TY - CHAP A1 - Hofmann-Böllinghaus, Anja ED - Vogdt, F. U. T1 - Brandschutz N2 - Grundlagen des vorbeugenden baulichen Brandschutzes KW - Brandprüfungen KW - Bauvorschriften PY - 2022 SN - 978-3-8348-2189-8 SP - 199 EP - 220 PB - Springer ET - 1 AN - OPUS4-54317 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kazlagic, Anera A1 - Russo, Francesco A1 - Vogl, Jochen A1 - Sturm, Patrick A1 - Stephan, D. A1 - Gluth, Gregor ED - Resch-Genger, Ute ED - Koch, Matthias ED - Meermann, Björn ED - Weller, Michael G. T1 - Development of a sample preparation procedure for Sr isotope analysis of Portland cements N2 - The 87Sr/86Sr isotope ratio can, in principle, be used for provenancing of cement. However, while commercial cements consist of multiple components, no detailed investigation into their individual 87Sr/86Sr isotope ratios or their influence on the integral 87Sr/86Sr isotope ratio of the resulting cement was conducted previously. Therefore, the present study aimed at determining and comparing the conventional 87Sr/86Sr isotope ratios of a diverse set of Portland cements and their corresponding Portland clinkers, the major component of these cements. Two approaches to remove the additives from the cements, i.e. to measure the conventional 87Sr/86Sr isotopic fingerprint of the clinker only, were tested, namely, treatment with a potassium hydroxide/sucrose solution and sieving on a 11-µm sieve. Dissolution in concentrated hydrochloric acid/nitric acid and in diluted nitric acid was employed to determine the 87Sr/86Sr isotope ratios of the cements and the individual clinkers. The aim was to find the most appropriate sample preparation procedure for cement provenancing, and the selection was realised by comparing the 87Sr/86Sr isotope ratios of differently treated cements with those of the corresponding clinkers. None of the methods to separate the clinkers from the cements proved to be satisfactory. However, it was found that the 87Sr/86Sr isotope ratios of clinker and cement generally corresponded, meaning that the latter can be used as a proxy for the clinker 87Sr/86Sr isotope ratio. Finally, the concentrated hydrochloric acid/nitric acid dissolution method was found to be the most suitable sample preparation method for the cements; it is thus recommended for 87Sr/86Sr isotope analyses for cement provenancing. KW - Cement KW - Provenancing KW - Sr isotopes KW - Portland clinker KW - Dissolution PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-542239 DO - https://doi.org/10.1007/s00216-021-03821-7 SN - 1618-2642 SN - 1618-2650 VL - 414 IS - 15 (Topical collection: Analytical methods and applications in the materials and life sciences) SP - 4379 EP - 4389 PB - Springer CY - Berlin AN - OPUS4-54223 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Simon, Patrick A1 - Helmrich, M. A1 - Herrmann, Ralf A1 - Schneider, Ronald A1 - Baeßler, Matthias A1 - Lorelli, S. A1 - Morgenthal, G. T1 - Maintalbrücke Gemünden: Bauwerksmonitoring und -identifikation aus einem Guss T1 - Maintalbrücke Gemünden – Integrated structural health monitoring and UAS diagnostics N2 - Die Infrastruktursysteme der Industriestaaten erfordern heute und in Zukunft ein effizientes Management bei alternder Bausubstanz, steigenden Lasten und gleichbleibend hohem Sicherheitsniveau. Digitale Technologien bieten ein großes Potenzial zur Bewältigung der aktuellen und künftigen Herausforderungen im Infrastrukturmanagement. Im BMBF-geförderten Projekt Bewertung alternder Infrastrukturbauwerke mit digitalen Technologien (AISTEC) wird untersucht, wie unterschiedliche Technologien und deren Verknüpfung gewinnbringend eingesetzt werden können. Am Beispiel der Maintalbrücke Gemünden werden ein sensorbasiertes Bauwerksmonitoring, bildbasierte Inspektion mit durch Kameras ausgestatteten Drohnen (UAS) und die Verknüpfung digitaler Bauwerksmodelle umgesetzt. Die aufgenommenen Bilder dienen u. a. als Grundlage für spätere visuelle Anomaliedetektionen und eine 3D-Rekonstruktion, welche wiederum für die Kalibrierung und Aktualisierung digitaler Tragwerksmodelle genutzt werden. Kontinuierlich erfasste Sensordaten werden ebenfalls zur Kalibrierung und Aktualisierung der Tragwerksmodelle herangezogen. Diese Modelle werden als Grundlage für Anomaliedetektionen und perspektivisch zur Umsetzung von Konzepten der prädiktiven Instandhaltung verwendet. Belastungsfahrten und historische Daten dienen in diesem Beitrag der Validierung von kalibrierten Tragwerksmodellen. N2 - Infrastructure systems of industrialised countries today and in the future require efficient management with an ageing stock, increasing loads while simultaneously maintaining a high level of safety. Digital technologies offer great potential for the current and future challenges in infrastructure management. The BMBF-funded project AISTEC is investigating how the individual technologies and their interconnection can be used beneficially. With the Maintalbrücke in Gemünden as an exemplary application, sensor-based structural monitoring, image-based inspection using unmanned aircraft systems (UAS) equipped with cameras and the integration of digital structural models are being implemented. The recorded images serve, among others, as basis for subsequent anomaly detection and a 3D reconstruction, which in turn are used for updating digital structural models. Continuously recorded sensor data is used to update the parameters of the structural models, which in turn provide the basis for predictive maintenance. Load tests are used to validate the models. KW - Bauwerksüberwachung KW - Strukturmonitoring KW - Structural Health Monitoring KW - Modell-Update KW - UAS KW - Belastungstest KW - Structural system identification KW - Structural health monitoring KW - Model update KW - UAS KW - Load tests PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-554924 DO - https://doi.org/10.1002/bate.202100102 SN - 0932-8351 VL - 99 IS - 3 SP - 163 EP - 172 PB - Ernst & Sohn CY - Berlin AN - OPUS4-55492 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mendler, A. A1 - Döhler, M. A1 - Hille, Falk T1 - Detecting changes in boundary conditions based on sensitivity-based statistical tests N2 - Structural health monitoring is a promising technology to automatically detect structural changes based on permanently installed sensors. Vibration-based methods that evaluate the global system response to ambient excitation are suited to diagnose changes in boundary conditions, i.e., changes in member prestress or imposed displacements. In this paper, these changes are evaluated based on sensitivity-based statistical tests, which are capable of detecting and localizing parametric structural changes. The main contribution is the analytical calculation of sensitivity vectors for changes in boundary conditions (i.e., changes in prestress or support conditions) based on stress stiffening, and the combination with a numerically efficient algorithm, i.e., Nelson’s method. One of the main advantages of the employed damage diagnosis algorithm is that, although it uses physical models for damage detection, it considers the uncertainty in the data-driven features, which enables a reliabilitybased approach to determine the probability of detection. Moreover, the algorithm can be trained and the probability of detecting future damages can be predicted based on data and a model from the undamaged structure, in an unsupervised learning mode, making it particularly relevant for unique structures, where no data from the damaged state is available. For proof of concept, a numerical case study is presented. The study assesses the loss of prestress in a two-span reinforced concrete beam and showcases suitable validation approaches for the sensitivity calculation. T2 - International Symposium on Non-Destructive Testing in Civil Engineering (NDT-CE 2022) CY - Zurich, Switzerland DA - 16.08.2022 KW - Nelson’s method KW - Global ambient vibrations KW - Asymptotic local approach KW - Sensitivity vectors KW - Probability of detection KW - Stress stiffening PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-566632 DO - https://doi.org/10.58286/27311 SN - 1435-4934 VL - 27 IS - 9 SP - 1 EP - 13 PB - NDT.net CY - Kirchwald AN - OPUS4-56663 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst A1 - Hille, Falk A1 - Hofmann, Detlev A1 - Kind, Thomas T1 - Überwachung der Brücke Altstädter Bahnhof, Branden-burg./H. N2 - Die B1 Brücke am Altstädter Bahnhof in Brandenburg an der Havel wurde im Dezember 2019 aufgrund von während einer turnusmäßigen Inspektion entdeckten Rissen und Hohlstellen entlang der vorgespannten Längsträger gesperrt und im Mai 2021 abgebrochen. In der Zwischenzeit wurde die Brücke detailliert überwacht. Vor dem Abriss wurden zudem umfangreiche Untersuchungen zur Bestandsaufnahme und Schadensanalyse sowie Tests moderner Sensorik vorgenommen. Dabei konnte sowohl die richtige, zuvor nicht sicher bekannte Anzahl von Spanngliedern in den Querträgern sicher ermittelt werden als auch durch moderne Varianten der Schwingungsmessungen und der faseroptischen Sensorik zusätzliche Kenntnisse püber das Bauwerksverhalten ermittelt werden . In dem Beitrag werden die Verfahren mit ihren Möglichkeiten und Grenzen vorgestellt, die Ergebnissee an der Brücke in Brandenburg erläutert und zukünftige Einsatzmöglichkeiten diskutiert. T2 - 5. Brückenkolloquium CY - Ostfildern, Germany DA - 06.09.2022 KW - Monitoring KW - Brücke KW - Radar KW - Vibration KW - Faseroptik PY - 2022 AN - OPUS4-55628 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bender, R. A1 - Féron, D. A1 - Mills, D. A1 - Ritter, S. A1 - Bäßler, Ralph A1 - Bettge, Dirk A1 - de Graeve, I. A1 - Dugstad, A. A1 - Grassini, S. A1 - Hack, T. A1 - Halama, M. A1 - Han, E.-H. A1 - Harder, T. A1 - Hinds, G. A1 - Kittel, J. A1 - Krieg, R. A1 - Leygraf, C. A1 - Martinelli, L. A1 - Mol, A. A1 - Neff, D. A1 - Nilsson, J.-O. A1 - Odnevall, I. A1 - Paterson, S. A1 - Paul, S. A1 - Prošek, T. A1 - Raupach, M. A1 - Revilla, R. I. A1 - Ropital, F. A1 - Schweigart, H. A1 - Szala, E. A1 - Terryn, H. A1 - Tidblad, J. A1 - Virtanen, S. A1 - Volovitch, P. A1 - Watkinson, D. A1 - Wilms, M. A1 - Winning, G. A1 - Zheludkevich, M. T1 - Corrosion challenges towards a sustainable society N2 - A global transition towards more sustainable, affordable and reliable energy systems is being stimulated by the Paris Agreement and the United Nation's 2030 Agenda for Sustainable Development. This poses a challenge for the corrosion industry, as building climate‐resilient energy systems and infrastructures brings with it a long‐term direction, so as a result the long‐term behaviour of structural materials (mainly metals and alloys) becomes a major prospect. With this in mind “Corrosion Challenges Towards a Sustainable Society” presents a series of cases showing the importance of corrosion protection of metals and alloys in the development of energy production to further understand the science of corrosion, and bring the need for research and the consequences of corrosion into public and political focus. This includes emphasis on the limitation of greenhouse gas emissions, on the lifetime of infrastructures, implants, cultural heritage artefacts, and a variety of other topics. KW - Corrosion KW - Corrosion costs KW - Corrosion protection KW - Preventive strategies PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-554801 DO - https://doi.org/10.1002/maco.202213140 SN - 1521-4176 VL - 73 IS - 11 SP - 1730 EP - 1751 PB - Wiley-VCH CY - Weinheim AN - OPUS4-55480 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rütters, H. A1 - Fischer, S. A1 - Le, Quynh Hoa A1 - Bettge, Dirk A1 - Bäßler, Ralph A1 - Maßmann, J. A1 - Ostertag-Henning, C. A1 - Wolf, J. L. A1 - Pumpa, M. A1 - Lubenau, U. A1 - Knauer, S. A1 - Jaeger, P. A1 - Neumann, A. A1 - Svensson, K. A1 - Pöllmann, H. A1 - Lempp, C. A1 - Menezes, F. F. A1 - Hagemann, B. T1 - Towards defining reasonable minimum composition thresholds – Impacts of variable CO2 stream compositions on transport, injection and storage N2 - To set up recommendations on how to define “reasonable minimum composition thresholds” for CO2 streams to access CO2 pipeline networks, we investigated potential impacts of CO2 streams with different and temporally variable compositions and mass flow rates along the CCS chain. All investigations were based on a generic “CCS cluster scenario” in which CO2 streams captured from a spatial cluster of eleven emitters (seven fossil-fired power plants, two cement plants, one refinery and one steel mill) are collected in a regional pipeline network. The resulting CO2 stream (19.78 Mio t impure CO2 per year) is transported in a trunk line (onshore and offshore) and injected into five generic replicate storage structures (Buntsandstein saline aquifers) offshore. Experimental investigations and modeling of selected impacts revealed beneficial as well as adverse impacts of different impurities and their combinations. Overall, no fundamental technical obstacles for transporting, injecting and storing CO2 streams of the considered variable compositions and mass flow rates were observed. We recommend to define minimum composition thresholds for each specific CCS project through limiting i) the overall CO2 content, ii) maximum contents of relevant impurities or elements, iii) acceptable variability of concentrations of critical impurities, and defining impurity combinations to be avoided. KW - Impurities KW - CO2 quality KW - Pipeline network KW - Whole-chain CCS scenario KW - Recommendations PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-543004 DO - https://doi.org/10.1016/j.ijggc.2022.103589 SN - 1750-5836 VL - 114 SP - 1 EP - 14 PB - Elsevier CY - New York, NY AN - OPUS4-54300 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Cuéllar, Pablo A1 - Geißler, Peter A1 - Baeßler, Matthias T1 - Geotechnical challenges in the field of Offshore Wind Energy. Micromechanical perspectives beyond the FEM N2 - This talk provides a brief overview on some geomechanical phenomena and problematic issues in the field of offshore wind-energy geotechnics, with reference to their associated challenges for a numerical analysis/simulation. These may include large deformations, fluid coupling and grain-scale phenomena, all of which are generally difficult to be addressed with conventional FE techniques. These challenges are illustrated here with a practical example for the retrofit of axially loaded piles using compaction grouting techniques. In this case, the mechanical effects of the retrofit may be analysed with standard FE techniques, but require the adoption of strong assumptions, while the injection process itself can only be analysed with special techniques such as the MPM. Finally, an LBM-DEM framework for the micromechanical analysis of such problems is introduced and a practical application for the estimation of the soil resistance to driving (SRD) in layered profiles is discussed. T2 - Online Symposium on Meshfree models for Engineers: Where are they really worthwhile? CY - Online meeting DA - 01.12.2022 KW - Offshore wind energy KW - Offshore geotechnics KW - Micromechanical simulation KW - LBM-DEM KW - Pile retrofit system PY - 2022 AN - OPUS4-56450 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Viefhues, Eva A1 - Döhler, M. A1 - Hille, Falk A1 - Mevel, L. T1 - Statistical subspace-based damage detection with estimated reference N2 - The statistical subspace-based damage detection technique has shown promising theoretical and practical results for vibration-based structural health monitoring. It evaluates a subspacebased residual function with efficient hypothesis testing tools, and has the ability of detecting small changes in chosen system parameters. In the residual function, a Hankel matrix of Output covariances estimated from test data is confronted to its left null space associated to a reference model. The hypothesis test takes into account the covariance of the residual for decision making. Ideally, the reference model is assumed to be perfectly known without any uncertainty, which is not a realistic assumption. In practice, the left null space is usually estimated from a reference data set to avoid model errors in the residual computation. Then, the associated uncertainties may be non-negligible, in particular when the available reference data is of limited length. In this paper, it is investigated how the statistical distribution of the residual is affected when the reference null space is estimated. The asymptotic residual distribution is derived, where its refined covariance term considers also the uncertainty related to the reference null space estimate. The associated damage detection test closes a theoretical gap for real-world applications and leads to increased robustness of the method in practice. The importance of including the estimation uncertainty of the reference null space is shown in a numerical study and on experimental data of a progressively damaged steel frame. KW - Damage detection KW - Uncertainty quantification KW - Statistical tests KW - Ambient excitation KW - Vibration measurement PY - 2022 DO - https://doi.org/10.1016/j.ymssp.2021.108241 SN - 0888-3270 VL - 164 SP - 108241 PB - Elsevier Ltd. AN - OPUS4-52998 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Küttenbaum, Stefan A1 - Maack, Stefan A1 - Taffe, A. A1 - Braml, T. ED - Sykora, M. ED - Lenner, R. ED - de Koker, N. T1 - On the Treatment of Measurement Uncertainty in Stochastic Modeling of Basic Variables N2 - The acquisition and appropriate processing of relevant information about the considered system remains a major challenge in assessment of existing structures. Both the values and the validity of computed results such as failure probabilities essentially depend on the quantity and quality of the incorporated knowledge. One source of information are onsite measurements of structural or material characteristics to be modeled as basic variables in reliability assessment. The explicit use of (quantitative) measurement results in assessment requires the quantification of the quality of the measured information, i.e., the uncertainty associated with the information acquisition and processing. This uncertainty can be referred to as measurement uncertainty. Another crucial aspect is to ensure the comparability of the measurement results.This contribution attempts to outline the necessity and the advantages of measurement uncertainty calculations in modeling of measurement data-based random variables to be included in reliability assessment. It is shown, how measured data representing time-invariant characteristics, in this case non-destructively measured inner geometrical dimensions, can be transferred into measurement results that are both comparable and quality-evaluated. The calculations are based on the rules provided in the guide to the expression of uncertainty in measurement (GUM). The GUM-framework is internationally accepted in metrology and can serve as starting point for the appropriate processing of measured data to be used in assessment. In conclusion, the effects of incorporating the non-destructively measured data into reliability analysis are presented using a prestressed concrete bridge as case-study. T2 - International Probabilistic Workshop 2022 (IPW2022) CY - Stellenbosch, South Africa DA - 09.09.2022 KW - Reliability KW - Assessment KW - Existing structures KW - Measurement uncertainty PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-556580 DO - https://doi.org/10.14311/APP.2022.36.0109 SN - 2336-5382 VL - 36 SP - 109 EP - 118 PB - Czech Technical University CY - Prague AN - OPUS4-55658 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hille, Falk A1 - Herrmann, Ralf A1 - Said, Samir A1 - Ziegler, Fred A1 - Baeßler, Matthias A1 - Wille, Frank A1 - Quercetti, Thomas A1 - Minack, Mathias A1 - Sterthaus, Jens T1 - Structural Health Monitoring am Großen Fallturm der BAM N2 - In diesem Beitrag wird die Structural Health Monitoring Kampagne am Großen Fallturm der BAM vorgestellt. T2 - Seminar "Zerstörungsfreie Prüfung" CY - Online meeting DA - 13.01.2022 KW - Belastungsversuch KW - Großer Fallturm Horstwalde KW - Schwingungsdynamik KW - Modalanalyse PY - 2022 AN - OPUS4-55478 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Le, Quynh Hoa A1 - Bäßler, Ralph A1 - Bettge, Dirk T1 - Electrochemical behaviors of casing steel/mortar interface in CO2 saturated aquifer fluid N2 - To reveal the corrosion resistance of casing steel/mortar interface in CO2 injection condition, sandwich samples were prepared and exposed up to 20 weeks in aquifer fluid under 10 MPa and 60 °C. Cross section analysis revealed the crevice corrosion as main mechanism instead of pitting corrosion, which would be expected to happen in the extremely high Chloride concentration. Detailed analysis using EDS line scan shown the slow diffusion of Chloride, suggesting why pitting did not happen after 20 weeks. To mimic the passivated steel surface, the steel coupon was passivated in simulated pore solution having pH 13.5 for 42 days. The passivated coupon was further exposed to NGB solution for 28 days. Electrochemical characterization was performed along the exposure processes to reveal the change in impedance, indicating the corrosion resistance of steel casing/mortar interface. T2 - EUROCORR 2022 CY - Berlin, Germany DA - 28.08.2022 KW - Corrosion KW - CO2 quality KW - Pipeline network KW - CCS PY - 2022 SP - 859 EP - 865 PB - European Federation of Corrosion AN - OPUS4-55622 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Patrick A1 - Herrmann, Ralf A1 - Schneider, Ronald A1 - Hille, Falk A1 - Baeßler, Matthias A1 - El-Athman, Rukeia T1 - Research Data Management of Structural Health Monitoring Projects and Subsequent Applications of Artificial Intelligence Methods N2 - Structural health monitoring (SHM) intends to improve the management of engineering structures. The number of successful SHM projects – especially SHM research projects – is ever growing, yielding added value and more scientific insight into the management of infrastructure asset. With the advent of the data age, the value of accessible data becomes increasingly evident. In SHM, many new data-centric methods are currently being developed at a high pace. A consequent application of research data management (RDM) concepts in SHM projects enables a systematic management of raw and processed data, and thus facilitates the development and application of artificial intelligence (AI) and machine learning (ML) methods to the SHM data. In this contribution, a case study based on an institutional RDM framework is presented. Data and metadata from monitoring the structural health of the Maintalbrücke Gemünden for a period of 16 months are managed with the RDM system BAM Data Store, which makes use of the openBIS data management software. An ML procedure is used to classify the data. Feature engineering, feature training and resulting data are performed and modelled in the RDM system. T2 - 11th International Conference on Bridge Maintenance, Safety and Management (IABMAS2022) CY - Barcelona, Spain DA - 11.07.2022 KW - Research data management KW - Structural health monitoring KW - Artificial intelligence PY - 2022 SN - 978-1-032-35623-5 SN - 978-1-003-32264-1 DO - https://doi.org/10.1201/9781003322641-127 SP - 1061 EP - 1068 PB - CRC Press CY - Boca Raton AN - OPUS4-55493 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Le, Quynh Hoa A1 - Bettge, Dirk T1 - Electrochemical behaviors of casing steel/mortar interface in CO2 saturated aquifer fluid N2 - To reveal the corrosion resistance of casing steel/mortar interface in CO2 injection condition, sandwich samples were prepared and exposed up to 20 weeks in aquifer fluid under 10 MPa and 60 °C. Cross section analysis revealed the crevice corrosion as main mechanism instead of pitting corrosion despite very high concentration of Cl in NGB. EDS element line scan analysis of the 20-week-exposed metal/mortar coupon showed Chloride distribution, which still not reached the metal/mortar interface, explaining no pitting was observed. It was confirmed that FeCO3 cannot protect the steel surface in CO2 saturated NGB. To verify the protective possibility of passivation happened on casing steel/mortar interface, simulated pore solution was synthesized and used to passivate the steel for 42 days. OCP and EIS confirmed the formation of passive layer. The 42 day passivated layer was broken during the first minute of exposure in CO2 saturated NGB. However, due to high concentration of Ca2+, a new carbonate CaCO3 dense layer was formed, increased the corrosion resistance of steel surface. T2 - EUROCORR 2022 CY - Berlin, Germany DA - 28.08.2022 KW - Corrosion KW - Geothermal KW - CO2 KW - Mortar PY - 2022 AN - OPUS4-55621 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hille, Falk A1 - Nerger, Deborah A1 - Moosavi, Robabeh A1 - Grunwald, Marcel T1 - Discussion on data evaluation of tomographic and numerical results N2 - The contribution discusses the processing and analysis of data generated on two different ways of investigations for impact damage in reinforced concrete structures. Damage investigations are essential to determine type and characteristics of damage and thus the residual capacity. Damage describing data is generated using two different types of investigation, a non-destructive tomographic as well as numerical examination. Subsequently, data of both sources was merged and analysed. Within the research project “Behaviour of structural components during impact load conditions caused by aircraft fuel tank collision” reinforces concrete plates were damaged by impact loading, see Hering (2020). Afterwards the damaged specimens were investigated tomographically as well as numerically using several methods and models. Aim of the presented research work was to specify an objective comparability of numerical data with experimentally determined damage patterns and based on this, to establish a quantitative damage evaluation. T2 - 26th International Conference on Structural Mechanics in Reactor Technology CY - Potsdam, Germany DA - 10.07.2022 KW - Impact damage on reinforced concrete KW - Tomographic damage evaluation KW - Numerical damage simulation PY - 2022 SP - 1 EP - 8 AN - OPUS4-55474 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Baeßler, Matthias A1 - Herrmann, Ralf A1 - Hille, Falk A1 - Wille, Frank T1 - Dynamisches Verhalten und Überwachung des Großen Fallturms der BAM in Horstwalde N2 - Falltürme sind Bauwerke, die als Versuchsanlagen sehr speziellen, impulsartigen Belastungen ausgesetzt sind. Am Fallturm auf dem Testgelände Technische Sicherheit (TTS) der BAM wurde bei Routineinspektionen eine Abnahme der strukturellen Integrität in Form von Vorspannungsverlusten in den Bolzen der Stahlverbindungen festgestellt. Um ein Verständnis für die zugrundeliegenden Trag- und Schädigungsmechanismen zu erlangen, wurde ein umfassendes Structural Health Monitoring (SHM) System geplant und am Bauwerk installiert unter Nutzung von digitalen Bauwerksmodellen. Für die Auslegung des Überwachungssystems, insbesondere aber zur Unterstützung der Untersuchung des Schädigungsprozesses, wurden Finite-Elemente-Modelle erstellt. Um sicherzustellen, dass die FE-Modelle das reale Tragwerksverhalten mit ausreichender Genauigkeit abbilden, mussten sie jedoch in Bezug auf die gemessenen Antworten des Tragwerks kalibriert werden. Der vorliegende Beitrag beschreibt experimentelle und numerische Untersuchungen zur Identifizierung des strukturellen Systems des Stahlrohrgitterturms in Vorbereitung einer Überwachungskampagne. Die Auswertung von gemessenen Schwingungen unter ambienter Anregung ermöglichte die Identifizierung der Eigenfrequenzen mehrerer globaler Schwingungsmoden des Fallturms. Zur Modellvalidierung wurde zunächst eine Sensitivitätsanalyse durchgeführt, um die Parameter mit dem größten Einfluss zu ermitteln. Anschließend wurde ein evolutionärer Algorithmus (EA) zur Optimierung nach dem Prinzip der Minimierung der Differenzen zwischen gemessenen und simulierten charakteristischen Antworten eingesetzt. Das aktualisierte Modell wurde schließlich an der dynamischen Reaktion der Turmstruktur infolge einer realen Falltest-induzierten Stoßbelastung validiert. Die Ergebnisse zeigten eine gute Übereinstimmung zwischen numerischen und experimentellen Ergebnissen. N2 - Drop test towers are structures subjected to very specific dynamic loadings. At the drop test tower at the Test Site Technical Safety (TTS) of BAM routine inspections revealed a decline of structural integrity in form of loss of pretension in bolts of structural steel connections. To get an understanding about the underlying damage mechanisms as well as to assure the structural safety in operation, a multifaceted Structural Health Monitoring (SHM) system was planned and installed at the structure with the help of digital models. For planning the monitoring system but especially for supporting the investigation of the damaging process finite element models are deployed. Though, to ensure the capability of the FE model to reproduce the real structural behavior in sufficient accuracy, it needs to be calibrated in respect to measured responses of the structure. The present contribution describes experimental and numerical investigations to identify the structural system of the steel tube lattice tower in preparation of the monitoring campaign. An ambient vibration test allowed the identification of the natural frequencies of several global vibrational modes of the drop test tower. For model updating first a sensitivity analysis is applied to identify the most influencing parameter. In succession a genetic algorithm was applied for optimization in the sense of minimization of the difference between measured and simulated characteristic responses. The updated model is finally validated on the dynamic response of the tower structure to a real drop test induced impact loading. The results showed a good agreement between numerical and experimental results though the robustness of the simulation should be improved by more sophisticated numerical modelling. T2 - 7. VDI-Fachtagung Baudynamik CY - Würzburg, Germany DA - 27.04.2022 KW - Großer Fallturm Horstwalde KW - Structural Health Monitoring KW - Belastungsversuch KW - Modalanalyse KW - Schwingungsdynamik KW - Finite Elemente Simulation PY - 2022 SN - 978-3-18-092379-6 SN - 978-3-18-102379-2 DO - https://doi.org/10.51202/9783181023792-265 SN - 0083-5560 VL - 2379 SP - 265 EP - 284 PB - VDI-Verlag CY - Düsseldorf AN - OPUS4-55472 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schneider, Ronald T1 - Überwachung von Brücken mit digitalen Methoden N2 - Brücken werden durch Inspektionen und teilweise durch Monitoring überwacht, um Daten und Informationen über den Zustand und die Einwirkungen zu sammeln. Auf deren Grundlage werden Entscheidungen hinsichtlich Maßnahmen zur Gewährleistung der Sicherheit und Verfügbarkeit getroffen. In diesem Vortrag werden die Potentiale der Digitalisierung zur Unterstützung und Verbesserung der Brückenüberwachung diskutiert. Insbesondere werden die Bereiche Datenmanagement, Brückenmodellierung und Entscheidungsfindung betrachtet. T2 - BVPI Arbeitstagung 2022 CY - Berlin, Germany DA - 16.09.2022 KW - Entscheidungsfindung KW - Brücken KW - Überwachung KW - Digitalisierung KW - Datenmanagement KW - Modellierung PY - 2022 AN - OPUS4-55770 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Baeßler, Matthias A1 - Herrmann, Ralf A1 - Hille, Falk A1 - Ziegler, Fred A1 - Said, Samir A1 - Wille, Frank A1 - Quercetti, Thomas A1 - Minack, Mathias A1 - Sterthaus, Jens T1 - Dynamisches Verhalten und Überwachung des Großen Fallturms der BAM in Horstwalde N2 - Falltürme sind Bauwerke, die als Versuchsanlagen sehr speziellen, impulsartigen Belastungen ausgesetzt sind. Am Fallturm auf dem Testgelände Technische Sicherheit (TTS) der BAM wurde bei Routineinspektionen eine Abnahme der strukturellen Integrität in Form von Vorspannungsverlusten in den Bolzen der Stahlverbindungen festgestellt. Um ein Verständnis für die zugrundeliegenden Trag- und Schädigungsmechanismen zu erlangen, wurde ein umfassendes Structural Health Monitoring (SHM) System geplant und am Bauwerk installiert unter Nutzung von digitalen Bauwerksmodellen. Für die Auslegung des Überwachungssystems, insbesondere aber zur Unterstützung der Untersuchung des Schädigungsprozesses, wurden Finite-Elemente-Modelle erstellt. Um sicherzustellen, dass die FE-Modelle das reale Tragwerksverhalten mit ausreichender Genauigkeit abbilden, mussten sie jedoch in Bezug auf die gemessenen Antworten des Tragwerks kalibriert werden. Der vorliegende Beitrag beschreibt experimentelle und numerische Untersuchungen zur Identifizierung des strukturellen Systems des Stahlrohrgitterturms in Vorbereitung einer Überwachungskampagne. Die Auswertung von gemessenen Schwingungen unter ambienter Anregung ermöglichte die Identifizierung der Eigenfrequenzen mehrerer globaler Schwingungsmoden des Fallturms. Zur Modellvalidierung wurde zunächst eine Sensitivitätsanalyse durchgeführt, um die Parameter mit dem größten Einfluss zu ermitteln. Anschließend wurde ein evolutionärer Algorithmus (EA) zur Optimierung nach dem Prinzip der Minimierung der Differenzen zwischen gemessenen und simulierten charakteristischen Antworten eingesetzt. Das aktualisierte Modell wurde schließlich an der dynamischen Reaktion der Turmstruktur infolge einer realen Falltest-induzierten Stoßbelastung validiert. Die Ergebnisse zeigten eine gute Übereinstimmung zwischen numerischen und experimentellen Ergebnissen. N2 - Drop test towers are structures subjected to very specific dynamic loadings. At the drop test tower at the Test Site Technical Safety (TTS) of BAM routine inspections revealed a decline of structural integrity in form of loss of pretension in bolts of structural steel connections. To get an understanding about the underlying damage mechanisms as well as to assure the structural safety in operation, a multifaceted Structural Health Monitoring (SHM) system was planned and installed at the structure with the help of digital models. For planning the monitoring system but especially for supporting the investigation of the damaging process finite element models are deployed. Though, to ensure the capability of the FE model to reproduce the real structural behavior in sufficient accuracy, it needs to be calibrated in respect to measured responses of the structure. The present contribution describes experimental and numerical investigations to identify the structural system of the steel tube lattice tower in preparation of the monitoring campaign. An ambient vibration test allowed the identification of the natural frequencies of several global vibrational modes of the drop test tower. For model updating first a sensitivity analysis is applied to identify the most influencing parameter. In succession a genetic algorithm was applied for optimization in the sense of minimization of the difference between measured and simulated characteristic responses. The updated model is finally validated on the dynamic response of the tower structure to a real drop test induced impact loading. The results showed a good agreement between numerical and experimental results though the robustness of the simulation should be improved by more sophisticated numerical modelling. T2 - 7. VDI-Fachtagung Baudynamik CY - Würzburg, Germany DA - 27.04.2022 KW - Großer Fallturm Horstwalde KW - Structural Health Monitoring KW - Belastungsversuch KW - Modalanalyse KW - Schwingungsdynamik KW - Finite Elemente Simulation PY - 2022 AN - OPUS4-55470 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schneider, Ronald A1 - Cuéllar, Pablo A1 - Baeßler, Matthias T1 - Probabilistic approaches to the design and assessment of offshore foundations considering spatially varying site conditions N2 - In this contribution, we consider two applications in which probabilistic approaches can potentially complement or enhance the design and assessment of offshore wind turbine foundations. First, we illustrate in a numerical example that probabilistic modelling can be helpful in dealing with chang-es in turbine locations during the planning phase of an offshore wind farm. In this case, spatial probabilistic modelling of the ground conditions enables (a) an inference of the soil properties at the modified turbine location from field data collected at different locations across an offshore wind farm site and (b) an optimisation of further site investigations. Second, we discuss the uncer-tainties and risks associated with the installation of large diameter monopiles in soils with hetero-geneities such as strong layers and/or embedded boulders. Subsequently, we present a concept for modelling, understanding, and managing these risks based on a probabilistic model of the subgrade conditions, monopile, and subgrade-pile-interaction. T2 - 3rd International Conference on Structural Integrity for Offshore Energy Industry (SI 2021) CY - Online meeting DA - 15.11.2021 KW - Probabilistic modelling KW - Spatially varying ground conditions KW - Foundation reliability analysis KW - Monopile installation risks PY - 2022 SN - 978-1-8383226-3-2 SP - 9 EP - 17 AN - OPUS4-54531 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Yevtushenko, Oleksandra A1 - Le, Quynh Hoa A1 - Bettge, Dirk T1 - Corrosion Effects on Materials Considered for CC(U)S Applications N2 - Commercially available carbon steels are suitable for compression and pipelines as long as moisture content and impurities are limited. (water 50 to 100 ppmv, SO2 and NO2 ca. 100 ppmv) Corrosion rates increase with increasing water content. (0.2 – 20 mm/a) Condensation of acids and therefore droplet formation is always possible, even at low water contents. A low SO2 content within the CO2-stream might be more important than a low water content. Cr13-steels showed a general susceptibility to shallow pitting and pitting. So, they seem to be not suitable for CCUS applications. Low alloyed steels showed better corrosion behavior (predictable uniform corrosion). For direct contact with saline aquifer fluids only high alloyed steels shall be used. T2 - EFC Webinar CY - Online Meeting (Chongqing, China) DA - 18.05.2022 KW - Corrosion KW - CO2 quality KW - CO2 KW - CCS KW - CCU KW - Pipeline PY - 2022 AN - OPUS4-54854 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Aristia, Gabriela A1 - Le, Quynh Hoa A1 - Bäßler, Ralph T1 - Integrated Coating System for Corrosion Protection of Carbon Steel in Artificial Geothermal Brine N2 - Corrosive geothermal brines are a major challenge to geothermal power-plants. For cost reasons, plant designers prefer to use carbon and low alloyed steels, which are susceptible to uniform and localized corrosion when exposed to geothermal brines having acidic and saline properties. To solve such problem, coatings or inhibitors would be a protective solution as an alternative to the use of high alloyed materials. This study investigated a coating system consisting of polyaniline/silicon dioxide based on resources locally available in Indonesia. Protection against corrosion of carbon steel was shown by long-term (28 day) exposure and electrochemical tests of coated carbon steels, performed in an artificial acidic and saline geothermal brine, comparable to the conditions encountered at a site in Indonesia. Therefore, an integrated coating system is proposed for corrosion protection, combining the electrochemical functionality of polyaniline and the physical advantages of silica. T2 - AMPP International Corrosion Conference CY - Online meeting DA - 06.03.2022 KW - Geothermal KW - Corrosion KW - Coating KW - Polyaniline KW - Silicon dioxide PY - 2022 SP - 1 EP - 11 CY - Houston TX (USA) AN - OPUS4-54451 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Herrmann, Ralf T1 - Digitalisierung sichert die Bauwerke von gestern und das Wissen von morgen N2 - Die moderne Gesellschaft in Deutschland und Europa profitiert von der hervorragenden baulichen Infrastruktur, die für uns viele Aspekte aus den Bereichen Mobilität, Energieversorgung, Transport, Umweltschutz, (Nah-)Erholung und Gefahrenabwehr zur Alltäglichkeit werden lassen und uns ein hohes Gefühl der technischen Sicherheit vermitteln. Viele der Annehmlichkeiten, wie beispielweise ein Hochgeschwindigkeitseisenbahnverkehrsnetz, zuverlässige Stromversorgung im europäischen Verbundsystem und ein immenser Personen-, Güter- und Warenverkehr auf der Straße, zu Wasser und in der Luft ist ohne eine leistungsfähige, resiliente und zuverlässige bauliche Infrastruktur undenkbar. KW - Bauwerksmonitoring KW - Bauwerksdiagnostik KW - Digitalisierung PY - 2022 DO - https://doi.org/10.1002/bate.202270303 SN - 1437-0999 SN - 0932-8351 VL - 99 IS - 3 SP - 161 EP - 162 PB - Ernst & Sohn GmbH CY - Berlin AN - OPUS4-54557 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Aristia, G. A1 - Le, Quynh Hoa T1 - Integrated Coating System for Corrosion Protection of Carbon Steel in Artificial Geothermal Brine N2 - Corrosive geothermal brines are a major challenge to geothermal power-plants. For cost reasons, plant designers prefer to use carbon and low alloyed steels, which are susceptible to uniform and localized corrosion when exposed to geothermal brines having acidic and saline properties. To solve such problem, coatings or inhibitors would be a protective solution as an alternative to the use of high alloyed materials. This study investigated a coating system consisting of polyaniline/silicon dioxide based on resources locally available in Indonesia. Protection against corrosion of carbon steel was shown by long-term (28 day) exposure and electrochemical tests of coated carbon steels, performed in an artificial acidic and saline geothermal brine, comparable to the conditions encountered at a site in Indonesia. Therefore, an integrated coating system is proposed for corrosion protection, combining the electrochemical functionality of polyaniline and the physical advantages of silica. T2 - AMPP International Corrosion Conference 2022 CY - San Antonio, TX, USA DA - 08.03.2022 KW - Geothermal KW - Corrosion KW - Coating KW - Polyaniline KW - Silicon dioxide PY - 2022 AN - OPUS4-54452 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph T1 - Evaluation of Corrosion Resistance of Metallic Materials in Geothermal Applications N2 - Evaluation of corrosion resistance of metallic materials is essential to assure safe and reliable operation of geothermal sites. One need to be aware that corrosion is not a material's but a system property, determined by medium, material and construction aspects. Various corrosion types have to be evaluated. Conditions in laboratory shall reflect on-site reality. Depending on brine composition and temperature suitability of metallic materials can be ranked. Most important outcome of the research is that highly saline geothermal brines require high alloyed materials, for safe long-term operation. T2 - Geothermal Essentials - Moving Geothermal Forward in Canada: Scaling and Corrosion (Surface Facilities) CY - Online Webinar DA - 16.03.2022 KW - Corrosion KW - Geothermal KW - Steel PY - 2022 AN - OPUS4-54482 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Stoljarova, A. A1 - Regenspurg, S. T1 - Influence of brine components on materials performance in geothermal applications N2 - Significant Cu-deposition and ‑precipitation only occurred in combination with carbon steel. High-alloyed materials prevent the disturbing Cu-agglomeration. Pb-deposition and ‑precipitation only occurred in combination with carbon steel. No negative Pb-effect could be observed in combination with high-alloyed steels. High alloyed corrosion resistant alloys are suitable and shall be chosen for future design of the piping system, either in massive or in cladded form, if formation of crevices with non-metallic materials can be excluded! T2 - EUROCORR 2022 CY - Berlin, Germany DA - 28.08.2022 KW - Corrosion KW - Geothermal KW - Copper PY - 2022 AN - OPUS4-55624 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hille, Falk A1 - Nerger, Deborah A1 - Moosavi, Robabeh A1 - Grunwald, Marcel T1 - Discussion on data evaluation of tomographic and numerical results N2 - The contribution discusses the processing and analysis of data generated on two different ways of investigations for impact damage in reinforced concrete structures. Damage investigations are essential to determine type and characteristics of damage and thus the residual capacity. Damage describing data is generated using two different types of investigation, a non-destructive tomographic as well as numerical examination. Subsequently, data of both sources was merged and analysed. Within the research project “Behaviour of structural components during impact load conditions caused by aircraft fuel tank collision” reinforces concrete plates were damaged by impact loading, see Hering (2020). Afterwards the damaged specimens were investigated tomographically as well as numerically using several methods and models. Aim of the presented research work was to specify an objective comparability of numerical data with experimentally determined damage patterns and based on this, to establish a quantitative damage evaluation. T2 - 26th International Conference on Structural Mechanics in Reactor Technology CY - Potsdam, Germany DA - 10.07.2022 KW - Impact damage of reinforced concrete KW - Tomographic damage evaluation KW - Numerical simulation of impact damage PY - 2022 AN - OPUS4-55476 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Patrick A1 - Herrmann, Ralf A1 - Schneider, Ronald A1 - Hille, Falk A1 - Baeßler, Matthias A1 - El-Athman, Rukeia T1 - Research Data Management of Structural Health Monitoring Projects and Subsequent Applications of Artificial Intelligence Methods N2 - Structural health monitoring (SHM) intends to improve the management of engineering structures. The number of successful SHM projects – especially SHM research projects – is ever growing, yielding added value and more scientific insight into the management of infrastructure asset. With the advent of the data age, the value of accessible data becomes increasingly evident. In SHM, many new data-centric methods are currently being developed at a high pace. A consequent application of research data management (RDM) concepts in SHM projects enables a systematic management of raw and processed data, and thus facilitates the development and application of artificial intelligence (AI) and machine learning (ML) methods to the SHM data. In this contribution, a case study based on an institutional RDM framework is presented. Data and metadata from monitoring the structural health of the Maintalbrücke Gemünden for a period of 16 months are managed with the RDM system BAM Data Store, which makes use of the openBIS data management software. An ML procedure is used to classify the data. Feature engineering, feature training and resulting data are performed and modelled in the RDM system. T2 - 11th International Conference on Bridge Maintenance, Safety and Management (IABMAS2022) CY - Barcelona, Spain DA - 11.07.2022 KW - Research data management KW - Structural health monitoring KW - Artificial intelligence PY - 2022 AN - OPUS4-55494 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Patrick A1 - Schneider, Ronald A1 - Herrmann, Ralf A1 - Hille, Falk A1 - Baeßler, Matthias T1 - Sensorbasierte Systemidentifikation N2 - Die aktuelle Instandhaltungsstrategien von Ingenieurbauwerken arbeiten zustandsbasiert und stützen sich auf visuelle Inspektionen in kurzen, starren Intervallen. Beim Übergang zu Predicitive-Maintenance-Strategien können Sensordaten eigesetzt werden um Prognosemodelle der Bauwerke zu aktualisieren. Ein erster Schritt hierzu ist die sensorbasierte Systemidentifikation. T2 - Abschlussveranstaltung AISTEC CY - Berlin, Germany DA - 02.05.2022 KW - Systemidentifikation KW - Strukturmonitoring PY - 2022 AN - OPUS4-55495 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schneider, Ronald A1 - Simon, Patrick A1 - Herrmann, Ralf A1 - Hille, Falk A1 - Baeßler, Matthias T1 - Belastungsversuch und Methodenvalidierung an der Maintalbrücke Gemünden N2 - Im Projekt AISTEC wurden Methoden entwickelt, die der prädiktiven Instandhaltung von Ingenieurbauwerken dienen. Zur Validierung dieser Methoden wurden an einem Referenzbauwerk - der Maintalbrücke Gemünden - Belastungstests durchgeführt. T2 - Abschlussveranstaltung AISTEC CY - Berlin, Germany DA - 02.05.2022 KW - Belastungsfahrt KW - GNSS KW - Einflusslinien PY - 2022 AN - OPUS4-55496 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pirskawetz, Stephan A1 - Steinbock, O. A1 - Hille, Falk A1 - Schmidt, S. A1 - Hofmann, Detlef T1 - Erfahrungen aus dem Rückbau der Brücke am Altstädter Bahnhof in der Stadt Brandenburg - Teil 2: Schadensmonitoring bei zerstörenden Versuchen N2 - Im Dezember 2019 wurden bei einer turnusmäßigen Inspektion der B 1-Brücke am Altstädter Bahnhof in Brandenburg an der Havel massive und schnell voranschreitende Schäden festgestellt. Als Ursache für die Risse entlang der Längsträger wurde das Versagen eines signifikanten Anteils der Spanndrähte der konzentrierten Spannglieder vermutet. Die Brücke wurde umgehend für den Verkehr gesperrt und im Mai 2021 gesprengt. Im Vorfeld der Sprengung wurden durch das Bundesministerium für Digitales und Verkehr (BMDV) weiterführende Untersuchungen zum Schadensbild veranlasst, welche vom Landesbetrieb Straßenwesen Brandenburg koordiniert und in den Bauablauf integriert wurden. Das von der Hochschule für Technik und Wirtschaft (HTW) Dresden erstellte Versuchskonzept ist Bestandteil des vorangestellten ersten Teils des Beitrags [1]. Hier im zweiten Teil werden ausgewählte Ergebnisse der umfangreichen versuchsbegleitenden Mess- und Monitoringmaßnahmen beschrieben, welche in Kooperation der HTW Dresden, der Bilfinger Noell GmbH sowie der Bundesanstalt für Materialforschung und -prüfung (BAM) durchgeführt wurden. N2 - A routine inspection of the B1 bridge at the Altstädter Bahnhof in Brandenburg an der Havel in December 2019 revealed massive and rapidly progressing damage. The cause of the cracks along the longitudinal girders was suspected to be the failure of a significant portion of the prestressing wires of the concentrated tendons. The bridge was immediately closed to traffic and demolished in May 2021. Prior to the demolition, the Federal Ministry for Digital and Transport (BMDV) initiated further investigations into the damage pattern, which were coordinated and integrated into the deconstruction process by the Landesbetrieb Straßenwesen Brandenburg. The test concept was developed by the Hochschule für Technik und Wirtschaft Dresden (HTW) and is described in the previous article (Part 1). The article at present (Part 2) describes selected results of the extensive measurement and monitoring measures accompanying the tests. The Tests were carried out in cooperation with the HTW Dresden, Bilfinger Noell GmbH and the Bundesanstalt für Materialforschung und -prüfung (BAM). KW - Spannbetonbrücke KW - Spannstahlbruch KW - Schallemission KW - Fotogrammetrie KW - Faseroptik KW - Stochastische Subspacebasierte Schadensdetektion PY - 2022 DO - https://doi.org/10.1002/best.202200052 SN - 1437-1006 VL - 117 IS - 8 SP - 581 EP - 589 PB - Ernst & Sohn CY - Berlin AN - OPUS4-55513 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst A1 - Hille, Falk A1 - Hofmann, Detlev A1 - Kind, Thomas ED - Isecke, B. ED - Krieger, J. T1 - Überwachung der Brücke Altstädter Bahnhof, Brandenburg./H. Begleituntersuchungen mit moderner Sensorik und zerstörungsfreier Prüfung N2 - Die B1 Brücke am Altstädter Bahnhof in Brandenburg an der Havel wurde im Dezember 2019 aufgrund von während einer turnusmäßigen Inspektion entdeckten Rissen und Hohlstellen entlang der vorgespannten Längsträger gesperrt und im Mai 2021 abgebrochen. In der Zwischenzeit wurde die Brücke detailliert überwacht. Vor dem Abriss wurden zudem umfangreiche Untersuchungen zur Bestandsaufnahme und Schadensanalyse sowie Tests moderner Sensorik vorgenommen. Dabei konnte sowohl die richtige, zuvor nicht sicher bekannte Anzahl von Spanngliedern in den Querträgern sicher ermittelt werden als auch durch moderne Varianten der Schwingungsmessungen und der faseroptischen Sensorik zusätzliche Kenntnisse püber das Bauwerksverhalten ermittelt werden . In dem Beitrag werden die Verfahren mit ihren Möglichkeiten und Grenzen vorgestellt, die Ergebnissee an der Brücke in Brandenburg erläutert und zukünftige Einsatzmöglichkeiten diskutiert. T2 - 5. Brückenkolloquium CY - Ostfildern, Germany DA - 06.09.2022 KW - Monitoring KW - Brücke KW - Radar KW - Vibration KW - Faseroptik PY - 2022 SN - 978-3-8169-3549-0 SP - 555 EP - 566 PB - Expert Verlag CY - Tübingen AN - OPUS4-55627 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Aristia, G. T1 - A Coating System for Corrosion Protection of Carbon Steel as an Alternative for High Alloyed Materials N2 - The screening of coatings shows that the modification by adding individual pigment was not sufficient to protect carbon steel even during a short-term exposure, indicated by the discoloration after only seven days of exposure. Electrochemical tests indicated that the coating cathodically protects carbon steel or slows down the corrosion reaction. A long-term exposure test confirmed that the PANI/SiO2 modified coating successfully protects the carbon steel in the Sibayak artificial geothermal water at 150 °C for 6 months. T2 - European Geothermal Congress CY - Berlin, Germany DA - 17.10.22 KW - Corrosion KW - Geothermal KW - Coatings KW - Polyaniniline KW - Silicate PY - 2022 AN - OPUS4-56084 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hille, Falk A1 - Herrmann, Ralf A1 - Ziegler, Fred A1 - Said, Samir A1 - Baeßler, Matthias A1 - Wille, Frank A1 - Quercetti, Thomas A1 - Minack, Mathias A1 - Sterthaus, Jens T1 - Structural Health Monitoring am Großen Fallturm der BAM N2 - Am Fallturm auf dem Testgelände Technische Sicherheit (TTS) der BAM wurden bei Inspektionen Vorspannungsverluste in den Bolzen der Stahlverbindungen festgestellt. Um ein Verständnis für die zugrundeliegenden Trag- und Schädigungsmechanismen zu erlangen und um den Zustand der vorgespannten Schraubverbindungen langzeitlich zu überwachen, wurde am Fallturm ein Structural Health Monitoring (SHM) System installiert. Für die Auslegung des Monitoringsystems sowie zur Unterstützung der Untersuchung des Schädigungsprozesses wurde ein numerisches Modell erstellt und in Bezug auf die gemessenen Antworten des Tragwerks kalibriert. Im Vortrag werden die experimentellen und numerischen Untersuchungen zur Systemidentifikation des Stahlrohrgitterturms als auch die Überwachungskampagne mit dem eingesetzten Monitoringsystem sowie die Messergebnisse und deren Bewertung vorgestellt. T2 - Seminar "Zerstörungsfreie Prüfung" am Lehrstuhl für Zerstörungsfreie Prüfung ,Technische Universität München CY - Online meeting DA - 13.01.2022 KW - Structural Health Monitoring KW - Schadensüberwachung KW - Schwingungsmonitoring PY - 2022 AN - OPUS4-56667 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Aristia, Gabriela A1 - Bäßler, Ralph T1 - A Coating System for Corrosion Protection of Carbon Steel as an Alternative for High Alloyed Materials N2 - Corrosive geothermal brines are a major challenge to geothermal power-plants. For cost reasons, plant designers favorize low alloyed steels, e.g., carbon steel, which are susceptible to uniform and localized corrosion when exposed to geothermal brines having acidic and saline properties. To solve such problem, coatings or inhibitors would be a protective solution as an alternative to the use of high alloyed materials. This study investigated a coating system consisting of polyaniline/silicon dioxide basing on locally available resources. Protection against corrosion of carbon steel is shown by long-term exposure and electrochemical tests of coated carbon steels, performed in an artificial acidic and saline geothermal brine, comparable to real conditions at a site in Indonesia. Therefore, an integrated coating system is presented for corrosion protection, combining the electro-chemical functionality of polyaniline and the physical advantages of silica. T2 - European Geothermal Congress CY - Berlin, Germany DA - 17.10.22 KW - Corrosion KW - Geothermal KW - Coatings KW - Polyaniniline KW - Silicate PY - 2022 SP - 1 EP - 7 CY - Berlin AN - OPUS4-56085 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Schaumann, P. A1 - Hothan, Sascha A1 - Mund, M. A1 - Häßler, Dustin A1 - Schartel, Bernhard A1 - Daus, Lars-Hendrik T1 - Bewertung des Feuerwiderstandes von Stahlkonstruktionen mit reaktiven Brandschutzsystemen unter Berücksichtigung des Alterungsverhaltens N2 - Im Rahmen des Forschungsprojektes IGF 20470N wurden Untersuchungen zum Alterungsverhalten von reaktiven Brandschutzsystemen (RBS) auf Stahlbauteilen durchgeführt. Mithilfe der Ergebnisse einer umfangreichen Literaturrecherche sowie experimentellen und numerischen Untersuchungen sollte ein Vorschlag für ein Prüfkonzept zum Nachweis einer Nutzungsdauer von RBS von mehr als 10 Jahren auf Basis von Kurzzeitversuchen abgeleitet werden. Dabei setzt die Bewertung des Alterungsverhaltens von RBS voraus, dass die Mechanismen der Alterung hinreichend bekannt sind. Dafür wurden zunächst systematisch Daten von Kurz- und Langzeitversuchen von nationalen Zulassungsprüfungen der letzten Jahrzehnte ausgewertet. Anschließend wurden umfangreiche experimentelle Untersuchungen an einer wasserbasierten sowie einer epoxidharzbasierten Richtrezeptur durchgeführt. Da aus der Literatur bekannt ist, dass die Einflüsse der Bewitterung zu einer Veränderung der Konzentration der Bestandteile innerhalb der Beschichtung führen können, wurden Untersuchungen mit Mangelrezepturen durchgeführt, wobei systematisch einzelne Bestandteile reduziert wurden. Neben optischen Untersuchungen wurden thermoanalytische Verfahren (DSC-TG-, ATR-FTIR-, Elementar-, Farbanalyse) angewandt sowie Brandversuche an beschichteten Stahlplatten durchgeführt. Des Weiteren wurden die Richtrezepturen den beschleunigten Kurzzeitversuchen gemäß EAD 350402-00-1106 (2017) unterzogen, welche die Zulassung von Produkten auf europäischer Ebene regelt. Für die wasserbasierte Richtrezeptur wurden die Bewitterung für den feuchten Innenraum (Typ Z1) mehrfach wiederholt (1x, 3x, 6x). Für die epoxidharzbasierte Richtrezeptur entsprach die Bewitterung dem Zyklus für die Außenanwendung (Typ X). In Brandversuchen sowie thermoanalytischen und optischen Untersuchungen wurde das Alterungsverhalten sowie die thermische Schutzwirkung analysiert. Anschließend wurden numerische Simulationen von Stahlbauteilen mit gealterten RBS durchgeführt und anhand der experimentellen Untersuchungen validiert. Mithilfe der numerischen Modelle kann eine Bewertung der thermischen Schutzwirkung von Stahlbauteilen mit gealterten RBS vorgenommen werden. Mithilfe der gesammelten Erkenntnisse wurde ein Vorschlag für ein Prüfkonzept für den Nachweis einer Nutzungsdauer von mehr als 10 Jahren abgeleitet. Das Prüfkonzept besteht dabei aus einem Katalog von Möglichkeiten, die aktuellen Zulassungsprüfungen auf europäischer Ebene für eine Nutzungsdauer von 10 Jahren auf einen längeren Zeitraum zu erweitern. N2 - Within the scope of the research project IGF 20470N, investigations were carried out on the assessment of the aging behavior of intumescent coatings (ICs) for the fire protection of steel members. With the help of the results of an extensive literature research as well as experimental and numerical investigations, a proposal for a test concept for the proof of a service life of ICs of more than 10 years was to be derived on the basis of short-term tests. The evaluation of the aging behavior of ICs presupposes that the aging mechanisms are sufficiently known. For this purpose, data from short- and long-term tests of national approval tests of the last decades were first systematically evaluated. Subsequently, extensive experimental investigations were carried out on a water-based and epoxy resin-based model formulation. Since it is known from the literature that the effects of weathering may lead to a change in the concentrations of the constituents within the coating, investigations were carried out with formulations of the ICs in which individual constituents were systematically reduced. In addition to optical investigations, thermoanalytical methods (DSC-TG-, ATR-FTIR-, elemental-, color analysis) were used and fire tests were carried out on coated steel plates. Furthermore, the model formulations were subjected to the accelerated short-term tests of EAD 350402-00-1106 (2017), which regulates the approval of products at the European level. For the water-based model formulation, the weathering for the interior application with a high moisture content (type Z1) was repeated several times (1x, 3x, 6x). For the epoxy resin-based model formulation, the weathering corresponded to the cycle for exterior application (type X). Fire tests as well as thermoanalytical and optical investigations were carried out to analyze the aging behavior and the thermal protection performance. Subsequently, numerical simulations of steel members with aged ICs were carried out and validated on the basis of the experimental investigations. With the help of the numerical models, an evaluation of the thermal protection performance of steel members with aged ICs can be carried out. Bases on the findings, a proposal for a test concept for the verification of a service life of more than 10 years was derived. The test concept consists of a catalogue of possibilities for extending the current approval tests at European level for a service life of 10 years to a longer period. KW - Brandschutz KW - Dauerhaftigkeit KW - Alterung KW - Reaktive Brandschutzsysteme KW - Brandversuche PY - 2022 UR - https://dast.deutscherstahlbau.de/veroeffentlichungen/forschungsberichte SP - 1 EP - 367 PB - Stahlbau Verlags- und Service GmbH CY - Düsseldorf AN - OPUS4-57257 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Bio, Waste, Non-vegan – Fun, Food for Thought, or Future N2 - Overview of the state of the art and current trends with the main topics: - renewable sources in flame retardant polymers (flame retarded bio-polymers and biocomposites; bio-flame retardants, renewable adjuvants from industrial waste) - flame retardancy meets sustainability - concepts between analogy and out-of-the-box. T2 - 18th SKZ International Conference on Trends in Fire Safety and InnovativeRFlame retardants for Plastics CY - Würzburg/Rottendorf, Germany DA - 27.09.2022 KW - Bio-polymer KW - Bio-composite KW - Renewable source KW - Renewable adjuvants KW - Vitrimer KW - Bio-flame retardant PY - 2022 AN - OPUS4-55840 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Strommer, Bettina A1 - Battig, Alexander A1 - Frasca, Daniele A1 - Schulze, Dietmar A1 - Huth, Christian A1 - Böhning, Martin A1 - Schartel, Bernhard T1 - Multifunctional Property Improvements by Combining Graphene and Conventional Fillers in Chlorosulfonated Polyethylene Rubber Composites N2 - The incorporation of nanoparticles like multilayer graphene (MLG) into elastomeric composites boosts their technical performance, such as their mechanical behavior and electrical conductivity. Common filler types (carbon black (CB) and aluminum trihydroxide (ATH)) generally fulfill single, specific purposes and are often used in high loadings. CB typically reinforces rubber mechanically, while ATH increases flame retardancy. Small amounts of MLG reduce these high filler contents and maintain the multifunctional characteristics of rubber composites. In chlorosulfonated polyethylene (CSM) + ATH, an intrinsically flame-retardant rubber was designed to achieve the highest standards such as maximum average of heat emission (MARHE) <90 kW m−2, 3 phrMLG was substituted for 15 phr CB and/or 3 phr ATH via an industrially applicable processing approach. Replacing either CB or ATH resulted in a property profile that was multifunctionally improved in terms of features such as mechanical performance, reduced sorption, and flame retardance. MLG nanocomposites are reported to show promise as an industrially utilizable route to obtain multifunctional high-performance rubbers. KW - Nanocomposites KW - Rubber KW - Multilayer graphene KW - Flame retardancy KW - Synergy KW - Nanoparticles KW - Elastomers PY - 2022 DO - https://doi.org/10.1021/acsapm.1c01469 SN - 2637-6105 VL - 4 IS - 2 SP - 1021 EP - 1034 PB - ACS Publ. CY - Washington, DC AN - OPUS4-54330 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Chan, Yin Yam A1 - Schartel, Bernhard T1 - It Takes Two to Tango: Synergistic Expandable Graphite–Phosphorus Flame Retardant Combinations in Polyurethane Foams N2 - Due to the high flammability and smoke toxicity of polyurethane foams (PUFs) during burning, distinct efficient combinations of flame retardants are demanded to improve the fire safety of PUFs in practical applications. This feature article focuses on one of the most impressive halogen-free combinations in PUFs: expandable graphite (EG) and phosphorus-based flame retardants (P-FRs). The synergistic effect of EG and P-FRs mainly superimposes the two modes of action, charring and maintaining a thermally insulating residue morphology, to bring effective flame retardancy to PUFs. Specific interactions between EG and P-FRs, including the agglutination of the fire residue consisting of expanded-graphite worms, yields an outstanding synergistic effect, making this approach the latest champion to fulfill the demanding requirements for flame-retarded PUFs. Current and future topics such as the increasing use of renewable feedstock are also discussed in this article. KW - Synergy KW - Phosphorus-containing flame retardant KW - Expandable graphite KW - Polyurethane foams PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-551958 DO - https://doi.org/10.3390/polym14132562 SN - 2073-4360 VL - 14 IS - 13 SP - 2562 PB - MDPI AN - OPUS4-55195 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Schartel, Bernhard ED - Morgan, A.B. T1 - Multicomponent Flame Retardants N2 - The important take home message of this chapter: When multicomponent flame retardant systems are applied to polymeric materials, it becomes possible to address multiple fire properties, increase efficiency, and minimize flame retardant use to maximize polymer property balance. Flame retardants are combined or used together with adjuvants or synergists; fibers and fillers make a crucial contribution to their fire properties. Multicomponent systems are discussed in their capacity as an overall powerful strategy for achieving and optimizing non-halogenated flame-retardant polymeric materials. KW - Flame retardants KW - Synergy KW - Adjuvants KW - Fillers KW - Fibres PY - 2022 SN - 978-1-119-75056-7 SP - 413 EP - 474 PB - Scrivener Publishing LLC CY - Bevery ET - 2nd Edition AN - OPUS4-54426 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Battig, Alexander A1 - Garfias González, Karla I. A1 - Schartel, Bernhard T1 - Valorizing “non-vegan” bio-fillers: Synergists for phosphorus flame retardants in epoxy resins N2 - Sustainable, biogenic flame retardant adjuvants for epoxy resins are receiving increased focus. Zoological products like insects, bone meal, and eggshells are available in large quantities, but remain uninvestigated as functional fillers to epoxy resins, although they are potential synergists to flame retardants. The efficacy and flame retardancy of “non-vegan” additives in combination with flame retardants is investigated and the fire behavior and thermal decomposition of bio-sourced epoxy resin composites is characterized. By comparing the fire performance of composites containing flame retardants or fillers at varying loadings (5, 10, and 20%), their role as synergists that enhance the function of organophosphorus flame retardants in bio-epoxy composites is identified and quantified. Peak heat release rates were 44% lower in composites containing both filler and flame retardant versus those containing only flame retardants, and fire loads were reduced by 44% versus the pure resin, highlighting the ability of “non-vegan” fillers to function as synergists. KW - Flame retardancy KW - Synergy KW - Bio-composite KW - Epoxy resin KW - Biogenic KW - Renewable PY - 2022 DO - https://doi.org/10.1016/j.polymdegradstab.2022.109875 SN - 0141-3910 VL - 198 SP - 109875 PB - Elsevier Ltd. AN - OPUS4-54438 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wachtendorf, Volker A1 - Schartel, Bernhard A1 - Lin, Xuebao A1 - Tan, Yi A1 - Schoch, R. A1 - Lang, M. A1 - Tröppner, O. A1 - Bosse, M. T1 - Untersuchung der Witterungsbeständigkeit komplexer Funktionalitäten von Polymerwerkstoffen durch künstliche Bewitterung: Flammschutz N2 - In den letzten Jahrzehnten wurde die Degradation der polymeren Matrix von flammgeschützten Polymeren eingehend untersucht. Erst in den letzten Jahren jedoch hat sich die Frage der Lebensdauer der Funktionalität des Flammschutzes selbst als wichtige Fragestellung herauskristallisiert, z.B. bei Kabeln. Deshalb sollte diese Fragestellung durch systematisch-variierte künstliche Klima- und Bewitterungstests an flammgeschützten Polymerwerkstoffen untersucht werden T2 - 50. Jahrestagung der Gesellschaft für Umweltsimulation (GUS) CY - Online meeting DA - 23.03.2022 KW - Flammschutz KW - Witterungsbeständigkeit KW - Langzeitbeständigkeit KW - UV KW - E&E PY - 2022 AN - OPUS4-54541 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wachtendorf, Volker A1 - Schartel, Bernhard A1 - Lin, Xuebao A1 - Tan, Yi A1 - Schoch, R. A1 - Lang, M. A1 - Tröppner, O. A1 - Bosse, M. ED - Ziegahn, K.-F. T1 - Untersuchung der Witterungsbeständigkeit komplexer Funktionalitäten von Polymerwerkstoffen durch künstliche Bewitterung: Flammschutz N2 - In den letzten Jahrzehnten wurde die Degradation der polymeren Matrix von flammgeschützten Polymeren eingehend untersucht. Erst in den letzten Jahren jedoch hat sich die Frage der Lebensdauer der Funktionalität des Flammschutzes selbst als wichtige Fragestellung herauskristallisiert, z.B. bei Kabeln. Deshalb sollte diese Fragestellung durch systematisch-variierte künstliche Klima- und Bewitterungstests an flammgeschützten Polymerwerkstoffen untersucht werden. T2 - 50. Jahrestagung der Gesellschaft für Umweltsimulation (GUS) CY - Online meeting DA - 23.03.2022 KW - Flammschutz, Witterungsbeständigkeit, Langzeitbeständigkeit, UV, E&E PY - 2022 SN - 978-3-9818507-7-2 VL - 50 SP - 143 EP - 148 CY - Pfinztal (Berghausen) AN - OPUS4-54543 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard A1 - Battig, Alexander A1 - Garfias González, K. I. A1 - Gleuwitz, F. R. A1 - Sánchez Olivares, G. T1 - Non-vegan flame-retardant (adjuvants in) biocomposites N2 - Emanating from developing flame retarded biocomposites, we have proposed renewable natural fibers (including keratin) taken from industrial waste as an authentic sustainable approach. More recently, we have investigated non-vegan flame retardant approaches. This paper loves to give you an insight into our ongoing projects on biogenic industrial wastes like leather, bone meal, and insects. Materials were characterized multi-methodically, flame retardant modes of action quantified, decomposition mechanism proposed, and synergisms explained. Considering the large quantities of leather waste (LW) in industrial-scale production, we underline LW as multifunctional bio-adjuvants. LW enhances the flame retardancy of poly(ethylene-vinyl acetate) (EVA) containing phosphorus flame retardants (P-FR). Products/by-products of the invertebrate and vertebrate farming, respectively, are promising bio-based adjuvants in flame retarded bio-epoxy thermosets. While the addition of bone meal yields the formation of an inorganic shield, protein-based powders from insects provide an intumescent behavior. In combination with a P-FR superior charring and self-extinguishing are obtained. Acknowledgement: In part of this work was supported by the Volkswagen Foundation grant “Experiment!” No. 97437. T2 - Fire and Polymers, workshop, ACS Division of Polymer Chemistry CY - Napa, California, US DA - 05.06.2022 KW - Fire behaviour KW - Renewable KW - Circular economy KW - Biocomposite PY - 2022 AN - OPUS4-55025 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard A1 - Battig, Alexander A1 - Böhning, Martin A1 - Frasca, Daniele A1 - Schulze, Dietmar A1 - Strommer, Bettina A1 - Tabaka, Weronika A1 - Wachtendorf, Volker T1 - Multifunctional Elastomer/Graphene Nanocomposites N2 - A few layer/multilayer graphene (MLG) with a specific surface area of BET=250 m2/g is proposed as an efficient multifunctional nanofiller for rubbers. The preparation method, i.e., ultrasonically-assisted solution mixing of master batches followed by two-roll milling, strongly influences the dispersion in the elastomeric matrix and is fundamental for the final properties. When homogenously dispersed, single stacks of only approximately 10 graphene sheets, with an aspect ratio of 34, work at low loadings, enabling the replacement of large amounts of carbon black (CB), an increase in efficiency, and a reduction in filler load. The appropriate preparation yielded nanocomposites in which just 3 phr are sufficient to significantly improve the rheological, curing, gas barrier properties, electrical and thermal conductivity, as well as mechanical properties of different rubbers, as shown for chlorine-Isobutylene-Isoprene rubber (CIIR), nitrile-butadiene rubber (NBR), natural rubber (NR), and styrene-butadiene rubber (SBR). 3 phr of MLG tripled the Young’s modulus of CIIR, an effect equivalent to 20 phr of CB. The stronger interactions between MLG and NR or SBR also resulted in a reduction in the elongation at break by 20% and 50%, respectively, while the same parameter was hardly changed for CIIR/MLG and NBR/MLG. CIIR/MLG and NBR/MLG were stiffer but just as defomable than CIIR and NBR. The strong reinforcing effect of 3 phr MLG was confirmed by the increase of greater than 10 Shore A in hardness. MLG reduces gas permeability, increases thermal and electrical conductivities, and retards flammability, the latter shown by the reduction in heat release rate in the cone calorimeter. We investigated MLG also as a synergist for reducing the aluminium trihydrate loading in flame retardant hydrogenated acrylonitrile-butadiene (HNBR), polybutadiene chloroprene (BR/CR), and chlorosulfonated polyethylene rubber(CSM). The higher the nanofiller concentration is, the greater the improvement in the properties. For instance, the permeability decreased by 30% at 3 phr of MLG, 50% at 5 phr and 60% at 10 phr, respectively. Moreover, the MLG nanocomposites improve stability of mechanical properties against the effects of weathering. In key experiments an increase in UV-absorption and a pronounced radical scavenging were proved as stabilizing mechanisms. In a nutshell, MLG is an efficient multifunctional nanofiller ready to be used for innovative rubber development. T2 - 19th European Polymer Congress, EPF 2022 CY - Prague, Czech Republic DA - 26.06.2022 KW - Graphene KW - Nanocomposite KW - Rubber KW - Elastomer PY - 2022 AN - OPUS4-55196 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Falkenhagen, Sandra F. A1 - Schartel, Bernhard A1 - Wang, Y.-Z. A1 - Bocz, K. T1 - black as hell, strong as death and sweet as love - pyrolyzed waste materials and cyclodextrins as effective filler in flame retarded epoxy composites N2 - Renewable alternatives for common thermoset resins are demanded to go for sustainability. The objective is to create a flame retarded epoxy resin from a commercial bio epoxy resin with halogen free inorganic and organic flame retardants, respectively. Alumina trihydrate, aluminum diethyl phosphinate, a DOPO-based phosphonamidate and ammonium polyphosphate seem to have promising performances. Properties are enhanced with different bio fillers: pyrolyzed cocoa shells and plant waste (provided by Otto A. Müller Recycling GmbH, thanks!), short fibers and nonwovens of the natural fiber kenaf, hydroxypropyl-ß-cyclodextrin and sulfobutylether-ß-cyclodextrin. Fire performance is investigated by cone calorimeter examinations, LOI and UL-94 ratings. Thermal analysis is given by TG-FTIR and DSC measurements. Combinations of flame retardants and bio-fillers lead to reduced PHRR and THR, reach V0 in UL-94 and have a significant increase in LOI of up to 37 vol.-%. 10 % ammonium polyphosphate with 10 % pyrolyzed cocoa shell performs best, builds a magnificent protective layer, and shows good intumescence. T2 - 3rd international conference on eco-friendly flame retardant additives and materials CY - Alès, France DA - 17.05.2022 KW - Epoxy resin KW - Flame retardant KW - Kenaf fiber KW - Pyrolyzed plant waste KW - Cyclodextrin PY - 2022 AN - OPUS4-54928 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mund, M. A1 - Häßler, Dustin A1 - Schaumann, P. A1 - Hothan, Sascha A1 - Schartel, Bernhard T1 - Experimentelle Untersuchungen zur Dauerhaftigkeit von reaktiven Brandschutzsystemen N2 - Reaktive Brandschutzsysteme finden im baulichen Brandschutz Anwendung zur Erhöhung des Feuerwiderstands von Stahlkonstruktionen. Neben den Anforderungen an die Feuerwiderstandsdauer können damit auch Ansprüche an die Ästhetik erfüllt werden. Die profilfolgende Applikation und die geringen Trockenschichtdicken der Produkte ermöglichen es, das filigrane Erscheinungsbild von Stahlkonstruktionen aufrechtzuerhalten. Neben der thermischen Schutzwirkung muss auch die Dauerhaftigkeit der Brandschutzbeschichtung sichergestellt werden. Die Bewertungsmethoden, die auf europäischer Ebene durch das EAD 350402-00-1106 zur Verfügung stehen, zielen auf eine Nutzungsdauer von zehn Jahren ab. Prüfverfahren für einen darüber hinausgehenden Zeitraum sind nicht beschrieben. In diesem Beitrag werden experimentelle Untersuchungen zum Einfluss der Bewitterung auf das Expansionsverhalten, zur thermischen Schutzwirkung und zu den während des Aufschäumens im Brandfall stattfindenden Reaktionen vorgestellt. Die Versuche wurden an einem wasserbasierten und einem epoxidharzbasierten reaktiven Brandschutzsystem durchgeführt. Die Ergebnisse wurden im Rahmen des IGF-Forschungsvorhabens 20470 N erzielt. KW - Brandschutz KW - Reaktive Brandschutzsysteme KW - Brandversuche KW - Alterung KW - Dauerhaftigkeit PY - 2022 DO - https://doi.org/10.1002/stab.202200063 SN - 0038-9145 VL - 92 IS - 2 SP - 93 EP - 102 PB - Ernst & Sohn CY - Berlin AN - OPUS4-56346 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard A1 - Lin, Xuebao A1 - Tan, Yi A1 - Wachtendorf, Volker A1 - Klack, Patrick A1 - Schoch, R. A1 - Lang, M. A1 - Tröppner, O. A1 - Bosse, M. T1 - Weathering Resistance of Halogen-free Flame Retardancy in E&E Plastics N2 - - Durability of fire retardancy - Impact of different exposure conditions - Degradation with respect to different fire properties/tests T2 - Fire Resistance in Plastics CY - Cologne, Germany DA - 28.11.2022 KW - Durability KW - Flame retardant KW - Thermoplastic Polyurethane KW - Cable KW - EVA KW - Weathering PY - 2022 AN - OPUS4-56444 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Composites in Fire and Flame N2 - Overview over the research results of the BAM in the field fire retardancy of composites. In different applications the flame retardancy of composites targets on different fire protection goals in the fire scenarios ignition, developing fire, and fully developed fire. Efficient solutions are tailored to pass a distinct fire test and to fit to a specific material. Flame inhibition as main flame retardancy mode of action combined with a minor mode of action in the condensed phase is general very efficient approach for composites. Alternatively residue design is demanded to achieve good results with only condensed phase mechanisms. Improving the fire stability asks for protective fire residues. T2 - Climate Change @ Fire Science Workshop CY - Berlin, Germany DA - 10.11.2022 KW - Composites in fire KW - Flame retarded composites KW - Fire stability KW - Phosphorous flame retardants KW - Residue design PY - 2022 AN - OPUS4-56299 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Gleuwitz, F. Robert A1 - Battig, Alexander A1 - Schartel, Bernhard T1 - Tenebrio molitor Beetle as a “Nonvegan” Adjuvant to Flame Retardants in Tannic Acid-Based Epoxy Thermosets N2 - Material solutions that meet both circular bioeconomy policies and high technical requirements have become a matter of particular interest. In this work, a prospectively abundant proteinrich waste resource for the manufacturing of flame-retardant epoxy biocomposites, as well as for the synthesis of biobased flame retardants or adjuvants, is introduced. Different biomass fillers sourced from the cultivation of the mealworm beetle Tenebrio molitor are embedded in a bioepoxy resin cured with tannic acid and investigated regarding the fire performance of the thermosets. By means of spectroscopic and thermal analysis (attenuated total reflectance FTIR spectroscopy, thermogravimetric analysis-coupled FTIR spectroscopy, and differential scanning calorimetry), the influence of the biomass microparticles on the curing and thermal degradation behavior is evaluated. The final performance of the biocomposites is assessed based on fire testing methodology (limited oxygen index, UL-94, and cone calorimetry). Providing a high charring efficiency in the specific tannic acid-based epoxy matrix, the protein-rich adult beetle is further investigated in combination with commercial environmentally benign flame retardants in view of its potential as an adjuvant. The results highlight a char forming effect of nonvegan fillers in the presence of tannic acid, particularly during thermal decomposition, and point toward the potential of protein-based flame retardants from industrial insect rearing for future formulations. KW - Tannic acid KW - Flame retardancy KW - Sustainable KW - Epoxy resin KW - Insects PY - 2022 DO - https://doi.org/10.1021/acssuschemeng.2c00746 SN - 2168-0485 VL - 10 IS - 19 SP - 6313 EP - 6324 PB - ACS AN - OPUS4-54845 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Marti, J. A1 - Schartel, Bernhard A1 - Oñate, E. T1 - Simulation of the burning and dripping cables in fire using the particle finite element method N2 - The behavior of the cable jacket in fire characterized by the tendency to melt and drip constitutes a major source of fire hazard. The reason is that the melted material may convey the flame from one point to another, expanding fire and contributing to the fire load. In this article, the capability of a new computational strategy based on the particle finite element method for simulating a bench-scale cables burning test is analyzed. The use bench-scale test has been previously used to simulate the full-scale test described in EN 50399. As the air effect is neglected, a simple combustion model is included. The samples selected are two cables consisting of a copper core and differently flame retarded thermoplastic polyurethane sheets. The key modeling parameters were determined from different literature sources as well as experimentally. During the experiment, the specimen was burned under the test set-up condition recording the process and measuring the temperature evolution by means of three thermocouples. Next, the test was reproduced numerically and compared with a real fire test. The numerical results show that the particle finite element method can accurately predict the evolution of the temperature and the melting of the jacket. KW - Dripping behavior KW - Particle finite element method KW - Cables in fire KW - Fire behavior KW - Fire simulation KW - Cable bundle PY - 2022 DO - https://doi.org/10.1177/07349041211039752 SN - 0734-9041 VL - 40 IS - 1 SP - 3 EP - 25 PB - Sage AN - OPUS4-54185 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -