TY - GEN A1 - Reuther, H. A1 - Menzel, Michael A1 - Vinnichenko, M. A1 - Kolitsch, A. ED - Garcia, M. T1 - Investigation of the Sn4+ Charge Density Variation in In2O3 using Mössbauer Spectroscopy T2 - International Symposium on the Industrial Application of the Mössbauer Effect CY - Madrid, Spain DA - 2004-10-04 PY - 2005 SN - 0-7354-0250-7 SN - 0094-243X N1 - Serientitel: AIP conference proceedings – Series title: AIP conference proceedings IS - 765 SP - 132 EP - 136 PB - American Inst. of Physics CY - Melville AN - OPUS4-12150 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lucka, R. A1 - Elshani, B. A1 - Kilic, M. S. A1 - Klimke, S. A1 - Krüger, C. A1 - Menzel, Michael A1 - Stößer, R. A1 - Titiš, J. A1 - Boča, R. A1 - Renz, F. T1 - ESR and Mössbauer spectroscopy of iron(III) spin crossover complexes based on pentadentate Schiff base ligands with pseudohalide coligands N2 - Two iron(III) spin crossover complexes [Fe(5Cl-L)(NCS)] (1) and [Fe(5Cl-L)(NCSe)] (2) were synthesized with the pentadentate Schiff base ligand 5Cl-L and thiocyanato and selenocyanato as coligands. 5Cl-L, as an asymmetric {N3O2} donor Schiff base, was synthesized by a condensation reaction of 5-chlorosalicyladehyde using the asymmetric N-(2-aminoethyl)-1,3-propanediamine. The complexes exhibited a spin crossover at 280 (1) and 293 K (2), respectively, and were subjected to electron spin resonance (ESR) and Mössbauer spectroscopy at 77, 295 and 325 K. Ab initio CASSCF calculations followed by the NEVPT2 method were applied for predicting the g-tensor components as well as Mössbauer parameters. KW - Spin crossover KW - Iron(III) complexes KW - Mössbauer spectroscopy KW - ESR spectroscopy KW - Ab initio calculations PY - 2025 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-634061 DO - https://doi.org/10.3390/magnetochemistry11050043 SN - 2312-7481 VL - 11 IS - 5 SP - 1 EP - 9 PB - MDPI CY - Basel AN - OPUS4-63406 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Renz, F. A1 - Jung, S. A1 - Klein, M. A1 - Menzel, Michael A1 - Thünemann, Andreas T1 - Molecular switching complexes with iron and tin as central atom N2 - The precursor [FeIII(L)Cl] (LH