TY - CONF A1 - Rabin, Ira T1 - Studies of the black writing inks N2 - In recent years, the interest in the composition of the inks in papyri documents grew exponentially. Different types of inks were found in the period 4th century BCE to 7th century CE. The paper will demonstrate a simple protocol based on comparison of the ink transparency in the near infrared light and X-ray fluorescence spectroscopy. The importance of including ink composition into new catalogues and possible formats of such data will be also presented and discussed. T2 - 31st International Congress of Papyrology CY - Cologne, Germany DA - 28.07.2025 KW - Ink KW - Historic ink KW - Papyrus PY - 2025 AN - OPUS4-64777 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rabin, Ira T1 - Inks in Early Medieval Manuscripts from Chelles: a Scientific Study N2 - The talk will start with the overview of the ink types and the methods of their characterisation. After displaying XRF spectra of different Carolingian inks the talk will discuss Chelles collection and the labels attributed to Chelles. We will concentrate then on the study of the Chelles manuscripts preserved in Cologne, Vatican and Paris. We will show that there is a good degree of coincidence between the inks of the Chelles manuscripts and the labels attributed to Chelles. We observe unusually early use of vitriolic ink north of the Alps. T2 - Leeds International Medieval Congress (IMC 2025) CY - Leeds, United Kingdom DA - 07.07.2025 KW - Ink KW - Historic ink PY - 2025 AN - OPUS4-64778 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Koerdt, Andrea T1 - The Power of networks – COST Action CA20130 N2 - For optimal research on microbiologically influenced corrosion (MIC), balanced and interdisciplinary cooperation is extremely important. However, differing perspectives, thought processes, and even variations in nomenclature/terminology often hinder the establishment of effective collaborations. Over the past four years, COST Action Euro-MIC (CA20130) has effectively addressed these discrepancies. Through regular meetings, conferences, and scientific exchanges, a large international network has been established. Many scientific findings and results have been achieved through scientific, interdisciplinary exchange within the international network. The upcoming presentation will highlight three examples (among many others) that have resulted in successful collaborations, third-party funding applications, publications, or outstanding results and emphasize that successful results in MIC research, facilitated by an interdisciplinary network, can lead more quickly to meaningful and application-oriented findings. Project 1&2 describe two different kinds of Projects related to the use of Nanoparticles; one is about the efficacy testing of novel Nanoparticles. Project 2 deals about how to apply already working and tested nanoparticles to different materials and conditions. Project 3a is related to the energy sector; a crucial part of our society, and currently undergoing significant changes. Climate change, rising temperatures, increased use of fertilizers and other environmental pollutants have led to an increasing occurrence of microorganisms and contamination in some sectors. But how we deal with “baggage” from the past and store nuclear waste without harm or risk for human and environment, but also how to transfer the gained knowledge to areas like safe Hydrogen storage in geological underground formation. T2 - ISMOS10 CY - Nashville, TN, USA DA - 11.08.2025 KW - COST Action CA20130 KW - MIC KW - STSM Grants KW - Networking PY - 2025 AN - OPUS4-64295 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Koerdt, Andrea T1 - Euro-MIC COST Action CA20130 Closing Workshop & Conference N2 - Ensuring the safety of offshore wind structures (OWS) is critical to guaranteeing their long-term performance and supporting reliable green energy supply. Microbiologically influenced corrosion (MIC) presents a significant challenge, particularly for monopiles in seabed environments. This study investigates the behavior of microorganisms and their impact on the corrosion process of carbon steel within monopiles. To simulate MIC at the sediment/water interface, an in-house experimental column was developed and inoculated with sediment and water samples from the North Sea. The system was operated under varying flow rates to replicate seabed movement conditions. Multiple molecular microbiological methods, surface analysis techniques, and other approaches were employed to assess the effects of different treatments. This study provides insights into MIC mechanisms in offshore environments and supports the development of strategies to monitor MIC in OWS infrastructure T2 - Final COST Action Conference - Horsens CY - Horsens, Denmark DA - 17.09.2025 KW - MIC KW - COST Action Euro-MIC KW - Interdisciplinarity PY - 2025 AN - OPUS4-64299 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Koerdt, Andrea T1 - Euro-MIC 2021-2025, our journey, and paths forward N2 - Microbiologically Influenced Corrosion (MIC) refers to the detrimental effects on materials caused by microorganisms, and it is becoming an increasingly significant issue for society. Unlike the USA, Canada, and Australia, Europe has less developed cooperation on MIC. Although several research groups and industrial stakeholders are addressing MIC, discussions remain fragmented, and information exchange is limited. A truly transdisciplinary approach is rarely seen. As a result, Europe often relies on methods, preventive measures, and standards from other regions, as there are no equivalent European standards. This situation makes Europe a) highly dependent, and b) in some cases, unable to use certain measures or standards due to European legal restrictions (e.g., the use of biocides). In 2021, researchers established the “Euro-MIC” network, financially supported by the EU project “COST-Action,” to tackle these issues. Through COST-Action, Euro-MIC aims to facilitate necessary interactions, communication, knowledge sharing, and training for personnel and researchers across various disciplines. COST-Action supports network activities, workshops, training schools, conferences, and more. Euro-MIC aspires to position Europe as a leader in MIC, promoting ideas on par with other nations while upholding European values and ensuring greater protection for people, property, and the environment. In this presentation, I will briefly introduce the principles of COST Action and highlight the significant opportunities provided by this EU-funded project. COST Action fosters interdisciplinarity, networking, training, scientific exchange, and the promotion of young scientists. By showcasing some examples of CA20130 COST ACTION Euro-MIC, I hope to demonstrate that COST Action is not only relevant for addressing MIC but can also be applied to other important topics and sectors. T2 - Unseen Corrosion: Unveiling Hidden Threats and Innovating Monitoring Solutions CY - Bergen, Norway DA - 15.05.2025 KW - COST Action CA20130 KW - MIC KW - Network KW - Corrosion KW - Microorganisms PY - 2025 UR - https://www.norceresearch.no/en/events/unseen-corrosion AN - OPUS4-63726 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Braymer, Joseph T1 - Methanobacterium IM1 as a model organism to study MIC N2 - Microbiologically influenced corrosion (MIC), also known as biocorrosion, is a process where microbes corrode metal surfaces causing detrimental damage to manmade infrastructure. Several studies, mainly under anaerobic conditions, have identified sulfate-reducing bacteria and methanogens as key players in biocorrosion. However, an important issue is that most MIC-related microbes at the moment are non-culturable. In addition, improved technologies (i.e., omics, biochemical, and microscopy methods) are needed to study, detect, simulate, and modulate MIC-related cases. Therefore, the selection of strains that can cause MIC, are culturable, and are genetically accessible, are of high importance for establishing new methods to study MIC on the molecular level. For example, the archaeal strain Methanobacterium IM1 has caught great attention due to its involvement in biocorrosion processes. Genes encoding for a novel enzyme (MIC NiFe-hydrogenase) have been proposed in this methanogen to be directly related to the e T2 - International Biodeterioration and Biodegradation Symposium 19 CY - Berlin, Germany DA - 11.09.2024 KW - Biocorrosion KW - Methanogen KW - Iron KW - Hydrogenase KW - Mechanism PY - 2024 AN - OPUS4-61508 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Olbrich, Adelina-Elisa A1 - An Stepec, Biwen Annie A1 - Wurzler, Nina A1 - Terol, E. C. A1 - Koerdt, Andrea A1 - Meermann, Björn T1 - Beyond corrosion: Development of a single cell-ICP-ToF-MS method to uncover the process of microbiologically influenced corrosion N2 - The development of the microbiologically influenced corrosion ( MIC ) -specific inductively coupled plasma-time of flight-mass spectrometry ( ICP-ToF-MS ) analytical method presented here, in combination with the investigation of steel-MIC interactions, contributes significantly to progress in instrumental MIC analysis. For this, a MIC-specific staining procedure was developed, which ensures the analysis of intact cells. It allows the analysis of archaea at a single cell level, which is extremely scarce compared to other well-characterized organisms. The detection method revealed elemental selectivity for the corrosive methanogenic strain Methanobacterium -affiliated IM1. Hence, the possible uptake of individual elements from different steel samples was investigated and results showed the cells responded at a single-cell level to the different types of supplemented elements and displayed the abilities to uptake chromium, vanadium, titanium, cobalt, and molybdenum from solid metal surfaces. The methods developed and information obtained will be used in the future to elucidate underlying mechanisms, compliment well-developed methods, such as SEM-EDS, and develop novel material protection concepts. KW - Single cell KW - Microbiological influenced corrosion MIC KW - Sc-ICP-ToF-MS KW - Method development KW - Ir DNA staining approach KW - Carbon steel corrosion PY - 2022 DO - https://doi.org/10.1093/mtomcs/mfac083 SN - 1756-591X VL - 14 IS - 11 SP - 1 EP - 15 PB - Oxford University Press CY - Oxford AN - OPUS4-56254 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dinter, Adelina-Elisa T1 - Development of a single cell-ICP-ToF-MS-method for multielement analysis of MIC organisms grown on solid steel samples N2 - The latest ICP-MS technology - ICP-ToF (time of flight)-MS – enables the analysis of the multi-element fingerprint of individual cells. The interface between material and environmental analysis thus receives special attention, e.g., when considering corrosion processes. Microbiologically influenced corrosion (MIC) is a highly unpredictable phenomenon due to the influence of the environment, microbial communities involved and the respective electron source. However, the interaction pathway between cells and the metal surface remains unclear. The development of the MIC-specific ICP-ToF-MS analytical method presented here at the single cell level, in combination with the investigation of steel-MIC interactions, contributes significantly to progress in instrumental MIC analysis and will enable clarification of the processes taking place. For this, a MIC-specific staining procedure was developed. It allows the analysis of archaea at a single cell level and provides information about the interaction of the cells with the staining agent which is extremely scarce compared to other well characterized organisms. Additionally, the single cell ICP-ToF-MS is used for the analysis of archaea involved in MIC of steel. Hence, the possible uptake of individual elements from different steel samples is investigated - the information obtained will be used in the future to elucidate underlying mechanisms and develop possible material protection concepts, thus combining modern methods of analytical sciences with materials. T2 - DAAS Doktorandenseminar 2021 CY - Online meeting DA - 20.09.2021 KW - Sc-ICP-ToF-MS KW - Single cell analysis KW - Microbiologically influenced corrosion KW - Archaea PY - 2021 AN - OPUS4-53340 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kirsch, Klemens T1 - Microbiologically Influenced Corrosion of Cast Iron Containers for High-Level Nuclear Waste Disposal N2 - Ductile and corrosion resistant cast iron is investigated as a potential container material to store high-level nuclear waste (HLW) in deep geological repositories (DGR) in claystone bedrock. The dynamic corrosion process is dependent on the conditions present in the DGR which are influenced and/or controlled by geochemical parameters (e.g., redox potential, pH, presence of and ionic concentration in (pore-)water), physical parameters (e.g., pressure), and the influence of metabolically active microorganisms. Cast iron corrosion will occur at the intersection of container and its decontaminable coating with the bentonite backfill material which contains natural microbial populations. The conditions in a DGR are simulated in microcosm experiments to investigate the impact of microbiologically influenced corrosion (MIC); the microcosms contain: B27 bentonite, synthetic pore water, N2 or N2-CO2 atmosphere, cast iron coupons, as well as the bacterium Desulfosporosinus burensis (isolated from repository depth in Buré, France). Three coupon configurations will be used: untreated, coated with decontaminable coating, and coated with decontaminable coating which has been damaged to simulate possible damages. The microcosms will be examined for bio- and geochemical parameters, such as pH, redox potential, mineral phases, sulphate concentration, Fe(II):Fe(III), changes in microbial populations, and the corrosion process for formation of corrosion products, and potential microbial influence, after a 270-day incubation period at 25°C under anaerobic conditions. In subsequent experiments, the sorption behavior of lanthanides and actinides onto the membranes of viable cells and spores of D. burensis, as well as the surface of corroded cast iron coupons will be investigated. T2 - 8th International Workshop on Long-term Prediction of Corrosion in Nuclear Waste Systems 2022 CY - Baden, Switzerland DA - 21.06.2022 KW - Microbiologically influenced corrosion (MIC) KW - Cast iron KW - Nuclear waste disposal PY - 2022 AN - OPUS4-55154 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Olbrich, Adelina-Elisa T1 - Material vs. Environment: Uncovering microbiological influenced corrosion processes on steel with single cell-ICP-ToF-MS N2 - Microbiologically influenced corrosion (MIC) is a highly unpredictable process dictated by the environment, microorganisms, and the respective electron source. Interaction pathways between cells and the metal surface remain unclear. The development of this novel single cell-inductively coupled plasma-time of flight-mass spectrometry analytical method and a MIC-specific staining procedure facilitate the investigation of steel-MIC interactions. With this it is possible to analyze the multi-elemental fingerprint of individual cells. The detection method revealed elemental selectivity for the corrosive methanogenic archaeal strain Methanobacterium-affiliated IM1. The interface between material and environmental analysis thus receives special attention, e.g., when considering MIC on solid steel. Hence, the possible uptake of individual elements from different steel samples is investigated. Results showed the cells responded at a single-cell level to the different types of supplemented elements and displayed the abilities to interact with chromium, vanadium, titanium, cobalt, and molybdenum from solid metal surfaces. The information obtained will be used in the future to elucidate underlying mechanisms and develop possible material protection concepts, thus combining modern methods of analytical sciences with materials research. T2 - ToFcon 2022 CY - Online meeting DA - 17.11.2022 KW - Single cell KW - Microbiological influenced corrosion MIC KW - Sc-ICP-ToF-MS KW - Method development KW - Ir DNA staining approach KW - Carbon steel corrosion PY - 2022 AN - OPUS4-56355 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Koerdt, Andrea T1 - Simulating Microbiologically Influenced Corrosion (MIC) at Seabed Environment in Monopile N2 - Ensuring the safety of offshore wind structures (OWS) is critical to guaranteeing their long-term performance and supporting reliable green energy supply. Microbiologically influenced corrosion (MIC) presents a significant challenge, particularly for monopiles in seabed environments. This study investigates the behavior of microorganisms and their impact on the corrosion process of carbon steel within monopiles. To simulate MIC at the sediment/water interface, an in-house experimental column was developed and inoculated with sediment and water samples from the North Sea. The system was operated under varying flow rates to replicate seabed movement conditions. Multiple molecular microbiological methods, surface analysis techniques, and other approaches were employed to assess the effects of different treatments. This study provides insights into MIC mechanisms in offshore environments and supports the development of strategies to monitor MIC in OWS infrastructure T2 - ISMOS10 CY - Nashville, TN, USA DA - 11.08.2025 KW - MIC KW - Environmental Simulation KW - Field testing KW - Marine Environment PY - 2025 AN - OPUS4-64298 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Koerdt, Andrea T1 - COST-Action - EURO-MIC (CA20130) European MIC Network - New paths for science, sustainability and standards N2 - Microbiologically Influenced Corrosion (MIC) is a phenomenon that is increasingly becoming a problem for the society. MIC describes the negative effects a material can experience due to the presence of microorganisms. In Europe, several research groups/ other industrial stakeholders are already dealing with MIC. Unfortunately, the discussions are fragmented and the exchange of information is limited. A true transdisciplinary approach is hardly ever experienced, although this would be logical for this material/biology related challenge. USA, Canada and Australia have strong networks, and develop methods, prevention measures and standards, which Europe is forced to use, since nothing similar exists for a network and combined knowledge to design them according to european standards. This makes Europe extremely dependent and, in some cases, the potential measures or standards cannot been used because the suggested solutions are prohibited by European laws (e.g. use of biocides). Therefore, it is important to initiate a new European MIC-network. Europe needs to combine the efforts as experts in different fields and develop prevention measures according to the European rules, in close cooperation with industry and plant operators and owners of critical infrastructure. This COST Action will provide the necessary interaction and communication, knowledge sharing, training of personnel and of researchers of different disciplines. This will bring Europe to a leading role in this process, bringing ideas on an equal level with other nations, considering the values which are important for Europe and attitudes (e.g.environmental protection) and representing greater protection for people, property and the environment. The main aim and objective of the Action is to , in the context of MIC-research/control, encourage a fluent/synergistic collaboration/communication, closing the gap between materials scientists, engineers, microbiologists, chemists and integrity managers to encourage sufficient interaction between academia and industry. This Action will create a common MIC-Network, including the important stakeholders. T2 - EuroCorr CY - Online meeting DA - 19.09.2021 KW - COST Action KW - MIC KW - Interdisciplinary KW - Stakeholder KW - Academia PY - 2021 AN - OPUS4-53382 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Abilio, André T1 - Expert System for Screening Microbiologically Influenced Corrosion asInternal Failure Cause in Oil and Gas Upstream Pipelines N2 - The analysis of pipeline failures due to Microbiologically Influenced Corrosion (MIC) is challenging due to the complex interaction of many influencing parameters including pipeline operation conditions, fluid chemistry and microbiology, as well as the analysis of corrosion features and products. To help address this challenge, an expert system was developed to assist non-specialists in screening internal pipeline corrosion failures due to MIC related threats. To accomplish this, 15 MIC subject matter experts (with a total of 355 man-years of accumulated MIC based experience) were recruited to evaluate a total of 65 MIC failure cases based on real-life scenarios. These case study parameters and the expert elicited results were input into an Artificial Neural Network (ANN) model to create a model system which can screen whether a given failure scenario is one of three outcomes: a) failure is likely due to MIC, b) failure is likely not due to MIC, or c) the conclusion is inconclusive (analysis needs more data/information). The model system had an overall accuracy of 74.8%and it showcases that knowledge from subject matter experts can be captured in a reasonably effective way to screen for possible MIC failures. Based on that, this presentation will provide details of the model development process and key results to date. Important considerations regarding the level of confidence of the diagnoses and variation between expert opinion will also be discussed alongside with ideas on how to improve the model for field applicability. T2 - ISMOS 9 CY - Edinburgh, United Kingdom DA - 27.06.2023 KW - Expert System KW - Microbiologically Influenced Corrosion (MIC) KW - Oil and Gas Upstream KW - Artificial neural networks (ANNs) KW - Failure analysis PY - 2023 AN - OPUS4-64602 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Frenzel, Olivia A1 - Westphalen, Tanja A1 - Kaminski, Katja A1 - Kluge, Stephanie A1 - Bücker, Michael A1 - Piechotta, Christian T1 - Evaluation and Validation of an Accelerated Weathering Procedure to Characterise the Release of Bisphenol A from Polycarbonate Under Exposure to Simulated Environmental Conditions N2 - Bisphenol A (BPA) has been listed as a substance of very high concern (SVHC) due to its endocrine-disrupting properties according to REACH in 2017. European competent authorities have prepared a REACH restriction proposal to reduce BPA levels in the environment. The proposed limit for the concentration of free BPA and other bisphenols in articles is 10 mg kg−1. If exceeded, migration testing can demonstrate that no more than 0.04 mg L−1 is released from the product or material over its lifetime. German authorities are drafting a new restriction proposal after the original was temporarily withdrawn. The residual and migration limits mentioned above were key requirements from the previous restriction proposal. Numerous national and international standards exist for assessing how environmental factors affect the physical and chemical properties of products and materials—such as notch impact strength and tensile strength—but these standards do not cover the release of pollutants. A standardised procedure that covers all aspects of artificial weathering and monitors the subsequent release of pollutants is necessary, especially in the context of the regulation of these substances. An accelerated weathering procedure was established for non-protected samples. This material was not intended for outdoor applications. The testing procedure applied a typical weathering scenario that represents Central European climate conditions. The procedure was validated and applied to samples under distinct quality assurance aspects. Released BPA is quantified via an organic isotope dilution LC-MS/MS method. In parallel, identical samples were weathered outdoors on a weathering rack. Haze and yellowness index are measured to compare outdoor and weathering chamber results. KW - Artificial weathering KW - Polycarbonate KW - Bisphenol A KW - Simulated environmental conditions PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-645020 DO - https://doi.org/10.3390/app151910361 SN - 2076-3417 VL - 15 IS - 19 SP - 1 EP - 15 PB - MDPI AG AN - OPUS4-64502 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Desvergnes, Amélie Couvrat A1 - Helman-Wazny, Agnieszka T1 - Sialkoti paper used by Pahari artists: Raw materials and fibre analysis N2 - This study aims to characterise the so-called Sialkoti paper used to produce Pahari drawings preserved today in the Wereldmuseum in Leiden (Netherlands) (WML). These works originate from the Punjab Hills in India (today Himachal Pradesh) and are commonly known as ‘Pahari miniature paintings’. The paper upon which these drawings are executed is said to have been produced in Sialkot during the eighteenth and nineteenth centuries when papermaking was an integral part of an overall regional economy correlated with other sectors such as agriculture and the textile industry. Although the term Sialkoti refers to identified papermills in Sialkot (now Pakistan), the paper from this region is yet to be subjected to a systematic study. This article therefore explores the paper(s) in question through macro- and microscopic observations of structure, pulp and fibres. The study of historical sources, complemented by the analysis of paper samples and fibre identification, has revealed that the pulp would have been prepared from a variety of manufactured products using different technologies, such as rags, cloth, mats, rope and other plant-based materials made from local bast fibres which, once tattered, were recycled to prepare the pulp. Microscopic study reveals that a variety of fibre combinations under different conditions and processing steps were used, in particular sunn hemp fibre (Crotalaria juncea L.), a plant species that has until now rarely been identified in historical paper. In addition, the presence of kenaf and jute fibres, as well as a significant quantity of cotton fibres, have also been demonstrated. To overcome the lack of comparative materials, our work was supported by a comparative study of several materials made from sunn hemp now held in the Ethnobotany Collection at Kew Gardens. Samples were taken from these materials and provided useful reference micrographs for the identification of the WML samples. The quality of the paper used by Pahari artists, as well as the raw materials available and their processing, are discussed in detail. Putting all the data, including technical and historical information into perspective, we conclude that the Pahari artists used a paper of inferior quality compared to other types of paper used for other purposes such as the creation of illuminated manuscripts in the Punjab plains. This study therefore provides useful analytical and material evidence that complements previous historical, technical and anthropological studies. KW - Sialkoti paper KW - Pahari drawings KW - Indian handmade paper KW - Sunn hemp KW - Fibre identification KW - Microscopy PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-645216 DO - https://doi.org/10.1186/s40494-024-01360-9 SN - 2050-7445 VL - 12 SP - 1 EP - 18 PB - Springer CY - Cham AN - OPUS4-64521 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - de Araujo Abilio, André A1 - Wolodko, John D. A1 - Eckert, Richard B. A1 - Skovhus, Torben L. T1 - Development of an expert system for assessing failures in oil and gas pipelines due to microbiologically influenced corrosion (MIC) N2 - This study highlights the modeling of an expert system for the classification of internal microbiologically influenced corrosion (MIC) failures related to pipelines in the upstream oil and gas industry. The model is based on artificial neural networks (ANNs) and involves the participation of 15 MIC experts. Each expert evaluated a number of model case studies ranging from MIC- to non-MIC-driven upstream pipeline failures. The model accounts for variations in microbiological testing methods, microbiological sample types, and degradation morphology, among other variables. It also accounts for missing datasets, which is commonly the case in actual failure assessments. The outcome is an expert system model whose outputs are classes (classification ANN) which comprises MIC potential and data confidence. The performances of two approaches are contrasted in this study. One classifies the output in 5 classes, a 5-output classification (5OC) model; the other in 3 classes, a 3-output classification (3OC) model. The 5OC model had an accuracy of 62.0% while the simpler 3OC model had a better accuracy of 74.8%. This modelling exercise has demonstrated that knowledge from experts can be captured in a reasonably effective model to screen for possible MIC failures. It is hoped that this study not only may contribute to a better understanding of the prevalence of MIC in the oil and gas sector, but also may highlight the key areas necessary to improve the diagnosis of MIC failures in the future. KW - Corrosion engineering KW - Oil and gas pipelines KW - Carbon steel KW - Artificial neural networks (ANNs) KW - Failure analysis KW - Microbiologically influenced corrosion (MIC) KW - Expert systems PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-632084 DO - https://doi.org/10.1016/j.engfailanal.2024.108426 SN - 1350-6307 VL - 163 SP - 1 EP - 16 PB - Elsevier Ltd. AN - OPUS4-63208 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Malefioudaki, Mariella A1 - Misra, Archismita A1 - Sbeity, Nadja A1 - Zueco-Vincelle, Juan A1 - Laguna-Bercero, Miguel A. A1 - Koerdt, Andrea A1 - Martín-Rapún, Rafael A1 - Mitchell, Scott G. T1 - Multifunctional polyoxomolybdate ionic liquid coatings for mitigating microbiologically influenced corrosion N2 - Corrosion of metals and other materials in marine environments poses significant economic, operational, safety, and environmental challenges across the oil and gas industry, the renewable energy sector, and maritime infrastructure. Microbiologically influenced corrosion (MIC) accounts for a substantial portion of this corrosion, with sulfate-reducing bacteria (SRB) and methanogenic archaea (MA) being key contributors. Conventional methods such as cathodic polarization have proven insufficient in mitigating the colonization of corrosive microbial communities in real marine environments, requiring the development of alternative, broad-spectrum antimicrobial strategies to prevent such biofilm formation. Recently, molybdate has emerged as a potential alternative to traditional biocides and nitrate. Our hypothesis is polyoxometalate-ionic liquids (POM-ILs), which exhibit antimicrobial and anticorrosion properties, could have a broader spectrum of antimicrobial activity than demonstrated until now and could be capable of shielding and protecting sensitive metal surfaces from the extreme acidic environments produced by MIC microorganisms. Here we show how two prototype polyoxomolybdate-based POM-ILs, [(CH3(CH2)6)4N]2[Mo6O19] and [(CH3(CH2)6)4N]4[Mo8O26], demonstrated antimicrobial activity at microgram per millilitre concentrations, prevented biofilm formation on metal surfaces, and provided resistance to corrosive acidic environments. Furthermore, impedance measurements were commensurate with electron microscopy studies showing that POM-IL-coated brass coupons withstood extremely corrosive environments. These proof-of-concept results demonstrate how multi-functional POM-IL coatings represent promising MIC mitigation solutions by providing a hydrophobic acid-resistant and biocidal protective layer that prevents biocolonisation and acidic corrosion by MIC microorganisms. KW - Polyoxometalates KW - Ionic liquid KW - Microbiologically influenced corrosion KW - Corrosion KW - Heritage preservation PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-631951 DO - https://doi.org/10.1039/d5mh00373c SN - 2051-6347 VL - 12 IS - 13 SP - 4648 EP - 4661 PB - Royal Society of Chemistry (RSC) CY - Cambridge AN - OPUS4-63195 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Erdmann, Maren A1 - Kleinbub, Sherin A1 - Wachtendorf, Volker A1 - Schütter, Jan David A1 - Niebergall, Ute A1 - Böhning, Martin A1 - Koerdt, Andrea T1 - Photo-oxidation of PE-HD affecting polymer/fuel interaction and bacterial attachment N2 - In the present study, a simple approach was used to investigate the effect of UV-exposure on two high density Polyethylene materials (PE-HD), commonly used for storage tanks, on fuel sorption behavior and colonization by microorganisms. The aim was to investigate whether the sorption behavior of the fuels (diesel/biodiesel) and the colonization by microorganisms, frequently occurring in the fuel, is affected and may lead to undesirable or safety-relevant material changes. We showed that the UV-irradiation leads to significant changes of the sorption behavior due to chemi-crystallization and crosslinking. The fuel Sorption is affected by the UV-induced formation of polar carbonyl and hydroxyl groups predominantly occurring at the surface. With respect to microbial colonization behavior for Bacillus subtilis and Pseudomonas aeruginosa, isolated from a contaminated diesel sample, differences of the initial adhesion could be shown depending on the initial type of polyethylene as well as on the degree of UV-induced degradation. KW - High density polyethylene KW - Bacterial attachment KW - UV-irradiation KW - Fuel sorption PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-510001 DO - https://doi.org/10.1038/s41529-020-0122-1 VL - 4 IS - 1 SP - Article number: 18 PB - Nature Partner Journals AN - OPUS4-51000 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - An, Biwen Annie A1 - Kunte, Hans-Jörg A1 - Koerdt, Andrea ED - Eibergen, N. ED - Poulassichidis, T. T1 - Microbiologically Influenced Corrosion (MIC) by Halophilic (Salt-Loving) Nitrate and Sulfate-Reducing Microorganisms N2 - The survey of Canadian shale sites showed a dominance of halophilic microorganisms, including Halomonas (HA). Nitrate-amended incubations of the field samples under high salinity (14.6% NaCl), revealed a dominance of HA (>72%) and an accumulation of nitrite. Nitrite accumulation directly inhibited the growth of SRB, thereby decreasing their souring and corrosion risks. However, accumulated nitrite may also contribute to iron corrosion, which will be tested by using different concentrations of nitrate as an electron acceptor to HA. Different salinities are further tested on HA strains supplemented with iron coupons to determine their effects on iron corrosion rates. HA incubated with separate cultures of corrosive methanogen and SRB were tested to determine whether a positive or adverse effect will occur between them. Lastly, analyses of iron coupons will be conducted using TOF-SIMS, FIB-SEM and EDS for corrosion product characterization T2 - Corrosion 2021 CY - Online Meeting DA - 19.04.2021 KW - MIC KW - Bacteria KW - Halophile KW - Corrosion KW - Environmental condition KW - Korrosion KW - High salinity PY - 2021 UR - https://my.nace.org/PaperTrail/Authors/Submission.aspx?id=2914f145-7f8f-ea11-813a-005056a95a7c SP - Paper C2021-16284, 1 AN - OPUS4-52479 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Misra, Archismita T1 - Polyoxometalate Ionic Liquids as Protective Coatings for Industrial Infrastructure and Cultural Heritage against Microbiologically Influenced Corrosion (MIC) N2 - Corrosion of stone and metal due to acid rain and biodeterioration poses significant challenges for industrial and residential infrastructure, as well as cultural heritage, including statues and historical artefacts. A promising mitigation strategy involves thin, transparent films of polyoxometalate-based ionic liquids (POM-ILs) as chemical shields. Stone samples coated with acid-resistant, biocidal POM-ILs exhibited negligible corrosion when exposed to simulated acid rain, in stark contrast to the severe deterioration of unprotected samples. Additionally, their biocidal properties effectively prevent biofilm formation on coated surfaces. Following studies successfully explored the effectiveness of the coating against lampenflora growing in the Pommery Champagne cellar; and the long-term performance of POM-ILs under outdoor environmental conditions. So, POM-ILs have already demonstrated remarkable anticorrosion and antimicrobial properties against aerobic microorganisms and, being water-insoluble, do not leach into aquatic ecosystem. The current research project repurposes the POM-ILs, extending their application to metals, specifically targeting microbiologically influenced corrosion (MIC) in cultural heritage artefacts made of brass, carbon steel, cast iron, and bronze. This involves optimizing nanocoating adhesion to the metal surface and evaluating its protective efficacy against MIC caused by anaerobic microorganisms such as methanogenic archaea and sulfate reducing bacteria (SRB). This presentation will highlight POM-ILs as sustainable, high-performance nanocoatings for biocorrosion mitigation. It will showcase published success stories, discuss ongoing research and proof-of-concept results, and explore future prospects for these advanced materials in safeguarding metal infrastructure and artefacts across different industrial sectors as well as in the context of cultural heritage conservation. T2 - 10th International symposium on applied microbiology and molecular biology in oil systems (ISMOS10) CY - Nashville, Tennessee, USA DA - 11.08.2025 KW - Polyoxometalates KW - Corrosion KW - Microbiologically Influenced Corrosion KW - Ionic Liquid PY - 2025 AN - OPUS4-64548 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -