TY - CONF A1 - Lecompagnon, Julien T1 - Full-frame thermographic super-resolution with 2D-structured laser heating N2 - Thermographic super-resolution techniques allow the resolution of defects/inhomogeneities beyond the classical limit, which is governed by the diffusion properties of thermal wave propagation. Photothermal super-resolution is based on a combination of an experimental scanning strategy and a numerical optimization which has been proven to be superior to standard thermographic methods in the case of 1D linear defects. In this contribution, we report on the extension of this approach towards a full frame 2D photothermal super-resolution technique. The experimental approach is based on a repeated spatially structured heating using high power lasers. In a second post-processing step, several measurements are coherently combined using mathematical optimization and taking advantage of the (joint) sparsity of the defects in the sample. In our work we extend the possibilities of the method to efficiently detect and resolve defect cross sections with a fully 2D-structured blind illumination. T2 - Thermosense: Thermal Infrared Applications XLIII CY - Online meeting DA - 12.04.2021 KW - Thermography KW - Super-resolution KW - NDT KW - Inspection KW - Image resolution PY - 2021 UR - https://www.spiedigitallibrary.org/conference-proceedings-of-spie/11743/117430T/Full-frame-thermographic-super-resolution-with-2D-structured-laser-heating/10.1117/12.2586093.full AN - OPUS4-52526 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien T1 - 2D-Photothermal super-resolution with sparse matrix stacking N2 - Thermographic super resolution techniques allow the spatial resolution of defects/inhomogeneities below the classical limit, which is governed by the diffusion properties of thermal wave propagation. In this work, we re-port on the extension of this approach towards a full frame 2D super resolution technique. The approach is based on a repeated spatially structured heating using high power lasers. In a second post-processing step, several measurements are coherently combined using mathematical optimization and taking advantage of the (joint) sparsity of the defects in the sample. T2 - Sensor and Measurement Science International Conference SMSI 2021 CY - Online meeting DA - 03.05.2021 KW - Thermography KW - Super-resolution KW - NDT KW - Inspection KW - Image resolution PY - 2021 AN - OPUS4-52579 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Adams, L. C. A1 - Brangsch, J. A1 - Reimann, C. A1 - Kaufmann, Jan Ole A1 - Buchholz, R. A1 - Karst, U. A1 - Botnar, R. M. A1 - Hamm, B. A1 - Makowski, M. R. T1 - Simultaneous molecular MRI of extracellular matrix collagen and inflammatory activity to predict abdominal aortic aneurysm rupture N2 - Abdominal aortic aneurysm (AAA) is a life-threatening vascular disease with an up to 80% mortality in case of rupture. Current biomarkers fail to account for size-independent risk of rupture. By combining the information of different molecular probes, multi-target molecular MRI holds the potential to enable individual characterization of AAA. In this experimental study, we aimed to examine the feasibility of simultaneous imaging of extracellular collagen and inflammation for size-independent prediction of risk of rupture in murine AAA. The study design consisted of: (1) A outcome-based longitudinal study with imaging performed once after one week with follow-up and death as the end-point for assessment of rupture risk. (2) A week-by-week study for the characterization of AAA development with imaging after 1, 2, 3 and 4 weeks. For both studies, the animals were administered a type 1 collagen-targeted gadolinium-based probe (surrogate marker for extracellular matrix (ECM) remodeling) and an iron oxide-based probe (surrogate marker for inflammatory activity), in one imaging session. In vivo measurements of collagen and iron oxide probes showed a significant correlation with ex vivo histology (p < 0.001) and also corresponded well to inductively-coupled plasma-mass spectrometry and laser-ablation inductively-coupled plasma mass spectrometry. Combined evaluation of collagen-related ECM remodeling and inflammatory activity was the most accurate predictor for AAA rupture (sensitivity 80%, specificity 100%, area under the curve 0.85), being superior to information from the individual probes alone. Our study supports the feasibility of a simultaneous assessment of collagen-related extracellular matrix remodeling and inflammatory activity in a murine model of AAA. KW - Atherosclerosis KW - Specific probe KW - Magnetic resonance imaging KW - Gadolinium KW - Iron oxide KW - Ferumoxytol KW - Inductively‑coupled mass spectrometry KW - ICP-MS KW - LA-ICP-MS KW - Laser ablation PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-525864 UR - https://www.nature.com/articles/s41598-020-71817-x DO - https://doi.org/10.1038/s41598-020-71817-x VL - 10 IS - 1 SP - 15206 PB - Springer Nature Limited CY - London, New York, Berlin, Shanghai and Tokyo AN - OPUS4-52586 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien A1 - Ahmadi, Samim A1 - Hirsch, Philipp Daniel A1 - Ziegler, Mathias T1 - 2D-Photothermal Super Resolution with Sparse Matrix Stacking N2 - Thermographic super resolution techniques allow the spatial resolution of defects/inhomogeneities below the classical limit, which is governed by the diffusion properties of thermal wave propagation. In this work, we report on the extension of this approach towards a full frame 2D super resolution technique. The approach is based on a repeated spatially structured heating using high power lasers. In a second post-processing step, several measurements are coherently combined using mathematical optimization and taking advantage of the (joint) sparsity of the defects in the sample T2 - Sensor and Measurement Science International Conference SMSI 2021 CY - Online meeting DA - 03.05.2021 KW - Thermography KW - Super-resolution KW - NDT KW - Inspection KW - Image resolution PY - 2021 SN - 978-3-9819376-4-0 DO - https://doi.org/10.5162/SMSI2021/C2.2 VL - SMSI 2021 - Sensors and Instrumentation SP - 183 EP - 184 AN - OPUS4-52589 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lay, Vera T1 - 3D seismic imaging of the Alpine Fault and the glacial valley at Whataroa, New Zealand N2 - The Alpine Fault at the West Coast of the South Island (New Zealand) is a major plate boundary that is expected to rupture in the next 50 years, likely as a magnitude 8 earthquake. The Deep Fault Drilling Project (DFDP) aimed to deliver insight into the geological structure of this fault zone and its evolution by drilling and sampling the Alpine Fault at depth. Here we present results from a seismic survey around the DFDP-2 drill site in the Whataroa Valley where the drillhole almost reached the fault plane. This unique 3D seismic survey includes several 2D lines and a 3D array at the surface as well as borehole recordings. Within the borehole, the unique option to compare two measurement systems is used: conventional three-component borehole geophones and a fibre optic cable (heterodyne Distributed Vibration Sensing system (hDVS)). Both systems show coherent signals but only the hDVS system allowed a recording along the complete length of the borehole. Despite the challenging conditions for seismic imaging within a glacial valley filled with sediments and steeply dipping valley flanks, several structures related to the valley itself as well as the tectonic fault system are imaged. The pre-processing of the seismic data also includes wavefield separation for the zero-offset borehole data. Seismic images are obtained by prestack depth migration approaches. Within the glacial valley, particularly steep valley flanks are imaged directly and correlate well with results from the P-wave velocity model obtained by first arrival travel-time tomography. Additionally, a glacially over-deepened trough with nearly horizontally layered sediments is identified about 0.5 km south of the DFDP-2B borehole. With regard to the expected Alpine fault zone, a set of several reflectors dipping 40-56° to the southeast are identified in a ~600 m wide zone between depths of 0.2 and 1.2 km that is interpreted to be the minimum extent of the damage zone. Different approaches image one distinct reflector dipping at 40°, which is interpreted to be the main Alpine Fault reflector. This reflector is only ~100 m ahead from the lower end of the borehole. At shallower depths (z<0.5 km), additional reflectors are identified as fault segments and generally have steeper dips up to 56°. About 1 km south of the drill site, a major fault is identified at a depth of 0.1-0.5 km that might be caused by the regional tectonics interacting with local valley structures. A good correlation is observed among the separate seismic data sets and with geological results such as the borehole stratigraphy and the expected surface trace of the fault. In conclusion, several structural details of the fault zone and its environment are seismically imaged and show the complexity of the Alpine Fault at the Whataroa Valley. Thus, a detailed seismic characterization clarifies the subsurface structures, which is crucial to understand the transpressive fault’s tectonic processes. T2 - EGU 2021 General Assembly CY - Online meeting DA - 19.04.2021 KW - Imaging KW - Signal processing KW - Seismic KW - Borehole KW - DAS PY - 2021 AN - OPUS4-52614 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Philipp, Rosemarie T1 - EURAMET.QM-S14 Measurement capabilities for the quantification of ethanol in water N2 - The presentation summarizes the results of the EURAMET key comparison QM-S14 “Measurement capabilities for the quantification of ethanol in water”. Possible options for the key comparison reference value (KCRV) are discussed. A Bayesian approach is finally used to estimate the KCRV and the degrees of equivalence of participants. T2 - EURAMET TC-MC Sector Committee Bio- and Organic Analysis Meeting CY - Online meeting DA - 02.02.2021 KW - Certified reference material KW - EMPIR project KW - Interlaboratory comparison PY - 2021 AN - OPUS4-52615 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gantois, F. T1 - EURAMET.QM-S13 Comparison of value assigned forensic alcohol in water reference materials N2 - The presentation summarizes the results of the EURAMET key comparison QM-S13 “Comparison of value assigned forensic alcohol in water reference materials”. Possible options for the key comparison reference function (KCRF) are discussed: the frequentist approach and a Bayesian approach. Both methods are used to determine the degrees of equivalence of materials and participants. T2 - EURAMET TC-MC Sector Committee Bio- and Organic Analysis Meeting CY - Online meeting DA - 02.02.2021 KW - Certified reference material KW - EMPIR project KW - Iinterlaboratory comparison PY - 2021 AN - OPUS4-52617 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Held, Mathias A1 - Rashwan, Abdalla A1 - Lauschkin, Maik A1 - Bulling, Jannis A1 - Lugovtsova, Yevgeniya A1 - Prager, Jens T1 - Inverse determination of elastic material parameters from ultrasonic guided waves dispersion measurements using Convolutional Neuronal Networks N2 - In the context of Industry 4.0 and especially in the field of Structural Health Monitoring, Condition Monitoring and Digital Twins, simulations are becoming more and more important. The exact determination of material parameters is required for realistic results of numerical simulations of the static and dynamic behavior of technical structures. There are many possibilities to determine elastic material parameters. One possibility of non-destructive testing are ultrasonic guided waves. For the evaluation of the measurement results, mostly inverse methods are applied in order to be able to draw conclusions about the elastic material parameters from analysing the ultrasonic guided wave propagation. For the inverse determination of the elastic material Parameters with ultrasonic guided waves, several investigations were carried out, e.g. the determination of the isotropic material parameters through the point of zero-groupvelocity or anisotropic material parameters with a simplex algorithm. These investigations are based on the evaluation of dispersion images. Machine learning and in particular Convolutional Neural Networks (CNN) are one possibility of the automated evaluation from Image data, e.g. classification or object recognition problems. This article shows how the dispersive behavior of ultrasonic guided waves and CNNs can be used to determine the isotropic elastic constants of plate-like structures. T2 - SMSI 2021 2021-05-03 - 2021-05-06 digital CY - Online meeting DA - 03.05.2021 KW - Convolutional Neuronal Networks KW - Inverse Probleme KW - Materialcharakterisierung KW - guided waves KW - Dispersion PY - 2021 SN - 978-3-9819376-4-0 DO - https://doi.org/10.5162/SMSI2021/A10.2 VL - 2021 SP - 239 EP - 240 AN - OPUS4-52618 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Fabian T1 - A fast and simple extraction method for the determination of PFASs in soil samples - HR-CS-GFMAS a new screening tool N2 - Here, we describe a fast and simple extraction method for the determination of per- and polyfluorinated alkyl substances (PFASs) utilizing extractable organic fluorine (EOF) sum parameter analysis and high resolution-continuum source-graphite furnace molecular absorption spectrometry (HR-CS-GFMAS) in soil samples. After extraction and separation of inorganic and organic fluorinated compounds, organically bound fluorinated compounds were indirectly determined via the molecular absorption of gallium mono-fluoride at 211.248 nm. The implementation of the decisions of the “Stockholm Convention on persistent organic pollutants” as well as the “Protocol on Persistent Organic Pollutants of the Convention on Long-Range Transboundary Air Pollution” of the UNECE include the reduction respectively the elimination of PFASs in the environment. Currently, regulations aim to target single compounds (mostly C8-PFAS). But the PFAS group includes over 4700 substances, which are potentially persistent and toxic, thus target analytical approaches are not suitable for a holistic approach investigating the PFAS pollutant situation. Furthermore, forbidden PFASs are substituted by short-chain PFASs, thus the number of unknow substances is steadily increasing. For this reason, sum parameter approaches are more suitable to investigate and assess the pollution situation as well as derive exposure limits. Our developed analytical method was successfully applied to determine PFASs in soil samples from a polluted site. In view of steadily increasing numbers of PFAS substances, our method will make an important contribution in assessing the pollution situation as well as support policy makers in deriving exposure limits for PFAS in the future. T2 - ENSOr - International Workshop on Emerging policy challenges on new soil contaminants CY - Online Meeting DA - 06.05.2021 KW - PFAS KW - HR-CS-GFMAS KW - Soil KW - Sediment PY - 2021 AN - OPUS4-52608 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Brauckmann, C. A1 - Pramann, A. A1 - Rienitz, O. A1 - Schulze, A. A1 - Phukphatthanachai, Pranee A1 - Vogl, Jochen T1 - Combining Isotope Dilution and Standard Addition—Elemental Analysis in Complex Samples N2 - A new method combining isotope dilution mass spectrometry (IDMS) and standard addition has been developed to determine the mass fractions w of different elements in complex matrices: (a) silicon in aqueous tetramethylammonium hydroxide (TMAH), (b) sulfur in biodiesel fuel, and (c) iron bound to transferrin in human serum. All measurements were carried out using inductively coupled plasma mass spectrometry (ICP–MS). The method requires the gravimetric preparation of several blends (bi)—each consisting of roughly the same masses (mx,i) of the sample solution (x) and my,i of a spike solution (y) plus different masses (mz,i) of a reference solution (z). Only these masses and the isotope ratios (Rb,i) in the blends and reference and spike solutions have to be measured. The derivation of the underlying equations based on linear regression is presented and compared to a related concept reported by Pagliano and Meija. The uncertainties achievable, e.g., in the case of the Si blank in extremely pure TMAH of urel (w(Si)) = 90% (linear regression method, this work) and urel (w(Si)) = 150% (the method reported by Pagliano and Meija) seem to suggest better applicability of the new method in practical use due to the higher robustness of regression analysis. KW - Isotope dilution mass spectrometry KW - tandard addition KW - ICP-MS KW - lank characterization KW - Silicon KW - Sulfur KW - Transferrin KW - Tetramethylammonium hydroxide KW - Biodiesel fuel KW - Human serum PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-526376 DO - https://doi.org/10.3390/molecules26092649 VL - 26 IS - 9 SP - 2649 PB - MDPI CY - Basel AN - OPUS4-52637 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -