TY - JOUR A1 - Klimek, André A1 - Stelzner, Ludwig A1 - Hothan, Sascha A1 - Rogge, Andreas T1 - Fire induced concrete spalling in combination with size effects N2 - The size effect has its origin in fracture mechanics and describes the formation as well as propagation of cracks in brittle and solid materials in dependence of the specimen size. However, the size effect in concrete spalling describes the damage behaviour on a macroscopic scale for different sized specimens in case of fire. Concrete spalling is a very complex and yet not fully understood phenomenon. To reduce the effort of fire tests to analyse the spalling behaviour of concrete mixtures, this study investigates the susceptibility to spalling for six different concrete mixtures and three specimen sizes. The sizes were divided in full scale slabs (1.8 m x 1.2 m x 0.3 m), intermediate scale cuboids (0.6 m x 0.6 m x 0.3 m) and small scale cylinders (Ø0.15 m x 0.3 m). For this purpose, a novel test set-up was built to test six intermediate scale or twelve small scale specimens simultaneously to ensure a similar heating regime for every specimen. All specimens were fire exposed on one side and remained unrestrained. A size effect occurred for four of the six concrete mixtures. Compared to the full scale specimens the spalling was reduced significantly for all smaller specimen sizes. Additionally, spalling did not occur for the small scale specimens. The results show that the specimen size is an essential parameter to investigate the susceptibility to spalling of a concrete mixture. For future investigations the testing conditions must be adjusted for the intermediate scale specimens to recreate the conditions of the slabs. KW - Concrete KW - Spalling KW - Size effect KW - Fire test PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-559231 DO - https://doi.org/10.1617/s11527-022-02051-2 VL - 55 IS - 8 SP - 1 EP - 14 PB - Springer AN - OPUS4-55923 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stelzner, Ludwig A1 - Eiz Eddin, Ahmad A1 - Häßler, Dustin A1 - Hothan, Sascha T1 - Zum Feuerwiderstand vorgespannter Carbonbetondecken N2 - Der Einsatz von hoch zugbeanspruchbarem und korrosionsbeständigem Carbongelege anstelle herkömmlichen Spannstahls ermöglicht es Beton vorzuspannen und gleichzeitig die Betondeckung auf ein für den Verbund nötiges Minimum zu reduzieren. Der Wechsel von massiven zu filigranen Bauteilen führt in der Regel aufgrund der geringeren thermischen Masse zu einer Abnahme des Feuerwiderstandes. Der Beitrag stellt Versuchsergebnisse zum Abplatz- und Hochtemperaturverhalten von Carbonbeton vor, die im Rahmen des Verbundvorhabens „Vorgespannte Carbonbetondecken mit reduzierten Querschnitten“ (CaPreFloor) erzielt wurden. Für die Untersuchung der Tragfähigkeit bei hohen Temperaturen wurden 4-Punktbiegeversuche mit instationärer Temperaturbeanspruchung an vorgespannten Carbonbetonplatten bei Variation des Carbongeleges und des Vorspanngrades durchgeführt. Ferner erfolgte die Analyse der Abplatzneigung an bewehrten und unbewehrten Bauteilen mittels Brandversuchen unter Einheits-Temperaturzeitkurve. T2 - 16. Carbonbetontage 2024 CY - Dresden, Germany DA - 24.09.2024 KW - Carbonbeton KW - Feuerwiderstand KW - Abplatzverhalten PY - 2024 SP - 56 EP - 57 AN - OPUS4-62430 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Xie, Yongliang A1 - Lv, Na A1 - Huang, Yan A1 - Wu, Dejian A1 - Gong, Liang A1 - Yang, Xufeng A1 - Zeng, Yikai T1 - Comparative analysis on temperature characteristics of hydrogen-powered and traditional fossil-fueled vehicle fires in the tunnel under longitudinal ventilations N2 - Vehicle fires in the tunnel are a great threat to the safe operation of the tunnel. Due to the rapid development of the hydrogen economy, the fire due to the hydrogen leakage could not be avoided and may bring great damage to the passengers and infrastructure. Due to the large difference between pool fires of traditional fossil-fueled and jet fires of hydrogen-powered vehicles, it is in doubt whether the existing longitudinal ventilation design could still be effective for the safety issue of hydrogen powered vehicles. To solve this problem, it is necessary to compare temperature characteristics of hydrogen-powered and traditional vehicle fires with and without longitudinal ventilations. In present work, we conducted a numerical investigation to discuss the different temperature distributions of traditional and hydrogen-fueled vehicle fires. Results indicate that the high temperature zone of the pool fire only exists above the ceiling of the vehicle. For hydrogen-powered vehicle fire, the high-speed hydrogen jet with the strong inertial force could push the hot smoke flows back to the ground. The ceiling temperature of hydrogen-powered vehicle fire is larger since hydrogen-powered vehicle has a larger heat release rate and the fire hazard of jet fires bring more danger compared with the pool fire. Although the temperature stratification is also obvious for the hydrogen-powered vehicle fire, the air temperature in the lower region could be heated and still high enough to bring a great damage to the passengers’ lives. This is quite different with the traditional pool fire. In addition, the critical ventilation velocity is also discussed. The theoretical equation could well predict the critical ventilation velocity of traditional vehicle fires. For hydrogen-powered vehicle fires, the critical ventilation velocity could reach up to 6 m/s. The theoretical equation could not well predict the critical ventilation velocity of hydrogen-powered vehicle fires due to exist of hydrogen jet fires. KW - Hydrogen fire KW - Tunnel KW - Longitudinal ventilation KW - Comparative study PY - 2022 DO - https://doi.org/10.1016/j.ijhydene.2022.05.203 SN - 0360-3199 VL - 47 IS - 57 SP - 24107 EP - 24118 PB - Elsevier CY - Oxford AN - OPUS4-62839 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pittrich, Tim A1 - Stelzner, Ludwig A1 - Weise, Frank T1 - Fire-induced spalling of normal strength concrete with different types of blended Portland cement N2 - The cement industry is looking to reduce its overall CO2 footprint. Greener manufacturing can be achieved by the introduction of more clinker-reduced cements. Concrete exposed to fire tends to show explosive spalling caused by thermomechanical and thermohydraulic processes. It is therefore essential to determine how concretes with clinker-reduced cements behave under fire exposure, especially for concretes containing calcined clays, as these are expected to be the supplementary cementitious material of the future. In this paper, normal strength concretes with four different cements (CEM I, CEM II/A-LL, CEM III/A and CEM II/B-Q) were examined for their fire-induced spalling behaviour. In addition, a mix with PP fibres was investigated for each concrete. The experiments were conducted on ring-restrained cylindrical specimens exposed to the hydrocarbon fire curve. The results showed that the cement type influences spalling behaviour. Samples with CEM I spalled the least, followed by CEM II/A-LL and CEM III/A. Finally, samples with CEM II/B-Q showed the most severe damage. It was found that the spalling behaviour of different concretes correlates with the moisture content before exposure to fire, meaning that higher moisture content leads to higher spalling susceptibility. The use of 2 kg/m³ PP fibres completely inhibited spalling regardless of the cement type used and therefore remains a successful avoidance strategy. T2 - Structures in Fire 2024 CY - Coimbra, Portugal DA - 19.06.2024 KW - Fire-induced concrete spalling KW - Concrete KW - Blended Portland cement KW - SCM KW - PP-fibres PY - 2024 SN - 978-989-35292-2-5 DO - https://doi.org/10.30779/cmm_SIF24 VL - 1st Edition SP - 461 EP - 471 AN - OPUS4-60809 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dombrowski, M. A1 - Hückler, A. A1 - Stelzner, Ludwig A1 - Häßler, Dustin A1 - Heidemann, L. A1 - Reinhold, S. A1 - Zeitler, B. A1 - Früke, J. A1 - Lenz, T. A1 - Theuerkauf, H. A1 - Söll, S. A1 - Reyher, B. A1 - Schlaich, M. T1 - Innovative lightweight floors made of prestressed CFRP-reinforced concrete – from research to construction practice N2 - The presented joint research project “CaPreFloor”, which started in 2023, aims to employ prestressed textile-reinforced concrete using carbonfibre-reinforced polymer (CFRP) to design lightweight floor elements. This allows the reduction of common steel-reinforced concrete floors of 30 cm thickness to a maximum of 6 cm for office, residential, and hotel buildings. Lower material consumption significantly contributes to the conservation of resources and minimises the carbon footprint. In addition, the prefabrication of these floor elements results in high and consistent quality, short construction times and enhanced reusability of the components. A team of experts from various research and practice fields works on this project to achieve the set goal. Currently, open questions include the anchorage and load transfer of the prestressed CFRP reinforcement, structural failure indication, the behaviour of CFRP reinforcement and high-performance concrete at elevated temperatures, as well as fire resistance and sound insulation. As a result, an extensive test programme on different size scales will be conducted. Practical aspects, such as design, field of application and life cycle, as well as the development of an automated production plant, are also considered. The paper will present considerations related to the geometry and design, material selection, manufacturing, ecological footprint, and intended experimental test programme. Four different geometries and two different CFRP reinforcements are being examined. As a result, the developed floor must fulfil all practical requirements in building construction. T2 - XI International Symposium on Fiber Reinforced Concrete (Befib 2024) CY - Dresden, Germany DA - 15.09.2024 KW - Lightweight floor system KW - Prestressed CFRP concrete KW - Fire resistance KW - Sound insulation PY - 2024 SP - 246 EP - 256 AN - OPUS4-62431 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neugum, Tim T1 - Feuerwiderstand gezwängter Stahlbetonstützen N2 - Bei realen Brandereignissen stellen sich in der Regel mechanische und thermische Randbedingungen ein, die deutlich von denen in präskriptiven, bauteilorientierten Brandprüfungen abweichen. Beispielsweise werden Interaktionen der brandbeanspruchten Bauteile mit dem umgebenden Tragwerk und daraus resultierende Zwangsbeanspruchungen bei konventionellen Brandprüfungen nicht berücksichtigt. Mit Hilfe der Substrukturtechnik kann das Verhalten einer Stütze im Brandfall unter Berücksichtigung der Interaktion mit dem umgebenden Tragwerk untersucht werden. T2 - 11. Jahrestagung des DAfStb mit 63. Forschungskolloquium der BAM CY - Berlin, Germany DA - 16.10.2024 KW - Substrukturtechnik KW - Stahlbeton KW - Stützen KW - Zwang KW - Brandschutz PY - 2024 AN - OPUS4-61402 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neugum, Tim A1 - Stelzner, Ludwig A1 - Häßler, Dustin A1 - Hothan, Sascha A1 - Zehfuß, J. T1 - Feuerwiderstand gezwängter Stahlbetonstützen N2 - Bei realen Brandereignissen stellen sich in der Regel mechanische und thermische Randbedingungen ein, die deutlich von denen in präskriptiven, bauteilorientierten Brandprüfungen abweichen. Beispielsweise werden Interaktionen der brandbeanspruchten Bauteile mit dem umgebenden Tragwerk und daraus resultierende Zwangsbeanspruchungen bei konventionellen Brandprüfungen nicht berücksichtigt. Mit Hilfe der Substrukturtechnik kann das Verhalten einer Stütze im Brandfall unter Berücksichtigung der Interaktion mit dem umgebenden Tragwerk untersucht werden. T2 - 11. Jahrestagung des DAfStb mit 63. Forschungskolloquium der BAM CY - Berlin, Germany DA - 16.10.2024 KW - Substrukturtechnik KW - Stahlbeton KW - Stützen KW - Zwang KW - Brandschutz PY - 2024 SN - 978-3-9818564-7-7 SP - 270 EP - 277 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-61401 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neugum, Tim A1 - Stelzner, Ludwig A1 - Häßler, Dustin A1 - Hothan, Sascha A1 - Zehfuß, J. T1 - Anwendung der Substrukturtechnik zur Untersuchung des Feuerwiderstands von Stützen unter Zwang N2 - Bei realen Brandereignissen stellen sich in der Regel mechanische und thermische Randbedingungen ein, die deutlich von denen in präskriptiven, bauteilorientierten Brandprüfungen abweichen. Beispielsweise werden Interaktionen der brandbeanspruchten Bauteile mit dem umgebenden Tragwerk und daraus resultierende Zwangsbeanspruchungen bei konventionellen Brandprüfungen nicht berücksichtigt. Mit Hilfe der Substrukturtechnik kann das Verhalten einer Stütze im Brandfall unter Berücksichtigung der Interaktion mit dem umgebenden Tragwerk untersucht werden. T2 - Symposium Heißbemessung 2024 CY - Braunschweig, Germany DA - 24.09.2024 KW - Substrukturtechnik KW - Stahlbeton KW - Stützen KW - Zwang KW - Brandschutz PY - 2024 SP - 40 EP - 60 PB - TU Braunschweig CY - Braunschweig AN - OPUS4-61234 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neugum, Tim T1 - Anwendung der Substrukturtechnik zur Untersuchung des Feuerwiderstands von Stützen unter Zwang N2 - Bei realen Brandereignissen stellen sich in der Regel mechanische und thermische Randbedingungen ein, die deutlich von denen in präskriptiven, bauteilorientierten Brandprüfungen abweichen. Beispielsweise werden Interaktionen der brandbeanspruchten Bauteile mit dem umgebenden Tragwerk und daraus resultierende Zwangsbeanspruchungen bei konventionellen Brandprüfungen nicht berücksichtigt. Mit Hilfe der Substrukturtechnik kann das Verhalten einer Stütze im Brandfall unter Berücksichtigung der Interaktion mit dem umgebenden Tragwerk untersucht werden. T2 - Symposium Heißbemessung 2024 CY - Braunschweig, Germany DA - 24.09.2024 KW - Substrukturtechnik KW - Stahlbeton KW - Stützen KW - Zwang KW - Brandschutz PY - 2024 AN - OPUS4-61232 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pittrich, Tim T1 - Fire-induced spalling of normal strength concrete with different types of blended Portland cement N2 - The cement industry is looking to reduce its overall CO2 footprint. Greener manufacturing can be achieved by the introduction of more clinker-reduced cements. Concrete exposed to fire tends to show explosive spalling caused by thermomechanical and thermohydraulic processes. It is therefore essential to determine how concretes with clinker-reduced cements behave under fire exposure, especially for concretes containing calcined clays, as these are expected to be the supplementary cementitious material of the future. In this paper, normal strength concretes with four different cements (CEM I, CEM II/A-LL, CEM III/A and CEM II/B-Q) were examined for their fire-induced spalling behaviour. In addition, a mix with PP fibres was investigated for each concrete. The experiments were conducted on ring-restrained cylindrical specimens exposed to the hydrocarbon fire curve. The results showed that the cement type influences spalling behaviour. Samples with CEM I spalled the least, followed by CEM II/A-LL and CEM III/A. Finally, samples with CEM II/B-Q showed the most severe damage. It was found that the spalling behaviour of different concretes correlates with the moisture content before exposure to fire, meaning that higher moisture content leads to higher spalling susceptibility. The use of 2 kg/m³ PP fibres completely inhibited spalling regardless of the cement type used and therefore remains a successful avoidance strategy. T2 - Structures in Fire 2024 CY - Coimbra, Portugal DA - 19.06.2024 KW - Fire-induced concrete spalling KW - Normal strength concrete KW - Blended Portland cement KW - SCM KW - PP-fibres PY - 2024 AN - OPUS4-60521 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kremberg, Jan A1 - Häßler, Dustin A1 - Stelzner, Ludwig A1 - Hothan, Sascha T1 - Brandversuche an mechanisch belasteten Carbonzuggliedern T1 - Fire testing of loaded carbon tension members N2 - Die Anwendung von Zuggliedern aus Carbon ist durch die außergewöhnlich gute Ermüdungs- sowie hohe Zugfestigkeit des Werkstoffs motiviert. Ferner ergibt sich gegenüber Stahl eine deutliche Reduzierung des Querschnitts. Perspektivisch sollen damit u. a. Stahlzugglieder im Netzwerkbogenbrückenbau ersetzt werden. Das Tragverhalten von Carbonzuggliedern im Brandfall ist jedoch bislang unbekannt. Daher wurden mittels Bauteilbrandversuchen die Versagensmechanismen untersucht sowie anhand gewonnener Versuchsdaten eine exemplarische Einschätzung zur Gleichwertigkeit gegenüber konventionellen Stahlzuggliedern vorgenommen. Der Beitrag beschreibt realmaßstäbliche Brandversuche an mechanisch belasteten Carbonzuggliedern, die im Rahmen des Verbundforschungsvorhabens NeZuCa durchgeführt wurden. Das Versuchsprogramm umfasste vier Carbonzugglieder mit kreisrunden Querschnitten in zwei verschiedenen Durchmessern, 36 mm und 51 mm. In Ermangelung eines präskriptiven Brandszenarios für den im Projekt vorgesehenen Anwendungsfall und aus Gründen der Vergleichbarkeit erfolgte die Brandbeanspruchung nach Einheitstemperaturzeitkurve (ETK). Neben den Längsverformungen der Zugglieder wurden auch die Bauteil und Brandraumtemperaturen aufgezeichnet. KW - Netzwerkbogenbrücke KW - Carbonzugglied KW - Feuerwiderstand KW - Brandversuche PY - 2023 DO - https://doi.org/10.1002/stab.202200081 SN - 1437-1049 SN - 0038-9145 VL - 92 IS - 7 SP - 427 EP - 436 PB - Ernst & Sohn CY - Berlin AN - OPUS4-57926 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Fürst, Richard A1 - Häßler, Dustin A1 - Stelzner, Ludwig A1 - Hothan, Sascha T1 - Development of an in situ test method to assess the fire resistance of steel members with applied intumes-cent coating N2 - Intumescent coatings are commonly used in civil engineering to improve the fire resistance of steel constructions. Exposed to fire, the intumescent coating reacts and forms a thermal protective char around the steel member. Thus, the heating of the steel is delayed, and a higher fire resistance can be achieved. Generally, the scope of application and the durability of intumescent coatings are described in national approvals or European Technical Assessment (ETA) documents. Due to environmental conditions, intumescent coatings are subjected to ageing effects, which can reduce their durability and thermal protection performance. Available in situ methods to investigate the performance of applied intumescent coatings, such as visual inspection, flame exposure testing, adhesive tensile tests or chemical analysis, are not fully conclusive. Therefore, in the civil engineering practice, there is an increasing demand to verify the fire resistance of existing steel structures with applied intumescent coatings necessary in several cases, e.g., the working life is exceeded, the visual appearance of the intumescent coating changed or the information about the applied product is missing. The research presented in the paper shows the progress of the ongoing research project "INSIST" at BAM [1], where a new in situ method is being developed to assess the actual fire resistance of existing steel structures with applied intumescent coating. The investigation is based on a development of the in situ test procedure and a mobile prototype furnace. T2 - 10th Symposium Structural Fire Engineering CY - Braunschweig, Germany DA - 24.09.2024 KW - In situ KW - Intumescent coating KW - Steel structures KW - Test procedure PY - 2024 SP - 1 EP - 15 AN - OPUS4-61275 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stelzner, Ludwig T1 - Zum Feuerwiderstand vorgespannter Carbonbetondecken N2 - Der Einsatz von hoch zugbeanspruchbarem und korrosionsbeständigem Carbongelege anstelle herkömmlichen Spannstahls ermöglicht es Beton vorzuspannen und gleichzeitig die Betondeckung auf ein für den Verbund nötiges Minimum zu reduzieren. Der Wechsel von massiven zu filigranen Bauteilen führt in der Regel aufgrund der geringeren thermischen Masse zu einer Abnahme des Feuerwiderstandes. Der Beitrag stellt Versuchsergebnisse zum Abplatz- und Hochtemperaturverhalten von Carbonbeton vor, die im Rahmen des Verbundvorhabens „Vorgespannte Carbonbetondecken mit reduzierten Querschnitten“ (CaPreFloor) erzielt wurden. Für die Untersuchung der Tragfähigkeit bei hohen Temperaturen wurden 4-Punktbiegeversuche mit instationärer Temperaturbeanspruchung an vorgespannten Carbonbetonplatten bei Variation des Carbongeleges und des Vorspanngrades durchgeführt. Ferner erfolgte die Analyse der Abplatzneigung an bewehrten und unbewehrten Bauteilen mittels Brandversuchen unter Einheits-Temperaturzeitkurve. T2 - Carbonbetontage 2024 CY - Dresden, Germany DA - 24.09.2024 KW - Carbonbeton KW - Feuerwiderstand KW - Abplatzverhalten PY - 2024 AN - OPUS4-62429 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Markwart, J. C. A1 - Battig, Alexander A1 - Urbaniak, T. A1 - Haag, K. A1 - Koschek, K. A1 - Schartel, Bernhard A1 - Wurm, F. R. T1 - Intrinsic flame retardant phosphonate-based vitrimers as a recyclable alternative for commodity polymers in composite materials N2 - Recycling of crosslinked fiber-reinforced polymers is difficult. Moreover, as they are often based on flammable resins, additional additives are needed. So-called “vitrimers” open the possibility of Recycling and reprocessing and repairing with dynamically crosslinked chemistries. To date, vitrimer-based composites still need flame retardant additives, such as organophosphates. An additive-free vitrimer composite has not been reported. Herein, we synthesized an intrinsic flame-retardant vitrimer, relying on vinylogous polyurethanes containing covalently installed phosphonates as flame-retardant units and prepared glassfiber-reinforced composites. We studied recycling and flame retardant properties and compared the data to phosphorus-free vitrimers and conventional epoxy resins (with and without additive flame retardant). Our phosphonate-based vitrimer proved in first tests, a flame retardant effect comparable to commercial flame retardant resins. The bending strength and bending modulus for the phosphorus-vitrimer glass fiber composites were comparable to glass fiber composites with permanently cross-linked epoxies. In summary, we were able to prove that the covalent installation of phosphonates into vitrimers allows the preparation of recyclable and intrinsic flame retardant composites that do not need flame retardant additives. We believe this concept can be expanded to other polymer networks and additives to generate recyclable and sustainable high-performance materials. KW - Vitrimer KW - Flame retardant KW - Recyclable KW - Organophosphonate KW - Polyurethane PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-510889 DO - https://doi.org/10.1039/d0py00275e VL - 11 IS - 30 SP - 4933 EP - 4941 AN - OPUS4-51088 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wachtendorf, Volker T1 - Untersuchung der Witterungsbeständigkeit komplexer Funktionalitäten von Polymerwerkstoffen durch künstliche Bewitterung: Flammschutz N2 - In den letzten Jahrzehnten wurde die Degradation der polymeren Matrix von flammgeschützten Polymeren eingehend untersucht. Erst in den letzten Jahren jedoch hat sich die Frage der Lebensdauer der Funktionalität des Flammschutzes selbst als wichtige Fragestellung herauskristallisiert, z.B. bei Kabeln. Deshalb sollte diese Fragestellung durch systematisch-variierte künstliche Klima- und Bewitterungstests an flammgeschützten Polymerwerkstoffen untersucht werden T2 - 50. Jahrestagung der Gesellschaft für Umweltsimulation (GUS) CY - Online meeting DA - 23.03.2022 KW - Flammschutz KW - Witterungsbeständigkeit KW - Langzeitbeständigkeit KW - UV KW - E&E PY - 2022 AN - OPUS4-54541 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Battig, Alexander A1 - Abdou-Rahaman Fadul, Naïssa A1 - Frasca, Daniele A1 - Schulze, Dietmar A1 - Schartel, Bernhard T1 - Multifunctional graphene nanofiller in flame retarded polybutadiene/chloroprene/carbon black composites N2 - To curtail flammability risks and improve material properties, flame retardants (FRs) and fillers are mixed into rubbers. High loadings of aluminum trihydroxide (ATH) and carbon black (CB) are the most used FRs and reinforcing additive, respectively, in rubbers. To reduce loading without losing mechanical properties, partial substitution of ATH as well as CB by low amounts of multilayer graphene (MLG) nanoparticles is investigated. The high aspect ratio MLG is made of ten graphene sheets. In polybutadiene/chloroprene (BR/CR) nanocomposites 3 phr MLG replaced 15 phr CB and/or 3 phr ATH. Material and mechanical properties as well as fire behavior of the nanocomposites are compared to BR/CR with 20 phr CB both with and without 50 phr ATH. MLG appears as a promising nanofiller to improve the functional properties: replacement of CB improved rheological, curing, and mechanical properties; substitution of ATH improved nanocomposite properties without affecting flame retardancy. KW - Nanocomposites KW - Rubber KW - Multilayer graphene KW - Carbon black KW - Polybutadiene/chloroprene KW - Graphene PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-523468 DO - https://doi.org/10.1515/epoly-2021-0026 SN - 1618-7229 VL - 21 IS - 1 SP - 244 EP - 262 PB - De Gruyter AN - OPUS4-52346 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Bio, Waste, Non-vegan – Fun, Food for Thought, or Future N2 - Overview of the state of the art and current trends with the main topics: - renewable sources in flame retardant polymers (flame retarded bio-polymers and biocomposites; bio-flame retardants, renewable adjuvants from industrial waste) - flame retardancy meets sustainability - concepts between analogy and out-of-the-box. T2 - 18th SKZ International Conference on Trends in Fire Safety and InnovativeRFlame retardants for Plastics CY - Würzburg/Rottendorf, Germany DA - 27.09.2022 KW - Bio-polymer KW - Bio-composite KW - Renewable source KW - Renewable adjuvants KW - Vitrimer KW - Bio-flame retardant PY - 2022 AN - OPUS4-55840 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Weathering resistance of halogen-free flame retardancy in thermoplastics N2 - Weathering resistance of halogen-free flame retardancy in thermoplastics - Durability of fire retardancy - Impact of different exposure condition - Degradation with respect to different fire tests T2 - 17th SKZ Conference on Trends in Fire Safety and Innovative Flame Retardants for Plastics CY - Online Meeting DA - 18.05.2021 KW - Durability KW - Flame retardant KW - Aluminum hydroxide (ATH) KW - Weathering KW - Cable KW - TPU KW - EVA KW - Polyamide 6.6 KW - Aluminium diethylphosphinate PY - 2021 AN - OPUS4-52680 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Sustainability Finding its Way into Flame Retardancy: Food for Thought between Fake Fiction and Future N2 - Main message: Sustainability, or in other words, exploiting environmental conservation for the economic welfare and prosperity for all, would revolutionise the plastics industry were it to become predominant practice as a linear, fossil-fuel–based economy is switched to a carbon circular economy. Food for though is given by dint of a critical overview of the current trends in sustainable flame-retardant polymeric materials. Introduction: Transforming the plastics industry into a carbon circular economy over the next 30 years requires an immediate revolution entailing the development of cutting-edge materials and the planning of future industrial production plants. Hence, the innovative field of flame-retardant polymeric materials should lend its strength to drive this challenge. Visionary solutions are proposed to inspire us, while the implementation of economically feasible concepts can take us forward into the future. Experimental The synthesis, processing, polymer analysis, thermal analysis, and investigation of fire behaviour from our own research are performed according to the state of the art, mostly in accordance with the pertinent ISO standards. Indeed, some of our equipment is part of the accredited lab; for the other methods we fulfil equivalent quality standards in terms of maintenance, calibration, participation in round robins, etc. Work steps such as the synthesis or preparation of new materials are usually outsourced or done with partners that have the relevant core competence. The talk also presents examples from other groups whose experimental is described in the corresponding scientific papers. Results and Discussion An overview of current trends towards producing sustainable, flame-retardant polymeric materials is presented, using examples from the literature and by sketching our own projects performed in recent years. The examples are structured along a common theme leading from the use of old and new natural materials with some intrinsic flame retardancy, via flame-retardant biopolymers and biocomposites, to using renewable sources for flame retardants with the objective of exploiting natural sources available as industrial waste streams. Natural flame retardants and adjuvants are highlighted, although the status of most may be assessed as merely motivating our vision. Nevertheless, there are natural material streams finding their way into polymer mass production as fillers, adjuvants, polymers, or renewable educt sources. Natural substances originating from industrial waste streams open the door to sustainable solutions, because they are often available at low cost and avoid competition for land with farming or virgin forests. Aside from this main topic, remarks will address the recycling of flame-retarded polymeric materials; vitrimers are mentioned as a potential material for recyclable thermosets. At the end of the day, only convincing property profiles will prevail both for exploiting renewable sources and circular design, including cost effectiveness, sufficient availability, consistent quality, processibility, mechanical properties, and flame retardancy. However, sustainability must not be merely tolerated as an additional demand, but should instead be recognized as a solution, because sustainability aspires to ensure our economic welfare now and in the future. Acknowledgement: The examples shown from own project were supported by funding grants: BMBF WTZ: 01DN16040, DFG Scha 730/19-1, VW-Stiftung: Experiment No: 97437, DFG Scha 730/20-1, BMBF KMU Innovativ 031B1289B. T2 - 19th European Meeting on Fire Retardant Polymeric Materials (FRPM23) CY - Dübendorf, Switzerland DA - 26.06.2023 KW - Renewable KW - Biocomposite KW - Sustainable KW - Circular economy KW - Natural PY - 2023 AN - OPUS4-57815 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pimienta, Pierre A1 - McNamee, Robert A1 - Robert, Fabienne A1 - Boström, Lars A1 - Huang, Shan-Shan A1 - Mróz, Katarzyna A1 - Davie, Colin A1 - Mohaine, Siyimane A1 - Alonso, Maria Cruz A1 - Bodnarova, Lenka A1 - Bosnjak, Josipa A1 - Dal Pont, Stefano A1 - Dao, Vinh A1 - Dauti, Dorjan A1 - Dehn, Frank A1 - Felicetti, Roberto A1 - Hager, Izabela A1 - Hela, Rudolf A1 - Hozjan, Tomaz A1 - Juknat, Michael A1 - Jumppanen, Ulla-Maija A1 - Kirnbauer, Johannes A1 - Kolsek, Jerneja A1 - Korzen, Manfred A1 - Lakhani, Hitesh A1 - Lion, Maxime A1 - Lo Monte, Francesco A1 - Maluk, Cristian A1 - Meftah, Fekri A1 - Miah, Md Jihad A1 - Millard, Alain A1 - Mindeguia, Jean-Christophe A1 - Moreau, Bérénice A1 - Msaad, Yahia A1 - Ozawa, Mitsuo A1 - Pesavento, Francesco A1 - Pham, Duc Toan A1 - Pistol, Klaus A1 - Rickard, Ieuan A1 - Rodrigues, Joao Paulo Correia A1 - Roosefid, Mohsen A1 - Schneider, Martin A1 - Sharma, Umesh Kumar A1 - Sideris, Kosmas A1 - Stelzner, Ludwig A1 - Weber, Benedikt A1 - Weise, Frank T1 - Recommendation of RILEM TC 256-SPF on fire spalling assessment during standardised fire resistance tests: complementary guidance and requirements N2 - The recommendation is based on the co-authors’ work organized by the RILEM TC 256-SPF “Spalling of concrete due to fire: testing and modelling”. It aims to provide useful information, guidance and best practices in fire spalling assessment to laboratories that perform large-scale tests based on fire resistance test standards. It provides guidance on the spalling observation techniques during testing, as well as post-test spalling quantification/assessment methods. This document is intended to be used in conjunction with the fire resistance test standards, e.g. EN 1363-1 and ISO 834-1. KW - Concrete KW - Fire spalling KW - Large scale tests KW - Standardised fire resistance tests PY - 2024 DO - https://doi.org/10.1617/s11527-023-02248-z SN - 1871-6873 VL - 57 IS - 1 SP - 1 EP - 12 PB - Springer CY - Dordrecht AN - OPUS4-59288 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pimienta, Pierre A1 - McNamee, Robert A1 - Hager, Izabela A1 - Mróz, Katarzyna A1 - Boström, Lars A1 - Mohaine, Siyimane A1 - Huang, Shan-Shan A1 - Mindeguia, Jean-Christophe A1 - Robert, Fabienne A1 - Davie, Colin A1 - Felicetti, Roberto A1 - Miah, Md Jihad A1 - Lion, Maxime A1 - Lo Monte, Francesco A1 - Ozawa, Mitsuo A1 - Rickard, Ieuan A1 - Sideris, Kosmas A1 - Alonso, Maria Cruz A1 - Millard, Alain A1 - Jumppanen, Ulla-Maija A1 - Bodnarova, Lenka A1 - Bosnjak, Josipa A1 - Dal Pont, Stefano A1 - Dao, Vinh A1 - Dauti, Dorjan A1 - Dehn, Frank A1 - Hela, Rudolf A1 - Hozjan, Tomaz A1 - Juknat, Michael A1 - Kirnbauer, Johannes A1 - Kolsek, Jerneja A1 - Korzen, Manfred A1 - Lakhani, Hitesh A1 - Maluk, Cristian A1 - Meftah, Fekri A1 - Moreau, Bérénice A1 - Pesavento, Francesco A1 - Pham, Duc Toan A1 - Pistol, Klaus A1 - Correia Rodrigues, Joao Paulo A1 - Roosefid, Mohsen A1 - Schneider, Martin A1 - Sharma, Umesh Kumar A1 - Stelzner, Ludwig A1 - Weber, Benedikt A1 - Weise, Frank T1 - Recommendation of RILEM TC 256-SPF on the method of testing concrete spalling due to fire: material screening test N2 - The recommendation is based on the coauthors’ work organized by the RILEM TC 256-SPF ‘‘Spalling of concrete due to fire: testing and modelling’’. The Committee has defined two types of screening tests for characterization of concrete propensity to fire spalling: Material screening tests and Product screening tests. Definitions of both types of tests are given in the paper. The following recommendations apply to Material screening tests. The material screening tests described in these recommendations are a set of minimum requirements to test concrete spalling propensity (for example, the minimal specimen size). This document covers the aspects of concrete characterization, specimen geometries, storage conditions, test methods and measured parameters. KW - Concrete KW - Fire Spalling KW - Screening tests KW - High temperature PY - 2023 DO - https://doi.org/10.1617/s11527-023-02202-z VL - 56 IS - 9 SP - 1 EP - 12 PB - Springer Science and Business Media LLC AN - OPUS4-60635 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klimek, Andre A1 - Hothan, Sascha A1 - Rogge, Andreas T1 - Das Abplatzverhalten von Beton im Zusammenhang mit dem Maßstabseffekt N2 - Beton, als aktuell am meisten verwendeter Baustoff ist nicht brennbar und weist zudem eine sehr geringe Temperaturleitfähigkeit auf. Er eignet sich somit gut für den baulichen Brandschutz. Jedoch neigt Beton im Brandfall zu explosionsartigen Abplatzungen, die zu einer Reduzierung des tragfähigen Querschnitts und sogar zum Versagen des Bauteils führen können. Derzeit werden thermomechanische und thermohydraulische Schädigungsprozesse als die zwei maßgeblichen Ursachen für explosionsartige Abplatzungen angesehen. Diese Schädigungsprozesse sind unter anderem abhängig von der Prüfkörpergröße, dem Wasser-Zement-Wert, der Porosität, der Permeabilität und dem Bewehrungsgrad des Bauteils. Im Rahmen des Vortrags werden die Forschungsarbeiten zum Maßstabseffekt des Abplatzverhaltens von Betonen bei Brandbeanspruchung präsentiert. Zu diesem Zweck wurden Betonprüfkörper aus sechs verschiedenen Betonmischungen in jeweils drei Prüfkörpergrößen einseitig, ohne Behinderung der thermischen Ausdehnung und ohne externe Last im Tunnelbrandprüfstand der BAM untersucht. Dieser unikale Prüfstand ermöglicht die Brandprüfung unterschiedlicher Prüfkörpergrößen unter vergleichbaren Brandbedingungen sowie die simultane Prüfung mehrerer kleinformatiger Betonprüfkörper. Das präsentierte, laufende Promotionsvorhaben basiert auf einem von der DFG geförderten Forschungsvorhaben und darauf aufbauenden Folgeuntersuchungen. Die Ergebnisse des DFG-Vorhabens zeigen einen deutlichen Maßstabseffekt mit einer starken Verringerung der Abplatztiefen bei einer Reduzierung der Prüfkörpergröße. Des Weiteren ist das Abplatzverhalten stark von der Betonmischung abhängig. Vor dem Hintergrund der Ressourcenschonung und Kostenreduzierung verfolgen die auf dem DFG-Vorhaben aufbauenden Untersuchungen das Ziel, das Abplatzverhalten großformatiger Betonprüfkörper durch kleinformatige Betonprüfkörper mit angepassten Randbedingungen nachzustellen. Hierfür wurden zwei Betonmischungen des DFG-Vorhabens verwendet. Die Ergebnisse zeigen, dass durch eine Anpassung der Versuchsrandbedingungen dem Maßstabseffekt entgegengewirkt werden kann. T2 - 7. Symposium 'Heißbemessung - Structural Fire Engineering' CY - Online meeting DA - 14.09.2021 KW - Maßstabseffekt KW - Beton KW - Abplatzen KW - Brand PY - 2021 SP - 1 EP - 12 PB - Technische Universität Braunschweig AN - OPUS4-53528 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stelzner, Ludwig T1 - Feuerwiderstand vorgespannter Carbonbetondecken – Abplatz- und Hochtemperaturverhalten N2 - Der Einsatz von hoch zugbeanspruchbarem und korrosionsbeständigem Carbongelege anstelle herkömmlichen Spannstahls ermöglicht es Beton vorzuspannen und gleichzeitig die Betondeckung auf ein für den Verbund nötiges Minimum zu reduzieren. Der Wechsel von massiven zu filigranen Bauteilen führt in der Regel aufgrund der geringeren thermischen Masse zu einer Abnahme des Feuerwiderstandes. Der Beitrag stellt Versuchsergebnisse zum Abplatzverhalten von Carbonbeton vor, die im Rahmen des Verbundvorhabens „Vorgespannte Carbonbetondecken mit reduzierten Querschnitten“ (CaPreFloor) erzielt wurden. T2 - 11. Jahrestagung des DAfStb mit 63. Forschungskolloquium der BAM Green Intelligent Building CY - Berlin, Germany DA - 16.10.2024 KW - Abplatzverhalten KW - CaPreFloor KW - Carbonbeton KW - Feuerwiderstand PY - 2024 AN - OPUS4-61424 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eiz Eddin, Ahmad T1 - Zum Feuerwiderstand von filigranen Deckenelementen aus vorgespanntem Carbonbeton N2 - Der Einsatz von hoch zugbeanspruchbarem und korrosionsbeständigem Carbongelege anstelle von herkömmlichem Spannstahl ermöglicht es Beton vorzuspannen und gleichzeitig die Betondeckung auf ein für den Verbund nötiges Minimum zu reduzieren. Das Carbongelege besteht aus Carbonfasern in einer Kunststoffmatrix. Mit dieser Bauweise können dünnwandige und damit ressourcenschonende Deckenelemente realisiert werden. Der Wechsel von massiven zu filigranen und vergleichsweise leichten Bauteilen führt jedoch aufgrund der geringeren Masse und der damit einhergehenden schnelleren Erwärmung zu einer Abnahme des Feuerwiderstands. Ferner führt die Erweichung der Matrix im Brandfall zu einer Abnahme der Verbundfestigkeit zwischen Carbongelege und Beton. Die Brennbarkeit des Carbongeleges sowie die Abplatzneigung des verwendeten Feinbetons stellen weitere Herausforderungen für den baulichen Brandschutz dar. Der Beitrag stellt Versuchsergebnisse zum Abplatz- und Hochtemperaturverhalten von Carbonbeton vor, die im Rahmen des Verbundvorhabens „Vorgespannte Carbonbetondecken mit reduzierten Querschnitten“ (CaPreFloor) erzielt wurden. Für die Untersuchung der Tragfähigkeit bei hohen Temperaturen wurden 4-Punkt-Biegeversuche an balkenförmigen Prüfkörpern (150 x 30 x 6 cm³) mit einlagiger Carbonbewehrung und instationärer Temperaturbeanspruchung durchgeführt. Neben dem Vorspanngrad des Carbongeleges wurde auch der Gelegetyp variiert. Im Bereich der konstanten Biegezugzone erfolgt die einseitige Erwärmung mittels elektrisch betriebener Heizmatten. Während der kontinuierlichen Erwärmung werden die Prüfkörper mit einer konstanten Kraft belastet, deren Betrag aus zuvor durchgeführten Biegeversuchen bei Raumtemperatur abgeleitet wurde. Die Abplatzversuche werden mit Einheits-Temperaturzeitkurve an rechteckigen (60 x 60 x 6 cm³) und kreisrunden (Ø 47 x 6 cm³), plattenförmigen Prüfkörpern am 1m³-Ofen der BAM durchgeführt. Die kreisrunden Prüfkörper sind zusätzlich mit einem Stahlring zur Behinderung der thermischen Dehnung des Betons versehen. Um den Einfluss des Geleges auf das Abplatzverhalten zu analysieren, werden sowohl Prüfkörper mit Carbongelege als auch unbewehrte Prüfkörper untersucht. Die daraus resultierenden Erkenntnisse fließen in die weitere Entwicklung der vorgespannten Carbonbetondeckenelemente ein. Anhand von realmaßstäblichen Brandversuchen wird der Feuerwiderstand dieser Bauteile im weiteren Projektverlauf bestimmt. T2 - Symposium Heißbemessung 2024 CY - Braunschweig, Germany DA - 24.09.2024 KW - Carbonbeton KW - Feuerwiderstand KW - Brandversuch KW - Carbon KW - Material PY - 2024 AN - OPUS4-61125 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kremberg, Jan T1 - Fire tests of carbon tension members for lightweight constructions N2 - Vorstellung der Brandversuche im Rahmen des Projektes NeZuCa an Carbonzuggliedern für den Brückenbau. T2 - ClimateChange@FireScience CY - Berlin, Germany DA - 10.11.2022 KW - Fire tests KW - Carbon KW - Lightweight constructions KW - Fire Science PY - 2022 AN - OPUS4-56302 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - BOOK A1 - Schoch, R. A1 - Schartel, Bernhard A1 - Wachtendorf, Volker A1 - Tan, Yi A1 - Lin, Xuebao A1 - Tröppner, O. A1 - Lang, M. A1 - Hochrein, T. A1 - Bastian, M. T1 - Langzeit- und Witterungsstabilität von halogenfreiem Flammschutz in Polymeren N2 - Die Forderung, dass der Flammschutz von Kunststoffen nicht nur zum bei der Herstellung der jeweiligen Produkte, sondern auch über die gesamte Einsatzdauer im geforderten Maß wirksam ist, stellt eine große Aufgabe dar. Ferner ist die Anforderung für viele Produkte in der Praxis neu, da bisher vor allem der Einfluss der Flammschutzmittel auf die Stabilität der Polymerwerkstoffe, nicht aber die Stabilität des Flammschutzes untersucht wurde. Das Langzeitverhalten halogenfreier Systeme ist bis heute wenig untersucht, insbesondere weil Phosphor- und Stickstoff-basierte Systeme die oxidative Beständigkeit von Polymeren weniger zu beeinflussen scheinen als halogenhaltige FSM. Die Frage, wie zuverlässig der Flammschutz wirkt, wenn Kunststoffe einige Jahre im Innen- und Außenbereich im Einsatz sind und dabei wechselnden Beanspruchungen ausgesetzt waren, wurde bislang nur vereinzelt untersucht. Mögliche Auswirkungen von Witterungseinflüssen auf flammgeschützte Polymerwerkstoffe sind, dass die Flammschutzmittel selbst abbauen, ausgewaschen werden, oder auch durch Wechselwirkung mit den eingesetzten Additiven oder mit den Alterungsprodukten der Polymermatrix in ihrer Wirkung nachlassen. Hier bestand großer Forschungsbedarf, um an den Punkt zu gelangen, die Beständigkeit der Flammschutzeigenschaften eines Produktes über seine gesamte Lebensdauer zuverlässig garantieren zu können. Diese Fragestellung greift das durchgeführte Forschungsvorhaben auf. Ziel war die Untersuchung der Langzeitstabilität der Flammschutzwirkung von halogenfrei flammgeschützten Polymerwerkstoffen unter diversen Witterungseinflüssen. Dazu wurden die Schädigungsmechanismen der Polymerwerkstoffe und der Flammschutzmittel sowie die auftretenden Wechselwirkungen analysiert, um ein Verständnis für die ablaufenden Prozesse zu entwickeln und Empfehlung für die Reduzierung der Alterung zu erarbeiten. Gegenstand der Untersuchungen waren anwendungsrelevante Flammschutz-Konzepte, die miteinander verglichen wurden. Die Erarbeitung von Struktur-Eigenschafts-Beziehungen ermöglichte die Beschreibung der Empfindlichkeiten und den Vergleich zwischen den Systemen. Darauf basierend wurden für die FSM spezifische Leitlinien für die Optimierung der Langzeitstabilität des Flammschutzes erstellt. N2 - The requirement that the flame retardancy of plastics is still effective to the required degree not only at the time of manufacture of the respective products, but also over the entire period of use, is a major challenge in view of the very long periods of time involved. In addition, the requirement is new for many products in practice, as up to now the influence of flame retardants on the stability of the polymer materials has been investigated, but not the stability of the flame retardant itself. The long-term behaviour of halogen-free systems has been little studied to date, especially because phosphorus- and nitrogen-based systems seem to have a much smaller influence on the oxidative stability of polymers than halogene containing flame retardants. The question of how reliable flame retardancy is when plastic products have been in use for several years indoors and outdoors and have been exposed to a wide range of climatic stresses has only been investigated in isolated cases. Possible effects of weathering on flame-retarded polymer materials are that the flame retardants themselves degrade, migrate or are washed out, or that their effect diminishes through interaction with other additives used or with the ageing products of the polymer matrix. At this point, there was a great need for research in order to reach the point where the stability of the flame retardant properties of a product can be reliably guaranteed over its entire service life. This question is taken up by the research project carried out. The aim of the research project was the systematic investigation of the long-term stability of the flame-retardant effect of halogen-free flame-retardant polymer materials under various weather conditions. For this purpose, the predominant damage mechanisms of the polymers and the flame retardants as well as the interactions occurring were analysed in order to develop an understanding of the processes taking place and to work out recommendations for reducing ageing. Subject of the investigations were different applicationrelevant flame retardant concepts, which were compared with each other. The development of structure-property relationships enabled the description of the specific sensitivities and the comparison between the different systems. Based on this, specific guidelines for the optimisation of the long-term stability of the flame retardants were developed for the different flame retardants. KW - Durability KW - Flame retardant KW - Flammschutz KW - Weathering KW - Ethylene-vinyl acetate KW - Cables KW - Polyamid KW - Langzeitstabilität PY - 2021 SN - 978-3-8440-7781-0 SN - 2364-754X SP - 1 EP - 222 PB - Shaker CY - Düren AN - OPUS4-54274 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Battig, Alexander A1 - Garfias González, Karla I. A1 - Schartel, Bernhard T1 - Valorizing “non-vegan” bio-fillers: Synergists for phosphorus flame retardants in epoxy resins N2 - Sustainable, biogenic flame retardant adjuvants for epoxy resins are receiving increased focus. Zoological products like insects, bone meal, and eggshells are available in large quantities, but remain uninvestigated as functional fillers to epoxy resins, although they are potential synergists to flame retardants. The efficacy and flame retardancy of “non-vegan” additives in combination with flame retardants is investigated and the fire behavior and thermal decomposition of bio-sourced epoxy resin composites is characterized. By comparing the fire performance of composites containing flame retardants or fillers at varying loadings (5, 10, and 20%), their role as synergists that enhance the function of organophosphorus flame retardants in bio-epoxy composites is identified and quantified. Peak heat release rates were 44% lower in composites containing both filler and flame retardant versus those containing only flame retardants, and fire loads were reduced by 44% versus the pure resin, highlighting the ability of “non-vegan” fillers to function as synergists. KW - Flame retardancy KW - Synergy KW - Bio-composite KW - Epoxy resin KW - Biogenic KW - Renewable PY - 2022 DO - https://doi.org/10.1016/j.polymdegradstab.2022.109875 SN - 0141-3910 VL - 198 SP - 109875 PB - Elsevier Ltd. AN - OPUS4-54438 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Strommer, Bettina A1 - Battig, Alexander A1 - Frasca, Daniele A1 - Schulze, Dietmar A1 - Huth, Christian A1 - Böhning, Martin A1 - Schartel, Bernhard T1 - Multifunctional Property Improvements by Combining Graphene and Conventional Fillers in Chlorosulfonated Polyethylene Rubber Composites N2 - The incorporation of nanoparticles like multilayer graphene (MLG) into elastomeric composites boosts their technical performance, such as their mechanical behavior and electrical conductivity. Common filler types (carbon black (CB) and aluminum trihydroxide (ATH)) generally fulfill single, specific purposes and are often used in high loadings. CB typically reinforces rubber mechanically, while ATH increases flame retardancy. Small amounts of MLG reduce these high filler contents and maintain the multifunctional characteristics of rubber composites. In chlorosulfonated polyethylene (CSM) + ATH, an intrinsically flame-retardant rubber was designed to achieve the highest standards such as maximum average of heat emission (MARHE) <90 kW m−2, 3 phrMLG was substituted for 15 phr CB and/or 3 phr ATH via an industrially applicable processing approach. Replacing either CB or ATH resulted in a property profile that was multifunctionally improved in terms of features such as mechanical performance, reduced sorption, and flame retardance. MLG nanocomposites are reported to show promise as an industrially utilizable route to obtain multifunctional high-performance rubbers. KW - Nanocomposites KW - Rubber KW - Multilayer graphene KW - Flame retardancy KW - Synergy KW - Nanoparticles KW - Elastomers PY - 2022 DO - https://doi.org/10.1021/acsapm.1c01469 SN - 2637-6105 VL - 4 IS - 2 SP - 1021 EP - 1034 PB - ACS Publ. CY - Washington, DC AN - OPUS4-54330 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Strommer, Bettina T1 - Natural Rubber Nanocomposites via Optimized Latex Premixing and Conventional Technical Processing N2 - Creation of highly functional materials and replacement of high amounts of conventional fillers are driving forces for the development of nanocomposites. Besides the type and properties of nanoparticles, their dispersing in the elastomeric matrix and the stability of this dispersion through all processing steps are the main factors for the resulting performance of the produced material. Therefore, a preparation chain via latex premixing to a highly filled masterbatch, followed by conventional technical processing is to be developed. Three types of carbon-based particles are characterized as such (SEM, Raman Spectroscopy, BET specific surface area) and in combination with natural rubber, as nanocomposites (TEM. Hardness, Abrasion resistance, Compression set, Cone calorimetry). All of the studied particles lead to an improvement in the investigated mechanical properties, the extent of reinforcement depends strongly on the specific surface of the particle interacting with the elastomeric matrix in combination with their shape. T2 - DKG Elastomer Symposium CY - Online meeting DA - 28.06.2021 KW - Processing KW - Elastomers KW - Nanocomposites KW - Graphene KW - Nanoparticles KW - Latex KW - Natural rubber PY - 2021 AN - OPUS4-53106 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Battig, Alexander T1 - Multifunctional Graphene in Flame Retarded Polybutadiene/ Chloroprene/ Carbon Black Composites N2 - Multilayer graphene is investigated as a multifunctional nanofiller to polybutadiene/ chloroprene rubbers (BR/CR) that partially substitutes carbon black (CB) and aluminum trihydroxide (ATH). Loadings of only 3 parts per hundred rubber (phr) MLG replaced 15 phr of CB and/or 3 phr of ATH in BR/CR nanocomposites. Mechanical and fire behavior were investigated, and results point to improved rheological, curing and mechanical properties of MLG-containing rubber composites. T2 - 18th European Meeting on Fire Retardant Polymeric Materials, FRPM21 CY - Budapest, Hungary DA - 29.08.2021 KW - Graphene KW - Rubber KW - Fire Retardant KW - Nanofiller KW - Nanocomposite KW - ATH PY - 2021 AN - OPUS4-53202 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tan, Yi A1 - Wachtendorf, Volker A1 - Klack, Patrick A1 - Kukofka, Tobias A1 - Ruder, J. A1 - Schartel, Bernhard T1 - Durability of the flame retardance of ethylene-vinyl acetate copolymer cables: Comparing different flame retardants exposed to different weathering conditions N2 - Scientific publications addressing the durability of the flame retardance of cables during their long-term application are rare and our understanding lacks. Three commercial flame retardants, aluminum hydroxide, aluminum diethyl phosphinate (AlPi-Et), and intumescent flame retardant based on ammonium polyphosphate, applied in ethylene-vinyl acetate copolymer (EVA) model cables, are investigated. Different artificial aging scenarios were applied: accelerated weathering (UV-irradiation/temperature/rain phases), humidity exposure (elevated temperature/humidity), and salt spray exposure. The deterioration of cables’ surface and flame retardancy were monitored through imaging, color measurements, attenuated total reflectance Fourier transform infrared spectroscopy, and cone calorimeter investigations. Significant degradation of the materials’ surface occurred. The flame retardant EVA cables are most sensitive to humidity exposure; the cable with AlPi-Et is the most sensitive to the artificial aging scenarios. Nevertheless, substantial flame retardance persisted after being subjected for 2000 h, which indicates that the equivalent influence of natural exposure is limited for several years, but less so for long-term use. KW - Durability KW - Flame retardant KW - Cable KW - Weathering KW - Cone calorimeter PY - 2020 DO - https://doi.org/10.1002/APP.47548 SN - 0021-8995 VL - 137 IS - 1 SP - 47548 PB - Wiley AN - OPUS4-50237 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Schartel, Bernhard ED - Hu, Y. ED - Wang, X. T1 - Influence of the Size and Dispersion State of Two-Dimensional Nanomaterials on the Fire Safety of Polymers N2 - Only the nano-scaled structure of the nanocomposite and the dispersion of nanoparticles within the polymer matrix harbor multifunctional potential including superior fire retardancy. Thus, this chapter focuses on the dispersion of nanoplates, based mainly on studies of layered silicates and graphene/graphene-related nanoplates. The nanostructure and properties of the nanocomposites are dependent mainly on thermodynamic and kinetic factors during preparation. Improving nano-dispersion often directly improves flame retardancy. Therefore, the modification of the nanoplates as well as the preparation of nanocomposites becomes very important to control this dispersion. The dispersion of nanoplates functions as a prerequisite for the formation of an efficient protective layer, changing the melt flow and dripping behavior, or the improvement of the char properties. KW - Nanocomposite KW - Flame retardancy KW - 2D nanoparticle KW - Exfoliation KW - Dispersion KW - Flammability PY - 2023 SN - 978-1-032-35268-8 SN - 978-1-032-35502-3 SN - 978-1-003-32715-8 DO - https://doi.org/10.1201/9781003327158-2 SP - 23 EP - 58 PB - CRC Press CY - Boca Raton AN - OPUS4-58290 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kremberg, Jan A1 - Häßler, Dustin A1 - Stelzner, Ludwig A1 - Hothan, Sascha T1 - Brandversuche an mechanisch belasteten Carbonzuggliedern N2 - Der Beitrag stellt experimentelle Untersuchungen zum Feuerwiderstand von Carbonzuggliedern vor. Die Anwendung von Zuggliedern aus Carbon ist durch die außergewöhnlich gute Ermüdungs- sowie hohe Zugfestigkeit des Werkstoffs motiviert. Ferner ergibt sich gegenüber Stahl eine deutliche Reduzierung des Querschnitts. Perspektivisch sollen damit Stahlzugglieder im Netzwerkbogenbrückenbau ersetzt werden. Durch die Materialsubstitution werden Ressourcen nicht nur beim Zugglied selbst, sondern auch am Gesamttragwerk der Brücke eingespart. Da zum Tragverhalten von Carbonzuggliedern im Brandfall bislang keine Erkenntnisse vorliegen, sollen mit Hilfe von Bauteilbrandversuchen die Versagensmechanismen sowie die grundsätzliche Gleichwertigkeit gegenüber konventionellen Stahlhängern untersucht werden. Der Beitrag beschreibt die Durchführung und die Ergebnisse von Brandversuchen an mechanisch belasteten Carbonzuggliedern. Die realmaßstäblichen Versuche werden am unikalen Zugbauteil-prüfofen der BAM im Mai 2022 durchgeführt. Das Versuchsprogramm umfasst vier Carbonzugglieder mit kreisrunden Querschnitten in zwei verschiedenen Durchmessern, ⌀36 mm und ⌀51 mm. Aus Gründen der Vergleichbarkeit erfolgt die Brandbeanspruchung nach Einheits-Temperaturzeitkurve (ETK). Während des Brandversuches wird die axiale Prüfkraft von 750 kN bzw. 1500 kN bis zum Eintreten des Probenversagens konstant gehalten. Zusätzlich werden die Längsverformung sowie die Bauteil- und Brandraumtemperaturen aufgezeichnet. In einem Vorversuch an einem unbelasteten Bauteilabschnitt eines Carbonzuggliedes konnte das Brand- und Erwärmungsverhalten des Verbundmaterials untersucht werden. Dabei zeigten sich Makrorisse und eine Zersetzung der Kunststoffmatrix sowie eine hohe Temperaturbeständigkeit der Kohlenstofffasern. Durch das Fehlen der schützenden Matrix reagierten die Carbonfasern sensibel auf Querbeanspruchung. Dies führte zu einem Bruch und Ablösen der oberflächennahen Fasern. T2 - 8th Symposium Structural Fire Engineering CY - Brunswick, Germany DA - 13.09.2022 KW - Carbon KW - Zugglied KW - Brandversuch KW - Feuerwiderstand KW - Brandschutz PY - 2022 SP - 1 EP - 13 PB - TU Braunschweig CY - Braunschweig AN - OPUS4-55704 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klimek, André A1 - Stelzner, Ludwig A1 - Hothan, Sascha A1 - Zehfuß, J. T1 - Auswirkung von passivem Zwang auf das Abplatzverhalten von Beton im Brandfall N2 - Der diesjährige Beitrag zeigt den Einfluss ausgewählter Versuchsrandbedingungen auf das Abplatzverhalten von Normalbeton im kleinskaligen Brandversuch. Im Rahmen der Untersuchungen wurde die Abplatzneigung von acht zylindrischen Betonprüfkörpern der Maße Ø47 cm x 29 cm aus Normalbeton analysiert. Vier Prüfkörper wurden aus Normalbeton mit quarzitischer Gesteinskörnung hergestellt, wohingegen die grobe Gesteinskörnung (>2 mm) der anderen vier Prüfkörper durch Basaltsplitt ersetzt wurde. Neben der Art der groben Gesteinskörnung wurden zusätzlich ausgewählte Versuchsrandbedingungen variiert. Dies umfasste zum einen die Vorlagerung der Prüfkörper bei verschiedenen Umgebungsfeuchten und zum anderen die Ummantelung der Prüfkörper mit zwei Ringen aus Stahl bzw. einem durchgehenden Stahlblech. Die Ummantelung der Prüfkörper mit Stahlringen im Brandversuch führt zu einer Behinderung der thermischen Ausdehnung der Prüfkörper und zum Aufbau thermomechanischer Zwangsdruckspannungen. Diese Zwangsdruckspannungen werden maßgeblich von der thermischen Ausdehnung der verwendeten Gesteinskörnung beeinflusst. Zusätzlich wird die Feuchteabgabe über die Mantelfläche behindert. Der Einsatz des Stahlblechs reduziert lediglich die Abgabe der Feuchtigkeit über die Mantelfläche und induziert vernachlässigbare Zwangsdruckspannungen im Beton. Die Brandbeanspruchung der Prüfkörper erfolgte einseitig nach der Einheits-Temperaturzeitkurve (ETK) über einen Zeitraum von 60 Minuten. Mit Hilfe eines Laser Scanners wurden vergleichende 3D-Messungen der brandbeanspruchten Oberfläche vor und nach dem Brandversuch durchgeführt. Aus diesen Messungen konnten das Abplatzvolumen, die Abplatztiefenverteilung und die maximale Abplatztiefe ermittelt werden. Während des Brandversuchs wurde die Temperaturverteilung im Prüfkörper mittels fünf eingebetteter Mantelthermoelemente in verschiedenen Tiefen bestimmt. Die Ergebnisse zeigen, dass die Abplatzungen an der brandbeanspruchten Oberfläche infolge der Prüfkörperummantelung mit Stahlringen bzw. Stahlblech zunehmen. Bei einer Ummantelung mit Stahlringen mit gleichzeitiger Vortrocknung der Betonrandzone platzt der Prüfkörper mit quarzitischer Gesteinskörnung ab, wohingegen der Prüfkörper mit basaltischer Gesteinskörnung keine Abplatzungen aufweist. Dies wird auf die unterschiedliche Ausprägung der thermomechanischen Schädigung infolge der unterschiedlichen thermischen Ausdehnungskoeffizienten von Quarzkies und Basalt zurückgeführt. Die Ergebnisse der Brandprüfserie zeigen, dass die Variation der Prüfrandbedingungen bei Beibehaltung der Prüfkörpergröße einen maßgeblichen Einfluss auf das Abplatzverhalten haben. Die Randbedingungen sind daher bei kleinskaligen Brandversuchen, die zukünftig als „Screening-Tests“ ersatzweise für kostenintensive Bauteilversuche verwendet werden sollen, zu berücksichtigen. T2 - 8th Symposium Structural Fire Engineering CY - Brunswick, Germany DA - 13.09.2022 KW - Brand KW - Beton KW - Abplatzen KW - Zwang PY - 2022 SP - 1 EP - 12 PB - TU-Braunschweig CY - Braunschweig AN - OPUS4-55731 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kremberg, Jan T1 - Brandversuche an mechanisch belasteten Carbonzuggliedern N2 - Präsentation zu den Ergebnissen des Forschungsprojektes NeZuCa. T2 - 8th Symposium Structural Fire Engineering CY - Brunswick, Germany DA - 13.09.2022 KW - Carbon KW - Brandschutz KW - Feuerwiderstand KW - Brandversuch KW - Zugglied PY - 2022 AN - OPUS4-55705 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klimek, André T1 - Auswirkung von passivem Zwang auf das Abplatzverhalten von Beton im Brandfall N2 - Beschreibung des Abplatzverhaltens von vier Prüfkörpertypen in Abhängigkeit der Ummantelungsart und Lagerungsbedingungen für zwei Betonrezepturen T2 - 8th Symposium Structural Fire Engineering CY - Brunswick, Germany DA - 13.09.2022 KW - Brand KW - Beton KW - Abplatzen KW - Zwang PY - 2022 AN - OPUS4-55734 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klimek, André A1 - Stelzner, Ludwig A1 - Hothan, Sascha A1 - Zehfuß, J. T1 - Screening-tests on the susceptibility to spalling of two ordinary concretes N2 - Investigating the spalling behaviour of a concrete mixture using large scale members is complex and expensive. Thus, the susceptibility of concrete to spalling is investigated by means of fire tests on small scale specimens. However, the reduction of the fire exposed surface increases the influence of boundary effects. Macrocracking and the water loss via the lateral surfaces reduce the impact of the thermomechanical and thermohydraulic damage mechanisms and therefore, lower the risk of spalling. Thus, the influence of different restraints on the spalling behaviour of intermediate scaled specimens (Ø=0.47 m; h=0.29 m) was investigated for two ordinary concrete mixtures. Both mixtures had the same composition except the type of aggregate. One mixture contained only quartzitic aggregates, whereas the other mixture was made with basalt grit as coarse aggregates. Applied steel rings restrained the thermal expansion of the specimen and prevented the loss of water, whereas applied steel sheet primarily reduced the loss of water during the fire test. Additionally, the fire exposed surface of one specimen of each mixture was pre-dried under controlled climate conditions and fire tested with applied steel rings. The results show a higher spalling volume for the ring restrained specimens compared to the other covering types. Further, the pre-dried boundary zone leads to delayed and decreased occurrence of spalling compared to the non-dried specimens for the concrete with quartzitic aggregates and to a prevention of spalling for the mixture with basalt aggregates. Additionally, the results show that the influence of the thermomechanical behaviour of the coarse aggregates increases with increasing restraint. The restrained conditions of the specimens with applied steel ring are comparable to the conditions in the centre of a large scale member. This test series is a further step for possible concept of steel ring restraint concrete specimens as “screening-tests” in upcoming projects. T2 - IWCS 2022 CY - Berlin, Germany DA - 12.10.2022 KW - Spalling KW - Fire test KW - Concrete KW - Restraint PY - 2022 SP - 15 EP - 24 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-56020 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klimek, André T1 - Screening-tests on the susceptibility to spalling of two ordinary concretes N2 - Investigating the spalling behaviour of a concrete mixture using large scale members is complex and expensive. Thus, the susceptibility of concrete to spalling is investigated by means of fire tests on small scale specimens. However, the reduction of the fire exposed surface increases the influence of boundary effects. Macrocracking and the water loss via the lateral surfaces reduce the impact of the thermomechanical and thermohydraulic damage mechanisms and therefore, lower the risk of spalling. Thus, the influence of different restraints on the spalling behaviour of intermediate scaled specimens (Ø0.47 m; h=0.29 m) was investigated for two ordinary concrete mixtures. Both mixtures had the same composition except the type of aggregate. One mixture contained only quartzitic aggregates, whereas the other mixture was made with basalt grit as coarse aggregates. Applied steel rings restrained the thermal expansion of the specimen and prevented the loss of water, whereas applied steel sheet primarily reduced the loss of water during the fire test. Additionally, the fire exposed surface of one specimen of each mixture was pre-dried under controlled climate conditions and fire tested with applied steel rings. The results show a higher spalling volume for the ring restrained specimens compared to the other covering types. Further, the pre-dried boundary zone leads to delayed and decreased occurrence of spalling compared to the non-dried specimens for the concrete with quartzitic aggregates and to a prevention of spalling for the mixture with basalt aggregates. Additionally, the results show that the influence of the thermomechanical behaviour of the coarse aggregates increases with increasing restraint. The restrained conditions of the specimens with applied steel ring are comparable to the conditions in the centre of a large scale member. This test series is a further step for possible concept of steel ring restraint concrete specimens as “screening-tests” in upcoming projects. T2 - 7th International Workshop on Concrete Spalling due to Fire Exposure CY - Berlin, Germany DA - 12.10.2022 KW - Spalling KW - Fire test KW - Concrete KW - Restraint PY - 2022 AN - OPUS4-56023 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Fürst, Richard A1 - Häßler, Dustin A1 - Stelzner, Ludwig A1 - Hothan, Sascha T1 - In situ test procedure to determine the fire resistance of exisiting steel structures with aged intumescent coating N2 - Intumescent coatings are commonly used in civil engineering to increase the fire resistance of steel structures. In case of a fire, the intumescent coating reacts and forms a thermally protective char around the steel member. Thus, the heating of the steel is significantly delayed, and as a result, a higher fire resistance can be achieved. Throughout the working life, intumescent coatings are aged by climatic factors. To predict durability for several years, the behaviour of the intumescent coatings is extrapolated based on accelerated artificial ageing. The established German and European assessment procedures to test and predict durability assume a working life of at least 10 years. For an extended period, additional evidence is required; yet the procedure and specifications to justify this are not described. Available in situ methods to assess the thermal performance of intumescent coatings are currently limited in their information content. Therefore, BAM is conducting a research project to develop a minimally invasive in situ test procedure to determine the fire resistance of existing steel structures with applied intumescent coating. The paper will describe the test setup, the developed prototype furnace, and the results of the performed test programme with uncoated and coated steel specimens. Based on this, recommendations for the test procedure are given. T2 - Structures in Fire 2024 CY - Coimbra, Portugal DA - 19.06.2024 KW - In situ KW - Intumescent coating KW - Steel structures KW - Test procedure PY - 2024 SN - 978-989-35292-2-5 DO - https://doi.org/10.30779/cmm_SIF24 SP - 1217 EP - 1228 AN - OPUS4-61258 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Fürst, Richard A1 - Häßler, Dustin A1 - Stelzner, Ludwig A1 - Hothan, Sascha T1 - Development of an in situ test method to assess the fire resistance of steel members with applied intumescent coating N2 - Intumescent coatings are commonly used in civil engineering to improve the fire resistance of steel constructions. Exposed to fire, the intumescent coating reacts and forms a thermal protective char around the steel member. Thus, the heating of the steel is delayed, and a higher fire resistance can be achieved. Generally, the scope of application and the durability of intumescent coatings are described in national approvals or European Technical Assessment (ETA) documents. Due to environmental conditions, intumescent coatings are subjected to ageing effects, which can reduce their durability and thermal protection performance. Available in situ methods to investigate the performance of applied intumescent coatings, such as visual inspection, flame exposure testing, adhesive tensile tests or chemical analysis, are not fully conclusive. Therefore, in the civil engineering practice, there is an increasing demand to verify the fire resistance of existing steel structures with applied intumescent coatings necessary in several cases, e.g., the working life is exceeded, the visual appearance of the intumescent coating changed or the information about the applied product is missing. The research presented in the paper shows the progress of the ongoing research project "INSIST" at BAM, where a new in situ method is being developed to assess the actual fire resistance of existing steel structures with applied intumescent coating. The investigation is based on a development of the in situ test procedure and a mobile prototype furnace. T2 - 10th Symposium Structural Fire Engineering – TU Braunschweig 2024 CY - Braunschweig, Germany DA - 24.09.2024 KW - In situ KW - Intumescent coating KW - Steel structures KW - Test procedure PY - 2024 AN - OPUS4-61261 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Fürst, Richard A1 - Häßler, Dustin A1 - Stelzner, Ludwig A1 - Hothan, Sascha T1 - In situ test procedure to determine the fire resistance of existing steel structures with aged intumescent coating N2 - BAM is conducting a research project to develop a minimally invasive in situ test procedure to determine the fire resistance of existing steel structures with applied intumescent coating. In presentation and submitted paper is describe the test setup, the developed prototype furnace, and the results of the performed test programme with uncoated and coated steel specimens. Based on this, recommendations for the test procedure are given. T2 - Structures in Fire 2024 CY - Coimbra, Portugal DA - 19.06.2024 KW - In situ KW - Intumescent coating KW - Steel structures KW - Test procedure PY - 2024 AN - OPUS4-61257 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Häßler, Dustin T1 - Forschungsprojekt "INSIST" in situ Bewertungsverfahren für reaktive Brandschutzsysteme (RBS) N2 - Projektvorstellung zum Arbeitsstand der Entwicklung des in situ Prüfverfahrens für Stahlbauteilen mit gealtertem reaktiven Brandschutzsystem. T2 - 110. Sitzung des Arbeitsausschusses „Brandschutz“ CY - Braunschweig, Germany DA - 05.11.2024 KW - Feuerwiderstand KW - Branversuch KW - Reaktives Brandschutzsystem KW - Stahl PY - 2024 AN - OPUS4-61521 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kobe, André A1 - Stelzner, Ludwig A1 - Hothan, Sascha A1 - Zehfuß, Jochen T1 - Der Einfluss der Prüfbedingungen auf das Abplatzverhalten von Beton im Brandfall T1 - The influence of the test conditions on the spalling behaviour of concrete due to fire exposure N2 - Die Durchführung von realmaßstäblichen Bauteilversuchen zur Analyse des Abplatzverhaltens von Beton im Brandfall ist aufwendig, material‐ und kostenintensiv und setzt die Verfügbarkeit von Großbrandversuchsständen voraus. Daher wird die Abplatzneigung von Beton vorwiegend an kleinformatigen Prüfkörpern untersucht. Mit der Reduktion der Prüfkörpergröße verringert sich der thermische und hygrische Gradient im Randbereich, wodurch sowohl die thermisch induzierten Schädigungen im Beton als auch die Abplatzungen verringert werden. Für ein besseres Verständnis dieser komplexen Zusammenhänge wurde das Abplatzverhalten kleinformatiger Betonprüfkörper (Ø = 0,47 m; h = 0,29 m) mit verschiedenartigen Ummantelungen und unterschiedlichen Feuchtezuständen der Betonrandzone für zwei Normalbetone analysiert. Am Prüfkörper applizierte Stahlringe behinderten dabei die thermische Ausdehnung sowie den Wasserverlust über die Mantelfläche. Die Ergebnisse zeigen, dass die Abplatzungen infolge der Prüfkörperummantelung zunehmen und die Größenordnung vergleichender Großbrandversuche erreichen. Dies lässt den Schluss zu, dass die Ummantelung eines kleinformatigen Prüfkörpers mit Stahlring die Prüfbedingungen in der Mitte der brandbeanspruchten Fläche eines großformatigen Bauteils nachstellen kann. Des Weiteren führt die Vortrocknung der Betonrandzone zur Verzögerung bzw. Verringerung von Abplatzungen. N2 - Investigating the spalling behaviour of a concrete mixture using large scale members is complex and expensive. Thus, the susceptibility to spalling of concrete is investigated by means of fire tests on small format specimens. However, the reduction of the fire exposed surface increases the influence of boundary effects. Macrocracking and the water loss via the lateral surfaces reduce the thermomechanical and thermohydraulic damage and therefore, lower the risk of spalling. Thus, this study investigated the influence of different restraint and moisture conditions on the spalling behaviour of small format specimens (Ø = 0.47m; h = 0.29m) for two ordinary concrete mixtures. Applied steel rings restrained the thermal expansion of the specimen and prevented the water loss during the fire test. The results show that increased spalling occurred to a similar extend as in large scale fire tests because of a restrained expansion of the specimen. Further, a pre-dried boundary zone led to a delayed or rather a prevention of spalling compared to the non-dried specimens. To determine the susceptibility to spalling of a concrete mixture, the test conditions in the centre of a large scale member can be simulated by restraining the expansion of a small format specimen with applied steel rings. KW - Beton KW - Brand KW - Abplatzen KW - Zwang PY - 2025 DO - https://doi.org/10.1002/best.202400104 SN - 1437-1006 SP - 1 EP - 10 PB - Wiley AN - OPUS4-62732 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Flame Retardancy Features Sustainability Food for Thought, Fake Fiction, and Future N2 - Sustainability (environmental conservation for the economic welfare and prosperity for all) would revolutionise the plastics industry were it to become predominant practice as a linear, fossil-fuel–based economy is switched to a carbon circular one. Hence, the innovative field of flame-retardant polymeric materials should lend its strength to drive this challenge. Visionary solutions are proposed to inspire us, while the implementation of economically feasible concepts take us forward into the future. A critical overview of current trends is presented, using examples from the literature and our own recent projects. The examples lead from the use of natural materials with some intrinsic flame retardancy, via biocomposites, to using renewable sources for flame retardants. Natural flame retardants and adjuvants are highlighted, motivating our vision. Some of the visionary approaches such as flame-retardant poly(limonene carbonate) or wastewater phosphorus enriched micro algae as a sustainable flame retardant are rather innovative. Further, natural material streams find their way into polymer mass production as fillers, adjuvants, or renewable educt sources; industrial waste streams open the door to sustainable solutions, because they avoid competition for land with farming or virgin forests. Remarks will address recycling, flame retardant vitrimers are potential materials for recyclable thermosets. Only convincing property profiles will prevail both for exploiting renewable sources and circular design; sustainability must not be merely tolerated as an additional demand but should instead be recognized as a solution ensuring our economic welfare now and in the future. Acknowledgement: Funding: BMBF WTZ 01DN16040, DFG Scha 730/19 u. 20, VW-Stiftung: Experiment 97437, BMBF KMU Innovativ 031B1289B. People: A Battig, R Bhatia, J Chacon Castro, M Dudziak, SF Falkenhagen, FR Gleuwitz, a.o. (BAM) and G Sánchez Olivares (CIATEC), R Dey (Constructor University), A Greiner (Bayreuth), a.o. T2 - 19th Bayreuth Polymer Symposium CY - Bayreuth, Germany DA - 21.09.2025 KW - Poly(limonene carbonate) KW - Flame retardant biocomposites KW - Wastewater phosphorus enriched micro algae KW - Non-vegan flame retardant KW - Flame retardant vitrimers KW - Bio-based flame retardant PY - 2025 AN - OPUS4-64204 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hothan, Sascha T1 - Forschungsprojekt "INSIST" N2 - Der Vortrag zeigt den Bearbeitungsstand des Forschungsvorhabens "Entwicklung eines Verfahrens zur in situ Bewertung des Feuerwiderstands von bestehenden Stahlkonstruktionen mit reaktiven Brandschutzsystem (RBS)" (INSIST). Die Entwicklung und der Bau eines Geräteprototyps wurden vorgenommen und ein Konzept zur Kalibration erarbeitet. Die bisherigen Untersuchungen belegen, dass das Verfahren Ergebnisse liefert, die denen konventioneller Brandversuche im untersuchten Parameterbereich gleichwertig sind. T2 - Sachverständigenausschuss Reaktive Baustoffe und Beschichtungen -B- (463a) des Deutschen Institutes für Bautechnik CY - Berlin, Germany DA - 13.02.2024 KW - INSIST KW - In situ Bewertung KW - RBS PY - 2024 AN - OPUS4-60777 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sperlich, Tim A1 - Häßler, Dustin A1 - Stelzner, Ludwig A1 - Hothan, Sascha T1 - In situ Prüfmethode zur Untersuchung des Feuerwiderstands von bestehenden Stahlkonstruktionen mit reaktivem Brandschutzsystem N2 - Der Beitrag beschreibt die Entwicklung eines neuartigen in situ Nachweisverfahrens zur Beurteilung des Feuerwiderstandes von bestehenden Stahlkonstruktionen mit gealtertem reaktivem Brandschutzsystem (RBS). Derzeit ist ein solcher Nachweis ausschließlich anhand eines Bauteilbrandversuchs möglich. Hierzu muss ein Bauteil aus der Bestandskonstruktion entnommen und einer zerstörenden Brandprüfung unterzogen werden. In Zusammenhang mit der Dauerhaftigkeitsbewertung von RBS für Zeiträume von mehr als 10 Jahren besteht in der Praxis vermehrt der Bedarf an einem minimal invasiven Prüfverfahren, mit dessen Hilfe sich direkt am Bestandsbauwerk die tatsächlich vorhandene Leistungsfähigkeit des gealterten RBS überprüfen lässt. Durch einen erfolgreichen Funktionsnachweis wäre eine Weiternutzung der Bestandkonstruktion bei Aufrechterhaltung des bestehenden Sicherheitsniveaus möglich. T2 - Symposium Heißbemessung - Structural Fire Engineering CY - Braunschweig, Germany DA - 05.09.2023 KW - Brandschutz KW - Stahlbau KW - reaktives Brandschutzsystem KW - Prüfmethode KW - Brandversuch PY - 2023 SP - 1 EP - 16 PB - TU Braunschweig CY - Braunschweig AN - OPUS4-58180 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sperlich, Tim T1 - In situ Prüfmethode zur Untersuchung des Feuerwiderstands von bestehenden Stahlkonstruktionen mit reaktivem Brandschutzsystem N2 - Der Beitrag beschreibt die Entwicklung eines neuartigen in situ Nachweisverfahrens zur Beurteilung des Feuerwiderstandes von bestehenden Stahlkonstruktionen mit gealtertem reaktivem Brandschutzsystem (RBS). Derzeit ist ein solcher Nachweis ausschließlich anhand eines Bauteilbrandversuchs möglich. Hierzu muss ein Bauteil aus der Bestandskonstruktion entnommen und einer zerstörenden Brandprüfung unterzogen werden. In Zusammenhang mit der Dauerhaftigkeitsbewertung von RBS für Zeiträume von mehr als 10 Jahren besteht in der Praxis vermehrt der Bedarf an einem minimal invasiven Prüfverfahren, mit dessen Hilfe sich direkt am Bestandsbauwerk die tatsächlich vorhandene Leistungsfähigkeit des gealterten RBS überprüfen lässt. Durch einen erfolgreichen Funktionsnachweis wäre eine Weiternutzung der Bestandkonstruktion bei Aufrechterhaltung des bestehenden Sicherheitsniveaus möglich. T2 - Symposium Heißbemessung - Structural Fire Engineering CY - Braunschweig, Germany DA - 05.09.2023 KW - Brandschutz KW - Stahlbau KW - Reaktives Brandschutzsystem KW - Prüfmethode KW - Brandversuch PY - 2023 AN - OPUS4-58183 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eiz Eddin, Ahmad A1 - Stelzner, Ludwig A1 - Häßler, Dustin A1 - Hothan, Sascha T1 - Zum Feuerwiderstand von filigranen Deckenelementen aus vorgespanntem Carbonbeton N2 - Der Einsatz von hoch zugbeanspruchbarem und korrosionsbeständigem Carbongelege anstelle von herkömmlichem Spannstahl ermöglicht es Beton vorzuspannen und gleichzeitig die Betondeckung auf ein für den Verbund nötiges Minimum zu reduzieren. Das Carbongelege besteht aus Carbonfasern in einer Kunststoffmatrix. Mit dieser Bauweise können dünnwandige und damit ressourcenschonende Deckenelemente realisiert werden. Der Wechsel von massiven zu filigranen und vergleichsweise leichten Bauteilen führt jedoch aufgrund der geringeren Masse und der damit einhergehenden schnelleren Erwärmung zu einer Abnahme des Feuerwiderstands. Ferner führt die Erweichung der Matrix im Brandfall zu einer Abnahme der Verbundfestigkeit zwischen Carbongelege und Beton. Die Brennbarkeit des Carbongeleges sowie die Abplatzneigung des verwendeten Feinbetons stellen weitere Herausforderungen für den baulichen Brandschutz dar. Der Beitrag stellt Versuchsergebnisse zum Abplatz- und Hochtemperaturverhalten von Carbonbeton vor, die im Rahmen des Verbundvorhabens „Vorgespannte Carbonbetondecken mit reduzierten Querschnitten“ (CaPreFloor) erzielt wurden. Für die Untersuchung der Tragfähigkeit bei hohen Temperaturen wurden 4-Punkt-Biegeversuche an balkenförmigen Prüfkörpern (150 x 30 x 6 cm³) mit einlagiger Carbonbewehrung und instationärer Temperaturbeanspruchung durchgeführt. Neben dem Vorspanngrad des Carbongeleges wurde auch der Gelegetyp variiert. Im Bereich der konstanten Biegezugzone erfolgt die einseitige Erwärmung mittels elektrisch betriebener Heizmatten. Während der kontinuierlichen Erwärmung werden die Prüfkörper mit einer konstanten Kraft belastet, deren Betrag aus zuvor durchgeführten Biegeversuchen bei Raumtemperatur abgeleitet wurde. Die Abplatzversuche werden mit Einheits-Temperaturzeitkurve an rechteckigen (60 x 60 x 6 cm³) und kreisrunden (Ø 47 x 6 cm³), plattenförmigen Prüfkörpern am 1m³-Ofen der BAM durchgeführt. Die kreisrunden Prüfkörper sind zusätzlich mit einem Stahlring zur Behinderung der thermischen Dehnung des Betons versehen. Um den Einfluss des Geleges auf das Abplatzverhalten zu analysieren, werden sowohl Prüfkörper mit Carbongelege als auch unbewehrte Prüfkörper untersucht. Die daraus resultierenden Erkenntnisse fließen in die weitere Entwicklung der vorgespannten Carbonbetondeckenelemente ein. Anhand von realmaßstäblichen Brandversuchen wird der Feuerwiderstand dieser Bauteile im weiteren Projektverlauf bestimmt. T2 - Symposium Heißbemessung 2024 CY - Braunschweig, Germany DA - 24.09.2024 KW - Carbonbeton KW - Feuerwiderstand KW - Brandversuch KW - Carbon PY - 2024 SP - 23 EP - 39 AN - OPUS4-61253 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eiz Eddin, Ahmad T1 - Innovative lightweight floors made of prestressed CFRP-reinforced concrete from research to construction practice N2 - The presented joint research project “CaPreFloor”, which started in 2023, aims to revolutionise the building construction practice by employing prestressed textile-reinforced concrete using carbon-fiber-reinforced polymer (CFRP) for the design of lightweight floor elements. This allows the reduction of common steel reinforced concrete floors of 30 cm thickness to 10 cm for office, residential, and hotel buildings. Lower material consumption significantly contributes to the conservation of resources and minimises the carbon footprint. In addition, the prefabrication of these floor elements leads to high and consistent quality, short construction times and enhanced reusability of the components. A team of experts from various fields of research and practice is working on this project to achieve the set goal. T2 - XI International Symposium on Fiber Reinforced Concrete (Befib 2024) CY - Dresden, Germany DA - 16.09.2024 KW - Fire Resistance KW - Sound protection KW - Ceiling KW - Concrete KW - CFRP PY - 2024 AN - OPUS4-61126 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Romero Navarrete, J. A. A1 - Otremba, Frank A1 - Lozano Guzmán, A. A. T1 - Experimental-theoretical modelling of the lateral sloshing in rail tankers N2 - The objective of this paper is to describe and to validate a simplified pendulum-analogy model to simulate the interaction of a liquid cargo with ist carrying vehicle. The resulting testing rig consists of a rectangular container, spring supported on a two wheelset-bogie having a scale down of 1/10 with respect to a full-size equipment. The testing rig is used to validate a simple pendulum-based, simplified three degree-of-freedom mathematical model of the response of a partially filled container to lateral accelerations. The length of the pendulum is set according to validated methodologies. The resulting mathematical scheme reveals a high correlation with the experimental output, on the order of 99%, while some other performance measures, related to the peak forces and the range of variation of the wheel-rail forces, also show good concordance with the experimental results. KW - Sloshing KW - Rail tankers KW - Pendulum analogy KW - Experimental modelling KW - Mechanical fatigue PY - 2021 DO - https://doi.org/10.1504/ijhvs.2021.117504 VL - 28 IS - 3 SP - 435 EP - 454 AN - OPUS4-53101 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Otremba, Frank A1 - Romero Navarrete, J. A. T1 - Assesing rail damage in turns due to lateral load transfer N2 - A testing procedure is proposed and used, to estimate the rail damage potentials of variations in both, the height of the cargo´s center of gravity and the railway car suspension´s spring constant. The experimental setup consisted of a tilt table that slowly exerted an increasing lateral acceleration on a two-axle bogie-type vehicle equipped with a spring supported container. The potential damaging effect derived from the resulting lateral load transfer, was assessed on the basis of the fourth-power law. Results suggest that the cargo having a higher center of gravity could be more damaging to the outside rail when compared with the effect of the shorter center of gravity of the cargo, in arrange from0.94% to 3.17%, as a function of the spring constant of the suspension. Consequently, and comparatively, there would be a long-term damaging effect on the rail when having a cargo with a higher center of gravity, so that specific cargo, having a high center of gravity, would be more aggressive to the infrastructure. On the other hand, for the range of time rate changes of the lateral acceleration, it was not found a consistent trend regarding the effect of the value of the spring constant on the magnitude of the load transfers. T2 - ASME 2024 CY - Portland, OR, USA DA - 17.11.2024 KW - Rail demage KW - Lateral load transfer PY - 2024 AN - OPUS4-61784 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. T1 - A testing facility to assess railway car infrastructure damage. A conceptual design N2 - A testing device and respective procedure have been proposed to assess the railway damage potentials of the railway cars The operational principles of the device consist of simple physical phenomena. Outputs from a preliminary test suggest that the device could have a good sensitivity T2 - COMPRAIL 2020 - 17th International Conference on Railway Engineering Design & Operation 2020 CY - Online meeting DA - 01.07.2020 KW - Railway KW - Infrastrucute KW - Demage PY - 2020 AN - OPUS4-51166 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Romero-Navarrete, José A. A1 - Otremba, Frank T1 - A testing facility to assess railway car infrastructure damage N2 - Wheel forces generate stresses in the rail as a function of several vehicle and infrastructure characteristics and operating conditions. The different components of the wheel forces develop strains in the rail which contain an elastic and hysteretic (irreversible) components. The irreversible deformations of the rail would be associated with locomotive energy losses. In this paper, a testing facility is proposed to indirectly characterize the level of stresses in the rail, in terms of the energy that is lost during tuming maneuvers. Different potentially influential factors are considered, including the friction at the Center plate, the wheelbase length, the distance between bogies and the radius of the curved track. The change in the potential energy during a U-turn displacement is measured. In this respect, an experimental model under this operating principle, aimed at validating such a principle of Operation, reveals a significant effect of the friction at the center plate on the energy lost during turning maneuvers, and consequently, on the level of stresses in the rail. T2 - COMPRAIL 2020 - 17th International Conference on Railway Engineering Design & Operation 2020 CY - Online meeting DA - 01.07.2020 KW - Energy losses in transportation KW - Experimental methods KW - Friction energy KW - Rail damage KW - Turning forces KW - Wheel forces PY - 2020 DO - https://doi.org/10.2495/TDI-V4-N2-142-151 SN - 2058-8305 VL - 4 IS - 2 SP - 142 EP - 151 PB - WitPress AN - OPUS4-51125 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Otremba, Frank A1 - Hildebrand, R. A1 - Romero Navarrete, J. A. A1 - Sklorz, Christian ED - Otremba, Frank T1 - A simplified analytical approach on the dynamic pressures in cylindrical vertical tanks N2 - A simplified methodology is proposed to estimate the dynamic pressures developed within partially filled cylindrical vertical tanks when subjected to earthquake-related horizontal accelerations. The total pressure at the bottom of the tank is calculated as the superposition of vertical and horizontal pressures. While the magnitude of the vertical pressure depends on the free surface height of the liquid, the horizontal pressure depends on the magnitude of the horizontal acceleration and on the diameter of the tank. The liquid free surface oscillation angle is simulated based upon the principles of the simple pendulum analogy for sloshing. The length of the pendulum, however, is set on the basis of a methodology to calculate the free sloshing frequency of partially filled containers. Such a methodology is experimentally verified in this work. The outputs of the model for full scale situations, suggest that the lateral perturbation - sloshing phenomenon (earthquake effect) can generate an increase in the total pressure of 56% above the no lateral perturbation situation, further suggesting that such an overpressure should be taken into account when designing tanks that could be potentially subjected to earthquake-related perturbations. KW - Vertical cylindrical tanks KW - Pendulum analogy KW - Experimental approach KW - Sloshing, transition matrix approach KW - Hazmat PY - 2021 SN - 978-981-15-8273-8 SP - 1 EP - 15 PB - Springer AN - OPUS4-51982 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Jauregui-Correa, J. C. A1 - Otremba, Frank A1 - Romero-Navarrete, José A. A1 - Hurtado-Hurtado, G. ED - Pucheta, M. ED - Cardona, A. ED - Preidikman, S. ED - Hecker, R. T1 - Determination of the Effect of Sloshing on the Railcar-Track Dynamic Behavior N2 - This paper presents the study of the impact caused by a liquid Cargo on a railway infrastructure. The dynamic behavior of a tank car corresponds to a multibody dynamic system with several degrees of freedom. This study’s data were obtained from a scale experimental fixture consisting of a track and a railcar with a tank. The track was instrumented with strain gauges and the railcar with accelerometers. The data showed non-periodic and periodic terms; therefore, the results were analyzed with the Empirical Mode Decomposition method (EMD). It was found that the EMD identified the signal components that were related to the sloshing. These components represent the mode shapes of the original signal. The location of the sloshing in the track was found applying spectrograms to the accelerometer data. This paper’s experimental outputs suggest that the sloshing effect is detectable at the track and in the vehicle dynamics. KW - Sloshing effect KW - Empirical Mode Decomposition KW - Wheel/track interaction KW - Multibody dynamics PY - 2021 SN - 978-3-030-88750-6 DO - https://doi.org/10.1007/978-3-030-88751-3_14 SP - 131 EP - 140 PB - Springer Nature Switzerland AG AN - OPUS4-53561 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rockel, Daniel A1 - Sanchez Olivares, G. A1 - Calderas, F. A1 - Schartel, Bernhard T1 - It’s not waste, it’s a resource: Utilizing industrial waste fibers/mineral fillers to attain flame retardant biocomposites N2 - Integrating natural fibers derived from local industrial waste streams into thermoplastic starch (TPS) proves to be a promising approach towards sustainable flame retardant biocomposites. Initially, three types of waste fibers from the agave, coconut, and leather industries were evaluated for their flame retardant properties in combination with aluminum trihydroxide (ATH), an environmental friendly flame retardant. Leather fiber (BLF) exhibited the best flame retardant performance and were further investigated along with ATH and varying amounts of bentonite nanoclay to enhance the residual protective layer. The combination of multiple components shows improvement in performance while reducing the total load of filler. The images of the fire residues revealed that a more enclosed surface correlates with a reduction in the peak of heat release rate. Whereas higher amounts of bentonite does not deliver further inprovements, only 1 phr nanoclay in the novel multicomponent system of TPS, ATH, BLF, and bentonite synergistically improved the UL-94 rating from HB to V1. The proposed system brings together the different approaches using a renewable biopolymer, natural waste fibres, and envirnmentally friendly flame retardancy and thus, is striking for its combination of outstanding sustainablity, instant feasability, and sufficient fire performance. KW - Biocomposites KW - Flame retardancy KW - Residue analysis KW - Sustainability KW - Waste streams PY - 2025 DO - https://doi.org/10.1177/08927057241297083 SN - 0892-7057 SN - 1530-7980 VL - 38 IS - 6 SP - 2225 EP - 2252 PB - Sage AN - OPUS4-63431 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hothan, Sascha T1 - Durability of Intumescent Coatings - Experimental investigations and test concepts for a working life of more than 10 years N2 - Intumescent coatings are subjected to ageing effects caused by climatic influences. The established European regulations to assess the durability of intumescent coatings are limited to a working life of 10 years. In the presentation experimental investigations and test concepts to extend the working life to 25 years are shown. In addition, a new in-situ testing method to assess the performance of applied intumescent coatings that have undergone ageing processes is presented. T2 - Annual Meeting of ECCS TC3 CY - Online meeting DA - 25.09.2023 KW - Intumescent coatings KW - Experimental investigations KW - In-situ testing PY - 2023 AN - OPUS4-63979 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sunder, S. A1 - Jauregui Rozo, Maria A1 - Inasu, S. A1 - Meinel, Dietmar A1 - Schartel, Bernhard A1 - Ruckdäschel, H. T1 - Effect of Ammonium Polyphosphate/Silicate Content on the Postfire Mechanics of Epoxy Glass-Fiber Composites Using Facile Chocolate Bar-Inspired Structures N2 - This study investigates the postfire mechanical properties of epoxy glass-fiber reinforced composites (EP GFRCs) using increasing concentrations of ammonium polyphosphate (APP) and inorganic silicate (InSi) to modify the char and fire residue. A facile chocolate bar-inspired structure was introduced for fire exposure and subsequent flexural testing of the GFRCs. The resin matrix used here was a diglycidyl ether of bisphenol-A (DGEBA) resin, cured with dicyandiamide (DICY), and accelerated by Urone. The microstructures of the degraded composites after three-point bending tests, were evaluated using scanning electron microscopy (SEM) and x-ray computed tomography (XCT) imaging. A previous study showed that increasing the APP and InSi content significantly enhanced flame retardancy, via improved char formation under fire conditions. However, flexural properties and fire resistance were adversely affected after fire exposure, highlighting a trade-off effect. Fiber breakage and delamination of the composites increased upon failure with increasing APP + InSi content in the composite due to unconsolidated char. The experimental values for the postfire flexural mechanics were in good agreement with the two-layer model proposed in literature. This paper presents a preliminary basis for postfire mechanical testing of epoxy composites for use in fire-safe structures, using a combination of standardized testing norms. KW - Flame retardants KW - Post-fire KW - Epoxy KW - Gass fiber composites KW - Prepregs PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-627176 DO - https://doi.org/10.1002/fam.3280 SN - 0308-0501 SN - 1099-1018 VL - 49 IS - 3 SP - 329 EP - 346 PB - Wiley AN - OPUS4-62717 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bibinger, J. A1 - Eibl, S. A1 - Gudladt, H.-J. A1 - Schartel, Bernhard A1 - Höfer, P. T1 - Pushing the limits of thermal resistance in nanocomposites: A comparative study of carbon black and nanotube modifications N2 - Enhancing the thermal resistance of carbon fiber-reinforced polymers (CFRPs) with flame retardants or coatings often leads to increased weight and reduced mechanical integrity. To address these challenges, this study introduces an innovative approach for developing nanocomposites using carbon-based nanoparticles, while preserving the structural lightweight properties. For this, carbon black particles (CBPs) up to 10% and carbon nanotubes (CNTs) up to 1.5% were incorporated into the RTM6/G939 composite material. The obtained samples were then analyzed for their properties and heat resistance under one-sided thermal loading at a heat flux of 50 kW/m2. Results demonstrate that integrating these particles improves heat conduction without compromising the material’s inherent advantages. As a result, thermo-induced damage and the resulting loss of mechanical strength are delayed by 17% with CBPs and 7% with CNTs compared to the unmodified material. Thereby, the thermal behavior can be accurately modeled by a straightforward approach, using calibrated, effective measurements of the nanoparticles in the polymer matrix rather than relying on theoretical assumptions. This approach thus provides a promising methode to characterize and improve thermal resistance without significant trade-offs. KW - Nanomaterial KW - Cabon fiber-reinforced polymer (CFRP) KW - Carbon black (CB) KW - Carbon nanotube (CNT) KW - Improving heat conduction KW - Prediction thermal properties PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-628632 DO - https://doi.org/10.3390/nano15070546 SN - 2079-4991 VL - 15 IS - 7 SP - 1 EP - 23 PB - MDPI CY - Basel AN - OPUS4-62863 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hupp, Vitus A1 - Schartel, Bernhard A1 - Flothmeier, K. A1 - Hartwig, A. T1 - Flame Retarded Adhesive Tapes and Their Influence on the Fire Behavior of Bonded Parts N2 - Pressure-sensitive adhesive tapes are used in automotives, railway vehicles and construction, where flame retardancy is of major importance. This is why industrial applicants often buy, and industrial tape manufacturers often produce, flame-retardant adhesive tapes, advertised for their good flammability characteristics. Yet, how flame-retardant tapes influence the fire behavior of bonded materials is a rather open question. To investigate this issue, three different substrates were bonded, using eight double-sided adhesive tapes containing two different carriers and two different flame retardants. The bonded substrates were compared to their monolithic counterparts in terms of flammability, fire behavior and fire stability. The fire behavior of adhesive tape bonded materials differed significantly from the monolithic substrates. The usage of different adhesive tapes let to different burning behavior of the bonded materials mainly due to different carrier systems. In contrast, the implementation of flame retardant into the adhesive had rather minor or no effect on the burning behavior of the bonded substrates despite their positive effect on the flammability of the free-standing tape. The carrier changed the HRR curve in the cone calorimeter and was able to both, reduce and increase fire hazards. Using the carrier with the better fire performance can lower the fire growth rate by 20%, the peak of heat release rate by 27%, and the maximum average rate of heat emission by 30% in cone calorimeter tests. Overall, the fire behavior of bonded materials is a complex interaction between substrate, adhesive, and carrier, and depends on the fire scenario the materials are exposed to. KW - Pressure-sensitive adhesive tapes KW - Bonded materials KW - Fire behaviour KW - Fire resistance KW - Flame retardant KW - Cone calorimeter PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-626006 DO - https://doi.org/10.1007/s10694-024-01637-2 SN - 1572-8099 SN - 0015-2684 VL - 61 IS - 2 SP - 729 EP - 749 PB - Springer Nature AN - OPUS4-62600 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - 1 + 1 ≠ 2 – Laminate Materials Meet Flame Retardancy N2 - Main message: Fire tests monitor the specific response of defined test specimens but are used to assess materials’ fire risks. The weakness of this simplification becomes obvious for laminate materials. The talk delivers inspiring food for thought in discussing the fire behaviour of laminates. The fire behaviour must not be expected to be a simple superposition. The design of laminate can generate fire risks as well as give birth to flame retardancy. Introduction Bench-scale fire testing monitors the reaction-to-fire response of well-defined test specimens in certain fire scenarios. Results are often discussed as kind of material properties; indeed, the fire risks of materials are assessed. The weakness of this simplifying concept becomes obvious when it comes to investigating material systems such as all kind of laminate materials. The talk delivers inspiring food for thought sketching the complex and sometimes surprising fire behaviour of laminates. Experimental The polymer analysis, thermal analysis, and investigation of fire behaviour were performed according to the state of the art, mostly in accordance with the ISO standards. We fulfil high quality standards in terms of maintenance, calibration, participation in round robins, and so on. Work steps such as compounding of the materials or injection moulding of test specimen were outsourced or done with partners that have the relevant core competence. The presentation is based on the conclusions and concrete results of projects performed in the group of the author, whose experimental is described in the corresponding scientific papers in detail.[1-3] Results and Discussion Examples show that the fire behaviour of laminates must not be expected to be a simple superposition of the fire behaviour of the individual materials. Indeed, laminate effects can be crucial and influence the flammability relevantly. The design of the laminate can generate fire risks as well as give birth to synergistic flame retardancy. Veneered wood, lacquered products, or foil laminated materials are sketched to illustrate the topic with its potential and challenges. Glued samples consisting of two plates of the same material are discussed to generate some basic understanding as well as to investigate the fire behaviour of glued materials. The impact of the glue line on the burning behaviour of different polymeric materials such as bisphenol A polycarbonate, polymethylmethacrylate, and wood differs remarkably.[2] Further, the role of the glue including but not limited to using flame retarded glues is scrutinized. Making the best out of this understanding we have proposed to concentrate flame retardancy in the top layer.[1, 3] To achieve optimum flame-retardant effect or flame retardancy without disturbing the property profile of the core, flame retardants are strategically concentrated in the surface layer of thermoplastic materials with a laminate structure. Several systems increasing the charring and forming a residual protective layer are identified showing a synergistic effect compared to homogenously flame retarded test specimen. This research presented a promising solution for reducing the use of flame retardants without sacrificing fire performance or mechanical properties, offering significant advantages for industrial applications. T2 - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025) CY - Madrid, Spain DA - 03.06.2025 KW - Fire behaviour of laminates KW - Flame retardancy by laminate design PY - 2025 AN - OPUS4-63394 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Fire Retardancy Featuring Sustainability: Food for Thought between Fake Fiction and Future N2 - MAIN MESSAGE: Sustainability, or in other words, exploiting environmental conservation for the economic welfare and prosperity for all, would revolutionise the plastics industry were it to become predominant practice as a linear, fossil-fuel–based economy is switched to a carbon circular economy. Food for though is given by dint of a critical overview of the current trends in sustainable flame-retardant polymeric materials. STARTING POINT AND INTRODUCTION: Transforming the plastics industry into a carbon circular economy over the next 30 years requires an immediate revolution entailing the development of cutting-edge materials and the planning of future industrial production plants. Hence, the innovative field of flame-retardant polymeric materials for electrical engineering, construction, or materials used in transportation should lend its strength to drive this challenge. Visionary solutions are proposed to inspire us, while the implementation of economically feasible concepts can take us forward into the future. A critical and structured overview of current trends towards sustainable, flame-retardant polymeric materials is presented, using examples from the literature and by sketching our own projects performed in recent years. RESULTS AND DISCUSSION: This overview of current trends towards producing sustainable, flame-retardant polymeric materials is presented, selecting outstanding and representative examples from the literature and sketching main points of our own projects performed in this field in recent years. The examples are structured along a common theme leading from the use of old and new natural materials with some intrinsic flame retardancy, via flame-retardant biopolymers and biocomposites, to using renewable sources for flame retardants with the objective of exploiting natural sources available as industrial waste streams. Natural flame retardants and adjuvants are highlighted, although the status of most may be assessed as merely motivating our vision. However, some of these visionary approaches such as discussing sustainable flame retardants for poly(limonene carbonate), a polymer synthesised from renewable waste and CO2, or wastewater phosphorus enriched micro algae as a sustainable flame retardant in polylactide are rather innovative when achieving a surprising high technological readiness level or providing a comprehensive solution for several urgent demands at once. Further, there are natural material streams finding their way into polymer mass production as fillers, adjuvants, polymers, or renewable educt sources. Natural substances originating from industrial waste streams open the door to sustainable solutions, because they are often available at low cost and avoid competition for land with farming or virgin forests. Aside from this main topic, remarks will address the recycling of flame-retarded polymeric materials; flame retardant vitrimers are mentioned as potential materials for recyclable thermosets. At the end of the day, only convincing property profiles will prevail both for exploiting renewable sources and circular design, including cost effectiveness, sufficient availability, consistent quality, processibility, mechanical properties, and flame retardancy. However, sustainability must not be merely tolerated as an additional demand, but should instead be recognized as a solution, because sustainability aspires to ensure our economic welfare now and in the future. T2 - Interflam 2025 CY - Royal Holloway, Egham, UK DA - 30.06.2025 KW - Biocomposites KW - Sustainability KW - Renewable KW - Bio wastefibres KW - Circular economy KW - Phosphorus flame retardants PY - 2025 AN - OPUS4-63671 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Jauregui Rozo, Maria A1 - Sunder, S. A1 - Inasu, S. A1 - Meinel, Dietmar A1 - Ruckdäschel, H. A1 - Schartel, Bernhard T1 - Weaving Through Fire and Force: Fire Behavior and Fire Stability of Unidirectional, Bidirectional, and Woven Roving Glass-Fiber Composites N2 - This study systematically investigates the transfer of flame retardants (FRs) from epoxy resins to composites. The flame-retardant composites are formulated using bisphenol A diglycidyl ether as the resin and dicyandiamide as the hardener, reinforced with glass fibers (GFs) using various textile architectures: unidirectional (UD), bidirectional (BD), and woven rovings (WR). These composites are evaluated using bench-scale fire stability tests and cone calorimeter experiments to assess critical parameters, including the temperature at failure, time to failure, and fire behavior. Among the tested configurations, UD-GFs demonstrate superior flame retardancy, fire stability, flammability, and mechanical performance, attributed to their higher residue yield, forming a more efficient protective char layer. However, the addition of FRs is limited by their impact on the material's mechanical properties. When the FR content increases to 30 and 50 wt.% of the resin, the composites exhibit a decrease in mechanical performance, adversely affecting both time to failure and temperature at failure. While adding FRs reduces the risk of fire propagation, it does not substantially enhance fire stability or mechanical performance. KW - Fire Resistance KW - Fiber-Reinforced Polymer Composites KW - Fire Stability KW - Glass Fibers KW - Fire Behavior PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-631220 SN - 1438-7492 SN - 1439-2054 VL - 310 IS - 5 SP - 2400432 PB - Wiley VHC-Verlag AN - OPUS4-63122 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Fire Retardancy Featuring Sustainability: Food for Thought between Fake Fiction and Future N2 - Sustainability, or in other words, exploiting resources under the terms of environmental conservation for the economic welfare and prosperity continuously over time, would revolutionise the plastics industry were it to become predominant practice as a linear, fossil-fuel–based economy is switched to a carbon circular economy. Food for though is given by dint of a critical overview of the current trends and mainly by sketching our own key projects performed in the field of sustainable flame-retardant polymeric materials in the recent years. T2 - Interflam 2025 CY - London, United Kingdom DA - 30.06.2025 KW - Biocomposites KW - Sustainability KW - Renewable KW - Bio wastefibres KW - Fire Behavior PY - 2025 VL - 1 SP - 187 EP - 190 PB - Interscience Communications Ltd AN - OPUS4-63681 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dey, R. A1 - Dudziak, Mateusz A1 - Prescher, A. A1 - Kreitsmann, T. A1 - Zhang, K. A1 - Posten, C. A1 - Thomson, C. A1 - Schartel, Bernhard A1 - Ullrich, M. S. A1 - Thomson, L. T1 - Sustainable Flame-Retardant Poly Lactic AcidBiocomposites Reinforced with Polyphosphate-EnrichedMicroalgae: Unlocking the Potential of Hyper-Compensation N2 - This study examines the dual benefits of microalgae cultivation for wastewatertreatment and the enhancement of polylactic acid-based biocomposites. UsingDesmodesmus sp. in a photobioreactor, both batch and continuous operationsachieve total nitrogen (TN) and total phosphorus (TP) removal rates of up to99.9%, maintaining TN and TP levels below 0.02 mg L−1 in the effluent, aligningwith European discharge standards. Continuous cultivation increases biomassproductivity from 0.102 to 0.43 g L−1 day−1 , a 322% improvement over batchoperations. Nutrient starvation followed by reintroduction to nutrient-richwastewater induces hyper-compensation luxury uptake, with P-enrichedcells accumulating 1.33% intracellular P within six hours — 21% higherthan natural accumulation. The results reveal that luxury phosphorus uptakein microalgae follows a triphasic system of uptake and storage, challengingthe previously suggested biphasic model. When incorporated into Poly lacticacid (PLA), the biomass enhances versatility, offering potential replacementof inorganic P in industrial applications, particularly flame retardants.Pyrolysis and cone calorimetry confirm the thermal and fire-retardantbenefits, with a 20% reduction in peak heat release rate and increased charyield. This work highlights microalgae’s role in sustainable biocomposites,supporting wastewater treatment, nutrient recovery, and CO2 sequestration. KW - biocomposites KW - biopolymers KW - Flame-retardant KW - Hyper compensation KW - Phycoremediation KW - Wastewater treatment PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-640408 DO - https://doi.org/10.1002/adsu.202500251 SN - 2366-7486 VL - 9 IS - 8 SP - 1 EP - 11 PB - Wiley VHC-Verlag AN - OPUS4-64040 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wagner, Jan T1 - This is the Way: An Evidence Based Route to Phytic-acid-based Flame Retardant Poly(lactide acid) N2 - Main message: This study provides an evidence-based route to flame retard poly (lactide acid) (PLA) with phytic acid (Phyt)-based flame retardants (FR). Phyt was prepared with lignin (Lig) and expandable graphite (EG). Three amine salts (arginine (Arg), piperazine (Pip), melamine (Mel)) were also synthesized with Phyt. Findings include UL 94 V0 classification, limited oxygen index (LOI) = 43.7 vol% and reduced total heat released (THR), while molecular weight (MW) was not affected. Combinations lead to the most effective FR. Introduction: As demand for biobased polymers increases, biobased FRs remain scarce in the market. With 28 wt.% P, Phyt is promising to be a biobased FR, but Phyt efficiency as a FR needs to be improved. [1] Furthermore, as a strong acid, it esterifies and hydrolysis PLAs backbone. With the combinations proposed in this study, processability and MW in PLA compounds were untouched, while FR performance of Phyt was enhanced. Experimental: Compounds analyzed in this study were: PLA, PLA Lig, PLA EG, PLA PhytLig, PLA PhytEG, PLA Mel, PLA PhytArg, PLA PhytPip, PLA PhytMel, PLA PhytMel Lig and PLA PhytMel EG. Addition of Phyt based FR was 16.7 wt.%, Lig and EG 10wt.%. Compounds were processed with twin screw extrusion, injection molding and hot press. Analysis was done with size exclusion tomography, differential scanning calorimetry (DSC), tensile strength, cone calorimeter, UL 94, LOI and thermogravimetry analysis (TGA) combined with Fourier transformation infrared spectroscopy (FTIR). Residues were analyzed with scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). Results and Discussion: To synthesize the FR, Lig and Phyt (solved in water) were mixed and dried. A solid material formed, which was grinded and then compounded with PLA. The same was done with EG. Phyt + Arg/Pip/Mel FR materials were each titrated to a pH of ~4.5, since this pH is known to be least harmful for the PLA backbone. For PhytMel a salt precipitated. PhytPip and PhytArg were dried and a resin-like structure was obtained, which was grinded to a powder. The molar mass distribution of PLA PhytArg (10,000 g/mol – 600,000 g/mol) is similar to PLAs ranging from 15,000 g/mol – 600,000 g/mol. MW distribution from highest to lowest was PLA > PLA PhytArg > PLA PhytMel > PLA PhytMel EG > PLA PhytMel Lig > PLA PhytEG > PLA PhytLig > PLA PhytPip. The reaction between Phyt and Arg/Mel prevents MW decomposition of PLA through a reaction of P acid and NH2 groups. Tensile strength declined to 35.9 MPA for PLA PhytMel and 32.1 MPA for PLA PhytArg, compared to 51.4 MPA for PLA. DSC analysis revealed TG was not affected for the FR compounds: Phyt Lig/EG/Arg/Mel, compared to PLA. PLA PhytMel crystallinity 𝐾∆𝐻𝑐𝑐𝑐𝑐 was 30%, PLA PhytArg crystallinity was 50%, compared to PLA 𝐾∆𝐻𝑐𝑐 was 46%. Melting peaks were not affected in PLA Phyt Arg/Mel. Flammability investigations lead to results of LOI 25.8 vol%/ UL 94 V2 classification in PLA, PLA PhytArg LOI 43.7 vol%/ UL 94 V2, due to strong dripping as a cooling mode of action. [2] PLA PhytMel burned with intumescent char and LOI 38.2 vol%/ UL 94 V2 was measured. Due to strong melt dripping, PLA PhytPip reached UL 94 V0. TGA revealed increased residue for all FR compounds. When materials were combined in PLA PhytMel EG residue was maximized to 19.9 wt.% (600°C, 𝑁𝑁2 atmosphere). FTIR analysis revealed PO and PH stretching vibrations, indicating radical scavenging. Cone calorimeter investigations of PLA, PLA PhytPip and PLA PhytArg lead to a steep incline in HRR to peak heat release rate (pHRR). Values are provided in Table 1. PLA PhytMel containing compounds exhibited prolonged burning and protective layer. PLA PhytLig, PLA PhytEG, PLA Mel (pHRR >1000) were investigated but proved inferior to PLA PhytMel, PLA PhytMel Lig and PLA PhytMel EG. THR was reduced in all Phyt compounds. Intumescence was observed in all compounds except for PLA Lig, PLA PhytLig and PLA PhytMel Lig. PLA PhytMel EG proved as the most effective compound in fire testing with a firm, coherent and intumescent char structure. This study provides an understanding of Phyt as a FR. It systematically improves Phyts effectiveness and processability in PLA. This evidence T2 - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025) CY - Madrid, Spain DA - 03.06.2025 KW - Polylactide acid KW - Intumescence KW - Phosphorous flame retardant KW - Phytic acid PY - 2025 AN - OPUS4-63395 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Häßler, Dustin T1 - Neues zum Brandschutz in Stahlbauten N2 - Editorial für die Septemberausgabe 2025 der Zeitschrift Bauingenieur KW - Brandschutz KW - Stahlbau KW - Reaktive Brandschutzsysteme KW - Modulbau PY - 2025 VL - 2025 IS - 9 SP - A3 EP - A3 PB - VDI Fachmedien GmbH & Co. KG CY - Düsseldorf AN - OPUS4-64034 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Flammschutz von Faserverbundwerkstoffen: Grundlagen und Konzepte N2 - Vor allen Kurz- und Lang-Glasfaser-verstärkte, aber auch Carbonfaser verstärkte Faserverbundwerkstoffe werden in Schienenfahrzeugen eingesetzt. Dabei sind die Brandschutzanforderungen entsprechend EN 45545 zu erfüllen. Der Übersichtsvortrag führt in die Grundlagen des Brandverhaltens und des Flammschutzes von Compositen ein. Anhand von eigenen Arbeiten wird verdeutlicht, dass Flammschutz maßgeschneidert für Composite, die Matrix und für den zu bestehenden Brandtest erforderlich ist. T2 - SKZ Fachtagung Faserverbundwerkstoffe im Schienenfahrzeugbau CY - Merseburg, Germany DA - 14.05.2025 KW - Faserverbundwerkstoffe KW - Composite KW - Flammschutz KW - Brandverhalten PY - 2025 AN - OPUS4-63123 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Chacon Castro, Jose P. T1 - Flame Retardant Polylimonen Carbonate: Material Innovation as a Game Changer N2 - Main message: This research seeks to understand and identify the most promising approaches to enhance the flame resistance of poly(limonene carbonate) (PLimC). Furthermore, the goal is to develop a PLimC-based material that incorporates halogen-free flame retardants (FRs) that are not only highly effective but also environmentally sustainable, contributing to the advancement of greener materials for safer use. Introduction The plastic industry depends on fossil-based materials, causing environmental concerns. PLimC, a sustainable polymer derived from limonene and CO₂ [1], offers a promising alternative. Its use in fire safe applications underscores the need to optimize its performance. This study evaluates halogen free FRs to identify and understand the most promising approaches to enhance PLimC’s flame resistance, aiming to improve fire safety and support eco-friendly material development. Experimental: This study has as its main task to conduct experimental evaluations to analyze the thermal properties, flammability, and fire behavior of each system. Pyrolysis, together with the evolved gases of the samples, were analyzed by thermogravimetric analysis coupled with a FTIR spectrometer. The energy content was determined by using a bomb calorimeter. The flammability of the samples was assessed by the reaction to small flame tests such as the UL 94 burning chamber and limiting oxygen index (LOI). The burning behavior in forced flamed conditions was evaluated using the cone calorimeter. Results and Discussion: Thermal properties were first evaluated to gain a deeper understanding of the pure PLimC thermal stability and fire behavior. This analysis builds on PLimC's structural similarity to polycarbonate (PC), due to its carbonate group, and to polyolefins (PO), due to its aliphatic limonene-derived segment, providing insights into optimizing PLimC for sustainable, fire-safe applications. The initial results, which defined our starting point, showed that the LOI of PLimC was 17.2%, very close to that of PO such as polyethylene (PE) and polypropylene (PP) (~18%). In contrast, PC has a higher LOI of ~24%. Additionally, PLimC did not produce any char (0 wt.-%), similar to PO, whereas PC forms char due to its phenolic structures. The effective heat of combustion of PLimC, measured using bomb calorimetry, was determined to be 31.1 MJ/kg. This value is comparable to that of PC (~30 MJ/kg) but significantly lower than PO (~44 MJ/kg). These findings, which demonstrated similarities to both PO and PC, prompted the evaluation of various commercially available FRs at standard market concentrations. Four halogen-free FR systems were chosen for evaluation: 1. mixture of APP (20 wt.-%) + pentaerythritol (10 wt.-%) as an intumescent system [PLimC / APP / Penta], 2. mixture of the phosphorus compound PX200® (16 wt.-%) + PTFE (0.4 wt.-%) as antidripping [PLimC / PhosC / PTFE], 3. metal hydroxide ATH (50 wt.-%) [PLimC / ATH], and the potassium sulfonate salt Bayowet® (0.4 wt.-%) [PLimC / SulfS]. The concentrations were decided according to the standards used in the industry for polyolefins (system 1 and 3), the mixture polycarbonate / ABS (system 2) and polycarbonates (system 4). PLimC has the usual behavior of a non-charring specimen (fast burning and high peak of heat release). ATH proved to be the most effective flame retardant, achieving the biggest reductions in the effective heat of combustion (EHC) and total heat evolved (THE), as demonstrated by cone calorimeter measurements. Additionally, ATH achieved the highest increase in the LOI (17.1% —> 26.0%). With these results, we understood that the FRs commonly used with polyolefins (at concentrations standard in the industry) exhibit similar behavior in terms of flammability and flame retardancy when applied to PLimC. Although ATH has proven to be an effective flame retardant for PLimC, offering a sustainable solution due to its abundance, non-toxicity, and low environmental impact, we aim to explore bio-based flame retardants to further enhance the material’s sustainability. Since phytic acid salts [2] and lignin [3] have demonstrated flame retardant efficacy in polyolefins, we believe these compounds could also perform well in our system. Phytic acid salts are particularly promising due to their high phosphorus content—and in some cases, nitrogen—which promotes char formation and enhances flame retardancy. Lignin’s unique ability to promote charring could significantly improve flame retardancy, due to the fact that PLimC like polyolefins, lacks inherent char formation. By integrating these bio-based flame retardants, we move closer to developing a fully sustainable material that aligns with the Sustainable Development Goals of the United Nations, contributing to a greener and more resilient future. T2 - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025) CY - Madrid, Spain DA - 03.06.2025 KW - Poly(limonene carbonate) KW - Sustainability KW - Halogen free flame retardants PY - 2025 AN - OPUS4-63397 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sałasińska, K. T1 - Bio-sourced Flame Retardant System for Engineering Plastics N2 - Main message: Intumescent flame retardant degradation products react with the lignocellulose hydroxyl groups by esterification, causing enhanced effectiveness in char formation [1]. The aim of this work is to prepare polyamide 11 with lower flammability by modifying it with a plant-based flame retardant system. An innovation is the thermal modification of plant raw materials to establish bio-sourced flame-retardant systems dedicated to engineering materials. Introduction: Using plant fillers to modify engineering materials raises concerns due to too low thermal stability and problems during processing. However, substances participating in char formation, such as cellulose and lignin, have higher decomposition temperatures than the processing temperature of most engineering plastics. Appropriate preparation of lignocellulosic materials through modification by thermal methods will enable their partial decomposition in controlled conditions and eliminate components with low thermal stability. Results and Discussion: For PA11, the heat release (HRR) curve is characterized by two peaks (Fig.1), with a maximum value at the end of burning. The flame retardant systems caused the curves to flatten, which was especially visible for samples with the highest sunflower husk share. The maximum values of heat release rate (pHRR) for samples with FRs varied from 991 to 626 kW/m2 and were much lower compared to PA11 (2152 kW/m2) and MPP (1234 kW/m2). All samples with FRs ignited much earlier than the reference materials, especially compared to unmodified polymer (Tab.1). The maximum average rate of heat emission (MARHE), used to forecast flame spread, decreased compared to PA11 (maximum by 30%) and slightly to MPP. Decreases were also noted in the case of total heat emission (THE), corresponding to the total heat released at the end of flame combustion. The values range from 112 to 127, and depending on the series, an increase (SH) or decrease (SHT) with the growth of the amount of bio-based components was observed. The reduction in THE follows from incomplete combustion as an effect of char forming or reduced combustion efficiency [2]. Char formation was proved by an increase in the yield of residue , while a slight decrease in the effective heat of combustion (EHC) suggests activity in the gas phase. Smoke emission was assessed by specific extinction area (SEA). The SEA reduction was noted only for the MPP sample, and introducing sunflower husks increased the smoke released. T2 - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025) CY - Madrid, Spain DA - 03.06.2025 KW - Bio-sourced flame retardant systems KW - Engineering plastics KW - Cone calorimetry PY - 2025 AN - OPUS4-63398 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Sanchez-Olivares, G. T1 - Fire Behaviour and Viscoelasticity of Sustainable Thermoplastic Polyurethane Multicomponent Systems N2 - Main message: An interesting influence of viscoelastic properties on fire behavior of multicomponent systems based on thermoplastic polyurethane using industrial-waste leather fibers was observed. A detailed investigation on rheological properties, morphology, pyrolysis, flammability and forced flaming combustion highlighted that fire retardancy is best achieved when the multicomponent systems exhibit a predominant elastic behavior. Introduction: Multicomponent systems represent a sustainable alternative to traditional high-loaded flame retardant polymer materials, particularly in local areas where industrial-waste fibers are a problem.The final properties of those systems greatly depend on the melt blending process [1-2]. In this work,thermoplastic polyurethane multicomponent systems using industrial-waste leather fibers and a commercial flame-retardant additive were produced and investigated. Results and Discussion: According to rheological measurements, the viscoelastic behavior of the TPU multicomponent systems depends on the melt blending process conditions. Systems produced under low blending temperature profile and high rotational speed (TPU/5LF/5APP_T1/V3) display a predominant viscous behavior, meanwhile TPU/5LF/5APP_T1/V1 and TPU/5LF/5APP_T2/V2 samples, exhibit a more elastic one. The combination of LF and APP at low loadings (5 phr each) results in an important reduction on the peak of heat release rate (pHRR), total heat evolved (THE) and total smoke production (TSP) regarding to pure TPU. The UL94 vertical test pointed out that multicomponent systems with predominant elastic behavior (TPU/5LF/5APP_T1/V1 and TPU/5LF/5APP_T2/V2 samples) reached the V-0 rating, meanwhile for the system with the most viscous tendency (TPU/5LF/5APP_T1/V3), non-rating is obtained. Acknowledgement: Part of this work was funded by the Consejo Nacional de Humanidades Ciencias y Tecnologías (CONAHCYT), Mexico, grant number CF-2023-I-865. T2 - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025) CY - Madrid, Spain DA - 03.06.2025 KW - TPU KW - Fire behavior KW - Viscoelastic properties KW - Leather fibers KW - Industrial wastes PY - 2025 AN - OPUS4-63400 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dudziak, Mateusz T1 - Synergistic effect of commercial and natural flame retardants in polylactide biocomposites N2 - Main message: We propose a combination of natural biomass from algae species Desmodesmus sp.along with commercially available flame retardant Melapur200 (melamine polyphosphate) in different mass ratios. We have successfully demonstrated that the use of both of them in PLA matrix biocomposites shows a synergistic flame retardant effect. Introduction: Poly(lactic acid) (PLA), a biodegradable polymer produced from renewable resources such as corn starch and sugarcane, is increasingly being used as a substitute for traditional petrochemical-based polymers in various commercial applications. However, its flammability characteristics need improvement to enable its use as a technical polymer. Based on previous successful experiments on PLA biocomposites with phosphor-enriched algae as filler [1], it was even mandatory to continue with enhancement of PLA flame retardancy. Therefore, tests for PLA biocomposites with P-algae containing melamine polyphosphate at different mass ratios were performed. Pyrolysis, reaction to small fire and fire behavior tests were carried out. Results and Discussion: Thermal stability analyses showed that all composites decompose earlier at lower temperature than pure PLA to a small extent. The evolved gases analysis revealed the release of ammonia and phosphates for the composites tested. PCFC analysis showed the greatest decrease in pHRR for the sample containing Melapur200/Algae (Figure 1A). Similarly, in the fire behaviour analysis, the best result was obtained for the sample containing a mixture of Melapur200 and Algae (Figure 1B). Satisfying results were obtained in the tests of reaction to small flame, where all the samples passed the classification from V-2 to V-0 (in the UL 94 test) and the oxygen index for the best sample was 27.4 +- 0.2%. When only Melapur200 or algae are added separately, a slight flame retardant effect is visible, however if both materials are added in suitable mixtures to the polymer, a synergistic effect is observable. In some cases, it can even be observed that the synergistic effect has surpassed expectations from the superposition. In conclusion, the combination of Melapur200 together with microalgae gives satisfying flame retardant effects for PLA biocomposites. Acknowledgement: The authors thank Dr. Georgios Mourgas (Tecnaro GmbH), and Dr. Michael Schweizer (Tecnaro GmbH) for their contributions to conceptualizing the project, raising the grant, and supporting this work. Thanks to Dr. Robert Gleuwitz (formerly of the BAM), Dr. Claudia Thomsen (iSeaMC GmbH) and Prof. Dr. Laurenz Thomsen (formerly of Jacobs University Bremen, now University of Gothenburg), Thanks to the financial support of the Bundesministerium für Bildung und Forschung – BMBF: KMU-innovativ: Biooekonomie 031B1289B T2 - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025) CY - Madrid, Spain DA - 03.06.2025 KW - Polylactide KW - Melamine polyphosphate KW - Microalgae KW - Synergism PY - 2025 AN - OPUS4-63399 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Chacon Castro, Jose P. T1 - Flame retardant poly(limonene carbonate): material innovation as a game changer N2 - The global plastic industry relies on fossil-based materials, presenting significant environmental challenges. Poly(limonene carbonate) (PLimC), a sustainable alternative, is made from two renewable monomers: limonene oxide, derived from non-food sources, and CO₂, positioning it as a promising material for applications requiring flame retardants (FRs) to meet fire safety standards. Thermal properties were initially assessed to better understand the thermal stability and fire behavior of PLimC. This analysis builds on PLimC's unique structural characteristics: its carbonate group resembling polycarbonate (PC) and its aliphatic limonene-derived segment resembling polyolefins (PO). The initial results revealed similarities to both PO and PC, prompting the evaluation of various commercially available flame retardants (FRs) at standard market concentrations. Four halogen-free FR systems were chosen for evaluation, with the conclusion that ATH proved to be the most effective FR, decreasing the heat release rate and the total heat evolved. With these results, we understood that the FRs commonly used with polyolefins (at concentrations standard in the industry) exhibit similar behavior in terms of flammability and flame retardancy when applied to PLimC. While ATH has proven to be an effective FR for PLimC, we aim to investigate bio-based alternatives to further improve the material's sustainability. Phytic acid salts and lignin have shown excellent FR performance in PO, and we believe these compounds could achieve similar success in our system. Their integration could bring us closer to achieving a fully sustainable material that aligns with current environmental goals. T2 - EPF European Polymer Congress 2025 CY - Groningen, Netherlands DA - 22.06.2025 KW - Poly(limonene carbonate) KW - Sustainability KW - Flame retardancy KW - CO2 as monomer KW - Fire Behavior PY - 2025 AN - OPUS4-63668 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Romero-Navarrete, José A. A1 - Otremba, Frank A1 - Lozano Guzman, A. A. T1 - Estimation of the effect of the driving style on pollutants emission by heavy trucks N2 - Different approaches have been attempted so far to reduce fuel consumption and linked pollutants, including vehicle equipment and design, with rational driving style being recognized as a potential source of fuel savings. However, no specific methodology had been suggested so far to assess fuel economy of driving other than the fuel consumed itself. In this paper, the Standard deviation of driving acceleration has been found to be directly associated to fuel consumption, so that the less dispersion of the driving acceleration, produces the lower fuel consumptions and emissions. Such metric could be thus used to assess driving style. KW - Driving style KW - Fuel consumption KW - Stored energy KW - GPS data KW - Simulation KW - Particle emissions PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-511540 UR - https://www.iaras.org/iaras/home/caijes/estimation-of-the-effect-of-the-driving-style-on-pollutants-emission-by-heavy-trucks SN - 2367-8941 VL - 5 SP - 220 EP - 226 PB - IARAS CY - Sofia AN - OPUS4-51154 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Romero-Navarrete, José A. A1 - Otremba, Frank T1 - A method to assess the gravity response efficiency of a truck N2 - In spite that transport activities do not represent the biggest contributor of pollutants emissions, their reduction has been a priority as some other externalities are associated to such emissions and to the transport itself. A crucial element to characterize the behavior of the vehicles against the environment are the losses that such vehicles exhibit in a passive way, that is, without any involvement of power conditions. The energy loses due to the rolling, the drag and to the friction in mechanical components, have been assessed so far in terms of the stopping acceleration when the vehicle idles on a ramp. However, such a testing procedure produces some uncertainties due to the dynamic conditions that are considered. To avoid such critical limitations, in this paper a testing procedure and facility are proposed, which are based on static conditions of the vehicle at the initiation and at the ending of the test, which are assumed to provide a better reliability to the testing. Some preliminary theoretical analysis should be made in order to validate the operational principles proposed herein for such testing facility. KW - Road tankers KW - Energy efficiency KW - Environmental assessment KW - Gravity response KW - Transportation energy KW - Rolling resistance KW - Drag resistance PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-511530 UR - https://www.iaras.org/iaras/home/caijes/a-method-to-assess-the-gravity-response-efficiency-of-a-truck SN - 2367-8941 VL - 5 SP - 213 EP - 219 PB - IARAS CY - Sofia AN - OPUS4-51153 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hurtado-Hurtado, G. A1 - Morales-Velazquez, L. A1 - Valtierra-Rodríguez, M. A1 - Otremba, Frank A1 - Jáuregui-Correa, J. C. T1 - Frequency Analysis of the Railway Track under Loads Caused by the Hunting Phenomenon N2 - Hunting is a potentially dangerous phenomenon related to the lateral oscillation of the wheels that impacts the rails and causes the wear of the infrastructure’s components. Therefore, the analysis and timely detection of hunting can lead to the application of corrective maintenance tasks, reducing damages, and costs and even derailments as a result. In this work, the vibration response of a finite element model of a rail with hunting-induced loads by a single wheel is analyzed in three directions: longitudinal, lateral, and vertical. The contact patch forces are calculated by means of Simpack® using the Kalker linear theory and the contact Hertz theory. The system is solved by using the Newmark-_ approach. The results of the deflection and vibration analysis, following the proposed methodology, show how the different characteristics of the loads impact the rail. KW - Continuous wavelet transform KW - Empirical mode decomposition KW - Finite element method KW - Frequency analysis KW - Hunting phenomenon KW - Mechanical modelling KW - Rail vibrations PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-551517 UR - https://www.mdpi.com/2227-7390/10/13/2286/htm# DO - https://doi.org/10.3390/math10132286 VL - 10 IS - 13 SP - 1 EP - 17 PB - MDPI AN - OPUS4-55151 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Jauregui-Correa, J. C. A1 - Morales-Velazquez, L. A1 - Otremba, Frank A1 - Hurtado-Hurtado, G. T1 - Method for predicting dynamic loads for a health monitoring system for subway tracks N2 - This paper presents a method for processing acceleration data registered on a train and determining the health condition of a subway’s substructure. The acceleration data was converted into a dynamic deformation by applying a transfer function defined using the Empirical Mode Decomposition Method. The transfer function was constructed using data produced on an experimental rig, and it was scaled to an existing subway system. The equivalent deformation improved the analysis of the dynamic loads that affect the substructure of the subway tracks because it is considered the primary load that acts on the track and substructure. The acceleration data and the estimated deformations were analyzed with the Continues Wavelet Transform. The equivalent deformation data facilitated the application of a health monitoring system and simplified the development of predictive maintenance programs for the subway or railroad operators. This method better identified cracks in the substructure than using the acceleration data. KW - Health monitoring KW - Transfer function KW - Railroad KW - Substructure failures KW - Dynamic loads PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-557480 DO - https://doi.org/10.3389/fmech.2022.858424 SN - 2297-3079 VL - 8 SP - 1 EP - 16 PB - Frontiers Media CY - Lausanne AN - OPUS4-55748 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hurtado-Hurtado, G. A1 - Morales-Velazquez, L. A1 - Otremba, Frank A1 - Jáuregui-Correa, J. C. T1 - Railcar Dynamic Response during Braking Maneuvers Based on Frequency Analysis N2 - The dynamic response of a vehicle during braking is influenced by the tangential forces developed at the wheel-rail’s contact surface. The friction coefficient affects the load transfer from the wheel’s tread to the vehicle. In this work, the vibrations of a scale-down railway vehicle are monitored during braking and their relationship with the friction coefficient between wheel and rail is found out. The vehicle is instrumented with encoders, accelerometers, and is controlled via Bluetooth. The tests are carried out with clean and friction-modified rails. The tangential forces transmitted from the wheel to the railcar’s body are visualized in time and frequency using a proposed correlation algorithm based on the outputs of the ContinuousWavelet Transform (CWT). The results demonstrate that tangential forces have a significant impact on railway vehicles under conditions of high friction coefficients and large creep values. KW - Railway vibration measurements KW - Vibration signal analysis KW - Wheel-rail tangential forces KW - Railway braking forces KW - Wheel-rail friction coefficient PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-572309 DO - https://doi.org/10.3390/app13074132 VL - 13 IS - 7 SP - 1 EP - 15 PB - MDPI AN - OPUS4-57230 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Otremba, Frank A1 - Romero-Navarrete, José A. T1 - A lowering friction treatment for railway materials N2 - A facility is proposed in this paper to apply a selective carburizing process to the lateral faces of a railways´ head, aiming to increase its carbon content and to decrease the friction coefficient in case that the flange of the railway car wheel gets in contact with the rail during turning. Such a treatment would reduce the energy that is lost during the turning maneuvers performed by the vehicle, further improving the energy efficiency of the railway car. The facility consists of a furnace, which should be set next to the rails´ hot-rolling facility, in order to use the available enthalpy. The proposed furnace is equipped with what is necessary to avoid the decarbonization of the remaining rail material, based upon batteries of oxy-acetylene burners that are installed at the bottom of the furnace, on the opposite side to the carburizing surface. An experimental facility is necessary to validate the operational principles for the equipment proposed in this paper. On the other hand, a study should also be carried out to assess the effect of any rail welding process on the carburized surfaces. KW - Transport efficiency KW - Dry friction KW - Carburizing KW - Selective carburizing KW - Decarbonization KW - Furnace design PY - 2020 DO - https://doi.org/10.5185/amlett.2020.041498 VL - 11 IS - 4 SP - 2004198 PB - IAAM - VRBI Press AN - OPUS4-50958 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Romero-Navarrete, José A. A1 - Otremba, Frank T1 - Vehicle’s components damage N2 - The failure of vehicle’s suspension components has contributed to road crashes, while their defective operation can deteriorate the fuel efficiency of the vehicles. In this context, and when compared with solid cargo transporters, the road tankers would tend to produce larger roll forces during turning, as the curved shape of the liquid cargo container, shifts upwards the centre of gravity of the cargo. With reference to a rectangular cargo container representing the solid cargo situation, the increase in the position due to elliptical and circular tank shapes, can attain a value of 17% (100% fill, circular tank). In this study, experimental results comparing the lateral load transfer due to solid and liquid cargoes, indicate that the average force increase on the vehicle’s load-receiver side due to a liquid cargo, is 4.3%. To analyse the fullscale situation of both situations, that is, the higher position of the centre of gravity and the shifting of the liquid cargo, a simplified model is developed. The outputs from such a model when subjected to realistic operating conditions (speed and turning radius), suggest that the higher position of the centre of gravity due to using a non-rectangular cargo container generates an average force increase of 4.9% on the side receiving the load transfer. The incorporation of the effect of the liquid cargo, through the simple pendulum analogy, suggests that such an average increases to 6.76%, with a maximum of 8.35% in the case of the elliptical tank at 75% fill level. It is found that the average liquid cargo effect is 5.44%, which should be compared with the 4.3% of the experiments. Road tankers components would thus have a relatively shorter load cycle life than those of the solid cargo trucks. KW - Liquid cargo KW - Load transfer KW - Roll reactions KW - Experimental modelling KW - Pendulum-analogy PY - 2020 DO - https://doi.org/10.1177/0954407020960543 VL - 235 IS - 2-3 SP - 446 EP - 454 PB - Sage Journals AN - OPUS4-51386 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Romero-Navarrete, José A. A1 - Otremba, Frank A1 - Hurtado-Hurtado, G. ED - Romero-Navarrete, José A. T1 - A Conceptual Design of a Self-Centering Centre Plate N2 - Turning maneuvers originate higher forces exerted on the rail and the loss of locomotive energy, at a rate that is function of several parameters that influence the magnitude of the developed horizontal wheel-rail forces, including the friction at the centre plate and the bogie´s yaw stiffness. However, such a friction at the contact surfaces of the centre plate is needed to mitigate the Hunting phenomenon when the train moves on straight track segments. In this paper, a self-centering centre plate is proposed, consisting of a lubricated centre plate, equipped with a spring- and damper-based self-centering mechanism. Simulation results of the proposed mechanism suggest that the energy performance in turns of a train car equipped with such self-centering centre plate is comparatively better, as the peak friction forces linked to the dry friction at the contact surfaces of current centre plate designs, are avoided. The assessment of the hunting performance of the proposed device in straight track segments is proposed as the continuation of this work. KW - Bogie´s yaw stiffness KW - Bogie´s yaw friction KW - Centre plate KW - Self-centering mechanism KW - Turning PY - 2020 UR - https://publications.waset.org/aerospace-and-mechanical-engineering SN - 1307-6892 VL - 14 IS - 9 SP - 376 EP - 382 AN - OPUS4-51241 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. A1 - Otremba, Frank A1 - Sklorz, Christian A1 - Martínez Madrid, M. T1 - Quasistatic rollover threshold of atmospheric road tankers N2 - Several geometrical analytical tools can be used for assessing the potential benefits of any alternative tank shape. The quasistatic evaluation of the cargo-vehicle behavior represents a fast way to objectively determine the roll stability benefits of any potentially new tank shape. In this paper, the geometrical, quasistatic rollover performance of a convex bottom tank shape is compared with that of standard tank shapes, finding that in spite of the lower position of the cargo´s center of gravity in such a tank shape for the un-perturbed condition, it has the same performance as the elliptical tank shape when subjected to Steady lateral acceleration. That as a result of the large cargo´s lateral displacement. Consequently, the combination of a lower center of gravity for the cargo when it is not perturbed, and a Minimum lateral shift due to lateral accelerations inputs, define the conditions for an ideal tank shape. T2 - CONIIN 2020 CY - Online meeting DA - 28.09.2020 KW - Tank shape KW - Road tankers KW - Center of gravity shifting KW - Quasistatic KW - Convex bottom KW - Geometrical analysis PY - 2020 SP - 1 EP - 6 AN - OPUS4-51388 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Würsig, Andreas T1 - BLEVE Problematik - Aktueller Stand N2 - BLEVE –Boiling Liquid Expanding Vapour Explosion, ist eine Gasexplosion einer expandierenden siedenden Flüssigkeit. Diese entstehung bei geschlossenen Tankbehältern, die brennbare flüssige oder verflüssigte Substanzen enthalten. Der Gefahrguttank wird durch ein Unfallfeuer belastet. T2 - 24. Gefahrgutkongress Mecklenburg-Vorpommern CY - Technologiezentrum Warnemünde, Germany DA - 29.10.2020 KW - Bleve KW - Boiling KW - Vapour KW - Explosion PY - 2020 AN - OPUS4-51496 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. T1 - Forces on rails in turns: A review N2 - Curves represent a demanding situation for the railway materials. The different levels of effects are Bogie “Adaptation”, Centre plate Friction and Longitudinal load transfer. Besides rail damage and safety effects, the kinetic energy is lost due to turning. T2 - CONIIN CY - Online meeting DA - 28.09.2020 KW - Forces KW - Rail KW - Turns PY - 2020 AN - OPUS4-51384 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. T1 - Quasistatic rollover threshold of atmospheric road tankers N2 - On the other hand, it was found that the quasistatic rollover threshold of a circular tank, does not depend on the fill level, namely, it is only determined by the position of the support and the diameter of the tank T2 - CONIIN 2020 CY - Online meeting DA - 28.09.2020 KW - Quasistatic KW - Atmospheric KW - Road KW - Tankers PY - 2020 AN - OPUS4-51385 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. A1 - Otremba, Frank A1 - Lozano Guzmán, A. A. T1 - An energy frame of reference to assess vehicle´s physical externalities N2 - Externalities of the road transportation are multidimensional in nature and involve the road-vehicle interaction under different environmental conditions. Estimating the pavement and vehicle damage potentials as a function of the condition sunder which such interaction takes place, is important to avoid accelerated or catastrophic damages in these systems. Such an assessing is crucial from the perspective of pricing the effects of the vehicle on the infrastructure and vice versa. The existing models for pricing such interaction, critically depends on gross average statistical models. In this paper, it is proposed a deterministic approach to realize such an assessment, based upon validated approaches for the pavement damage. The simulation scheme considers different degrees-of-freedom vehicle models, and a discrete asphalt pavement, that make possible the simulation of massive traffic situations on realistic road lengths. T2 - IMECE 2020 CY - Online meeting DA - 16.11.2020 KW - Energy KW - Frame KW - Assess KW - Vehicles PY - 2020 SP - 1 EP - 9 AN - OPUS4-51645 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krentel, Daniel T1 - Einsatz von Messtechnik bei Großversuchen N2 - Vortrag über den Einsatz von Messtechnik bei Großversuchen auf dem BAM TTS im Rahmen des Projektes CoFi-ABV T2 - Öffentlicher Vortrag im Rahmen der Lehrveranstaltung "Experimentelle Methoden der Aerodynamik", TU Berlin CY - Online meeting DA - 12.01.2021 KW - Alternative Antriebe KW - Behälterversagen KW - Fahrzeugbrand KW - Großversuch KW - Messtechnik PY - 2021 AN - OPUS4-52011 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krentel, Daniel T1 - Forschungsauftrag CNG- und LPG-Behälter: Gasbehälter bei Unterfeuerung N2 - Die BAM hat umfangreiche Versuchsreihen zur Auswirkungsbetrach-tung beim Versagen von Gasbehältern für alternative Treibstoffe (LPG, CNG) für PKW aufgrund unfallbedingter Brände durchgeführt. Im Rahmen des Vortrags werden die für Einsatzkräfte relevanten Ergebnisse zusammengefasst und vorgestellt. T2 - Symposium Technische Hilfeleistung im Rahmen der Messe FLORIAN CY - Online meeting DA - 08.10.2020 KW - Behälterversagen KW - Feuerwehr KW - LPG KW - CNG KW - Alternative Antriebe PY - 2020 AN - OPUS4-51411 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krentel, Daniel T1 - Einsatz von Messtechnik bei Großversuchen N2 - Vortrag über den Einsatz von Messtechnik bei Großversuchen auf dem BAM TTS im Rahmen des Projektes CoFi-ABV T2 - Öffentlicher Vortrag im Rahmen der Lehrveranstaltung "Experimentelle Methoden der Aerodynamik" (Fachgebiet Aerodynamik, Institut für Luft- und Raumfahrt, TU Berlin) CY - Berlin, Germany DA - 23.11.2021 KW - alternative Antriebe KW - Behälterversagen KW - Fahrzeugbrand KW - Großversuch KW - Auswirkungsbetrachtung PY - 2021 AN - OPUS4-53814 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tschirschwitz, Rico A1 - Krentel, Daniel A1 - Kluge, Martin T1 - Druckgasbehälter im Feuer - Auswirkungen im Versagensfall N2 - Es wurden insgesamt 57 Einzelversuche zum Versagen von Druckgasbehältern durchgeführt. Untersucht wurden dabei 11-kg-Propangasflaschen, PKW-Radmuldentanks für LPG sowie CNG-Tanks vom Typ III (Compositetanks mit Aluminiumliner) und Typ IV (Compositetanks mit Polymerliner). Mit 18 hydraulischen Berstversuchen wurde das Versagensverhalten unter kalten Bedingungen charakterisiert. In 39 Unterfeuerungsversuchen mit den gefüllten LPG- und CNG-Tanks, davon 36 mit Tanks ohne Sicherheitseinrichtung, wurde das Behälterversagen durch Brandbeaufschlagung untersucht. Neben verschiedenen Behältermanteltemperaturen und dem Behälterinnendruck wurde auch die Temperatur des gespeicherten Mediums dokumentiert. Dadurch war es möglich, genau zu dokumen-tieren, unter welchen Bedingungen und bei welchem Zustand der Behälter versagt hat. In einem Großteil der Unterfeuerungsversuche mit Behältern ohne Sicherheitseinrichtungen kam es zur Bildung eines Feuerballs, einer massiven Druck- und Temperaturwirkung auf den Nahbereich sowie einer Vielzahl von Fragmenten im Nah- und Fernbereich. In einer Entfernung von l = 7 m wurden Überdrücke von bis zu p = 0,41 bar gemessen. In 30 Unterfeuerungsversuchen kam es zur Fragmentierung des Behälters. Dabei konnten 159 Fragmente mit Wurfweite und Masse dokumentiert werden. Die dabei maximal festgestellte Wurfweite eines Fragments lag bei l = 311 m. T2 - 15. BAM-PTB-Kolloquium zur chemischen und physikalischen Sicherheitstechnik CY - Brunswick, Germany DA - 21.05.2019 KW - Behälterversagen KW - Druckgasbehälter KW - Propan KW - LPG KW - CNG PY - 2020 DO - https://doi.org/10.7795/310.20200199 SN - 0030-834X VL - 130 IS - 1 SP - 55 EP - 70 AN - OPUS4-50570 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neugum, Tim T1 - Fire tests on HPC columns with and without restraint N2 - Usually, the fire resistance of load-bearing structural elements is determined based on testing of separate members. In this test method, a mechanical load is applied to the member in a force-controlled manner and is held constant throughout the fire test. After applying the mechanical load, the thermal exposure begins according to the ISO 834 fire curve. In this conventional test method, no interaction between the member and the entire building structure is considered. In buildings, the surrounding structure can restrain the thermal expansion of a member in case of fire. This may have both positive and negative effects on the fire resistance of this structural element. T2 - CrossFire – Advanced Structural Fire Engineering at intersections among disciplines CY - Como, Italy DA - 26.05.2025 KW - Substructure method KW - Structural interaction KW - Fire resistance KW - Column KW - Concrete PY - 2025 AN - OPUS4-63351 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eiz Eddin, Ahmad T1 - Fire induced spalling behaviour of CFRP-reinforced concrete N2 - Fire tests on CFRP-reinforced concrete elements without and with various protection measures to prevent spalling are presented. The protection measures include the application of an intumescent coating to the fire exposed surface as well as the use of a modified concrete mixture containing polypropylene fibres (PP-fibres). T2 - CrossFire School CY - Como, Italy DA - 26.05.2025 KW - Concrete spalling KW - CFRP KW - Polypropylene fibres KW - Intumescent coating PY - 2025 AN - OPUS4-63349 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krentel, Daniel T1 - Einsatz von Messtechnik bei Großversuchen N2 - Im Rahmen dieses Vortrags werden die Besonderheiten beim Einsatz von Messtechnik bei Versuchen im Groß- und Realmaßstab und unter Freifeldbedingungen dargestellt. Anhand des Themenfeldprojektes CoFi-ABV und der dort durchgeführten Versuchsreihen werden die Rand- und Rahmenbedingungen beim Durchführen der Experimente, Instrumentierung und Versuchsaufbau sowie beispielhafte Ergebnisse erläutert. T2 - Lehrveranstaltung "Experimentelle Methoden der Aerodynamik" an der TU Berlin CY - Berlin, Germany DA - 24.01.2023 KW - Alternative Antriebe KW - Behälterversagen KW - Fahrzeugbrand KW - Großversuch KW - Auswirkungsbetrachtung PY - 2023 AN - OPUS4-56951 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Würsig, Andreas A1 - Otremba, Frank T1 - Neue FVK-Tanks in den Unmodellvorschriften sowie Ergebnisse aktueller Forschungsvorhaben N2 - 100 mm of PUR-foam give satisfying results in terms of thermal properties. The non-pressure testing methods gives reliable and repeatable results. Bending modulus of laminates does not change until the first damage occurs. After that, the bending modulus decreases by 50 % but max. stress is still higher than at room temperature. T2 - 25. Gefahrgutkongress MV CY - Rostock, Germany DA - 19.10.2021 KW - FVK-Tanks KW - Unmodellvorschriften KW - Forschungsvorhaben PY - 2021 AN - OPUS4-53570 LA - mul AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Werner, Jan A1 - Kutz, P. W. A1 - Otremba, Frank T1 - Testing of Small Scale Tank Prototypes under Cryogenic Conditions N2 - Climate change, CO2 reduction, resource efficiency are only 3 current keywords that describe the current industrial-economic situation. In order to influence climate change effectively, the conversion of supply systems with technically usable forms of energy must succeed in the next decade. The international network founded in Baku in 2015 bundles research activities in the broad field of energy supply and energy efficiency. Discuss current research approaches and results with scientists and experts from renowned universities and follow Azerbaijan's efforts to implement the energy revolution. T2 - Neseff 2020 CY - Online meeting DA - 28.09.2020 KW - Mud pumps KW - Mud circulation system KW - Pistons KW - Hydrostatic pressure KW - Friction wear KW - Ceramic liners KW - Tribology PY - 2020 SN - 978-3-940471-59-8 SP - 4 EP - 9 AN - OPUS4-52149 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Prabhakaran, Anand T1 - Characterizing the Performance of Tank Car Pressure Relief Devices Under Derailment Fire Conditions – Flammable Fuel Tests N2 - Evaluate tank car PRV behavior under realistic fire conditions Subject 1/3 scale tank with full size PRV to engulfing pool fire Initial tests with water lading. Current tests with flammable lading (Ethanol). Document PRV performance with respect to opening pressure, reclosing, and evacuating the tank T2 - Joint Railways Conference CY - Online meeting DA - 20.04.2021 KW - PRV KW - Flammable lading KW - Vessel KW - Pool fire PY - 2021 AN - OPUS4-52799 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Jauregui-Correa, J. C. A1 - Otremba, Frank A1 - Romero-Navarrete, José A. A1 - Hurtado-Hurtado, G. T1 - Determination of the effect of sloshing on the railcar-track dynamic behavior N2 - Liquid cargo has a significant impact on the interface wheel-track interaction. The sloshing affects the track-railcar's dynamic behavior. The effect is detectable at the track level and at the vehicle. Its characterization requires the combination of different techniques: Empirical Mode Decomposition (EMD) Time-Frequency Maps Sloshing occurred when significant perturbations happened in the railcar: The railcar entered a curve Reduction in its travel speed A railcar with a tank is a clear example of a multibody dynamic system with a nonlinear behavior. T2 - 7th International Symposium on Multibody Systems and Mechatronics - MuSMe 2021 CY - Córdoba, Argentina DA - 12.10.2021 KW - Liquid cargo KW - Wheel-track interaction KW - Sloshing affects KW - Vehicle PY - 2021 AN - OPUS4-53572 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero-Navarrete, José A. T1 - A testing facility to assess railway car infrastructure damage N2 - A testing device and respective procedure have been proposed to assess the railway damage potentials of the railway cars The operational principles of the device consist of simple physical phenomena. Outputs from a preliminary test suggest that the device could have a good sensitivity. T2 - COMPRAIL 2020 - 17th International Conference on Railway Engineering Design & Operation 2020 CY - Online meeting DA - 01.07.2020 KW - Wheel rail forces KW - Friction PY - 2020 AN - OPUS4-51127 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Romero Navarrete, Jose Antonio T1 - Experimental methods for road tankers. A critical review (IMECE2020-23069) N2 - Still experimental modelling is necessary to assess the effects of all of the influential factors. T2 - IMECE 2020 CY - Online meeting DA - 16.11.2020 KW - Road KW - Tanker KW - Methods PY - 2020 AN - OPUS4-51638 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Otremba, Frank A1 - Romero-Navarrete, José A. A1 - Jáuregui Correa, J.C.A. T1 - Forces on rails in turns: A review N2 - Regardless of the mode of transportation, directional changes generate greater forces on the infrastructure as a result of the lateral load transfer and of the respective steering forces in the vehicles. In the case of Railway transportation, a concentrated damage occurs in the rail at the initiation of the turning maneuver, whose magnitude depends on the bogie´s yaw stiffness and on the level of friction at its centre plate. To mitigate such rail-damaging effects, some new designs have been proposed and used for the bogies´ wheelset. However, no new designs for the centre plate have been used. In this paper, a review of the causality for the forces arising during Railway Vehicle's turn negotiations, is presented, including the description of a modeling framework to analyze the influential Parameters for determining the magnitude of such forces. T2 - CONIIN 2020 CY - Online meeting DA - 28.09.2020 KW - Turning maneuvers KW - Rail damage KW - Yaw stiffness KW - Yaw resistance KW - Self-aligning bogies KW - Lateral load transfer KW - Steering forces PY - 2020 SP - 1 EP - 6 AN - OPUS4-51390 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bradley, Ian A1 - Scarponi, G. E. A1 - Otremba, Frank A1 - Birk, A. M. T1 - An overview of test standards and regulations relevant to the fire testing of pressure vessels N2 - Fire exposure of storage and transportation vessels of hazardous materials (including pressure liquefied gases) can result in BLEVEs and other high-consequence incidents with large societal and economic impacts. To reduce risk most countries have numerous regulations, codes of practice and guidance notes covering the design, operation and maintenance of vessels and thermal protection systems. Yet despite such regulations there remains no internationally accepted fire test procedure for pressure vessel and accompanying thermal protection systems that is capable of meeting a range of regulatory requirements. This paper considers some of the regulations in place in the western world and considers the origin of these based on large and medium-scale testing conducted to date. It examines conditions found in these tests to propose a set of recommendations on which to base a standard method of test. These recommendations are proposed as being representative of a credible large pool fire scenario that may occur. KW - LPG KW - Pressure vessel KW - Test KW - BLEVE KW - Fire PY - 2021 DO - https://doi.org/10.1016/j.psep.2020.07.047 SN - 0957-5820 VL - 145 SP - 150 EP - 156 PB - Elsevier CY - Amsterdam AN - OPUS4-51139 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -