TY - JOUR A1 - Marin, L. A1 - Döhler, Michael A1 - Bernal, D. A1 - Mevel, L. T1 - Robust statistical damage localization with stochastic load vectors N2 - The stochastic dynamic damage locating vector approach is a vibration-based damage localization method based on a finite element model of a structure and output-only measurements in both reference and damaged states. A stress field is computed for loads in the null space of a surrogate of the change in the transfer matrix at the sensor positions for some values in the Laplace domain. Then, the damage location is related to positions where the stress is close to zero. Robustness of the localization information can be achieved by aggregating results at different values in the Laplace domain. So far, this approach, and in particular the aggregation, is deterministic and does not take the uncertainty in the stress estimates into account. In this paper, the damage localization method is extended with a statistical framework. The uncertainty in the output-only measurements is propagated to the stress estimates at different values of the Laplace variable, and these estimates are aggregated based on statistical principles. The performance of the new statistical approach is demonstrated both in a numerical application and a lab experiment, showing a significant improvement of the robustness of the method due to the statistical evaluation of the localization information. KW - Damage localization KW - Load vectors KW - Ambient vibration KW - Covariance analysis KW - Subspace methods PY - 2015 UR - http://onlinelibrary.wiley.com/doi/10.1002/stc.1686/full DO - https://doi.org/10.1002/stc.1686 SN - 1545-2255 SN - 1545-2263 VL - 22 IS - 3 SP - 557 EP - 573 PB - Wiley CY - Chichester AN - OPUS4-28069 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Marin, L. A1 - Döhler, Michael A1 - Bernal, D. A1 - Mevel, L. ED - Chang, F.-K. T1 - Statistical based decision making for damage localization with influence lines N2 - A theorem on damage localization from flexibility changes has been proven recently, where it has been shown that the image of the change in flexibility δF between damaged and reference states of a structure is a basis for the influence lines of stress resultants at the damaged locations. This damage localization approach can operate on output-only vibration measurements from damaged and reference states, and a finite element model of the structure in reference state is required. While the localization approach is based on purely mechanical principles, an estimate of the image of δF is required from the data that is subject to statistical uncertainty due to unknown noise excitation and finite data length. In this paper, this uncertainty is quantified from the measurements and a statistical framework is added for the decision about damaged elements. The combined approach is successfully applied to a numerical simulation and to a cantilever beam in a lab experiment. T2 - IWSHM 2013 - 9th International workshop on structural health monitoring CY - Stanford, CA, USA DA - 2013-09-10 PY - 2013 SN - 978-1-60595-115-7 VL - 1 SP - 159 EP - 166 AN - OPUS4-30476 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mohammad, W. A1 - Wegner, Karl David A1 - Comby-Zerbino, C. A1 - Trouillet, V. A1 - Ogayer, M. P. A1 - Coll, J.-L. A1 - Marin, R. A1 - Jaque Garcia, D. A1 - Resch-Genger, Ute A1 - Antoine, R. A1 - Le Guevel, X. T1 - Enhanced brightness of ultra-small gold nanoparticles in the second biological window through thiol ligand shell control N2 - Gold-based nanoparticles below 2 nm in size are promising as luminescent probes for in vivo bioimaging, owing to their brightness and rapid renal clearance. However, their use as contrast agents in the near-infrared II (NIR-II, 1000–1700 nm) range remains challenging due to their low photoluminescence (PL) quantum yield. To address this, PL enhancement can be achieved by either rigidifying the ligand-shell structure or increasing the size of the ligand shell. In this study, we synthesized ultra-small gold nanoparticles stabilized by co-ligands, namely monothiol and short dithiol molecules. By precisely controlling the amount of reducing agent used during particle preparation, we successfully modulated the physicochemical properties of the co-ligand shell, including its size, composition, and structure. Consequently, we achieved a remarkable 60-fold increase in the absorption cross-section at 990 nm while maintaining the small size of the 1.5-nm metal core. The analytical and optical characterization of our thiol-capped gold nanoparticles indicates that the ligand shell size is governed by the quantity of the reducing agent, which, in turn, impacts the balance between radiative and non-radiative processes, thereby influencing the PL quantum yield. KW - Gold nanocluster KW - NIR-II fluorescence KW - SWIR KW - Nanomaterial design KW - Calibrated fluorescence measurements PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-588117 DO - https://doi.org/10.1039/D3TC03021K SN - 2050-7526 VL - 11 IS - 42 SP - 14714 EP - 14724 PB - Royal Society of Chemistry (RSC) AN - OPUS4-58811 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -