TY - CONF A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter A1 - Schönbucher, A. T1 - Radiative characteristics of large pool fires of organic peroxides T2 - 4th European Combustion Meeting (Proceedings) CY - Vienna, Austria DA - 2009-04-14 KW - Pool fire KW - TBPB KW - TBPEH KW - CFD KW - Temperature KW - Surface emissive power KW - Irradiance PY - 2009 SN - 978-3-902655-06-6 SP - 1 EP - 6(?) PB - ProcessEng Engineering GmbH CY - Vienna AN - OPUS4-19400 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Pool Fires of Organic Peroxides: Experimental and CFD Study T2 - IGUS Energetic and Oxidising Substances (EOS) Working Group Meeting CY - Saint Petersburg, Russia DA - 2009-06-10 PY - 2009 AN - OPUS4-19503 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Turbulent Combustion in Pool Fires of Organic Peroxides T2 - von Karman Institute for Fluid Dynamics, Lecture Series on "Turbulent Combustion" CY - Sint-Genesius-Rode, Belgium DA - 2009-05-25 PY - 2009 AN - OPUS4-19505 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Impact of fuel properties on the large pool fire (hydrocarbons and organic peroxides) characteristics T2 - 6th U. S. National Combustion meeting CY - Ann Arbor, MI, USA DA - 2009-05-17 PY - 2009 AN - OPUS4-19475 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter A1 - Schönbucher, A. T1 - Numerical prediction of safety distances from large pool fires of organic peroxides N2 - Organic peroxides are energetic substances liable to decompose due to exothermic reactions when exposed to uncontrolled temperature, contamination, confinement and quantity. Their safe storage and transportation are the prime concern and chemical industries and regulating authorities. Their accidental release may and most often lead to shape of a pool. In present study, safety distances from such large pool fires (diameter d = 3.4 m) of organic peroxides are numerically predicted by solving the reactive, 3-D time dependent Navier-Stokes equations with reliable assumptions. The present model is validated against the data on buoyant turbulent diffusion flames. The safety distances predicted by simulation assume three regions in a fully developed fire i.e. hot spot, luminous zone and a flame surface. The time averaged data of temperatures of these regions lead to better estimation of irradiances against the measured data. A developed sphere analogy method (for a special class of organic peroxides) for maximum surface emissive power prediction is also verified. T2 - 40th International annual conference of ICT - Energetic Materials - Characterisation, Modelling and Validation CY - Karlsruhe, Germany DA - 2009-06-23 KW - Organic peroxides KW - Safety distances KW - Navier-stokes equations KW - Irradiance KW - Surface emissive power PY - 2009 SN - 0722-4087 SP - 88-1 - 88-14 PB - DWS Werbeagentur und Verlag GmbH CY - Pfinztal (Berghausen) AN - OPUS4-19599 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Numerical prediction of safety distances from large pool fires of organic peroxides T2 - 40th Annual Conference of ICT, Energetic Materials - Characterisation, Modelling and Validation CY - Karlsruhe, Germany DA - 2009-06-23 PY - 2009 AN - OPUS4-19578 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Vela, I. A1 - Chun, Hyunjoo A1 - Mishra, Kirti Bhushan A1 - Gawlowski, M. A1 - Sudhoff, P. A1 - Rudolph, Michael A1 - Wehrstedt, Klaus-Dieter A1 - Schönbucher, A. T1 - Vorhersage der thermischen Strahlung großer Kohlenwasserstoff- und Peroxid-Poolfeuer mit CFD Simulation KW - CFD Simulation KW - Poolfeuer KW - JP-4 KW - Kerosin KW - Di-tert-butylperoxid KW - Thermische Strahlung PY - 2009 DO - https://doi.org/10.1007/s10010-009-0094-3 SN - 0015-7899 SN - 1434-0860 VL - 73 IS - 2 SP - 87 EP - 97 PB - Springer CY - Berlin AN - OPUS4-19531 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Prediction of burning rate of an accidentally released flammable fuel by means of CFD simulation T2 - Seventh International Conference on CFD in the Minerals and Process Industries CSIRO CY - Melbourne, Australia DA - 2009-12-09 PY - 2009 AN - OPUS4-20635 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Measurement and CFD Prediction of Gas Velocities and Temperatures in Large Pool Fires of Organic Peroxides T2 - 36th National Conference on Fluid Mechanics and Fluid Power (NCFMP-2009) CY - Pune, India DA - 2009-12-17 PY - 2009 AN - OPUS4-20749 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter A1 - Schönbucher, A. ED - Witt, P. J. ED - Schwarz, M.P. T1 - Prediction of burning rate of an accidentally released flammable fuel by means of CFD simulation T2 - 7th International Conference on CFD in the minerals and process industries CY - Melbourne, Australia DA - 2009-12-09 KW - Mass burning rate KW - CFD simulation KW - TBPB KW - TBPEH KW - Turbulent fire KW - Fuel Froude number PY - 2009 SN - 978-0-643-09825-1 SP - 1 EP - 7 AN - OPUS4-20768 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter A1 - Schönbucher, A. T1 - Measurement and CFD prediction of gas velocities and temperatures in large pool fires of organic peroxides T2 - 36th National conference on fluid mechanics and fluid power - NCFMFP-2009 CY - Pune, India DA - 2009-12-17 KW - Pool fire KW - TBPB KW - TBPEH KW - Froude number KW - CFD (Computational fluid dynamics) PY - 2009 IS - Paper 58-CFD-5 SP - 1 EP - 11 AN - OPUS4-20769 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Safety aspects of organic peroxide pool fires T2 - CUMBURA 2010 (Combustion Research and Application) CY - Maastricht, Netherlands DA - 2010-10-12 PY - 2010 AN - OPUS4-22093 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - What do we reliably know about pool fire? T2 - Zweites gemeinsames wissenschaftliches Kolloquium der Uni Duisburg-Essen, Institut für technische Chemie I, und der BAM, Abteilung II "Chemische Sicherheitstechnik" CY - Essen, Germany DA - 2007-04-19 PY - 2007 AN - OPUS4-14777 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Interpretations of temperature measurements in organic peroxide pool fires T2 - 5th European Combustion Meeting ECM 2011, Cardiff University CY - Cardiff, Wales DA - 2011-06-29 PY - 2011 AN - OPUS4-24099 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - An efficient and clean fuel for high temperature process industries T2 - 11th International Conference on Energy for a Clean Environment CY - Lisbon, Portugal DA - 2011-07-05 PY - 2011 AN - OPUS4-24101 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter T1 - Burner for peroxy-fuels (PEROXY-BAM Burner) N2 - A new burner concept (PEROXY-BAM®) for the combustion of liquid organic peroxides (Peroxy-fuels) is presented. As peroxy-fuels are thermally unstable the design of burners for them should be accordingly modified ensuring a safe operation. It is found that 10 to 100 time less amounts of peroxy fuels are required for the same heat flux or output in comparison to hydrocarbons. Correspondingly, the fuel pump power and the volume of combustion chamber (furnace) are also reduced. As a result of less amount of fuel the emissions will also be stepped down and oxygen in the molecule helps to establish conditons like in an oxy-fuel combustion process. The advantages of using peroxy-fuels over hydrocarbons inside a model combustion chamber are also investigated with the help of CFD (Computational Fluid Dynamics) simulations. T2 - 25. Deutscher Flammentag - Verbrennung und Feuerung CY - Karlsruhe, Germany DA - 14.09.2011 KW - Organic peroxide KW - Peroxy-fuel KW - Burner concept KW - Combustion KW - Combustion chamber PY - 2011 SN - 978-3-18-092119-8 SN - 0083-5560 N1 - Serientitel: VDI-Berichte – Series title: VDI-Berichte VL - 2119 SP - 307 EP - 312 PB - VDI-Verl. AN - OPUS4-24388 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter A1 - Schönbucher, A. T1 - Interpretations of temperature measurements in organic peroxide pool fires N2 - Most of the measurements of temperatures in large pool fires are indirect and present a number of complexities due to the interactions of convection, radiation and soot blockage. In the present work these influences for two organic peroxide [tert-butyl peroxybenzoate (TBPB) and tert-butyl peroxy-2-ethylhexanoate (TBPEH)] pool fires are analysed. Thermocouple measured temperature in the clear flame zone i.e. combustion zone are found to be 250-400 K lower than from the thermographic measurements. The convective and radiative heat flux contributions from the fire on temperature measurements are discussed. CFD (Computational Fluid Dynamics) simulations have been performed for large pool fires and the predicted time averaged flame temperatures were found to be in qualitative agreement with measurements due to the stoichiometric combustion model used in the present simulations. T2 - 5th European combustion meeting 2011 CY - Cardiff, UK DA - 28.06.2011 KW - Pool fire KW - Organic peroxides KW - TBPB KW - TBPEH KW - CFD KW - Temperature measurement PY - 2011 UR - http://www.uni-due.de/tchem/as/skripte/paper_mishra_et_al_cardiff_2011.pdf SP - 1 EP - 5 AN - OPUS4-24686 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter T1 - An efficient and clean fuel for high temperature process industries N2 - The use of energetic materials as a main fuel in high temperature process industries are not known to the scientific community as such. This paper highlights some of the features and advantages of using organic peroxides especially di-tert-butyl peroxide (DTBP) in high temperature process industries. The feasibility of using DTBP as a main or supporting fuel in process industries have also been justified with the help of Computational Fluid Dynamics (CFD) simulations. For peroxides requirement of less fuel and air for the same amount of heat flux has been shown. The resulted emission from the combustion of DTBP is also discussed. T2 - 11th Conference on Energy for a Clean Environment CY - Lisbon, Portugal DA - 2011-07-05 KW - Energetic materials KW - Process industries KW - Organic peroxide KW - Di-tert-butylperoxide (DTBP) KW - CFD simulation KW - Emission PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-247071 SP - 1 EP - 10 AN - OPUS4-24707 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan A1 - Wehrstedt, Klaus-Dieter T1 - Combustion of peroxy-fuels N2 - The diffusion flames of organic peroxides exhibit quite different characteristics than hydrocarbons. What makes them interesting to study is their fast burning behaviour. As a result the flame temperature enhances and so does the thermal radiation. Due to all these they demand safe handling during processing. However, they can be utilised at several places in different industries where a fuel with fast burning, high temperature and intense radiation are desired. Some of the possibilities to use them as a main or supporting fuel in a wide range of industrial utilities are the major content of this paper. T2 - ERCOFTAC conference - Highly resolved experimental and numerical diagnostics for turbulent combustion CY - Rouen, France DA - 25.05.2011 KW - Energetic materials KW - Process industries KW - Organic peroxide KW - Di-tert-butyl peroxide (DTBP) KW - CFD simulation KW - Emission PY - 2011 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-247083 SP - 1 EP - 5 AN - OPUS4-24708 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mishra, Kirti Bhushan T1 - Burner for peroxy fuels (Peroxy-BAM® Burner) T2 - 25. Deutscher Flammentag - Verbrennung und Feuerung CY - Karlsruhe, Germany DA - 2011-09-14 PY - 2011 AN - OPUS4-24329 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -