TY - CONF A1 - Beckmann, Jörg A1 - von der Ehe, Kerstin A1 - Jaunich, Matthias A1 - Schade, U. A1 - Aziz, E. F. A1 - Wolff, Dietmar T1 - Fourier-spektroskopische Untersuchungen im mittleren- und fernen Infrarotbereich an Co-60 bestrahlten und thermisch belasteten ultrahochmolekularen Polyethylen-Proben T2 - DGZfP-Berichtsband N2 - Fourier-Spektroskopische Untersuchungen von hochmolekularem Polyethylen (HMW-PE) und ultrahochmolekularem Polyethylen (UHMW-PE) im Mittleren - und Fernen Infrarotbereich können Veränderungen der molekularen Strukturen nachweisen, die durch Co60 γ-Strahlung und Rekristallisationsprozesse initiiert werden. UHMW-PE und HMW-PE sind im gewählten IR-Bereich unterscheidbar. Die integrale Absorption der B1u – Gitterschwingungen im Fernen Infrarotbereich (THz-Bereich) ermöglichen die quantitative Beschreibung des Kristallinitätsgrades und dessen Abbau. Die Bildung ungesättigter Vinylengruppen und der Abbau ungesättigter Methylengruppen können im Mittleren Infrarotbereich nachgewiesen werden. T2 - DGZfP-Jahrestagung 2014 CY - Potsdam, Germany DA - 26.05.2014 KW - Infrared and far-infrared spectroscopy KW - Polyethylene KW - Co-60 irradiation PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-313317 SN - 978-3-940283-61-0 VL - 148 SP - 1 EP - 7 PB - Deutsche Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) CY - Berlin AN - OPUS4-31331 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Beckmann, Jörg A1 - Schade, U. A1 - von der Ehe, Kerstin A1 - Jaunich, Matthias A1 - Wolff, Dietmar A1 - Aziz, E. F. T1 - THz and Mid IR Fourier transform spectroscopy on polyethylene irradiated with Gamma- Co60 radiation T2 - IRMMW-THz 2014 - 39th International conference on infrared, millimeter, and terahertz waves N2 - THz and mid IR spectroscopy of high molecular PE (HMW) and ultra high molecular PE (UHMW) reveals modifications of the molecular structure induced by γ-Co60 radiation. UHMW-PE and HMW-PE can be distinguished. The integral absorption in the B1u THz-region can quantitatively describe the amorphization of crystallinity. The formation of trans vinylene unsaturations and the decay of vinyl can be followed by mid IR spectroscopy T2 - IRMMW-THz 2014 - 39th International conference on infrared, millimeter, and terahertz waves CY - Tucson, Arizona, USA DA - 14.09.2014 KW - Thz and Mid IR Fourier transform spectroscopy KW - Polyethylene KW - Gamma-Co-60 radiation KW - Fourier transform spectroscopy KW - Infrared spectroscopy KW - Light absorption KW - Molecular electronic states KW - Polymers KW - MidIR Fourier transform spectroscopy KW - Terahertz spectroscopy KW - THz spectroscopy KW - γ-Co60radiation KW - HMW KW - High molecular PE KW - Ultrahigh molecular PE KW - Molecular structure modifications KW - UHMW-PE KW - HMW-PE KW - Integral absorption KW - B1uTHz-region KW - Crystallinity amorphization KW - Transvinylene unsaturation formation KW - Vinyl decay KW - Absorption KW - Radiation effects KW - Temperature measurement KW - Spectroscopy PY - 2014 UR - http://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=6956355&isnumber=6955975 SN - 978-1-4799-3877-3 DO - https://doi.org/10.1109/IRMMW-THz.2014.6956355 IS - IEEE Catalog No.: CFP14IMM-ART SP - 1 EP - 2 AN - OPUS4-32699 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kömmling, Anja A1 - von der Ehe, Kerstin A1 - Wolff, Dietmar A1 - Jaunich, Matthias T1 - Effect of high-dose gamma irradiation on (U)HMWPE neutron shielding materials JF - Radiation Physics and Chemistry N2 - High and ultra-high molecular weight polyethylenes were gamma-irradiated with doses up to 600 kGy. The changes in the material properties were analysed using DSC, DMA, IR spectroscopy, as well as measurements of density and insoluble content. The irradiation led to an increase of the degree of crystallinity because of chain scissions during irradiation, leading to shorter and thus more mobile chains. Both the plateau value of the shear modulus G′ and the insoluble content increased with Irradiation dose, indicating the formation of additional crosslinks. Furthermore, IR spectroscopy revealed irradiation induced oxidation and the formation of double bonds, indicating that some of the hydrogen atoms responsible for the neutron shielding capability have been released. KW - Ultra high molecular weight KW - Polyethylene KW - Gamma irradiation KW - Crosslinking KW - Oxidation PY - 2018 DO - https://doi.org/10.1016/j.radphyschem.2017.02.014 SN - 0969-806X VL - 142 SP - 29 EP - 33 PB - Elsevier AN - OPUS4-42941 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -