TY - CONF A1 - Nehrig, Marko A1 - Wille, Frank A1 - Rolle, Annette A1 - Linnemann, Konrad T1 - Effects of additional gases resulting from residual water inside ILW packages N2 - Packages for intermediate level waste (ILW) often contain residual water besides the actual waste. The water either exists as obvious free water or it may be bound physically or chemically, e.g. as pore water. A water driven gas generation could occur by vaporisation and by radiolysis. Steam as the result of vaporisation causes an increasing pressure inside a package and can affect corrosion. Vaporisation and condensation processes itself change the thermal behavior of the content especially during strongly unsteady thermal situations like accident fire situations. Radiolysis changes the chemical composition of the content which could cause an unexpected interaction, e.g. hydrogen embrittlement. Besides the pressure build-up the radiolysis of water generates hydrogen and oxygen, which can be highly flammable respectively explosive. The gas generation caused by vaporisation and radiolysis must be taken into account during the design and the safety assessment of a package. Pressure build-up, a changed thermal behavior and content chemistry, and especially the risk of accumulation of combustible gases exceeding the limiting concentration for flammability has to be considered in the safety assessment. Approaches to ensure the transportability of stored packages due to radiolysis will be discussed. T2 - ASME 2016 Pressure Vessels & Piping Conference (PVP2016) CY - Vancouver, BC, Canada DA - 17.07.2016 KW - Radioactive material KW - Pressure build-up KW - Gas generation PY - 2016 SN - 978-0-7918-5045-9 VL - 7 SP - Paper 63008, 1 EP - 6 AN - OPUS4-38451 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zerbst, Uwe T1 - Fatigue strength and fracture mechanics of mechanical components N2 - The present paper provides a discussion on all these topics and it offers solutions for it. The authors present an analytical solution of a Delta J based crack driving force based on an R6 type approach but modified for cyclic loading. The gradual build-up of the crack closure effect is modelled by the so-called cyclic R curve which describes the crack size dependency of the fatigue crack propagation threshold in the short crack regime. It is explained how the cyclic R curve is experimentally determined and how it can be estimated by a modified Kitagawa-Takahashi approach. T2 - Proceedings of the 7th International Conference on Mechanics and Materials in Design T2 - 7th International Conference on Mechanics and Materials in Design CY - Albufeira, Portugal DA - 11.07.2017 KW - Fatigue strength KW - S-N curve KW - Crack propagation KW - J-integral KW - Residual lifetime PY - 2017 SN - 978-989-98832-7-7 SP - 507 EP - 508 AN - OPUS4-46863 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rolle, Annette A1 - Ballheimer, Viktor A1 - Neumeyer, Tino A1 - Wille, Frank T1 - Application of leakage rates measured on scaled cask or component models to the package containment safety assessment N2 - The containment systems of transport casks for spent fuel and high radioactive waste usually include bolted lids with metallic or elastomeric seals. The mechanical and thermal loadings associated with the routine, normal and accident conditions of transport can have a significant effect on the leak tightness of such containment system. Scaled cask models are often used for providing the required mechanical and thermal tests series. Leak tests have been conducted on those models. It is also common practice to use scaled component tests to investigate the influence of deformations or displacements of the lids and the seals on the standard leakage rate as well as to study the temperature and time depending alteration of the seals. In this paper questions of the transferability of scaled test results to the full size design of the containment system will be discussed. T2 - ASME 2018 Pressure Vessels and Piping Conference CY - Prag, Czech Republic DA - 15.08 2018 KW - Containment KW - Spent fuel KW - Leakage rate PY - 2018 VL - 7 SP - PVP2018-84089, 1 EP - 8 AN - OPUS4-46533 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weber, Mike A1 - Ballheimer, Viktor A1 - Wille, Frank A1 - Zencker, Uwe T1 - Numerical approach to determine the correct puncture bar length for the IAEA puncture bar drop test N2 - Among other mechanical tests the 1 meter drop onto a steel puncture bar shall be considered for accident safe packages for the transport of radioactive material. According with the IAEA regulations “the bar shall be of solid mild steel of circular section, 15.0 ± 0.5 cm in diameter and 20 cm long, unless a longer bar would cause greater damage…”. The most damaging puncture bar length can be estimated by iterative processes in numerical simulations. On the one hand, a sufficient puncture bar length has to guarantee that shock absorbers or other attachments do not prevent or reduce the local load application to the package, on the other hand, a longer and thus less stiff bar causes a smaller maximum contact force. The contrary influence of increasing puncture bar length and increasing effective drop height shall be taken into account if a shock absorber is directly placed in the target area. The paper presents a numerical approach to identify the bar length that causes maximum damage to the package. Using the example of two typical package masses the sensitivity of contact forces and puncture bar deformations to the initial length are calculated and assessed with regard to the international IAEA package safety requirements. T2 - ASME Pressure Vessels and Piping Conference 2018 CY - Prague, Czech Republic DA - 15.07.2018 KW - Length of puncture bar KW - Mechanical assessment KW - Numerical simulation KW - Puncture bar test KW - Transport of radioactive materials PY - 2018 SP - PVP2018-84614, 1 EP - 7 AN - OPUS4-46538 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lörchner, Dominique A1 - Kroh, L.W. A1 - Köppen, Robert T1 - First insights into electrochemical transformations of two triazine-based brominated flame retardants in model systems N2 - In this work, a study of electrochemical conversion was performed to elucidate different degradation pathways of the heterocyclic brominated flame retardants 1,3,5-Tris-(2,3-dibromopropyl)-1,3,5-triazine-2,4,6-trione (TDBP-TAZTO) and 2,4,6-Tris-(2,4,6-tribromo-phenoxy)-1,3,5-triazine (TTBP-TAZ). EC/MS was used to simulate the (bio)-transformation processes and to identify possible transformation products (TPs) which have never been reported before. For TDBP-TAZTO, six new TPs were observed after the electrochemical oxidation (applied potential of 0 to 1,800 mV vs. Pd/H2). In case of TTBP-TAZ, seven debromination products were generated with an applied potential of 0 to 2,200 mV vs. Pd/H2. The main degradation pathways confirmed by high resolution mass spectrometry for both compounds were hydroxylation, debromination as well as dehydrobromination. KW - Emerging/novel brominated flame retardant KW - Transformation products KW - Electrochemistry mass spectrometry PY - 2018 DO - https://doi.org/10.1039/c8ay01968a SN - 1759-9660 SN - 1759-9679 VL - 10 IS - 43 SP - 5164 EP - 5170 PB - Royal Society of Chemistry CY - Cambridge AN - OPUS4-46488 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weber, Mike A1 - Kömmling, Anja A1 - Jaunich, Matthias A1 - Wolff, Dietmar A1 - Zencker, Uwe A1 - Völzke, Holger A1 - Schulze, Dietmar T1 - Testing and numerical simulation of elastomeric seals under consideration of time dependent effects N2 - Due to delays in the siting procedure to establish a deep geological repository for spent nuclear fuel and high level waste and in construction of the already licensed Konrad repository for low and intermediate level waste, extended periods of interim storage will become more relevant in Germany. BAM is involved in most of the cask licensing procedures and is responsible for the evaluation of cask-related long-term safety issues. Elastomeric seals are widely used as barrier seals for containers for low and intermediate level radioactive waste. In addition they are also used as auxiliary seals in spent fuel storage and transportation casks (dual purpose casks (DPC)). To address the complex requirements resulting from the described applications, BAM has initiated several test programs for investigating the behavior of elastomeric seals. These include experiments concerning the hyperelastic and viscoelastic behavior at different temperatures and strain rates, the low temperature performance down to -40°C, the influence of gamma irradiation and the aging behavior. The first part of the paper gives an overview of these tests, their relevant results and their possible impact on BAM’s work as a consultant in the framework of approval and licensing procedures. The second part presents an approach of the development of a finite element model using the finite element code ABAQUS®. The long-term goal is to simulate the complex elastomeric behavior in a complete lid closure system under specific operation and accident conditions. T2 - ASME 2016 Pressure Vessels & Piping Conference (PVP2016) CY - Vancouver, BC, Canada DA - 17.07.2016 KW - Elastomeric seals KW - Testing KW - Low temperature behavior KW - Aging KW - Simulation KW - Time dependent effects PY - 2016 SN - 978-0-7918-5045-9 VL - 7 SP - Paper 63192, 1 EP - 10 AN - OPUS4-37046 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - El-Khatib, A. H. A1 - Radbruch, H. A1 - Trog, S. A1 - Neumann, B. A1 - Paul, F. A1 - Koch, A. A1 - Linscheid, M. W. A1 - Jakubowski, Norbert A1 - Schellenberger, E. T1 - Gadolinium in human brain sections and colocalization with other elements N2 - Recent recommendations by the Food and Drug Administration1 and the European Medicines Agency2 are to limit the clinical use of linear gadolinium-based contrast agents (GBCAs) due to convincing evidence of deposition in tissues. Macrocyclic GBCA continued to be considered safe, provided that patients have normal renal function. To date, given the low sensitivity of conventional MRI, there has been a debate about the signal increase following the injections of a macrocyclic GBCA. KW - Gadolinium PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-471309 DO - https://doi.org/10.1212/NXI.0000000000000515 SN - 2332-7812 VL - 6 IS - 1 SP - e515, 1 EP - 3 PB - American Academy of Neurology AN - OPUS4-47130 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -