TY - CONF A1 - Schwarz, W. A1 - Wilsch, Gerd A1 - Katsumi, N. A1 - Ebell, Gino A1 - Völker, Tobias T1 - Ion distribution in concrete overlay, mapped by laser induced breakdown spectroscopy (LIBS), modified by an embedded zinc anode N2 - Galvanic corrosion protection by embedded zinc anodes is an accepted technique for the corrosion protection of reinforcing steel in concrete. Galvanic currents flow between the zinc anode and the steel reinforcement due to the potential difference that is in the range of a few hundred mV. The ion distribution was studied on two steel reinforced concrete specimens admixed with 3 wt.% chloride/wt. cement and galvanically protected by a surface applied EZ-anode. On both specimens, a zinc anode was embedded and glued to the concrete surface by a geo-polymer-based chloride-free binder. At one specimen, the EZ-anode was operated for 2,5 years, the EZ-anode at the other specimen was not electrically connected to the reinforcement, this specimen serves as a reference. Both specimens have been stored under identical conditions. The ion distribution between the anode (EZ-anode) and cathode (steel reinforcement) was studied by laser-induced breakdown spectroscopy (LIBS) after 7 months, 12 months, and 2,5 years. Results of the LIBS studies on the specimen with activated EZ-anode after 7 months, 12 months, and 2,5 years and of the reference specimen after 2,5 years are reported. Results show that diffusion of ions contributes to the changes in the ion distribution but migration, especially of chlorides towards the EZ-anode is significant despite the weak electric field – several hundred millivolts - generated by the galvanic current. Results show that chloride ions accumulate near the zinc-anode as in water-insoluble zinc-hydroxy chlorides - Simonkolleit. T2 - ICCRRR 2022 CY - Capetown, South Africa DA - 03.10.2022 KW - Korrosion KW - Corrosion KW - LIBS KW - Zinc PY - 2022 AN - OPUS4-55948 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Romero Navarrete, J. A. A1 - Otremba, Frank A1 - Lozano Guzmán, A. A. T1 - Liquid cargo effect on load transfer under orthogonal accelerations N2 - A methodology is proposed for the experimental analysis of the liquid cargo effect under combined orthogonal accelerations. To simultaneously subject the vehicle-cargo system to longitudinal and lateral accelerations, the vehicle is set obliquely on a tilt table. The experimental outputs suggest that there is a significant effect of the liquid cargo on the lateral load transfer ratio (LTR), on the order of 20%, which is attributable to the resulting shifting of the liquid cargo’s centre of gravity. That is, the peak LTR values due exclusively to sloshing were not significant, in such a way that the liquid cargo would only pose a safety risk under a steady acceleration input. Also, the inverse of the product of the magnitude of the acceleration times the free surface length, correlates with the liquid cargo effect. That is, the magnitude of the input acceleration is not fully determinant for greater load transfers. KW - Sloshing KW - Liquid cargo KW - Cargo shifting KW - Lateral load transfer KW - Braking in a turn manoeuvre KW - Experimental methods KW - Transport safety PY - 2022 DO - https://doi.org/10.1504/ijhvs.2022.127011 SN - 1744-232X VL - 29 IS - 3 SP - 213 EP - 226 PB - Inderscience Enterprises CY - Geneva AN - OPUS4-56016 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klimek, André A1 - Stelzner, Ludwig A1 - Hothan, Sascha A1 - Zehfuß, J. T1 - Screening-tests on the susceptibility to spalling of two ordinary concretes N2 - Investigating the spalling behaviour of a concrete mixture using large scale members is complex and expensive. Thus, the susceptibility of concrete to spalling is investigated by means of fire tests on small scale specimens. However, the reduction of the fire exposed surface increases the influence of boundary effects. Macrocracking and the water loss via the lateral surfaces reduce the impact of the thermomechanical and thermohydraulic damage mechanisms and therefore, lower the risk of spalling. Thus, the influence of different restraints on the spalling behaviour of intermediate scaled specimens (Ø=0.47 m; h=0.29 m) was investigated for two ordinary concrete mixtures. Both mixtures had the same composition except the type of aggregate. One mixture contained only quartzitic aggregates, whereas the other mixture was made with basalt grit as coarse aggregates. Applied steel rings restrained the thermal expansion of the specimen and prevented the loss of water, whereas applied steel sheet primarily reduced the loss of water during the fire test. Additionally, the fire exposed surface of one specimen of each mixture was pre-dried under controlled climate conditions and fire tested with applied steel rings. The results show a higher spalling volume for the ring restrained specimens compared to the other covering types. Further, the pre-dried boundary zone leads to delayed and decreased occurrence of spalling compared to the non-dried specimens for the concrete with quartzitic aggregates and to a prevention of spalling for the mixture with basalt aggregates. Additionally, the results show that the influence of the thermomechanical behaviour of the coarse aggregates increases with increasing restraint. The restrained conditions of the specimens with applied steel ring are comparable to the conditions in the centre of a large scale member. This test series is a further step for possible concept of steel ring restraint concrete specimens as “screening-tests” in upcoming projects. T2 - IWCS 2022 CY - Berlin, Germany DA - 12.10.2022 KW - Spalling KW - Fire test KW - Concrete KW - Restraint PY - 2022 SP - 15 EP - 24 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-56020 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klimek, André A1 - Stelzner, Ludwig T1 - Screening-tests on the susceptibility to spalling of two ordinary concretes N2 - Investigating the spalling behaviour of a concrete mixture using large scale members is complex and expensive. Thus, the susceptibility of concrete to spalling is investigated by means of fire tests on small scale specimens. However, the reduction of the fire exposed surface increases the influence of boundary effects. Macrocracking and the water loss via the lateral surfaces reduce the impact of the thermomechanical and thermohydraulic damage mechanisms and therefore, lower the risk of spalling. Thus, the influence of different restraints on the spalling behaviour of intermediate scaled specimens (Ø0.47 m; h=0.29 m) was investigated for two ordinary concrete mixtures. Both mixtures had the same composition except the type of aggregate. One mixture contained only quartzitic aggregates, whereas the other mixture was made with basalt grit as coarse aggregates. Applied steel rings restrained the thermal expansion of the specimen and prevented the loss of water, whereas applied steel sheet primarily reduced the loss of water during the fire test. Additionally, the fire exposed surface of one specimen of each mixture was pre-dried under controlled climate conditions and fire tested with applied steel rings. The results show a higher spalling volume for the ring restrained specimens compared to the other covering types. Further, the pre-dried boundary zone leads to delayed and decreased occurrence of spalling compared to the non-dried specimens for the concrete with quartzitic aggregates and to a prevention of spalling for the mixture with basalt aggregates. Additionally, the results show that the influence of the thermomechanical behaviour of the coarse aggregates increases with increasing restraint. The restrained conditions of the specimens with applied steel ring are comparable to the conditions in the centre of a large scale member. This test series is a further step for possible concept of steel ring restraint concrete specimens as “screening-tests” in upcoming projects. T2 - 7th International Workshop on Concrete Spalling due to Fire Exposure CY - Berlin, Germany DA - 12.10.2022 KW - Spalling KW - Fire test KW - Concrete KW - Restraint PY - 2022 AN - OPUS4-56023 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Gluth, Gregor A1 - Ke, X. A1 - Vollpracht, A. A1 - Weiler, L. A1 - Bernal, S. A. A1 - Cyr, M. A1 - Dombrowski-Daube, K. A1 - Geddes, D. A. A1 - Grengg, C. A1 - Le Galliard, C. A1 - Nedeljkovic, M. A1 - Provis, J. L. A1 - Valentini, L. A1 - Walkley, B. T1 - Carbonation rate of alkali-activated concretes and high-volume SCM concretes: a literature data analysis by RILEM TC 281-CCC N2 - The current understanding of the carbonation and the prediction of the carbonation rate of alkali-activated concretes is complicated inter alia by the wide range of binder chemistries used and testing conditions adopted. To overcome some of the limitations of individual studies and to identify general correlations between mix design parameters and carbonation resistance, the RILEM TC 281-CCC ‘Carbonation of Concrete with Supplementary Cementitious Materials’ Working Group 6 compiled and analysed carbonation data for alkali-activated concretes and mortars from the literature. For comparison purposes, data for blended Portland cement-based concretes with a high percentage of SCMs (≥ 66% of the binder) were also included in the database. The analysis indicates that water/CaO ratio and water/binder ratio exert an influence on the carbonation resistance of alkali-activated concretes; however, these parameters are not good indicators of the carbonation resistance when considered individually. A better indicator of the carbonation resistance of alkali-activated concretes under conditions approximating natural carbonation appears to be their water/(CaO + MgOeq + Na2Oeq + K2Oeq) ratio, where the subscript ‘eq’ indicates an equivalent amount based on molar masses. Nevertheless, this ratio can serve as approximate indicator at best, as other parameters also affect the carbonation resistance of alkali-activated concretes. In addition, the analysis of the database points to peculiarities of accelerated tests using elevated CO2 concentrations for low-Ca alkali-activated concretes, indicating that even at the relatively modest concentration of 1% CO2, accelerated testing may lead to inaccurate predictions of the carbonation resistance under natural exposure conditions. KW - Alkali-activated materials KW - Durability KW - Carbonation KW - Accelerated testing PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-560037 DO - https://doi.org/10.1617/s11527-022-02041-4 VL - 55 IS - 8 SP - 1 EP - 15 PB - Springer Nature AN - OPUS4-56003 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Patzelt, Anne-Katrin A1 - Krentel, Daniel A1 - Wiesner, Anja T1 - InnoBOSK - Ergebnisse der Bedarfserhebung N2 - Im Projekt InnoBOSK wurden insgesamt vier wissenschaftlich basierte Bedarfserhebungsworkshops durchgeführt. Die Workshops hatten jeweils thematische Schwerpunkte und wurden mit Vertretern unterschiedlicher BOS (Behörden und Organisationen mit Sicherheitsaufgaben) durchgeführt. In der vorliegenden Arbeit werden die erhobenen Bedarfe ausgewertet. KW - BOS KW - InnoBOSK KW - Bedarfserhebung KW - Forschungsbedarf PY - 2022 SP - 1 EP - 23 AN - OPUS4-55831 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Epple, Niklas A1 - Fontoura Barroso, Daniel A1 - Niederleithinger, Ernst A1 - Hindersmann, I. A1 - Sodeikat, C. A1 - Groschup, R. T1 - Monitoring of a German Road Bridge Using Embedded Ultrasonic Transducers and Coda Waves N2 - The ‘G¨anstorbr¨ucke’ bridge between the cities of Ulm and Neu-Ulm is one of the best-monitored bridges all over Germany. In addition to an already active bride monitoring system, we have equipped the bridge with 30 ultrasonic transducers to explore the monitoring possibilities at an in-service large-scale reinforced concrete structure with continuous active ultrasonic measurements. The monitoring system is based on the detection of small changes in the entire signal, especially the multiply scattered parts of the recording, the so-called coda. Applying Coda Wave Interferometry (CWI), subtle changes in the signal can be detected and related to changing velocities in the area between source and receiver. A comparison of the results from coda wave interferometry with the strain measurements of the permanent monitoring system shows a correlation between strain measurements and CWI results. We discuss the challenges of changing environmental conditions, pose for interpretation of the results, and highlight the advantages of embedded versus externally attached ultrasonic transducers in permanent bridge monitoring, especially when coda wave interferometry is applied. T2 - EWSHM 2022 CY - Palermo, Italy DA - 04.07.2022 KW - Bridge monitoring KW - Ultrasound KW - Embedded sensors KW - Coda wave interferometry PY - 2022 AN - OPUS4-55383 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Epple, Niklas A1 - Fontoura Barroso, Daniel A1 - Niederleithinger, Ernst A1 - Hindersmann, I. A1 - Sodeikat, C. A1 - Groschup, R. ED - Rizzo, P. ED - Milazzo, A. T1 - From the Lab to the Structure: Monitoring of a German Road Bridge Using Embedded Ultrasonic Transducers and Coda Waves N2 - The ‘Gänstorbrücke’ bridge between the cities of Ulm and Neu-Ulm is one of the best-monitored bridges all over Germany. In addition to an already active bride monitoring system, we have equipped the bridge with 30 ultrasonic transducers to explore the monitoring possibilities at an in-service large-scale reinforced concrete structure with continuous active ultrasonic measurements. The monitoring system is based on the detection of small changes in the entire signal, especially the multiply scattered parts of the recording, the so-called coda. Applying Coda Wave Interferometry (CWI), subtle changes in the signal can be detected and related to changing velocities in the area between source and receiver. A comparison of the results from coda wave interferometry with the strain measurements of the permanent monitoring system shows a correlation between strain measurements and CWI results. We discuss the challenges of changing environmental conditions, pose for interpretation of the results, and highlight the advantages of embedded versus externally attached ultrasonic transducers in permanent bridge monitoring, especially when coda wave interferometry is applied. KW - Bridge monitoring KW - Ultrasound KW - Embedded sensors KW - Coda wave interferometry PY - 2022 SN - 978-3-031-07258-1 DO - https://doi.org/10.1007/978-3-031-07258-1_83 VL - 254 SP - 824 EP - 832 PB - Springer Cham CY - Cham AN - OPUS4-55385 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mundra, S. A1 - Furcas, F. E. A1 - Huthwelker, T. A1 - Simon, Sebastian A1 - Borca, C. N. A1 - Provis, J. L. A1 - Gluth, Gregor T1 - Kinetics of Sulfide Oxidation in alkaline solutions studied by X-ray absorption near-edge structure spectroscopy N2 - The oxidation of sulfur in aqueous solutions is an important process in several geochemical and industrial contexts. In concrete technology, it is particularly relevant for the protection of steel reinforcement in slag cement-based concretes, as the presence of sulfides affects the passivation of the steel and corrosion initiation in the presence of chlorides. However, the knowledge about the kinetics of sulfide oxidation in alkaline solutions, such as concrete pore solutions, is incomplete. To address this issue, we prepared solutions with 0.80 M NaOH, and nominally 10, 100 and 350 mM HS−, respectively, and followed the evolution of the sulfur species during bubbling with oxygen-containing gas (concentration 100% or 22%) using X-ray absorption near-edge structure (XANES) spectroscopy at the sulfur K-edge. Polysulfide, thiosulfate, sulfite and sulfate were identified and quantified via linear combination fitting of the spectra, using previously measured standards. A preliminary analysis of the results shows that the initial rate constant of sulfide oxidation depends strongly on the HS− concentration, while it less strongly depending on the oxygen concentration, in line with previous results for lower pH values. Approaches to fit the data to obtain the rate constants of all relevant reactions will be discussed. T2 - 41st Cement & Concrete Science Conference CY - Leeds, Great Britain DA - 12.09.2022 KW - XANES KW - Sulfide oxidation KW - Kinetics PY - 2022 SP - 1 EP - 3 PB - Institute of Materials, Minerals & Mining (IOM3) AN - OPUS4-55650 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Liao, Chun-Man A1 - Hicke, Konstantin A1 - Bernauer, F. A1 - Igel, H. A1 - Hadziioannou, C. A1 - Niederleithinger, Ernst ED - Isecke, B. ED - Krieger, J. T1 - Multi-Sensor measurements on a large-scale bridge model N2 - This contribution introduces an investigation of a large-scale prestressed concrete bridge model (“BLEIB” structure at the BAM-TTS open air test site) by means of on-site cooperative measurements. This bridge has an external post-tensioning system and has been instrumented with the ultrasonic transducers, temperature sensors and optical fibers for Distributed Acoustic Sensing (DAS). Our experiment was designed to test the suitability of the novel 6C sensors developed within the framework of the GIOTTO project – the IMU50. The IMU50 sensor enables vibration measurements in translation along three axes and rotation around three axes. The geophone sensors were considered for complementary measurements of vertical velocity response. In the experiment, several perturbations were achieved by controlling the external influence factors such as loading and prestressing changes. The aim of the integrated measurement strategy was to fully observe the results of the condition change and to verify the effectiveness of multiple sensors for bridge monitoring. T2 - 5. Brückenkolloquium CY - Ostfildern, Germany DA - 06.09.2022 KW - Concrete KW - Bridge KW - Monitoring KW - Rotation KW - Distributed acoustic sensing PY - 2022 SN - 978-3-8169-3549-0 SP - 223 EP - 230 PB - Expert Verlag CY - Tübingen AN - OPUS4-55625 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -