TY - CONF A1 - Waurischk, Tina A1 - Balzer, R. A1 - Kiefer, P. A1 - Müller, Ralf A1 - Reinsch, Stefan A1 - Behrens, H. A1 - Deubener, J. T1 - The influence of volatile constituents on mechanical properties of glasses N2 - Im Rahmen des Young Researcher Day des SPP1594 wurden die bisherigen Inhalte der Projekte zusammengefasst und vorgetragen. T2 - Annual Meeting and Young Researcher Day CY - Jena, Germany DA - 11.09.2018 KW - Glass KW - Crack growth KW - Vickers KW - DCB KW - Water speciation PY - 2018 AN - OPUS4-46728 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Nofz, Marianne T1 - High temperature coatings (Book review) N2 - All in all, practicing professionals as well as researchers can read this book with pleasure and great benefit. It presents a comprehensive collection of data and practical examples manifested in about 100 graphs, 80 schemes of processes and devices, a manifold of images showing the microstructure of alloys or details of components and several phase diagrams. Tables containing data on commercially available coatings, alloys, compositions of corrosive salts, function of constituents of coatings add further important pieces of information. Thus, this book is a valuable source of information for anyone engaged in work with or research on high temperature coatings. KW - Coating KW - High temperature PY - 2018 DO - https://doi.org/10.1002/maco.201870104 SN - 0947-5117 VL - 69 IS - 10 SP - 1490 EP - 1490 PB - Wiley‐VCH Verlag GmbH & Co. KGaA CY - Weinheim AN - OPUS4-46749 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tielemann, Christopher A1 - Kirzdörfer, Adrian A1 - Reinsch, Stefan A1 - Müller, Ralf T1 - First hints on reorientation of surface crystals N2 - Up to now, the mechanisms of surface nucleation and surface-induced texture formation are far from being understood. Very few observations of crystal orientation were focused on separately growing surface crystals. In conclusion, no systematic studies on initially oriented crystal growth or nucleation from defined active surface nucleation sites exists. Therefore, the main objective of this just is to advance the basic understanding of the mechanisms of surface-induced microstructure formation in glass ceramics. As a first attempt, we focus on reorientation of separately growing surface crystals during their early growth. T2 - 92nd Annual Meeting of the German Society of Glass Technology in Conjunction with the Annual Meetings of the Czech Glass Society & the Slovak Glass Society CY - Bayreuth, Germany DA - 28. Mai 2018 KW - Glass KW - Crystallization KW - BCS PY - 2018 AN - OPUS4-47536 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tielemann, Christopher A1 - Reinsch, Stefan A1 - Patzig, C. A1 - Höche, T. A1 - Busch, R. T1 - Surface Initiated Microstructure Formation in Glass -Ceramics N2 - Übersicht zur Oberflächeninitiierten Mikrostrukturbildung in Glasoberflächen. Dabei wird auf die Kristallvorzugsorientierung senkrecht zur Oberfläche der sich unter Temperatureinfluss behandelten Glasproben eingegangen. Zudem werden die ersten Experimente zur Eingrenzung des Ursprungs dieser Orientierung vorgestellt. N2 - Overview about the surface initiated microstructure formation in glass surfaces. Samples which are exposed to a temperature treatment, can develop a crystalline microstructure above Tg at the surface. These separated crystals can be preferably oriented towards the surface of the sample. First experiments about the origin of these orientation phenomenon as well as the potentially causing mechanisms are presented and discussed within the presentation. T2 - AK Glasig-kristalline Multifunktionswerkstoffe 2019 CY - TU Clausthal, Germany DA - 21.02.2019 KW - Orientation KW - Glass KW - Crystallization KW - Diopside PY - 2019 AN - OPUS4-47537 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Abel, Andreas A1 - Rosalie, Julian M. A1 - Reinsch, Stefan A1 - Zapala, Pawel A1 - Michels, Heiner A1 - Skrotzki, Birgit T1 - Influence of Mo and B additions in intermetallic near-Fe3Al alloys on microstructure and mechanical properties N2 - Iron aluminides, already reported in the late 19th century, did not cease to attract the interest of scientists and engineers ever since. Besides good oxidation resistance, low density and resource availability, potentials for hightemperature strengths that compete with high-alloy steels were unlocked by low alloy contents. Still, research on alloy design continues, as alloying usually comes at the price of brittleness in low-temperature regimes. A potential candidate is the quinary Fe–Al–Mo–Ti–B system which is strengthened by solid solution and eutectic borides. It was shown to have good strength and outstanding creep resistance under compressive loading up to elevated temperatures. Although the individual effect of alloy additions is well understood in iron aluminides, little is known about the combined effects of alloying concentrations on microstructure, phase stability and mechanical properties. Therefore a systematic study of two Ti-doped near-Fe3Al alloys with varying contents of Mo (2–4 at.%) and B (0.5–1 at.%) was conducted. In total eight different alloys were fabricated by investment casting into ceramic shell molds. Alloys were characterized and compared by grain size, phase transitions, microstructure evolution as well as elemental compositions and volume fractions of phases. For mechanical characterization, macrohardness and microhardness tests as well as tensile tests at ambient and high tempera tures were conducted. Independent of alloy additions, alloys with 24–25 at.% Al exhibit superior proof strength due to a higher matrix hardness. Decreasing B content generally decreases strength by lower secondary phase fractions which contribute via particle hardening. Reducing Mo content decreases both the solute concentration in the matrix and secondary phase fractions. Surprisingly, strength is similar or even superior to alloys with higher Mo content. Strength relations are discussed with a focus on solid-solution hardening theory and other competing strengthening mechanisms. KW - Materials Chemistry KW - Metals and Alloys KW - Mechanical Engineering KW - Mechanics of Materials KW - General Chemistry PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-585284 DO - https://doi.org/10.1016/j.intermet.2023.108074 VL - 163 SP - 1 EP - 11 PB - Elsevier Ltd. AN - OPUS4-58528 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Aristia, Gabriela A1 - Le, Quynh Hoa A1 - Nofz, Marianne A1 - Sojref, Regine A1 - Bäßler, Ralph T1 - Study of Al2O3 Sol-Gel Coatings on X20Cr13 in Artificial North German Basin Geothermal Water at 150 °C N2 - Al2O3 has been widely used as a coating in industrial applications due to its excellent chemical and thermal resistance. Considering high temperatures and aggressive mediums exist in geothermal systems, Al2O3 can be a potential coating candidate to protect steels in geothermal applications. In this study, γ-Al2O3 was used as a coating on martensitic steels by applying AlOOH sol followed by a heat treatment at 600 °C. To evaluate the coating application process, one-, two-, and three-layer coatings were tested in the artificial North German Basin (NGB), containing 166 g/L Cl−, at 150 °C and 1 MPa for 168 h. To reveal the stability of the Al2O3 coating in NGB solution, three-layer coatings were used in exposure tests for 24, 168, 672, and 1296 h, followed by surface and cross-section characterization. SEM images show that the Al2O3 coating was stable up to 1296 h of exposure, where the outer layer mostly transformed into boehmite AlOOH with needle-like crystals dominating the surface. Closer analysis of cross-sections showed that the interface between each layer was affected in long-term exposure tests, which caused local delamination after 168 h of exposure. In separate experiments, electrochemical impedance spectroscopy (EIS) was performed at 150 °C to evaluate the changes of coatings within the first 24 h. Results showed that the most significant decrease in the impedance is within 6 h, which can be associated with the electrolyte penetration through the coating, followed by the formation of AlOOH. Here, results of both short-term EIS measurements (up to 24 h) and long-term exposure tests (up to 1296 h) are discussed. KW - Al2O3 KW - Geothermal KW - Martensitic steels KW - Behmite KW - Corrosion PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-525551 DO - https://doi.org/10.3390/coatings11050526 SN - 2079-6412 VL - 11 IS - 5 SP - 526 PB - MDPI CY - Basel AN - OPUS4-52555 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Portella, Pedro Dolabella A1 - Müller, Ralf T1 - The contribution of the Platform MaterialDigital (PMD) in building up a Materials Data Space - Application to glass design and manufacturing N2 - Suitable material solutions are of key importance in designing and producing components for engineering systems – either for functional or structural applications. Materials data are generated, transferred, and introduced at each step along the complete life cycle of a component. A reliable materials data space is therefore crucial in the digital transformation of an industrial branch. A great challenge in establishing a materials data space lies in the complexity and diversity of materials science and engineering. It must be able to handle data from different knowledge areas over several magnitudes of length scale. The Platform MaterialDigital (PMD) is expected to network a large number of repositories of materials data, allowing the direct contact of different stakeholders as materials producers, testing labs, designers and end users. Following the FAIR principles, it will promote the semantic interoperability across the frontiers of materials classes. In the frame of a large joint initiative, PMD works intensively together with currently near 20 research consortia in promoting this exchange (www.material-digital.de). In this presentation we will describe the status of our Platform MaterialDigital. We will also present in more detail the activities of GlasDigital, one of the joint projects mentioned above dealing with the digitalization of glass design and manufacturing. (https://www.bam.de/Content/EN/Projects/GlasDigital/glasdigital.html) T2 - Onto Commons Workshop CY - Berlin, Germany DA - 04.04.2023 KW - Ontology KW - Data space PY - 2023 AN - OPUS4-58732 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Finn, Monika A1 - Uhlemann, Patrick A1 - Meyer, Christian A1 - Scheuerlein, C. A1 - Amez-Droz, M. A1 - Meuter, F. A1 - Konstantopoulou, K. A1 - Savary, F. A1 - Tock, J.-P. T1 - Thermomechanical properties of polymers for use in superconducting magnets N2 - The coefficient of thermal expansion (CTE) and the thermomechanical properties of the polymers used in superconducting magnets need to be known in order to predict their stress state under the different magnet assembly and operating conditions. We have measured Young’s moduli of typically used polymers during in situ heat cycles with the dynamic resonancemethod. The dynamic test results are compared with Young’s moduli determined from quasi-static stress–strain measurements at room temperature, 77 K and 4.2 K. A moderate elastic anisotropy is found for the fiber reinforced polymers. CTEs are compared based on dilation experiments. TheCTEs of the fiber reinforced polymers studied are similar to those of copper or steel. In contrast, the pure resins exhibit relatively larger CTEs. KW - Polymer KW - Superconducting magnet KW - Young´s modulus KW - Stress-strain behavior KW - Resonance testing KW - Coefficient of thermal expansion PY - 2019 DO - https://doi.org/10.1109/TASC.2019.2898321 SN - 1051-8223 SN - 1558-2515 VL - 29 IS - 5 SP - 7701605, 1 EP - 5 PB - IEEE AN - OPUS4-47616 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Deubener, J. A1 - Behrens, H. A1 - Müller, Ralf T1 - An overview on the effect of dissolved water on the viscosity of soda lime silicate melts N2 - In this review article, the impact of dissolved water on the viscous properties of soda lime silicate melts is addressed against the background of the upcoming switch from natural gas to hydrogen combustion. This change will lead to an increase in the total water content of the glasses by up to 0.4 mol%. In order to better define possible influences of water speciation, water-rich glasses were synthesised under increasing pressure up to the kbar range. It is shown that a distinction must be made between the influence of dissolved OH-groups and H2Omolecules in order to accurately reflect the dependence of isokom temperatures on water content. In addition, an increase of one order of magnitude in the tolerance to higher deformation rates was observed for the range of expected increased water contents during isothermal deformation processes, which is based on the timetemperature superposition principle, i.e. congruent flow curves were determined under isokomal conditions. KW - Water in glass KW - Viscosity KW - Soda lime silicate glass KW - Shear thinning KW - Nydrogen melting PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-587276 DO - https://doi.org/10.1016/j.nocx.2023.100195 VL - 19 SP - 1 EP - 10 PB - Elsevier B.V. AN - OPUS4-58727 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reinsch, Stefan A1 - Welter, T. A1 - Müller, Ralf A1 - Deubener, J. T1 - Hydrogen Permeability of Tectosilicate Glasses for Tank Barrier Liners N2 - The permeation of hydrogen gas was studied in meta-aluminous (tectosilicate) glass powders of Li2O×Al2O3×SiO2 (LAS), Na2O×Al2O3×SiO2 (NAS) and MgO×Al2O3×SiO2 (MAS) systems by pressure loading and vacuum extraction in the temperatures range 210–310 °C. With this method, both the solubility S and the diffusivity D were determined, while the permeability was given by the product SD. For all glasses, S was found to decrease with temperature, while D increased. Since the activation energy of diffusion of H2 molecules exceeded that of dissolution, permeation increased slightly with temperature. When extrapolated to standard conditions (25 °C), the permeability of tectosilicate glasses was found to be only 10-22–10-24 mol H2 (m s Pa)-1, which is 8–10 magnitudes lower than most polymers. Thin glass liners of these compositions are expected to be the most effective barrier for tanks of pressurised hydrogen. KW - Hydrogen permeation KW - Aluminosilicate glasses KW - Hydrogen storage tank KW - Glass liner PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-587284 DO - https://doi.org/10.52825/glass-europe.v1i.425 VL - 1 SP - 1 EP - 11 AN - OPUS4-58728 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -