TY - JOUR A1 - Hachet, G. A1 - Wei, S. A1 - Tehranchi, Ali A1 - Dong, X. A1 - Lestang, J. A1 - Zhang, A. A1 - Sun, B. A1 - Zaefferer, S. A1 - Gault, B. A1 - Ponge, D. A1 - Raabe, D. ED - Tehranchi, Ali T1 - Protection of metal interfaces against hydrogen-assisted cracking N2 - Enabling a hydrogen economy requires the development of materials resistant to hydrogen embrittlement (HE). More than 100 years of research have led to several mechanisms and models describing how hydrogen interacts with lattice defects and leads to mechanical property degradation. However, solutions to protect materials from hydrogen are still scarce. Here, we investigate the role of interstitial solutes in protecting critical crystalline defects sensitive to hydrogen. Ab initio calculations show that boron and carbon in solid solutions at grain boundaries can efficiently prevent hydrogen segregation. We then realized this interface protection concept on martensitic steel, a material strongly prone to HE, by doping the most sensitive interfaces with different concentrations of boron and carbon. These segregations, in addition to stress relaxations, critically reduce the hydrogen ingress by half, leading to an unprecedented resistance against HE. This tailored interstitial segregation strategy can be extended to other metallic materials susceptible to hydrogen-induced interfacial failure. KW - Hydrogen embrittlement KW - interstitial PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-650881 DO - https://doi.org/10.1038/s41467-025-67310-6 SN - 2041-1723 VL - 16 IS - 1 SP - 1 EP - 11 PB - Springer Science and Business Media LLC AN - OPUS4-65088 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Liu, H. A1 - Song, W. A1 - Gröninger, Delia A1 - Zhang, L. A1 - Lu, Y. A1 - Chan, K. S. A1 - Zhou, Z. A1 - Rurack, Knut A1 - Shen, Z. T1 - Real-time monitoring of newly acidified organelles during autophagy enabled by reaction-based BODIPY dyes N2 - Real-time monitoring of newly acidified organelles during autophagy in living cells is highly desirable for a better understanding of intracellular degradative processes. Herein, we describe a reaction-based boron dipyrromethene (BODIPY) dye containing strongly electron-withdrawing diethyl 2-cyanoacrylate groups at the α-positions. The probe exhibits intense red fluorescence in acidic organelles or the acidified cytosol while negligible fluorescence in other regions of the cell. The underlying mechanism is a nucleophilic reaction at the central meso-carbon of the indacene core, resulting in the loss of π-conjugation entailed by dramatic spectroscopic changes of more than 200 nm between its colorless, non-fluorescent leuco-BODIPY form and its red and brightly emitting form. The reversible transformation between red fluorescent BODIPY and leuco-BODIPY along with negligible cytotoxicity qualifies such dyes for rapid and direct intracellular lysosome imaging and cytosolic acidosis detection simultaneously without any washing step, enabling the real-time monitoring of newly acidified organelles during autophagy. KW - Autophagy KW - BODIPY KW - Fluorescence KW - Lysosome KW - Real-time imaging PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-498358 UR - https://www.nature.com/articles/s42003-019-0682-1 DO - https://doi.org/10.1038/s42003-019-0682-1 SN - 23993642 VL - 2 SP - 442 PB - Nature Research CY - London AN - OPUS4-49835 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bosch, R.-W. A1 - Cottis, R.A. A1 - Csecs, K. A1 - Dorsch, T. A1 - Dunbar, L. A1 - Heyn, Andreas A1 - Huet, F. A1 - Hyökyvirta, O. A1 - Kerner, Z. A1 - Kobzova, A. A1 - Macak, J. A1 - Novotny, R. A1 - Öijerholm, J. A1 - Piippo, J. A1 - Richner, R. A1 - Ritter, S. A1 - Sánchez-Amaya, J.M. A1 - Somogyi, A. A1 - Väisänen, S. A1 - Zhang, W. T1 - Reliability of electrochemical noise measurements: Results of round-robin testing on electrochemical noise N2 - Sixteen laboratories have performed electrochemical noise (EN) measurements based on two systems. The first uses a series of dummy cells consisting of a 'star' arrangement of resistors in order to validate the EN measurement equipment and determine its baseline noise performance, while the second system, based on a previous round-robin in the literature, examines the corrosion of aluminium in three environments. All participants used the same measurement protocol and the data reporting and analysis were performed with automatic procedures to avoid errors. The measurement instruments used in the various laboratories include commercial general-purpose potentiostats and custom-built EN systems. The measurements on dummy cells have demonstrated that few systems are capable of achieving instrument noise levels comparable to the thermal noise of the resistors, because of its low level. However, it is of greater concern that some of the instruments exhibited significant artefacts in the measured data, mostly because of the absence of anti-aliasing filters in the equipment or because the way it is used. The measurements on the aluminium samples involve a much higher source noise level during pitting corrosion, and most (though not all) instruments were able to make reliable measurements. However, during passivation, the low level of noise could be measured by very few systems. The round-robin testing has clearly shown that improvements are necessary in the choice of EN measurement equipment and settings and in the way to validate EN data measured. The results emphasise the need to validate measurement systems by using dummy cells and the need to check systematically that the noise of the electrochemical cell to be measured is significantly higher than the instrument noise measured with dummy cells of similar impedance. KW - Electrochemical noise KW - Round-robin KW - Corrosion PY - 2014 DO - https://doi.org/10.1016/j.electacta.2013.12.093 SN - 0013-4686 SN - 1873-3859 VL - 120 SP - 379 EP - 389 PB - Elsevier Science CY - Kidlington AN - OPUS4-30284 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zerbst, Uwe A1 - Ainsworth, R. A. A1 - Beier, H.T. A1 - Pisarski, H. A1 - Zhang, Z. L. A1 - Nikbin, K. A1 - Nitschke-Pagel, T. A1 - Münstermann, S. A1 - Kucharczyk, P. A1 - Klingbeil, Dietmar T1 - Review on fracture and crack propagation in weldments - A fracture mechanics perspective N2 - Welding is one of the most common methods in industrial practice for joining components. Its main advantages are high speed in manufacturing combined with low costs and, usually, a high degree of flexibility, integrity and reliability. Nevertheless, welding is a highly complex metallurgical process and, therefore, weldments are susceptible to material discontinuities, flaws and residual stresses which may lead to structural failure and life time reduction. As a consequence weldments are an important field of fracture mechanics methods although its application is more complex than for homogeneous or non-welded structures. The aim of the paper is to provide an overview on the current state of fracture mechanics application to weldments. It starts by discussing the specific features which any fracture mechanics analysis of weldments has to take into account. Then, the experimental determination of fracture toughness, fatigue crack propagation and tensile properties of weldments is addressed. Finally, the analytical determination of the crack driving force in components and structural integrity assessment approaches for weldments are presented. KW - Weldments KW - Fracture mechanics KW - Fracture toughness KW - Fatigue crack propagation KW - Residual stresses KW - Strength mismatch PY - 2014 DO - https://doi.org/10.1016/j.engfracmech.2014.05.012 SN - 0013-7944 SN - 1873-7315 VL - 132 SP - 200 EP - 276 PB - Elsevier Science CY - Kidlington AN - OPUS4-32819 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zhang, Yue A1 - Martin, A. A1 - Wolf, G.-U. A1 - Rabe, S. A1 - Worzala, H. A1 - Lücke, B. A1 - Meisel, M. A1 - Witke, Klaus T1 - Structural transformations of VOHPO4.1/2H2O in the Presence of Ammonia KW - Vanadium KW - Ammoniak KW - Phosphat KW - Phyrophosphorsäure PY - 1996 SN - 0897-4756 SN - 1520-5002 VL - 8 IS - 5 SP - 1135 EP - 1140 PB - American Chemical Society CY - Washington, DC AN - OPUS4-684 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dey, R. A1 - Dudziak, Mateusz A1 - Prescher, A. A1 - Kreitsmann, T. A1 - Zhang, K. A1 - Posten, C. A1 - Thomson, C. A1 - Schartel, Bernhard A1 - Ullrich, M. S. A1 - Thomson, L. T1 - Sustainable Flame-Retardant Poly Lactic AcidBiocomposites Reinforced with Polyphosphate-EnrichedMicroalgae: Unlocking the Potential of Hyper-Compensation N2 - This study examines the dual benefits of microalgae cultivation for wastewatertreatment and the enhancement of polylactic acid-based biocomposites. UsingDesmodesmus sp. in a photobioreactor, both batch and continuous operationsachieve total nitrogen (TN) and total phosphorus (TP) removal rates of up to99.9%, maintaining TN and TP levels below 0.02 mg L−1 in the effluent, aligningwith European discharge standards. Continuous cultivation increases biomassproductivity from 0.102 to 0.43 g L−1 day−1 , a 322% improvement over batchoperations. Nutrient starvation followed by reintroduction to nutrient-richwastewater induces hyper-compensation luxury uptake, with P-enrichedcells accumulating 1.33% intracellular P within six hours — 21% higherthan natural accumulation. The results reveal that luxury phosphorus uptakein microalgae follows a triphasic system of uptake and storage, challengingthe previously suggested biphasic model. When incorporated into Poly lacticacid (PLA), the biomass enhances versatility, offering potential replacementof inorganic P in industrial applications, particularly flame retardants.Pyrolysis and cone calorimetry confirm the thermal and fire-retardantbenefits, with a 20% reduction in peak heat release rate and increased charyield. This work highlights microalgae’s role in sustainable biocomposites,supporting wastewater treatment, nutrient recovery, and CO2 sequestration. KW - biocomposites KW - biopolymers KW - Flame-retardant KW - Hyper compensation KW - Phycoremediation KW - Wastewater treatment PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-640408 DO - https://doi.org/10.1002/adsu.202500251 SN - 2366-7486 VL - 9 IS - 8 SP - 1 EP - 11 PB - Wiley VHC-Verlag AN - OPUS4-64040 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lu, J. A1 - Zhang, S. A1 - Yao, J. A1 - Guo, Z. A1 - Osenberg, M. A1 - Hilger, A. A1 - Markötter, Henning A1 - Wilde, F. A1 - Manke, I. A1 - Zhang, X. A1 - Sun, F. A1 - Cui, G. T1 - Synergistic Effect of CO2 in Accelerating the Galvanic Corrosion of Lithium/Sodium Anodes in Alkali Metal−Carbon Dioxide Batteries N2 - Rechargeable alkali metal−CO2 batteries, which combine high theoretical energy density and environmentally friendly CO2 fixation ability, have attracted worldwide attention. Unfortunately, their electrochemical performances are usually inferior for practical applications. Aiming to reveal the underlying causes, a combinatorial usage of advanced nondestructive and postmortem characterization tools is used to intensively study the failure mechanisms of Li/Na−CO2 batteries. It is found that a porous interphase layer is formed between the separator and the Li/Na anode during the overvoltage rising and battery performance decaying process. A series of control experiments are designed to identify the underlying mechanisms dictating the observed morphological evolution of Li/Na anodes, and it is found that the CO2 synergist facilitates Li/Na chemical corrosion, the process of which is further promoted by the unwanted galvanic corrosion and the electrochemical cycling conditions. A detailed compositional analysis reveals that the as-formed interphase layers under different conditions are similar in species, with the main differences being their inconsistent quantity. Theoretical calculation results not only suggest an inherent intermolecular affinity between the CO2 and the electrolyte solvent but also provide the most thermodynamically favored CO2 reaction pathways. Based on these results, important implications for the further development of rechargeable alkali metal−CO2 batteries are discussed. The current discoveries not only fundamentally enrich our knowledge of the failure mechanisms of rechargeable alkali metal−CO2 batteries but also provide mechanistic directions for protecting metal anodes to build high-reversible alkali metal−CO2 batteries. KW - Alkali metal batteries KW - Synchrotron X-ray computed tomography KW - Lithium/sodium−carbon dioxide batteries KW - Battery failure mechanisms KW - Alkali metal anodes PY - 2024 DO - https://doi.org/10.1021/acsnano.4c02329 SP - 1 EP - 16 AN - OPUS4-59922 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kim, K.J. A1 - Kim, C.S. A1 - Ruh, S. W. A1 - Unger, Wolfgang A1 - Radnik, Jörg A1 - Mata-Salazar, J. A1 - Juarez-Garcia, J.M. A1 - Cortazar-Martinez, O. A1 - Herrera-Gomez, A. A1 - Hansen, P.E. A1 - Madesen, J.S. A1 - Senna, C.A. A1 - Archanjo, B.S. A1 - Damasceno, J.C. A1 - Achete, C.A. A1 - Wang, H. A1 - Wang, M. A1 - Windover, D. A1 - Steel, E. A1 - Kurokawa, A. A1 - Fujimoto, T. A1 - Azuma, Y. A1 - Terauchi, S. A1 - Zhang, L. A1 - Jordaan, W.A. A1 - Spencer, S.J. A1 - Shard, A.G. A1 - Koenders, L. A1 - Krumrey, M. A1 - Busch, I. A1 - Jeynes, C. T1 - Thickness measurement of nm HfO2 films N2 - A pilot study for the thickness measurement of HfO2 films was performed by the Surface Analysis Working Group (SAWG) of the Consultative Committee for Amount of Substance (CCQM). The aim of this pilot study was to ensure the equivalency in the measurement capability of national metrology institutes for the thickness measurement of HfO2 films. In this pilot study, the thicknesses of six HfO2 films with nominal thickness from 1 nm to 4 nm were measured by X-ray Photoelectron Spectroscopy (XPS), X-ray Reflectometry(XRR), X-ray Fluorescence Analysis (XRF), Transmission Electron Spectroscopy (TEM), Spectroscopic Ellipsometry (SE) and Rutherford Backscattering Spectrometry (RBS). The reference thicknesses were determined by mutual calibration of a zero-offset method (Medium Energy Ion Scattering Spectroscopy (MEIS) of KRISS) and a method traceable to the length unit (the average thicknesses of three XRR data except the thinnest film). These reference thicknesses are traceable to the length unit because they are based on the traceability of XRR. For the thickness measurement by XPS, the effective attenuation length of Hf 4f electrons was determined. In the cases of XRR and TEM, the offset values were determined from a linear fitting between the reference thicknesses and the individual data by XRR and TEM. The amount of substance of HfO2, expressed as thickness of HfO2 films (in both linear and areal density units), was found to be a good subject for a CCQM key comparison. To reach the main text of this paper, click on Final Report. The final report has been peer-reviewed and approved for publication by the CCQM. KW - Thickness measurements KW - nm films KW - X-ray Photoelectron Spectroscopy KW - Mutual calibration PY - 2021 DO - https://doi.org/10.1088/0026-1394/58/1A/08016 SN - 0026-1394 VL - 58 IS - 1a SP - 08016 PB - IOP Publishing Lt. CY - Bristol AN - OPUS4-54175 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Vogel, F. A1 - Ngai, S. A1 - Zhou, X. Y. A1 - Zaiser, E. A1 - Manzoni, Anna Maria A1 - Wu, Y. A1 - Zheng, W. W. A1 - Zhang, P. A1 - Thompson, G. B. T1 - Tracking maze-like hierarchical phase separation behavior in a Fe-Si-V alloy N2 - Optimizing the properties of next-generation high-temperature and corrosion-resistant alloys is rooted in balancing structure-property relationships and phase chemistry. Here, we implement a complementary approach based on transmission electron microscopy (TEM) and atom probe tomography (APT) to ascertain aspects of hierarchical phase separation behavior, by understanding the microstructural evolution and the three-dimensional (3D) nanochemistry of a single crystal Fe79.5Si15.5V5.0 (at%) alloy. A maze-like hierarchical microstructure forms, in which a complex network of metastable disordered α plates (A2 phase) emerges within ordered α1 precipitates (D03 phase). The supersaturation in α1 (D03) precipitates with Fe and V drives the formation of α (A2) plates. The morphology of α (A2) plates is discussed concerning crystal structure, lattice misfit, and elastic strain. Phase compositions and a ternary phase diagram aid the thermodynamic assessment of the hierarchical phase separation mechanism via the Gibbs energy of mixing. A perspective on the stabilization of hierarchical microstructures beyond Fe79.5Si15.5V5.0 is elaborated by comparing hierarchical alloys. We find that the ratio of elastic anisotropy (Zener ratio) serves as a predictor of the hierarchical particles’ morphology. We suggest that the strengthening effect of hierarchical microstructures can be harnessed by improving the temporal and thermal stability of hierarchical particles. This can be achieved through phase-targeted alloying aiming at the hierarchical particles phase by considering the constituents partitioning behavior. Beyond Fe79.5Si15.5V5.0, our results demonstrate a potential pathway for improving the properties of high-temperature structural materials. KW - Atom probe tomography KW - Transmission electron microscopy KW - Hierarchical microstructure KW - Phase separation PY - 2023 DO - https://doi.org/10.1016/j.jallcom.2023.172157 SN - 0925-8388 VL - 968 SP - 1 EP - 17 PB - Elsevier B.V. AN - OPUS4-58343 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schneider, Rudolf A1 - He, Y. A1 - Zhu, R. A1 - Cai, Y. A1 - Zhang, Y. A1 - Zhang, Y. A1 - Pan, S. A1 - Zhang, Y. T1 - Transcriptomics and protein biomarkers reveal the detoxifying mechanisms of UV radiation for nebivolol toward zebrafish (Danio rerio) embryos/larvae N2 - Nebivolol (NEB), a β-blocker frequently used to treat cardiovascular diseases, has been widely detected in aquatic environments, and can be degraded under exposure to UV radiation, leading to the formation of certain transformation products (UV-TPs). Thus, the toxic effects of NEB and its UV-TPs on aquatic organisms are of great importance for aquatic ecosystems. In the present study, the degradation pathway of NEB under UV radiation was investigated. Subsequently, zebrafish embryos/larvae were used to assess the median lethal concentration (LC50) of NEB, and to clarify the sub-lethal effects of NEB and its UV-TPs for the first time. It was found that UV radiation could reduce the toxic effects of NEB on the early development of zebrafish. Transcriptomic analysis identified the top 20 enriched Kyoto Encyclopedia of Genes and Genomes (KEGG) pathways in zebrafish larvae exposed to NEB, most of which were associated with the antioxidant, nervous, and immune systems. The number of differentially expressed genes (DEGs) in the pathways were reduced after UV radiation. Furthermore, the analysis of protein biomarkers, including CAT and GST (antioxidant response), AChE and ACh (neurotoxicity), CRP and LYS (immune response), revealed that NEB exposure reduced the activity of these biomarkers, whereas UV radiation could alleviate the effects. The present study provides initial insights into the mechanisms underlying toxic effects of NEB and the detoxification effects of UV radiation on the early development of zebrafish. It highlights the necessity of considering the toxicity of UV-TPs when evaluating the toxicity of emerging pollutants in aquatic systems. KW - Biomarker KW - Pharmazeutika KW - Toxikologie KW - UV Bestrahlung KW - Zebrafisch KW - Transformationsprodukte PY - 2022 DO - https://doi.org/10.1016/j.aquatox.2022.106241 SN - 0166-445X VL - 249 SP - 1 EP - 10 PB - Elsevier CY - Amsterdam AN - OPUS4-55559 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -