TY - JOUR A1 - Som, Tirtha A1 - Troppenz, G.V. A1 - Wendt, R. R. A1 - Wollgarten, M. A1 - Rappich, J. A1 - Emmerling, Franziska A1 - Rademann, Klaus T1 - Graphene oxide/alpha-Bi2O3 composites for visible-light photocatalysis, chemical catalysis, and solar energy conversion N2 - The growing challenges of environmental purification by solar photocatalysis, precious-metal-free catalysis, and photocurrent generation in photovoltaic cells receive the utmost global attention. Here we demonstrate a one-pot, green chemical synthesis of a new stable heterostructured, ecofriendly, multifunctional microcomposite that consists of α-Bi2O3 microneedles intercalated with anchored graphene oxide (GO) microsheets (1.0 wt?%) for the above-mentioned applications on a large economical scale. The bare α-Bi2O3 microneedles display two times better photocatalytic activities than commercial TiO2 (Degussa-P25), whereas the GO-hybridized composite exhibits approximately four to six times enhanced photocatalytic activities than the neat TiO2 photocatalyst in the degradation of colored aromatic organic dyes (crystal violet and rhodamine 6G) under visible-light irradiation (300 W tungsten lamp). The highly efficient activity is associated with the strong surface adsorption ability of GO for aromatic dye molecules, the high carrier acceptability, and the efficient electron–hole pair separation in Bi2O3 by individual adjoining GO sheets. The introduction of Ag nanoparticles (2.0 wt?%) further enhances the photocatalytic performance of the composite over eightfold because of a plasmon-induced electron-transfer process from Ag nanoparticles through the GO sheets into the conduction band of Bi2O3. The new composites are also catalytically active and catalyze the reduction of 4-nitrophenol to 4-aminophenol in the presence of borohydride ions. Photoanodes assembled from GO/α-Bi2O3 and Ag/GO/α-Bi2O3 composites display an improved photocurrent response (power conversion efficiency ~20?% higher) over those prepared without GO in dye-sensitized solar cells. KW - Bismuth KW - Dyes/pigments KW - Environmental chemistry KW - Graphene KW - Photochemistry PY - 2014 DO - https://doi.org/10.1002/cssc.201300990 SN - 1864-5631 SN - 1864-564X VL - 7 IS - 3 SP - 854 EP - 865 PB - Wiley-VCH CY - Weinheim AN - OPUS4-30390 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Fuhrmann, A. A1 - Göstl, R. A1 - Wendt, R. A1 - Kötteritzsch, J. A1 - Hager, M. D. A1 - Schubert, U. S. A1 - Brademann-Jock, Kerstin A1 - Thünemann, Andreas A1 - Nöchel, U. A1 - Behl, M. A1 - Hecht, S. T1 - Conditional repair by locally switching the thermal healing capability of dynamic covalent polymers with light N2 - Healable materials could play an important role in reducing the environmental footprint of our modern technological society through extending the life cycles of consumer products and constructions. However, as most healing processes are carried out by heat alone, the ability to heal damage generally kills the parent material’s thermal and mechanical properties. Here we present a dynamic covalent polymer network whose thermal healing ability can be switched ‘on’ and ‘off’ on demand by light, thereby providing local control over repair while retaining the advantageous macroscopic properties of static polymer networks. We employ a photoswitchable furan-based crosslinker, which reacts with short and mobile maleimidesubstituted poly(lauryl methacrylate) chains forming strong covalent bonds while simultaneously allowing the reversible, spatiotemporally resolved control over thermally induced de- and re-crosslinking. We reason that our system can be adapted to more complex materials and has the potential to impact applications in responsive coatings, photolithography and microfabrication. KW - Small-angle X-ray scattering KW - SAXS KW - Polymer PY - 2016 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-386689 DO - https://doi.org/10.1038/ncomms13623 SN - 2041-1723 VL - 7 SP - Article 13623, 1 EP - 7 PB - NATURE PUBLISHING GROUP CY - MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND AN - OPUS4-38668 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - C. Pardo Pérez, L. A1 - Arndt, A. A1 - Stojkovikj, S. A1 - Y. Ahmet, I. A1 - T. Arens,, J. A1 - Dattila, F. A1 - Wendt, R. A1 - de Oliveira Guilherme Buzanich, Ana A1 - Radtke, Martin A1 - Davies, V. A1 - Höflich, K. A1 - Köhnen, E. A1 - Tockhorn, P. A1 - Golnak, R. A1 - Xiao, J. A1 - Schuck, G. A1 - Wollgarten, M. A1 - López, N. A1 - T. Mayer, M. T1 - Determining Structure-Activity Relationships in Oxide Derived CuSn Catalysts During CO2 Electroreduction Using X-Ray Spectroscopy N2 - The development of earth-abundant catalysts for selective electrochemical CO2 conversion is a central challenge. Cu-Sn bimetallic catalysts can yield selective CO2 reduction toward either CO or formate. This study presents oxide-derived Cu-Sn catalysts tunable for either product and seeks to understand the synergetic effects between Cu and Sn causing these selectivity trends. The materials undergo significant transformations under CO2 reduction conditions, and their dynamic bulk and surface structures are revealed by correlating observations from multiple methods—X-ray absorption spectroscopy for in situ study, and quasi in situ X-ray photoelectron spectroscopy for surface sensitivity. For both types of catalysts, Cu transforms to metallic Cu0 under reaction conditions. However, the Sn speciation and content differ significantly between the catalyst types: the CO-selective catalysts exhibit a surface Sn content of 13 at. % predominantly present as oxidized Sn, while the formate-selective catalysts display an Sn content of ≈70 at. % consisting of both metallic Sn0 and Sn oxide species. Density functional theory simulations suggest that Snδ+ sites weaken CO adsorption, thereby enhancing CO selectivity, while Sn0 sites hinder H adsorption and promote formate production. This study reveals the complex dependence of catalyst structure, composition, and speciation with electrochemical bias in bimetallic Cu catalysts. KW - Electrochemical CO2 conversion KW - Cu catalysts KW - X-ray absorption spectroscopy PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-547116 DO - https://doi.org/10.1002/aenm.202103328 SN - 1614-6832 VL - 12 IS - 5 SP - 2103328 PB - Wiley-VCH GmbH AN - OPUS4-54711 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wendt, Mario A1 - Krebber, Katerina A1 - Glötzl, R. ED - Boller, C. T1 - Development of a PMMA-POF based fiber optic inclinometer with smart transport and installation characteristics T2 - EWSHM'12 - 6th European workshop on structural health monitoring 2012 CY - Dresden, Germany DA - 2012-07-03 PY - 2012 SN - 978-3-940283-41-2 IS - Chapt. Optical Sensors SP - 411 EP - 416 CY - Berlin AN - OPUS4-26193 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lenke, Philipp A1 - Wendt, Mario A1 - Krebber, Katerina A1 - Glötzl, R. ED - Bock, W.J. ED - Albert, J. ED - Bao, X. T1 - Highly sensitive fiber optic inclinometer - easy to transport and easy to install N2 - We present the status of our work on a tube shaped 3D deformation sensor based on continuously distributed fiber optic sensing. A sensor tube of very large diameter is used to ensure high sensitivity while the transportability and applicability are still comfortable due to our application strategy. The setup is designed to use different measurement techniques in the applied optical fibers including Brillouin based measurements and interferometric optical frequency domain measurements using an OBR 4400 from Luna Technologies. T2 - 21st International conference on optical fiber sensors (OFS 21) CY - Ottawa, Canada DA - 15.05.2011 KW - Inclinometer KW - Bend KW - Sensor KW - Fiber KW - Optic KW - Brillouin KW - OBR PY - 2011 SN - 0277-786X N1 - Serientitel: Proceedings of SPIE – Series title: Proceedings of SPIE VL - 7753 SP - 775352-1 EP - 775352-4 AN - OPUS4-24970 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Liehr, Sascha A1 - Lenke, Philipp A1 - Wendt, Mario A1 - Krebber, Katerina A1 - Glötzl, R. A1 - Schneider-Glötzl, J. A1 - Gabino, L. A1 - Krywult, L. ED - Bernadette Havranek, ED - Masoud Motavalli, ED - Urs Meier, T1 - Distributed polymer optical fiber sensors in geotextiles for monitoring of earthwork structures T2 - 4th International conference on structural health monitoring of intelligent infrastructure CY - Zurich, Switzerland DA - 2009-07-22 KW - Distributed sensor KW - Optical fiber sensor KW - Geotextile KW - Technical textile KW - POF sensor KW - Structural health monitoring KW - SHM KW - OTDR KW - Fiber optic sensors KW - Polymer optical fibers (POF) KW - Strain sensor PY - 2009 SN - 978-3-905594-52-2 IS - Paper 520 SP - 1 EP - 7(?) CY - Zurich, Switzerland AN - OPUS4-19787 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schneider-Gloetzl, J. A1 - Gloetzl, R. A1 - Krebber, Katerina A1 - Liehr, Sascha A1 - Wendt, Mario A1 - Wosniok, Aleksander T1 - Geotechnical monitoring of construction activities by distributed fiber optic sensors embedded in geotextiles T2 - 5th European workshop on structural-health-monitoring 2010 CY - Sorrento, Italy DA - 2010-06-29 KW - Foundation engineering KW - Geotechnical monitoring KW - Smart textiles KW - Distributed fiber optic sensors KW - POF sensors KW - Brillouin sensors PY - 2010 IS - SS4-07 SP - 1 EP - 6 AN - OPUS4-21872 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Flatken, M. A. A1 - Radicchi, E. A1 - Wendt, R. A1 - de Oliveira Guilherme Buzanich, Ana A1 - Härk, E. A1 - Pascual, J. A1 - Mathies, F. A1 - Shargaieva, O. A1 - Prause, A. A1 - Dallmann, A. A1 - De Angelis, F. A1 - Hoell, A. A1 - Abate, A. T1 - Role of the Alkali Metal Cation in the Early Stages of Crystallization of Halide Perovskites N2 - ABX3 metal halide perovskites revolutionized the research and development of new optoelectronics, including solar cells and light-emitting diodes. Processing polycrystalline thin films from precursor solutions is one of the core advantages of these materials since it enables versatile and cost-effective manufacturing. The perovskite film morphology, that is, continuous substrate coverage and low surface roughness, is of paramount importance for highly efficient solar cells and optoelectronic devices in general. Controlling the chemistry of precursor solutions is one of the most effective strategies to manage the perovskite film morphology. Herein, we show the fundamental influence of the A-site cation composition on the perovskite precursor arrangement and the consequent film formation. Extended X-ray absorption fine structure spectroscopy and small-angle X-ray scattering give unprecedented insights into the complex structural chemistry of the perovskite precursors and, in particular, their repulsive interactions as a crucial parameter for colloidal stability. Combining these techniques with in situ grazing incidence wide-angle X-ray scattering during thin-film formation allows us to identify the mechanism for using alkali metals as a decisive criterion to control the colloidal stability of the perovskite precursor and thus the thin-film morphology. We illustrate the fundamental principle behind the systematic use of alkali metals regardless of whether they are incorporated in the lattice or not. Hence, this work provides tools to selectively control the morphology and crystal growth in present and future systems KW - MAPbI3 perovskites KW - Halide Perovskites KW - X-ray absorption spectroscopy PY - 2022 DO - https://doi.org/10.1021/acs.chemmater.1c03563 SN - 0897-4756 VL - 34 IS - 3 SP - 1121 EP - 1131 PB - American Chemical Society AN - OPUS4-54713 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Glötzl, R. A1 - Schneider-Glötzl, J. A1 - Liehr, Sascha A1 - Lenke, Philipp A1 - Wendt, Mario A1 - Krebber, Katerina A1 - Gabino, L. A1 - Krywult, J. ED - Klapperich, Herbert ED - Jacob, Dieter ED - Azzam, Rafig ED - Wolf, Rainer T1 - Eine neue Geotextilmessmatte mit verteilter Sensortechnik im Einsatz - Suche einer geeigneten Baustelle, Einbauerfahrungen und erste Ergebnisse T2 - 4. Symposium Umweltgeotechnik & 5. Freiberger Geotechnik-Kolloquium & Fachausstellung CY - Freiberg, Deutschland DA - 2009-06-04 PY - 2009 SN - 1613-4753 IS - Publication 7 SP - 1 EP - 9(?) CY - Freiberg AN - OPUS4-20400 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Glötzl, R. A1 - Schneider-Glötzl, J. A1 - Liehr, Sascha A1 - Lenke, Philipp A1 - Wendt, Mario A1 - Krebber, Katerina A1 - Gabino, L. A1 - Krywult, J. A1 - Krywult, L. T1 - First results of a field test in Belchatow brown coal mine to investigate creeping slopes T2 - VI. International brown coal mining congress "Brown coal - energy - environment - future" CY - Belchatów, Poland DA - 2009-05-18 PY - 2009 SN - 978-83-88316-85-2 SP - 57 EP - 64 PB - Art-Teskt CY - Kraków, Poland AN - OPUS4-20401 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -