TY - CONF A1 - Wan, Wei A1 - Biyikal, Mustafa A1 - Wagner, R. A1 - Sellergren, B. A1 - Rurack, Knut T1 - Enantioselective fluorescence response of molecularly imprinted polymers (MIPs) toward carbobenzyloxy- (Cbz) protected amino acids N2 - Integration of a polymerisable fluorescent urea-nitrobenzoxadiazole monomer 1 into a few-nanometre thin molecularly imprinted polymer (MIP) shell coated onto a 300 nm silica core with the tetrabutylammonium salt of N-carbobenzyloxy-L-phenylalanine (Cbz- or Z-ʟ-Phe) as the imprinted template yields core/shell MIP nanoparticles that respond to the designated analyte with a strong fluorescence increase in the visible spectral range. The system shows promising imprinting and enantioselectivity factors of 3.6 and 1.9 when benzylmethylacrylate (BMA) is used as co-monomer and ethylene glycol dimethacrylate (EDMA) as cross-linker. A second, naphthalimide-based fluorescent urea 2 is employed in the preparation of MIP thin-films and monolithic polymers for separation techniques. Spectroscopic and chromatographic studies of the MIPs with the analytes Z-ʟ-Phe, Z-ʟ-glutamic acid (Z-ʟ-Glu) and penicilin G (PenG) revealed the (enantio)selective discrimination behaviour of these materials. T2 - 11. Dresdner Sensor Symposium 2013 CY - Dresden, Germany DA - 09.12.2013 KW - Enantioselectivity KW - Molecular imprinting KW - Fluorescence KW - Core-shell nanoparticles KW - Chromatography PY - 2013 SN - 978-3-9813484-5-3 DO - https://doi.org/10.5162/11dss2013/3.2 SP - 53 EP - 58 CY - Wunstorf AN - OPUS4-29818 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rurack, Knut T1 - Towards simple and efficient molecular reporters by combining electron and/or charge transfer processes in fluorescent bifunctional dyes T2 - 57th Southwest Regional Meeting CY - San Antonio, TX, USA DA - 2001-10-17 KW - Donor-Acceptor-Systems KW - Heterocycles KW - Electron Transfer KW - Fluorescence KW - Chelates PY - 2001 VL - 57 SP - 1(?) EP - 2(?) AN - OPUS4-1183 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Resch-Genger, Ute A1 - Rurack, Knut A1 - Bricks, J. A1 - Koval'chuk, A. A1 - Slominskii, J. T1 - Synthesis and Photophysical Properties of Cation-sensitive styryl bases derived from substituted Benzothiazole T2 - 1st All-Russian Conference on Heterocyclic Chemistry CY - Suzdal, Russia DA - 2000-09-19 PY - 2000 SP - 1 AN - OPUS4-858 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Biyikal, Mustafa A1 - Rurack, Knut T1 - Development of a Lab-on-a-Chip for the Detection of Nerve Agents with a Handheld Device N2 - The development of a Lab-on-a-Chip (LoC) is presented, which can detect reactive phosphorous compounds in the gas phase in combination with an optochemical hand-held sensor. The LoC prototype contains three pairs of sensing materials containing fluorescent indicator dyes in various carrier materials. By measuring the fluorescence response to phosphoryl chloride, a surrogate compound, the detection of chemical warfare agents (CWAs) in gas phase becomes possible within seconds, introducing a novel approach to CWA detection. T2 - 2023 IEEE SENSORS Conference CY - Vienna, Austria DA - 29.10.2023 KW - Lab-on-a-Chip KW - Nerve agents KW - Hand-held KW - Fluorescence KW - Toxic industrial chemicals PY - 2023 UR - https://ieeexplore.ieee.org/document/10325263 SN - 979-8-3503-0387-2 DO - https://doi.org/10.1109/SENSORS56945.2023.10325263 SP - 1 EP - 4 PB - IEEE CY - New York AN - OPUS4-59367 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Unger, Brita A1 - Rurack, Knut A1 - Müller, Ralf A1 - Jancke, Harald T1 - Untersuchungen zur Alterung von Kieselsolen und -gelen T2 - 11. Arbeitstagung des AK Nichtkristalline und Partiellkristalline Strukturen CY - Wolfersdorf, Deutschland DA - 2003-09-08 PY - 2003 UR - http://www2.uni-jena.de/chemie/DGK-AK4/VOR_03/Unger.pdf SP - 1(?) EP - 10(?) AN - OPUS4-3119 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rurack, Knut A1 - Al-Soufi, W. ED - Braslavsky, S. T1 - pH-Dependent Photophysics of 2,2'-Bipyridiyl-3-OL T2 - Workshop on Theoretical Organic (Photo) Chemistry ; 18th IUPAC Symposium on Photochemistry CY - Dresden, Germany DA - 2000-07-22 KW - pH KW - Photophysik KW - Bipyridyl OL PY - 2001 SN - 1010-6030 VL - 144 IS - 2-3 SP - 1 PB - Elsevier CY - Amsterdam AN - OPUS4-859 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rurack, Knut A1 - Unger, Brita A1 - Müller, Ralf A1 - Resch-Genger, Ute T1 - SiO2-Gele als Matrices für Fluoreszenzmarker T2 - 75. Glastechnische Tagung CY - Wernigerode, Deutschland DA - 2001-05-21 PY - 2001 SP - 8 EP - 11 PB - DGG, Deutsche Glastechnische Gesellschaft e.V. CY - Frankfurt/M. AN - OPUS4-2084 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wander, Lukas A1 - Paul, Andrea A1 - Rurack, Knut A1 - Biyikal, Mustafa A1 - Juritsch, Elevtheria A1 - Bernstein, Thomas A1 - Bartholmai, Matthias A1 - Noske, Reinhard T1 - Kompaktsensor zur Online-Überwachung von Nitroaromaten N2 - Nitroaromaten und insbesondere Trinitrotoluol (TNT) sind weit verbreitete Spreng- und Umweltschadstoffe. Die größte Herausforderung bei der Detektion von TNT in der Gasphase ist der geringe Dampfdruck. Derzeit werden vielerorts günstige, schnelle, handliche und einfach zu bedienende Alternativen zur klassischen TNT-Analytik entwickelt. Aktuell existieren keine einheitlichen Richtlinien für Sprengstoffsensoren. Hier wird die Entwicklung eines Messplatzes zur Validierung von Sprengstoffsensoren sowie die Erprobung eines kompakten Mustersensors vorgestellt. T2 - 12. Kolloquium Prozessanalytik CY - Berlin, Germany DA - 28.11.2016 KW - Nitroaromaten KW - Fluoreszenzlöschung KW - Sensor PY - 2016 SP - P11, 61 EP - 62 AN - OPUS4-38402 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rurack, Knut A1 - Unger, Brita A1 - Müller, Ralf A1 - Jancke, Harald A1 - Resch-Genger, Ute T1 - Die Strukturentwicklung von SiO2 Solen und Gelen im Vergleich mikroskopischer und makroskopischer Untersuchungsmethoden T2 - 77. Glastechnische Tagung CY - Leipzig, Deutschland DA - 2003-05-26 PY - 2003 VL - 77 SP - 101 EP - 104 PB - DGG CY - Offenbach AN - OPUS4-3121 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rurack, Knut A1 - Resch-Genger, Ute A1 - Rettig, W. T1 - Fluoreszenzmarker für Schwer- und Übergangsmetallionen - Selektivität durch gezieltes Rezeptordesign und ionenspezifische Fluoreszenzverstärkung T2 - Tagung "Tag der Chemie 2000" CY - Potsdam, Deutschland DA - 2000-11-08 KW - Fluoreszenzmarker KW - Schwermetalle KW - Rezeptoren PY - 2000 SP - 87 AN - OPUS4-1016 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gawlitza, Kornelia A1 - Tiebe, Carlo A1 - Banach, Ulrich A1 - Noske, Reinhard A1 - Bartholmai, Matthias A1 - Rurack, Knut T1 - Novel sensor for long-term monitoring of ammonia in gas phase N2 - Because ammonia and its reaction products can cause considerable damage to human health and ecosystems, there is a need for reliably operating and reversibly interacting sensor materials to monitor traces of gaseous ammonia in ambient air, which at best can be used on-site for in-the-field measurements. Herein, the development of a sensor material for gaseous ammonia in the lower ppm to ppb range using optical fluorescence as transduction mechanism is presented. A fluorescent dye, which shows reversible fluorescence enhancement in the presence of ammonia is incorporated into a polymer matrix, the latter to ensure the accumulation of ammonia. The sensor material is integrated into a prototype of a miniaturized sensor device, facilitating long-term operation. To calibrate the optical sensor system a gas standard generator, producing standard gas mixtures, is used, leading to a sensitivity down to lower ppm concentrations of ammonia. T2 - 13. Dresdner Sensor-Symposium 2017 CY - Dresden, Germany DA - 04.12.2017 KW - Ammonia gas sensor KW - Fluorescence KW - Air quality monitoring KW - Standard gas generator KW - Miniaturized sensor device PY - 2017 DO - https://doi.org/10.5162/13dss2017/P4.02 SP - P4.02, 272 EP - 276 AN - OPUS4-43352 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gawlitza, Kornelia A1 - Johann, Sergej A1 - Mansurova, Maria A1 - Kohlhoff, Harald A1 - Tiebe, Carlo A1 - Bell, Jérémy A1 - Bartholmai, Matthias A1 - Rurack, Knut T1 - Semi-automatic Measurement Device for Long-Term Monitoring of Ammonia in Gas Phase N2 - In the present paper the development of a semi-automated device for long-term monitoring of gaseous ammonia is described. A sensor material was produced that changes its optical properties in the pres-ence of low concentrations of ammonia in air. The implementation into an electronic device enables precise, simple, economic and fast monitoring of low concentrations of harmful gases, like ammonia, and hence can help to improve the climate monitoring in livestock housing, barns or stables. T2 - SMSI 2021 CY - Online meeting DA - 03.05.2021 KW - Spectroscopy KW - Embedded sensor KW - Environment KW - Air quality PY - 2021 SP - 133 EP - 134 AN - OPUS4-52576 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gawlitza, Kornelia A1 - Johann, Sergej A1 - Mansurova, M. A1 - Kohlhoff, Harald A1 - Tiebe, Carlo A1 - Bell, Jérémy A1 - Bartholmai, Matthias A1 - Rurack, Knut T1 - Semi-automatic Measurement Device for Long-Term Monitoring of Ammonia in Gas Phase N2 - The present paper describes the development of a sensor material that changes its fluorescence in the presence of gaseous ammonia in a relevant concentration range. The implementation into a semi-automatic gas measurement device enables low-cost, precise, simple and fast monitoring of low con-centrations of harmful gases, like ammonia, and hence can help to improve the climate monitoring in livestock housing, barns or stables. T2 - SMSI 2020 CY - Meeting was canceled KW - Spectroscopy KW - Emmbedded sensor KW - Environment KW - Air quality PY - 2020 DO - https://doi.org/10.5162/SMSI2020/B5.4 SP - 133 EP - 134 AN - OPUS4-50867 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -