TY - CONF A1 - Nattuveettil, Keerthana A1 - Brunner, Nanine A1 - Tiebe, Carlo A1 - Thomas, Marcus A1 - Melzer, Michael A1 - Bartholmai, Matthias A1 - Johann, Sergej A1 - Neumann, Patrick P. T1 - Digital approach of certification in Quality Infrastructure N2 - QI-Digital is a joined project aiming at digitalising Quality Infrastructure (QI) processes involving standardization, conformity assessment, accreditation, metrology, and market surveillance [1]. Federal institute of material research and testing (BAM) is working on the creation of a digital calibration certifi-cate (DCC) to achieve digital metrological traceability and conformity assessment. The utilisation of machine readable and executable DCCs in the XML format is demonstrated on an example of a tem-perature measurement at a hydrogen refueling station. The certificates will be retrieved and analysed automatically at a Process Control System or at a Digital Twin. T2 - SMSI 2023 Conference CY - Nürnberg, Germany DA - 08.05.2023 KW - Quality Infrastructure KW - Digital Certificates KW - Temperature calibration KW - Digitalisation KW - Hydrogen technology PY - 2023 DO - https://doi.org/10.5162/SMSI2023/A3.4 SP - 51 EP - 52 PB - AMA Service GmbH CY - Wunstorf AN - OPUS4-57964 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Jacobasch, Stefan A1 - Duffner, Eric A1 - Goedecke, Thomas A1 - Portella, Pedro Dolabella A1 - Mair, Georg A1 - Schendler, Thomas A1 - Gradt, Thomas A1 - Askar, Enis A1 - Bartholmai, Matthias A1 - Schröder, Volkmar A1 - Maiwald, Michael A1 - Holtappels, Kai A1 - Tschirschwitz, Rico A1 - Neumann, Patrick P. T1 - Unser Beitrag zum Thema Wasserstoff N2 - Die BAM ist nahezu über die gesamte Wertschöpfungskette hinweg wissenschaftlich tätig. Von der sicheren und effizienten Wasserstofferzeugung (POWER-to-GAS), über die (Zwischen-)Speicherung von Wasserstoff in Druckgasspeichern bis hin zum Transport bspw. mittels Trailerfahrzeug zum Endverbraucher. Komplettiert werden die Aktivitäten der BAM durch die sicherheitstechnische Beurteilung von wasserstoffhaltigen Gasgemischen, die Verträglichkeitsbewertung von Werkstoffen bis hin zur Detektion von Wasserstoffkonzentrationen über geeignete Sensorik, auch mittels ferngesteuerter Messdrohnen (sog. UAV-Drohnen). Zudem untersucht die BAM proaktiv Schadensrisiken und Unfallszenarien für die Sicherheitsbetrachtung, um mögliche Schwachstellen aufzeigen und potenzielle Gefährdungen erkennen zu können. KW - Wasserstoff KW - Wasserstofferzeugung KW - Energiespeicherung KW - Gasdetektion KW - Risikoanalyse KW - Power-to-Gas KW - Explosionsschutz KW - Tribologie KW - Druckgasspeicher KW - Glasspeicher KW - Gassensorik KW - Mini-UAV PY - 2019 SP - 1 CY - Berlin AN - OPUS4-47960 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neumann, Patrick P. A1 - Grotelüschen, Bjarne A1 - Bartholmai, Matthias A1 - Strangfeld, Christoph ED - Kossa, A. ED - Kiss, R. T1 - Towards Autonomous NDT Inspection: Setup and Validation of an Indoor Localization System N2 - Monitoring and maintenance of civil infrastructure are of great importance, as any undetected damage can cause high repair costs, unintended deadtime, or endanger structural integrity. The inspection of large concrete structures such as bridges and parking lots is particularly challenging and time-consuming. Traditional methods are mostly manual and involve mapping a grid of measurement lines to record the position of each measurement. Current semi-automated methods, on the other hand, use GPS or tachymeters for localization but still require trained personnel to operate. An entirely automated approach using mobile robots would be more cost- and time-efficient. While there have been developments in using GPS-enabled mobile robots for bridge inspection, the weak signal strength in indoor areas poses a challenge for the automated inspection of structures such as parking lots. This paper aims to develop a solution for the automated inspection of large indoor concrete structures by addressing the problem of robot localization in indoor spaces and the automated measurement of concrete cover and rebar detection. T2 - 39th Danubia-Adria Symposium on Advances in Experimental Mechanics CY - Siófok, Hungary DA - 26.09.2023 KW - NDT Inspection KW - Mobile Robot KW - Indoor Localization KW - Setup and Validation PY - 2023 SN - 978-963-421-927-9 SP - 88 EP - 89 PB - Hungarian Scientific Society of Mechanical Engineering (GTE) CY - Siófok, Hungary AN - OPUS4-58660 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neumann, Patrick P. A1 - Bartholmai, Matthias A1 - Grotelüschen, Bjarne A1 - Strangfeld, Christoph T1 - Towards Autonomous NDT Inspection: Setup and Validation of an Indoor Localization System N2 - Monitoring and maintenance of civil infrastructure are of great importance, as any undetected damage can cause high repair costs, unintended deadtime, or endanger structural integrity. The inspection of large concrete structures such as bridges and parking lots is particularly challenging and time-consuming. Traditional methods are mostly manual and involve mapping a grid of measurement lines to record the position of each measurement. Current semi-automated methods, on the other hand, use GPS or tachymeters for localization but still require trained personnel to operate. An entirely automated approach using mobile robots would be more cost- and time-efficient. While there have been developments in using GPS-enabled mobile robots for bridge inspection, the weak signal strength in indoor areas poses a challenge for the automated inspection of structures such as parking lots. This paper aims to develop a solution for the automated inspection of large indoor concrete structures by addressing the problem of robot localization in indoor spaces and the automated measurement of concrete cover and rebar detection. T2 - 39th Danubia-Adria Symposium on Advances in Experimental Mechanics CY - Siófok, Hungary DA - 26.09.2023 KW - NDT Inspection KW - Mobile Robot KW - Indoor Localization KW - Setup and Validation PY - 2023 AN - OPUS4-58662 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mansurova, Maria A1 - Gotor, Raúl A1 - Johann, Sergej A1 - Neumann, Patrick P. A1 - Bartholmai, Matthias A1 - Rurack, Knut A1 - Bell, Jérémy T1 - Fluorescent Hydrophobic Test Strips with Sterically Integrated Molecular Rotors for the Detection of Hydrocarbons in Water and Soil with an Embedded Optical Read-Out N2 - Contamination of natural bodies of water or soil with oils and lubricants (or generally, hydrocarbon derivatives such as petrol, fuels, and others) is a commonly found phenomenon around the world due to the extensive production, transfer, and use of fossil fuels. In this work, we develop a simple system for the on-field detection of total petroleum hydrocarbons (TPHs) in water and soil. The test is based on the measurement of the fluorescence signal emitted by the molecular rotor 2-[ethyl[4-[2-(4-nitrophenyl)ethenyl]phenyl]amino]ethanol (4-DNS-OH). This dye is embedded in a hydrophobic polymeric matrix (polyvinylidene fluoride), avoiding interactions with water and providing a robust support for use in a test strip fashion. Together with the strips, an embedded optical system was designed for fluorescence signal read-out, featuring a Bluetooth low-energy connection to a commercial tablet device for data processing and analysis. This system works for the detection and quantification of TPHs in water and soil through a simple extraction protocol using a cycloalkane solvent with a limit of detection of 6 ppm. Assays in surface and sea waters were conclusive, proving the feasibility of the method for in-the-field operation. KW - Test strip KW - Sensor KW - Smartphone KW - Fluorescence KW - Test Streifen KW - Sensoren KW - Fluoreszenz KW - Petrol KW - Öl PY - 2023 DO - https://doi.org/10.1021/acs.energyfuels.3c01175 SN - 0887-0624 SP - 1 EP - 6 PB - American Chemical Society CY - Washington, United States AN - OPUS4-57892 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mansurova, Maria A1 - Johann, Sergej A1 - Kohlhoff, Harald A1 - Rurack, Knut A1 - Bartholmai, Matthias A1 - Bell, Jérémy T1 - On-Site Analytical Tool Based on Crude Oil Fluorescence and Chemometrics for the Rapid Determination of the Nature and Essential Properties of Oil Spills N2 - With the reduction of large oil spills because of stricter regulations and safety measures, the question of how to manage smaller oil spills arises. Few on-site analytical tools are available for first responders or other law enforcement personnel to rapidly test for crude oil in the early management of localized polluted areas. The approach reported here relies on well-described computer-assisted multivariate data analysis of the intrinsic fluorescence fingerprints of crude oils to build a multivariate model for the rapid classification of crude oils and the prediction of their properties. Thanks to a dedicated robust portable reader, the method allowed classification and accurate prediction of various properties of crude oil samples like density (according to API, the American Petroleum Institute and viscosity as well as composition parameters such as volume fractions of paraffins or aromatics. In this way, autonomous operation in on-site or in-the-field applications becomes possible based on the direct (undiluted and untreated) measurement of samples and a rapid, tablet-operated readout system to yield a robust and simple analytical test with superior performance. Testing in real-life scenarios allowed the successful classification and prediction of a number of oil spill samples as well as weathered samples that closely resemble samples collected by first responders. KW - Oil spills KW - Fluorescence KW - PCA KW - Petroleum KW - Rapid test KW - Portable PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595442 DO - https://doi.org/10.1021/acsestwater.3c00648 VL - 4 IS - 2 SP - 621 EP - 627 PB - American Chemical Society (ACS) AN - OPUS4-59544 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bartholmai, Matthias A1 - Schartel, Bernhard T1 - Layered silicate polymer nanocomposites: new approach or illusion for fire retardancy? Investigations of the potentials and the tasks using a model system N2 - Polymeric nanocomposites are discussed as one of the most promising advanced materials whose nanoscale effects can be exploited for industry. Layered silicate polypropylene-graft-maleic anhydride nanocomposites are investigated as a model to clarify the potential of such materials in terms of fire retardancy. The nanostructure is characterized using transmission electron microscopy (TEM) and shear viscosity. The fire behavior is characterized using different external heat fluxes in cone calorimeter, limiting oxygen index and UL 94 classification. A comprehensive fire behavior characterization is presented which enables an assessment of the materials’ potential with respect to different fire scenarios and fire tests. The influence of morphology and the active mechanisms are discussed, such as barrier formation and changed melt viscosity. To our knowledge, it is the first attempt to illuminate the concept’s strengths, such as the reduction of flame spread, and weaknesses, such as the lack of influence on ignitability, in a clear, comprehensive and detailed manner. KW - Fire retardancy KW - Nanocomposites KW - Cone Calorimeter KW - LOI KW - UL94 KW - Flame retardance KW - poly(propylene) (PP) KW - Organoclay PY - 2004 UR - http://www3.interscience.wiley.com/cgi-bin/jissue/109085890 SN - 1042-7147 SN - 1099-1581 VL - 15 IS - 7 SP - 355 EP - 364 PB - John Wiley & Sons, Ltd. CY - Chichester AN - OPUS4-3706 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schartel, Bernhard A1 - Kunze, Ralf A1 - Bartholmai, Matthias A1 - Neubert, Dietmar A1 - Schriever, Robert T1 - TG-MS and TG-FTIR applied for an unambiguous thermal analysis of intumescent coatings N2 - Thermogravimetry (TG), thermogravimetry coupled with mass spectroscopy (TG-MS) and thermogravimetry coupled with Fourier transform infrared spectroscopy (TG-FTIR) were used to characterise the thermo-oxidative behaviour of two intumescent coating materials. The temperature dependence, the corresponding volatile products and the amount of residue of the different processes were determined. Using both TG-MS and TG-FTIR results in an unambiguous interpretation of the volatile products. Characteristics such as the influence of endothermic reactions, the release of non-flammable gases, the dehydrogenation enhancing the char formation and the stability of the cellular char were discussed in detail. It was demonstrated, that TG, TG-MS and TG-FTIR are powerful methods to investigate mechanisms in intumescent coatings and that they are suitable methods in respect to quality assurance and unambiguous identification of such materials. KW - Intumescent coating materials KW - TG KW - TG-FTIR KW - TG-MS PY - 2002 DO - https://doi.org/10.1023/A:1022272707412 SN - 1388-6150 SN - 1418-2874 SN - 0368-4466 SN - 1572-8943 VL - 70 IS - 3 SP - 897 EP - 909 PB - Kluwer Academic Publ. CY - Dordrecht AN - OPUS4-2133 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hartwig, A. A1 - Pütz, D. A1 - Schartel, Bernhard A1 - Bartholmai, Matthias A1 - Wendschuh-Josties, M. T1 - Combustion behaviour of epoxide based nanocomposites with ammonium and phosponium bentonites N2 - The influence of different organobentonites on the decomposition and the combustion behaviour of an epoxy resin were examined. The epoxy resin is a cationically polymerised cycloaliphatic epoxy resin flexibilised with poly(tetrahydrofuran) (PTHF), with hydroxyl endgroups. The bentonite was modified with either an ammonium or a phosphonium salt. The thermal decomposition of the PTHF induced by the initiator, used for the cationic polymerisation, did neither take place for the nanocomposite based on the ammonium bentonite nor for that based on the phosphonium bentonite. This improved decomposition characteristic lead to a larger time to ignition for both kinds of nanocomposites compared to the not modified polymer, which is not the case for other polymer/clay nanocomposites described in the literature. The fire behaviour was investigated using limiting oxygen index (LOI), a horizontal burner test and a cone calorimeter. The forced flaming conditions in the cone calorimeter were varied using different external heat fluxes between 30 and 70 kW · m-2. The fire behaviour of the nanocomposites was improved in comparison to the polymer, and phosphonium bentonite was superior to ammonium bentonite. The main mechanism is a barrier formation resulting in a reduction of the fire growth rate, which was more pronounced in the case of high external heat fluxes. KW - Cationic polymerisation KW - Clay KW - Combustion KW - Degradation KW - Epoxide KW - Nanocomposite PY - 2003 DO - https://doi.org/10.1002/macp.200300047 SN - 1022-1352 SN - 1521-3935 VL - 204 IS - 18 SP - 2247 EP - 2257 PB - Wiley-VCH Verl. CY - Weinheim AN - OPUS4-2801 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bartholmai, Matthias A1 - Schriever, Robert A1 - Schartel, Bernhard T1 - Influence of external heat flux and coating thickness on the thermal insulation properties of two different intumescent coatings using cone calorimeter and numerical analysis N2 - Polymeric intumescent coatings are fire protective materials that increase their thermal resistance when exposed to high temperatures to prevent building structures from damage. The idea of the investigation was to develop a simple test method to determine the time dependent thermal conductivity of intumescent coatings. Therefore steel plates were coated with two different intumescent systems. During cone calorimeter tests the temperature at the back side of the coated plates was measured. These results were used to calculate the time dependent thermal resistance of the protective layer with the simulation program IOPT2D for different external heat fluxes and different layer thickness. KW - Intumescent coatings KW - Thermal resistance KW - Cone calorimetry KW - Numerical analysis PY - 2003 DO - https://doi.org/10.1002/fam.823 SN - 0308-0501 SN - 1099-1018 VL - 27 IS - 4 SP - 151 EP - 162 PB - Heyden CY - London AN - OPUS4-2633 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard A1 - Bartholmai, Matthias A1 - Braun, Ulrike T1 - Residue, Charring and Intumescence N2 - The exploration of condensed phase mechanisms such as charring and intumescence has been pushed forward in the last decades, since it is believed that focusing on these concepts will bring materials closer to an efficient and ecologically friendly fire retardancy. They promise to concentrate efficient fire retardancy at the key position between pyrolysis zone and gas phase. Examples of residue/char forming and intumescent materials are used to illustrate the influence of mass and heat barrier effects on the fire behavior of materials and general results are presented. A comprehensive understanding of the mechanisms and structure-property relationships in fire retardancy is presented. KW - Fire retardancy KW - Nanocomposites KW - Red Phosphorus KW - Intumescence KW - Cone Calorimeter PY - 2006 SN - 1-59623-221-8 VL - XV SP - 15 EP - 21 PB - BCC Research CY - Norwalk, Conn. AN - OPUS4-4068 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bartholmai, Matthias A1 - Schartel, Bernhard T1 - Comprehensive Fire Behaviour Assessment of Nanocomposites T2 - 9th European Meeting on Fire Retardancy and Protection of Materials, FRPM '03 CY - Lille, France DA - 2003-09-17 PY - 2003 AN - OPUS4-4615 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schartel, Bernhard A1 - Bartholmai, Matthias A1 - Knoll, Uta T1 - Some comments on the use of cone calorimeter data N2 - The cone calorimeter has become one of the most important and widely used instruments for the research and development of fire retarded polymeric materials. The paper addresses three important ways in which the principal setup influences the results — factors which sometimes do not receive due consideration when drawing conclusions. The paper discusses in detail the impact on cone calorimeter results of the choice of external heat flux, the influence on the peak of heat release rate of sample thickness and thermal feedback from the back of the sample, and the influence on irradiance of the horizontal and vertical distances from the cone heater. KW - Cone Calorimeter KW - Fire retardancy KW - Fire testing KW - Nanocomposites KW - Intumescence PY - 2005 DO - https://doi.org/10.1016/j.polymdegradstab.2004.12.016 SN - 0141-3910 SN - 1873-2321 VL - 88 IS - 3 SP - 540 EP - 547 PB - Applied Science Publ. CY - London AN - OPUS4-7211 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Schartel, Bernhard A1 - Bartholmai, Matthias A1 - Braun, Ulrike ED - Le Bras, M. T1 - Barrier effects for the fire retardancy of polymers T2 - 9th European Meeting on Fire Retardancy and Protection of Materials CY - Lille, France DA - 2003-09-15 KW - Fire retardancy KW - Nanocomposites KW - Red Phosphorus KW - Mg(OH)2 KW - Cone Calorimeter KW - LOI PY - 2005 SN - 0-85404-582-1 VL - 9 SP - 264 EP - 275 PB - Royal Society of Chemistry CY - Cambridge AN - OPUS4-7377 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bartholmai, Matthias A1 - Schartel, Bernhard T1 - A new approach for assessing the performance of intumescent coatings T2 - 10th European Meeting on Fire Retardancy and Protection of Materials (10th European Conference on Fire Retardant Polymers), FRPM '05, BAM CY - Berlin, Germany DA - 2005-09-07 PY - 2005 AN - OPUS4-6363 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schartel, Bernhard A1 - Braun, Ulrike A1 - Knoll, Uta A1 - Bartholmai, Matthias A1 - Goering, Harald A1 - Neubert, Dietmar A1 - Pötschke, P. T1 - Mechanical, Thermal, and Fire Behavior of Bisphenol A Polycarbonate/Multiwall Carbon Nanotube Nanocomposites N2 - Nanocomposites of bisphenol A polycarbonate with 2, 4, 6, and 15 wt% multiwall carbon nanotubes (MWNT) and their use in fire retardancy are investigated. Their thermal behavior and pyrolysis are characterized using thermogravimetry, differential scanning calorimeter, oscillatory shear rheology, and dynamic mechanical analysis. The flammability is addressed using LOI and UL 94; the fire behavior, with a cone calorimeter using different irradiation. With increasing MWNT content the storage modulus is increased (10-20%) and melt viscosity increases by several orders of magnitude, particularly for low shear rates. The melt flow, dripping, and deformation during fire are hindered, which influences UL 94 and cone calorimeter results. The peak heat release rate is reduced up to 40-50% due to an improved barrier for small amounts (2 wt%) of MWNT and for low irradiation, whereas the effect is reduced for increasing irradiation and nearly vanishes for increasing filling. Adjuvant but also deleterious mechanisms result in the complex dependency on the MWNT content. Significant flame retardancy effects are specific and limited to only some fire properties. This study allows the materials' potential for implementation in different fire scenarios and tests to be assessed and provides insight into active mechanisms. KW - Flame retardancy KW - Nanocomposite KW - Carbon multiwall nanotube (MWNT) KW - Cone Caorimeter KW - Flammability PY - 2008 DO - https://doi.org/10.1002/pen.20932 SN - 0032-3888 SN - 1548-2634 VL - 48 IS - 1 SP - 149 EP - 158 PB - Wiley CY - Hoboken, NY AN - OPUS4-16365 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schartel, Bernhard A1 - Bartholmai, Matthias A1 - Knoll, Uta T1 - Some comments on the main fire retardancy mechanisms in polymer nanocomposites N2 - Barrier formation and increasing the melt viscosity are addressed as the two main general fire retardancy mechanisms of polymer nanocomposites. They result in specific impacts on fire properties that consequentially cause varying flame retardancy efficiency in different fire tests. The barrier formation retards mainly flame spread (peak of heat release rate) in developing fires, but does not reduce fire load (total heat evolved), ignitability or flammability (limiting oxygen index, UL 94). Furthermore, this flame retardancy effect increases with increasing irradiation and vanishes with decreasing irradiation. The increased melt viscosity prevents dripping, which is beneficial or disadvantageous depending on the fire test used. In some test, it become the dominant influence, transforming self-extinguishing samples into flammable materials or causing wicking. Advantages and the limits are sketched comprehensively for exploiting the main general fire retardancy mechanisms of polymer nanocomposites. It is concluded that barrier formation and changing the melt viscosity in nanocomposites are not sufficient for most applications, but must be accompanied by additional mechanisms in special systems or in combination with other flame retardants. KW - Flame retardance KW - Nanocomposites KW - Organoclay KW - Cone calorimeter KW - Flammability PY - 2006 DO - https://doi.org/10.1002/pat.792 SN - 1042-7147 SN - 1099-1581 VL - 17 IS - 9-10 SP - 772 EP - 777 PB - John Wiley & Sons, Ltd. CY - Chichester AN - OPUS4-13868 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bartholmai, Matthias A1 - Schartel, Bernhard T1 - Assessing the performance of intumescent coatings using bench-scaled cone calorimeter and finite difference simulations N2 - A method was developed to assess the heat insulation performance of intumescent coatings. The method consists of temperature measurements using the bench-scaled experimental set-up of a cone calorimeter and finite difference simulation to calculate the effective thermal conductivity dependent on time/temperature. This simulation procedure was also adapted to the small scale test furnace, in which the standard time-temperature curve is applied to a larger sample and thus which provides results relevant for approval. Investigations on temperature and calculated effective thermal conduction were performed on intumescent coatings in both experimental set-ups using various coating thicknesses. The results correspond to each other as well as showing the limits of transferability between both fire tests. It is shown that bench-scaled cone calorimeter tests are a valuable tool for assessing and predicting the performance of intumescent coatings in larger tests relevant for approval. The correlation fails for processes at surface temperatures above 750°C, which are not reached in the cone calorimeter, but are attained in the small scale furnace set-up. KW - Intumescent coatings KW - Cone calorimetry KW - Numerical analysis KW - Small scale test furnace PY - 2007 SN - 0308-0501 SN - 1099-1018 VL - 31 IS - 3 SP - 187 EP - 205 PB - Heyden CY - London AN - OPUS4-14645 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Johann, Sergej A1 - Stührenberg, Jan A1 - Tandon, Aditya A1 - Dragos, Kosmas A1 - Bartholmai, Matthias A1 - Strangfeld, Christoph A1 - Smarsly, Kay T1 - Implementation and validation of robot-enabled embedded sensors for structural health monitoring N2 - In the past decades, structural health monitoring (SHM) has matured into a viable supplement to regular inspections, facilitating the execution of repair and maintenance work in the early stages of structural damage. With the advent of wireless technologies and advancements in information and communication technologies, civil infrastructure has been increasingly instrumented with wireless sensor nodes to record, analyze, and communicate data relevant to SHM. A promising method for SHM is to embed sensors directly into concrete for recording SHM data from inside structural elements. In this paper, a sensor system for embedment into concrete is proposed, able to assess SHM data recorded from concrete. Power is supplied to the sensors on-demand by quadruped robots, which also collect the SHM data via radio-frequency identification (RFID), providing an automated and efficient SHM process. In laboratory experiments, the capability of the sensor system of automatically collecting the SHM data using quadruped robots is validated. In summary, the integration of RFID technology and robot-based inspection presented in this study demonstrates a vital approach to evolve current SHM practices towards more digitalized and automated SHM. T2 - 11th European Workshop On Structural Health Monitoring CY - Potsdam, Germany DA - 10.06.2024 KW - Structural health monitoring KW - RFID-based sensors KW - Smart sensors KW - Embedded sensors KW - Legged robots KW - Quadruped robots PY - 2024 SP - 1 EP - 8 AN - OPUS4-60335 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Johann, Sergej A1 - Strangfeld, Christoph A1 - Müller, Maximilian A1 - Mieller, Björn A1 - Bartholmai, Matthias ED - Emri, I. T1 - RFID sensor systems embedded in concrete – requirements for long–term operation N2 - Structural Health Monitoring (SHM) is an important topic for Industry 4.0. More and more systems are embedded in different materials and are connected to each other. To embed sensors for a long time in concrete, an exact preparation is required. In this paper, we identify Radio-Frequency Identification (RFID) as promising technology for monitoring of concrete structures. This paper present the concept for long term monitoring, defines the requirements and shows first development steps, for example, the system design, the possibilities of sensor connection, and an encapsulation for embedding in concrete. T2 - 33nd Danubia Adria Symposium on Advances in Experimental Mechanics CY - Portoroz, Slovenia DA - 20.09.2016 KW - RFID sensors KW - Long-term requirements KW - Structural health monitoring KW - Passive RFID KW - Sensor requirements KW - Sensors in concrete KW - Smart structures PY - 2017 UR - http://www.sciencedirect.com/science/article/pii/S2214785317308283 DO - https://doi.org/10.1016/j.matpr.2017.06.053 SN - 2214-7853 VL - 4 IS - 5, Part 1 SP - 5827 EP - 5832 PB - Elsevier Ltd. AN - OPUS4-41581 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bartholmai, Matthias A1 - Johann, Sergej A1 - Strangfeld, Christoph A1 - Müller, Maximilian A1 - Mieller, Björn T1 - RFID sensor systems embedded in concrete – validation experiments for long-term monitoring N2 - Structural Health Monitoring (SHM) is an important part of buildings surveillance and maintenance to detect material failure as early as possible and to contribute in protection of structures and their users. The implementation of Radio Frequency Identification (RFID) sensor systems without cable connection and battery into building components offers innovative possibilities to enable long-term in-situ SHM of addressed structures, bridges. The objectives of the presented study are complete embedding of RFID sensors systems in concrete, full passive communication with the systems, at best for the whole life span of structures. One challenge for this task is the highly alkaline environment in concrete, which requires non-degrading and robust encapsulation. Further Requirements are passive communication and energy supply, appropriate antenna design, placement and fixation in concrete, and the selection and implementation of sensors and connections. The concept is to develop and optimize a simple and robust system, which meets the requirements, as well as comprehensive validation in concrete specimen and real world applications. Two different systems were developed (HF and UHF RFID, respectively). First tasks were the implementation of analog sensors using the superposition principle for the signal adaption. Investigation of suitable materials for robust encapsulation and sensor protection against basic environments. Four materials were investigated in pH 13 solution for 14 days - 3D-Printer-Polymer was completely resolved - PVC has no noticeable decrease in weight - (VitaPro) glass filter for the sensor protector, has weight loss 2.7 % - The epoxy resin has increased by 1.8 % due to moisture expansion Different concrete samples were prepared for the validation of the systems. RFID sensors were embedded in different integration depths. Investigate the energy- and data transfer through concrete, also with varying moisture content. Additionally, signal strength data was used to optimize and validate the antenna characteristics in concrete. Next steps are to guarantee a sufficient energy supply for UHF RFID systems embedded in different concrete mixtures and further embedding the HF and UHF RFID systems in real bridges and buildings to validate the long term monitoring. T2 - DGZfP-Jahrestagung 2017 CY - Koblenz, Germany DA - 22.05.2017 KW - RFID sensors KW - Long-term requirements KW - Structural health monitoring KW - Passive RFID KW - Sensor requirements KW - Sensors in concrete KW - Smart structures PY - 2017 AN - OPUS4-40348 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hüllmann, Dino A1 - Neumann, Patrick P. A1 - Scheuschner, Nils A1 - Bartholmai, Matthias A1 - Lilienthal, A.J. T1 - Experimental Validation of the Cone-Shaped Remote Gas Sensor Model N2 - Remote gas sensors mounted on mobile robots enable the mapping of gas distributions in large or hardly accessible areas. A challenging task, however, is the generation of threedimensional distribution maps from these gas measurements. Suitable reconstruction algorithms can be adapted, for instance, from the field of computed tomography (CT), but both their performance and strategies for selecting optimal measuring poses must be evaluated. For this purpose simulations are used, since, in contrast to field tests, they allow repeatable conditions. Although several simulation tools exist, they lack realistic models of remote gas sensors. Recently, we introduced a model for a Tunable Diode Laser Absorption Spectroscopy (TDLAS) gas sensor taking into account the conical shape of its laser beam. However, the novel model has not yet been validated with experiments. In this paper, we compare our model with a real sensor device and show that the assumptions made hold. T2 - IEEE Sensors 2019 CY - Montreal, Canada DA - 27.10.2019 KW - Remote gas sensor model KW - TDLAS KW - Gas dispersion simulation PY - 2019 SN - 978-1-7281-1634-1 SP - 104 EP - 107 PB - IEEE AN - OPUS4-49548 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bartholmai, Matthias A1 - Hüllmann, Dino A1 - Neumann, Patrick P. A1 - Scheuschner, Nils A1 - Lilienthal, A.J. T1 - Experimental Validation of the Cone-Shaped Remote Gas Sensor Model N2 - Remote gas sensors mounted on mobile robots enable the mapping of gas distributions in large or hardly accessible areas. A challenging task, however, is the generation of threedimensional distribution maps from these gas measurements. Suitable reconstruction algorithms can be adapted, for instance, from the field of computed tomography (CT), but both their performance and strategies for selecting optimal measuring poses must be evaluated. For this purpose simulations are used, since, in contrast to field tests, they allow repeatable conditions. Although several simulation tools exist, they lack realistic models of remote gas sensors. Recently, we introduced a model for a Tunable Diode Laser Absorption Spectroscopy (TDLAS) gas sensor taking into account the conical shape of its laser beam. However, the novel model has not yet been validated with experiments. In this paper, we compare our model with a real sensor device and show that the assumptions made hold. T2 - IEEE Sensors 2019 CY - Montreal, Canada DA - 27.10.2019 KW - Remote gas sensor model KW - TDLAS KW - Gas dispersion simulation PY - 2019 AN - OPUS4-49549 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Johann, Sergej A1 - Strangfeld, Christoph A1 - Müller, Maximilian A1 - Mieller, Björn A1 - Bartholmai, Matthias T1 - RFID sensor systems embedded in concrete – validation experiments for long-term monitoring N2 - Structural Health Monitoring (SHM) is an important part of buildings surveillance and maintenance to detect material failure as early as possible and to contribute in protection of structures and their users. The implementation of Radio Frequency Identification (RFID) sensor systems without cable connection and battery into building components offers innovative possibilities to enable long-term in-situ SHM of addressed structures, bridges. The objectives of the presented study are complete embedding of RFID sensors systems in concrete, full passive communication with the systems, at best for the whole life span of structures. One challenge for this task is the highly alkaline environment in concrete, which requires non-degrading and robust encapsulation. Further Requirements are passive communication and energy supply, appropriate antenna design, placement and fixation in concrete, and the selection and implementation of sensors and connections. The concept is to develop and optimize a simple and robust system, which meets the requirements, as well as comprehensive validation in concrete specimen and real world applications. Two different systems were developed (HF and UHF RFID, respectively). First tasks were the implementation of analog sensors using the superposition principle for the signal adaption. Investigation of suitable materials for robust encapsulation and sensor protection against basic environments. Four materials were investigated in pH 13 solution for 14 days - 3D-Printer-Polymer was completely resolved - PVC has no noticeable decrease in weight - (VitaPro) glass filter for the sensor protector, has weight loss 2.7 % - The epoxy resin has increased by 1.8 % due to moisture expansion Different concrete samples were prepared for the validation of the systems. RFID sensors were embedded in different integration depths. Investigate the energy- and data transfer through concrete, also with varying moisture content. Additionally, signal strength data was used to optimize and validate the antenna characteristics in concrete. Next steps are to guarantee a sufficient energy supply for UHF RFID systems embedded in different concrete mixtures and further embedding the HF and UHF RFID systems in real bridges and buildings to validate the long term monitoring. T2 - DGZfP-Jahrestagung 2017 CY - Koblenz, Germany DA - 22.05.2017 KW - Smart structures KW - RFID sensors KW - Long-term requirements KW - Structural health monitoring KW - Passive RFID KW - Sensor requirements KW - Sensors in concrete PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-403496 UR - https://www.ndt.net/?id=21499 SN - 1435-4934 VL - 22 IS - 9 SP - 1 EP - 7 PB - NDT.net CY - Kirchwald AN - OPUS4-40349 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Johann, Sergej A1 - Strangfeld, Christoph A1 - Müller, Maximilian A1 - Mieller, Björn A1 - Bartholmai, Matthias T1 - RFID sensor systems embedded in concrete – Validation experiments for long-term monitoring T1 - RFID Sensorsysteme eingebettet in Beton – Validierungsexperimente zum Langzeitmonitoring N2 - Structural Health Monitoring (SHM) is an important part of buildings surveillance and maintenance to detect material failure as early as possible and to contribute in protection of structures and their users. The implementation of Radio Frequency Identification (RFID) sensor systems without cable connection and battery into building components offers innovative possibilities to enable long-term in-situ SHM of addressed structures, bridges. The objectives of the presented study are complete embedding of RFID sensors systems in concrete, full passive communication with the systems, at best for the whole life span of structures. One challenge for this task is the highly alkaline environment in concrete, which requires non-degrading and robust encapsulation. Further Requirements are passive communication and energy supply, appropriate antenna design, placement and fixation in concrete, and the selection and implementation of sensors and connections. The concept is to develop and optimize a simple and robust system, which meets the requirements, as well as comprehensive validation in concrete specimen and real world applications. Two different systems were developed (HF and UHF RFID, respectively). First tasks were the implementation of analog sensors using the superposition principle for the signal adaption. Investigation of suitable materials for robust encapsulation and sensor protection against basic environments. Four materials were investigated in pH13 solution for 14 days - 3D-Printer-Polymer was completely resolved - PVC has no noticeable decrease in weight - (VitaPro) glass filter for the sensor protector, has weight loss 2.7% - The epoxy resin has increased by 1.8% due to moisture expansion Different concrete samples were prepared for the validation of the systems. RFID sensors were embedded in different integration depths. Investigate the energy- and data transfer through concrete, also with varying moisture content. Additionally, signal strength data was used to optimize and validate the antenna characteristics in concrete. Next steps are to guarantee a sufficient energy supply for UHF RFID systems embedded in different concrete mixtures and further embedding the HF and UHF RFID systems in real bridges and buildings to validate the long term monitoring. KW - RFID sensors KW - Structural health monitoring KW - Sensors in concrete KW - Smart structures KW - Sensor requirements PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-418331 UR - http://www.ndt.net/?id=21499 SN - 1435-4934 VL - 22 IS - 9 SP - Artikel 8, 1 EP - 7 PB - NDT.net CY - Bad Breisig AN - OPUS4-41833 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -