TY - JOUR A1 - Gleim, Tobias A1 - Chen, Hefeng ED - Kleiber, M. ED - Onate, E. T1 - High-Order Accurate Methods for the Numerical Analysis of a Levitation Device N2 - This paper establishes different axisymmetric and two-dimensional models for a levitation device. Therein, the Maxwell equations are combined with the balance of linear momentum. Different possible formulations to describe the Maxwell equations are presented and compared and discussed in the example. A high order finite element discretization using Galerkin’s method in space and the generalized Newmark−alpha method in time are developed for the electro-magneto-mechanical approach. Several studies on spatial and temporal discretization with respect to convergence will be investigated. In addition, the boundary influences and the domain size with respect to the levitation device are also examined. KW - Maxwell equations KW - Levitation KW - High-Order KW - Accurate-Numerical-Methods KW - Generalized Newmark-alpha PY - 2020 DO - https://doi.org/10.1007/s11831-020-09427-z SN - 1134-3060 VL - 28 IS - 3 SP - 1517 EP - 1543 PB - Springer Nature AN - OPUS4-50734 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ruiz-Hervias, J. A1 - Simbruner, Kai A1 - Cristobal-Beneyto, M. A1 - Perez-Gallego, D. A1 - Zencker, Uwe T1 - Failure mechanisms in unirradiated ZIRLO® cladding with radial hydrides N2 - The purpose of this paper is to investigate the relationship between hydride morphology, in particular the presence of radial hydrides (RHs), stress state and failure mechanisms associated with the ring compression test (RCT). Samples of ZIRLO®cladding were pre-hydrided and subjected to thermo-mechanical treatments to precipitate long radial hydrides. The results show that the reorientation treatment was very successful. A considerable fraction of RHs was generated, the radial hydride continuity factor being around 80 to 90% of the wall thickness. The samples with reoriented hydrides were tested using the RCT at room temperature. Macroscopic brittle failure was observed with sudden load drops for displacements around 0.5 mm, with a calculated “offset strain”between 0.5 and 1%. Crack nucleation occurs in RHs located in regions with the highest values of hoop stress. These locations are the inner diameter of cladding at the vertical plane of the sample (12 and 6 o’clock positions) and the outer diameter at the horizontal plane (3 and 9 o’clock positions). Noticeable load drops in the RCT are associated with unstable crack propagation events through the radial hydride network, the crack front reaching up to 90% of the wall thickness in some cases. The failure micro-mechanism is quasi-cleavage in the hydrides and micro-void nucleation, growth and coalescence in the Zr matrix, with ductile tearing patches connecting neighboring hydrides. The main conclusion is that radial hydride metrics is not the only parameter that determines cladding failure in the presence of RHs, but the interaction between the location and continuity of RHs and the stress normal to the hydride (the hoop stress in this case). Consequently, if a radial hydride is located at a position within the cladding where the hoop stress is small, a crack will not be initiated easily in the RCT. KW - ZIRLO® KW - Cladding Embrittlement KW - Radial Hydrides KW - Failure Mechanism KW - Ring compression test PY - 2021 DO - https://doi.org/10.1016/j.jnucmat.2020.152668 SN - 0022-3115 VL - 544 SP - 152668 PB - Elsevier B.V. AN - OPUS4-52000 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sjöland, A. A1 - Christensen, P. A1 - Zetterström Evins, L. A1 - Bosbach, D. A1 - Duro, L. A1 - Farnan, I. A1 - Metz, V. A1 - Zencker, Uwe A1 - Ruiz-Hervias, J. A1 - Rodriguez-Villagra, N. A1 - Kiraly, M. A1 - Schillebeeckx, P. A1 - Rochman, D. A1 - Seidl, M. A1 - Dagan, R. A1 - Verwerft, M. A1 - Herranz Puebla, L. E. A1 - Hordynskyi, D. A1 - Feria, F. A1 - Vlassopoulos, E. T1 - Spent nuclear fuel management, characterisation, and dissolution behaviour: progress and achievement from SFC and DisCo N2 - SFC is a work package in Eurad that investigates issues related to the properties of the spent nuclear fuel in the back-end of the nuclear fuel cycle. Decay heat, nuclide inventory, and fuel integrity (mechanical and otherwise), and not least the related uncertainties, are among the primary focal points of SFC. These have very significant importance for the safety and operational aspect of the back-end. One consequence is the operation economy of the back-end, where deeper understanding and quantification allow for significant optimization, meaning that significant parts of the costs can be reduced. In this paper, SFC is described, and examples of results are presented at about half-time of the work package, which will finish in 2024. The DisCo project started in 2017 and finished in November 2021 and was funded under the Horizon 2020 Euratom program. It investigated if the properties of modern fuel types, namely doped fuel, and MOX, cause any significant difference in the dissolution behavior of the fuel matrix compared with standard fuels. Spent nuclear fuel experiments were complemented with studies on model materials as well as the development of models describing the solid state, the dissolution process, and reactive transport in the near field. This research has improved the understanding of processes occurring at the interface between spent nuclear fuel and aqueous solution, such as redox reactions. Overall, the results show that from a long-term fuel matrix dissolution point of view, there is no significant difference between MOX fuel, Cr+Al-doped fuel, and standard fuels. KW - Spent nuclear fuel management KW - Spent fuel characterization KW - Dissolution behaviour PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-572461 DO - https://doi.org/10.1051/epjn/2022029 SN - 2491-9292 VL - 9 SP - 1 EP - 12 PB - EDP Sciences CY - Les Ulis Cedex, France AN - OPUS4-57246 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Simbruner, Kai A1 - Billone, Michael C. A1 - Zencker, Uwe A1 - Liu, Yung Y. A1 - Völzke, Holger T1 - Brittle failure analysis and modeling of high-burnup PWR fuel cladding alloys N2 - The aim of this research is the development of methods for predicting mechanical behavior and identification of limiting conditions to prevent brittle failure of high-burnup (HBU) pressure water reactor (PWR) fuel cladding alloys. A finite element (FE) model of the ring compression test (RCT) was created to analyze the failure behavior of zirconium-based alloys with radial hydrides during the RCT. An elastic-plastic material model describes the zirconium alloy. The stress-strain curve needed for the elastic-plastic material model was derived by inverse finite element analyses. Cohesive zone modeling is used to reproduce sudden load drops during RCT loading. Based on the failure mechanism in non-irradiated ZIRLO® claddings, a micro-mechanical model was developed that distinguishes between brittle failure along hydrides and ductile failure of the zirconium matrix. Two different cohesive laws representing these types of failure are present in the same cohesive interface. The key differences between these constitutive laws are the cohesive strength, the stress at which damage initiates, and the cohesive energy, which is the damage energy dissipated by the cohesive zone. Statistically generated matrix-hydride distributions were mapped onto the cohesive elements and simulations with focus on the first load drop were performed. Computational results are in good agreement with the RCT results conducted on high-burnup M5® samples. It could be shown that crack initiation and propagation strongly depend on the specific configuration of hydrides and matrix material in the fracture area. KW - Cladding KW - Radial hydrides KW - Ring compression test KW - Cohesive zone model PY - 2024 DO - https://doi.org/10.1515/kern-2024-0109 SN - 2195-8580 SP - 1 EP - 9 PB - Walter de Gruyter GmbH AN - OPUS4-62409 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nagel, Thomas A1 - Rühaak, Wolfram A1 - Amann, Florian A1 - Bracke, Guido A1 - Buske, Stefan A1 - Kowalski, Julia A1 - Reiche, Sönke A1 - Schäfer, Thorsten A1 - Scheytt, Traugott A1 - Stumpf, Thorsten A1 - Völzke, Holger A1 - Wellmann, Florian A1 - Kolditz, Olaf T1 - Deep geological disposal - Editorial to the topical collection N2 - The subsurface geological environment, historically a key source of fossil and mineral resources, has seen a significant broadening of its potential applications in recent years, with increasing emphasis on its use for energy production and storage. A critical factor in utilizing subsurface space is ensuring the sustainability of management practices, with particular attention to the potential environmental impacts that may result. The current Topical Collection on Deep Geological Disposal places greater emphasis on the geotechnical aspects of geological disposal, with a particular focus on the safe isolation of hazardous materials, including radioactive waste. The Topical Collection on Deep Geological Disposal covers both experimental (laboratory and in-situ) and theoretical studies of various geotechnical applications, such as geological disposal of radioactive or other materials, e.g. coal-based solid waste, carbon dioxide sequestration in fractured reservoirs, and brine solutions, but also aspects of uranium mining. The articles in the Topical Collections are arranged under the following headings: – Fundamental studies – Experimental studies – Numerical studies KW - Disposal KW - Radioactive Waste KW - Geology PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-624955 DO - https://doi.org/10.1007/s12665-024-12075-2 SN - 1866-6299 VL - 84 IS - 3 SP - 1 EP - 6 PB - Springer Nature AN - OPUS4-62495 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Qiao, Linan A1 - Nagelschmidt, Sven A1 - Herbrich, Uwe A1 - Keller, Christian T1 - Introduction of a Power Law Time-Temperature Equivalent Formulation for the Description of Thermorheologically Simple and Complex Behavior N2 - Abstract: In this work, a conceptual framework is suggested for analyzing thermorheologically simple and complex behavior by using just one approach. Therefore, the linear relation between master time and real time which is required in terms of the time-temperature superposition principle was enhanced to a nonlinear equivalent relation. Furthermore, we evaluate whether there is any relation among well-known existing time-temperature equivalent formulations which makes it possible to generalize different existing formulations. For this purpose, as an example, the power law formulation was used for the definition of the master time. The method introduced here also contributes a further framework for a unification of established time-temperature equivalent formulations, for example the time-temperature superposition principle and time-temperature parameter models. Results show, with additional normalization conditions, most of the developed time-temperature parameter models can be treated as special cases of the new formulation. In the aspect of the arrow of time, the new defined master time is a bended arrow of time, which can help to understand the corresponding physical meaning of the suggested method. KW - bended arrow of time KW - time-temperature superposition principle KW - time-temperature equivalent formulation PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-543800 DO - https://doi.org/10.3390/ma15030726 VL - 15 IS - 3 SP - 1 EP - 11 PB - MDPI AN - OPUS4-54380 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Neumann, Martin A1 - Gleim, Tobias A1 - Gradt, Thomas T1 - Friction coefficients for wood-wood and wood-steel high pressure contact under temperatures between -40 °C and 90 °C N2 - Wood is widely used in impact limiters of Transport casks for radioactive material. Encapsulated by an outer and inner Steel structure, spruce wood is offen applied in layers of altemating direction. The friction at the interfaces between these layers is of crucial importance for the impact and energy absorption e.g., at an accidental impact of a cask against a hard component. In order to get detailed Information for corresponding numerical calculations, in this study the friction coefficient for the combinations wood-wood and wood-steel was measured in the temperature ränge between -40 °C and 90 °C according to the relevant stress conditions for such casks. Results show decreasing friction with increasing temperature, ranging from 0.43 at -40 °C to 0.22 for 90 °C for wood-steel combinations and from 0.3 at -40 °C to 0.24 at 90 °C to for a wood-wood combination. KW - Wood KW - Friction KW - Transport cask KW - Radioactive material PY - 2023 DO - https://doi.org/10.24053/TuS-2023-0007 SN - 0724-3472 VL - 70 IS - 2 SP - 5 EP - 12 PB - expert verlag AN - OPUS4-57787 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nagelschmidt, Sven A1 - Herbrich, Uwe A1 - Keller, Christian A1 - Qiao, Linan T1 - Re-evaluation of tensile and creep rupture data of metals using a modified Larson–Miller approach N2 - More than 70 years ago, in 1952 Larson and Miller adapted an existing relationship whichevaluates the relative effects of time and temperature on creep rupture behavior of various alloys by using existing data and by constructing so-called master curves. Since that time, the formulated Larson–Miller relation, commonly known as Larson–Miller parameter, is a widely used time–temperature parameter for various applications, e.g. for rupture life, creep and relaxation analyses of metals and some other materials such as polymers, concrete and ceramics.Nevertheless, the physical meaning of this parameter as well as the determination of master curves are still the subject of major criticism. In this work, both aspects are reviewed and analyzed with data originally considered in thepaper of Larson and Miller based on the following approach: (a) the parameter was modifiedregarding a reference time and a reference temperature according to the time–temperature superposition principle; (b) master curves were generated for five materials investigated originally by Larson and Miller, based on a stretched exponential function type. It has been shown, that: (1) With normalized time and temperature, the Larson–Miller parameter corresponds to real logarithmic rupture time. (2) For the relationship between Creep rupture stress and the modified Larson–Miller parameter, the stretched exponential function is a good choice as a master function. (3) Corresponding model parameters have physical meaning and can be easily determined based on data from creep test data. The investigations provide a better understanding and applicability of Larson–Miller approach. KW - Larson–Miller parameter KW - Creep rupture time KW - Time–temperature equivalence KW - Stretched exponential function KW - Extrapolation of short-term data PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-644486 DO - https://doi.org/10.1016/j.engfracmech.2025.111582 SN - 0013-7944 VL - 329 SP - 1 EP - 16 PB - Elsevier Ltd. AN - OPUS4-64448 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Brunk, Gerd A1 - Herbrich, Uwe A1 - Weckner, Olaf A1 - Smith, Jay A1 - Rossi, John T1 - Geometrically non-linear large planar deformations of shear deformable beams: Derivation, approximation, and numerical validation using Finite Element analysis N2 - In this paper, we present derivations for the dynamic equations of motion of a shear deformable beam undergoing geometrically non-linear large deformations in a single plane. In the static case, these governing equations are given by six coupled, non-linear ordinary differential equations of first order which we present in the Lagrangian frame of reference and henceforth refer to as the Brunk–Herbrich–Weckner (BHW) beam theory. We confirm analytically that under pure bending an initially straight beam deforms into a circle, a known bench-mark solution. Next, we confirm numerically that our results agree well with the commercial Finite-Element code Abaqus for several example problems with increasing complexity, including the effect of axial preload as well as varying property domains along the beam. Abaqus is regarded as the state-of-the-art for non-linear structural analysis within the aerospace industry. Next, we show that the well-known Timoshenko–Ehrenfest and Euler–Bernoulli beam theory can be obtained from the general Brunk-Herbrich-Weckner beam theory in the limit of small deformations. Finally, we introduce the Iterative Projection Method which improves the results of the linearized Timoshenko–Ehrenfest beam theory without the computational cost associated with the fully non-linear analysis for all numerical test cases considered. KW - Linear and non-linear beam theory KW - Deformation problem KW - Euler–Bernoulli, Timoshenko–Ehrenfest and Brunk–Herbrich–Weckner beam KW - Iterative projection method KW - Finite Element analysis PY - 2025 DO - https://doi.org/https://doi.org/10.1177/10812865251342777 SN - 1081-2865 SP - 1 EP - 26 PB - Sage CY - Thousand Oaks, Calif. AN - OPUS4-64383 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Goral, Milan A1 - Wolff, Dietmar T1 - Insights for lifetime predictions of O-ring seals from five-year long-term aging tests N2 - O-rings made of HNBR, EPDM and FKM were aged in the compressed and uncompressed state at 150 °C, 125 °C, 100 °C, 75 °C, 60 °C and 23 °C for aging times of up to five years. Hardness was measured and increased with aging time and temperature for HNBR and EPDM, but it remained practically constant for FKM. Indenter modulus measurements were performed on the lateral O-ring surface (that was free of DLO effects) to assess an influence of the compression during aging, but none was detected. The equilibrium compression set (CS) exhibited faster and stronger degradation than hardness and was used for lifetime predictions using the time-temperature superposition (TTS) principle. With an end-of-lifetime criterion of 70 % CS, lifetimes of 4.5 years, 50 years and 526 years at 75 °C were estimated for HNBR, EPDM and FKM, respectively. The activation energies derived from an Arrhenius plot of the shift factors from the TTS were 85 kJ/mol, 99 kJ/mol and 78 kJ/mol for HNBR, EPDM and FKM, respectively, revealing that a higher activation energy does not necessarily mean that the material has a higher lifetime at lower temperatures. Furthermore, the measured lifetime of EPDM O-rings at 100 °C (5 years) was compared to that predicted on the basis of the lifetime at 150 °C as well as 125 °C using the corresponding shift factors. The error of the prediction was only ± 4 %. However, this precise prediction could only be achieved using the five-year long-term aging data. When using only data from aging times up to 0.5 years and 2 years, the lifetime of EPDM O-rings at 100 °C was underestimated by 31 % and 22 %, respectively. KW - HNBR KW - EPDM KW - FKM KW - DLO KW - Hardness KW - Compression set KW - Rubber KW - Elastomer KW - Degradation PY - 2020 DO - https://doi.org/10.1016/j.polymdegradstab.2020.109278 VL - 179 SP - 109278 PB - Elsevier Ltd. AN - OPUS4-51060 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zaghdoudi, Maha A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar T1 - Erroneous or Arrhenius: A Degradation Rate-Based Model for EPDM during Homogeneous Ageing N2 - To improve the predictive capability of long-term stress relaxation of elastomers during thermo-oxidative ageing, a method to separate reversible and irreversible processes was adopted. The separation is performed through the analysis of compression set after tempering. On the Basis of this separation, a numerical model for long-term stress relaxation during homogeneous ageing is proposed. The model consists of an additive contribution of physical and chemical relaxation. Computer simulations of compression stress relaxation were performed for long ageing times and the results were validated with the Arrhenius treatment, the kinetic study and the time-temperature superposition technique based on experimental data. For chemical relaxation, two decay functions are introduced each with an activation energy and a degradative process. The first process with the lower activation energy dominates at lower ageing times, while the second one with the higher activation energy at longer ageing times. A degradation-rate based model for the evolution of each process and ist contribution to the total system during homogeneous ageing is proposed. The main advantage of the model is the possibility to quickly validate the interpolation at lower temperatures within the range of slower chemical processes without forcing a straight-line extrapolation. KW - Kinetic study KW - Arrhenius KW - TTS KW - Modeling KW - Chemical processes KW - Stress relaxation PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-512931 DO - https://doi.org/10.3390/polym12092152 SN - 2073-4360 VL - 12 IS - 9 SP - 1 EP - 21 AN - OPUS4-51293 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zaghdoudi, Maha A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar T1 - Understanding the recovery behaviour and the degradative processes of EPDM during ageing N2 - Recovery is an important measure for seal applications representing to which extent the elastomer regains its initial shape after deformation and release of an applied force. Compression set (CS) indicates the degree of recovery. Ethylene propylene diene rubber (EPDM) was aged at 75 ◦C, 100 ◦C, 125 ◦C and 150 ◦C for different ageing times up to five years and compression set measurements were performed at different times after disassembly and after additional tempering. Short- and long-term recovery up to one year after release for samples aged at 125 ◦C and 150 ◦C was also studied. To assess the curvature in the Arrhenius diagram that may occur due to non-sufficiently aged specimens, a degradation-rate based model was fitted to the CS data after tempering. For each ageing temperature, two decay fit functions were proposed, each with an activation energy and a corresponding degradative process. The influence of ageing on the leak-tightness after fast small partial release is investigated and estimated through the analysis of the shift factors from time temperature superposition (TTS) of CS measurements at different times after disassembly. Shift factors of CS measurement after 1 s and after additional tempering are in good agreement. KW - Compression set KW - Ageing KW - Recovery KW - Degradative processes KW - Leakage rate PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-573699 DO - https://doi.org/10.1016/j.polymertesting.2023.107987 SN - 0142-9418 VL - 121 SP - 107987 PB - Elsevier Ltd. AN - OPUS4-57369 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zaghdoudi, Maha A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar T1 - Oxidative ageing of elastomers: Experiment and modelling N2 - During an extensive test programme at the Bundesanstalt für Materialforschung und prüfung, material property changes of EPDM O-rings were investigated at different ageing times and two ageing temperatures of 125∘C and 150∘C. To exclude possible diffusion-limited oxidation (DLO) effects that can distort the data, IRHD microhardness measurements were taken over the cross section of compressed O-rings. Continuous stress relaxation measurements were taken on samples free of DLO effects. The additional effect of physical processes to irreversible chemical ones during a long-term thermal exposure is quantified by the analysis of compression set measurements under various test conditions. By combining the different experimental methods, characteristic times relative to the degradation processes were determined. On the basis of experimental data, a microphysically motivated model that takes into account reversible and irreversible processes was developed. The parameter identification strategy of the material model is based on our experimental investigations on homogeneously aged elastomer O-rings. The simulated results are in good agreement with the experiments. KW - Compression stress relaxation KW - Compression set KW - IRHD microhardness KW - Modelling PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-545910 DO - https://doi.org/10.1007/s00161-022-01093-9 SN - 1432-0959 SP - 1 EP - 9 PB - Springer CY - Berlin AN - OPUS4-54591 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Jaunich, Matthias A1 - Goral, Milan A1 - Wolff, Dietmar A1 - Völzke, Holger ED - Krüssenberg, A. T1 - Overview of metal seal tests performed at BAM and implications for extended interim storage N2 - The investigation of the long-term performance of sealing systems employed in containers of radioactive waste and spent nuclear fuel is one research focus area for division 3.4 \Safety of Storage Containers" at the Bundesanstalt für Materialforschung und -prüfung. The behaviour of metallic seals, which are employed in interim storage casks for spent nuclear fuel and high active waste, over time is of high importance for ensuring safe enclosure. Therefore, investigations on these systems were started at BAM to get a general understanding of the relevant processes. Our investigations comprise investigations on different parameters which influence the seal Performance and the main part is focussed on the time and temperature dependent behaviour. Our aim is to understand the longterm behaviour of the sealing systems for evaluation of their performance during possible extended interim storage and subsequent transportation. In this contribution an overview of the performed tests and their respective results is given. A focus lies on a comparison between seals with large torus diameter in comparison to small diameters. T2 - Safety of Extended Dry Storage of Spent Nuclear Fuel SEDS2020: International online-workshop CY - Online meeting DA - 03.06.2020 KW - Metal seal KW - Seal performance KW - Long-term investigation KW - Ageing PY - 2020 DO - https://doi.org/10.3139/124.200071 SN - 0932-3902 VL - 85 IS - 6 SP - 440 EP - 443 PB - Carl Hanser Verlag CY - München AN - OPUS4-51833 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zaghdoudi, M. A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar T1 - Oxidative ageing of elastomers: experiment and modelling N2 - During an extensive test programme at the Bundesanstalt für Materialforschung und prüfung, material property changes of EPDM O-rings were investigated at different ageing times and two ageing temperatures of 125 ◦ C and 150 ◦ C. To exclude possible diffusion-limited oxidation (DLO) effects that can distort the data, IRHD microhardness measurements were taken over the cross section of compressed O-rings. Continuous stress relaxation measurements were taken on samples free of DLO effects. The additional effect of physical processes to irreversible chemical ones during a long-term thermal exposure is quantified by the analysis of compression set measurements under various test conditions. By combining the different experimental methods, characteristic times relative to the degradation processes were determined. On the basis of experimental data, a microphysically motivated model that takes into account reversible and irreversible processes was developed. The parameter identification strategy of the material model is based on our experimental investigations on homogeneously aged elastomer O-rings. The simulated results are in good agreement with the experiments. KW - Compression Set KW - Compression stress relaxation KW - Modelling KW - Ageing KW - Microhardness PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-609332 DO - https://doi.org/10.1007/s00161-022-01093-9 VL - 36 SP - 289 EP - 297 PB - Springer Nature AN - OPUS4-60933 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zaghdoudi, Maha A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar T1 - Overview of ongoing long-term ageing investigations on elastomer seals N2 - At the Bundesanstalt für Materialforschung und -prüfung (BAM) in Division 3.4 Safety of Storage Containers, one of our tasks is to evaluate the safety of containers designed for disposal of low and intermediate radioactive waste. As such containers might be transported before and stored until disposal, safe enclosure of the radioactive inventory is important for this time span. Elastomer O-rings are widely used as barrier seals in these containers. Thus, as for many other applications, an understanding of the practical effects of ageing degradation on elastomer seals during long-term exposure is mandatory for predicting the lifetime of such components. According to a long-term test programme on three kinds of rubbers (EPDM and FKM (relevant for application), HNBR (for comparison)), over several years we have studied the degradation and the change of mechanical properties (e.g. hardness, strain at break) at four different ageing temperatures (75 °C, 100 °C, 125 °C and 150 °C) as well as the change of sealing properties. Continuous and intermittent compression stress relaxation (CSR) measurements were performed in order to investigate the respective contribution of crosslinking and chain scission to the observed degradation effects. Thus, the degradation kinetics and mechanisms could be resolved more clearly. For assessing the seal performance, compression set (CS) and leakage rate measurements were conducted. The experimental results showed that the O-rings remained leak-tight under purely static conditions even when CSR, CS and mechanical properties already indicated far advanced degradation. For this reason, a modified leakage test involving a small and rapid partial decompression of the seal was developed that enabled determining an end-of-lifetime criterion for O-rings with a safety margin for thermal shrinkage and vibrations. KW - Seal KW - O-Ring KW - Ageing KW - Component tests PY - 2020 SN - 1863-7116 VL - 15 IS - 3 SP - 146 EP - 151 PB - Gupta CY - Ratingen AN - OPUS4-51161 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kömmling, Anja A1 - Grelle, Tobias A1 - Jaunich, Matthias A1 - Goral, Milan A1 - Wolff, Dietmar T1 - Three-dimensional thermal expansion of neat and irradiated (U)HMWPE materials at elevated temperatures N2 - The thermal expansion of polymeric parts can be an issue in many applications where the available space is limited, or exact dimensions of the part are required. For this study, a device was designed and built that allowed measuring the thermal expansion simultaneously in all three spatial directions on cubic samples with real-scale dimensions (78 mm edge length). The results are shown between 25 °C and 125 °C for two PE materials, one HMWPE and one tempered UHMWPE, for non-irradiated samples as well as cubes that have been irradiated with 100 and 400 kGy. The results measured with the new device were very similar to those measured with conventional thermo-mechanical analysis equipment and to literature data of UHMWPE. The HMWPE material shows a much larger thermal expansion coefficient in one direction compared to the other two directions during the first heating due to frozen stresses from the pressing step during material manufacturing. These stresses are mostly released by the expansion during the first heating, so that the expansion during the second heating is more uniform. The overall volumetric expansion is the same for both heating runs. By contrast, the tempered UHMWPE material shows no significant difference between first and second heating run, as the stresses from processing could already relax in the tempering step. The irradiation treatment does not affect the values significantly for the given test set-up. KW - Lupolen KW - Ultra high molecular weight polyethylene KW - GUR KW - Coefficient of thermal expansion KW - High temperature PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-563987 DO - https://doi.org/10.1016/j.polymertesting.2022.107841 SN - 0142-9418 VL - 117 SP - 1 EP - 8 PB - Elsevier Ltd. AN - OPUS4-56398 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -