TY - JOUR A1 - James, G. L. A1 - Latif, M. T. A1 - Isa, M. N. M. A1 - Bakar, M. F. A. A1 - Yusuf, N. Y. M. A1 - Broughton, William A1 - Murad, A. M. A1 - Abu Bakar, F. D. T1 - Metagenomic datasets of air samples collected during episodes of severe smoke-haze in Malaysia N2 - Transboundary emissions of smoke-haze from land and forest fires have recurred annually during the dry period (June to October, over the past few decades) in South East Asia. Hazardous air quality has been recorded in Malaysia during these episodes. Agricultural practices such as slash-and-burn of biomass and peat fires particularly in Sumatera and Kalimantan, Indonesia, have been implicated as the major causes of the haze. Past findings have shown that a diversity of microbes can thrive in air including in smoke-haze polluted air. In this study, metagenomic data were generated to reveal the diversity of microorganisms in air during days with and without haze. Air samples were collected during non-haze (2013A01) and two haze (2013A04 and 2013A05) periods in the month of June 2013. DNA was extracted from the samples, subjected to Multiple Displacement Amplification and whole genome sequencing (Next Generation Sequencing) using the HiSeq 2000 Platform. Extensive bio-informatic analyses of the raw sequence data then followed. Raw reads from these six air samples were deposited in the NCBI SRA databases under Bioproject PRJNA662021 with accession numbers SRX9087478, SRX9087479 and SRX9087480. KW - Forest fires KW - Haze Samples KW - NGS KW - Multiple Displacement Amplification PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-528973 DO - https://doi.org/10.1016/j.dib.2021.107124 SN - 2352-3409 VL - 36 SP - 107124 PB - Elsevier Inc. CY - Amsterdam, Netherlands AN - OPUS4-52897 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Seneschal-Merz, Karine A1 - Bücker, Michael A1 - Wachtendorf, Volker A1 - Heidrich, Christa A1 - Sander, Christoph T1 - New UV-protective glazing for the conservation of cultural assets N2 - For centuries, churches, secular buildings and museums have been furnished with valuable works of art. Many works of art are UV- and light-sensitive. It is well known that especially UV radiation causes damage and discoloration in paintings, textiles, plastics, wood and other materials. In particular, the wavelengths between 280 and 410 nm cause color changes, embrittlement or destruction of e.g. plastics over time. Therefore, strongly UV-absorbing glasses are advantageous for architecture and are necessary for the protection of cultural assets. As restorers in all disciplines become more and more aware, the demands placed on buildings and their furnishings in terms of climate are becoming increasingly detailed and precise. The aim in each case is to preserve the valuable artwork. For some years now, the industry has been offering the protection of cultural objects by installing special UV-protective glasses. Currently, UV protection for church buildings is realized by laminated safety glass equipped with appropriate UV-protective plastic films. Technically, this always means a second pane of glass in front of the windows, which is installed outside the building. This creates climatic gaps that are difficult to control and deterioration due to ageing effects can be expected. At the same time, this protective glazing is not invisible and has a considerable aesthetic influence on the interior and exterior appearance of the building. Meanwhile, the preservation of historical monuments accepts such aesthetic cuts on buildings in order to protect the artwork in the interior from UV light. To this day, however, the long-term durability of UV protection provided by inserted plastic films is still controversial. To date the only available alternative on the market is a mouth-blown UV protection glass which uses a so-called overlay to provide UV protection. This shows that UV protection can also be achieved by glasses without plastic films thus realizing an exclusive inorganic protection which normally is more stable than a polymeric one. So far there are not enough studies to prove long-term durability. The aim of this project is to provide existing glazing or new glazing to be created with a highly transparent layer that ensures this UV-protective filter function below 400 nm. The glass coating is to be applied to the glass over a large area and fired into the surface like a classic ceramic enamel paint with the same technics. In addition, it should be long-term durable in its function. It means, that the glass has to be fused at temperatures below 630 °C during the firing process, its chemical durability has to be high, its coefficient of thermal expansion has to be as close as the one of the substrate (usually float glass) and the glass has to absorb the UV-radiation within a thin thickness (thinner as 100 µm). In this project, the long-term durability of commercial UV-protective glasses is examined. New low melting glasses containing UV-absorbing ions are being developed. Their UV-absorption as a thin layer is analyzed as well as their chemical durability and their thermal properties. We are grateful to BMWI for the financial support in the frame of the Central Innovation Programme for SMEs (ZIM). T2 - HVG-DGG: 94. Glastechnische Tagung CY - Online meeting DA - 10.05.2021 KW - Glass KW - Low melting KW - Chemical durability KW - Weathering tests KW - Aging test KW - UV absorption KW - UV protection KW - Architecture KW - Optical properties PY - 2021 AN - OPUS4-52648 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Even, Morgane A1 - Juritsch, Elevtheria A1 - Richter, Matthias T1 - Development of a procedure for the analysis of the emissions of VVOCs – Results of a research project N2 - Since 1997, the Committee for Health-related Evaluation of Building Products (AgBB) has been developing the basis for building regulations for protection against indoor health risks that may arise when building products are used. In 2009, the AgBB decided to include relevant VVOCs in the assessment procedure. The ISO 16000-6 (2021) states that the use of the thermal desorption gas chromatography technique is appropriate for VVOCs, if adaptations are considered. However, a suitable method for the trustworthy quantification of VVOC emissions from building products and in the indoor air is still missing. This webinar will present the results of a research project on the development of a procedure for VVOC analysis: • identification of the gaps towards standardization • investigations on gas standards and the suitability of chromatography columns • investigations on sorbent combinations and water management • validation of the method and screening of VVOC emissions from building products. T2 - Webinar organized by Umweltbundesamt and BAM CY - Online meeting DA - 13.09.2022 KW - Analytical method KW - EN 16516 KW - ISO 16000-6 KW - VVOCs PY - 2022 AN - OPUS4-55693 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bresch, Harald A1 - Kuchenbecker, Petra A1 - Löhmann, Oliver A1 - Rühle, Bastian A1 - Resch-Genger, Ute A1 - Hodoroaba, Vasile-Dan T1 - Schwerpunktthema nano@BAM – Projekt Nanoplattform N2 - Darstellung der Digitalisierung im Rahmen des Themenfeldprojektes Nanoplattform. Es werden beleuchtet: BAM-DataStore, Voraussetzungen für ELNs, Möglichkeitenvon OpenBIS, NFDI-Antrag InnoMatSafety, Digitalisierung von Workflows. T2 - BAM Beiratssitzung Umwelt CY - Online meeting DA - 11.03.2022 KW - Nano KW - Elektronisches Laborbuch KW - Workflows KW - Digitalisierung KW - Standardarbeitsanweisungen PY - 2022 AN - OPUS4-56756 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Jann, Oliver T1 - Emissionsarme Materialien und Produkte für eine saubere Innenraumluft N2 - Mit dem Fokus auf eine saubere Innenraumluft wird darauf eingegangen, welche Emissionen aus Materialien und Produkten es gibt und wie sie nach Art und Flüchtigkeit definiert sind und wie sie gemessen werden. Im weiteren wird dargestellt, was und wie viel aus Materialien und Produkten emittieren kann und wie die Emissionen zu bewerten sind. Hierbei wird auch auf besonders emissionsarme Materialien und Produkte eingegangen. T2 - Kolloquium am Institut für Technischen Umweltschutz, Sommersemester 2018 CY - Berlin, Germany DA - 28.05.2018 KW - Emissionen KW - Luft KW - VOC KW - Aerosol KW - Radon KW - Geruch PY - 2018 AN - OPUS4-45052 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Torge, Manfred A1 - Feldmann, Ines A1 - Günther, Tobias A1 - Wilsch, Gerd ED - Glaser, L. T1 - Analytische Untersuchungen an Glasmalfarben mittels EDX und LIBS N2 - Nach 1850 wurde zur weiteren Herabsetzung der Einbrenntemperatur von Glasmalfarben Borax (Na2B4O7 · 10 H2O) zugesetzt. Das Verhältnis war nun 1 Teil SiO2, 3 Teile PbO und 0,5 Teile Borax. Der analytische Nachweis von Bor in eingebrannten Malschichten war bisher jedoch nicht möglich.Daher wurden in Laborversuchen Glasmalfarben mit unterschiedlichem Gehalt an Borax auf Modellgläser aufgetragen, eingebrannt und anschließend unter simulierten Umweltbedingungen zeitraffend im Klimaschrank bewittert. Mit Hilfe von elektronenmikroskopischen Untersuchungen können Malschichten charakterisiert werden und somit Hinweise auf mögliche Schadensursachen liefern. Erste Versuche zum Nachweis von Bor erfolgten mit Hilfe von LIBS-Messungen (Laser Induced Breakdown Spectroscopy) an im Labor hergestellten Glasmalfarben mit unterschiedlichem Boraxgehalt. T2 - Archäometrie und Denkmalpflege 2018 CY - Hamburg, Germany DA - 20.03.2018 KW - Glasmalfarben KW - Umweltsimulation KW - Analytik PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-450664 SN - 978-3-945931-16-5 DO - https://doi.org/10.3204/DESY-PROC-2018-01 SN - 1435-8077 SP - 283 EP - 285 PB - Deutsches Elektronen -Synchrotron CY - Hamburg AN - OPUS4-45066 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Torge, Manfred A1 - Feldmann, Ines A1 - Günther, Tobias A1 - Wilsch, Gerd T1 - Analytische Untersuchungen an Glasmalfarben mittels EDX und LIBS N2 - Nach 1850 wurde zur weiteren Herabsetzung der Einbrenntemperatur von Glasmalfarben Borax (Na2B4O7 · 10 H2O) zugesetzt. Das Verhältnis war nun 1 Teil SiO2, 3 Teile PbO und 0,5 Teile Borax. Der analytische Nachweis von Bor in eingebrannten Malschichten war bisher jedoch nicht möglich. In Laborversuchen wurden Glasmalfarben mit unterschiedlichem Gehalt an Borax auf Modellgläser aufgetragen, eingebrannt und anschließend unter simulierten Umweltbedingungen zeitraffend im Klimaschrank bewittert. Mit Hilfe von elektronenmikroskopischen Untersuchungen können Malschichten charakterisiert werden und somit Hinweise auf mögliche Schadensursachen liefern. Der Nachweis von Bor erfolgte mit Hilfe von LIBS-Messungen (Laser Induced Breakdown Spectroscopy) an im Labor hergestellten Glasmalfarben mit unterschiedlichem Boraxgehalt. T2 - Archäometrie und Denkmalpflege 2018 CY - Hamburg, Germany DA - 20.04.2018 KW - Glasmalfarben KW - Umweltsimulation KW - Analytik PY - 2018 AN - OPUS4-45069 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Raedel, Martina A1 - Bücker, Michael A1 - Feldmann, Ines A1 - Reimann, Mandy T1 - Mobile anodization for the conservation of damaged architectural aluminium elements N2 - Initial situation: Aluminum is an often-used building material in modern architecture, not only for construction but as well for facades and decorative elements. In the 1950th and 1960th, after World War II, many buildings in Germany were constructed with aluminum or contain elements of colored anodized aluminum. In the last years a larger number of these buildings are increasingly in the sight of conservation works including the aluminum parts such as window frames or facade coverings. Damaged Aluminum Surfaces: Common damages are a change of color or gloss changes through weathering processes, drill holes or marks due to later modifications, scratches in the anodized layer due to extensive wear e.g. at handrails or door handles. To repair damaged aluminum surfaces, there are usually two options: smaller damaged areas are repaired by using a touch-up pen. In case of larger damages, the complete re-anodization is necessary. This includes to de-anodize the surface with cleaning and grinding the whole aluminum object. Both possibilities are disadvantageous for the objects. The touch-up pen often does not match the color of the original surface together with an insufficient corrosion protection for outdoors. While the newly anodized surface differs in color and gloss from the originally applied color. Research Approach: The whole procedure contrasts with the principal approach in conservation which aims to intervene as less as possible, in case of the conservation of an object. To fulfill this approach in a more appropriate way the research project focuses on a mobile and partial application for colored, anodized aluminum parts. To anodize aluminum the application of an electrolyte onto the surface together with sufficient voltage and current is necessary. Generally diluted sulfuric acid is used as electrolyte. Different possibilities are examined to enable the mobile application of the electrolyte, e. g. the application by producing a gel matrix or like in electroplating by pen or brush wrapped with a fleece fabric. Experimental part: First experiments are conducted to examine the structure of the anodized layer in relation with proper cleaning, anodization time with applied voltage and current and the coloring process. The aim was to reduce the preparation procedure and the anodization time as much as possible to facilitate the mobile application. Examinations with Keyence microscope, Eddy current testing and REM are performed to characterize the layers. The results are shown in table 1. A clear connection between proper cleaning, anodization time, voltage and amperage and the achieved thickness of the anodized layer is significant. Cracks in the layer show that raising the voltage and amperage results in thicker layers but as well in a crumbled and less stable anodized surface. Gel preparation: In addition to the anodization process with a liquid e.g. sulfuric acid a gel application is tested to prevent the electrolyte from rinsing down during the mobile application. For this purpose, several gel-forming agents are tested together with their stability in acid systems. It was observed, that the consistency of the gels varies dependent of the time. Conductivity: The conductivity of sulfuric acid combined with different gel-systems was measured and compared in order to predict the possible growth of layers during anodic oxidation process. Further steps: Determination and optimization of application parameters like voltage, amperage and anodization-time to build up a preferably stable and sufficient thick anodized layer. Examination of gel preparation to guarantee a stable product, enforcing with textile tape for easy application. T2 - Architectural Aluminum in the 21st Century CY - Boston, MA, USA DA - 24.03.2018 KW - Aluminum KW - Anodization KW - Historic buildings KW - Mobile application PY - 2018 AN - OPUS4-45018 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Seneschal-Merz, Karine A1 - Bücker, Michael T1 - Entwicklung von transparenten farbigen keramischen Schmelzfarben für den Einsatz auf digitalen Druckmaschinen N2 - Ziel des Projektes war es, schwermetallfreie Schmelzfarben für den Einsatz auf einem Digitaldrucker zu entwickeln. Dafür sollten die Glasfarben, bei Temperaturen unter 630°C verarbeitbar und deren Eigenschaften kompatibel mit denen von Floatgläsern sein. Zudem sollte die aufgeschmolzene Farbe transparent und im Außenbereich eingesetzt beständig sein. Weiterhin mussten die Farben eine Partikelkorngröße kleiner als 20µm besitzen, um die Druckköpfe des Digitaldruckers nicht zu verstopfen. Gute Dispergierbarkeit, thixotropes Verhalten und eine schnelle Trocknung waren weitere Voraussetzungen. Die Ersetzung von PbO durch ZnO und Bi2O3 wurde getestet und zeigte positive Ergebnisse. Ein geeigneter Mahl-und Dispergierprozess wurde entwickelt. Bei der Firma „glas&räume“ wurden die Musterfarben getestet und zeigten ein gutes Druckverhalten. Bedingt durch das Tintenstrahlverfahren erreicht der Farbauftrag keine 100%ige Transparenz. Trotzdem erscheint die transparente keramische Schmelzfarbe im Vergleich zur Verwendung von opaker Schmelzfarbe tatsächlich völlig transparent. Der Unterschied ist signifikant und öffnet so ein neues Kapitel im keramischen Digitaldruck. KW - Glass KW - Low melting KW - Chemical durability KW - Dispersion of glass particle KW - Printing KW - Architecture KW - Weathering KW - Architektur KW - Chemische Beständigkeit KW - Dispergierung von Glaspartikeln KW - Glas KW - Niedrig schmelzend KW - Druck KW - Bewitterung PY - 2018 SP - 1 EP - 61 AN - OPUS4-44650 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Blaeß, Carsten A1 - Müller, Ralf A1 - Feldmann, Ines A1 - Brauer, D.S. T1 - Sintering ability of fluoride-containing bioactive glass powder N2 - Sintered bioactive glass scaffolds of defined shape and porosity, e.g. made via additive manufacturing, must provide sufficient bioactivity and sinterability. As higher bioactivity is often linked to high corrosion and crystallization tendency, a certain compromise between sintering ability and bioactivity is therefore required. Groh et al. developed a fluoride-containing bioactive glass (F3), which allows fiber drawing and shows a bioactivity well comparable to that of Bioglass®45S5. To study whether and to what extent the sinterability of F3 glass powder is controlled by particle size, coarse and fine F3 glass powders (300-310µm and 0-32µm) were prepared by crushing, sieving and milling. Sintering, degassing and phase transformation during heating were studied with heating microscopy, vacuum hot extraction (VHE), DTA, XRD, and SEM. For the coarse glass powder, sintering proceeds slowly and is limited by surface crystallization of primary Na2CaSi2O6 crystals. Although the crystallization onset of Na2CaSi2O6 is shifted to lower temperature, full densification is attained for the fine powder. This finding indicate that certain porosity might be tuned via particle size variation. Above 900°C, intensive foaming is evident for the fine powder. VHE studies revealed that carbon species are the main foaming source. T2 - 92. Glastechnische Tagung CY - Bayreuth, Germany DA - 28.05.2018 KW - Sintering KW - Bioactive glass KW - Crystallization PY - 2018 AN - OPUS4-45568 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -