TY - JOUR A1 - Kautek, Wolfgang A1 - Reetz, Susanne A1 - Pentzien, Simone T1 - Template Electrodeposition of Nanowire Arrays on Gold Foils Fabricated by Pulsed-Laser Deposition KW - Nanodraht KW - Gold KW - Galvanisierung, elektrisch KW - Verbundwerkstoff KW - Laser KW - Impulslaser PY - 1995 SN - 0013-4686 SN - 1873-3859 VL - 40 IS - 10 SP - 1461 EP - 1468 PB - Elsevier Science CY - Kidlington AN - OPUS4-626 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kautek, Wolfgang A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Krüger, Jörg A1 - Brzezinka, Klaus-Werner T1 - Pulsed-laser deposition and boron-blending of diamond-like carbon (DLC) thin films KW - Pulslaser KW - Bor KW - Dünnfilmtechnologie KW - Dünnfilm, diamantartig PY - 1996 SN - 0169-4332 SN - 1873-5584 VL - 106 SP - 158 EP - 165 PB - North-Holland CY - Amsterdam AN - OPUS4-630 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kautek, Wolfgang A1 - Ligterink, F. J. A1 - Pedersoli Jr., J. L. A1 - Teule, R. A1 - Havermans, J. A1 - Balas, C. A1 - Pentzien, Simone A1 - Rudolph, Pascale ED - Daniels, V. T1 - Laser technology as a solution to unanswered cleaning problems in paper conservation - PARELA - a new European cooperative research project T2 - Baltimore Congress CY - Baltimore, MD, USA DA - 2002-09-02 PY - 2002 SN - 0-9500525-7-4 SP - 1(?) EP - 2(?) CY - London AN - OPUS4-1584 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kautek, Wolfgang A1 - Puchinger, L. A1 - Leichtfried, D. A1 - Pentzien, Simone ED - Meunier, M. T1 - Laser interaction with parchment in the near-ultraviolet and near-infrared wavelength range N2 - A detailed diagnostic study of the interaction of nanosecond laser pulses from the near-ultraviolet into the near-infrared wavelength range with various types of contemporary and ancient parchments is presented. The advantages of laser cleaning due to the absence of chemical agents, spectroscopic selectivity, micro-precision, computer-aided handling can only be verified when physico-chemical diagnostics guarantee destructionless processing. Scanning Electron Microscopy (SEM) data are correlated with morphological changes in dependence on the laser fluence and wavelength. The question, to what extent the chemical degradation of collagen is affected by various laser treatment parameters, could be resolved by Transmission Electron Microscopy (TEM) of collagen fibres collected from the outermost laser-exposed surface layer. It is also shown how Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFT), and Pyrolysis Capillary Gaschromatography (PY-CGC) can be employed in the chemical diagnostics of laser cleaning of parchment. This study suggests that the ageing status of parchment artefacts plays a major role in assessing the laser cleaning limits. T2 - Symposium D - European Materials Research Society CY - Strasbourg, France DA - 2002-06-18 PY - 2002 UR - http://www.emrs-strasbourg.com/files/pdf/2002_SPRING/02_Prog_Dv2.pdf N1 - Serientitel: Applied surface science – Series title: Applied surface science VL - 208/209.2003,1 IS - 1 SP - 1(?) PB - Elsevier CY - Amsterdam AN - OPUS4-1590 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Müller-Hess, D. A1 - Troschke, K.K. A1 - Kolar, J. A1 - Strlic, M. A1 - Kautek, Wolfgang A1 - Pentzien, Simone T1 - Laserreinigung von Papier - Zwischenbericht des Eurocare-Projektes 1681 LACLEPA PY - 2001 SN - 0933-4017 IS - 8 SP - 604 EP - 610 PB - Callwey CY - München AN - OPUS4-6282 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pentzien, Simone A1 - Kautek, Wolfgang A1 - Müller-Hess, D. A1 - Troschke, K. A1 - Kolar, J. A1 - Strlic, M. T1 - Cleaning of 19th century Paper Artefacs with a remote-control Laser System on Basis of a Q-Switched Nd: YAG Laser (532 nm) T2 - International Conference on Lasers in the Conservation of Artworks (LACONA V) CY - Osnabrück, Germany DA - 2003-09-15 PY - 2003 AN - OPUS4-4363 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kautek, Wolfgang A1 - Pentzien, Simone A1 - Krüger, Jörg A1 - König, E. ED - Kautek, W. ED - König, E. T1 - Laser cleaning of ancient parchments T2 - LACONA I CY - Heraklion, Crete, Greece DA - 1995-10-04 PY - 1997 SN - 3-901025-68-5 VL - 18 SP - 69 EP - 78 PB - Mayer CY - Klosterneuburg AN - OPUS4-11784 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kolar, J. A1 - Strlic, M. A1 - Pentzien, Simone A1 - Kautek, Wolfgang T1 - Near-UV, visible and IR pulsed laser light interaction with cellulose PY - 2000 UR - http://www.sciencedirect.com/science?_ob=PublicationURL&_tockey=%23TOC%236640%231991%23999289998%23271349%23FLP%23&_cdi=6640&_pubType=J&_auth=y&_acct=C000049503&_version=1&_urlVersion=0&_userid=963821&md5=0020a82b8d5f591abc3354091a7def13 U6 - https://doi.org/10.1007/s003390050031 SN - 0947-8396 VL - 71 IS - 1 SP - 87 EP - 90 PB - Springer CY - Berlin AN - OPUS4-5991 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kautek, Wolfgang A1 - Pentzien, Simone A1 - Röllig, Mathias A1 - Rudolph, Pascale A1 - Krüger, Jörg A1 - Maywald-Pitellos, C. A1 - Bansa, H. A1 - Grösswang, H. A1 - König, E. T1 - Near-UV laser interaction with contaminants and pigments on parchment: laser cleaning diagnostics by SE-microscopy, VIS-, and IR-spectroscopy PY - 2000 SN - 1296-2074 SN - 1778-3674 VL - 1 IS - sup.1 PB - Elsevier CY - Paris AN - OPUS4-5981 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kautek, Wolfgang A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Leichtfried, D. A1 - Puchinger, L. T1 - Diagnostics of parchment laser cleaning in the near-ultraviolet and near-infrared wavelength range: a systematic scanning electron microscopy study N2 - A detailed diagnostic study of the interaction of nanosecond laser pulses from the near-ultraviolet to the near-infrared wavelength range with various types of contemporary and ancient parchments is presented. The advantages of laser cleaning due to the absence of chemical agents, spectroscopic selectivity, micro-precision and computer-aided handling can only be verified when physico-chemical diagnostics guarantee destructionless processing. Scanning electron microscopy data are correlated with chemical degradation and morphological changes dependent on the laser fluence and wavelength. It is also shown how transmission electron microscopy, diffuse reflectance infrared Fourier transform spectroscopy, and pyrolysis capillary gas chromatography can be employed in the chemical diagnostics of laser cleaning of parchment. This study suggests that the ageing status of parchment artefacts plays a major role in assessing the laser cleaning limits. PY - 2003 U6 - https://doi.org/10.1016/S1296-2074(02)01195-0 SN - 1296-2074 SN - 1778-3674 VL - 4 IS - sup.1 SP - 179s EP - 184s PB - Elsevier CY - Paris AN - OPUS4-5989 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kolar, J. A1 - Strlic, M. A1 - Müller-Hess, D. A1 - Gruber, A. A1 - Troschke, K. A1 - Pentzien, Simone A1 - Kautek, Wolfgang T1 - Near-UV and visible pulsed laser interaction with paper N2 - The applicability of excimer laser at 308 nm and Nd:YAG laser at 532 nm with fluences below 0.86 J/cm2 for cleaning of cellulose and paper materials was evaluated. The extent of degradation of purified cotton cellulose and Fabriano paper after laser treatment as well as after a period of accelerated humid oven ageing was determined by following the changes in the degree of polymerization. While irradiation of paper with the excimer laser at 308 nm results in depolymerization of cellulose accompanied by a decrease in ISO brightness, no detrimental effects of Nd:YAG laser treatments were observed. PY - 2000 U6 - https://doi.org/10.1016/S1296-2074(00)00149-7 SN - 1296-2074 SN - 1778-3674 VL - 1 IS - sup.1 SP - 221 EP - 224 PB - Elsevier CY - Paris AN - OPUS4-5979 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Daminelli-Widany, Grazia A1 - Pentzien, Simone A1 - Hertwig, Andreas A1 - Krüger, Jörg T1 - Influence of film thickness on laser ablation of hydrogenated amorphous carbon films N2 - Single-pulse damage thresholds of hydrogenated amorphous carbon (a-C:H) films were measured for 8-ns laser pulses at 532-nm wavelength. Layer thicknesses from below the optical penetration depth to above the thermal diffusion length (60 nm–13 µm) were examined. After correction of the damage-threshold values for the fraction of energy effectively absorbed by the material, the damage threshold was found to increase linearly with the layer thickness, also for film thicknesses below the optical penetration depth of a-C:H. The threshold fluence reached the bulk value for a layer thickness equal to the thermal diffusion length. The thermal diffusion coefficient was obtained from fitting the experimental data. Several phenomena like graphitization, blistering, exfoliation, and ablation were observed for different fluence regimes and film thicknesses. PY - 2006 U6 - https://doi.org/10.1007/s00339-005-3460-5 SN - 0340-3793 VL - 83 IS - 1 SP - 89 EP - 94 PB - Springer CY - Berlin AN - OPUS4-12022 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pentzien, Simone A1 - Rabin, Ira A1 - Hahn, Oliver A1 - Krüger, Jörg A1 - Kleber, F. A1 - Hollaus, F. A1 - Diem, M. A1 - Sablatnig, R. ED - Park, J.-I. ED - Kim, J. T1 - Can Modern Technologies Defeat Nazi Censorship? N2 - Censorship of parts of written text was and is a common practice in totalitarian regimes. It is used to destroy information not approved by the political power. Recovering the censored text is of interest for historical studies of the text. This paper raises the question, whether a censored postcard from 1942 can be made legible by applying multispectral imaging in combination with laser cleaning. In the fields of art conservation (e.g. color measurements), investigation (e.g. Analysis of underdrawings in paintings), and historical document analysis, multispectral imaging techniques have been applied successfully to give visibility to information hidden to the human eye. The basic principle of laser cleaning is to transfer laser pulse energy to a contamination layer by an absorption process that leads to heating and evaporation of the layer. Partial laser cleaning of postcards is possible; dirt on the surface can be removed and the obscured pictures and writings made visible again. We applied both techniques to the postcard. The text could not be restored since the original ink seems to have suffered severe chemical damage. T2 - ACCV 2012 Workshops, 11th Asian conference on computer vision CY - Daejeon, Korea DA - 05.11.2012 KW - Laser cleaning KW - Multispectral imaging KW - Image restoration KW - Image enhancement PY - 2013 SN - 978-3-642-37483-8 SN - 0302-9743 VL - II IS - LNCS 7729 SP - 13 EP - 24 PB - Springer CY - Berlin Heidelberg AN - OPUS4-28160 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mann, Guido A1 - Pentzien, Simone A1 - Krüger, Jörg T1 - Beam diameter dependence of surface damage threshold of fused silica fibers and preforms for nanosecond laser treatment at 1064 nm wavelength N2 - Optical fibers made of fused silica are a common method of transmitting high laser pulse energies. Failure of those fibers is a significant risk. The determination of laser-induced damage thresholds (LIDT) on fiber end facets according to ISO 21254 standard is needed. In the past, single pulse nanosecond laser experiments showed an improvement of LIDT with increasing fiber core diameter for 1064 nm wavelength and a constant beam diameter of 50 µm. This paper pays particular attention to the influence of the laser beam diameter on damage resistance. All-silica fiber types (LEONI) with different core diameters (100–600 µm) were investigated using beam diameters in a range from 30 µm to 100 µm. For comparison experiments on fused silica preform material (Heraeus F300) were performed. On one hand, surface LIDT of fused silica preform material decreases significantly with increasing beam size. A model considering a random distribution of point defects explains the experimental data qualitatively. On the other hand, LIDT of fiber end facets stays constant. White light microscopy results suggest that the point defect density on fiber end facets is lower compared to the preform surface due to an excellent surface polish quality. KW - Laser-induced damage threshold KW - Nanosecond laser KW - Optical fiber KW - Fused silica KW - Spot size KW - Defect model PY - 2013 U6 - https://doi.org/10.1016/j.apsusc.2013.03.088 SN - 0169-4332 SN - 1873-5584 VL - 276 SP - 312 EP - 316 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-28310 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pentzien, Simone A1 - Rabin, Ira A1 - Hahn, Oliver A1 - Krüger, Jörg A1 - Kleber, F. A1 - Hollaus, F. A1 - Diem, M. A1 - Sablatnig, R. T1 - Can modern technologies defeat nazi censorship? KW - Laser cleaning KW - Multispectral imaging KW - Image enhancement KW - Ancient manuscripts KW - Image restoration PY - 2010 SN - 1556-4673 VL - 2 IS - 3, Article 1 SP - 1 EP - 16 PB - Association for Computing Machinery CY - New York, NY, USA AN - OPUS4-25651 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Schmidt, Birgit A1 - Koch, W. A1 - Pentzien, Simone A1 - Krüger, Jörg ED - Gabsch, T. T1 - Der Einsatz von Lasertechnik an Modellsystemen zentralasiatischer Wandmalereifragmente KW - Laserreinigung KW - Wandmalerei KW - Verrußung KW - Kunststoffschicht KW - Probekörper PY - 2012 SN - 978-3-7338-0385-8 IS - Kap. 10 SP - 152 EP - 157 PB - Koehler & Amelang GmbH AN - OPUS4-26178 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kotsifaki, D.G. A1 - Zekou, L. A1 - Pentzien, Simone A1 - Krüger, Jörg A1 - Serafetinides, A.A. ED - Saunders, D. ED - Strlic, M. ED - Korenberg, C. ED - Luxford, N. ED - Birkhölzer, K. T1 - Cleaning of artificially soiled papers by infrared and mid-infrared lasers N2 - One of the most important materials presenting and witnessing human culture is paper. The cleaning of paper is often necessary because contamination must be removed so that the fragile organic substrate can be preserved. The conventional cleaning methods are mechanical or involve the application of chemicals. These methods can damage drawings or print layers to some extent or make the original paper substrate brittle. More specifically, the use of a scalpel blade can cause damage to fibers. Chemical cleaning is difficult to perform locally, can dissolve foreign matter that then migrates into the paper substrate, or involves volatile organic compounds that can be harmful to the conservator. There is, therefore, a need for new conservation technologies aimed at the safe cleaning of paper. Lasers have proved to be an appropriate tool for cleaning as the energy dose and penetration depth at the specific point of contamination can be controlled. Additionally, if used properly, laser cleaning is not destructive to the paper. T2 - LACONA IX - Lasers in the conservation of artworks CY - London, UK DA - 07.09.2011 KW - Laser cleaning KW - Paper KW - Artificial soiling KW - Nanosecond laser KW - Microsecond laser PY - 2013 SN - 978-1-904982-87-6 SP - 219 EP - 221 PB - Archetype publications Ltd. AN - OPUS4-27956 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eberstein, M. A1 - Geier, M. A1 - Grießmann, H. A1 - Partsch, U. A1 - Voelkel, L. A1 - Böhme, R. A1 - Pentzien, Simone A1 - Koter, Robert A1 - Mann, Guido A1 - Bonse, Jörn A1 - Krüger, Jörg T1 - Towards an industrial laser doping process for the selective emitter using phosphoric acid as dopant N2 - Different laser supported approaches have already been realized, proving the great potential of laserdoped selective emitters (LDSE). However, it is challenging to establish a low-cost process by using pulsed laser tools. So far a single-step process only leads to satisfying results utilizing cw-lasers. In this paper we have examined a two-step process to produce laser-doped selective emitters on multicrystalline textured standard silicon photovoltaic wafers (90-Ω/sq-Emitter, SiN-antireflection coating (ARC)). The precise ARC removal by near-infrared fs-laser pulses (30 fs, 800 nm), and the doping of uncoated silicon wafers by ns-laser pulses (8 ns, 532 nm) were systematically investigated. In the fs-experiment, optimum conditions for ARC removal were identified. In the nsexperiments under suitable conditions (melting regime), the phosphorous concentration underneath the wafer surface was significantly increased and the sheet resistance was reduced by nearly a factor of two. Moreover, electrical measurements on fired metallization fingers deposited on the laser processed wafers showed low contact resistances. Hence, wafer conditioning with combined fs-laser- and ns-laser-processes are expected to be a promising technology for producing selective emitters. T2 - 26th European photovoltaic solar energy conference and exhibition CY - Hamburg, Germany DA - 05.09.2011 KW - Laser processing KW - Doping KW - Selective emitter KW - Multicrystalline silicon PY - 2011 SN - 3-936338-27-2 U6 - https://doi.org/10.4229/26thEUPVSEC2011-2BV.1.2 SP - 1220 EP - 1223 AN - OPUS4-24996 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rudolph, Pascale A1 - Pentzien, Simone A1 - Krüger, Jörg A1 - Kautek, Wolfgang A1 - König, E. T1 - Laserreinigung von Pergament und Papier PY - 1998 SN - 0933-4017 IS - 6 SP - 396 EP - 402 PB - Callwey CY - München AN - OPUS4-11598 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kautek, Wolfgang A1 - Pentzien, Simone A1 - Rudolph, Pascale A1 - Krüger, Jörg A1 - König, E. T1 - Laser interaction with coated collagen und cellulose fibre composites: fundamentals of laser cleaning of ancient parchment manuscripts and paper N2 - Laser cleaning of delicate biological composite materials such as ancient parchment manuscripts from the 15th and 16th century and printed paper from the 19th century is demonstrated with an ultraviolet excimer pulsed laser at 308 nm. Laser fluence levels must stay below the ablation and destruction threshold of the parchment or paper substrate, and have to surpass the threshold of the contaminant matter. Foreign layers to be removed must exhibit a higher optical density than the artifact substrates. Synthetic carbonaceous dirt modelled by water-soluble black crayons showed a characteristically weak featureless laser-induced plasma spectroscopy spectrum near the noise limit. It turned out that laser-induced plasma spectroscopy is of limited use in monitoring halting points (or etch-stops) because it relies on the destruction not only of the laterally inhomogenously distributed contaminant but also of pigment phases on a microscopically rough parchment substrate. Laser-induced fluorescence spectroscopy, however, promises to be a valuable non-destructive testing technique for etch-stop monitoring. KW - Laser KW - Parchment KW - Papery KW - Spectroscopy KW - Laser cleaning PY - 1998 SN - 0169-4332 SN - 1873-5584 VL - 127-129 SP - 746 EP - 754 PB - North-Holland CY - Amsterdam AN - OPUS4-11516 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Krüger, Jörg A1 - Wurster, R. T1 - Monitoring of the cleaning process of soiled paper by the investigation of laser-induced microparticles T2 - Lasers in the Conservation of Artworks VII (LACONA VII) CY - Madrid, Spain DA - 2007-09-17 PY - 2007 AN - OPUS4-15844 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Krüger, Jörg A1 - Wurster, R. ED - M. Castillejo, ED - P. Moreno, ED - M. Oujja, ED - R. Radvan, ED - J. Ruiz, T1 - Monitoring of the laser cleaning process of artificially soiled paper N2 - Laser cleaning of soiled paper is a challenging task due to the fact that a contamination has to be removed and a fragile organic material has to be preserved. The ejection of particles forms a significant channel for the removal of unwanted surface contaminations and can be exploited for an in-situ monitoring of the cleaning procedure. 532-nm-nanosecond single and multi pulse laser cleaning of artificially soiled Whatman© paper was performed. Particles were registered with a dust monitor. These in-situ experiments were combined with ex-situ investigations of cleaning and substrate damage thresholds by means of light and scanning electron microscopic techniques. The cleaning efficiency measured by a multi-spectral imaging system was compared to the in-situ particle monitoring. Additionally, possible color changes of the paper substrate were evaluated. T2 - LACONA VII International Conference, "Lasers in the Conservation of Artworks" CY - Madrid, Spain DA - 2007-09-17 PY - 2008 SN - 978-0-415-47596-9 SP - 345 EP - 351 PB - Taylor & Francis AN - OPUS4-17974 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kautek, Wolfgang A1 - Pentzien, Simone A1 - Rudolph, Pascale A1 - Krüger, Jörg A1 - Maywald-Pitellos, C. A1 - Bansa, H. A1 - Grösswang, H. A1 - König, W. ED - Fotakis, C. T1 - Near-Ultraviolet Pulsed Laser Interaction with Contaminants and Pigments on Parchment: Spectroscopic Diagnostics for Laser Cleaning Safety T2 - 5th International Conference on Optics within Life Sciences CY - H¯erakleion, Greece DA - 1998-01-01 PY - 2000 SN - 3-540-66648-6 N1 - Serientitel: Optics within life sciences – Series title: Optics within life sciences IS - 5 SP - 100 EP - 107 PB - Springer CY - Berlin AN - OPUS4-6189 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Engel, P. A1 - Krüger, Jörg A1 - Lußky, Katharina A1 - Pentzien, Simone T1 - Analyse häufig verwendeter europäischer Papiere. Im Fokus: Fasermaterial, Füllstoffe und Leimung N2 - Restauratoren können verschiedene Papierarten mit dem bloßen Auge aufgrund von Merkmalen in der Textur und der Oberflächenbeschaffenheit, seinem Aussehen im Durchlicht sowie an Griff und Klang grob unterscheiden. Dabei ist sich der Restaurator stets der Tatsache bewusst, dass es sich lediglich um eine erste grobe Einschätzung handeln kann. Erst bei mikroskopischen Analysen und physikalischen Experimenten treten Charakteristika zu Tage, die eine weitere Annäherung an die Zusammensetzung des Papiers und damit seiner Provenienz erlauben. Gegenstand dieser Arbeit war es, ein europäisches Hadernpapier, ein holzhaltiges Zeichenpapier und ein Whatman®-Filterpapier mit zwei mikroskopischen Methoden und einer Verbrennungstechnik zu untersuchen. Das Fasermaterial, die Füllstoffe, die Leimung und eventuelle Verunreinigungen wurden detailliert evaluiert. Neben konventioneller Lichtmikroskopie kam die weniger bekannte Umweltrasterelektronenmikroskopie (ESEM = Environmental Scanning Electron Microscopy) zum Einsatz, die neben der bildlichen Darstellung der Probenoberflächen zusätzlich eine Elementanalyse derselben gestattet. Letzteres erfordert allerdings das Vorhandensein eines zusätzlichen Röntgenspektrometers. Darüber hinaus wurden die verschiedenen Papiere trocken verascht. Es wurde eine oxidative Zerstörung der organischen Stoffe gewährleistet bis nur noch nichtbrennbare mineralische Asche zu verzeichnen war. Die Komplementarität der eingesetzten Methoden wird demonstriert und ein Einblick in die Zusammensetzung und Struktur der Papiere ermöglicht. Die Analysemethoden sind durch ihren partiell zerstörenden Charakter bzw. Limitierungen hinsichtlich der Objektgröße nur bedingt für die Untersuchung am Original geeignet, sehr wohl aber dafür, das Probenmaterial für Versuchsreihen genau zu definieren und zu standardisieren. PY - 2007 SN - 0933-4017 IS - 7 SP - 472 EP - 477 PB - Callwey CY - München AN - OPUS4-16046 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wurster, R. A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Krüger, Jörg T1 - Characterization of laser-generated microparticles by means of a dust monitor and SEM imaging N2 - Nanosecond laser (1064 nm wavelength) cleaning of artificially soiled paper as a model sample simulating a real-world artwork was performed. During the cleaning process, the ejection of particles was monitored in situ by means of a dust monitor (8 size classes, ranging from 0.3 µm to >2 µm) and ex situ using a mini-cascade impactor (MKI, 5 stages). The cleaning result was analyzed by scanning electron microscopy (SEM) considering possible laser-induced damages to the substrate. Size distributions of emitted particles were measured depending on the processing parameters: laser fluence, F, and pulse number per spot, N. High numbers of large (>2 µm) particles were collected by the mini-cascade impactor indicating a gas dynamical liftoff process. Obviously, these particles were not affected by the laser-matter interaction. The different methods (SEM, MKI, and dust monitor) are compared with respect to their usefulness for a proper interpretation of the cleaning results. PY - 2006 U6 - https://doi.org/10.1155/2006/31862 SN - 0278-6273 SN - 1476-3516 VL - 2006 IS - Article ID 31862 SP - 1 EP - 5(?) PB - Harwood Academic Publ. CY - London AN - OPUS4-14467 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mäder, M. A1 - Holle, H. A1 - Schreiner, M. A1 - Pentzien, Simone A1 - Krüger, Jörg A1 - Kautek, Wolfgang ED - Johann Nimmrichter, ED - Kautek, Wolfgang ED - Manfred Schreiner, T1 - Traditional and laser cleaning methods of historic picture post cards T2 - LACONA VI CY - Vienna, Austria DA - 2005-09-21 KW - Laser KW - Cleaning KW - Picture Post Card PY - 2007 SN - 978-3-540-72129-1 SN - 0930-8989 N1 - Serientitel: Springer proceedings in physics – Series title: Springer proceedings in physics IS - 116 SP - 281 EP - 286 PB - Springer CY - Berlin AN - OPUS4-16378 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lerber, K. von A1 - Strlic, M. A1 - Kolar, J. A1 - Krüger, Jörg A1 - Pentzien, Simone A1 - Kennedy, C. A1 - Wess, T. A1 - Sokhan, M. A1 - Kautek, W. ED - Johann Nimmrichter, ED - Kautek, Wolfgang ED - Manfred Schreiner, T1 - Laser cleaning of undyed silk: Indications of chemical change T2 - LACONA VI CY - Vienna, Austria DA - 2005-09-21 KW - Laser KW - Cleaning KW - Silk KW - Textiles KW - Viscometry KW - X-ray diffraction KW - SIMS PY - 2007 SN - 978-3-540-72129-1 SN - 0930-8989 N1 - Serientitel: Springer proceedings in physics – Series title: Springer proceedings in physics IS - 116 SP - 313 EP - 319 PB - Springer CY - Berlin AN - OPUS4-16379 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krüger, Jörg A1 - Pentzien, Simone A1 - Lerber, K. von ED - Johann Nimmrichter, ED - Kautek, Wolfgang ED - Manfred Schreiner, T1 - Determination of a working range for the laser cleaning of soiled silk T2 - LACONA VI CY - Vienna, Austria DA - 2005-09-21 KW - Laser KW - Cleaning KW - Silk KW - Textiles PY - 2007 SN - 978-3-540-72129-1 SN - 0930-8989 N1 - Serientitel: Springer proceedings in physics – Series title: Springer proceedings in physics IS - 116 SP - 321 EP - 327 PB - Springer CY - Berlin AN - OPUS4-16380 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Krüger, Jörg A1 - Pentzien, Simone A1 - Conradi, Andrea T1 - Cleaning of artificially soiled paper with 532-nm nanosecond laser radiation N2 - Cleaning of paper is a challenging task due to the fact that a contamination should be removed and a fragile organic original material has to be preserved. Pulsed laser cleaning of artificially soiled Whatman© filter paper samples serving as models for historical paper was performed. Different cleaning strategies employing 8-ns laser pulses at 532 nm wavelength were applied to clean paper avoiding undesired effects like discoloration (yellowing) and mechanical deterioration of the substrate. Multi shot experiments with low-energy pulses were compared with single pulse investigations utilizing high pulse energies achieving a constant energy load incident on the samples in both cases. The cleaning efficiency and possible yellowing effects were evaluated by means of a multi spectral imaging system. An extensive microscopic analysis of the cleaned parts of the samples provided insight into the remaining soiling on the surface and in the bulk of the paper material after laser treatment. As a reference, a hard and a soft eraser were used to clean the samples. KW - Laser cleaning KW - Paper KW - Colorimetry PY - 2008 U6 - https://doi.org/10.1007/s00339-008-4476-4 SN - 0947-8396 VL - 92 IS - 1 SP - 179 EP - 183 PB - Springer CY - Berlin AN - OPUS4-17331 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pilch, E. A1 - Pentzien, Simone A1 - Mädebach, Heinrich A1 - Kautek, Wolfgang ED - Dickmann, K. T1 - Anti-fungal laser treatment of paper: a model study with a laser wavelength of 532 nm T2 - Laser in the Conservation of Artworks - LACONA V CY - Osnabrück, Germany DA - 2005-09-15 PY - 2005 SN - 3-540-22996-5 SN - 0930-8989 N1 - Serientitel: Springer proceedings in physics – Series title: Springer proceedings in physics IS - 100 SP - 19 EP - 27 PB - Springer CY - Berlin AN - OPUS4-6872 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Puchinger, L. A1 - Pentzien, Simone A1 - Koter, Robert A1 - Kautek, Wolfgang ED - Dickmann, K. T1 - Chemistry of parchment-laser interaction T2 - Laser in the Conservation of Artworks - LACONA CY - Osnabrück, Germany DA - 2005-09-15 PY - 2005 SN - 3-540-22996-5 SN - 0930-8989 N1 - Serientitel: Springer proceedings in physics – Series title: Springer proceedings in physics IS - 100 SP - 51 EP - 58 PB - Springer CY - Berlin AN - OPUS4-6873 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kautek, Wolfgang A1 - Pentzien, Simone ED - Dickmann, K. T1 - Laser Cleaning System for Automated Paper and Parchment Cleaning T2 - Laser in the Conservation of Artworks - LACONA CY - Osnabrück, Germany DA - 2005-09-15 PY - 2005 SN - 3-540-22996-5 SN - 0930-8989 N1 - Serientitel: Springer proceedings in physics – Series title: Springer proceedings in physics IS - 100 SP - 403 EP - 410 PB - Springer CY - Berlin AN - OPUS4-6874 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rabin, Ira A1 - Schütz, R. A1 - Kohl, Anka A1 - Wolff, Timo A1 - Tagle, R. A1 - Pentzien, Simone A1 - Hahn, Oliver A1 - Emmel, S. T1 - Identification and classification of historical writing inks in spectroscopy: a methodological overview KW - Archaeometry KW - Non-destructive testing KW - Spectroscopy KW - Manuscript studies PY - 2012 SN - 2078-3841 VL - 3 SP - 26 EP - 30 PB - ESF CY - Strasbourg AN - OPUS4-26940 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bonse, Jörn A1 - Koter, Robert A1 - Hartelt, Manfred A1 - Spaltmann, Dirk A1 - Pentzien, Simone A1 - Höhm, S. A1 - Rosenfeld, A. A1 - Krüger, Jörg T1 - Femtosecond laser-induced periodic surface structures on steel and titanium alloy for tribological applications N2 - Laser-induced periodic surface structures (LIPSS, ripples) were generated on stainless steel (100Cr6) and titanium alloy (Ti6Al4V) surfaces upon irradiation with multiple femtosecond laser pulses (pulse duration 30 fs, central wavelength 790 nm). The experimental conditions (laser fluence, spatial spot overlap) were optimized in a sample-scanning geometry for the processing of large surface areas (5 × 5 mm²) covered homogeneously by the nanostructures. The irradiated surface regions were subjected to white light interference microscopy and scanning electron microscopy revealing spatial periods around 600 nm. The tribological performance of the nanostructured surface was characterized by reciprocal sliding against a ball of hardened steel in paraffin oil and in commercial engine oil as lubricants, followed by subsequent inspection of the wear tracks. For specific conditions, on the titanium alloy a significant reduction of the friction coefficient by a factor of more than two was observed on the laser-irradiated (LIPSS-covered) surface when compared to the non-irradiated one, indicating the potential benefit of laser surface structuring for tribological applications. PY - 2014 U6 - https://doi.org/10.1007/s00339-014-8229-2 SN - 0947-8396 VL - 117 IS - 1 SP - 103 EP - 110 PB - Springer CY - Berlin AN - OPUS4-31450 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Holle, H. A1 - Kautek, W. A1 - Pentzien, Simone A1 - Krüger, Jörg A1 - Mäder, M. A1 - Schreiner, M. T1 - Laser cleaning on historic picture postcards N2 - This contribution compares traditional cleaning and laser methods. Partial laser cleaning with a nanosecond pulse laser (wavelength of 532 nm) has proved very promising for future application in paper conservation-restoration. Traditional cleaning methods are not always sufficient or successful in surface cleaning of objects of art. Comparative studies of traditional paper cleaning methods and laser cleaning were made on several historic picture postcards printed with the chromolithography technique. PY - 2009 SN - 978-3-85028-490-5 SP - 189 EP - 206 PB - Berger Horn CY - Wien, Austria AN - OPUS4-20397 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Lussky, K. A1 - Engel, P. A1 - Krüger, Jörg ED - Engel, Patricia T1 - Laser cleaning of artificially soiled paper N2 - Laser cleaning for works of art on paper might be a supplemental, noncontact method to overcome some of the limitations of traditional dry cleaning techniques. Three different types of paper (pure-cellulose filter paper, rag paper, and wood-pulp paper) were mechanically soiled with pulverized charcoal in a standardized procedure to make model samples. These samples were characterized microscopically and by means of lightness measurements using a multi-spectral imaging system. A prototype laser workstation with Laser Class I conditions for the operator was used for the cleaning experiments. For 10-ns laser pulses at a wavelength of 532 nm, a set of laser parameters was established for a successful cleaning of the samples avoiding damage to the paper substrate. Single- and multi-pulse illumination conditions were tested. An extensive microscopic analysis after laser treatment of the cleaned parts of the samples provided insight into the remaining soiling on the surface and in the bulk of the paper material. PY - 2009 SN - 978-3-85028-490-5 SP - 171 EP - 188 PB - Berger Horn CY - Wien, Austria AN - OPUS4-20398 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Krüger, Jörg T1 - The influence of paper type and state of degradation on laser cleaning of artificially soiled paper N2 - Lasers can be a supplemental tool for restorers to overcome some of the limitations of traditional dry cleaning techniques for works of art on paper. The laser working range has to be optimized allowing for safe removal of contamination and limitation of damage to the substrate. This paper addresses the influence of paper type and state of degradation on laser working range. Three types of new paper (pure cellulose, bleached pulp paper, rag paper) were degraded and characterized with respect their degree of polymerization. Laser-induced damage thresholds of new and degraded paper were determined using SEM and viscometry. Additionally, artificially soiled model samples were made using two kinds of soiling, namely pulverized charcoal and soot-blackened standard test dust. Cleaning thresholds of soiled paper samples were evaluated. A working range for all combinations of paper and soiling between 0.05 J/cm2 and 0.5 J/cm2 was found for the application of 8-ns laser pulses at 532 nm wavelength. T2 - LACONA VIII - Lasers in the Conservation of Artworks VIII CY - Sibiu, Romania DA - 21.09.2009 KW - Nanosecond laser cleaning KW - Paper KW - Ageing KW - Degree of polymerization KW - Cleaning threshold KW - Damage threshold PY - 2011 SN - 978-0-415-58073-1 SP - 59 EP - 65 PB - Taylor & Francis CY - London, UK AN - OPUS4-23634 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Krüger, Jörg A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Lußky, Katharina A1 - Engel, P. ED - Günter Wiedemann, ED - Udo Klotzbach, ED - Ulrich Bauer-Bornemann, T1 - Laserreinigung von künstlich verschmutzten europäischen Papieren des 19. Jahrhunderts N2 - Diese Arbeit beschreibt die Laserreinigung von gebräuchlichen Papieren des 19. Jahrhunderts in Kombination mit zwei Schmutzvarianten. Aufgrund der weiten Verbreitung in Bibliotheken und Kunstsammlungen wurden Hadernpapier und holzhaltiges Papier ausgewählt. Als Referenz diente Whatman-Filterpapier. Zur künstlichen Verschmutzung wurden Zeichenkohle oder Standardschmutz (Standard Test Dust SAE J 726 fine, mit Flammruß im Verhältnis 20:1 gemischt) mit Hilfe von Pinsel und Staubsauger jeweils auf die drei Papierarten aufgetragen und in den Faserverbund eingesaugt. Die Nutzung von Modellproben erweist sich für grundlegende Untersuchungen als vorteilhaft, da das Vorhandensein hinreichend großer Flächen (gleichartiger Objekte) für einen Vergleich mit Ergebnissen klassischer Reinigungstechniken unabdingbar ist. Die preiswerten Proben erlauben darüber hinaus auch die Anwendung zerstörender Analysetechniken. Für die Laserreinigungsexperimente wurde ein Nd:YAG-Laser mit Impulsdauern in der Größenordnung von 10 ns bei 532 nm Wellenlänge und einer Repetitionsrate von 500 Hz verwendet. Die Laser-Bearbeitungsstation erlaubt die flächige Bearbeitung von Objekten, wobei der Laserstrahl bewegt wird. Der Laser wird mittels Computer ferngesteuert und unter Klasse-1-Sicherheitsbedingungen betrieben. Bei der Untersuchung der Modellproben wurde jeweils die Anzahl der Impulse pro Probenstelle sowie die Laser-Energiedichte variiert. Ziel der Arbeiten war die Ermittlung eines Laser-Arbeitsbereiches für die Reinigung der verschiedenen Papierproben. Die Modellobjekte wurden vor und nach der Laserbehandlung mittels lichtmikroskopischer, rasterelektronenmikroskopischer und colorimetrischer Analysemethoden untersucht. T2 - Tagung "Laseranwendung in Restaurierung und Denkmalpflege" CY - Osnabrück, Deutschland DA - 2009-01-30 KW - Laserreinigung KW - Nd:YAG-Laser KW - Hadernpapier KW - Holzhaltiges Papier KW - Filterpapier KW - Mikroskopie KW - Farbmessung PY - 2009 SN - 978-3-8167-8106-6 SP - 177 EP - 189 PB - Fraunhofer IRB Verl. CY - Stuttgart AN - OPUS4-20059 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Koter, Robert A1 - Krüger, Jörg T1 - Cleaning of artificially soiled paper using nanosecond, picosecond and femtosecond laser pulses N2 - Cleaning of cultural assets, especially fragile organic materials like paper, is a part of the conservation process. Laser radiation as a non-contact tool offers prospects for that purpose. For the studies presented here, paper model samples were prepared using three different paper types (pure cellulose, rag paper, and wood-pulp paper). Pure cellulose serves as reference material. Rag and woodpulp paper represent essential characteristics of the basic materials of real-world artworks. The papers were mechanically soiled employing pulverized charcoal. Pure and artificially soiled paper samples were treated with laser pulses of 28 fs (800 nm wavelength) and 8–12 ns (532 nm) duration in a multi pulse approach. Additionally, the cellulose reference material was processed with 30 ps (532 nm) laser pulses. Damage and cleaning thresholds of pure and soiled paper were determined for the different laser regimes. Laser working ranges allowing for removal of contamination and avoiding permanent modification to the substrate were found. The specimens prior and after laser illumination were characterized by light-optical microscopy (OM) and scanning electron microscopy (SEM) as well as multi spectral imaging analysis. The work extends previous nanosecond laser cleaning investigations on paper into the ultra-short pulse duration domain. KW - Laser cleaning KW - Ablation KW - Laser impact on surfaces KW - Paper KW - Femtosecond laser PY - 2010 U6 - https://doi.org/10.1007/s00339-010-5809-7 SN - 0947-8396 VL - 101 IS - 2 SP - 441 EP - 446 PB - Springer CY - Berlin AN - OPUS4-22155 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Koter, Robert A1 - Krüger, Jörg ED - Engel, P. ED - Schirò, J. ED - Larsen, R. ED - Moussakova, E. ED - Kecskeméti, I. T1 - Cleaning of soiled paper model samples using short and ultrashort laser pulses N2 - Paper is one of the most important materials representing and witnessing human culture particularly as a carrier medium for text and image. As soiling hampers the reception of information, paper cleaning techniques are needed. Traditional mechanical and chemical cleaning methods are used by conservator-restorers. In some cases, a classical cleaning procedure of paper objects yields unsatisfactory results or a conventional treatment is even impossible. Especially, fragile paper objects cause problems due to mechanical instabilities. Laser cleaning as a non-contact method might be a way to overcome some of the limitations of classical cleaning techniques. Laser parameters have to be chosen to achieve removal of the soiling without influencing the artwork. Any immediate as well as long-term effects causing an irreversible change of the artwork have to be avoided. At present, most laser applications are found in stone and metal conservation, while laser treatment of complex organic materials like paper is still not fully developed for application in conservators' workshops. This contribution describes recent work of pulsed laser cleaning of soiled model samples. Pure cellulose, rag paper and wood-pulp paper were mechanically soiled with pulverized charcoal in a standardized procedure to make model samples representing essential characteristics of contaminated real-world artworks. Afterwards, model samples were cleaned using short and ultrashort laser pulses in the nanosecond and femtosecond time domain, respectively. An extensive analysis of the model samples after laser treatment using an optical microscope and a multi-spectral imaging system allows a comparison of the cleaning results obtained with both laser sources. T2 - Conference 'New Approaches to Book and Paper Conservation - Restoration' CY - Horn, Austria DA - 09.05.2011 KW - Laser cleaning KW - Ablation KW - Laser impact on surfaces KW - Paper KW - Femtosecond laser KW - Nanosecond laser PY - 2011 SN - 978-3-85028-518-6 SP - 519 EP - 532 PB - Verlag Berger, Horn CY - Vienna, Austria AN - OPUS4-23705 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bonse, Jörn A1 - Koter, Robert A1 - Hartelt, Manfred A1 - Spaltmann, Dirk A1 - Pentzien, Simone A1 - Höhm, S. A1 - Rosenfeld, A. A1 - Krüger, Jörg T1 - Tribological performance of femtosecond laser-induced periodic surface structures on titanium and a high toughness bearing steel N2 - Laser-induced periodic surface structures (LIPSS, ripples) were processed on steel (X30CrMoN15-1) and titanium (Ti) surfaces by irradiation in air with linear polarized femtosecond laser pulses with a pulse duration of 30 fs at 790 nm wavelength. For the processing of large LIPSS covered surface areas (5 mm × 5 mm), the laser fluence and the spatial spot overlap were optimized in a sample-scanning geometry. The laser-processed surfaces were characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). Spatial LIPSS periods between 450 and 600 nm were determined. The nanostructured surface regions were tribologically tested under reciprocal sliding conditions against a 10-mm diameter ball of hardened 100Cr6 steel. Paraffin oil and engine oil were used as lubricants for 1000 sliding cycles at 1 Hz with a normal load of 1.0 N. The corresponding wear tracks were analyzed by OM and SEM. In particular cases, the laser-generated nanostructures endured the tribological treatment. Simultaneously, a significant reduction of the friction coefficient and the wear was observed in the laser-irradiated (LIPSS-covered) areas when compared to the non-irradiated surface. The experiments reveal the potential benefit of laser surface structuring for tribological applications. KW - Laser-induced periodic surface structures (LIPSS) KW - Femtosecond laser processing KW - Tribology KW - Metals PY - 2015 U6 - https://doi.org/10.1016/j.apsusc.2014.08.111 SN - 0169-4332 SN - 1873-5584 VL - 336 SP - 21 EP - 27 PB - North-Holland CY - Amsterdam AN - OPUS4-32861 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Bonse, Jörn A1 - Höhm, S. A1 - Hartelt, Manfred A1 - Spaltmann, Dirk A1 - Pentzien, Simone A1 - Koter, Robert A1 - Marschner, S. A1 - Rosenfeld, A. A1 - Krüger, Jörg ED - König, K. ED - Ostendorf, A. T1 - Femtosecond laser-induced surface nanostructures for tribological applications N2 - Laser-induced periodic surface structures (LIPSS) were generated on two types of steel (100Cr6, X30CrMoN15-1) and two types of titanium (Ti, Ti6A14V) surfaces upon irradiation with multiple linear polarized femtosecond laser pulses in air environment (pulse duration 30 fs, central wavelength 790 nm, pulse repetition rate 1 kHz, Gaussian beam shape). Teh conditions (laser fluence, spatial spot overlap) were optimized in a sample-scanning geometry for the processing of large surface areas covered homogeneously by two different types of LIPSS - either near wavelength or sub-100 nm structures. The tribological performance of the nanostructured surfaces was characterized under reciprocating sliding at 1 Hz against a ball of hardened steel using different lubricants and normal forces. After 1000 cycles the corresponding wear tracks were characterized by optical and scanning electron microscopy. For specific conditions, the wear was strongly reduced and laser-generated nanostructures endured the tribological treatment. Simultaneously, a significant reduction of the friction coefficient was observed in the laser-irradiated LIPSS-covered areas, indicating the benefit of laser surface structuring for tribological applications. The spatially Gaussian shaped beam used for the laser processing was transformed via beam shaping into a top hat distribution at the surface of the samples for optimization. The tribological performance of the laser-induced nanostructures is discussed on the basis of different physical and chemical mechanisms. PY - 2015 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-332647 SN - 978-3-11-033718-1 SN - 978-3-11-035432-4 SP - Chapter 7, 141 EP - 156 PB - De Gruyter AN - OPUS4-33264 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Legall, Herbert A1 - Schwanke, Christoph A1 - Pentzien, Simone A1 - Dittmar, G. A1 - Bonse, Jörn A1 - Krüger, Jörg T1 - X-ray emission as a potential hazard during ultrashort pulse laser material processing N2 - In laser machining with ultrashort laser pulses unwanted X-ray radiation in the keV range can be generated when a critical laser intensity is exceeded. Even if the emitted X-ray dose per pulse is low, high laser repetition rates can lead to an accumulation of X-ray doses beyond exposure safety limits. For 925 fs pulse duration at a center wavelength of 1030 nm, the X-ray emission was investigated up to an intensity of 2.6 × 10^14 W/cm2. The experiments were performed in air with a thin disk laser at a repetition rate of 400 kHz. X-ray spectra and doses were measured for various planar target materials covering a wide range of the periodic table from aluminum to tungsten. Without radiation shielding, the measured radiation doses at this high repetition rate clearly exceed the regulatory limits. Estimations for an adequate radiation shielding are provided. KW - Laser-induced X-ray emission KW - Ultrashort laser material interaction KW - Femtosecond laser KW - Radiation protection PY - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-448431 SN - 0947-8396 SN - 1432-0630 VL - 124 IS - 6 SP - Article 407, 1 EP - 8 PB - Springer AN - OPUS4-44843 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Birgit Angelika A1 - Ziemann, M. A A1 - Pentzien, Simone A1 - Gabsch, T. A1 - Koch, W. A1 - Krüger, Jörg T1 - Technical analysis of a Central Asian wall painting detached from a Buddhist cave temple on the northern Silk Road N2 - A great number of Central Asian wall paintings, archeological materials, architectural fragments, and textiles, as well as painting fragments on silk and paper, make up the so called Turfan Collection at the Asian Art Museum in Berlin. The largest part of the collection comes from the Kucha region, a very important cultural center in the third to ninth centuries. Between 1902 and 1914, four German expeditions traveled along the northern Silk Road. During these expeditions, wall paintings were detached from their original settings in Buddhist cave complexes. This paper reports a technical study of a wall painting, existing in eight fragments, from the Buddhist cave no. 40 (Ritterhöhle). Its original painted surface is soot blackened and largely illegible. Grünwedel, leader of the first and third expeditions, described the almost complete destruction of the rediscovered temple complex and evidence of fire damage. The aim of this case study is to identify the materials used for the wall paintings. Furthermore, soot deposits as well as materials from conservation interventions were of interest. Non-invasive analyses were preferred but a limited number of samples were taken to provide more precise information on the painting technique. By employing optical and scanning electron microscopy, energy dispersive X-ray spectroscopy, micro X-ray fluorescence spectroscopy, X-ray diffraction analysis, and Raman spectroscopy, a layer sequence of earthen render, a ground layer made of gypsum, and a paint layer containing a variety of inorganic pigments were identified. KW - Wall paintings KW - Central Asia KW - Silk Road KW - Pigments KW - Microscopy PY - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-357297 VL - 61 IS - 2 SP - 113 EP - 122 PB - Routledge Taylor & Francis Group CY - London AN - OPUS4-35729 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bonse, Jörn A1 - Höhm, S. A1 - Koter, Robert A1 - Hartelt, Manfred A1 - Spaltmann, Dirk A1 - Pentzien, Simone A1 - Rosenfeld, A. A1 - Krüger, Jörg T1 - Tribological performance of sub-100-nm femtosecond laser-induced periodic surface structures on titanium N2 - Sub-100-nm laser-induced periodic surface structures (LIPSS) were processed on bulk titanium (Ti) surfaces by femtosecond laser pulse irradiation in air (30 fs pulse duration, 790 nm wavelength). The laser peak fluence, the spatial spot overlap, and the number of overscans were optimized in a sample-scanning geometry in order to obtain large surface areas (5 mm × 5 mm) covered homogeneously by the LIPSS. The laser-processed regions were characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). The friction coefficient of the nanostructured surfaces was tested during 1000 cycles under reciprocal sliding conditions (1 Hz, 1.0 N normal load) against a 10-mm diameter ball of hardened 100Cr6 steel, both in paraffin oil and in engine oil used as lubricants. Subsequently, the corresponding wear tracks were qualified by OM, SEM, and energy dispersive X-ray analyses (EDX). The results of the tribological tests are discussed and compared to that obtained for near wavelength-sized fs-LIPSS, processed under somewhat different irradiation conditions. Some constraints for a beneficial effect of LIPSS on the tribological performance are provided. KW - Femtosecond laser ablation KW - Laser-induced periodic surface structures, LIPSS KW - Friction KW - Wear KW - Nanostructures KW - Surface functionalization PY - 2016 UR - http://www.sciencedirect.com/science/article/pii/S0169433215026987 U6 - https://doi.org/10.1016/j.apsusc.2015.11.019 SN - 0169-4332 SN - 1873-5584 VL - 374 SP - 190 EP - 196 PB - Elsevier B.V. CY - Amsterdam, Netherlands AN - OPUS4-35937 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Birgit Angelika A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Krüger, Jörg A1 - Roth, C. A1 - Beier, O. A1 - Hartmann, A. A1 - Grünler, B. T1 - Decontamination of biocidal loaded wooden artworks by means of laser and plasma processing N2 - Many wooden artworks are contaminated by DDT (dichlorodiphenyltrichloroethane) as a result of a surface treatment by means of the liquid preservative Hylotox-59©. It was used until the end of the 1980s. DDT crystal structures are formed on the wood surfaces by the "blooming" of chlorine compounds. In addition to an aesthetic disturbance, it is assumed that DDT represents a health risk. Even decades after applying, the toxins in the wood preservatives are still detectable because they are of low volatility in many wood samples. Contaminated waste wood with natural biocide ageing, gilded and wood carved elements of an old picture frame and wooden samples with paint layers were provided by the Schlossmuseum Sondershausen. Non-contact procedures using laser and plasma appear reasonable to remove the DDT crystals. During the experiments, health and safety issues for the operator have to be taken into account. The removal of DDT was evaluated employing femtosecond and nanosecond laser radiation and cold atmospheric plasma techniques with different working gases (air, nitrogen, and argon). Before laser application, a chlorine measurement representing the DDT density on the wooden surface is done by X-ray fluorescence (XRF) analysis as reference. After laser processing, the XRF analysis is used again at the same surface position to determine the depletion rate. Additionally, a documentation and characterization of the sample surface is performed before and after laser and plasma treatment using optical microscopy (OM). For plasma processing with various systems a chlorine measurement is done by gas chromatographic-mass spectrometry (GCMS) analysis. T2 - 11th Conference on Lasers in the Conservation of Artworks CY - Kraków, Poland DA - 20.09.2016 KW - Decontamination KW - DDT KW - Wooden artworks KW - Femtosecond laser KW - Cold atmospheric pressure plasma PY - 2017 SN - 978-83-231-3875-4 U6 - https://doi.org/10.12775/3875-4.17 SP - 241 EP - 251 PB - NCU Press CY - Toruń AN - OPUS4-43526 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bonse, Jörn A1 - Kirner, Sabrina A1 - Koter, Robert A1 - Pentzien, Simone A1 - Spaltmann, Dirk A1 - Krüger, Jörg T1 - Femtosecond laser-induced periodic surface structures on titanium nitride coatings for tribological applications N2 - Titanium nitride (TiN) was coated on different substrate materials, namely pure titanium (Ti), titanium alloy (Ti6Al4V) and steel (100Cr6), generating 2.5 μm thick TiN layers. Using femtosecond laser pulses (30 fs, 790 nm, 1 kHz pulse repetition rate), large surface areas (5 mm × 5 mm) of laser-induced periodic surface structures (LIPSS) with sub-wavelength periods ranging between 470 nm and 600 nm were generated and characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). In tribological tests, coefficients of friction (COF) of the nanostructured surfaces were determined under reciprocating sliding conditions (1 Hz, 1.0 N normal load) against a 10-mm diameter ball of hardened 100Cr6 steel during 1000 cycles using two different lubricants, namely paraffin oil and engine oil. It turned out that the substrate material, the laser fluence and the lubricant are crucial for the tribological performance. However, friction and wear could not be significantly reduced by LIPSS on TiN layers in comparison to unstructured TiN surfaces. Finally, the resulting wear tracks on the nanostructured surfaces were investigated with respect to their morphology (OM, SEM), depth (WLIM) and chemical composition by energy dispersive X-ray spectroscopy (EDX) and, on one hand, compared with each other, on the other hand, with non-structured TiN surfaces. KW - Laser-induced periodic surface structures (LIPSS) KW - Femtosecond laser ablation KW - Titanium nitride films KW - Friction KW - Wear PY - 2017 UR - http://www.sciencedirect.com/science/article/pii/S0169433216322486 U6 - https://doi.org/10.1016/j.apsusc.2016.10.132 SN - 0169-4332 SN - 1873-5584 VL - 418 IS - Part B SP - 572 EP - 579 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-40507 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Birgit Angelika A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Krüger, Jörg T1 - Femtosecond and nanosecond laser decontaminations of biocidal-loaded wooden artworks N2 - Until the end of the 1980s many wooden artworks underwent surface treatment by liquid preservatives, e.g. Hylotox-59. DDT (dichlorodiphenyltrichloroethane) crystal structures are formed on the wooden surfaces by the "blooming" of chlorine compounds by time. In addition to an aesthetic disturbance, it is assumed that DDT represents a health risk. Therefore, the removal of DDT crystals from the surfaces is requested. Contaminated wood with natural biocide ageing, gilded and wood carved elements and wooden samples with paint layers were provided by the Schlossmuseum Sondershausen, Germany. Laser cleaning on selected surface areas on the objects was done by means of femtosecond and nanosecond laser pulses. For the same object, cleaning results using 30-fs laser pulses at 800 nm wavelength are compared to findings utilizing 10-ns laser pulses at 1064 nm wavelength. Before and after laser treatment, chlorine measurements at the same surface position were done by X-ray fluorescence analysis (XRF) as an indicator for the presence of DDT. In this way, pointwise chlorine depletion rates can be obtained for the different pulse duration regimes and wavelengths. Additionally, the object surfaces were examined using optical microscopy and multi spectral imaging analysis. T2 - EMRS Spring Meeting 2017, Symposium X “New frontiers in laser interaction: from hard coatings to smart materials" CY - Strasbourg, France DA - 22.05.2017 KW - Laser cleaning KW - Decontamination KW - Wood KW - DDT KW - Femtosecond laser PY - 2017 U6 - https://doi.org/10.1007/s00339-017-1316-4 SN - 0947-8396 SN - 1432-0630 VL - 123 IS - 11 SP - Article 696, 1 EP - 9 PB - Springer AN - OPUS4-42564 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pérez Blanes, H. A1 - Ghiasi, Pouria A1 - Sandkühler, J. A1 - Yesilcicek, Yasemin A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Prinz, Carsten A1 - Al-Sabbagh, Dominik A1 - Thünemann, Andreas A1 - Özcan Sandikcioglu, Özlem A1 - Witt, Julia T1 - High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation N2 - Noble metal-free nanoparticles (NPs) based on multi-principal element alloys (MPEAs) were synthesized using a one-step pulsed laser ablation in liquids (PLALs) method for the electrochemical reduction of CO2. Laser ablation was performed in pure water or poly-(diallyldimethylammonium chloride) (PDADMAC)-containing an aqueous solution of Al8Cr17Co17Cu8Fe17Ni33 MPEA targets. Transmission electron microscopy (TEM) measurements combined with energy dispersive X-ray (EDX) mapping were used to characterize the structure and composition of the laser-generated MPEA nanoparticles (MPEA-NPs). These results confirmed the presence of a characteristic elemental distribution of a core-shell phase structure as the predominant NP species. The electrocatalytic performance of the laser-generated MPEA-NPs was characterized by linear sweep voltammetry (LSV) demonstrating an enhanced electrocatalytic CO2 activity for PDADMAC-stabilized NPs. The findings of these investigations indicate that MPEAs have great potential to replace conventional, expensive noble metal electrocatalysts. KW - Metals and Alloys KW - Surfaces KW - Biomaterials KW - Ceramics and Composites KW - Coatings and Films PY - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-588218 SN - 2238-7854 VL - 24 SP - 9434 EP - 9440 PB - Elsevier B.V. AN - OPUS4-58821 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pérez Blanes, H. A1 - Ghiasi, P. A1 - Sandkühler, J. A1 - Yesilcicek, Yasemin A1 - Pentzien, Simone A1 - Conradi, Andrea A1 - Prinz, Carsten A1 - Al-Sabbagh, Dominik A1 - Thünemann, Andreas.F. A1 - Ozcan, Ozlem A1 - Witt, Julia T1 - High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation N2 - Noble metal-free nanoparticles (NPs) based on multi-principal element alloys (MPEAs) were synthesized using a one-step pulsed laser ablation in liquids (PLALs) method for the electrochemical reduction of CO2. Laser ablation was performed in pure water or poly-(diallyldimethylammonium chloride) (PDADMAC)-containing an aqueous solution of Al8Cr17Co17Cu8Fe17Ni33 MPEA targets. Transmission electron microscopy (TEM) measurements combined with energy dispersive X-ray (EDX) mapping were used to characterize the structure and composition of the laser-generated MPEA nanoparticles (MPEA-NPs). These results confirmed the presence of a characteristic elemental distribution of a core-shell phase structure as the predominant NP species. The electrocatalytic performance of the laser-generated MPEA-NPs was characterized by linear sweep voltammetry (LSV) demonstrating an enhanced electrocatalytic CO2 activity for PDADMAC-stabilized NPs. The findings of these investigations indicate that MPEAs have great potential to replace conventional, expensive noble metal electrocatalysts. KW - Multi-principal element alloys KW - Chemically Complex Materials KW - CCMat KW - Electrocatalysis KW - Carbon dioxide reduction KW - Pulsed laser ablation PY - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-594018 VL - 24 SP - 9434 EP - 9440 PB - Elsevier BV AN - OPUS4-59401 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kirner, Sabrina V. A1 - Slachciak, Nadine A1 - Elert, Anna Maria A1 - Griepentrog, Michael A1 - Fischer, Daniel A1 - Hertwig, Andreas A1 - Sahre, Mario A1 - Dörfel, Ilona A1 - Sturm, Heinz A1 - Pentzien, Simone A1 - Koter, Robert A1 - Spaltmann, Dirk A1 - Krüger, Jörg A1 - Bonse, Jörn T1 - Tribological performance of titanium samples oxidized by fs-laser radiation, thermal heating, or electrochemical anodization N2 - Commercial grade-1 titanium samples (Ti, 99.6%) were treated using three alternative methods, (i) femtosecond laser processing, (ii) thermal heat treatment, and (iii) electrochemical anodization, respectively, resulting in the formation of differently conditioned superficial titanium oxide layers. The laser processing (i) was carried out by a Ti:sapphire laser (pulse duration 30 fs, central wavelength 790 nm, pulse repetition rate 1 kHz) in a regime of generating laser-induced periodic surface structures (LIPSS). The experimental conditions (laser fluence, spatial spot overlap) were optimized in a sample-scanning setup for the processing of several square-millimeters large surface areas covered homogeneously by these nanostructures. The differently oxidized titanium surfaces were characterized by optical microscopy, micro Raman spectroscopy, variable angle spectroscopic ellipsometry, and instrumented indentation testing. The tribological performance was characterized in the regime of mixed friction by reciprocating sliding tests against a sphere of hardened steel in fully formulated engine oil as lubricant. The specific tribological performance of the differently treated surfaces is discussed with respect to possible physical and chemical mechanisms. KW - Femtosecond laser KW - Titanium KW - Oxidation KW - Friction PY - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-445609 SN - 0947-8396 SN - 1432-0630 VL - 124 IS - 4 SP - 326, 1 EP - 10 PB - Springer-Verlag AN - OPUS4-44560 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -