TY - GEN A1 - Rurack, Knut A1 - Martínez-Mánez, Ramon ED - Charles M. Lukehart, ED - Robert A. Scott, T1 - Functional Supramolecular Hybrid Materials T2 - Nanomaterials: Inorganic and Bioinorganic Perspectives N2 - The combination of suitable nanoscopic inorganic supports with supramolecular concepts and bioconjugation strategies opens up exciting perspectives for the development of bioinorganic and organic–inorganic hybrid materials with improved functionalities. Many of the examples from the period 2004 to mid-2007 reviewed here bridge the gap between molecules, materials sciences, biochemistry, and nanotechnology. The synergistic use of these approaches has led to the advancement of various functions such as enhanced recognition, amplified signaling, the controlled assembly and disassembly of aggregates and 3-D architectures. Many of the implemented active functions can be carried out in a reversible and directed fashion on purpose by triggering with an external stimulus. These ideas bring tunability to properties of inorganic solids and new perspectives of application to biochemical and supramolecular concepts. Classic inorganic chemistries such as metal or semiconductor nanoparticles, silica or carbon materials, and coordination chemistry are thus elevated to another level of sophistication and contribute significantly to frontier research areas in directed transport and delivery, nanoelectronics and mechanics, chip technology, smart materials, memory devices, and bioanalytics. KW - Biochemie KW - Biomakromoleküle KW - DNA KW - Gold KW - Hybridmaterialien KW - Nanopartikel KW - Quantenpunkte KW - Selbstorganisation KW - Sensorik KW - Silica KW - Supramolekulare Chemie PY - 2008 SN - 978-0470-51644-7 SP - 789 EP - 812 PB - Wiley CY - Chichester AN - OPUS4-19212 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Rurack, Knut A1 - Martínez-Mánez, Ramon ED - Charles M. Lukehart, ED - Robert A. Scott, T1 - Biomimetic chemistry of hybrid materials T2 - Nanomaterials: Inorganic and Bioinorganic Perspectives N2 - The article discusses representative examples published in the field of functional biomimetic chemistry of hybrid materials between 2004 and mid-2007. First, we focus on the modification of morphological aspects of (bio)organic–inorganic hybrid materials to create sophisticated gating and switching mechanisms. The architecture of the systems is presented and the elements of control by external stimuli that have been established in recent years, such as optical, electrochemical, chemical, thermal, or magnetic means, are described. Various functions ranging from (site-specific) delivery to indication at the nanometric level are reported. Next we develop the idea of utilizing hybrid frameworks for biomimetic signaling inspired by the way nature has created binding pockets and the concept of induced-fit. Such a merging of inorganic scaffolds with supramolecular concepts results in enhanced molecular recognition and signaling. Finally selected recent advances in the field of hybrid biomimetic motors both of linear and rotary types are presented. The contribution shows how novel biomimetic functions can arise from synergisms between specifically designed hybrid materials and the implementation of supramolecular and/or bioorganic concepts. KW - Biochemie KW - Biomimetika KW - DNA KW - Gold KW - Hybridmaterialien KW - Molekulare Schalter KW - Molekulare Motoren KW - Nanopartikel KW - Quantenpunkte KW - Schalter KW - Sensorik KW - Silica KW - Supramolekulare Chemie PY - 2008 SN - 978-0470-51644-7 SP - 31 EP - 50 PB - Wiley CY - Chichester AN - OPUS4-19213 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - BOOK A1 - Rurack, Knut A1 - Martínez-Mánez, Ramon T1 - Biomimetic chemistry of hybrid materials T3 - Encyclopedia of inorganic chemistry N2 - The article discusses representative examples published in the field of functional biomimetic chemistry of hybrid materials between 2004 and mid-2007. First, we focus on the modification of morphological aspects of (bio)organic–inorganic hybrid materials to create sophisticated gating and switching mechanisms. The architecture of the systems is presented and the elements of control by external stimuli that have been established in recent years, such as optical, electrochemical, chemical, thermal, or magnetic means, are described. Various functions ranging from (site-specific) delivery to indication at the nanometric level are reported. Next we develop the idea of utilizing hybrid frameworks for biomimetic signaling inspired by the way nature has created binding pockets and the concept of induced-fit. Such a merging of inorganic scaffolds with supramolecular concepts results in enhanced molecular recognition and signaling. Finally selected recent advances in the field of hybrid biomimetic motors both of linear and rotary types are presented. The contribution shows how novel biomimetic functions can arise from synergisms between specifically designed hybrid materials and the implementation of supramolecular and/or bioorganic concepts. KW - Biochemie KW - Biomimetika KW - DNA KW - Gold KW - Hybridmaterialien KW - Molekulare Schalter KW - Molekulare Motoren KW - Nanopartikel KW - Quantenpunkte KW - Schalter KW - Sensorik KW - Silica KW - Supramolekulare Chemie PY - 2009 DO - https://doi.org/10.1002/0470862106.ia420 SP - 1 EP - 20 PB - Wiley CY - Chichester AN - OPUS4-19846 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Rurack, Knut A1 - Martínez-Mánez, Ramon ED - Robert H. Crabtree, T1 - Functional supramolecular hybrid materials T2 - Encyclopedia of inorganic chemistry N2 - The combination of suitable nanoscopic inorganic supports with supramolecular concepts and bioconjugation strategies opens up exciting perspectives for the development of bioinorganic and organic–inorganic hybrid materials with improved functionalities. Many of the examples from the period 2004 to mid-2007 reviewed here bridge the gap between molecules, materials sciences, biochemistry, and nanotechnology. The synergistic use of these approaches has led to the advancement of various functions such as enhanced recognition, amplified signaling, the controlled assembly and disassembly of aggregates and 3-D architectures. Many of the implemented active functions can be carried out in a reversible and directed fashion on purpose by triggering with an external stimulus. These ideas bring tunability to properties of inorganic solids and new perspectives of application to biochemical and supramolecular concepts. Classic inorganic chemistries such as metal or semiconductor nanoparticles, silica or carbon materials, and coordination chemistry are thus elevated to another level of sophistication and contribute significantly to frontier research areas in directed transport and delivery, nanoelectronics and mechanics, chip technology, smart materials, memory devices, and bioanalytics. KW - Biochemie KW - Biomakromoleküle KW - DNA KW - Gold KW - Hybridmaterialien KW - Nanopartikel KW - Quantenpunkte KW - Selbstorganisation KW - Sensorik KW - Silica KW - Supramolekulare Chemie PY - 2009 DO - https://doi.org/10.1002/0470862106.ia400 SP - 1 EP - 23 PB - Wiley CY - Chichester AN - OPUS4-19847 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Rurack, Knut A1 - Martínez-Mánez, Ramon A1 - Sancenón, F. A1 - Descalzo López, Ana Belén ED - Rurack, Knut ED - Martínez-Mánez, Ramon T1 - Biomimetically inspired signaling T2 - The supramolecular chemistry of organic - inorganic hybrid materials KW - Bindungstaschen KW - Biochemie KW - Biomimetika KW - Chromatophore KW - Gold KW - Hybridmaterialien KW - Ionenkanäle KW - Metalloregulation KW - Nanopartikel KW - Quantenpunkte KW - Sensorik KW - Silica KW - Supramolekulare Chemie KW - Verdrängungsassays PY - 2010 SN - 978-0-470-37621-8 SP - 549 EP - 580 PB - John Wiley & Sons CY - Hoboken, New Jersey, USA AN - OPUS4-21960 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Martínez-Mánez, Ramon A1 - Sancenón, F. A1 - Descalzo López, Ana Belén A1 - Rurack, Knut ED - Abd-El Aziz, Alaa S. ED - Carraher, Charles E. ED - Pittman, Charles U. ED - Zeldin, Martel T1 - Supramolecular hybrid materials - integrating functionality with sensing T2 - Macromolecules containing metal and metal-like elements - Supramolecular and self-assembled metal-containing materials KW - Biochemie KW - Biomakromoleküle KW - DNA KW - Gold KW - Hybridmaterialien KW - Nanopartikel KW - Quantenpunkte KW - Selbstorganisation KW - Sensorik KW - Silica KW - Supramolekulare Chemie PY - 2009 SN - 978-0-470-25144-7 SN - 1545-438X VL - 9 SP - 369 EP - 405 PB - John Wiley & Sons CY - Hoboken, New Jersey, USA AN - OPUS4-20318 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -