TY - CONF A1 - Lüth, Peter A1 - Uhlig, S. A1 - Frost, K. A1 - Malow, Marcus A1 - Michael-Schulz, Heike A1 - Schmidt, Martin A1 - Zakel, S. T1 - CEQAT-DGHS interlaboratory tests for chemical safety: Validation of laboratory test methods by determining the measurement uncertainty and probability of incorrect classification including so-called “Shark profiles” N2 - Laboratory test results are of vital importance for correctly classifying and labelling chemicals as “hazardous” as defined in the UN Globally Harmonized System (GHS) / EC CLP Regulation or as “dangerous goods” as defined in the UN Recommendations on the Transport of Dangerous Goods. Interlaboratory tests play a decisive role in assessing the reliability of laboratory test results. Interlaboratory tests performed over the last 10 years have examined different laboratory test methods. After analysing the results of these interlaboratory tests, the following conclusions can be drawn: 1. There is a need for improvement and validation for all laboratory test methods examined. 2. To avoid any discrepancy concerning the classification and labelling of chemicals, the use of validated laboratory test methods should be state of the art, with the results accompanied by the measurement uncertainty and (if applicable) the probability of incorrect classification. This paper addresses the probability of correct/incorrect classification (for example, as dangerous goods) on the basis of the measurement deviation obtained from interlaboratory tests performed by the Centre for quality assurance for testing of dangerous goods and hazardous substances (CEQAT-DGHS) to validate laboratory test methods. This paper outlines typical results (e.g. so-called “Shark profiles” – the probability of incorrect classification as a function of the true value estimated from interlaboratory test data) as well as general conclusions and steps to be taken to guarantee that laboratory test results are fit for purpose and of high quality. T2 - 13th International Symposium on Hazards, Prevention and Mitigation of Industrial Explosions (ISHPMIE 2020) CY - Braunschweig, Germany DA - 27.07.2020 KW - Dangerous goods KW - Hazardous substances KW - Interlaboratory test KW - Test method KW - Validation KW - Quality assurance KW - Measurement uncertainty KW - Incorrect classification KW - Shark profile PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-515376 UR - https://oar.ptb.de/files/download/5f3e662f4c93901010006dbf DO - https://doi.org/10.7795/810.20200724 VL - 2020 SP - 50 EP - 61 PB - Open Access Repository der Physikalisch-Technischen Bundesanstalt (PTB-OAR) CY - Braunschweig AN - OPUS4-51537 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Braun, T. A1 - Uhlmann, E. A1 - Häcker, Ralf A1 - Jäger, M. A1 - Rauch, H. A1 - Kondas, J. A1 - Brach, K. A1 - Singh, R. T1 - Evaluation of electric conductivity and mechanical load capacity of copper deposits for application in large winding components for electrical high-voltage machines made with cold spray additive manufacturing N2 - In line with the industrial trend of additive manufacturing, cold spray as a non-laser-based process is becoming increasingly important for many fields of application. For the evaluation of additive manufacturing of winding components made of copper for large electrical high-voltage machines, material and component properties such as electrical conductivity, mechanical load capacity and the component size that can be produced are of particular importance. In this context, the cold spray process offers advantages over laser-based additive manufacturing processes such as laser powder bed fusion (LPBF) or laser cladding by using the kinetic energy of the copper powder particles to generate particle cohesion. To investigate the electrical conductivity as well as the mechanical load capacity of cold spray parts, specimens were machined out of cold sprayed bulk copper deposits. The characteristic values were obtained with regard to the direction of deposition, which is defined by the direction of the robot’s movement. Thus, for the investigation of the component properties, specimens were provided that had been produced both longitudinally and transversely as well as orthogonally to the direction of deposition. The results of the investigations show that both the electrical conductivity and the mechanical load capacity of the specimen have a strong preferential direction of the specimen orientation with respect to the direction of deposition. Furthermore, it could be shown that by increasing the deposition height, there is an increasing oxygen content in the sample material, combined with increasingly significant defect networks. These effects have a negative impact on the electrical conductivity as well as on the mechanical load capacity. As a conclusion, further need for investigation is identified in the optimization of the process parameters as well as in the deposition strategy for the additive manufacturing of large-volume components with cold spray. T2 - ITSC 2022 CY - Wien, Austria DA - 04.05.2022 KW - Cold Spray KW - Electrical conductivity KW - Copper powder particles KW - Large electrical high-voltage machine PY - 2022 SP - 1 EP - 7 AN - OPUS4-56108 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schoknecht, Ute A1 - Mathies, Helena A1 - Wegner, R. A1 - Uhlig, S. A1 - Baldauf, H. A1 - Colson, B. T1 - Leaching of biocides from organic coatings N2 - Biocide leaching was investigated for acrylate and vinyl acetate based coatings containing biocides either as liquid formulations or microcapsules. Laboratory and field tests indicate similar relations of results on carbendazim, diuron, terbutryn and OIT from different coatings in laboratory and field experiments. Emissions were higher in EN 16105 laboratory tests than from vertically installed test specimens exposed to weathering, and slower for microencapsulated biocides. Competing processes that cause losses of active substances can occur in both tests, but to a higher degree in field experiments. Emission curves related to runoff water were similar in repeated field experiments. Relative humidity, temperature and global radiation were identified as meteorological factors that affect leaching by complex interaction besides the amount of driving rain. T2 - 12th International Conference 'Advances in Coatings Technology ACT´16' CY - Sosnowiec, Poland DA - 08.11.2016 KW - Biocide KW - Leaching KW - Coating PY - 2016 SN - 978‒83‒63555‒50‒4 SP - Paper 51, 1 EP - 10 AN - OPUS4-38236 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scheidemann, Robert A1 - Qiao, Linan A1 - Müller, Karsten T1 - Ermittlung dynamischer Kennwerte von Dämpferbeton für die Simulation des Beanspruchungsverhaltens N2 - Die Sicherheit und Integrität von Verpackungen radioaktiver Stoffe wird anhand von numerischen Berechnungen bewertet. Bei einem Anprall oder Absturz sind die mechanischen Beanspruchungen auf die Behälter auch von den Eigenschaften des Untergrunds abhängig. Um potentielle Gefahren während der Verladung zu minimieren, wird energieabsorbierender Dämpferbeton in den Handhabungsbereichen nuklearer Lager eingesetzt. Zu einer umfassenden sicherheitstechnischen Analyse und Bewertung gehört die Berücksichtigung des Beanspruchungsverhaltens von Dämpferbeton. Hierfür ist ein numerisches Materialmodell notwendig, das in der Literatur bisher nicht vorlag. Die dafür notwendigen dynamischen Kennwerte sind in verschiedenen Druck- und Eindringversuchen ermittelt worden. Dazu wurden dynamische Druckversuche an würfelförmigen Prüfkörpern durchgeführt, sowie Eindringversuche mit unterschiedlichen Eindringkörpern und Dämpferbetonproben. Die experimentell ermittelten Kennwerte wurden verwendet, um ein Materialmodell für Dämpferbeton zu entwickeln und kritische Beanspruchungsszenarien numerisch zu berechnen. Um die Qualität des Materialmodells zu überprüfen, wurde ein realitätsnaher Fallversuch eines Behälters in Originalgröße auf ein lagertypisches Dämpferbetonfundament durchgeführt. In dem Beitrag sollen die unterschiedlichen Untersuchungen zur Ermittlung dynamischer Kennwerte sowie deren Ergebnisse dargestellt werden. Gezeigt werden ebenso numerische Nachberechnungen einzelner Versuche sowie die ausführliche Berechnung des Fallversuchs im Originalmaßstab. Experimentelle und numerische Ergebnisse aus der Simulation werden hier gegenübergestellt. T2 - Tagung Werkstoffprüfung 2016 CY - Neu-Ulm, Germany DA - 01.12.2016 KW - Druckversuche KW - Eindringversuche KW - Dynamisch KW - Simulation KW - Materialmodell KW - Dämpferbeton PY - 2016 SN - 978-3-514-00830-4 VL - 2016 SP - 149 EP - 154 PB - Stahleisen GmbH CY - Düsseldorf AN - OPUS4-38580 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Nehrig, Marko A1 - Wille, Frank A1 - Rolle, Annette A1 - Linnemann, Konrad T1 - Effects of additional gases resulting from residual water inside ILW packages N2 - Packages for intermediate level waste (ILW) often contain residual water besides the actual waste. The water either exists as obvious free water or it may be bound physically or chemically, e.g. as pore water. A water driven gas generation could occur by vaporisation and by radiolysis. Steam as the result of vaporisation causes an increasing pressure inside a package and can affect corrosion. Vaporisation and condensation processes itself change the thermal behavior of the content especially during strongly unsteady thermal situations like accident fire situations. Radiolysis changes the chemical composition of the content which could cause an unexpected interaction, e.g. hydrogen embrittlement. Besides the pressure build-up the radiolysis of water generates hydrogen and oxygen, which can be highly flammable respectively explosive. The gas generation caused by vaporisation and radiolysis must be taken into account during the design and the safety assessment of a package. Pressure build-up, a changed thermal behavior and content chemistry, and especially the risk of accumulation of combustible gases exceeding the limiting concentration for flammability has to be considered in the safety assessment. Approaches to ensure the transportability of stored packages due to radiolysis will be discussed. T2 - ASME 2016 Pressure Vessels & Piping Conference (PVP2016) CY - Vancouver, BC, Canada DA - 17.07.2016 KW - Radioactive material KW - Pressure build-up KW - Gas generation PY - 2016 SN - 978-0-7918-5045-9 VL - 7 SP - Paper 63008, 1 EP - 6 AN - OPUS4-38451 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rühlmann, Madlen A1 - Büchele, Dominique A1 - Schmid, Thomas A1 - Ostermann, Markus T1 - Development of an online-analysis technique for the determination of plant essential nutrients in soils using XRF and LIBS N2 - Currently, there is almost no comprehensive mapping of agricultural cropland because of the lack of fast and affordable mapping methods for important soil properties. Arable land of some hectares in size show a broad range of different nutrient compositions. Because of this heterogeneity wrong fertilization can occur and can cause environmental pollution or lead to smaller harvests and this is simply a waste of resources. The goal of I4S (intelligence for soil) is to develop an integrated system for site-specific soil fertility management. The I4S consortium consists of 10 different institutions, which are testing various sensors for their suitability for the requested applications. Besides the preparation of reference materials, the main task of the Federal Institute for Materials Research and Testing (BAM) in this project is the method development for online-XRF (x-ray fluorescence spectroscopy) and for online-LIBS (laser-induced breakdown spectroscopy) sensor systems. Both methods have the advantage that there is no or only little sample preparation necessary. Each method provides a fast and simultaneous multi-element analysis. Both measurement setups can be utilized for a mobile application which is fundamental for reaching the goals of I4S. Having finally a set of some reference materials, further work will focus on the online-XRF and online-LIBS methods in order to obtain useable calibration models. The calibration models will then be tested using stationary and moving samples. T2 - 12. Kolloquium Prozessanalytik CY - Berlin, Germany DA - 28.11.2016 KW - RFA KW - LIBS KW - Soil KW - Agricultural KW - Online KW - Sensor system PY - 2016 SP - P12, 63 EP - 65 AN - OPUS4-38377 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zerbst, Uwe T1 - Fatigue strength and fracture mechanics of mechanical components N2 - The present paper provides a discussion on all these topics and it offers solutions for it. The authors present an analytical solution of a Delta J based crack driving force based on an R6 type approach but modified for cyclic loading. The gradual build-up of the crack closure effect is modelled by the so-called cyclic R curve which describes the crack size dependency of the fatigue crack propagation threshold in the short crack regime. It is explained how the cyclic R curve is experimentally determined and how it can be estimated by a modified Kitagawa-Takahashi approach. T2 - Proceedings of the 7th International Conference on Mechanics and Materials in Design T2 - 7th International Conference on Mechanics and Materials in Design CY - Albufeira, Portugal DA - 11.07.2017 KW - Fatigue strength KW - S-N curve KW - Crack propagation KW - J-integral KW - Residual lifetime PY - 2017 SN - 978-989-98832-7-7 SP - 507 EP - 508 AN - OPUS4-46863 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Otremba, Frank A1 - Bradley, I. A1 - Romero-Navarrete, José A. T1 - Boiling Thermohydraulics within Pressurized Vessels N2 - Transport safety depends in great extent of what happens to the cargo once the carrying vehicle derails or rollovers. The exposure of tanks to direct fire is a condition that potentially involves catastrophic consequences. Studying the behavior of the contained fluid under these drastic circumstances, is critical to develop methods and techniques to mitigate the serious consequences of many mishaps. In this paper, the experimental potentials of a Particle Image Velocimetry data acquisition system are described, for providing experimental data that could be used to calibrate mathematical models. As an example of the situations that need to be modelled, an experiment is described concerning the effect of the boundary conditions and protecting devices, on the rate of variation of pressure and temperature of the fluid in a tank exposed to a direct fire. In this regard, the results emphasize the importance of equipping the vessels with both thermal insulation and safety valves. T2 - WCECS 2018 CY - San Francisco, CA, USA DA - 23.10.2018 KW - Thermohydraulic KW - Vessels PY - 2018 SN - 978-988-14049-0-9 SN - 2078-0958 SN - 2078-0966 SP - 538 EP - 542 AN - OPUS4-46419 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. ED - Otremba, Frank ED - Lozano Guzmán, A. A. T1 - Study on the potential effect of sloshing cargoes on rail endurance N2 - Current railway infrastructure design methodologies take into account the load Transfer derived from the lateral acceleration exerted on the vehicle while Tuning, recommending the highest grades for such infrastructure Segments. T2 - Railways 2018 CY - Sitges, Barcelona, Spain DA - 03.09.2018 KW - Potential effect KW - Sloshing cargoes KW - Rail endurance PY - 2018 UR - http://www.railwaysconference.com/ SP - 1 EP - 3 AN - OPUS4-45908 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. ED - Otremba, Frank ED - Lozano Guzmán, A. A. T1 - Comparative simulations of rail and road infrastructure with the transportation of liquid cargoes N2 - Transportation of liquids implies lower stability Limits for the Transportation vehicles, and a potentially higher damaging effect on the infrastructure. In this paper, these two effects are comparatively simulated for two modes of Transportation. T2 - ECT2018 Conference CY - Sitges, Barcelona, Spain DA - 04.09.2019 KW - Comparative simulations KW - Rail KW - Road KW - Infrastructure KW - Transportation KW - Liquid cargoes PY - 2018 UR - http://www.ectconference.com/ SP - 1 EP - 3 AN - OPUS4-45910 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -