TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Circular Economy - Umsetzung: Wer, was, wo, wie? N2 - Der Vortrag gibt komplementär zu der Theorie der Circular Economy und der technischen Umsetzung sowie Forschung einen Überblick über die aktuellen Entwicklungen in der Politik und Normung. Es werden die Schlüssel-Stakeholder und -gremien inkl. ihrer Wirkungsradien und der Schnittstellen miteinander vorgestellt. Des Weiteren erfolgt ein Überblick und Erklärungen zu Webseiten der Europäischen Kommission mit allgemeinen Inhalten zur Rechtslandschaft der Circular Economy und Möglichkeiten der Beteiligung. T2 - Besuch FH-Potsdam Circular Product Design CY - Berlin, Germany DA - 21.01.2025 KW - Circular economy KW - Rechtssetzung KW - Normung KW - Politikberatung PY - 2025 AN - OPUS4-62443 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlegel, Moritz-Caspar A1 - Koch, Claudia A1 - Mirtsch, Mona A1 - Harrer, Andrea T1 - Smart Products Enable Smart Regulations—Optimal Durability Requirements Facilitated by the IoT N2 - The challenges and opportunities linked with IoT have been intensively discussed in recent years. The connectivity of things over their entire life cycle and the smart properties associated with it provide new functionalities and unprecedented availability of (usage) data. This offers huge opportunities for manufacturers, service providers, users, and also policymakers. The latter May impact policy areas such as the regulations on resource and materials efficiency under the Ecodesign Directive 2009/125/EC. With the general approach as it is practiced today, legal requirements are usually set for entire product groups without considering the products individually, including user behavior and environmental conditions. The increasing number of smart products and the growing availability of product data are sparking a discussion on whether these requirements could be more product and application-specific. This paper presents a method for calculating the economically and ecologically optimal durability of a product. It allows determining the point in time when a product should be replaced by combining consumer data with product design data. This novel Approach could contribute to making product regulation more flexible and possibly more efficient. In this context, fundamental challenges associated with smart products in policymaking are also discussed. KW - Ecodesign KW - Internet of Things KW - Connectivity KW - Resource efficiency KW - Policy making PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-524924 DO - https://doi.org/10.3390/su13084395 VL - 13 IS - 8 SP - 4395 PB - MDPI CY - Basel AN - OPUS4-52492 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Nano-porous Materials - Introduction into Metal-organic Frameworks N2 - Metallic organic frameworks are the materials stirring great interest by their large variety of structure types and chemical composition as well as low density and very high surface area, which are desirable properties for gas storage such as for hydrogen, methane or carbon dioxide. Using different so called secondary building units offer an opportunity to form tunable structures with channels of various geometry and allow in this way to study the absorption of the molecular hydrogen, methane or carbon dioxid in the systematic way. T2 - Neutron Scattering Application to Hydrogen Storage Materials CY - Berlin, Germany DA - 07.08.2017 KW - MOFs KW - Hydrogen KW - Crystallography PY - 2017 AN - OPUS4-41285 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Palkowski, Carsten A1 - Schlegel, Moritz-Caspar A1 - Akkerman, Floris A1 - Simo, Anne T1 - EU Energy Label for heating appliances - Optimization of test standards for heat pumps N2 - The European Standards EN14511 and EN14825 are representing standardized procedures for testing the energy efficiency of heat pumps and air conditioners with electrically driven compressors for both space heating and cooling. In this study, these standards are analyzed and validated. It was figured out that the currently used methods implicate high complexity and high financial effort. In order to clarify the circumstances and to identify the deficits more in detail, a round robin test with independent and accredited laboratories was initiated. The aim is to develop an optimized test procedure that improves the feasibility of the testing procedure and finally its application. This study should lead to a repeatable and reproducible testing procedure, which is also compatible with the state of the art in heat pump technology and real operation conditions. T2 - ECEEE Summer Study 2017 CY - Hyères, France DA - 29.05.2017 KW - Climate change KW - Energy efficiency KW - Energy labelling KW - Heat pumps KW - Test method standard optimization PY - 2017 SN - 978-91-983878-1-0 SN - 2001-7960 SP - 1551 EP - 1555 AN - OPUS4-41287 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar A1 - Svetogorov, R. T1 - Crystal structure refinements - Rietveld Method N2 - The talk is an introduction into the Rietveld method and basic aspects concerning powder diffraction analysis. The FOX- and Jana software are explained stepwise which should enable the audiences of the talk to start structure refinements by their own. T2 - Neutron Scattering Application to Hydrogen Storage Materials CY - Berlin, Germany DA - 07.08.2017 KW - Rietveld KW - Refinement KW - FOX KW - Jana2006 PY - 2017 AN - OPUS4-41345 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - In-situ Untersuchungen an zementgebundenen Baustoffen mittels röntgengraphischer Verfahren T2 - Jährlicher Workshop der Deutschen Mineralogischen Gesellschaft (DMG) CY - Bad Münster, Germany DA - 2010-02-24 PY - 2010 AN - OPUS4-21040 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - In-situ Untersuchungen an zementgebundenen Baustoffen mittels röntgengraphischer Verfahren T2 - Geladener Gastredner bei der Eröffnungsfeier des Masterstudienganges Materialwissenschaftliche Mineralogie, Chemie und Physik, Universität Bremen CY - Bremen, Germany DA - 2009-11-20 PY - 2009 AN - OPUS4-21057 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sarfraz, Adnan A1 - Schlegel, Moritz-Caspar A1 - Wright, J. A1 - Emmerling, Franziska T1 - Advanced gas hydrate studies at ambient conditions using suspended droplets N2 - We report the spontaneous formation of a clathrate hydrate in a suspended droplet at ambient conditions. A novel method for producing and stabilizing clathrates for analytical studies is described. KW - Clathrates KW - Thermography KW - Acoustic levitator KW - Dichloromethane PY - 2011 DO - https://doi.org/10.1039/c1cc13049h SN - 0022-4936 SN - 1359-7345 VL - 47 IS - 33 SP - 9369 EP - 9371 PB - Royal Society of Chemistry CY - Cambridge AN - OPUS4-24480 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - High resolution investigations of cementitious materials by Synchrotron radiation based X-ray diffraction T2 - Jahrestagung der deutschen mineranologischen Gesellschaft (DMG) und Deutsche Gesellschaft für Kristallographie (DGK) CY - Salzburg, Austria DA - 2011-09-20 PY - 2011 AN - OPUS4-23741 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Early crystallization processes and high resolution phase analysis of cementitious materials T2 - The Power of Powder Diffraction (Workshop) CY - Erice, Italy DA - 2011-06-02 PY - 2011 AN - OPUS4-23735 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rückschloss, Jana A1 - Tochtrop, Christoph A1 - von Geibler, Justus A1 - Schlegel, Moritz-Caspar T1 - “Oh no, it’s broken!” – How product functionality limits lifespan N2 - Today a large variety of products with various features and designs are available for consumers. In addition to the main functions of a product, there are more and more additional functions, especially for electrical and electronic appliances. This means that looking for the right product may require extensive research by consumers and does not always lead to a sense of making an informed purchase decision. The wide variety of designs and functions can overwhelm consumers. This creates uncertainty and might lead to overrate products functionality and thus significantly shorten the service lifetime of appliances. Furthermore, the environmental impact of such functions is usually unclear, and can vary depending on the actual usage scenario. In this study, a survey was carried out in order to better understand consumers perceptions and experiences related to additional functions of products, with specific focus on domestic hobs, household refrigerating appliances and televisions. The results confirm the large number of additional functions and their overwhelming effect for consumers. Consumers purchase devices with more features than desired, or replaced them prematurely because an extra feature fails while the main function is still available. The findings of the study can be used to better inform consumers and support them to make environmentally sustainable purchasing decisions. T2 - 6th Product Lifetimes and the Environment Conference (PLATE2025) CY - Aalborg, Denmark DA - 02.07.2025 KW - Circular economy KW - Functionality KW - Durability KW - Purchase decision KW - Ecodesign PY - 2025 UR - https://journals.aau.dk/index.php/plate2025 SN - 97887-7642-060-4 DO - https://doi.org/10.54337/plate2025 SN - 2794-9540 SP - 666 EP - 674 AN - OPUS4-63823 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Circular Economy - Einführung in die Umsetzung N2 - Der Vortrag fasst die internationalen, europäischen und nationalen Entwicklungen zur Transformation der linearen hin zu einer zirkulären Wirtschaft zusammen. Auf den drei Ebenen folgt der Vortrag jeweils der selben Logik: (i) Bedarfe, (ii) Strategien und Pläne sowie (iii) konkrete Maßnahmen. Ebenfalls werden Hinweise zu weiteren Informationsquellen gegeben. T2 - Seminarreihe FH Potsdam CY - Potsdam, Germany DA - 17.06.2025 KW - Circular economy KW - Kreislaufwirtschaft KW - Rechtssetzung KW - Normung PY - 2025 AN - OPUS4-63445 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Hochaufgelöste in situ Sy-XRD Untersuchungen an zementgebundenen Baustoffen T2 - GDCh-Wissenschaftsforum Chemie 2011 CY - Bremen, Germany DA - 2011-09-04 PY - 2011 AN - OPUS4-24215 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Early Stages of Cement Hydration - An In-Situ Study Utilizing High resolution SyXRD T2 - Jahrestagung der Deutschen Gesellschaft für Kristallographie (DGK) CY - Munich, Germany DA - 2011-05-12 PY - 2011 AN - OPUS4-24992 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Neue Wege in der Zementanalytik-Hochaufgelöste in-situ Sy-XRD T2 - 52. DAfStb- Forschungskolloquium, BAM CY - Berlin, Germany DA - 2011-11-07 PY - 2011 AN - OPUS4-25132 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Early Stages of Cement Hydration - An In-Situ Study Utilizing High resolution SyXRD T2 - Jahrestagung der Deutschen Gesellschaft für Kristallographie (DGK) CY - Munich, Germany DA - 2012-03-11 PY - 2012 AN - OPUS4-25713 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Analysis of cementitious materials by X-Ray diffraction methods -Time and spatial resolved T2 - 13th International Congress on the Chemistry of Cement (ICCC) CY - Madrid, Spain DA - 2011-07-03 PY - 2011 AN - OPUS4-22568 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - High resolution phase analyses and early crystallization processes of cement T2 - 26th European Crystallographic Meeting (ECM) CY - Darmstadt, Germany DA - 2010-08-29 PY - 2010 AN - OPUS4-21231 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - In situ investigations of cementitious material by high resolution X-ray diffraction T2 - Doktorandenseminar der GDCh CY - Attendorn, Germany DA - 2011-02-27 PY - 2011 AN - OPUS4-23609 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Stakeholder-Beteiligung und -Konsultation im Ökodesign-Rechtsrahmen N2 - Entlang des EU-Rechtssetzungsprozesses für Produktregulierungen im Ökodesign-Rechtsrahmen werden Möglichkeiten zur Beteiligung sowie die Konsultation der Europäischen Kommission von diversen Stakeholdergruppen erörtert. Darüber hinaus werden öffentliche Konsultationen und das Einbringen von Expertenwissen in Normung und Forschung skizziert. T2 - DIN-Infoveranstaltung: Ökodesign-Verordnung CY - Berlin, Germany DA - 06.10.2025 KW - Circular economy KW - Kreislaufwirtschaft KW - Rechtssetzung KW - Normung KW - Ecodesign PY - 2025 AN - OPUS4-64310 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Entwicklungen zur Circular Economy in Rechssetzung und Normung N2 - Zusammenfassung der Implementierung von Circular Economy Prinzipien in der Rechtssetzung und Normung. Schwerpunkte sind das EU-Produktrecht, Bewertungsmethoden zur Zirkularität von Produkten und angekündigte EU-Rechtsrahmen und ihre Ausgestaltung. T2 - Industrieforum Global Environmental Compliance CY - Online meeting DA - 06.11.2025 KW - Circular economy KW - Rechtssetzung KW - Normung KW - Politikberatung KW - Ecodesign PY - 2025 AN - OPUS4-64601 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Die Rolle der ESPR bei der Transformation zu einer Circular Economy N2 - Die Präsentation fasst die aktuellen Entwicklungen zur Umsetzung einer Circular Economy in der EU zusammen. Besonderes Augenmerk wird auf die aktuelle Ausgestaltung der Rechtslandschaft, sowie Möglichkeiten der wissenschaftsbasierten Politikberatung und rechtsetzungsbegleitenden Normung gelegt. Beendet wird der Vortrag mit einem Überblick über zukünftige Verknüpfungen zum Circular Economy Act, Advanced Materials Act, Single Market Strategy der Europäischen Kommission sowie dem Digitalen Produktpass. T2 - Sustainability Heroes 2025 CY - Online meeting DA - 25.11.2025 KW - Circular economy KW - Rechtssetzung KW - Normung KW - Politikberatung KW - Ecodesign PY - 2025 AN - OPUS4-64884 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Engelt, Alexandra A1 - Schlegel, Moritz-Caspar T1 - Circular Design - Prinzipien der Circular Economy in der Produktentwicklung N2 - Die Präsentation fasst die Entwicklung und das aktuelle Verständnis von Produkteffizienz im europäischen Kontext zusammen. Aufbauend darauf werden verschiedene Möglichkeiten zur besseren Selbstreflexion der eigenen Produkte erörtert und ein entsprechendes systematisches Vorgehen dazu vorgestellt. Abschließend werden die Verknüpfungen zu weiteren und zukünftigen Rechtsbereichen mit einer Schnittmenge zum Produktrecht zusammengefasst. T2 - Handelsblatt Konferenz 2026 CY - Düsseldorf, Germany DA - 21.01.2026 KW - Circular economy KW - Product efficiency KW - Product design KW - Ecodesign KW - Policy making PY - 2026 AN - OPUS4-65430 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar A1 - Akkerman, Floris T1 - One step back, two steps forward – Resource efficiency requirements within ecodesign N2 - Resource efficiency is a much discussed topic in terms of improving the sustainability of energy related and energy non-related products. Resource efficiency aspects such as the availability of spare parts, the ability to dismantle, etc. have been included in draft working documents in the revision of several already existing Ecodesign regulations as a first step. However, often these aspects are not consistent with the current technology and design of these products. A possible reason could be a lack of sufficient consultation or of a methodology which is sufficiently tailored for this topic. The established strategies and tools, used by policymakers, such as the Methodology for the Ecodesign of Energy-related Products (MEErP), do not seem to deal with these aspects appropriately. Draft requirements need to be very well developed before being discussed with member states and other related stakeholders, because including resource efficiency parameters could lead to additional, very wide-ranging effects on society. This topic cannot be covered well with legislative tools developed primarily for energy aspects. In this paper, a method is presented which can be used to combine products’ properties with crucial resource efficiency indicators. The method can be used to develop a set of draft legislative requirements and to pre-evaluate these requirements by target groups which would be affected by additional legal requirements. These include: market surveillance authorities, standardization organizations, manufacturers and their associations, environmental organizations and research facilities. The method incorporates stakeholders’ feedback to identify potential resource efficiency measures for materials and/or products, their impact on the European ecology, economy and society. Based on this it would help to develop legislative requirements which are feasible and desirable. The results can then be fed into the formal legislative process, probably speeding it up. T2 - ECEEE 2019 Summer Study on Energy Efficiency CY - Belambra Presqu'île de Giens, France DA - 03.06.2019 KW - Resources KW - Circular economy KW - Ecodesign KW - Energy policy PY - 2019 UR - https://www.eceee.org/library/conference_proceedings/eceee_Summer_Studies/2019/ SN - 978-91-983878-5-8 SN - 2001-7960 VL - 2019 SP - 1553 EP - 1562 AN - OPUS4-48341 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar A1 - Giegerich, J. A1 - Dworak, C. T1 - Neue Trendlinien für das Ökodesign - Materialeffizienz von energieverbrauchsrelevanten Produkten (M/543) N2 - Die Kreislaufwirtschaftsinitiative der Europäischen Kommission fordert eine grundlegende Erweiterung bestehender Rechtsrahmen. Anforderungen zu einer gesetzlich vorgeschriebenen Lebensdauer, Reparierbarkeit, Recyclingfähigkeit, etc. von Produkten sollen unter der Ökodesign-Richtlinie geregelt werden. Bei diesem Vorhaben steht der Normungsauftrag M/543 im Zentrum. Es wurde 2015 von der Europäischen Kommission vergeben und bislang sind acht horizontale bzw. generische EN-Normen geplant. Trotz der zu erwartenden hohen Reichweite dieses Vorhabens scheinen die Inhalte und der eigentliche Zweck der zu erarbeitenden Normen vielen Marktakteuren noch nicht vollständig bekannt zu sein, daher sollen im Rahmen des Webinars diese Inhalte kurz vorgestellt werden. T2 - DIN-Akademie CY - Webinar DA - 30.04.2019 KW - Kreislaufwirtschaft KW - Circular economy KW - Lebensdauer KW - Reparierbarkeit KW - Recyclinkgfähigkeit KW - Ökodesign KW - Rechtssetzung PY - 2019 AN - OPUS4-47905 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Ecodesign spinning towards the circular Economy - The contribution of new standards on the material efficiency N2 - Whilst the concept of ecodesign is intended to account for the environmental impacts of the product across its whole lifecycle, European ecodesign policy to date has been heavily focused upon energy efficiency in the use phase. The Ecodesign Directive and Energy Labelling Regulation have achieved substantial energy savings since their inception. For many products, the magnitude of savings available from further tightening existing energy efficiency requirements is now often outweighed by savings that can be achieved by material efficiency requirements. Further, there are some products such as smartphones for which there are limited gains to be made in energy efficiency but for material efficiency. In the Commission’s Circular Economy Action Plan from 2015, a new direction was defined for ecodesign policy, to systematically examine considerations such as reparability, durability, upgradability, recyclability, or the identification of certain materials or substances. The Commission consequently issued a standardisation request (M/543, 2015) to the European Standardization Organisations (CEN / CENELEC / ETSI) to develop generic/horizontal standards relevant to energy-related products that address these major aspects of material efficiency. In this study we evaluate the potential contribution of these new standards (with specific focus on the standards for repair, durability and recyclability) to future developments under the European Ecodesign Directive. Opportunities for the impact of these standards to be enhanced by future work are highlighted. T2 - PLATE - Product Lifetimes and the Environment CY - Berlin, Germany DA - 18.09.2019 KW - Ecodesign KW - Circular economy KW - Material efficiency KW - Resource efficiency KW - Standardisation PY - 2019 AN - OPUS4-49146 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Russina, M. A1 - Gunther, G. A1 - Grzimek, V. A1 - Schlegel, Moritz-Caspar A1 - Veziri, C. M. A1 - Karanikolos, G. N. A1 - Yamada, T. A1 - Mezei, Ferenc T1 - Nanoscale Dynamics and Transport in Highly Ordered Low-Dimensional Water N2 - Highly ordered and highly cooperative water with properties of both solid and liquid states has been observed by means of neutron scattering in hydrophobic one-dimensional channels with van der Waals diameter of 0.78 nm. We have found that in the initial stages of adsorption water molecules occupy niches close to pore walls, followed later by the filling of the central pore area. Intensified by confinement, intermolecular water interactions lead to the formation of well-ordered hydrogen-bonded water chains and to the onset of cooperative vibrations. On the other hand, the same intermolecular interactions lead to two relaxation processes, the faster of which is the spontaneous position exchange between two water molecules placed 3.2-4 A from each other. Self-diffusion in an axial pore direction is the result of those spontaneous random exchanges and is substantially slower than the self-diffusion in bulk water. KW - Hydrophobic confinement KW - Neutron scattering KW - Water dynamics PY - 2019 DO - https://doi.org/10.1021/acs.jpclett.9b02303 VL - 10 IS - 20 SP - 6339 EP - 6344 PB - ACS Publications AN - OPUS4-49257 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Investigations of cement phase assemblage by space- and time-resolved X-Ray diffraction T2 - International Congress on the Chemistry of Cement (ICCC 2011) CY - Madrid, Spain DA - 2011-07-03 PY - 2011 AN - OPUS4-21206 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Müller, Urs A1 - Schlegel, Moritz-Caspar A1 - Emmerling, Franziska T1 - Advanced techniques for studying damage mechanisms of cementitious matrices affected by sulfate attack N2 - Cementitious materials, in particular concrete, are durable materials if prepared appropriately and the Service life of concrete structures is now often required to last 120 years or more. Concrete durability depends strongly on intrinsic (e.g. composition, porosity) and exterior factors (e.g. moisture condition and composition, frost cycles, load pattem). Deleterious actions leading to concrete degradation are often created by the environment. Extemal sulfate attack is one of the more spectacular damage scenarios for concrete structures caused by the ingress of sulfate ions into the pore System of the material and successive formation of expanding phases. Though in recent years well studied there are still many questions remaining conceming the mechanisms of sulfate attack. In particular over the last ten years, with the increased utilization of blended cements, new questions arose concerning the sulfate resistance of those binder Systems. In the presented study therefore a method was developed to analyze the changes of the phase composition within the micro structure due to sulfate attack. The analytical method was based on pX-Ray diffraction (pXRD) using Synchrotron radiation in Debye-Scherrer (transmission) geometry. The spatial resolution of the method is ca. 10 pm and allows the characterization of phase transformations in the wake of damaging processes in more detail compared to other techniques. Furthermore, the experimental setup provides the possibility for analyzing the phase assemblage of a given sample without destroying the micro structure. This is possible because the specimens for phase analysis consists of thick sections, which can be used for further microscopic analysis of the micro structure and micro chemistry (e.g. by SEM-EDX). Samples containing supplementary cementitious materials were measured in comparison and to reconstruct the influence of the degradation process in detail. Additionally, reaction ffonts within the samples were localized by micro x-ray fluorescence analysis (MXRF). T2 - EMABM 2011 - 13th Euroseminar on microscopy applied to building materials CY - Ljubljana, Slovenia DA - 14.06.2011 KW - Sulfate attack KW - Concrete KW - Synchrotron KW - XRD KW - Phase analysis PY - 2011 SN - 978-961-90366-7-9 SP - 1 EP - 9 AN - OPUS4-24878 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlegel, Moritz-Caspar A1 - Wenzel, Klaus-Jürgen A1 - Sarfraz, Adnan A1 - Panne, Ulrich A1 - Emmerling, Franziska T1 - A wall-free climate unit for acoustic levitators N2 - Acoustic levitation represents the physical background of trapping a sample in a standing acoustic wave with no contact to the wave generating device. For the last three decades, sample holders based on this effect have been commonly used for contact free handling of samples coupled with a number of analytical techniques. In this study, a wall-free climate unit is presented, which allows the control of the environmental conditions of suspended samples. The insulation is based on a continuous cold/hot gas flow around the sample and thus does not require any additional isolation material. This provides a direct access to the levitated sample and circumvents any influence of the climate unit material to the running analyses. KW - Acoustic levition PY - 2012 DO - https://doi.org/10.1063/1.4705968 SN - 0034-6748 SN - 1089-7623 VL - 83 IS - 5 SP - 055101-1 EP - 055101-3 PB - American Institute of Physics CY - Melville, NY AN - OPUS4-25881 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Combining High Resolution X-ray Diffraction with Acoustic Levitation T2 - Seminar HZB CY - Berlin, Germany DA - 2012-05-30 PY - 2012 AN - OPUS4-25984 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stroh, Julia A1 - Schlegel, Moritz-Caspar A1 - Schmidt, Wolfram A1 - Nguyen, Thi Yen A1 - Meng, Birgit A1 - Emmerling, Franziska T1 - Time-resolved in situ investigation of Portland cement hydration influenced by chemical admixtures N2 - Numerous admixtures are used in the building practice to customize the properties of the cement paste during application. The influences of admixtures on the course of cement hydration and formation of hydrate phases have to be considered. Polycarboxylate ether (PCE) based polymeric superplasticizers (SPs) are known to retard the setting of the cement paste. The extent of the retardation differs depending on the molecular structure of the SP. Additionally, the presence of a stabilizing agent (SA) in the cement paste has a retarding side effect on the setting. The initial cement hydration processes and the detailed mechanisms of the retardation influenced by PCEs, as well as their interactions with particular SAs, are insufficiently understood. Up to now, only the results of phenomenological studies were taken into account to describe this retardation process. A detailed structure analysis monitoring the change of the phase composition during the hydration was never applied. Both SP and SA affect the adsorption of the sulphate ions on the clinker particles, causing changes in the formation of ettringite during the initial hydration, and are therefore a crucial part of the setting process itself. Here, the initial hydration of cement influenced by the interaction of SP and SA was monitored in situ by synchrotron X-ray diffraction. The high time resolution of the measurements allowed a continuous detection of the hydrates formed. The hydration was followed from the starting point of water addition and for couple of hours afterwards. The hydration of the levitated cement pellets containing starch as SA was initialized by adding aqueous solutions of different commercial SPs. Changes in the ettringite formation were detected in comparison to the reference hydration of pure cement. KW - Synchrotron KW - Portland cement Initial hydration KW - Superplasticizer KW - Stabilizer KW - XRD PY - 2016 DO - https://doi.org/http://dx.doi.org/10.1016/j.conbuildmat.2015.12.097 IS - 106 SP - 18 EP - 26 PB - Elsevier AN - OPUS4-35467 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlegel, Moritz-Caspar A1 - Sarfraz, Adnan A1 - Müller, Urs A1 - Panne, Ulrich A1 - Emmerling, Franziska T1 - First seconds in a building's life - In situ synchrotron X-ray diffraction study of cement hydration on the millisecond timescale N2 - Setting cement: Highly dynamic hydration processes that occur during the first seconds of cement hydration were studied by time-resolved synchrotron X-ray diffraction. Polycarboxylate ether additives were found to influence the formation of the initial crystalline hydration products on a molecular level. KW - Cement hydration KW - Colloidal suspensions KW - In situ analysis KW - X-ray diffraction KW - SyXRD KW - High resolution KW - In-situ PY - 2012 DO - https://doi.org/10.1002/anie.201200993 SN - 1433-7851 SN - 1521-3773 SN - 0570-0833 VL - 51 IS - 20 SP - 4993 EP - 4996 PB - Wiley-VCH CY - Weinheim AN - OPUS4-26287 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Die Ökodesign-Rahmenverordnung - Produkteffizienz neu gedacht N2 - Die Präsentation fasst das europäische Verständnis für den Begriff "Produkteffizienz" und die diesbezügliche Entwicklungen der vergangenen Jahre zusammen. Es wird eine Verbindung zwischen Rechtssetzung, Normung und Forschung hergestellt und entsprechende Beiträge zur der Transformation von einer linearen- zu einer zirkulären Wirtschaft (Circular Economy) erörtert. T2 - DIN-Mitgliederdialog CY - Berlin, Germany DA - 03.03.2026 KW - Circular economy KW - Product efficiency KW - Normung KW - Ecodesign KW - Policymaking PY - 2026 AN - OPUS4-65631 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stroh, Julia A1 - Schlegel, Moritz-Caspar A1 - Irassar, E.F. A1 - Meng, Birgit A1 - Emmerling, Franziska T1 - Applying high resolution SyXRD analysis on sulfate attacked concrete field samples N2 - High resolution synchrotron X-ray diffraction (SyXRD) was applied for a microstructural profile analysis of concrete deterioration after sulfate attack. The cement matrices consist of ordinary Portland cement and different amounts of supplementary cementitious materials, such as fly ash, natural pozzolana and granulated blast furnace slag. The changes of the phase composition were determined along the direction of sulfate ingress. This approach allows the identification of reaction fronts and zones of different phase compositions and conclusions about the mechanisms of sulfate attack. Two reaction fronts were localized in the initial 4 mm from the sample surface. The mechanism of deterioration caused by the exposition in the sulfate-bearing soil is discussed. SyXRD is shown to be a reliable method for investigation of cementitious materials with aggregates embedded in natural environments. KW - X-ray diffraction (B) KW - High resolution KW - Degradation (C) KW - Sulfate attack (C) KW - Concrete (E) PY - 2014 DO - https://doi.org/10.1016/j.cemconres.2014.07.015 SN - 0008-8846 SN - 1873-3948 VL - 66 SP - 19 EP - 26 PB - Pergamon Press CY - New York, NY AN - OPUS4-31253 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlegel, Moritz-Caspar A1 - Müller, Urs A1 - Malaga, Katarina A1 - Panne, Ulrich A1 - Emmerling, Franziska T1 - Spatially resolved investigation of complex multi-phase systems using muXRF, SEM-EDX and high resolution SyXRD N2 - Spatially resolved analysis of complex multi-phase systems can be validated through different analytical methods. This study compares investigations by scanning electron microscopy coupled with energy dispersive X-ray fluorescence analysis and high resolution X-ray diffraction. The studied sulfate attacked cement paste containing fly ashes consists of different interacting crystalline and amorphous phases. The complementary methods revealed in detail changes in phase composition due to the chemical attack. The advantages and disadvantages of both methods are discussed and suggestions are given for combining them with additional methods to maximize the information content. KW - EDX-SEM KW - SyXRD KW - Spatial investigations KW - Comparison KW - High resolution KW - Cement paste KW - Sulfate attack KW - Damaging mechanism PY - 2013 DO - https://doi.org/10.1016/j.cemconcomp.2012.08.018 SN - 0958-9465 SN - 1873-393X VL - 37 SP - 241 EP - 245 PB - Elsevier Ltd. CY - Barking, Essex AN - OPUS4-29111 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - In-situ SyXRD Analysis of Cement Hydration on the ms-Scale T2 - Chemistry of Construction Materials CY - Berlin, Germany DA - 2013-10-07 PY - 2013 AN - OPUS4-29829 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar A1 - Müller, Urs A1 - Panne, Ulrich A1 - Emmerling, Franziska A1 - Meng, Birgit ED - Rogge, A. ED - Meng, B. T1 - Neue Wege in der Zementanalytik - Hochaufgelöste in-situ Sy-XRD T2 - 52. DAfStb-Forschungskolloquium CY - Berlin, Deutschland DA - 2011-11-07 PY - 2011 SN - 978-3-9814281-0-0 SP - 18 EP - 24 PB - BAM Bundesanstalt für Materialforschung und -prüfung CY - Berlin AN - OPUS4-25197 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - In-situ investigations utilizing levitated droplets T2 - Bessy User Meeting 2011 CY - Berlin, Germany DA - 2011-11-29 PY - 2011 N1 - Geburtsname von Batzdorf, Lisa: Tröbs, L. - Birth name of Batzdorf, Lisa: Tröbs, L. AN - OPUS4-24988 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Early Stages of Cement Hydration - An In-Situ Study Utilizing High Resolution SyXRD T2 - ECM CY - Munich, Germany DA - 2012-03-12 PY - 2012 AN - OPUS4-25564 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Characterisation of early hydration processe4s and chemical attacks of cementitious materials by time- and space-resolved X-Ray diffraction methods T2 - Jahrestagung der deutschen mineralogischen Gesellschaft (DMG) CY - Münster, Germany DA - 2010-10-19 PY - 2010 AN - OPUS4-21472 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Time- and space-resolved investigations of cementitious materials by X-Ray diffraction methods T2 - The 20th general meetng of the international mineralogical association (IMA) CY - Budapest, Hungary DA - 2010-08-21 PY - 2010 AN - OPUS4-21041 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - Investigations of cement phase assemblage by spyce-and time-resolved X-Ray diffraction T2 - International Congress on the Chemistry of Cement (ICCC 2011) CY - Madrid, Spain DA - 2011-07-03 PY - 2011 AN - OPUS4-21094 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schlegel, Moritz-Caspar T1 - First and Last Seconds of a Building´s Life - Applied Chemistry in Build Environment T2 - Doktorandentagung der GDCh CY - Berlin, Germany DA - 2012-02-26 PY - 2012 AN - OPUS4-25712 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlegel, Moritz-Caspar A1 - Müller, Urs A1 - Panne, Ulrich A1 - Emmerling, Franziska T1 - Deciphering the sulfate attack of cementitious materials by high-resolution micro-x-ray diffraction N2 - The durability of cementitious materials depends, among others, on their resistance against chemical attack during the service life of a building. Here, we present an approach to analyze changes in the phase composition due to chemical attack in the form of sulfate ingress within the microstructure. Micro-X-ray (µX-ray) diffraction using synchrotron radiation in Debye–Scherrer (transmission) geometry allowed a spatial resolution of 10 µm. Phase transformations in the wake of damaging processes were observed in a detailed high-resolution imaging study. In comparison, samples containing supplementary cementitious materials were investigated and used to reconstruct the influence of different degeneration processes in detail. Additionally, reaction fronts within the bulk were localized by micro-X-ray fluorescence analysis. The experimental setup provided the possibility for analyzing the phase assemblage of a given sample without destroying the microstructure. The specimens for phase analysis are thick sections of the primary material and can be used for further microscopic analysis of the microstructure and microchemistry, e.g., scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM–EDX) or Raman spectroscopy. PY - 2011 DO - https://doi.org/10.1021/ac200181g SN - 0003-2700 SN - 1520-6882 VL - 83 IS - 10 SP - 3744 EP - 3749 PB - American Chemical Society CY - Washington, DC AN - OPUS4-23669 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlegel, Moritz-Caspar A1 - Sarfraz, Adnan A1 - Müller, Urs A1 - Panne, Ulrich A1 - Emmerling, Franziska T1 - Erste Sekunden im Leben eines Bauwerks - In-situ-Synchrotron-Röntgenbeugungsuntersuchungen der Zementhydratation mit Millisekunden-Auflösung N2 - Höchst dynamische Hydratationsprozesse in den ersten Sekunden bei der Entstehung eines Bauwerkes lassen sich mithilfe von Synchrotron-Röntgenbeugung mit einer sehr hohen Zeitauflösung nachverfolgen. Der Schwerpunkt lag dabei auf der Beeinflussung der Bildung erster kristalliner Hydratationsprodukte während des Frühstadiums der Zementhydratation. KW - SyXRD KW - High resolution KW - In-situ KW - Colloidal suspension KW - Cement hydration KW - In-situ-Analyse KW - Kolloidale Suspensionen KW - Röntgenbeugung KW - Zementhydratation PY - 2012 DO - https://doi.org/10.1002/ange.201200993 SN - 0044-8249 SN - 0932-2140 SN - 1521-3757 VL - 124 IS - 20 SP - 5078 EP - 5081 PB - Wiley-VCH CY - Weinheim AN - OPUS4-26284 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -