TY - JOUR A1 - Sturm, Heinz A1 - Cappella, Brunero A1 - Heyde, M. A1 - Ritter, C. A1 - Rademann, K. T1 - Dislocation of antimony clusters on graphite by means of dynamic plowing nanolithography N2 - Antimony clusters of different shapes and dimensions have been obtained by evaporating antimony on graphite. The dependence of the shape and dimensions of the particles on the evaporation parameters (effective layer thickness, temperature, pressure) is discussed. A characterisation of the different structures is presented. In particular, the decoration of graphite steps is discussed. Clusters have been dislocated by means of dynamic plowing nanolithography, both in vector and in image pattern mode. The dependence of the energy needed to dislocate a cluster on its dimensions and position is discussed. KW - Antimony clusters KW - Nanolithography PY - 2001 DO - https://doi.org/10.1016/S0039-6028(00)01113-4 SN - 0039-6028 VL - 476 IS - 1-2 SP - 54 EP - 62 PB - Elsevier CY - Amsterdam AN - OPUS4-875 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ebell, Gino A1 - Scheerer, S. A1 - Fiedler, M. A1 - Schacht, G. A1 - Ritter, R. A1 - Marzahn, G. A1 - Marx, S. T1 - Die wechselvolle Geschichte der Carolabrücke in Dresden N2 - Am 11. September 2024 fand in Dresden ein Ereignis statt, welches man in Deutschland nicht erwartet hatte: der Teileinsturz einer Spannbetonbrücke unter Betrieb ohne Vorankündigung. Die Dresdner Carolabrücke war eine Ikone der Ingenieurbaukunst ihrer Zeit. Sie war ein sehr ästhetisches und schlankes Bauwerk. Ihre Konstruktion und Bau wären auch heute noch eine Herausforderung. Die vorhandenen Unterlagen zeugen von einer hohen Entwurfsqualität und einer sehr sorgsamen Bauausführung. Im Beitrag werden die Entstehungsgeschichte, die Konstruktion selbst und der Bau der Brücke vorgestellt. Es wird der Versuch der Rekonstruktion des Einsturzvorgangs unternommen und die Suche nach der Einsturzursache beschrieben. Am Schluss des Beitrags wird auf das aktuelle Überwachungskonzept eingegangen und ein Ausblick auf das mögliche weitere Vorgehen gegeben. T2 - 34. Dresdner Brückenbausymposium CY - Dresden, Germany DA - 19.03.2025 KW - Spanungsrisskorrosion KW - Wasserstoff KW - Spannstahl KW - Brücke PY - 2025 SP - 15 EP - 33 CY - Dresden AN - OPUS4-63063 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Jaeger, Carsten A1 - Ritter, D. A1 - Goeritzer, M. A1 - Thiele, A. A1 - Blumrich, A. A1 - Beyhoff, N. A1 - Luettges, K. A1 - Smeir, E. A1 - Kasch, J. A1 - Grune, J. A1 - Müller, O. A1 - Klopfleisch, R. A1 - Foryst-Ludwig, A. A1 - Kintscher, U. T1 - Liver X Receptor Agonist AZ876 Induces Beneficial Endogenous Cardiac Lipid Reprogramming and Protects Against Isoproterenol-Induced Cardiac Damage N2 - Background - It is known that dietary intake of polyunsaturated fatty acids may improve cardiac function. However, relatively high daily doses are required to achieve sufficient cardiac concentrations of beneficial omega‐3 fatty acids. The liver X receptor (LXR) is a nuclear hormone receptor and a crucial regulator of lipid homeostasis in mammals. LXR activation has been shown to endogenously reprogram cellular lipid profiles toward increased polyunsaturated fatty acids levels. Here we studied whether LXR lipid reprogramming occurs in cardiac tissue and exerts cardioprotective actions. Methods and Results - Male 129SV mice were treated with the LXR agonist AZ876 (20 µmol/kg per day) for 11 days. From day 6, the mice were injected with the nonselective β‐agonist isoproterenol for 4 consecutive days to induce diastolic dysfunction and subendocardial fibrosis while maintaining systolic function. Treatment with isoproterenol led to a marked impairment of global longitudinal strain and the E/e' ratio of transmitral flow to mitral annular velocity, which were both significantly improved by the LXR agonist. Histological examination showed a significant reduction in isoproterenol‐induced subendocardial fibrosis by AZ876. Analysis of the cardiac lipid composition by liquid chromatography‐high resolution mass spectrometry revealed a significant increase in cardiac polyunsaturated fatty acids levels and a significant reduction in saturated fatty acids by AZ876. Conclusions - The present study provides evidence that the LXR agonist AZ876 prevents subendocardial damage, improves global longitudinal strain and E/e' in a mouse model of isoproterenol‐induced cardiac damage, accompanied by an upregulation of cardiac polyunsaturated fatty acids levels. Cardiac LXR activation and beneficial endogenous cardiac lipid reprogramming may provide a new therapeutic strategy in cardiac disease with diastolic dysfunction. KW - Heart failure KW - Lipids KW - Liver X receptor KW - Diastolic dysfunction KW - Nuclear receptor PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-529352 DO - https://doi.org/10.1161/JAHA.120.019473 VL - 10 IS - 14 SP - e019473 AN - OPUS4-52935 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ebell, Gino A1 - Scheerer, S. A1 - Schacht, G. A1 - Fiedler, M. A1 - Marx, S. A1 - Marzahn, G. A1 - Ritter, R. T1 - Die wechselvolle Geschichte der Carolabrücke in Dresden - Teil 2 N2 - Am 11. September 2024 fand in Dresden ein Ereignis statt, welches man in Deutschland nicht erwartet hatte: der Teileinsturz einer Spannbetonbrücke unter Betrieb ohne Vorankündigung. Die Dresdner Carolabrücke war eine Ikone der Ingenieurbaukunst ihrer Zeit. Sie war ein sehr ästhetisches und schlankes Bauwerk. Ihre Konstruktion und Bau wären auch heute noch eine Herausforderung. Die vorhandenen Unterlagen zeugen von einer hohen Entwurfsqualität und einer sehr sorgsamen Bauausführung. Im Beitrag werden die Entstehungsgeschichte, die Konstruktion selbst und der Bau der Brücke vorgestellt. Es wird der Versuch der Rekonstruktion des Einsturzvorgangs unternommen und die Suche nach der Einsturzursache beschrieben. Am Schluss des Beitrags wird auf das aktuelle Überwachungskonzept eingegangen und ein Ausblick auf das mögliche weitere Vorgehen gegeben. KW - Korrosion KW - Spannstahl KW - Spannungsrisskorrosion KW - Wasserstoff PY - 2025 VL - 2025 IS - 6 SP - 744 EP - 751 PB - Eugen G. Leuze Verlag CY - Bad Saulgau AN - OPUS4-63331 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ebell, Gino A1 - Scheerer, S. A1 - Schacht, G. A1 - Fiedler, M. A1 - Marx, S. A1 - Marzahn, G. A1 - Ritter, R. T1 - Die wechselvolle Geschichte der Carolabrücke in Dresden N2 - Am 11. September 2024 fand in Dresden ein Ereignis statt, welches man in Deutschland nicht erwartet hatte: der Teileinsturz einer Spannbetonbrücke unter Betrieb ohne Vorankündigung. Die Dresdner Carolabrücke war eine Ikone der Ingenieurbaukunst ihrer Zeit. Sie war ein sehr ästhetisches und schlankes Bauwerk. Ihre Konstruktion und Bau wären auch heute noch eine Herausforderung. Die vorhandenen Unterlagen zeugen von einer hohen Entwurfsqualität und einer sehr sorgsamen Bauausführung. Im Beitrag werden die Entstehungsgeschichte, die Konstruktion selbst und der Bau der Brücke vorgestellt. Es wird der Versuch der Rekonstruktion des Einsturzvorgangs unternommen und die Suche nach der Einsturzursache beschrieben. Am Schluss des Beitrags wird auf das aktuelle Überwachungskonzept eingegangen und ein Ausblick auf das mögliche weitere Vorgehen gegeben. KW - Korrosion KW - Spannstahl KW - Spannungsrisskorrosion KW - Wasserstoff PY - 2025 VL - 2025 IS - 5 SP - 569 EP - 578 PB - Eugen G. Leuze Verlag CY - Bad Saulgau AN - OPUS4-63330 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Müller, Anja A1 - Krahl, T. A1 - Radnik, Jörg A1 - Wagner, Andreas A1 - Werner, W. S. M. A1 - Ritter, B. A1 - Kemnitz, E. A1 - Unger, Wolfgang T1 - Chemical in-depth analysis of (Ca/Sr)F2 core–shell like nanoparticles by X-ray photoelectron spectroscopy with tunable excitation energy N2 - The fluorolytic sol–gel synthesis is applied with the intention to obtain two different types of core–shell nanoparticles, namely, SrF2–CaF2 and CaF2–SrF2. In two separate fluorination steps for core and shell formation, the corresponding metal lactates are reacted with anhydrous HF in ethylene glycol. Scanning transmission electron microscopy (STEM) and dynamic light scattering (DLS) confirm the formation of particles with mean dimensions between 6.4 and 11.5 nm. The overall chemical composition of the particles during the different reaction steps is monitored by quantitative Al Kα excitation X-ray photoelectron spectroscopy (XPS). Here, the formation of stoichiometric metal fluorides (MF2) is confirmed, both for the core and the final core–shell particles. Furthermore, an in-depth analysis by synchrotron radiation XPS (SR-XPS) with tunable excitation energy is performed to confirm the core–Shell character of the nanoparticles. Additionally, Ca2p/Sr3d XPS intensity ratio in-Depth profiles are simulated using the software Simulation of Electron Spectra for Surface Analysis (SESSA). In principle, core–shell like particle morphologies are formed but without a sharp interface between calcium and strontium containing phases. Surprisingly, the in-depth chemical distribution of the two types of nanoparticles is equal within the error of the experiment. Both comprise a SrF2-rich core domain and CaF2-rich shell domain with an intermixing zone between them. Consequently, the internal morphology of the final nanoparticles seems to be independent from the synthesis chronology. KW - Metal fluorides KW - Sol-gel synthesis KW - Synchrotron radiation KW - X-ray photoelectron spectroscopy PY - 2021 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-522284 DO - https://doi.org/10.1002/sia.6937 SN - 0142-2421 VL - 53 IS - 5 SP - 494 EP - 508 PB - Wiley VCH AN - OPUS4-52228 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bosch, R.-W. A1 - Cottis, R.A. A1 - Csecs, K. A1 - Dorsch, T. A1 - Dunbar, L. A1 - Heyn, Andreas A1 - Huet, F. A1 - Hyökyvirta, O. A1 - Kerner, Z. A1 - Kobzova, A. A1 - Macak, J. A1 - Novotny, R. A1 - Öijerholm, J. A1 - Piippo, J. A1 - Richner, R. A1 - Ritter, S. A1 - Sánchez-Amaya, J.M. A1 - Somogyi, A. A1 - Väisänen, S. A1 - Zhang, W. T1 - Reliability of electrochemical noise measurements: Results of round-robin testing on electrochemical noise N2 - Sixteen laboratories have performed electrochemical noise (EN) measurements based on two systems. The first uses a series of dummy cells consisting of a 'star' arrangement of resistors in order to validate the EN measurement equipment and determine its baseline noise performance, while the second system, based on a previous round-robin in the literature, examines the corrosion of aluminium in three environments. All participants used the same measurement protocol and the data reporting and analysis were performed with automatic procedures to avoid errors. The measurement instruments used in the various laboratories include commercial general-purpose potentiostats and custom-built EN systems. The measurements on dummy cells have demonstrated that few systems are capable of achieving instrument noise levels comparable to the thermal noise of the resistors, because of its low level. However, it is of greater concern that some of the instruments exhibited significant artefacts in the measured data, mostly because of the absence of anti-aliasing filters in the equipment or because the way it is used. The measurements on the aluminium samples involve a much higher source noise level during pitting corrosion, and most (though not all) instruments were able to make reliable measurements. However, during passivation, the low level of noise could be measured by very few systems. The round-robin testing has clearly shown that improvements are necessary in the choice of EN measurement equipment and settings and in the way to validate EN data measured. The results emphasise the need to validate measurement systems by using dummy cells and the need to check systematically that the noise of the electrochemical cell to be measured is significantly higher than the instrument noise measured with dummy cells of similar impedance. KW - Electrochemical noise KW - Round-robin KW - Corrosion PY - 2014 DO - https://doi.org/10.1016/j.electacta.2013.12.093 SN - 0013-4686 SN - 1873-3859 VL - 120 SP - 379 EP - 389 PB - Elsevier Science CY - Kidlington AN - OPUS4-30284 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -