS) operiert mit elektromagnetischen Impulsen, die ein Amplitudenspektrum im unteren THz-Bereich aufweisen. Die THz-TDS ist in der Lage, dielektrische Volumina zerstörungs- und kontaktfreie zu durchstrahlen. Um eine 3D-THz Bildung zu ermöglichen, wurde für die THz-TDS ein rechnergestütztes Mess- und Rekonstruktionsverfahren (THz-TDSAFT) entwickelt, mit dem es gelingt, unter Verwendung der im Zeitbereich registrierten THz-TDS-Daten das Volumeninnere in Form eines dreidimensionalen Tomogramms zu rekonstruieren. Die THz-TD-SAFT basiert auf die für die Ultraschalltechnik entwickelte Synthetische Apertur Fokussierung (SAFT) bzw. des heuristisch begründeten Algorithmus des Synthetischen Apertur Radars (SAR). Anhand von Beispielen wird die Möglichkeiten der THz-TD-SAFT demonstriert und nachgewiesen, dass mit dem Rekonstruktionsansatz die künstlich eingebauten Fehlstellen bezüglich der Position und Größe geometrisch richtig im Tomogramm abgebildet werden können. T2 - 4. Fachseminar des FA MTHz, Mikrowellen- und Terahertz-Prüftechnik in der Praxis CY - Fürth, Germany DA - 02.04.2019 KW - THz-TDS KW - Tomographie, KW - Zerstörungsfreie Prüfung PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-490481 UR - https://www.ndt.net/search/docs.php3?MainSource=262 SP - 1 EP - 8 PB - DGZfP CY - Berlin AN - OPUS4-49048 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rahrig, M. A1 - Torge, Manfred T1 - 3D inspection of the restoration and conservation of stained glass windows using high resolution structured light scanning N2 - The initial focus of this research was on the development of a general workflow for the documentation and monitoring of historical stained glass windows using structured light scanning. Therefore windows from different churches, time periods and with different corrosion and damage phenomena were scanned before and after conservation measures. To evaluate the execution of the restoration measures the data was compared using 3D inspection software to examine the differences in geometry between the two scans. Various problems had to be solved, for example, how to deal with heavily reflective surfaces and the extreme contrast between light and dark surfaces, as seen in the borders between ‘Schwarzlot’ painting and plain glass. The application of materials for matting the surfaces, such as Cyclododecane spray, was impossible due to the high accuracy of the surface measurement required for 3D inspection. Regarding the contrast differences of the surfaces, the creation of exposure fusions and the use of polarization filters to reduce reflections were tested. In addition to the general problems encountered when recording translucent surfaces, the historical glasses caused additional problems in calculating surface comparisons. For example, the windows have to be moved and turned around several times, both during the conservation process and while scanning, causing deformations of the geometry due to the flexible lead rods allowing a certain degree of movement. T2 - 27th CIPA International Symposium “Documenting the past for a better future” CY - Ávila, Spain DA - 01.09.2019 KW - Stained glass KW - Restoration and conservation KW - Structured light scanning KW - 3D inspection KW - Glass scanning PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-491286 DO - https://doi.org/10.5194/isprs-archives-XLII-2-W15-965-2019 VL - XLII-2/W15 SP - 965 EP - 972 PB - International Society of Photogrammetry and Remote Sensing (ISPRS) CY - Hannover AN - OPUS4-49128 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bartelmeß, Jürgen A1 - Valderrey, Virginia A1 - Rurack, Knut T1 - Development of a “Turn-on” Fluorescent Probe-Based Sensing System for Hydrogen Sulfide in Liquid and Gas Phase N2 - A “turn-on” fluorescence sensing system based on a BODIPY-cobaloxime complex for the detection of H2S in liquid and gas phase was developed. To that aim, two cobaloxime complexes bearing an axial pyridyl-BODIPY ligand were initially evaluated as sensitive fluorescent HS− indicators in aqueous solution. The sensing mechanism involves the selective substitution of the BODIPY ligand by the HS− anion at the cobalt center, which is accompanied by a strong fluorescence enhancement. The selection of a complex with an ideal stability and reactivity profile toward HS− relied on the optimal interaction between the cobalt metal-center and two different pyridyl BODIPY ligands. Loading the best performing BODIPY-cobaloxime complex onto a polymeric hydrogel membrane allowed us to study the selectivity of the probe for HS− against different anions and cysteine. Successful detection of H2S by the fluorescent “light-up” membrane was not only accomplished for surface water but could also be demonstrated for relevant H2S concentrations in gas phase. KW - Sulfide sensing KW - Fluorescence KW - BODIPYs KW - Cobaloxime complex KW - Gas sensing PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-492186 DO - https://doi.org/10.3389/fchem.2019.00641 SN - 2296-2646 VL - 7 SP - Art. Nr. 641 PB - Frontiers Media CY - Lausanne AN - OPUS4-49218 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zocca, Andrea A1 - Lüchtenborg, Jörg A1 - Mühler, T. A1 - Wilbig, Janka A1 - Mohr, Gunther A1 - Villatte, T. A1 - Léonard, Fabien A1 - Nolze, Gert A1 - Sparenberg, M. A1 - Melcher, J. A1 - Hilgenberg, Kai A1 - Günster, Jens T1 - Enabling the 3D Printing of Metal Components in μ-Gravity N2 - As humanity contemplates manned missions to Mars, strategies need to be developed for the design and operation of hospitable environments to safely work in space for years. The supply of spare parts for repair and replacement of lost equipment will be one key need, but in-space manufacturing remains the only option for a timely supply. With high flexibility in design and the ability to manufacture ready-to-use components directly from a computeraided model, additive manufacturing (AM) technologies appear extremely attractive. For the manufacturing of metal parts, laser-beam melting is the most widely used AM process. However, the handling of metal powders in the absence of gravity is one prerequisite for its successful application in space. A gas flow throughout the powder bed is successfully applied to compensate for missing gravitational forces in microgravity experiments. This so-called gas-flow-assisted powder deposition is based on a porous Building platform acting as a filter for the fixation of metal particles in a gas flow driven by a pressure difference maintained by a vacuum pump. KW - Additive manufacturing KW - µ-gravity KW - Laser beam melting KW - Parabolic flight KW - 3D printing PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-492190 DO - https://doi.org/10.1002/admt.201900506 SP - 1900506 PB - WILEY-VCH Verlag GmbH AN - OPUS4-49219 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Habib, Abdel Karim A1 - Schalau, Bernd T1 - Pool evaporation - experimental data collection and modelling N2 - When handling flammable or toxic liquids or liquefied gases, the occurrence of a leakage and formation of a liquid pool is a scenario to be considered for risk assessment. Several models are available for the estimation of the evaporating mass flow, but only a very reduced number of experimental data is available for Validation purposes. In the last years, the Federal Institute for Materials Research and Testing (BAM) in Berlin, Germany, carried out pool Evaporation experiments with different substances in basins with a Diameter ranging from 0,50 m to 1 m mainly on open air test sites with a built up (inner city) and a non-built-up (flat terrain) topography, but also in an enclosed space. The resulting experimental data sets cover a range of vapor pressures from 0,1 bar to 0,94 bar. The aim of this work is to make the füll data set publicly available and to provide a description of the experimental boundary conditions. Based on these data, a Validation of existing pool Evaporation models has been carried out and eventually led to a new formulation of an evaporation model, which is also presented here, covering the whole ränge from low wind speeds up to high vapor pressures. KW - Lache KW - Verdunstung KW - Verdampfung KW - Dampfdruck KW - Windgeschwindigkeit PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-491826 DO - https://doi.org/10.1002/ceat.201800093 VL - 42 IS - 11 SP - 2450 EP - 2457 PB - WILEY‐VCH Verlag GmbH & Co. KGaA CY - Weinheim AN - OPUS4-49182 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Herrmann, Ralf A1 - Moortgat-Pick, A. A1 - Marx, S. ED - Helmerich, Rosemarie ED - Ilki, A. ED - Motavalli, M. T1 - Vibration Analysis of Structures using a Drone (UAV) based Mobile Sensing Platform N2 - The identification of the dynamic behavior of structures, like bridges and towers, is relevant to address multiple issues. In many cases the dynamic parameters should be acquired only once or at a frequency that doesn’t justify the installation of distinct vibration sensors for a long-term monitoring. To identify modal frequencies of a structure, a drone based mobile sensing platform has been implemented. This sensing platform measures the relative displacement be-tween the structure and the drone, which also shows a strong dynamic behavior under wind tur-bulences. By regarding the dynamic model of the drone and additional measurements at the dis-tance sensor the absolute movement of the structure can be estimated based on the measured relative distance. This time domain data is a suitable input for various operational modal analysis algorithms. The system has been used to identify the dynamic properties of test and real structure, like a 1.5 MW wind turbine tower. T2 - 5th International Conference on Smart Monitoring, Assessment and Rehabilitation of Civil Structures (SMAR 2019) CY - Potsdam, Germany DA - 27.08.2019 KW - Modal Analysis KW - Drone KW - Vibration KW - Wind Turbines KW - Bridges PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-492045 UR - http://data.smar-conferences.org/downloads/SMAR_2019_Proceedings.zip SN - 978-3-947971-07-7 SP - We.4.C.3 EP - 8 PB - German Society for Non-Destructive Testing (DGZfP e.V.) AN - OPUS4-49204 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schwibbert, Karin A1 - Menzel, F. A1 - Epperlein, N. A1 - Bonse, Jörn A1 - Krüger, Jörg T1 - Bacterial adhesion on femtosecond laser-modified polyethylene N2 - In this study, femtosecond laser-induced sub-micrometer structures are generated to modify polyethylene (PE) surface topographies. These surfaces were subjected to bacterial colonization studies with Escherichia coli and Staphylococcus aureus as test strains. The results reveal that the nanostructures do not influence S. aureus coverage, while the adhesion of E. coli is reduced. KW - Bacterial adhesion KW - Laser-modified surface KW - Polyethylene KW - Laser-induced nanostructures KW - Biofilm PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-492280 DO - https://doi.org/10.3390/ma12193107 VL - 12 IS - 19 SP - 3107 PB - MDPI CY - Basel, Schweiz AN - OPUS4-49228 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Herrmann, K. A1 - Pech May, Nelson Wilbur A1 - Retsch, M. T1 - Photoacoustic thermal characterization of low thermal diffusivity thin films N2 - The photoacoustic measurement technique is a powerful yet underrepresented method to characterize the thermal transport properties of thin films. For the case of isotropic low thermal diffusivity samples, such as glasses or polymers, we demonstrate a general approach to extract the thermal conductivity with a high degree of significance. We discuss in particular the influence of thermal effusivity, thermal diffusivity, and sample layer thickness on the significance and accuracy of this measurement technique. These fundamental thermal properties guide sample and substrate selection to allow for a feasible thermal transport characterization. Furthermore, our data evaluation allows us to directly extract the thermal conductivity from this transient technique, without separate determination of the volumetric heat capacity, when appropriate boundary conditions are fulfilled. Using silica, poly(methyl methacrylate) (PMMA) thin films, and various substrates (quartz, steel, and silicon), we verify the quantitative correctness of our analytical approach. KW - Thermal conductivity KW - Photoacoustic characterization KW - Thin film characterization PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-528743 DO - https://doi.org/10.1016/j.pacs.2021.100246 SN - 2213-5979 VL - 22 SP - 100246 PB - Elsevier AN - OPUS4-52874 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pech May, Nelson Wilbur A1 - Tabasco-Novelo, Carolina A1 - Quintana, Patricia A1 - Rodriguez-Gattorno, Geonel A1 - Alvarado-Gil, Juan J. T1 - Evidence of a Thermal Diffusivity Gap in Sintered Li–Co–Sb–O Solid Solutions N2 - In this work, the thermal properties of ternary Li₃ₓCo₇₋₄ₓSb₂₊ₓO₁₂ solid solutions are studied for different concentrations in the range 0 ≤ x ≤ 0.7. Samples are elaborated at four different sintering temperatures: 1100, 1150, 1200 and 1250 °C. The effect of increasing the content of Li⁺ and Sb⁵⁺, accompanied by the reduction of Co²⁺, on the thermal properties is studied. It is shown that a thermal diffusivity gap, which is more pronounced for low values of x, can be triggered at a certain threshold sintering temperature (around 1150 °C in this study). This effect is explained by the increase of contact area between adjacent grains. Nevertheless, this effect is found to be less pronounced in the thermal conductivity. Moreover, a new framework for heat diffusion in solids is presented that establishes that both the heat flux and the thermal energy (or heat) satisfy a diffusion equation and therefore highlights the importance of thermal diffusivity in transient heat conduction phenomena. KW - General Chemical Engineering KW - General Chemistry PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-593248 DO - https://doi.org/10.1021/acsomega.2c07557 SN - 2470-1343 VL - 8 IS - 8 SP - 7808 EP - 7815 PB - American Chemical Society (ACS) CY - Washington, DC AN - OPUS4-59324 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Breese, Philipp Peter A1 - Becker, Tina A1 - Oster, Simon A1 - Altenburg, Simon A1 - Metz, C. A1 - Maierhofer, Christiane T1 - Aktive Laserthermografie im L-PBF-Prozess zur in-situ Detektion von Defekten N2 - Die zerstörungsfreie Prüfung von metallischen Bauteilen hergestellt mit additiver Fertigung (Additive Manufacturing - AM) gewinnt zunehmend an industrieller Bedeutung. Grund dafür ist die Feststellung von Qualität, Reproduzierbarkeit und damit auch Sicherheit für Bauteile, die mittels AM gefertigt wurden. Jedoch wird noch immer ex-situ geprüft, wobei Defekte (z.B. Poren, Risse etc.) erst nach Prozessabschluss entdeckt werden. Übersteigen Anzahl und/oder Abmessung die vorgegebenen Grenzwerte für diese Defekte, so kommt es zu Ausschuss, was angesichts sehr langer Bauprozessdauern äußerst unrentabel ist. Eine Schwierigkeit ist dabei, dass manche Defekte sich erst zeitverzögert zum eigentlichen Materialauftrag bilden, z.B. durch thermische Spannungen oder Schmelzbadaktivitäten. Dementsprechend sind reine Monitoringansätze zur Detektion ggf. nicht ausreichend. Daher wird in dieser Arbeit ein Verfahren zur aktiven Thermografie an dem AM-Prozess Laser Powder Bed Fusion (L-PBF) untersucht. Das Bauteil wird mit Hilfe des defokussierten Prozesslasers bei geringer Laserleistung zwischen den einzelnen gefertigten Lagen unabhängig vom eigentlichen Bauprozess erwärmt. Die entstehende Wärmesignatur wird ort- und zeitaufgelöst durch eine Infrarotkamera erfasst. Durch diese der Lagenfertigung nachgelagerte Prüfung werden auch zum Bauprozess zeitversetzte Defektbildungen nachweisbar. In dieser Arbeit finden die Untersuchungen als Proof-of-Concept, losgelöst vom AM-Prozess, an einem typischen metallischen Testkörper statt. Dieser besitzt eine Nut als oberflächlichen Defekt. Die durchgeführten Messungen finden an einer eigens entwickelten L-PBF-Forschungsanlage innerhalb der Prozesskammer statt. Damit wird ein neuartiger Ansatz zur aktiven Thermografie für L-PBF erforscht, der eine größere Bandbreite an Defektarten auffindbar macht. Der Ansatz wird validiert und Genauigkeit sowie Auflösungsvermögen geprüft. Eine Anwendung am AM-Prozess wird damit direkt forciert und die dafür benötigten Zusammenhänge werden präsentiert. T2 - DGZfP-Jahrestagung 2022 CY - Kassel, Germany DA - 23.05.2022 KW - Additive Manufacturing KW - Laser Powder Bed Fusion KW - Thermografie KW - Zerstörungsfreie Prüfung KW - Aktive Laserthermografie PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-550353 SN - 978-3-947971-25-1 VL - 177 SP - 1 EP - 9 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung e.V. AN - OPUS4-55035 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Metz, Christian A1 - Franz, Philipp A1 - Fischer, C. A1 - Wachtendorf, Volker A1 - Maierhofer, Christiane T1 - Active thermography for quality assurance of 3D-printed polymer structures N2 - Additively manufactured test specimens made of polyamide 12 (PA 12) by Laser Sintering (LS) as well as of acrylnitril-butadien-styrol (ABS) by Fused Layer Modeling (FLM), were tested with active thermography. For this, two different excitation methods (flash and impulse excitation) were used and compared, regarding the suitability for the detection of constructed and imprinted defects. To increase the quality of the thermograms, data processing methods like thermal signal reconstruction (TSR) and Fourier-Transformation were applied. Furthermore, the long-term stability of the probes towards environmental stress, like UV-radiation, heat, water contact and frost is being investigated in the presented project with artificial weathering tests. T2 - 14th Quantitative InfraRed Thermography Conference CY - Berlin, Germany DA - 25.06.2018 KW - Additive manufacturing KW - Active thermography KW - Artificial weathering PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-453919 SP - Tu.3.A.2, 1 EP - 9 AN - OPUS4-45391 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pohl, Rainer A1 - Casperson, Ralf A1 - Maierhofer, Christiane A1 - Müller, Jan A1 - Pelkner, Matthias T1 - Gegenüberstellung von Wirbelstromprüfung und aktiver Thermografie an CFK-Versuchskörpern N2 - In vielen Bereichen der Technik haben Konstruktionen unter Einsatz von CFK-Bauteilen und Komponenten die klassischen Metalle abgelöst. Die zerstörungsfreie Prüfung solcher CFK-Bauteile gewinnt somit zunehmend an Bedeutung. Ein mögliches Prüfverfahren ist dabei die Wirbelstromprüfung. Aufgrund der relativ geringen elektrischen Leitfähigkeit von CFK-Komponenten kommt hierbei häufig die sogenannte HF-Wirbelstromprüfung zum Einsatz. In verschiedenen Untersuchungen der BAM konnten jedoch auch mit Wirbelstromprüfsystemen in niedrigen Frequenzbereichen gute Ergebnisse erzielt werden. Um die Möglichkeiten und Grenzen dieser konventionellen Wirbelstromprüfung auszuloten, wurden Messungen an Versuchskörpern durchgeführt, welche bereits bei der Validierung der Blitz- und Lock-in-Thermografie für neue Verfahrensnormen erfolgreich eingesetzt wurden. Ein Typ dieser Versuchskörper sind Flachproben aus CFK von 6 mm Dicke. In diesen wurden Flachbodenbohrungen mit Durchmessern zwischen 4 mm und 24 mm eingebracht. Die Restwandstärken liegen zwischen 0,06 mm und 3,66 mm. Ein weiterer CFK-Versuchskörper hat die Geometrie eines Stufenkeiles. Bei verschiedenen Stufenkeilen sind Wanddicken zwischen 1,4 mm und 5,4 mm realisiert worden. In diesen wurden künstliche quadratische Delaminationen mit Kantenlängen zwischen 2 mm und 20 mm eingebracht. Die Ergebnisse der Wirbelstromprüfung werden denen der aktiven Thermografie gegenübergestellt. Zur Nachbildung von Kompositwerkstoffen wurden die flachen Versuchskörper mit geeigneten Versuchskörpern aus Aluminium und Stahl kombiniert. Die Wirbelstromprüfungen wurden mit einem handelsüblichen Prüfgerät im Frequenzbereich zwischen 500 Hz und 3 MHz und entsprechend angepassten Sensoren durchgeführt. T2 - DGZfP Jahrestagung 2017 CY - Koblenz, Germany DA - 22.05.2017 KW - Wirbelstromprüfung KW - Aktive Thermografie KW - CFK PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-403607 SN - 978-3-940283-85-6 VL - 162 SP - 1 EP - 10 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) CY - Berlin AN - OPUS4-40360 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlichting, Joachim A1 - Steinfurth, Henrik A1 - Maierhofer, Christiane A1 - Kreutzbruck, Marc T1 - Thermografische Prüfung von Punktschweißverbindungen N2 - Vor allem in der Automobilindustrie wird das Widerstandpunktschweißen im großen Unfang zur Verbindung von Blechen im Karosseriebau verwendet. Durch den anhaltenden Trend zum Leichtbau und den immer höheren Anforderungen an die passive Sicherheit kommt es hier zu einem verstärkten Einsatz innovativer hochfester Stähle. Obwohl es sich beim Punktschweißen um ein lange erprobtes Verfahren handelt, das sich anhand der Prozessparameter und regelmäßiger zerstörender Prüfung überwachen lässt, ist durch diese Entwicklung die Suche nach geeigneten zerstörungsfreien Prüfverfahren wieder aktuell. Wegen der hohen Produktionsgeschwindigkeiten in der automatisierten Fertigung muss sich das Prüfverfahren für eine hundertprozentige Prüfung vollautomatisch mit der typischen Taktrate von etwa einem Hertz durchführen lassen. In dieser Arbeit wird zuerst die prinzipielle Durchführbarkeit der thermografischen Prüfung von Punktschweißverbindungen an speziell präparierten Proben überprüft. Auf dieser Grundlage wird eine Serienuntersuchung an 75 Proben, die sich auf drei Gruppen von Schweißparametern aufteilen und neben optimal geschweißten Proben typische Fehlerbilder repräsentieren, eine Serienuntersuchung gezeigt. Hierzu wird eine Blitzlichtanregung in Transmissionsanordnung verwendet. Es kann gezeigt werden, dass sich mit einer geeigneten Datenaufbereitung die einzelnen Gruppen sicher trennen lassen. Durch eine statistische Bewertung der Ergebnisse kann unter Verwendung eines angepassten Gütekriteriums die Trennschärfe noch deutlich erhöht werden. T2 - DGZfP-Jahrestagung 2011 CY - Bremen, Germany DA - 30.05.2011 KW - Aktive Thermografie KW - Blitzlichtanregung KW - Punktschweißverbindung KW - Transmissionsmessung PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-249915 SN - 978-3-940283-33-7 IS - DGZfP-BB 127 (Di.1.C.3) SP - 1 EP - 7 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) AN - OPUS4-24991 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lecompagnon, Julien A1 - Ahmadi, Samim A1 - Hirsch, Philipp Daniel A1 - Rupprecht, C. A1 - Ziegler, Mathias T1 - Thermographic detection of internal defects using 2D photothermal super resolution reconstruction with sequential laser heating N2 - Thermographic photothermal super resolution reconstruction enables the resolution of internal defects/inhomogeneities below the classical limit, which is governed by the diffusion properties of thermal wave propagation. Based on a combination of the application of special sampling strategies and a subsequent numerical optimization step in post-processing, thermographic super resolution has already proven to be superior to standard thermographic methods in the detection of one-dimensional defect/inhomogeneity structures. In our work, we report an extension of the capabilities of the method for efficient detection and resolution of defect cross sections with fully two-dimensional structured laser-based heating. The reconstruction is carried out using one of two different algorithms that are proposed within this work. Both algorithms utilize the combination of several coherent measurements using convex optimization and exploit the sparse nature of defects/inhomogeneities as is typical for most nondestructive testing scenarios. Finally, the performance of each algorithm is rated on reconstruction quality and algorithmic complexity. The presented experimental approach is based on repeated spatially structured heating by a high power laser. As a result, a two-dimensional sparse defect/inhomogeneity map can be obtained. In addition, the obtained results are compared with those of conventional thermographic inspection methods that make use of homogeneous illumination. Due to the sparse nature of the reconstructed defect/inhomogeneity map, this comparison is performed qualitatively. KW - Thermography KW - Super resolution KW - NDT KW - Inspection KW - Internal defects PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-548351 DO - https://doi.org/10.1063/5.0088102 SN - 1089-7550 VL - 131 IS - 18 SP - 1 EP - 12 PB - AIP Publishing AN - OPUS4-54835 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bernegger, Raphael A1 - Maierhofer, Christiane A1 - Altenburg, Simon T1 - Quantification of delaminations in semitransparent solids using pulsed thermography and mathematical 1D models N2 - Material defects in fiber reinforced polymers such as delaminations can rapidly degrade the material properties or can lead to the failure of a component. Pulse thermography (PT) has proven to be a valuable tool to identify and quantify such defects in opaque materials. However, quantification of delaminations within semitransparent materials is extremely challenging. We present an approach to quantify delaminations within materials being semitransparent within the wavelength ranges of the optical excitation sources as well as of the infrared (IR) camera. PT experimental data of a glass fiber reinforced polymer with a real delamination within the material were reconstructed by one dimensional (1D) mathematical models. These models describe the heat diffusion within the material and consider semitransparency to the excitation source as well to the IR camera, thermal losses at the samples surfaces and a thermal contact resistance between the two layers describing the delamination. By fitting the models to the PT data, we were able to determine the depth of the delamination very accurately. Additionally, we analyzed synthetic PT data from a 2D simulation with our 1D-models to show how the thermal contact resistance is influenced by lateral heat flow within the material. KW - Pulsed thermography KW - Quantification KW - Numerical simulation KW - Analytical model KW - Semitransparent KW - GFRP KW - Delamination PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-505766 DO - https://doi.org/10.1007/s10765-020-02642-7 VL - 41 IS - 5 SP - Article number: 67 PB - Springer AN - OPUS4-50576 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Müller, Jan P. A1 - Götschel, S. A1 - Weiser, M. A1 - Maierhofer, Christiane T1 - Thermografie mit optimierter Anregung für die quantitative Untersuchung von Delaminationen in kohlenstofffaserverstärkten Kunststoffen N2 - Da kohlenstofffaserverstärkte Kunststoffe (CFK) in anspruchsvollen sicherheitsrelevanten Einsatzgebieten wie im Automobilbau und in der Luftfahrt eingesetzt werden, besteht ein zunehmender Bedarf an zerstörungsfreien Prüfmethoden. Ziel ist die Gewährleistung der Sicherheit und Zuverlässigkeit der eingesetzten Bauteile. Aktive Thermografieverfahren ermöglichen die effiziente Prüfung großer Flächen mit hoher Auflösung in wenigen Arbeitsschritten. Ein wichtiges Teilgebiet der Prüfungen ist die Ortung und Charakterisierung von Delaminationen, die sowohl bereits in der Fertigung als auch während der Nutzung eines Bauteils auftreten können, und dessen strukturelle Integrität schwächen. In diesem Beitrag werden CFK-Strukturen mit künstlichen und natürlichen Delaminationen mit Hilfe unterschiedlich zeitlich modulierter Strahlungsquellen experimentell untersucht. Verwendet werden dabei Anregungen mit Blitzlampen und mit frequenzmodulierten Halogenlampen. Mittels Filterfunktionen im Zeit- und Frequenzbereich wird das Kontrast-zu-Rausch-Verhältnis (CNR) der detektierten Fehlstellen optimiert. Verglichen werden anschließend die Nachweisempfindlichkeit, das CNR und die Ortsauflösung der zu charakterisierenden Delaminationen für die unterschiedlichen Anregungs- und Auswertungstechniken. Ergänzt werden die Experimente durch numerische Simulationen des dreidimensionalen Wärmetransportes. T2 - DGZfP Jahrestagung 2017 CY - Koblenz, Germany DA - 22.05.2017 KW - CFK KW - Contrast Noise Ratio KW - Lock-in Thermografie KW - Gepulste Thermografie KW - Kurzzeit-Fouriertransformation PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-404276 SN - 978-3-940283-85-6 VL - DGZfP BB 162 SP - Mi.1.A.4, 1 EP - 11 AN - OPUS4-40427 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ziegler, Mathias A1 - Myrach, Philipp A1 - Schlichting, Joachim A1 - Maierhofer, Christiane A1 - Kreutzbruck, Marc T1 - Laser-Thermografie für die schnelle Prüfung auf mikroskopische Risse in reflektierenden metallischen Oberflächen N2 - Thermografische ZfP-Verfahren erlauben die Erkennung einer Vielzahl von Defekten in unterschiedlichsten Werkstoffen. Neue Ansätze unter Verwendung von Lasern ermöglichen darüber hinaus die Prüfung auf Oberflächenrisse. Wir stellen die neuesten Entwicklungen dieser vielversprechenden Technik vor und zeigen warum deren Einsatz potentiell die Standardprüfverfahren Magnetpulver- bzw. Eindringprüfung für eine Reihe von Prüfproblemen beerben könnte. Hierzu stellen wir die Prüfergebnisse zu unterschiedlichen metallischen Werkstoffen, Rissgrößen und -typen in Abhängigkeit der Prüfparameter vor. Die aktuelle Grenze der Nachweisempfindlichkeit für die mittels klassischer Thermografie schwer prüfbaren hochreflektierenden Metalloberflächen liegt mit Rissbreiten und -tiefen von weni-gen Mikrometern im Bereich der fluoreszierenden Magnetpulver- und Eindringprüfung. Dabei sind weder Verbrauchsmittel noch eine Oberflächenpräparation notwendig und eine Prüfung kann berührungslos und automatisiert über Entfernungen im Meter-Bereich erfolgen. T2 - DGZfP-Jahrestagung 2013 CY - Dresden, Germany DA - 06.05.2013 KW - Thermografie KW - Laser KW - Risse PY - 2013 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-288706 SN - 978-3-940283-49-8 IS - DGZfP-BB 141 (Di.2.A.4) SP - 1 EP - 8 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-28870 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maierhofer, Christiane A1 - Krankenhagen, Rainer A1 - Röllig, Mathias A1 - Hosseini, Seyed A1 - Heckel, Thomas A1 - Gaal, Mate A1 - Schadow, Florian A1 - Brackrock, Daniel A1 - Gower, M. A1 - Lodeiro, M. A1 - Baker, G. T1 - Quantitative Bewertung künstlicher und natürlicher Fehler in Faserverbundwerkstoffen mit aktiver Thermografie und Ultraschall N2 - Im EMRP-Projekt VITCEA werden komplementäre ZFP-Verfahren zur Prüfung von Faserverbundwerkstoffen weiterentwickelt und validiert. In diesem Beitrag werden Ergebnisse verschiedener Techniken der aktiven Thermografie und des Ultraschalls vorgestellt. Die Nachweisempfindlichkeiten bezüglich künstlicher und natürlicher Fehler mit unterschiedlichen lateralen Ausdehnungen und in verschiedenen Tiefen werden miteinander verglichen. T2 - DGZfP Jahrestagung 2017 CY - Koblenz, Germany DA - 22.05.2017 KW - CFK KW - GFK KW - Aktive Thermografie KW - Phased Array Ultraschall KW - Luftultraschall PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-410902 SN - 978-3-940283-85-6 VL - BB 162 SP - Di1B1, 1 EP - Di1B1, 8 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung e. V. AN - OPUS4-41090 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlichting, Joachim A1 - Ziegler, Mathias A1 - Pelkner, Matthias A1 - Maierhofer, Christiane A1 - Kreutzbruck, Marc T1 - Kameragestütztes Flying-Spot-Verfahren zur Risserkennung N2 - In dieser Arbeit wird ein kameragestütztes Verfahren zur Flying- Spot-Thermografie vorgestellt. Die Anregung wird über einen Diodenlaser mit einem optischen Scanner realisiert. Bei der Auswertung kommt ein effizienter und robuster Algorithmus zum Einsatz, der direkt auf die mit der Kamera aufgenommene Thermografiesequenz angewendet werden kann, ohne auf eine Synchronisation zwischen Kamera und Lasersystem angewiesen zu sein. Daher eignet sich diese Herangehensweise besonders zur Nachrüstung bestehender Thermografiesysteme. Die prinzipielle Eignung dieser Methode wird anhand einer Messung an einem Schienenstück mit Rollkontaktermüdungsrissen gezeigt. Als Referenzverfahren werden die Magnetpulverprüfung und eine auf GMR (Giant Magnetoresistance)- Sensoren basierende Streufeldmessung herangezogen. Mit dem thermografischen Verfahren konnten sämtliche enthaltenen Fehler erkannt werden. Dabei wurden Risse im mm-Abstand getrennt nachgewiesen, was etwa der geometrischen Auflösung der eingesetzten Kamera entspricht. T2 - Thermographie-Kolloquium 2011 CY - Stuttgart, Germany DA - 29.09.2011 KW - Flying-Spot Thermografie KW - Diodenlaser KW - Rissortung KW - Magnetpulverprüfung KW - GMR-Sensoren PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-246220 SN - 978-3-940283-36-8 IS - DGZfP-BB 130 (Vortrag 09) SP - 1 EP - 6 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-24622 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maierhofer, Christiane A1 - Myrach, Philipp A1 - Steinfurth, Henrik T1 - Einfluss von Material, Messparametern und Umgebungsbedingungen auf die Nachweisempfindlichkeit der Blitzthermografie N2 - Dieser Beitrag fasst die Untersuchungsergebnisse zu den Verfahrensgrenzen der Blitzthermografie zur Ortung und Charakterisierung von Fehlstellen in Metallen zusammen. Regeln zur Abschätzung von Eindringtiefe und Tiefenauflösung werden vorgestellt und überprüft. Weiterhin werden Vorgehensweisen zur Optimierung des Intensitätskontrastes von Fehlstellenanzeigen vorgestellt. Einfache analytische Abschätzungen werden durch eine Vielzahl von experimentellen Untersuchungen an Kupfer- und Stahl-Probekörpern ergänzt. Dabei wurden sowohl die Parameter der Blitzlichtanregung als auch der Messwerterfassung umfassend variiert. T2 - DGZfP-Jahrestagung 2013 CY - Dresden, Germany DA - 06.05.2013 PY - 2013 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-285733 SN - 978-3-940283-49-8 IS - Di.2.A.1 SP - 1 EP - 8 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-28573 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maierhofer, Christiane A1 - Krankenhagen, Rainer A1 - Röllig, Mathias A1 - Riemer, Stefanie A1 - Gower, M. A1 - Baker, G. A1 - Lodeiro, M. A1 - Knazovicka, L. A1 - Blahut, A. A1 - Monte, C. A1 - Adibekyan, A. ED - Gutschwager, B. T1 - Characterisation of artificial and natural defects in fibre reinforced plastics designed for energy applications using active thermography N2 - Amongst various other NDT methods, within the EMRP-project ‘VITCEA’ active thermography is validated for testing of CFRP and GFRP structures constructed for energy application. In this contribution, the optical and thermal properties of CFRP and GFRP reference defect artefact (RDA) and natural defects artefact (NDA) test specimens are characterized. Different excitation techniques and techniques for data analysis are compared for optimizing the number of detected defects. T2 - 19th World Conference on Non-destructive Testing (WCNDT) CY - Munich, Germany DA - 13.06.2016 KW - Active thermography KW - CFRP KW - GFRP KW - Artificial and natural defects PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-370207 UR - http://www.ndt.net/article/wcndt2016/papers/we2i4.pdf SN - 978-3-940283-78-8 VL - BB 158 SP - Paper we2i4, 1 EP - 9 PB - DGZfP CY - Berlin AN - OPUS4-37020 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krankenhagen, Rainer A1 - Maierhofer, Christiane A1 - Heckel, Thomas A1 - Brackrock, Daniel A1 - Gower, M. A1 - Lodeiro, M. A1 - Baker, G. T1 - Quantitative comparison of different non-destructive techniques for the detection of artificial defects in GFRP N2 - In order to test their suitability different non-destructive methods were performed to inspect a GFRP plate with artificial defects. These defects were manufactured by means of thin PTFE sheets inserted between two plies in three different depth. The inspection methods were microwave reflection, flash thermography and phased array ultrasonics, all applied to the same specimen. Selected results are shown for all methods demonstrating opportunities and limits of the particular inspection methods. The achieved detection limits and further application aspects are compared directly to provide a useful information for the planning of inspection tasks. T2 - ECNDT CY - Gothenburg, Sweden DA - 11.06.2018 KW - Fiber resisted polymers KW - Non-destructive testing KW - Thermographic testing KW - Ultrasonic testing PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-453728 SP - ECNDT-0247-2018 AN - OPUS4-45372 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kreutzbruck, Marc A1 - Bauer, P. A1 - Caspers, F. A1 - Heck, S. A1 - Müller, F. A1 - Pohl, Rainer A1 - Scheuerlein, C. A1 - Sickert, Roland A1 - Maierhofer, Christiane A1 - Brackrock, Daniel T1 - Sensoren für Verbunddrähte aus Niob-Titan und Kupfer N2 - Der Large Hadron Collider (LHC) des europäischen Kernforschungszentrums CERN ist einer der weltweit größten und leistungsfähigsten Teilchenbeschleuniger. Um den Teilchenstrahl auf seiner Kreisbahn zu halten, werden mit Hilfe supraleitender Spulen sehr starke Magnetfelder erzeugt. Die hierzu benötigten hohen Ströme werden über Verbunddrähte aus Niob-Titan und Kupfer geleitet. Die Drähte werden u.a. durch Ultraschallschweißungen miteinander verbunden. Eine mangelhafte Verbindung kann zur Erwärmung der Kontaktstelle und in Folge davon zum Zusammenbruch der Supraleitung führen. Auf Anfrage des CERN wurden an der BAM Untersuchungen zur Prüfbarkeit solcher Verbindungen bei Umgebungstemperatur durchgeführt. Es gelang, für einen Verbindungstypen einen Wirbelstromsensor für eine manuelle Prüfung zu entwickeln. Ein Prototyp des Sensors befindet sich beim CERN in der praktischen Erprobung. Das Sensorprinzip sowie Prüfergebnisse aus Labor und Praxis werden vorgestellt. T2 - DGZfP-Jahrestagung 2014 CY - Potsdam, Germany DA - 26.05.2014 KW - Ultraschallprüfung mit Matrix-Sensoren KW - Aktive Thermografie KW - Gabelsensor PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-319785 SN - 978-3-940283-61-0 VL - 148 SP - 1 EP - 12 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) CY - Berlin AN - OPUS4-31978 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krankenhagen, Rainer A1 - Doroshtnasir, Manoucher A1 - Maierhofer, Christiane A1 - Brackrock, Daniel A1 - Brekow, Gerhard T1 - Charakterisierung einer durch Überlast geschädigten GFK-Platte mit Thermografie und Ultraschall N2 - Eine GFK-Platte mit eingefräster Nut wurde in einem Zugversuch mit ca. 90 kN belastet, was zu einer sichtbaren Veränderung an den Seitenflächen führte. Anschließend wurde die Platte mit Ultraschall und Thermografie auf innere Schädigungen untersucht. Beide Verfahren konnten räumlich ausgedehnte Bereiche mit zahlreichen Anzeigen nachweisen, jedoch keine geschlossene Fläche. Mit UT wurden außerdem porenreiche oberflächennahe Schichten in dem Material detektiert. Diese Poren verringerten die Nachweisempfindlichkeit beider Messverfahren. T2 - DGZfP-Jahrestagung 2013 CY - Dresden, Germany DA - 06.05.2013 KW - Blitzthermografie KW - Matrixarray KW - GFK KW - Delamination KW - Überlast PY - 2013 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-285563 SN - 978-3-940283-49-8 IS - Mi.3.A.1 SP - 1 EP - 8 PB - Deutsche Gesellschaft für zerstörungsfreie Prüfung e.V. (DGZfP) AN - OPUS4-28556 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maierhofer, Christiane A1 - Röllig, Mathias A1 - Steinfurth, Henrik A1 - Ziegler, Mathias A1 - Heck, S.J. A1 - Scheuerlein, C. T1 - Aktive Thermografie zur zerstörungsfreien Prüfung von Lötverbindungen N2 - In diesem Beitrag werden die Möglichkeiten der Ortung von Fehlstellen in Cu Lötverbindungen unterhalb verschiedener Cu Blechdicken mit aktiver Thermografie demonstriert. Dabei wurden die Anregung mit Blitzlicht und die periodische Anregung mit der Lock-In Technik miteinander verglichen. Die Vor- und Nachteile der Anwendung unterschiedlicher IR-Kamerasysteme, einer gekühlten InSb-Quantendetektor IR-Kamera und einer Mikrobolometer IR-Kamera, werden dargestellt. Als objektives Kriterium wurde das SNR für unterschiedliche Fehlstellengrößen herangezogen. T2 - DGZfP-Jahrestagung 2011 CY - Bremen, Germany DA - 30.05.2011 KW - Aktive Thermografie KW - Blitzlichtanregung KW - Lock-In Anregung KW - Lötverbindung KW - Kupfer PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-249935 SN - 978-3-940283-33-7 IS - DGZfP-BB 127 (Di.1.C.1) SP - 1 EP - 8 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) AN - OPUS4-24993 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Treiling, S. A1 - Wang, Cui A1 - Förster, C. A1 - Reichenauer, F. A1 - Kalmbach, J. A1 - Boden, P. A1 - Harris, J. P. A1 - Carrella, L. M. A1 - Rentschler, E. A1 - Resch-Genger, Ute A1 - Reber, C. A1 - Seitz, M. A1 - Gerhards, M. A1 - Heinze, K. T1 - Luminescence and Light-Driven Energy and Electron Transfer from an Exceptionally Long-Lived Excited State of a Non-Innocent Chromium(III) Complex N2 - Photoactive metal complexes employing Earth‐abundant metal ions are a key to sustainable photophysical and photochemical applications. We exploit the effects of an inversion center and ligand non‐innocence to tune the luminescence and photochemistry of the excited state of the [CrN6] chromophore [Cr(tpe)2]3+ with close to octahedral symmetry (tpe=1,1,1‐tris(pyrid‐2‐yl)ethane). [Cr(tpe)2]3+ exhibits the longest luminescence lifetime (τ=4500 μs) reported up to date for a molecular polypyridyl chromium(III) complex together with a very high luminescence quantum yield of Φ=8.2 % at room temperature in fluid solution. Furthermore, the tpe ligands in [Cr(tpe)2]3+ are redox non‐innocent, leading to reversible reductive chemistry. The excited state redox potential and lifetime of [Cr(tpe)2]3+ surpass those of the classical photosensitizer [Ru(bpy)3]2+ (bpy=2,2′‐bipyridine) enabling energy transfer (to oxygen) and photoredox processes (with azulene and tri(n‐butyl)amine). KW - Quantum yield KW - Cr(III) complex KW - Longst luminescence lifetime KW - Electron transfer PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-494870 DO - https://doi.org/10.1002/anie.201909325 VL - 58 SP - 2 EP - 13 PB - Wiley-VCH AN - OPUS4-49487 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Metz, Christian A1 - Franz, Philipp A1 - Fischer, C. A1 - Wachtendorf, Volker A1 - Maierhofer, Christiane T1 - Zerstörungsfreie Charakterisierung der Alterung additiv gefertigter Kunststoffbauteile N2 - Das vorgestellte Projekt beschäftigt sich mit den optischen, thermophysikalischen und mechanischen Materialeigenschaften von additiv gefertigten Kunststoffteilen und deren Alterung. Dazu wurden mittels Fused Layer Modeling (FLM) Probekörper aus ABS hergestellt, die anschließend für drei Monate einer künstlichen Bewitterung unterzogen wurden. Die dabei erzeugte definierte Alterung wurde nach drei Zeitabschnitten jeweils mit zerstörungsfreien Methoden charakterisiert. Dabei wurde neben den spektroskopischen Standardmethoden auch die aktive Thermografie eingesetzt. Die Ergebnisse zeigen, dass sich mittels der Thermografie sowohl chemische Veränderungen als auch mechanische Schädigungen (Fehlstellen) darstellen lassen. Die Bewitterung beeinflusst die Teiltransparenz der Proben zumindest im sichtbaren Spektralbereich, was bei der Charakterisierung der Fehlstellen, die mittels optisch angeregter aktiver Thermografie detektiert wurden, berücksichtigt werden muss. T2 - DGZfP-Jahrestagung 2019 CY - Friedrichshafen, Germany DA - 27.05.2019 KW - 3D Druck KW - Additive Fertigung KW - Thermografie KW - Polymere KW - Künstliche Bewitterung PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-491561 UR - https://jt2019.dgzfp.de/Portals/jt2019/bb/Di.3.B.1.pdf SN - 978-3-947971-02-2 VL - 171 SP - 1 EP - 8 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) CY - Berlin AN - OPUS4-49156 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rothbart, Nick A1 - Maierhofer, Christiane A1 - Goldammer, M. A1 - Hohlstein, F. A1 - Koch, J. A1 - Kryukov, I. A1 - Mahler, G. A1 - Stotter, B. A1 - Walle, G. A1 - Oswald-Tranta, B. A1 - Sengebusch, M. T1 - A round robin test on flash thermography N2 - A round robin test on flash thermography was organized within the scope of a standardization research project. This test gives information on reliability, comparability and efficiency of different testing situations. Data recorded on metal and CFRP test specimens with flat bottom holes (FBH) were analysed by evaluating the detectability and by calculating the signal-to-noise ratio (SNR) of the defect signatures as a function of defect parameters. For the investigation of the influence of material properties on the spatial resolution as well as on penetration depth, test specimens made of steel and copper with crossed notches and a notch ramp were constructed and investigated. Here, the minimum resolvable notch distance and the maximum detectable depth of the ramp were analysed. T2 - 19th World Conference on Non-destructive Testing (WCNDT) CY - Munich, Germany DA - 13.06.2016 KW - Active thermography KW - Flash excitation KW - Round robin test KW - Standardisation PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-366853 SN - 978-3-940283-78-8 VL - BB 158 SP - We.3.D.4., 1 EP - 8 PB - DGZfP CY - Berlin AN - OPUS4-36685 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Even, Morgane A1 - Hutzler, C. A1 - Wilke, Olaf A1 - Luch, A. T1 - Emissions of volatile organic compounds from polymer-based consumer products: comparison of three emission chamber sizes N2 - The ISO 16000 standard series provide guidelines for emission measurements of volatile organic compounds (VOCs) from building materials. However, polymer-based consumer products such as toys may also release harmful substances into indoor air. In such cases, the existing standard procedures are unsuitable for official control laboratories due to high costs for large emission testing chambers. This paper aims at developing and comparing alternative and more competitive methods for the emission testing of consumer products. The influence of the emission chamber size was investigated as smaller chambers are more suited to the common size of consumer products and may help to reduce the costs of testing. Comparison of the performance of a 203 l emission test chamber with two smaller chambers with the capacity of 24 l and 44 ml, respectively, was carried out by using a polyurethane reference material spiked with 14 VOCs during the course of 28 days. The area-specific emission rates obtained in the small chambers were always similar to those of the 203 l reference chamber after a few hours. This implies that smaller chambers can provide at least useful numbers on the extent of polymer-based consumer product emissions into indoor air, thereby supporting meaningful exposure assessments. KW - Comparison KW - Consumer products KW - Emission chamber KW - Reference material KW - Volatile organic compounds PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-493697 DO - https://doi.org/10.1111/ina.12605 VL - 30 IS - 1 SP - 40 EP - 48 PB - Wiley VCH-Verlag AN - OPUS4-49369 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ahmed, R. A1 - Vaishampayan, A. A1 - Cuellar-Camacho, J. L. A1 - Wight, D. J. A1 - Donskyi, Ievgen A1 - Unger, Wolfgang A1 - Grohmann, E. A1 - Haag, R. A1 - Wagner, O. T1 - Multivalent Bacteria Binding by Flexible Polycationic Microsheets Matching Their Surface Charge Density N2 - Aiming at the overall negative surface charge of bacteria, a new strategy of antibacterial agents based on large polymer-modified graphene oxide (GO) sheets is assessed. The presented flexible, polycationic Sheets match the size and charge density of the Escherichia coli surface charge density (2 × 1014 cm−2). These matching parameters create an unspecific but very strong bacteria adsorber by multivalent, electrostatic attraction. Their interaction with bacteria is visualized via atomic force and confocal microscopy and shows that they effectively bind and wrap around E. coli cells, and thereby immobilize them. The incubation of Gram-negative and -positive bacteria (E. coli and methicillin-resistant Staphylococcus aureus, MRSA) with these polycationic sheets leads to the inhibition of proliferation and a reduction of the colony forming bacteria over time. This new type of antibacterial agent acts in a different mode of Action than classical biocides and could potentially be employed in medicinal, technical, or agriculture applications. The presented microsheets and their unspecific binding of cell interfaces could further be employed as adsorber material for bacterial filtration or immobilization for imaging, analysis, or sensor technologies. KW - Surface charge KW - Bacteria KW - Graphene oxide KW - Escherichia coli KW - XPS PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-509651 DO - https://doi.org/10.1002/admi.201902066 VL - 7 IS - 15 SP - 1902066 PB - WILEY-VCH Verlag GmbH & Co. KGaA CY - Weinheim AN - OPUS4-50965 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Neukammer, J. A1 - Hussels, M. A1 - Kummrow, A. A1 - Devonshire, A. A1 - Foy, C. A1 - Huggett, J. A1 - Parkes, H. A1 - Zel, J. A1 - Milavec, M. A1 - Schimmel, H. A1 - Unger, Wolfgang A1 - Akgoz, M. A1 - McHugh, V. A1 - Grunert, H.-P. A1 - Zeichhardt, H. T1 - Survey results on nucleic acid tests of infectious diseases: present status and need for rapid and patient near diagnostics N2 - This survey will discuss current and emerging isothermal and rapid polymerase chain reaction (PCR) based nucleic acid amplification methods for patient near diagnostics. To assess the clinical need of rapid diagnostics for infectious diseases based on nucleic acid tests (NATs) we performed and analysed a questionnaire among laboratories participating in corresponding INSTAND ring trials for external quality assurance. The questions concerning new amplification technologies like isothermal nucleic acid amplification, potentially suited to significantly decrease turnaround times, were complemented by questions to evaluate the present status of NATs. Besides end-users, companies were also addressed by sending out a manufacturer specific questionnaire. Analysis of the answers from 48 laboratories in 14 European countries revealed that a much shorter turnaround time is requested for selected pathogens compared to about 2 h or longer when applying temperature cycling amplification, i.e. PCR. In this context, most frequently mentioned were MRSA, norovirus, influenza A and B viruses, cytomegalovirus (CMV) as well as hepatitis B virus (HBV) and hepatitis C virus (HCV). At present, 8% of the laboratories having participated in this survey apply isothermal amplification of nucleic acid to identify infectious pathogens. KW - Nucleic acid tests KW - Infectious diseases KW - Virus detection KW - Bacteria detection KW - Isothermal nucleic acid amplification KW - Status report KW - Questionnaire KW - NAT KW - PCR PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:0183-lab0000160 UR - http://www.egms.de/static/en/journals/lab/2015-6/lab000016.shtml DO - https://doi.org/10.3205/lab000016 SN - 1869-4241 VL - 6 SP - 1 EP - 11 PB - GMS CY - Düsseldorf AN - OPUS4-36133 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mozetic, M. A1 - Ostrikov, K. A1 - Ruzic, D.N. A1 - Curreli, D. A1 - Cvelbar, U. A1 - Vesel, A. A1 - Primc, G. A1 - Leisch, M. A1 - Jousten, K. A1 - Malyshev, O.B. A1 - Hendricks, J.H. A1 - Kövér, L. A1 - Tagliaferro, A. A1 - Conde, O. A1 - Silvestre, A.J. A1 - Giapintzakis, J. A1 - Buljan, M. A1 - Radic, N. A1 - Drazic, G. A1 - Bernstorff, S. A1 - Biedermann, H. A1 - Kylián, O. A1 - Hanus, J. A1 - Milosevic, S. A1 - Galtayries, A. A1 - Dietrich, Paul A1 - Unger, Wolfgang A1 - Lehocky, M. A1 - Sedlarik, V. A1 - Stana-Kleinschek, K. A1 - Drmota-Petric, A. A1 - Pireaux, J.J. A1 - Rogers, J.W. A1 - Anderle, M. T1 - Recent advances in vacuum sciences and applications N2 - Recent advances in vacuum sciences and applications are reviewed. Novel optical interferometer cavity devices enable pressure measurements with ppm accuracy. The innovative dynamic vacuum standard allows for pressure measurements with temporal resolution of 2 ms. Vacuum issues in the construction of huge ultra-high vacuum devices worldwide are reviewed. Recent advances in surface science and thin films include new phenomena observed in electron transport near solid surfaces as well as novel results on the properties of carbon nanomaterials. Precise techniques for surface and thin-film characterization have been applied in the conservation technology of cultural heritage objects and recent advances in the characterization of biointerfaces are presented. The combination of various vacuum and atmospheric-pressure techniques enables an insight into the complex phenomena of protein and other biomolecule conformations on solid surfaces. Studying these phenomena at solid–liquid interfaces is regarded as the main issue in the development of alternative techniques for drug delivery, tissue engineering and thus the development of innovative techniques for curing cancer and cardiovascular diseases. A review on recent advances in plasma medicine is presented as well as novel hypotheses on cell apoptosis upon treatment with gaseous plasma. Finally, recent advances in plasma nanoscience are illustrated with several examples and a roadmap for future activities is presented. KW - Vacuum KW - Surface KW - Plasma KW - Interface KW - Nanoscience PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-304884 DO - https://doi.org/10.1088/0022-3727/47/15/153001 SN - 0022-3727 SN - 1361-6463 VL - 47 IS - 15 SP - 153001-1 EP - 153001-23 PB - IOP Publ. CY - Bristol AN - OPUS4-30488 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rades, Steffi A1 - Hodoroaba, Vasile-Dan A1 - Salge, T. A1 - Wirth, Thomas A1 - Lobera, M.P. A1 - Labrador, R.H. A1 - Natte, Kishore A1 - Behnke, Thomas A1 - Gross, Thomas A1 - Unger, Wolfgang T1 - High-resolution imaging with SEM/T-SEM, EDX and SAM as a combined methodical approach for morphological and elemental analyses of single engineered nanoparticles N2 - The combination of complementary characterization techniques such as SEM (Scanning Electron Microscopy), T-SEM (Scanning Electron Microscopy in Transmission Mode), EDX (Energy Dispersive X-ray Spectroscopy) and SAM (Scanning Auger Microscopy) has been proven to be a powerful and relatively quick characterization strategy for comprehensive morphological and chemical characterization of individual silica and titania nanoparticles. The selected “real life” test materials, silica and titania, are listed in the OECD guidance manual as representative examples because they are often used as commercial nanomaterials. Imaging by high resolution SEM and in the transmission mode by T-SEM allows almost simultaneous surface and in-depth inspection of the same particle using the same instrument. EDX and SAM enable the chemical characterization of bulk and surface of individual nanoparticles. The core–shell properties of silica based materials are addressed as well. Titania nominally coated by silane purchased from an industrial source has been found to be inhomogeneous in terms of chemical composition. KW - surface and in-depth inspection KW - silica nanoparticles KW - titania nanoparticles PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-316296 DO - https://doi.org/10.1039/c4ra05092d SN - 2046-2069 VL - 4 IS - 91 SP - 49577 EP - 49587 PB - RSC Publishing CY - London AN - OPUS4-31629 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Guo, Y. A1 - Lippitz, Andreas A1 - Saftien, P. A1 - Unger, Wolfgang A1 - Kemnitz, E. T1 - Tuning the surface properties of novel ternary iron(III) fluoride-based catalysts using the template effect of the matrix N2 - Sol–gel prepared ternary FeF3–MgF2 materials have become promising heterogeneous catalysts due to their porosity and surface Lewis/Brønsted acidity (bi-acidity). Despite the good catalytic performance, nanoscopic characterisations of this type of material are still missing and the key factors controlling the surface properties have not yet been identified, impeding both a better understanding and further development of ternary fluoride catalysts. In this study, we characterised the interaction between the bi-acidic component (FeF3) and the matrix (MgF2) on the nano-scale. For the first time, the formation pathway of FeF3–MgF2 was profiled and the template effect of MgF2 during the synthesis process was discovered. Based on these new insights two novel materials, FeF3–CaF2 and FeF3–SrF2, were established, revealing that with decreasing the atomic numbers (from Sr to Mg), the ternary fluorides exhibited increasing surface acidity and surface area but decreasing pore size. These systematic changes gave rise to a panel of catalysts with tuneable surface and bulk properties either by changing the matrix alkaline earth metal fluoride or by adjusting their ratios to Fe or both. The template effect of the alkaline earth metal fluoride matrix was identified as the most probable key factor determining the surface properties and further influencing the catalytic performance in ternary fluoride based catalysts, and paves the way to targeted design of next-generation catalysts with tunable properties. KW - Catalysis KW - Surface analysis KW - XPS PY - 2015 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-327410 DO - https://doi.org/10.1039/c4dt03229b SN - 1477-9226 SN - 1477-9234 SN - 1364-5447 VL - 44 IS - 11 SP - 5076 EP - 5085 PB - RSC CY - Cambridge AN - OPUS4-32741 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Heinrich, Thomas A1 - Traulsen, Christoph Hans-Henning A1 - Darlatt, Erik A1 - Richter, S. A1 - Poppenberg, J. A1 - Traulsen, N.L. A1 - Linder, I. A1 - Lippitz, Andreas A1 - Dietrich, Paul A1 - Dib, B. A1 - Unger, Wolfgang A1 - Schalley, C.A. T1 - The versatility of 'Click' reactions at surfaces: Molecular recognition at interfaces N2 - In order to investigate molecular recognition on surfaces, an azide-functionalized monolayer was deposited on gold. The monolayer was characterized by X-ray photoelectron spectroscopy (XPS) and angle-resolved near-edge X-ray absorption fine structure (NEXAFS) experiments and the decomposition of the azide upon irradiation with X-ray beams was investigated. Subsequently, various alkyne-functionalized host and guest molecules were attached to the azide by 1,3-dipolar cycloaddition. These modified surfaces and their host–guest chemistry were analysed by XPS and angle-resolved NEXAFS. The reversibility of guest binding was shown for one example as a proof of principle. KW - 'Click' reaction KW - Azide-terminated surfaces KW - SAMs KW - Host guest molecules KW - Molecular recognition at interfaces PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-306463 DO - https://doi.org/10.1039/C4RA01730G SN - 2046-2069 VL - 4 IS - 34 SP - 17694 EP - 17702 PB - RSC Publishing CY - London AN - OPUS4-30646 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sobol, Oded A1 - Straub, F. A1 - Wirth, Thomas A1 - Holzlechner, G. A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang T1 - Real Time Imaging of Deuterium in a Duplex Stainless Steel Microstructure by Time-of-Flight SIMS N2 - For more than one century, hydrogen assisted degradation of metallic microstructures has been identified as origin for severe technical component failures but the mechanisms behind have not yet been completely understood so far. Any in-situ observation of hydrogen transport phenomena in microstructures will provide more details for further elucidation of these degradation mechanisms. A novel experiment is presented which is designed to elucidate the permeation behaviour of deuterium in a microstructure of duplex stainless steel (DSS). A hydrogen permeation cell within a TOF-SIMS instrument enables electrochemical charging with deuterium through the inner surface of the cell made from DSS. The outer surface of the DSS permeation cell exposed to the vacuum has been imaged by TOF-SIMS vs. increasing time of charging with subsequent chemometric treatment of image data. This in-situ experiment showed evidently that deuterium is permeating much faster through the ferrite phase than through the austenite phase. Moreover, a direct proof for deuterium enrichment at the austenite-ferrite interface has been found. KW - Characterization and analytical techniques KW - Corrosion KW - Imaging technique KW - Mass spectrometry PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-353872 UR - http://www.nature.com/articles/srep19929 DO - https://doi.org/10.1038/srep19929 SN - 2045-2322 VL - 6 IS - 19929 SP - 1 EP - 7 PB - nature publishing group CY - London, United Kingdom AN - OPUS4-35387 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Coelho Lima, Isabela A1 - Robens-Radermacher, Annika A1 - Titscher, Thomas A1 - Kadoke, Daniel A1 - Koutsourelakis, P.-S. A1 - Unger, Jörg F. T1 - Bayesian inference for random field parameters with a goal-oriented quality control of the PGD forwardmodel's accuracy N2 - Numerical models built as virtual-twins of a real structure (digital-twins) are considered the future ofmonitoring systems. Their setup requires the estimation of unknown parameters, which are not directly measurable. Stochastic model identification is then essential, which can be computationally costly and even unfeasible when it comes to real applications. Efficient surrogate models, such as reduced-order method, can be used to overcome this limitation and provide real time model identification. Since their numerical accuracy influences the identification process, the optimal surrogate not only has to be computationally efficient, but also accurate with respect to the identified parameters. This work aims at automatically controlling the Proper Generalized Decomposition (PGD) surrogate’s numerical accuracy for parameter identification. For this purpose, a sequence of Bayesian model identification problems, in which the surrogate’s accuracy is iteratively increased, is solved with a variational Bayesian inference procedure. The effect of the numerical accuracy on the resulting posteriors probability density functions is analyzed through two metrics, the Bayes Factor (BF) and a criterion based on the Kullback-Leibler (KL) divergence. The approach is demonstrated by a simple test example and by two structural problems. The latter aims to identify spatially distributed damage, modeled with a PGD surrogate extended for log-normal random fields, in two different structures: a truss with synthetic data and a small, reinforced bridge with real measurement data. For all examples, the evolution of the KL-based and BF criteria for increased accuracy is shown and their convergence indicates when model refinement no longer affects the identification results. KW - Variational inference KW - Proper generalized decomposition KW - Goal-oriented KW - Digital twin KW - Random field PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-555755 DO - https://doi.org/10.1007/s00466-022-02214-6 SN - 1432-0924 SP - 1 EP - 22 PB - Springer CY - Berlin AN - OPUS4-55575 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Oster, Simon A1 - Fritsch, Tobias A1 - Ulbricht, Alexander A1 - Mohr, Gunther A1 - Bruno, Giovanni A1 - Maierhofer, Christiane A1 - Altenburg, Simon T1 - On the Registration of Thermographic In Situ Monitoring Data and Computed Tomography Reference Data in the Scope of Defect Prediction in Laser Powder Bed Fusion N2 - The detection of internal irregularities is crucial for quality assessment in metal-based additive manufacturing (AM) technologies such as laser powder bed fusion (L-PBF). The utilization of in-process thermography as an in situ monitoring tool in combination with post-process X-ray micro computed tomography (XCT) as a reference technique has shown great potential for this aim. Due to the small irregularity dimensions, a precise registration of the datasets is necessary as a requirement for correlation. In this study, the registration of thermography and XCT reference datasets of a cylindric specimen containing keyhole pores is carried out for the development of a porosity prediction model. The considered datasets show variations in shape, data type and dimensionality, especially due to shrinkage and material elevation effects present in the manufactured part. Since the resulting deformations are challenging for registration, a novel preprocessing methodology is introduced that involves an adaptive volume adjustment algorithm which is based on the porosity distribution in the specimen. Thus, the implementation of a simple three-dimensional image-to-image registration is enabled. The results demonstrate the influence of the part deformation on the resulting porosity location and the importance of registration in terms of irregularity prediction. KW - Selective laser melting (SLM) KW - Laser powder bed fusion (L-PBF) KW - Additive manufacturing (AM) KW - Process monitoring KW - Infrared thermography KW - X-ray computed tomography (XCT) KW - Defect detection KW - Image registration PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-549412 DO - https://doi.org/10.3390/met12060947 VL - 12 IS - 6 SP - 1 EP - 21 PB - MDPI AN - OPUS4-54941 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Straße, Anne A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Study on Duplex Stainless Steel Powder Compositions for the Coating of thick Plates of Laser Beam Welding N2 - Duplex stainless steels combine the positive properties of its two phases, austenite and ferrite. Due to its good corrosion resistance, high tensile strength, and good ductility, it has multiple applications. But laser beam welding of duplex steels changes the balanced phase distribution in favor of ferrite. This results in a higher vulnerability to corrosion and a lower ductility. Herein, different powder combinations consisting of duplex and nickel for coating layers by laser metal deposition (LMD) are investigated. Afterward, laser tracks are welded, and the temperature cycles are measured. The ferrite content of the tracks is analyzed by feritscope, metallographic analysis, and electron backscatter diffraction. The goal is the development of a powder mixture allowing for a duplex microstructure in a two-step process, where first the edges of the weld partners are coated with the powder mixture by LMD and second those edges are laser beam welded. The powder mixture identified by the pretests is tested in the two-step process and analyzed by metallographic analysis, energy-dispersive X-ray spectroscopy, and Vickers hardness tests. The resulting weld seams show a balanced duplex microstructure with a homogenous nickel distribution and a hardness of the weld seam similar to the base material. KW - Duplex AISI 2205 KW - Laser metal deposition KW - Laser beam welding KW - Nickel KW - Stainless steels PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-547024 DO - https://doi.org/10.1002/adem.202101327 SN - 1438-1656 SP - 1 EP - 11 PB - Wiley-VCH CY - Weinheim AN - OPUS4-54702 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Straße, Anne A1 - Bakir, Nasim A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael ED - Schmidt, M. ED - Vollertsen, F. ED - Schmidt, B. M. T1 - Preliminary study to investigate the applicability of optical strain measurement technique for the detection of hot cracks in laser metal deposited layers N2 - Laser metal deposition (LMD) as an additive manufacturing technique became increasingly important in recent years and thus the demand for component safety. This is the reason, for the need for reliable in-situ defect detection techniques. For laser beam weld seams an optical measurement technique based on an optical flow algorithm was successfully used to define the critical straining conditions that lead to hot cracking. This algorithm was adapted for bead-on-plate weld seams on LMD deposited layers of IN718 alloy while performing external strain on the specimen in an externally loaded hot cacking test facility. The resulting transversal hot cracks along the weld seam were localized via X-Ray inspection and the type of cracking confirmed by Scanning Electron Microscopy (SEM). The strain distribution was measured in the vicinity of the solidification front and correlated to the detected hot cracks. Based on the results this technique could be adopted for LMD experiments. T2 - 12th CIRP Conference on Photonic Technologies [LANE 2022] CY - Fürth, Germany DA - 04.09.2022 KW - Laser Metal Deposition (LMD) KW - Strain measurement KW - Optical flow KW - Critical strain PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-556445 DO - https://doi.org/10.1016/j.procir.2022.08.034 VL - 111 SP - 335 EP - 339 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-55644 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien A1 - Hirsch, Philipp Daniel A1 - Rupprecht, C. A1 - Ziegler, Mathias T1 - Hochaufgelöste thermografische Detektion eingeschlossener Defekte mit Hilfe von 2Dstrukturierten Beleuchtungsmustern N2 - Für die aktive Thermografie als zerstörungsfreie Prüfmethode galt lange Zeit die Faustformel, dass die Auflösung interner Defekte/Inhomogenitäten auf ein Verhältnis von Defekttiefe/Defektgröße ≤ 1 beschränkt ist. Die Ursache hierfür liegt in der diffusiven Natur der Wärmeleitung in Festkörpern. Sogenannte Super-Resolution-Ansätze erlauben seit Kurzem die Überwindung dieser physikalischen Grenze um ein Vielfaches. Damit ergibt sich die attraktive Möglichkeit die Thermografie von einem rein oberflächensensitiven Prüfverfahren hin zu einem Verfahren mit verbesserter Tiefenreichweite zu entwickeln. Wie weit diese Entwicklung getrieben werden kann, ist Gegenstand aktueller Forschung. Wir konnten bereits zeigen, dass diese klassische Grenze für 1D- und 2D Defektgeometrien mit Hilfe des Abscannens des Prüfkörpers mittels einzelner Laserspots und der anschließenden Anwendung von photothermischer Super-Resolution-Rekonstruktion überwunden werden kann. Bei dieser Methode wird eine Kombination aus sequenzieller räumlich strukturierter Beleuchtung und numerischen Optimierungsmethoden eingesetzt. Dies geschieht allerdings auf Kosten der experimentellen Komplexität, die zu einer langen Messdauer, großen Datensätzen und langwieriger numerischer Auswertung führt. In dieser Arbeit berichten wir über einen neuen experimentellen Ansatz, bei dem räumlich strukturierte 2D-Beleuchtungsmuster in Verbindung mit Compressed-Sensing und Computational-Imaging-Methoden verwendet werden, um die experimentelle Komplexität deutlich zu verringern und die Methode für die Untersuchung größerer Prüfflächen nutzbar zu machen. Der experimentelle Ansatz basiert dabei auf der wiederholten (blinden) photothermischen Anregung mit räumlich strukturierten 2D-Mustern unter Verwendung moderner Projektortechnik und eines Hochleistungslasers. In der anschließenden numerischen Rekonstruktion werden mehrere Messungen unter Ausnutzung der Joint-Sparsity der Defekte innerhalb des Prüfkörpers mittels nichtlinearer konvexer Optimierungsmethoden kombiniert. Als Ergebnis kann eine 2D-sparse Defekt-/Inhomogenitätskarte erstellt werden. T2 - DGZfP-Jahrestagung 2022 CY - Kassel, Germany DA - 23.05.2022 KW - Thermografie KW - Super resolution KW - NDT KW - ZfP KW - Eingeschlossene Defekte KW - Projektor PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-548945 SN - 978-3-947971-25-1 VL - 177 SP - 1 EP - 16 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung AN - OPUS4-54894 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bruno, Giovanni A1 - Maierhofer, Christiane T1 - Advanced Characterization and On-Line Process Monitoring of Additively Manufactured Materials and Components N2 - Additive manufacturing (AM) techniques have risen to prominence in many industrial sectors. This rapid success of AM is due to the freeform design, which offers enormous possibilities to the engineer, and to the reduction of waste material, which has both environmental and economic advantages. Even safety-critical parts are now being produced using AM. This enthusiastic penetration of AM in our daily life is not yet paralleled by a thorough characterization and understanding of the microstructure of materials and of the internal stresses of parts. The same holds for the understanding of the formation of defects during manufacturing. While simulation efforts are sprouting and some experimental techniques for on-line monitoring are available, still little is known about the propagation of defects throughout the life of a component (from powder to operando/service conditions). This Issue was aimed at collecting contributions about the advanced characterization of AM materials and components (especially at large-scale experimental facilities such as Synchrotron and Neutron sources), as well as efforts to liaise on-line process monitoring to the final product, and even to the component during operation. The goal was to give an overview of advances in the understanding of the impacts of microstructure and defects on component performance and life at several length scales of both defects and parts. KW - Non-destructive Testing KW - Additive Manufacturing KW - Materials Characterization KW - Online Monitoring KW - Residual Stress KW - Thermography KW - Computed Tomography PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-556833 DO - https://doi.org/10.3390/met12091498 VL - 12 IS - 9 SP - 1 EP - 3 PB - MDPI CY - Basel, Schweiz AN - OPUS4-55683 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Haustein, T. A1 - Busweiler, Sabine A1 - Haustein, V. A1 - von Laar, C. A1 - Plarre, Rüdiger T1 - Laboratory breeding of Korynetes caeruleus (Coleoptera: Cleridae) for the biological of Anobium punctatum) (Coleoptera, Ptinidae) N2 - Larvae and adults of Korynetes caeruleus (de Geer 1775) (Coleoptera: Cleridae) were collected from old churches and reared in the laboratory on Anobium punctatum (de Geer 1774) (Coleoptera: Ptinidae). Breeding success of K. caeruleus was low, but basic parameters of this species’ developmental cycle were identifi ed. At 21°C and 75% relative humidity and a fourmonth cold period at 4°C, the development of K. caeruleus from egg to adult appearance lasted 2 years. The pupal stage may be reached and completed after one and a half years. Feeding on larvae of A. punctatum by larvae of K. caeruleus was observed and consisted of a combination of sucking haemolymph and consuming body parts. The sickle-like mandibles of larvae of K. caeruleus penetrate the cuticle of prey larvae; this is followed by pumping and sucking body movements. Adult beetles of A. punctatum were not attacked by K. caeruleus larvae. Feeding behaviour of adult K. caeruleus was not investigated. KW - Cultural heritage KW - Coleoptera KW - Korynetes caeruleus KW - Cleridae KW - Ptinidae KW - Anobium punctatum KW - Biological pest control KW - Life history data KW - Laboratory breeding KW - Wood protection PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-494999 DO - https://doi.org/10.14411/eje.2019.038 SN - 1802-8829 VL - 116 SP - 362 EP - 371 PB - České Budějovice AN - OPUS4-49499 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Roveda, Ilaria A1 - Serrano Munoz, Itziar A1 - Haubrich, Jan A1 - Requena, Guillermo A1 - Madia, Mauro T1 - Investigation on the fatigue strength of AlSi10Mg fabricated by PBF-LB/M and subjected to low temperature heat treatments N2 - This work provides an investigation of the influence of low temperature heat treatments on the fatigue behavior of a PBF-LB AlSi10Mg alloy. Fatigue specimens are produced in form of round bars on a build platform preheated at 200 ◦C. The specimens have been tested in three different conditions: as-built, and after heat treatments at 265 ◦C for 1 h and 300 ◦C for 2 h. Prior to the fatigue testing, the defect distribution is analyzed by means of micro computed tomography. Subsequently, the peak over threshold method is successfully applied to provide a prediction of the size of killer defect. The defect population was of gas porosity type. No clear improvement of the fatigue performance is observed after the heat treatments. The fatigue strength predicted using fracture mechanics-based approaches is in good agreement with the experimental data. Among the studied approaches, short crack models provided the most conservative predictions. KW - PBF-LB/M AlSi10Mg KW - Fatigue strength KW - Defects KW - Kitagawa-Takahashi Diagram KW - Short Crack Models PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-607071 DO - https://doi.org/10.1016/j.matdes.2024.113170 SN - 0264-1275 VL - 244 SP - 1 EP - 12 PB - Elsevier Ltd. AN - OPUS4-60707 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Ghigo, Tea A1 - Rabin, Ira ED - Buzi, P. T1 - Detecting Early Medieval Coptic literature in Dayr Al-Anba Maqar, Between textual conservation and literary rearrangement: The case of Vat. Copt. 57 N2 - The study of the VAt.Copt. 57 at the Vatican Library. Codicological, palaeographical, textual and archaeometrical considerations. KW - Coptic KW - Archaeometry KW - Ink KW - Manuscripts PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-494004 SN - 978-88-210-1025-5 SP - 77 EP - 83 PB - Biblioteca Apostolica Vaticana AN - OPUS4-49400 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Markwart, J. C. A1 - Battig, Alexander A1 - Velencoso, M. M. A1 - Pollok, D. A1 - Schartel, Bernhard A1 - Wurm, F. R. T1 - Aromatic vs. Aliphatic Hyperbranched Polyphosphoesters as Flame Retardants in Epoxy Resins N2 - The current trend for future flame retardants (FRs) goes to novel efficient halogen-free materials, due to the ban of several halogenated FRs. Among the most promising alternatives are phosphorus-based FRs, and of those, polymeric materials with complex shape have been recently reported. Herein, we present novel halogen-free aromatic and aliphatic hyperbranched polyphosphoesters (hbPPEs), which were synthesized by olefin Metathesis polymerization and investigated them as a FR in epoxy resins. We compare their efficiency (aliphatic vs. aromatic) and further assess the differences between the monomeric compounds and the hbPPEs. The decomposition and vaporizing behavior of a compound is an important factor in its flame-retardant behavior, but also the interaction with the pyrolyzing matrix has a significant influence on the performance. Therefore, the challenge in designing a FR is to optimize the chemical structure and its decomposition pathway to the matrix, with regards to time and temperature. This behavior becomes obvious in this study, and explains the superior gas phase activity of the aliphatic FRs. KW - Phosphorus KW - Metathesis KW - Dendritic KW - Cone calorimeter KW - Fire test PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-494535 DO - https://doi.org/10.3390/molecules24213901 SN - 1420-3049 VL - 24 IS - 21 SP - 3901 PB - MDPI AN - OPUS4-49453 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Strangfeld, Christoph A1 - Stolpe, Heiko A1 - Kruschwitz, Sabine ED - Schumann, R. T1 - Correlation between the electric impedance and the water layer thickness in partially saturated screed samples N2 - The moisture content of screed samples is monitored by means of embedded sensors. Relative humidity sensors and multi-ring-electrodes are used to measure the spatial moisture distribution during desorption. Based on the humidity data and the pore volume distribution, the moisture and the water layer thickness within the pore space are predicted. Slit shape as well as cylindrical pores are evaluated. Finally, the measured real part of the electrical impedance and the calculated water layer thickness are correlated. Based on the available data, a significant trend change of the impedance is documented at a water layer thickness of approximately 3 nm. This water layer thickness corresponds to a relative humidity of 88.3%. T2 - 10. CMM Tagung CY - Ettlingen, Germany DA - 10.10.2019 KW - Material moisture KW - Screed KW - Embedded sensors KW - Electric impedance KW - Water layer thickness PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-494636 VL - 10 SP - 79 EP - 102 PB - CMM, Karlsruher Institut für Technologie CY - Karlsruhe AN - OPUS4-49463 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schütz, R. A1 - Maragh, J. A1 - Weaver, J. A1 - Rabin, Ira A1 - Masic, A. T1 - The Temple Scroll: Reconstructing an ancient manufacturing practice N2 - The miraculously preserved 2000-year-old Dead Sea Scrolls, ancient texts of invaluable historical significance, were discovered in the mid-20th century in the caves of the Judean desert. The texts were mainly written on parchment and exhibit vast diversity in their states of preservation. One particular scroll, the 8-m-long Temple Scroll is especially notable because of its exceptional thinness and bright ivory color. The parchment has a layered structure, consisting of a collagenous base material and an atypical inorganic overlayer. We analyzed the chemistry of the inorganic layer using x-ray and Raman spectroscopies and discovered a variety of evaporitic sulfate salts. This points toward a unique ancient production technology in which the parchment was modified through the addition of the inorganic layer as a writing surface. Furthermore, understanding the properties of these minerals is particularly critical for the development of suitable conservation methods for the preservation of these invaluable historical documents. KW - Temple Scroll KW - Dead Sea Scrolls PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-495314 DO - https://doi.org/10.1126/sciadv.aaw7494 VL - 5 IS - 9 SP - 1 EP - 9 PB - AAAS AN - OPUS4-49531 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bayerlein, Bernd A1 - Hanke, T. A1 - Muth, Thilo A1 - Riedel, Jens A1 - Schilling, Markus A1 - Schweizer, C. A1 - Skrotzki, Birgit A1 - Todor, A. A1 - Moreno Torres, Benjami A1 - Unger, Jörg F. A1 - Völker, Christoph A1 - Olbricht, Jürgen T1 - A Perspective on Digital Knowledge Representation in Materials Science and Engineering N2 - The amount of data generated worldwide is constantly increasing. These data come from a wide variety of sources and systems, are processed differently, have a multitude of formats, and are stored in an untraceable and unstructured manner, predominantly in natural language in data silos. This problem can be equally applied to the heterogeneous research data from materials science and engineering. In this domain, ways and solutions are increasingly being generated to smartly link material data together with their contextual information in a uniform and well-structured manner on platforms, thus making them discoverable, retrievable, and reusable for research and industry. Ontologies play a key role in this context. They enable the sustainable representation of expert knowledge and the semantically structured filling of databases with computer-processable data triples. In this perspective article, we present the project initiative Materials-open-Laboratory (Mat-o-Lab) that aims to provide a collaborative environment for domain experts to digitize their research results and processes and make them fit for data-driven materials research and development. The overarching challenge is to generate connection points to further link data from other domains to harness the promised potential of big materials data and harvest new knowledge. KW - Data infrastructures KW - Digital representations KW - Digital workflows KW - Knowledge graphs KW - Materials informatics KW - Ontologies KW - Vocabulary providers PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-546729 DO - https://doi.org/10.1002/adem.202101176 SN - 1438-1656 SP - 1 EP - 14 PB - Wiley-VCH GmbH CY - Weinheim AN - OPUS4-54672 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ehlert, Christopher A1 - Unger, Wolfgang A1 - Saalfrank, P. T1 - C K-edge NEXAFS spectra of graphene with physical and chemical defects: a study based on density functional theory N2 - Recently, C K-edge Near Edge X-ray Absorption Fine Structure (NEXAFS) spectra of graphite (HOPG) surfaces have been measured for the pristine material, and for HOPG treated with either bromine or krypton plasmas (Lippitz et al., Surf. Sci., 2013, 611, L1). Changes of the NEXAFS spectra characteristic for physical (krypton) and/or chemical/physical modifications of the surface (bromine) upon plasma treatment were observed. Their molecular origin, however, remained elusive. In this work we study by density functional theory, the effects of selected point and line defects as well as chemical modifications on NEXAFS carbon K-edge spectra of single graphene layers. For Br-treated surfaces, also Br 3d X-ray Photoelectron Spectra (XPS) are simulated by a cluster approach, to identify possible chemical modifications. We observe that some of the defects related to plasma treatment lead to characteristic changes of NEXAFS spectra, similar to those in experiment. Theory provides possible microscopic origins for these changes. KW - Graphene KW - NEXAFS KW - Spectrum simulation KW - Density functional theory PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-309658 DO - https://doi.org/10.1039/c4cp01106f SN - 1463-9076 SN - 1463-9084 VL - 16 IS - 27 SP - 14083 EP - 14095 PB - The Royal Soc. of Chemistry CY - Cambridge AN - OPUS4-30965 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kaur, I. A1 - Ellis, L.-J. A1 - Romer, I. A1 - Tantra, R. A1 - Carriere, M. A1 - Allard, S. A1 - Mayne-L'Hermite, M. A1 - Minelli, C. A1 - Unger, Wolfgang A1 - Potthoff, A. A1 - Rades, Steffi A1 - Valsami-Jones, E. T1 - Dispersion of nanomaterials in aqueous media: Towards protocol optimization N2 - The sonication process is commonly used for de-agglomerating and dispersing nanomaterials in aqueous based media, necessary to improve homogeneity and stability of the suspension. In this study, a systematic step-wise approach is carried out to identify optimal sonication conditions in order to achieve a stable dispersion. This approach has been adopted and shown to be suitable for several nanomaterials (cerium oxide, zinc oxide, and carbon nanotubes) dispersed in deionized (DI) water. However, with any change in either the nanomaterial type or dispersing medium, there needs to be optimization of the basic protocol by adjusting various factors such as sonication time, power, and sonicator type as well as temperature rise during the process. The approach records the dispersion process in detail. This is necessary to identify the time Points as well as other above-mentioned conditions during the sonication process in which there may be undesirable changes, such as damage to the particle surface thus affecting surface properties. Our goal is to offer a harmonized approach that can control the Quality of the final, produced dispersion. Such a guideline is instrumental in ensuring dispersion quality repeatability in the nanoscience community, particularly in the field of nanotoxicology. KW - Dispersion of nanomaterials KW - Aqueous media KW - Protocol development PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-435886 UR - https://www.jove.com/video/56074 DO - https://doi.org/10.3791/56074 SN - 1940-087X IS - 130 SP - e560741, 1 EP - e560741, 23 PB - MyJove Corp. CY - Cambridge, MA, USA AN - OPUS4-43588 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Abbas, F. A1 - Donskyi, Ievgen A1 - Gholami, M. A1 - Ziem, B. A1 - Lippitz, Andreas A1 - Unger, Wolfgang A1 - Böttcher, C. A1 - Rabe, J. A1 - Haag, R. A1 - Adeli, M. T1 - Controlled covalent functionalization of thermally reduced graphene oxide to generate defined bifunctional 2D nanomaterials N2 - A controlled, reproducible, gram-scale method is reported for the covalent functionalization of graphene Sheets by a one-pot nitrene [2+1] cycloaddition reaction under mild conditions. The reaction between commercially available 2,4,6-trichloro-1,3,5-triazine and sodium azide with thermally reduced graphene oxide (TRGO) results in defined dichlorotriazine-functionalized sheets. The different reactivities of the chlorine substituents on the functionalized graphene allow stepwise post-modification by manipulating the temperature. This new method provides unique access to defined bifunctional 2D nanomaterials, as exemplified by chiral surfaces and multifunctional hybrid architectures. KW - Graphene oxide KW - Bifunctional 2D nanomaterials KW - XPS KW - NEXAFS KW - AFM PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-394789 DO - https://doi.org/10.1002/ange.201612422 SN - 1433-7851 VL - 56 IS - 10 SP - 2675 EP - 2679 PB - Wiley-VCH Verlag GmbH & Co. KGaA CY - Weinheim AN - OPUS4-39478 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Swaraj, S. A1 - Dietrich, Paul A1 - Unger, Wolfgang T1 - Simultaneous surface and bulk sensitive XAS measurements of magnetic particle clusters N2 - Magnetic iron oxide nanoparticle clusters (mnpc) coated with organic stabilizers were investigated using scanning transmission x-ray microscopy (STXM). Simultaneous surface and bulk sensitive Fe L₃ edge absorption spectra, obtained using a photomultiplier tube and a channeltron, were used to detect subtle changes in the oxidation state in the surface and bulk of Iron Oxide mnpc. The effectiveness of this mode of STXM operation is demonstrated for these nanoparticle clusters. T2 - X-Ray Microscopy Conference 2016 (XRM 2016) CY - Oxford, UK DA - 15.08. 2016 KW - Fe L3 edge absorption spectra KW - Scanning transmission x- ray microscopy KW - Magnetic iron oxide nanoparticle clusters KW - XAS PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-410576 UR - http://iopscience.iop.org/article/10.1088/1742-6596/849/1/012014/pdf DO - https://doi.org/10.1088/1742-6596/849/1/012014 SN - 1742-6588 VL - 849 SP - 012014, 1 EP - 012014, 5 PB - IOP Publishing AN - OPUS4-41057 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Swaraj, S. A1 - Dietrich, Paul A1 - Unger, Wolfgang T1 - Simultaneous surface and bulk sensitive XAS measurements of magnetic particle clusters N2 - Magnetic iron oxide nanoparticle clusters (mnpc) coated with organic stabilizers were investigated using scanning transmission x-ray microscopy (STXM). Simultaneous surface and bulk sensitive Fe L3 edge absorption spectra, obtained using a photomultiplier tube and a channeltron, were used to detect subtle changes in the oxidation state in the surface and bulk of Iron Oxide mnpc. The effectiveness of this mode of STXM operation is demonstrated for These nanoparticle clusters. T2 - X-Ray Microscopy Conference 2016 (XRM 2016) CY - Oxford, UK DA - 15.08.2016 KW - Scanning transmission x-ray microscopy (STXM) KW - Magnetic nanoparticles KW - Fe L3 edge absorption spectra PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-435907 UR - http://iopscience.iop.org/article/10.1088/1742-6596/849/1/012014/meta DO - https://doi.org/10.1088/1742-6596/849/1/012014 VL - 849 SP - 012014, 1 EP - 012014, 4 PB - IOP Publishing AN - OPUS4-43590 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pohl, Christoph A1 - Unger, Jörg F. ED - von Scheven, M. ED - Keip, M.-A. ED - Karajan, N. T1 - Obtaining macroscopic properties from a mesoscale thermomechanical model of concrete N2 - A coupled thermomechanical mesoscale model for concrete under heating is presented. When considering the heterogeneous structure under coupled loads, complex macroscopic material properties can be modelled using simple constitutive relations. For instance, damage evolution is directly driven by the incompatibility of thermal strains between matrix and aggregates. Without prescribing fc = f(T), a decline in compressive strength with rising temperatures will be shown. T2 - 7th GACM Colloquium on Computational Mechanics for Young Scientists from Academia and Industry CY - Stuttgart, Germany DA - 11.10.2017 KW - Multiscale KW - Concrete mesoscale KW - Thermomechanical PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-436540 DO - https://doi.org/10.18419/opus-9334 VL - 7 SP - MS13, 418 EP - 422 PB - Institute for Structural Mechanics, University of Stuttgart CY - Stuttgart AN - OPUS4-43654 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Franz, Philipp A1 - Metz, Christain A1 - Brackrock, Daniel A1 - Fischer, C. A1 - Wachtendorf, Volker A1 - Maierhofer, Christiane T1 - Zerstörungsfreie Charakterisierung und Qualitätssicherung der Materialeigenschaften und Beständigkeit additiv gefertigter Kunststoffteile N2 - Mit additiven Fertigungsverfahren hergestellte Bauteile und Produkte aus Kunststoffen werden zunehmend nicht mehr nur als Prototypen, sondern als voll funktionsfähige Bauteile und Produkte gefertigt. Bedingt durch die Fertigungsprozesse und den schichtweisen Aufbau resultieren physikalische Materialeigenschaften, die stark von den Fertigungsparametern abhängen und zudem anisotrop sind. Von den Fertigungsparametern werden auch die Oberflächeneigenschaften beeinflusst, sodass zu erwarten ist, dass sich die Beständigkeit gegenüber äußeren Umwelteinflüssen bei additiv gefertigten Bauteilen von der konventionell gefertigter unterscheiden kann. Nachfolgend wird daher die Entwicklung eines Qualitätssicherungskonzeptes basierend auf spektroskopischen und zerstörungsfreien Prüfverfahren vorgestellt, in dem der Alterungsprozess von mittels Fused Deposition Modelling (FDM) und mittels Lasersintering (LS) hergestellten Probekörpern untersucht wird. T2 - DGZfP-Jahrestagung 2018 CY - Leipzig, Germany DA - 07.05.2018 KW - Additive Fertigung KW - Kunststoffe KW - Zerstörungsfreie Prüfung PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-449016 SN - 978-3-940283-92-4 VL - DGZfP BB 166 SP - Mo.2.A.1, 1 EP - 9 AN - OPUS4-44901 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maierhofer, Christiane A1 - Krankenhagen, Rainer A1 - Röllig, Mathias A1 - Heckel, Thomas A1 - Brackrock, Daniel A1 - Gaal, Mate T1 - Quantification of impact damages in CFRP and GFRP structures with thermography and ultrasonics N2 - The extent of damage caused by impacts in fibre reinforced composites depends on the energy of the impacts, on the velocity and the shape of the impacting body, on the material and structure of the composite and on the geometry of the structure. Here, mainly the thickness of the component is essential. The non-destructive evaluation of these damages can be carried out using both ultrasound and active thermography methods. A comparison of the detection sensitivity of these methods for the different damages is carried out in this paper depending on the fibre composite material used (CFRP and GFRP), the thickness of the material and the impact energy. The NDT methods used after the damage are supplemented by thermographic measurements with high temporal resolution, which were already recorded during the impact. T2 - 14th Quantitative InfraRed Thermography Conference CY - Berlin, Germany DA - 25.06.2018 KW - Active thermography KW - Passive thermography KW - Ultrasonics KW - CFRP KW - GFRP KW - Impact PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-454952 UR - http://www.qirt.org/archives/qirt2018/papers/126.pdf DO - https://doi.org/10.21611/qirt.2018.126 SP - 933 EP - 940 PB - DGZfP e. V. AN - OPUS4-45495 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Becker, Tina A1 - Altenburg, Simon A1 - Scheuschner, Nils A1 - Breese, Philipp Peter A1 - Metz, C. A1 - Hilgenberg, Kai A1 - Maierhofer, Christiane T1 - In-situ monitoring of the Laser Powder Bed Fusion build process via bi- chromatic optical tomography N2 - As metal additive manufacturing (AM) is entering industrial serial production of safety relevant components, the need for reliable process qualification is growing continuously. Especially in strictly regulated industries, such as aviation, the use of AM is strongly dependent on ensuring consistent quality of components. Because of its numerous influencing factors, up to now, the metal AM process is not fully controllable. Today, expensive part qualification processes for each single component are common in industry. This contribution focusses on bi-chromatic optical tomography as a new approach for AM in-situ quality control. In contrast to classical optical tomography, the emitted process radiation is monitored simultaneously with two temperature calibrated cameras at two separate wavelength bands. This approach allows one to estimate the local maximum temperatures during the manufacturing process, thus increases the comparability of monitoring data of different processes. A new process information level at low investment cost is reachable, compared to, e.g., infrared thermography. T2 - LANE 2022 CY - Fürth, Germany DA - 04.08.2022 KW - Optical tomography KW - Additive Manufacturing KW - L-PBF KW - In-process monitoring PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-560270 DO - https://doi.org/10.1016/j.procir.2022.08.035 SN - 2212-8271 VL - 111 SP - 340 EP - 344 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-56027 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -