TY - CONF A1 - Liebner, Christian A1 - Schröder, Volkmar A1 - Holtappels, Kai T1 - Safety characteristics of hydrogen at super ambient conditions: Lubricant contamination influencing the Auto Ignition Temperature T2 - WHEC 2006 - 16th World Hydrogen Energy Conference CY - Lyon, France DA - 2006-06-13 KW - Hydrogen KW - Safety Characteristics KW - Auto Ignition KW - Lubricant KW - Motor Oil PY - 2013 SN - 978-1-62276-540-9 SP - 7 pages (Ref 638) PB - International Association for Hydrogen Energy CY - Lyon AN - OPUS4-12508 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Schröder, Volkmar T1 - Flammable gases and vapors N2 - ULLMANN'S Encyclopedia of Industrial Chemistry is the benchmark reference in chemistry and chemical and life science engineering, covering inorganic and organic chemicals, advanced materials, pharmaceuticals, polymers and plastics, metals and alloys, biotechnology and biotechnological products, food chemistry, process engineering and unit operations, analytical methods, environmental protection, and much more. KW - Hazardous materials KW - Gases KW - Safety characteristics KW - Flammability KW - Explosion protection PY - 2013 SN - 978-3-527-30673-2 U6 - https://doi.org/10.1002/14356007 IS - Chapter 2.2 PB - Wiley-VCH AN - OPUS4-28382 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scheid, Marc A1 - Kusche, Christian A1 - Schröder, Volkmar A1 - Barth, Uli ED - Pierucci, S. ED - Klemes, J.J. ED - De Rademaeker, E. ED - Fabiano, B. ED - Buratti, S.S. T1 - Tests on suitability of the ignition source 'exploding wire' for the determination of explosion characteristics of combustible dusts in the 20-L-sphere N2 - According to international standards several safety characteristics of dusts are determined in the 20-Lsphere (also known as SIWEK Chamber). Dust cloud ignition is carried out using pyrotechnical igniters. Due to various disadvantages of such igniters the need for alternative ignition sources arises again and again. An alternative ignition source could be the so called 'exploding wire' or 'fuse wire'. The paper presents test results of a comparative study between both ignition sources for the determination of the safety characteristics Maximum Explosion Pressure and Maximum Explosion Pressure Rise of five selected dusts in the 20-L-sphere. In addition to that the ignition mechanisms of both ignition sources were analysed by high speed camera recordings and the ignition energy was determined with electric and calorimetric recordings. T2 - 14th International symposium on loss prevention and safety promotion in the process industries CY - Florence, Italy DA - 12.05.2013 KW - Sicherheitstechnische Kenngrößen Staub KW - Staubexplosionsschutz KW - Explodierender Draht KW - Alternative Zündquelle PY - 2013 SN - 978-88-95608-22-8 U6 - https://doi.org/10.3303/CET1331118 SN - 1974-9791 N1 - Serientitel: Chemical engineering transactions – Series title: Chemical engineering transactions IS - 31 SP - 703 EP - 708 PB - AIDIC, Associazione Italiana di Ingegneria Chimica CY - Milano AN - OPUS4-28554 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ferrero, Fabio A1 - Meyer-Scherf, Ronald A1 - Kluge, Martin A1 - Schröder, Volkmar A1 - Spoormaker, T. T1 - Study of the spontaneous ignition of stoichiometric tetrafluoroethylene-air mixtures at elevated pressures N2 - The Ignition Temperature (IT) of stoichiometric tetrafluoroethylene–air mixtures on hot walls was determined in a 3-dm³-reactor. Tests at elevated pressure conditions were performed, namely at 5, 15 and 25 bar(a), showing a decrease of the IT with the initial pressure. Furthermore, the measured ignition temperatures of stoichiometric tetrafluoroethylene–air mixtures were lower than the ignition temperatures required for the decomposition pure tetrafluoroethylene (Minimum Ignition Temperature of Decomposition, MITD) reported in previous works. Equations from the Semenov thermal explosion theory on spontaneous ignition were used to identify approximate combustion kinetics of tetrafluoroethylene from the experimental results. The determined kinetics was used for the prediction of the IT of stoichiometric tetrafluoroethylene-air by simplified calculation methods. A very good agreement with the experimental results was observed. KW - Tetrafluoroethylene KW - Combustion KW - Ignition KW - Self-ignition PY - 2013 U6 - https://doi.org/10.1016/j.jlp.2013.02.008 SN - 0950-4230 SN - 1873-3352 N1 - Geburtsname von Meyer-Scherf, Ronald: Meyer, R. - Birth name of Meyer-Scherf, Ronald: Meyer, R. VL - 26 IS - 4 SP - 759 EP - 765 PB - Butterworth CY - Guildford, Surrey AN - OPUS4-28548 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ferrero, Fabio A1 - Zeps, Robert A1 - Kluge, Martin A1 - Schröder, Volkmar A1 - Spoormaker, T. ED - Pierucci, S. ED - Klemes, J.J. ED - De Rademaeker, E. ED - Fabiano, B. ED - Buratti, S.S. T1 - The explosive decomposition of tetrafluoroethylene: large scale tests and simulations N2 - There is a lack of data on the self-ignition behaviour of tetrafluoroethylene (TFE) in industrial sized equipment. In order to assess the tendency of TFE for decomposition in large scale vessels, , a facility was designed and constructed. Tests were carried out in a cylindrical reactor with a volume of 100 L with initial pressures of 5 and 10 bar(a). The effect of the reacto r adjustment (vertical or horizontal) was taken into account. The current work describes the test set up and summarizes the experimental results achieved. Furthermore, this paper reports on a numerical model for the prediction of the self -heating of TFE in closed vessels, which was previously developed for small scale reactors and has been here validated for larger dimensions with the experiments performed in the new facility. T2 - 14th International symposium on loss prevention and safety promotion in the process industries CY - Florence, Italy DA - 2013-05-12 KW - Tetrafluoroethylene KW - Self-heating KW - Large-scale reactor KW - Numerical simulation PY - 2013 SN - 978-88-95608-22-8 SN - 1974-9791 N1 - Serientitel: Chemical engineering transactions – Series title: Chemical engineering transactions IS - 31 SP - 1 EP - 6(?) PB - AIDIC, Associazione Italiana di Ingegneria Chimica CY - Milano AN - OPUS4-28549 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scheid, Marc A1 - Klippel, Alexander A1 - Tschirschwitz, Rico A1 - Schröder, Volkmar A1 - Zirker, Stefan A1 - Kusche, Christian T1 - New ignition source 'exploding wire' for the determination of explosion characteristics of combustible dusts in the 20-L-sphere N2 - According to international Standards several safety characteristics of dusts are determined in the 20-L-sphere (also known as SIWEK-Chamber). Dust cloud ignition is carried out using pyrotechnical igniters. Due to various disadvantages of pyrotechnical igniters the need for alternative ignition sources arises again and again. An alternative ignition source could be the socalled “exploding wire” or “fuse wire". The paper presents test results of a comparative study between both ignition sources for the determination of the safety characteristics Maximum Explosion Pressure and Maximum Rate of Explosion Pressure Rise of selected dusts in the 20-Lsphere. In addition to that the flame/arc propagation of both ignition sources was analysed by high speed and IR camera recordings. Tests in a windowed autoclave were performed to get information on the influence of turbulence generated due to dispersion of the dust on the shape of the generated flame and its propagation. Turbulence measurements in the windowed autoclave as well as in the 20-L-sphere with a LDA System allowed investigation if the igniter led to turbulence increase at the moment of ignition in comparison to tests without ignition. T2 - GCPS 2013 - 9th Global congress on process safety CY - San Antonio, TX, USA DA - 28.04.2013 KW - Sicherheitstechnische Kenngrößen Staub KW - Staubexplosionsschutz KW - Explodierender Draht KW - Alternative Zündquelle PY - 2013 SN - 978-0-8169-1075-5 SP - 1 EP - 10 AN - OPUS4-28552 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Scheid, Marc A1 - Klippel, Alexander A1 - Tschirschwitz, Rico A1 - Schröder, Volkmar A1 - Zirker, Stefan A1 - Kusche, Christian ED - Makhviladze, G. ED - Molkov, V. ED - Bradley, D. ED - Sunderland, P. ED - Tamanini, F. T1 - New ignition source 'exploding wire' for the determination of explosion characteristics of combustible dusts in the 20-L sphere N2 - According to international standards several safety characteristics of dusts are determined in the 20-L sphere (also known as SIWEK-Chamber). Dust cloud ignition is carried out using pyrotechnical igniters. Due to various disadvantages of pyrotechnical igniters the need for alternative ignition sources arises again and again. An alternative ignition source could be the so-called 'exploding wire' or 'fuse wire'. The paper presents test results of a comparative study between both ignition sources for the determination of the safety characteristics Maximum Explosion Pressure and Maximum Rate of Explosion Pressure Rise of selected dusts in the 20-L sphere. In addition the propagation of flame and electrical arc was analysed by high speed camera recordings. Tests in a windowed autoclave were performed to get information on the influence of turbulence during ignition on the shape of the generated flame (electrical arc) and its propagation. Turbulence measurements with a LDA system in the windowed autoclave as well as in the 20-L sphere allowed investigation if the ignition sources led to an additional turbulence increase at the moment of ignition in comparison to tests without ignition. T2 - ISFEH7 - 7th International seminar on fire & explosion hazards CY - Providence, RI, USA DA - 05.05.2013 KW - Dust explosion testing KW - Exploding wire KW - Explosion characteristics KW - Ignition source KW - Sicherheitstechnische Kenngrößen Staub KW - Staubexplosionsschutz KW - Explodierender Draht KW - Alternative Zündquelle PY - 2013 SN - 978-981-07-5936-0 SN - 978-981-07-5940-7 U6 - https://doi.org/10.3850/978-981-07-5936-0_13-04 SP - 810 EP - 819 PB - Research publishing AN - OPUS4-28553 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Volkmar A1 - Pahl, Robert T1 - Entzündbare Gasgemische in Biogasanlagen T2 - 13. BAM-PTB-Kolloquium zur chemischen und physikalischen Sicherheitstechnik CY - Braunschweig, Germany DA - 2013-06-18 PY - 2013 AN - OPUS4-28700 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Volkmar A1 - Sotelo Meza, Miriam Veronica A1 - Lohse, Volkmar T1 - Einsatz von Gasmesstechnik zur Bestimmung von Leckraten an gasgetriebenen Fahrzeugen T2 - Fachkolloquium "Gasgetriebene Fahrzeuge", VW-AG CY - Wolfsburg, Germany DA - 2013-05-28 PY - 2013 AN - OPUS4-28669 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tschirschwitz, Rico A1 - Schröder, Volkmar A1 - Brandes, E. A1 - Krause, U. T1 - Bestimmungsverfahren sicherheitstechnischer Kenngrößen bei nichtatmosphärischen Bedingungen N2 - Es werden die Untersuchungsergebnisse für ein geeignetes Zündkriterium zur Bestimmung von Explosionsgrenzen bei nichtatmosphärischen Bedingungen vorgestellt. Dazu wurden für Anfangsdrücke bis 20 bar Zündversuche an den Explosionsgrenzen von CHL/Luft-, CaHg/Luft-, H2/Luft- und NHs/Luft-Gemischen in einem Autoklav mit Sichtscheibe durchgeführt. In der Auswertung wurden visuelle Zündkriterien und ein Druckschwellenkriterium miteinander verglichen. Weiterhin wurden Untersuchungen zum erforderlichen Mindesvolumen des Explosionsgefäßes in Abhängigkeit des Anfangsdrucks durchgeführt. Dazu wurden jeweils Zündversuche mit demselben Gemisch aus CH4 und Luft bei Anfangsdrücken bis 50 bar in Volumina zwischen 0,2 dm3 und 6,0 dm3 durchgeführt. T2 - 3. Magdeburger Brand- und Explosionsschutztag / vfdb-Workshop CY - Magdeburg, Germany DA - 21.03.2013 KW - Kenngrößen KW - Nichtatmosphärische Bedingungen KW - Zündkriterium PY - 2013 SN - 978-3-00-041601-9 SP - 1 EP - 12 AN - OPUS4-28271 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -