TY - JOUR A1 - Gharaati, S. A1 - Wang, Cui A1 - Förster, C. A1 - Weigert, Florian A1 - Resch-Genger, Ute A1 - Heinze, K. T1 - Triplet–Triplet Annihilation Upconversion in a MOF with AcceptorFilled Channels N2 - In summary, we report a highly modular solid TTA-UC system comprising of a crystalline, thermally stable PCN222(Pd) MOF with CA-coated MOF channels and with a DPA annihilator embedded in a solution-like environment in the MOF channels. This solid material displays blue upconverted delayed emission with a luminescence lifetime of 373 us, a threshold value of 329 mW*cm-2 and a triplet–triplet energy transfer efficiency of 82%. This optical application adds another facet to the versatile chemistry of PCN-222 MOFs. The design concept is also applicable to other TTA-UC pairs and enables tuning of the UCL color, for example, by replacing DPA with other dyes as exemplarily shown for 2,5,8,11-tetra-tert-butyl-perylene, that yields UCL at 450 nm. Current work aims to reduce the oxygen sensitivity and to increase the retention of the trapped annihilators in organic environments, for example, by tuning the chain length of the carboxylic acid and by coating the MOF surface. In addition, the TTA-UC efficiency will be further enhanced by reducing the reabsorption of the UC emission caused by Pd(TCPP) and by optimizing the sensitizer/annihilator interface. KW - Porphyrin KW - Method KW - MOF KW - Fluorescence KW - Dye KW - Sensor KW - Oxygen sensitive KW - Single molecule KW - DPA KW - Lifetime KW - Upconverstion KW - Quantum yield KW - Triplet-triplet annihilation KW - Sensitization KW - Energy transfer KW - NMR PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-500580 DO - https://doi.org/10.1002/chem.201904945 VL - 26 IS - 5 SP - 1003 EP - 1007 PB - Wiley-VCH Verlag CY - Weinheim AN - OPUS4-50058 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wurster, S. A1 - Ladu, Luana T1 - Triple-C: A Tridimensional Sustainability-Oriented Indicator for Assessing Product Circularity in Public Procurement N2 - Various microlevel circular economy indicators for assessing sustainability and, partly, additional sustainability characteristics have been developed, but an integrated solution considering the environmental, social, and economic pillars remains a research gap. Method: Based on a multimethod approach, including surveys and the analysis of existing sustainability assessment methodologies and standards, this paper proposes a concept for a multidimensional circular economy indicator tailored to public procurers. It relies on attractive existing building blocks including: the ecological scarcity method, European and international sustainability standards and indicators,and the STAR-ProBio-IAT concept. Results: This article presents the concept of the composite indicator Triple-C, consisting of 20 elements and aimed at facilitating sustainable circular public procurement. It is intended to be incorporated into software that facilitates sustainable product decisions among public procurers in Germany. Conclusions: We propose a generic indicator concept covering all three (environmental, social, and economic) sustainability pillars. More research and additional standards are needed to develop the Triple-C concept further into product-specific applications. KW - Circular economy KW - Sustainability assessment KW - Circularity KW - Ecological scarcity method KW - Life-cycle assessment KW - LCA KW - Life-cycle costing KW - LCC KW - Social sustainability KW - Indicators PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-564115 DO - https://doi.org/10.3390/su142113936 VL - 14 IS - 21 SP - 1 EP - 23 PB - MDPI CY - Berlin AN - OPUS4-56411 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Scholtz, G. A1 - Staude, Andreas A1 - Dunlop, J.A. T1 - Trilobite compound eyes with crystalline cones and rhabdoms show mandibulate affinities N2 - Most knowledge about the structure, function, and evolution of early compound eyes is based on investigations in trilobites. However, these studies dealt mainly with the cuticular lenses and little was known about internal anatomy. Only recently some data on crystalline cones and retinula cells were reported for a Cambrian trilobite species. Here, we describe internal eye structures of two other trilobite genera. The Ordovician Asaphus sp. reveals preserved crystalline cones situated underneath the cuticular lenses. The same is true for the Devonian species Archegonus (Waribole) warsteinensis, which in addition shows the fine structure of the rhabdom in the retinula cells. These results suggest that an apposition eye with a crystalline cone is ancestral for Trilobita. The overall similarity of trilobite eyes to those of myriapods, crustaceans, and hexapods corroborates views of a phylogenetic position of trilobites in the stem lineage of Mandibulata. KW - Trilobite compound eyes KW - Computed Tomography PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-510784 DO - https://doi.org/10.1038/s41467-019-10459-8 SN - 2041-1723 VL - 10 SP - 2503 PB - Nature AN - OPUS4-51078 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Staude, Andreas A1 - Scholtz, G. A1 - Dunlop, J. A. T1 - Trilobite compound eyes with crystalline cones and rhabdoms show mandibulate affinities N2 - Most knowledge about the structure, function, and evolution of early compound eyes is based on investigations in trilobites. However, these studies dealt mainly with the cuticular lenses and little was known about internal anatomy. Only recently some data on crystalline cones and retinula cells were reported for a Cambrian trilobite species. Here, we describe internal eye structures of two other trilobite genera. The Ordovician Asaphus sp. reveals preserved crystalline cones situated underneath the cuticular lenses. The same is true for the Devonian species Archegonus (Waribole) warsteinensis, which in addition shows the fine structure of the rhabdom in the retinula cells. These results suggest that an apposition eye with a crystalline cone is ancestral for Trilobita. The overall similarity of trilobite eyes to those of myriapods, crustaceans, and hexapods corroborates views of a phylogenetic position of trilobites in the stem lineage of Mandibulata. KW - Coputed tomography KW - Crystalline cones PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-483889 DO - https://doi.org/10.1038/s41467-019-10459-8 SN - 2041-1723 VL - 10 SP - 2503, 1 EP - 7 PB - Nature AN - OPUS4-48388 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kirner, Sabrina V. A1 - Slachciak, Nadine A1 - Elert, Anna Maria A1 - Griepentrog, Michael A1 - Fischer, Daniel A1 - Hertwig, Andreas A1 - Sahre, Mario A1 - Dörfel, Ilona A1 - Sturm, Heinz A1 - Pentzien, Simone A1 - Koter, Robert A1 - Spaltmann, Dirk A1 - Krüger, Jörg A1 - Bonse, Jörn T1 - Tribological performance of titanium samples oxidized by fs-laser radiation, thermal heating, or electrochemical anodization N2 - Commercial grade-1 titanium samples (Ti, 99.6%) were treated using three alternative methods, (i) femtosecond laser processing, (ii) thermal heat treatment, and (iii) electrochemical anodization, respectively, resulting in the formation of differently conditioned superficial titanium oxide layers. The laser processing (i) was carried out by a Ti:sapphire laser (pulse duration 30 fs, central wavelength 790 nm, pulse repetition rate 1 kHz) in a regime of generating laser-induced periodic surface structures (LIPSS). The experimental conditions (laser fluence, spatial spot overlap) were optimized in a sample-scanning setup for the processing of several square-millimeters large surface areas covered homogeneously by these nanostructures. The differently oxidized titanium surfaces were characterized by optical microscopy, micro Raman spectroscopy, variable angle spectroscopic ellipsometry, and instrumented indentation testing. The tribological performance was characterized in the regime of mixed friction by reciprocating sliding tests against a sphere of hardened steel in fully formulated engine oil as lubricant. The specific tribological performance of the differently treated surfaces is discussed with respect to possible physical and chemical mechanisms. KW - Femtosecond laser KW - Titanium KW - Oxidation KW - Friction PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-445609 DO - https://doi.org/10.1007/s00339-018-1745-8 SN - 0947-8396 SN - 1432-0630 VL - 124 IS - 4 SP - 326, 1 EP - 10 PB - Springer-Verlag AN - OPUS4-44560 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Gradt, Thomas A1 - Schneider, Thomas T1 - Tribological performance of MoS2 coatings in various environments N2 - Molybdenum disulfide (MoS₂) is a well-known solid lubricant for tribosystems running in vacuum or dry gases. Problems arise due to its sensitivity to humidity, which is a drawback for its application under ambient conditions. However, by using a physical vapor deposition (PVD) process, deposition parameters can be optimized not only to gain a coatings structure with favorable frictional properties but also to minimize the sensitivity to attack by water molecules. Therefore, an improved tribological behavior even under moist conditions can be achieved. MoS₂coatings are also candidates for being applied at cryogenic temperatures. They already have proven their suitability, e.g., for sliding support elements between superconducting magnets of the nuclear fusion-experiment Wendelstein 7-X. However, these coatings were exclusively produced for this particular application and the utilization for more common tribosystems may be precluded due to cost considerations. In view of a wider range of applications, pure and Cr containing PVD-MoS₂ coatings with an optimized structure were tested under varying environments including hydrogen gas and cryogenic temperatures. Results of the most promising variant are presented in this paper. KW - Solid lubrication KW - MoS2 KW - Extreme environments KW - Hydrogen KW - Cryogenic einvironment PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-381460 DO - https://doi.org/10.3390/lubricants4030032 SN - 2075-4442 VL - 32 IS - 4 PB - MPPI AG CY - Basel, Switzerland AN - OPUS4-38146 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pirker, F. A1 - Toth, I. A1 - Cihak-Bayr, U. A1 - Grundtner, R. A1 - Vernes, A. A1 - Benedicto, J. A1 - Spaltmann, Dirk A1 - Gradt, Thomas A1 - Alberdi, A. A1 - Alonso, I. A1 - Bayón, R. A1 - Igartua, A. A1 - García, Á. A1 - Pagano, F. A1 - Bravo, I. A1 - Kogia, M. A1 - Dykeman, D. A1 - Liedtke, S. A1 - Minami, I. A1 - Nyberg, E. A1 - Soivio, K. A1 - Ronkainen, H. A1 - Majaniemi, S. A1 - Heino, V. A1 - Gkagkas, K. A1 - Mont, L. A1 - Amigorena, I. T1 - Tribological characterisation services for materials - i-TRIBOMAT N2 - Um den Entwicklungsprozess von neuen Komponenten zu beschleunigen, ist die Vorrausage der Eigenschaften der eingesetzten Werkstoffe im Betrieb der Komponenten von enormer Bedeutung. Um neue Werkstoffe hinsichtlich Ihrer Performance (in einer Komponente) bewerten zu können, ist deshalb die Entwicklung neuer innovativer Methoden notwendig. Diese Methoden können auch unter dem Begriff „lab-to-field“ oder „materials“ – up-scaling zusammengefasst werden. D. h. Werkstoffe werden im Labor charakterisiert, und deren Eigenschaften mittels z.B. Simulation auf die Komponentenperformance hochskaliert (upscaling). i-TRIBOMAT ist ein EU gefördertes Projekt (H2020, GA Nr. 814494) mit dem Ziel ein Open Innovation Test Bed für tribologische Werkstoffcharakterisierung aufzubauen und entsprechende Services von der tribologischen Charakterisierung neuer Werkstoffe bis hin zu Simulationsmodellen zur Vorrausage der Perfomance von Komponenten der Industrie anzubieten. Durch die Bündelung von Knowhow und Infrastruktur zu Charakterisierung sowie den Aufbau einer digitalen Plattform, wird i-TRIBOMAT das weltgrößte Open Innovation Test Bed für tribologische Werkstoffcharakterisierung. N2 - The prediction of the properties of the materials used in the operation of components is of enormous importance, in order to accelerate the development process of new components. To evaluate new materials in terms of their performance (in a component), the development of new innovative methods is necessary. These methods can also be summarized under the term lab-to-field or materials – upscaling, meaning materials being characterised in a laboratory and their properties being upscaled to the component performance by means of e.g. simulation. i-TRIBOMAT is a EU funded project (H2020, GA Nr. 814494) aiming at building an Open Innovation Test Bed for tribological material characterization and offering corresponding services from tribological characterization of new materials to simulation models for predicting the performance of industrial components. By bundling the infrastructure, know-how for characterization and building a digital platform, i-TRIBOMAT becomes the world’s largest open innovation test bed for tribological material characterization. T2 - 22nd International Colloquium Tribology CY - Esslingen, Germany DA - 28.01.2020 KW - Tribologie KW - Lab-to-field up-scaling KW - Werkstoffdatenbank KW - Geteilte Infrastruktur KW - Tribo-Analytik KW - Intelligente tribologische Werkstoffcharakterisierung KW - Lab-to-field upscaling KW - Tribology KW - Intelligent tribological material characterization KW - Materials database KW - Shared infrastruture KW - Tribo-analytics PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-576762 DO - https://doi.org/10.30419/TuS-2020-0026 SN - 0724-3472 SN - 2941-0908 VL - 67 IS - 5-6 SP - 35 EP - 50 PB - Expert CY - Tübingen AN - OPUS4-57676 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Michalchuk, Adam A1 - Boldyreva, E. A1 - Belenguer, A. M. A1 - Emmerling, Franziska A1 - Boldyrev, V. V. T1 - Tribochemistry, mechanical alloying, mechanochemistry: what is in a name? N2 - Over the decades, the application of mechanical force to influence chemical reactions has been called by various names: mechanochemistry, tribochemistry, mechanical alloying, to name but a few. The evolution of these terms has largely mirrored the understanding of the field. But what is meant by these terms, why have they evolved, and does it really matter how a process is called? Which parameters should be defined to describe unambiguously the experimental conditions such that others can reproduce the results, or to allow a meaningful comparison between processes explored under different conditions? Can the information on the process be encoded in a clear, concise, and self-explanatory way? We address these questions in this Opinion contribution, which we hope will spark timely and constructive discussion across the international mechanochemistry community. KW - Mechanochemistry KW - Tribochemistry KW - Mechanical alloying KW - Tribology KW - Mechanical activation KW - Nomenclature KW - Mechanochemical pictographs PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-523291 DO - https://doi.org/10.3389/fchem.2021.685789 SN - 2296-2646 VL - 9 SP - 1 EP - 29 PB - Frontiers Media CY - Lausanne AN - OPUS4-52329 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sprengel, Maximilian A1 - Mohr, Gunther A1 - Altenburg, Simon A1 - Evans, Alexander A1 - Serrano Munoz, Itziar A1 - Kromm, Arne A1 - Pirling, T. A1 - Bruno, Giovanni A1 - Kannengießer, Thomas T1 - Triaxial Residual Stress in Laser Powder Bed Fused 316L: Effects of Interlayer Time and Scanning Velocity N2 - The triaxial distribution of the residual stress in laser powder bed fused austenitic steel 316L was determined by X-ray and neutron diffraction. The residual stress analysis results were linked to the thermal history of the specimens, which were manufactured with varying inter-layer-times and scanning velocities. A clear link between the in-process temperature of the specimens and the residual stress was found, based on in-situ monitoring data. KW - Stainless Steel KW - AGIL KW - Residual Stress KW - X-ray and Neutron Diffraction KW - Additive Manufacturing PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-542620 DO - https://doi.org/10.1002/adem.202101330 SP - 1 EP - 13 PB - Wiley-VCH GmbH AN - OPUS4-54262 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Recknagel, Sebastian A1 - Bresch, Harald A1 - Kipphardt, Heinrich A1 - Resch-Genger, Ute A1 - Koch, Matthias A1 - Rosner, M. T1 - Trends in selected fields of reference material production N2 - For more than 110 years, BAM has been producing reference materials for a wide range of application fields. With the development of new analytical methods and new applications as well as continuously emerging more stringent requirements of laboratory accreditation with regard to quality control and metrological traceability, the demand and requirements for reference materials are increasing. This trend article gives an overview of general developments in the field of reference materials as well as developments in selected fields of application in which BAM is active. This includes inorganic and metal analysis, gas analysis, food and consumer products, and geological samples. In addition to these more traditional fields of application, developments in the areas of optical spectroscopy, particulary fluorescence methods, and nanomaterials are considered. T2 - 150 years BAM: Science with impact CY - Berlin, Germany DA - 01.01.2021 KW - Reference material KW - ISO REMCO KW - Gas analysis KW - Food KW - Nanomaterials KW - Fluorescence PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-548407 DO - https://doi.org/10.1007/s00216-022-03996-7 SN - 1618-2642 SN - 1618-2650 VL - 414 IS - Topical collection: Analytical methods and applications in the materials and life sciences SP - 4281 EP - 4289 PB - Springer CY - Berlin AN - OPUS4-54840 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -