TY - CONF A1 - Fürst, Richard A1 - Häßler, Dustin A1 - Peter, A. A1 - Rohleder, R. A1 - Hothan, Sascha T1 - European test standard intumescent coatings applied to steel tension bars with solid section N2 - Intumescent coatings are used in civil engineering to improve the fire resistance of steel constructions. Due to the thin coating thickness and the profile-following application, the architectural appearance of the steel structure can be preserved. EN 13381-8 provides regulations to determine the contribution to the fire resistance of intumescent coatings applied to steel beams and columns. The scope of this standard excludes tension members and steel members with solid sections. For products that have already been successfully tested and assessed on beams and columns, EN 13381-10 offers the possibility based on unloaded fire tests to extend the scope of application of intumescent coatings to tension bars with solid sections. This approach contradicts the national safety level in Germany, where mechanically loaded testing is mandatory. Therefore, a new part of the test standard series EN 13381 is currently developed to enable the application of intumescent coatings on steel tension bars with solid section based on mechanically loaded fire tests. BAM has already carried out numerous fire tests on loaded steel tension members with intumescent coatings. Currently, in the BAM research project FIRESTEMIC, the influence of the steel bar orientation and the profile type on the thermal performance of intumescent coatings are investigated. Both questions concerning the thermal protection ability of intumescent coatings were analysed based on three different test sets, which were carried out in the tension furnace (Fig. 1a). The fire exposure corresponds to the standard temperature-time curve according to EN 1363-1. This paper summarises the main findings from the fire tests conducted in the FIRESTEMIC project. The results serve as an experimental background for the proposal of the new standard. Regarding the bar orientation, a new test setup was developed and proposed for the new standard. The two tested commercial water-based intumescent coatings with applied dry film thickness from 1.5 mm to 2.5 mm showed only a slight dependence on the bar orientation. In terms of the steel profile type, circular and rectangular solid sections with identical section factor and applied dry film thickness were tested. It was observed that the circular solid bars with diameter 30 mm heat up faster compared to the solid rectangular bars with dimension 30×30 mm (Fig. 1b). Also at larger steel bars, i.e. diameter 40 mm and dimension 40×40 mm, the same trend occurred. Thus, it is recommended for the new test standard to allow a transfer of the test results from circular to rectangular solid sections. In addition, the paper will describe and explain the test and assessment procedure proposed for the newly developed standard. T2 - 8th Symposium Structural Fire Engineering CY - Brunswick, Germany DA - 13.09.2022 KW - Fire test KW - Steel KW - Tension member KW - Intumescent coating KW - Test standard PY - 2022 SP - 1 EP - 14 PB - TU Braunschweig CY - Braunschweig AN - OPUS4-55703 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Yevtushenko, Oleksandra A1 - Le, Quynh Hoa A1 - Bettge, Dirk T1 - Suitability of Metallic Materials in CC(U)S Applications N2 - Carbon Capture Utilization and Storage (CCUS) is a promising technology to reach the target for reduction of CO2 emissions, e.g. from fossil-fuel operated power plants or cement mills. Crucial points for a sustainable and future-proof CCUS procedure are reliability and cost efficiency of the whole process chain, including separation of CO2 from the source, compression of CO2, its subsequent transportation to the injection site and injection into geological formations, e.g. aquifers. Most components that are in contact with CO2-stream consist of steel. Depending on the operating conditions (e.g. temperature, pressure, and CO2-stream composition) specific suitable steels should be used. The compressed CO2-stream is likely to contain process specific impurities; small amounts of SO2 and NO2 in combination with oxygen and water are most harmful. One approach, as currently preferred by pipeline operators, is to clean the CO2-stream to such levels, acceptable for carbon steel, commonly used as pipeline material. Another consideration would be, to use more corrosion resistant alloys for CO2-streams with higher amounts of impurities. Due to the absence of certified benchmarks for upper limits, systematic experiments with impurities in the CO2-stream were carried out reflecting mainly transport and injection conditions. Within the COORAL project (German acronym for “CO2 purity for capture and storage”) levels of impurities in the CO2-stream, being acceptable when using specific steels, were evaluated. Material exposure to dense or multiphase carbon dioxide (CO2) containing specific amounts of water vapor, oxygen (O2) sulfur dioxide (SO2), nitrogen dioxide (NO2), carbon monoxide (CO) can be a challenge to steels. In some situations, condensation of impurities and reaction products from the CO2 stream can occur. CO2 saturated brine is supposed to rise in the well when the injection process is interrupted. The material selection shall ensure that neither CO2 nor brine or a combination of both will leak out of the inner tubing. This COORAL-work was extended by a follow-up project, called CLUSTER. Here the additional influence of impurities was investigated when merging CO2 streams from different sources, combined within a “so-called” cluster. Results are summarized within the following table regarding suitability for different parts of the process chain. T2 - EUROCORR 2021 CY - Online meeting DA - 20.09.2021 KW - Carbon capture storage KW - Corrosion KW - Steel KW - CCS KW - CCU KW - CO2 PY - 2021 SP - 1 EP - 2 AN - OPUS4-53460 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Stoljarova, A. A1 - Regenspurg, S. T1 - Influence of Precipitating Brine Components on Materials Selection for Geothermal Applications N2 - Since geothermal wells are a feasible energy source to replace fossil fuel supply, many technologies have been developed to take advantage of geothermal energy. Nevertheless, service conditions in geothermal facilities are in many cases extreme in terms of corrosion due to the chemical composition of hydrothermal fluids and temperatures. Therefore, materials selection based on preliminary material qualification is essential to guarantee a secure and reliable operation of the facilities. During operation of a geothermal research facility in Groß Schönebeck copper and lead effects have been found downhole. Occurring mechanisms and measures to prevent precipitation or scaling needed to be investigated as well as potential influences of such precipitates on corrosion resistance of metallic materials used for equipment. This contribution deals with the evaluation of the corrosion behavior of carbon steel and corrosion resistant alloys in copper and/or lead containing artificial geothermal water, simulating the conditions in the Northern German Basin. The behavior of these materials in an artificial geothermal water obtained by electrochemical measurements and exposure tests are presented. While carbon steel exhibits precipitation and deposition, higher alloyed material shows different response to such species and a higher resistance in saline geothermal water. Basing on these results the suitability of the investigated corrosion resistant alloy is given for use in such conditions, whereas carbon steel creates difficulties due to its susceptibility to Cu- and Pb-precipitation. T2 - World Geothermal Congress CY - Online meeting DA - 30.03.2021 KW - Copper KW - Lead KW - Corrosion KW - Steel KW - Geothermal energy PY - 2021 SP - 1 EP - 11 AN - OPUS4-52828 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -