TY - CONF A1 - Schroeder, Nina T1 - Influence of microalloying on precipitation behavior and notched impact strength of welded high-strength structural steels N2 - This presentation summarizes the latest results on the microalloying influence on the preciptitation behavior on the mechanical properties of welded high-strength steel with a design yield strength of 690 MPa and above. For that reason, Charpy tests were performed for the pure weld metal and different heat-affected zones. Thermodynamic phase field modeling showed the usefulness of calculations in Thermocalc to predict the preciptiation behavior and (finally) to conclude the mechanistic behavior of the welded joint. T2 - IIW Intermediate meeting of Commission II-A CY - Garching, Germany DA - 06.03.2023 KW - Welding KW - High-strength steel KW - Phase field modeling KW - Preciptiates KW - Microstructure characterization PY - 2023 AN - OPUS4-57107 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Joining Processes in Hydrogen Technologies - Current need and future R&D activites, a review N2 - This study gives an overview on the important field of joining processes for component fabrication in hydrogen technologies. For that reason, the current need and future research and developement activites are highlighted for the different technological field of hydrogen generation, storage, transport and use. In addition, the emerging field of additive manufacturing is included. Finally, some remarks are given for necessary changes in the standardization and its challenges. T2 - 46th Seminar - Additive Manufacturing, Hydrogen, Energy, Integrity CY - Online meeting DA - 12.10.2021 KW - Hydrogen KW - Joining process KW - Welding KW - Review KW - Research and Development PY - 2021 AN - OPUS4-53554 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Joining processes for components in hydrogen technologies: Current need and future importance N2 - This presentation gives an overview on the importance of joining processes for component fabrication in hydrogen technologies. For that reason, the current need and future research and developement activites are highlighted for the three technological fields: hydrogen storage, transport and use (in terms of the emerging field of additive manufacturing). Finally, some remarks are given for necessary changes in the standardization. T2 - IIW Intermediate Meeting, Comm. II-A "Welding Metallurgy" CY - Online meeting DA - 17.03.2022 KW - Hydrogen KW - Welding KW - Research KW - Review KW - Additive manufacturing PY - 2022 AN - OPUS4-54488 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kromm, Arne T1 - Residual stresses and hydrogen assisted cracking in thick walled submerged arc weld joints for offshore applications N2 - Offshore wind turbines continuously increase in size and weight and demand adequate offshore foundations concepts like monopiles, tripods or jackets. These components are typically submerged arc welded (SAW) high-strength thick steel plates like the S420ML. During welding, the occurrence of delayed hydrogen assisted cracking (HAC) must be anticipated. HAC is a critical combination of the local hydrogen concentration within a susceptible microstructure under certain mechanical load, i.e., the occurring (welding) residual stresses. The welding sequence of the thick-walled plates complicate the residual stress distribution due to the necessary repeated thermal cycling, i.e., welding seam / layer deposition to fill the joint. For that purpose, SAW with two-wire-technique was used to weld a specially designed and prototype-like mock-up of a real component with a thickness of 50 mm, filled with 22 passes and a seam length of 1,000 mm. Additional welded stiffeners simulated the effect of a high restraint, to stimulate critical HAC conditions. The residual stresses were determined by a robot XRD goniometer. A least square regression analysis of the sin²ψ-law by using multiple ψ- and φ-tilts was applied. Tensile residual stresses up to the yield limit are found both in the weld metal and in the heat-affected zone. Numerical modelling allowed the qualitative estimation of the hydrogen diffusion in the weld, enabling the determination of critical conditions for the formation of HAC. In a future step, a structural simulation will allow the assessment of the welding residual stresses and the comparison to the XRD-values. T2 - International Conference on Residual Stresses ICRS-11 CY - Nancy, France DA - 27.03.2022 KW - Welding KW - X-ray diffraction KW - Hydrogen KW - Cracking KW - Offshore steel PY - 2022 AN - OPUS4-54576 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Welding (and joining) technologies for the hydrogen economy - a short overview N2 - This study gives an overview on the important field of joining processes for component fabrication in hydrogen technologies. The current main issues and future perspectives are highlighted for the different technological field of hydrogen generation, storage, transport and use. In addition, the emerging field of additive manufacturing is included. Some remarks are given for standardization and regulations. T2 - Meeting of the European Welding Association (EWA), Executive Committee (EC) 1 CY - Frankfurt am Main, Germany DA - 22.03.2023 KW - Hydrogen KW - Welding KW - Research KW - Study PY - 2023 AN - OPUS4-57222 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - A decarbonized future requires pipelines for CO2? A brief overview on perspectives and challenges N2 - Despite the use of hydrogen, for example, in various industrial production processes, CO2 emissions are still unavoidable in the medium term. For example, cement, lime and glass production or waste recycling (waste-to-energy plants) will continue to emit CO2 due to the processing involved chemical reactions. Conversely, the chemical industry with its value chains needs CO2 / carbon as a primary raw material for all compounds that fall within the organic chemistry. In this connection, carbon capture utilization (CCU) will play a key role here. In addition to “natural” methods (via reforestation and the dilution of moors), carbon capture storage (CSS) is already playing a major role, for example by injecting it into old natural gas underground caverns. The resulting quantities of CO2 have to be transported on a large scale and similar to hydrogen pipelines, there are concrete plans for CO2 pipeline networks. For this reason, this presentation provides an introduction to the topic and briefly outlines the associated challenges. On the one hand, these lie in the qualification (testing and construction) and especially in the operation of the pipelines with regard to strict monitoring of the gas quality (e.g. carbonic acid corrosion) and in the avoidance of critical service conditions (sudden pressure fluctuations), which can lead to localized condensation. Among other things, this can lead to the lowering of the typically welded low-alloyed steel pipes below the ductile brittle transition temperature (DBTT) and thus can have an impact on pipeline integrity. T2 - 49th MPA Conference CY - Stuttgart, Germany DA - 06.10.2025 KW - CO2 KW - Pipeline KW - Welding KW - Testing PY - 2025 AN - OPUS4-64316 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Ti and Nb influence on the HAZ microstructures of weld-simulated high-strength structural steel S690QL N2 - High-strength low-alloyed (HSLA) steels with yield strength / proof stress ≥ 600 MPa are the basis of modern light-weight steel constructions. Indeed, the economic and ecological benefits strongly depend on their processability in terms of welding. In this context, the use of highly productive welding processes, suitable welding consumables is of vital interest and requires a fundamental understanding of the microstructural changes in the HSLA steel and especially the heat-affected zone (HAZ) of the welded joint. Microalloying elements, such as Ti or Nb, are essential to achieve the desired mechanical properties. In this context, the underlying standards (such as EN 10025-6) only specify maximum values, resulting in different manufacturer customized microalloy concepts. Furthermore, even small deviations can have a drastic effect expressed by an excessive hardening or softening despite identical welding conditions and filler metal. The reason is the different thermal stability of the Ti and Nb-related precipitates (typically carbides or carbon nitrides). As a result, it is difficult (or even impossible) to adequately predict the weldability. Against this background, different microalloying routes with varying Ti and Nb contents for a S690QL reference grade were systematically investigated in terms of lab-cast alloys close to realistic chemical compositions. To investigate the influence of the welding heat input on the HAZ microstructure formation, physical simulations were carried with specified peak temperatures and cooling times (by a dilatometry). The focus was the identification of the occurring phase transformations during cooling and the final HAZ microstructure. In this context, a double welding cycle was simulated to further identify the behavior of the so-called intercritical HAZ (where softening is likely to occur) in case of the common multi-layer welding for thick plates. The results showed: (1) microalloying has significant influence on the formation of the individual HAZ dependent on (2) the thermal stability of the Ti or Nb-precipitates and (3) synergistic effects of further elements such as Mo and their effect on phase transformations in the HAZ. The results represent a microstructure-based validation of welding processing of such HSLA-steels e.g. in terms of preferred microalloy and weld heat input combinations. T2 - 49th MPA Conference CY - Stuttgart, Germany DA - 06.10.2025 KW - High-strength steel KW - Microalloy elements KW - Welding KW - Weld simulation KW - Microstructure PY - 2025 AN - OPUS4-64319 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Manzoni, Anna Maria T1 - Mechanical performance and integrity of tungsten inert gas (TIG) welded CoCrFeMnNi high entropy alloy with austenitic steel AISI 304 N2 - High entropy alloys (HEA) are a new class of materials that have been investigated since the early 2000s and offer great potential to replace conventional alloys. However, since they sometimes have significant contents of expensive alloying elements such as Co or Ni, their use is only conceivable in highly stressed areas of components. For this purpose, the weldability with conventional alloys such as high-alloy austenitic steels must be investigated. In addition to the resulting microstructure, the mechanical properties are also fundamental for the usability of HEAs in DMWs. For this purpose, TIG welds of CoCrFeMnNi HEA (cold rolled and recrystallized state) with AISI 304 austenitic steel are investigated. These mechanical properties are analyzed in this work by means of tensile tests and local hardness measurement. The local strain behavior of the welded joints is also characterized by means of Digital Image Correlation (DIC). The results of the local hardness measurement show a clear influence of the initial condition of the HEA on the HAZ. Thus, the HEA in the cold-rolled condition shows a clear softening because of recrystallization processes in the HAZ. On the other hand, there is no influence on the hardness of the weld metal, which is approx. 200 HV0.1 in both cases. The tensile tests show a consistent failure of the weld in the weld metal. However, regardless of the HEA condition, strengths in the range of the recrystallized HEA (RM ~ 550–600 MPa) are achieved, although with significantly reduced fracture elongations. T2 - International Conference on High-Entropy Materials (ICHEM 2023) CY - Knoxville, TN, USA DA - 18.06.2023 KW - Multi-principal element alloys KW - Welding KW - Mechanical properties KW - Dissimilar metal weld KW - Digital image correlation PY - 2023 AN - OPUS4-57713 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael T1 - Processing and application properties of multiple principal element alloys (MPEA) N2 - The presentation gives an overview of BAM's activities on processing influences and application properties of MPEAs in the form of joined and machined high and medium entropy alloys (CoCrFeMnNi and CoCrNi). In the case of welding, the focus is on defect-free welded joints with sufficient mechanical properties. In the case of machining, the focus is on the possible influence on the surface quality of the materials through adequate milling parameters. In addition, the hydrogen absorption and diffusion properties as well as the electrochemical corrosion behavior are fundamentally examined. T2 - FAU-Department Werkstoffwissenschaften, Seminar: Aktuelle Probleme der Werkstoffwissenschaften CY - Erlangen, Germany DA - 25.04.2024 KW - Welding KW - Application properties KW - Machining KW - High-entropy alloy KW - Hydrogen PY - 2024 AN - OPUS4-59975 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -