TY - JOUR A1 - Fomine, Pavel A1 - Trotsyuk, A.V. A1 - VasilĀ“ev, A.A. A1 - Mitropetros, Constantinos A1 - Hieronymus, Hartmut A1 - Roekaerts, D. T1 - Model of chemical reaction kinetics for calculating detonation processes in gas and heterogeneous mixtures containing hydrogen peroxide N2 - An approximate two-stage kinetic model of the chemical reaction in hydrogen-oxygen mixtures containing hydrogen peroxide, water, and inert diluents is developed. The model includes one differential equation for the calculation of the molar mass of the gas after the induction period and algebraic formulas for the calculation of the heat release, internal energy and thermodynamic parameters of the mixture. Based on this model, 2D numerical simulations of a multifront gas detonation wave are performed. These pioneering simulations correspond to the stoichiometric hydrogen-oxygen mixture with hydrogen peroxide and argon additions. An approximate model of chemical equilibrium in heterogeneous gas-condensed phase systems containing hydrogen peroxide is presented. KW - H2O2 KW - Chemical kinetics KW - Detonation PY - 2006 DO - https://doi.org/10.1080/00102200500270023 SN - 0010-2202 SN - 1563-521X VL - 178 IS - 5 SP - 895 EP - 919 PB - Gordon and Breach CY - New York, NY AN - OPUS4-12394 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -