TY - JOUR A1 - Martin-Sanchez, Pedro Maria A1 - Miller, A. Z. A1 - Garcia-Sanchez, A. M. A1 - Martin-Sanchez, Pedro Maria A1 - F.C. Pereira, M. A1 - Afonso, M. J. A1 - Saiz-Jimenez, C. A1 - Spangenberg, J. E. A1 - Jurado, V. A1 - Dionísio, A. A1 - Chaminé, H. I. A1 - Hermosin, B. T1 - Origin of abundant moonmilk deposits in a subsurface granitic environment JF - Sedimentology N2 - Subsurface granitic environments are scarce and poorly investigated. A multi-disciplinary approach was used to characterize the abundant moonmilk deposits and associated microbial communities coating the granite walls of the 16th Century Paranhos spring water tunnel in Porto city (north-west Portugal). It is possible that this study is the first record of moonmilk in an urban subsurface granitic environment. The morphology and texture, mineralogical composition, stable isotope composition and microbial diversity of moonmilk deposits have been studied to infer the processes of moonmilk formation. These whitish secondary mineral deposits are composed of very fine needle fibre calcite crystals with different morphologies and density. Calcified filaments of fungal hyphae or bacteria were distinguished by field emission scanning electron microscopy. Stable isotope analysis revealed a meteoric origin of the needle fibre calcite, with an important contribution of atmospheric CO2, soil respiration and HCO3 − from weathering of Ca-bearing minerals. The DNA-based analyses revealed the presence of micro-organisms related to urban contamination, including Actinobacteria, mainly represented by Pseudonocardia hispaniensis, Thaumarchaeota and Ascomycota, dominated by Cladosporium. This microbial composition is consistent with groundwater pollution and contamination sources of the overlying urban area, including garages, petrol stations and wastewater pipeline leakage, showing that the Paranhos tunnel is greatly perturbed by anthropogenic activities. Whether the identified micro-organisms are involved in the formation of the needle fibre calcite or not is difficult to demonstrate, but this study evidenced both abiotic and biogenic genesis for the calcite moonmilk in this subsurface granitic environment. KW - Biomineralization KW - Carbonate precipitation KW - Granite KW - Moonmilk KW - Needle fibre calcite PY - 2017 UR - https://onlinelibrary.wiley.com/doi/full/10.1111/sed.12431 DO - https://doi.org/10.1111/sed.12431 SN - 1365-3091 VL - 65 IS - 2 SP - 1482 EP - 1503 PB - Wiley AN - OPUS4-43622 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Segovia, J. J. A1 - Tuma, Dirk A1 - Lozano-Martín, D. A1 - Moreau, A. A1 - Martín, M. C. A1 - Vega-Maza, D. T1 - Speed of sound data and acoustic virial coefficients of two binary (N2 + H2) mixtures at temperatures between (260 and 350) K and at pressures between (0.5 and 20) MPa JF - Journal of Chemical Thermodynamics N2 - This work aims to address the technical concerns related to the thermodynamic characterization of gas mixtures blended with hydrogen for the implementation of hydrogen as a new energy vector. For this purpose, new experimental speed of sound measurements have been done in gaseous and supercritical phases of two binary mixtures of nitrogen and hydrogen using the most accurate technique available, i.e., the spherical acoustic resonator, yielding an experimental expanded (k = 2) uncertainty of only 220 parts in 106 (0.022%). The measurements cover the pressure range between (0.5 and 20) MPa, the temperature range between (260 and 350) K, and the composition range with a nominal mole percentage of hydrogen of (5 and 10) mol%, respectively. From the speed of sound data sets, thermophysical properties that are relevant for the characterization of the mixture, namely the second βa and third γa acoustic virial coefficients, are derived. These results are thoroughly compared and discussed with the established reference mixture models valid for mixtures of nitrogen and hydrogen, such as the AGA8-DC92 EoS, the GERG-2008 EoS, and the recently developed adaptation of the GERG-2008 EoS, here denoted GERG-H2_improved EoS. Special attention has been given to the effect of hydrogen concentration on those properties, showing that only the GERG-H2_improved EoS is consistent with the data sets within the experimental uncertainty in most measuring conditions. KW - Speed of sound KW - Acoustic resonance KW - Binary gas mixture PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-551482 DO - https://doi.org/10.1016/j.jct.2022.106791 SN - 0021-9614 VL - 171 SP - 1 EP - 13 PB - Elsevier B. V. CY - Amsterdam AN - OPUS4-55148 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tuma, Dirk A1 - Lozano-Martín, D. A1 - Vega-Maza, D. A1 - Moreau, A. A1 - Martín, M. C. A1 - Segovia, J. J. T1 - Speed of sound data, derived perfect-gas heat capacities, and acoustic virial coefficients of a calibration standard natural gas mixture and a low-calorific H2-enriched mixture JF - Journal of Chemical Thermodynamics N2 - This work aims to address the technical aspects related to the thermodynamic characterization of natural gas mixtures blended with hydrogen for the introduction of alternative energy sources within the Power-to-Gas framework. For that purpose, new experimental speed of sound data are presented in the pressure range between (0.1 up to 13) MPa and at temperatures of (260, 273.16, 300, 325, and 350) K for two mixtures qualified as primary calibration standards: a 11 component synthetic natural gas mixture (11 M), and another low-calorific H2-enriched natural gas mixture with a nominal molar percentage x(H2) = 3 %. Measurements have been gathered using a spherical acoustic resonator with an experimental expanded (k = 2) uncertainty better than 200 parts in 106 (0.02 %) in the speed of sound. The heat capacity ratio as perfect-gas gammapg, the molar heat capacity as perfect-gas Cp,m pg, and the second betaa and third gammaa acoustic virial coefficients are derived from the speed of sound values. All the results are compared with the reference mixture models for natural gas-like mixtures, the AGA8-DC92 EoS and the GERG-2008 EoS, with Special attention to the impact of hydrogen on those properties. Data are found to be mostly consistent within the model uncertainty in the 11 M synthetic mixture as expected, but for the hydrogen-enriched mixture in the limit of the model uncertainty at the highest measuring pressures. KW - Natural gas mixtures KW - Speed-of-sound measurements KW - Equations of state KW - Acoustic virial coefficients PY - 2021 DO - https://doi.org/10.1016/j.jct.2021.106434 SN - 0021-9614 VL - 158 SP - 106434 PB - Elsevier Ltd. CY - Amsterdam AN - OPUS4-52292 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lozano-Martín, D. A1 - Martín, M. C. A1 - Chamorro, C. R. A1 - Tuma, Dirk A1 - Segovia, J. J. T1 - Speed of sound for three binary (CH4 + H2) mixtures from p = (0.5 up to 20) MPa at T = (273.16 to 375) K JF - International Journal of Hydrogen Energy N2 - Speed of sound is one of the thermodynamic properties that can be measured with least uncertainty and is of great interest in developing equations of state. Moreover, accurate models are needed by the H2 industry to design the transport and storage stages of hydrogen blends in the natural gas network. This research aims to provide accurate data for (CH4 + H2) mixtures of nominal (5, 10, and 50) mol-% of hydrogen, in the p = (0.5 up to 20) MPa pressure range and with temperatures T = (273.16, 300, 325, 350, and 375) K. Using an acoustic spherical resonator, speed of sound was determined with an overall relative expanded (k = 2) uncertainty of 220 parts in 10^6 (0.022%). Data were compared to reference equations of state for natural gas-like mixtures, such as AGA8-DC92 and GERG-2008. Average absolute deviations below 0.095% and percentage deviations between 0.029% and up to 0.30%, respectively, were obtained. Additionally, results were fitted to the acoustic virial equation of state and adiabatic coefficients, molar isochoric heat capacities and molar isobaric heat capacities as perfect-gas, together with second and third acoustic virial coefficients were estimated. Density second virial coefficients were also obtained. KW - Speed of sound KW - Acoustic resonator KW - Heat capacity PY - 2020 DO - https://doi.org/10.1016/j.ijhydene.2019.12.012 SN - 0360-3199 VL - 45 IS - 7 SP - 4765 EP - 4783 PB - Elsevier Ltd. CY - Amsterdam AN - OPUS4-50454 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - López de Ipina, J.-M. A1 - Arevalillo, A. A1 - Martín, A. A1 - Caillard, B. A1 - Marcoulaki, E. A1 - Aguerre- Charol, O. A1 - van Duuren-Stuurman, B. A1 - Hodoroaba, Vasile-Dan A1 - Viitanen, A.-K. A1 - Witters, H. A1 - Vercauteren, S. A1 - Persson, K. A1 - Bard, D. A1 - Evans, G. A1 - Jensen, K.A. A1 - Himly, M. A1 - Scalbi, S. A1 - Papin, A. A1 - Le Bihan, O. A1 - Kanerva, T. A1 - Tirez, K. A1 - Frijns, E. A1 - Niga, P. A1 - Eleftheriadis, K. A1 - Travlos, A. A1 - Geppert, M. A1 - Himly, M. A1 - Radnik, Jörg A1 - Kuchenbecker, Petra A1 - Resch-Genger, Ute A1 - Fraboulet, I. A1 - Bressot, C. A1 - Rissler, J. A1 - Gaucher, R. A1 - Binotto, G. A1 - Krietsch, Arne A1 - Braun, A. A1 - Abenet, S. A1 - Catalan, J. A1 - Verstraelen, S. A1 - Manier, N. A1 - Manzo, S. A1 - Fransman, S. A1 - Queron, J. A1 - Charpentier, D. A1 - Taxell, D. A1 - Säämänen, A. A1 - Brignon, J.-M. A1 - Jovanovic, A. A1 - Bisson, M A1 - Neofytou, P. T1 - EC4Safenano - Catalogue of Services N2 - The publicly available document encapsulates the first version of the Catalogue of Services of the future EC4Safenano Centre (CoS 2019). The CoS 2019 is structured in 12 Service Categories and 27 Service Topics, for each of the 12 categories considered. This architecture configures a 12 x 27 matrix that allows ordering the potential EC4Safenano offer in 324 types of services/groups of services. Each type of service/group of services is described, in a simple and friendly way, by means of a specific service sheet: the EC4Safenano - Service Data Sheet (EC4-SDS). These EC4-SDSs allow structuring and summarizing the information of each service, providing the customer with a concise view of characteristics of the service and also the contact details with the service provider. The CoS 2019 deploys a map of services consisting of a set of 100 EC4-SDSs, covering 7 of the 12 Service Categories and 17 of the 27 Service Topics. The harmonization of services is visualized as a future necessary step in EC4Safenano, in order to strengthen the offer and provide added value to customers with a growing offer of harmonized services in future versions of the CoS. The information contained in this document is structured in 3 main sections, as follows: • Catalogue structure. This section describes in short the main characteristics of the CoS 2019. • Catalogue content. This section represents the core part of the document and encapsulates the set of 100 SDSs displaying the offer proposed by the CoS 2019. • Online Catalogue. This section describes the resources implemented by EC4Safenano to facilitate the on-line consultation of the CoS 2019 by customers and other interested parties. KW - Nano-safety KW - Analytical services KW - Nanomaterials KW - Catalogue of services KW - EC4SafeNano KW - European Centre PY - 2021 UR - https://ec4safenano.eu-vri.eu/Public/Guidance SP - 1 EP - 72 PB - EU-VRi – European Virtual Institute for Integrated Risk Management CY - Stuttgart, Germany AN - OPUS4-52943 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dreßler, Martin A1 - Röllig, Mathias A1 - Schmidt, Martin A1 - Maturilli, A. A1 - Helbert, J. T1 - Temperature distribution in powder beds during 3D printing JF - Rapid prototyping journal N2 - Purpose – This purpose of this paper is to report about the temperature distribution in metal and ceramic powder beds during 3D printing. The differing powders are thoroughly characterized in terms of thermal conductivity, thermal diffusivity, emissivity spectra and density. Design/methodology/approach – The temperature distribution was measured in a 3D printing appliance (Prometal R1) with the help of thin thermocouples (0.25 mm diameter) and thermographic imaging. Temperatures at the powder bed surface as well as at differing powder bed depths were determined. The thermal conductivity, thermal diffusivity and emissivity spectra of the powders were measured as well. Numerical simulation was used to verify the measured temperatures. Findings – The ceramic powder heated up and cooled down more quickly. This finding corresponds well with numerical simulations based on measured values for thermal conductivity and thermal diffusivity as well as emissivity spectra. An observed color change at the metal powder has only little effect on emissivity in the relevant wavelength region. Research limitations/implications – It was found that thermocouple-based temperature measurements at the powder bed surface are difficult and these results should be considered with caution. Practical implications – The results give practitioners valuable information about the transient temperature evolution for two widely used but differing powder systems (metal, ceramic). The paramount importance of powder bed porosity for thermal conductivity was verified. Already small differences in thermal conductivity, thermal diffusivity and hence volumetric heat capacity lead to marked differences in the transient temperature evolution. Originality/value – The paper combines several techniques such as temperature measurements, spectral emissivity measurements, measurements of thermal conductivity and diffusivity and density measurements. The obtained results are put into a numerical model to check the obtained temperature data and the other measured values for consistency. This approach illustrates that determinations of surface temperatures of the powder beds are difficult. KW - Rapid prototypes KW - Printers KW - Heat transfer KW - Powders KW - Ceramics KW - Metals PY - 2010 DO - https://doi.org/10.1108/13552541011065722 SN - 1355-2546 VL - 16 IS - 5 SP - 328 EP - 336 PB - MCB University Press CY - Bradford AN - OPUS4-22002 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ewert, Uwe A1 - Martin Tschaikner, Martin A1 - Hohendorf, Stefan A1 - Bellon, Carsten A1 - Haith, M. I. A1 - Huthwaite, P. A1 - Lowe, M. J. S. T1 - Corrosion monitoring with tangential radiography and limited view computed tomography T2 - 42nd Annual Review of Progress in Quantitative Nondestructive Evaluation N2 - Accurate and reliable detection of subsea Pipeline corrosion is required in order to verify the integrity of the pipeline. A laboratory trial was conducted with a representative pipe sample. The accurate measurement of the wall thickness and corrosion was performed with high energy X-rays and a digital detector array. A 7.5 MV betatron was used to penetrate a stepped pipe and a welded test pipe of 3 m length and 327 mm outer diameter, with different artificial corrosion areas in the 24 mm thick steel wall. The radiographs were taken with a 40 x 40 cm² digital detector array, which was not large enough to cover the complete pipe diameter after magnification. A C-arm based geometry was tested to evaluate the potential for automated inspection in field. The primary goal was the accurate measurement of wall thickness conforming to the standard. The same geometry was used to explore the ability of a C-arm based scanner in asymmetric mode for computed tomography (CT) measurement, taking projections covering only two thirds of the pipe diameter. The technique was optimized with the modelling Software aRTist. A full volume of the pipe was reconstructed and the CT data set was used for reverse engineering, providing a CAD file for further aRTist simulations to explore the technique for subsea inspections. T2 - 42nd Annual Review of Progress in Quantitative Nondestructive Evaluation CY - Minneapolis, Minnesota, USA DA - 26.07.2015 KW - Corrosion monitoring KW - Tangential radiography KW - Computed tomography PY - 2016 SN - 978-0-7354-1353-5 DO - https://doi.org/10.1063/1.4940574 SN - 0094-243X VL - 1706 SP - 110003-1 EP - 110003-8 PB - AIP Publishing AN - OPUS4-37555 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Gruskovà, J. A1 - Martin, G. A1 - Kresten, O. A1 - Mitthoff, F. A1 - Kaska, K. A1 - Hofmann, C. A1 - Kreuzer, W. A1 - Phelps, M. A1 - Boydston, K. A1 - Easton Jr., R. L. A1 - Knox, K. T. A1 - Kelbe, D. A1 - Kasotakis, D. A1 - Christens-Barry, W. A. A1 - Stewart, D. A1 - Rabin, Ira A1 - Hahn, Oliver A1 - Glaser, L. A1 - Garrevoet, J. A1 - Shevchuk, I. A1 - Klumpp, S. A1 - Deckers, D. A1 - Buck, J. ED - Cronier, M. ED - Mondrain, B. T1 - Insights-into-the-Digital-Recovery-of-the-Scythica-Vindobonesia T2 - Collège de France – CNRS Centre de recherche d'histoire et civilisation de Byzance N2 - The Scythica Vindobonensia, the new fragments on Gothic incursions into Roman provinces in the Balkans in the middle of the third century AD that were revealed some years ago in a Greek palimpsest at the Austrian National Library in Vienna (ÖNB), are commonly considered as one of the most important additions of the last decades to the corpus of texts from classical Antiquity. Tere is a high degree of confdence among scholars in supposing that the fragments come from the lost work Scythica written in Greek by the third-century historian P. Herennius Dexippus (Δέξιππος) of Athens. The new fragments have hence also been called Dexippus Vindobonensis. In his Scythica, Dexippus recorded wars of the Romans with the Goths (and other tribes) whom he called Scythians. The work had been hitherto known only from excerpts and quotes by later authors. Eight pages of a Byzantine manuscript copy of the ancient text have survived hidden underneath the visible surface of the last four parchment folios of the Vienna manuscript Historicus graecus 73, f. 192r -195v4. The copy is written in a Greek calligraphic minuscule which has been estimated by palaeographers to be of the middle or the second half of the eleventh century. In the thirteenth century, the text (on each of the eight pages arranged in one column, with 30 lines per page) was washed of the parchment and the valuable material made from animal skin was re-used for Christian texts. The new writing largely covered the faded remnants of the original text. It thus became hidden from the human eye for more than seven hundred years. Its discovery by Jana Grusková, a classical philologist specialized in the transmission of Greek texts, resulted from a systematic review of all Greek palimpsests kept at the Austrian National Library in Vienna at the beginning of the twenty-first century and a detailed examination of the four folios in 2007-20097. KW - Scythica Vindobonensia, KW - Gothic incursions KW - A Greek palimpsest KW - Antiquity KW - Byzantine manuscript KW - Vienna manuscript PY - 2020 SN - 978-2-916716-81-7 SN - 0577-1471 VL - 2020 IS - 24/1 SP - 945 EP - 967 PB - Association des Amis du Centre d’Histoire et Civilisation de Byzance CY - Paris ET - 1 AN - OPUS4-53843 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Strüder, L. A1 - Hartmann, R. A1 - Holl, P. A1 - Ihle, S. A1 - Huth, M. A1 - Schmidt, J. A1 - Tham, Ch. A1 - Kanngießer, B. A1 - Baumann, J. A1 - Renno, A. A1 - Grenzer, J. A1 - Radtke, Martin A1 - Abboud, A. A1 - Pietsch, U. A1 - Soltau, H. T1 - High Speed, High Resolution imaging spectrometers based on pnCCDs for XRF and XRD applications JF - Microscopy and Microanalysis N2 - For many years pnCCDs have been well known as X-ray detectors for spectroscopic imaging in many fields of science: X-Ray Fluorescence analysis (XRF), X-ray Diffraction (XRD) with light sources in large accelerator facilities as well as with laboratory light sources or with X-rays from celestial sources in X-ray astronomy. A brief introduction in GEXRF (Grazing Emission XRF) measurements with a laboratory laser produced plasma source will be given, PIXE (Particle Induced X-ray Emission) measurements and D2XRF (Double Dispersive X-Ray Fluorescence) and Slicing experiments with pnCCDs coupled to polycapillary optics performed at the BESSY synchrotron will be shown. Energy-dispersive Laue diffraction with ultra-hard X-rays for the analysis of defects in metals will conclude the overview of spectroscopic X-ray imaging measurements in the field of structure and dynamics of matter. KW - PnCCD KW - Synchrotron KW - XRF PY - 2016 DO - https://doi.org/10.1017/S1431927616001355 VL - 22 IS - S3 SP - 100 EP - 101 AN - OPUS4-38884 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nilsson, R. H. A1 - Taylor, A. F. S. A1 - Adams, R. I. A1 - Baschien, C. A1 - Bengtsson-Palme, J. A1 - Cangren, P. A1 - Coleine, C. A1 - Iršėnaitė, R. A1 - Martin-Sanchez, Pedro Maria A1 - Meyer, W. A1 - Oh, S.-Y. A1 - Sampaio, J. P. A1 - Seifert, K. A. A1 - Sklenář, F. A1 - Stubbe, D. A1 - Suh, S.-O. A1 - Summerbell, R. A1 - Svantesson, S. A1 - Unterseher, M. A1 - Visagie, C. M. A1 - Weiss, M. A1 - Woudenberg, J. HC. A1 - Wurzbacher, C. A1 - Van den Wyngaert, S. A1 - Yilmaz, N. A1 - Yurkov, A. A1 - Kõljalg, U. A1 - Abarenkov, K. A1 - Daniel, H.-M. A1 - Glassman, S. I. A1 - Hirooka, H. A1 - Irinyi, L. T1 - Taxonomic annotation of public fungal ITS sequences from the built environment – a report from an April 10–11, 2017 workshop (Aberdeen, UK) JF - MycoKeys N2 - Recent DNA-based studies have shown that the built environment is surprisingly rich in fungi. These indoor fungi – whether transient visitors or more persistent residents – may hold clues to the rising levels of human allergies and other medical and building-related health problems observed globally. The taxo¬nomic identity of these fungi is crucial in such pursuits. Molecular identification of the built mycobiome is no trivial undertaking, however, given the large number of unidentified, misidentified, and technically compromised fungal sequences in public sequence databases. In addition, the sequence metadata required to make informed taxonomic decisions – such as country and host/substrate of collection – are often lacking even from reference and ex-type sequences. Here we report on a taxonomic annotation workshop (April 10–11, 2017) organized at the James Hutton Institute/University of Aberdeen (UK) to facilitate reproducible studies of the built mycobiome. The 32 participants went through public fungal ITS bar¬code sequences related to the built mycobiome for taxonomic and nomenclatural correctness, technical quality, and metadata availability. A total of 19,508 changes – including 4,783 name changes, 14,121 metadata annotations, and the removal of 99 technically compromised sequences – were implemented in the UNITE database for molecular identification of fungi (https://unite.ut.ee/) and shared with a range of other databases and downstream resources. Among the genera that saw the largest number of changes were Penicillium, Talaromyces, Cladosporium, Acremonium, and Alternaria, all of them of significant importance in both culture-based and culture-independent surveys of the built environment. KW - Indoor mycobiome KW - Built environment KW - Molecular identification KW - Fungi KW - Taxonomy KW - Systematics KW - Sequence annotation KW - Metadata KW - Open data PY - 2018 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-438949 DO - https://doi.org/10.3897/mycokeys.28.20887 SN - 1314-4049 SN - 1314-4057 VL - 28 SP - 65 EP - 82 PB - Pensoft Publishers CY - Washington, DC AN - OPUS4-43894 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Nowak, S. H. A1 - Petric, M. A1 - Buchriegler, J. A1 - Bjeoumikhov, A. A1 - Bjeoumikhova, Z. A1 - von Borany, J. A1 - Munnik, F. A1 - Radtke, Martin A1 - Renno, A. D. A1 - Reinholz, Uwe A1 - Scharf, O. A1 - Tilgner, J. A1 - Wedell, R. T1 - Road to micron resolution with a color X-ray camera – polycapillary optics characterization T2 - arXiv.org N2 - In a color X-ray camera spatial resolution is achieved by means of a polycapillary optic conducting X-ray photons from small regions on a sample to distinct energy dispersive pixels on a CCD matrix. At present, the resolution limit of color X-ray camera systems can go down to several microns and is mainly restricted by Pixel dimensions. The recent development of an efficient subpixel resolution algorithm allows a release from pixel size, limiting the resolution only to the quality of theoptics. In this work polycapillary properties that influence the spatial resolution are systematized and assessed both theoretically and experimentally. It is demonstrated that with the current technological Level reaching one micron resolution is challenging, but possible. KW - Color X-ray camera KW - Polycapillary optics PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-404404 UR - https://arxiv.org/abs/1705.08939 SN - 2331-8422 SP - 1 EP - 11 PB - Cornell University CY - Ithaca, NY AN - OPUS4-40440 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Casperson, Ralf A1 - Engert, D. A1 - Heilmann, S. A1 - Herold, F. A1 - Hofmann, D. A1 - Küchler, H. A1 - Leinenbach, F. A1 - Lorenz, S. A1 - Martin, J. A1 - Rehbein, J. A1 - Sprau, B. A1 - Suppes, A. A1 - Vrana, J. A1 - Wild, E. T1 - DICONDE in der ZfP N2 - DICONDE (Digital Imaging and Communication in Non-Destructive Evaluation) ist ein offener internationaler Standard zur Speicherung und zum Austausch industrieller Prüfdaten und prozessbezogener Informationen. Der DICONDE-Standard definiert sowohl die Semantik für eine strukturierte Speicherung von Daten als auch die netzwerkbasierte Kommunikation zwischen zwei Endpunkten. Damit lassen sich viele Vorgänge von Prüfprozessen digital und sicher abbilden und gleichzeitig normative Anforderungen wie eine Rückführbarkeit zum Prüfer und Prüfobjekt sowie eine Reproduzierbarkeit von Prüfergebnissen erfüllen. KW - DICONDE KW - ZfP KW - Interoperabilität KW - Datenspeicherung KW - Kommunikation PY - 2023 SP - 1 EP - 13 PB - DGZfP CY - Berlin AN - OPUS4-58578 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Brierley, N. A1 - Casperson, Ralf A1 - Engert, D. A1 - Heilmann, S. A1 - Herold, F. A1 - Hofmann, D. A1 - Küchler, H. A1 - Leinenbach, F. A1 - Lorenz, S. A1 - Martin, J. A1 - Rehbein, J. A1 - Sprau, B. A1 - Suppes, A. A1 - Vrana, J. A1 - Wild, E. T1 - DICONDE in industrial inspection N2 - DICONDE (Digital Imaging and Communication in Non-Destructive Testing) is an open international standard for storing and exchanging industrial test data and process-related information. The DICONDE standard defines both the semantics for structured storage of data and the network-based communication between two endpoints. This allows many test processes to be mapped digitally and securely, while at the same time meeting normative requirements such as traceability to the tester and test object and reproducibility of test results. KW - DICONDE KW - NDT KW - Interoperability KW - Data storage KW - Communication PY - 2023 SP - 1 EP - 13 PB - DGZfP CY - Berlin AN - OPUS4-58576 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - de O. Primo, J. A1 - Horsth, D.F. A1 - de S. Correa, J. A1 - Das, A. A1 - Bittencourt, C. A1 - Umek, P. A1 - de Oliveira Guilherme Buzanich, Ana A1 - Radtke, Martin A1 - Yusenko, Kirill A1 - Zanetta, C. A1 - Anaissi, F.J. T1 - Synthesis and Characterization of Ag/ZnO Nanoparticles for Bacteria Disinfection in Water JF - Nanomaterials N2 - n this study, two green synthesis routes were used for the synthesis of Ag/ZnO nanoparticles, using cassava starch as a simple and low-cost effective fuel and Aloe vera as a reducing and stabilizing agent. The Ag/ZnO nanoparticles were characterized and used for bacterial dis- infection of lake water contaminated with Escherichia coli (E. coli). Characterization indicated the formation of a face-centered cubic structure of metallic silver nanoparticles with no insertion of Ag into the ZnO hexagonal wurtzite structure. Physicochemical and bacteriological analyses described in “Standard Methods for the Examination of Water and Wastewater” were used to evaluate the efficiency of the treatment. In comparison to pure ZnO, the synthesized Ag/ZnO nanoparticles showed high efficiencies against Escherichia coli (E. coli) and general coliforms present in the lake water. These pathogens were absent after treatment using Ag/ZnO nanoparticles. The results indicate that Ag/ZnO nanoparticles synthesized via green chemistry are a promising candidate for the treatment of wastewaters contaminated by bacteria, due to their facile preparation, low-cost synthesis,and disinfection efficiency. KW - Synchrotron KW - BAMline PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-562440 DO - https://doi.org/10.3390/nano12101764 SN - 2079-4991 VL - 12 IS - 10 SP - 1 EP - 18 PB - MDPI CY - Basel AN - OPUS4-56244 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Retzlaff, J. A1 - Bronstein, Z. A1 - Müller-Rochholz, J. A1 - Böhning, Martin A1 - Robertson, Daniela A1 - Schröder, Hartmut T1 - Oxidative resistance of geosynthetics: practical aspects and developments of testing at elevated temperature and oxygen pressure T2 - EuroGeo4, 4th European Geosynthetics Conference, September 7-10, 2008, Edinburgh, UK N2 - Service life of geosynthetics made of polyolefin materials is mainly limited by oxidative degradation. Durability of polyolefin products depend on formulation, morphology resulting from manufacturing, design and particularly on the antioxidants used. Although the fundamental oxidative reactions are known, the complex effect of geosynthetic characteristics and external influences mean that durability assessments require practical tests. The assessment of oxidative durability involves exposure to accelerating conditions as well as the material characterisation with respect to the state of stabilisation and/or degradation (e.g. by tensile testing and/or oxidation induction time). The autoclave test developed by BAM for durability assessments of polyolefin geosynthetics is based on the simultaneous application of moderately elevated temperatures (up to 80 degrees Celsius) and elevated oxygen pressures (up to 5.0 MPa) in combination with a surrounding aqueous medium. Thus this test method provides several advantages in comparison to conventional oven testing, especially with respect to test duration, impact of surrounding environment and the potential to differentiate and rank oxidative resistance between products of very different dimensions (surface/volume) and stabilisation. In view of the increasing demand for durability assessments of geosynthetic products with lifetimes significantly exceeding 25 years, the contribution is focused on practical aspects concerning implementation and optimisation of test procedures, conditions and evaluation of results. Furthermore, advanced approaches based on multiple exposure conditions will also be included and corresponding calculations of expected service life in typical applications will be evaluated with respect to significance and repeatability. Thereby involved standards and recommendations - such as EN ISO 13438, Part C or EAG-EDT - are considered. T2 - EuroGeo4, 4th European Geosynthetics Conference CY - Edinburgh, UK DA - 2008-09-07 KW - Ageing KW - Degradation KW - HDPE KW - Laboratory test KW - Oxidation KW - Polypropylene PY - 2008 IS - Paper 178 SP - 1 EP - 4 AN - OPUS4-18423 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Retzlaff, J. A1 - Müller-Rochholz, J. A1 - Klapperich, H. A1 - Böhning, Martin T1 - The behaviour of geosynthetics under cyclic load T2 - EuroGeo4, 4th European Geosynthetics Conference, September 7-10, 2008, Edinburgh, UK N2 - Whenever geosynthetics are used to reinforce or stabilise infrastructural elements such as road- and railways, bridge abutments, run- and taxiways on airports or to protect coastlines of canals and other steep slopes they may be exposed to cyclic loads. Therefore, a reduction factor for dynamic effects on the geosynthetic tensile strength has been included into the calculation of the Long Term Design Strength (LTDS). An approach to assess the behaviour of geosynthetics is to adopt Woehler- or Smith graphs and Haigh-diagrams for polymers. This is because an endurance limit for polymers, which defines an infinite life under a defined cyclic load, has not been seen so far. A huge amount of mechanical testing is needed to predict the behaviour of geosynthetics against this particular background. To reduce these efforts while getting an indication of the cyclic effect on geosynthetics, a combined method of mechanical and chemical analysis has been developed. The pure tensile strength tests to determine the residual strength after cyclic stress has been amended by IR-spectroscopy and Differential Scanning Calorimetry (DSC). In this context the chain change model of PET has been proven as valid for cyclic loads as well, which helps to define the endurance limit of materials made out of PET. For polyolefins such as PP and PE, a limit for the maximum alternating load has been identified at the point of the stress strain graph where the actual and the numerical stress of a material diverge from each other. Cyclic tensile strength tests have been carried out in a hydraulic test frame. The test parameters have been set to simulate the service life of a railway bed trafficked by high speed trains (ICE). T2 - EuroGeo4, 4th European Geosynthetics Conference CY - Edinburgh, UK DA - 2008-09-07 KW - Cyclic load KW - Dynamic loads KW - Laboratory test KW - Reduction factor KW - Reinforcement KW - Stiffness PY - 2008 IS - Paper 179 SP - 1 EP - 7 AN - OPUS4-18425 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - C. Pardo Pérez, L. A1 - Arndt, A. A1 - Stojkovikj, S. A1 - Y. Ahmet, I. A1 - T. Arens,, J. A1 - Dattila, F. A1 - Wendt, R. A1 - de Oliveira Guilherme Buzanich, Ana A1 - Radtke, Martin A1 - Davies, V. A1 - Höflich, K. A1 - Köhnen, E. A1 - Tockhorn, P. A1 - Golnak, R. A1 - Xiao, J. A1 - Schuck, G. A1 - Wollgarten, M. A1 - López, N. A1 - T. Mayer, M. T1 - Determining Structure-Activity Relationships in Oxide Derived CuSn Catalysts During CO2 Electroreduction Using X-Ray Spectroscopy JF - Advanced Energy Materials N2 - The development of earth-abundant catalysts for selective electrochemical CO2 conversion is a central challenge. Cu-Sn bimetallic catalysts can yield selective CO2 reduction toward either CO or formate. This study presents oxide-derived Cu-Sn catalysts tunable for either product and seeks to understand the synergetic effects between Cu and Sn causing these selectivity trends. The materials undergo significant transformations under CO2 reduction conditions, and their dynamic bulk and surface structures are revealed by correlating observations from multiple methods—X-ray absorption spectroscopy for in situ study, and quasi in situ X-ray photoelectron spectroscopy for surface sensitivity. For both types of catalysts, Cu transforms to metallic Cu0 under reaction conditions. However, the Sn speciation and content differ significantly between the catalyst types: the CO-selective catalysts exhibit a surface Sn content of 13 at. % predominantly present as oxidized Sn, while the formate-selective catalysts display an Sn content of ≈70 at. % consisting of both metallic Sn0 and Sn oxide species. Density functional theory simulations suggest that Snδ+ sites weaken CO adsorption, thereby enhancing CO selectivity, while Sn0 sites hinder H adsorption and promote formate production. This study reveals the complex dependence of catalyst structure, composition, and speciation with electrochemical bias in bimetallic Cu catalysts. KW - Electrochemical CO2 conversion KW - Cu catalysts KW - X-ray absorption spectroscopy PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-547116 DO - https://doi.org/10.1002/aenm.202103328 SN - 1614-6832 VL - 12 IS - 5 SP - 2103328 PB - Wiley-VCH GmbH AN - OPUS4-54711 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Coutinho, M.L. A1 - Miller, A. Z. A1 - Martin-Sanchez, Pedro Maria A1 - Mirao, J. A1 - Gomez-Bolea, A. A1 - Machado-Moreira, B. A1 - Cerqueira-Alves, L. A1 - Jurado, V. A1 - Saiz-Jimenez,, C. A1 - Lima, A. A1 - Phillips, A. J. L. A1 - Pina, F. A1 - Macedo, M. F. T1 - A multiproxy approach to evaluate biocidal treatments on biodeteriorated majolica glazed tiles JF - Environmental Microbiology N2 - The Fishing House located on the grounds of the Marquis of Pombal Palace, Oeiras, Portugal, was built in the 18th century. During this epoch, Portuguese gardens, such as the one surrounding the Fishing House, were commonly ornamented with glazed wall tile claddings. Currently, some of these outdoor tile panels are covered with dark colored biofilms, contributing to undesirable aesthetic changes and eventually inducing chemical and physical damage to the tile surfaces. Phylogenetic analyses revealed that the investigated biofilms are mainly composed of green algae, cyanobacteria and dematiaceous fungi. With the aim of mitigating biodeterioration, four different biocides (TiO2 nanoparticles, Biotin® T, Preventol® RI 80 and Albilex Biostat®) were applied in situ to the glazed wall tiles. Their efficacy was monitored by visual examination, epifluorescence microscopy and DNA-based analysis. Significant changes in the microbial community composition were observed 4 months after treatment with Preventol® RI 80 and Biotin® T. Although the original community was inactivated after these treatments, an early stage of re-colonization was detected 6 months after the biocide application. TiO2 nanoparticles showed promising results due to their self-cleaning effect, causing the detachment of the biofilm from the tile surface, which remained clean 6 and even 24 months after biocide application. KW - Biofilm KW - Glazed tiles KW - Fungi PY - 2016 DO - https://doi.org/10.1111/1462-2920.13380 SN - 1462-2912 SN - 1462-2920 VL - 18 IS - 12 SP - 4794 EP - 4816 PB - Society for Applied Microbiology and John Wiley & Sons Ltd AN - OPUS4-37380 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nowak, S.H. A1 - Bjeoumikhov, A. A1 - Von Borany, J. A1 - Buchriegler, J. A1 - Munnik, F. A1 - Petric, M. A1 - Renno, A.D. A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Scharf, O. A1 - Strüder, L. A1 - Wedell, R. A1 - Ziegenrücker, R. T1 - Examples of XRF and PIXE imaging with few microns resolution using SLcam® a color X-ray camera JF - X-ray spectrometry N2 - We present results of recent development of the color X-ray camera, type SLcam®, allowing detection of X-ray images with few microns resolution. Such spectral resolution is achieved with the use of high-quality polycapillary optics combined with sub-pixel resolution. Imaging of Siemens star resolution test chart reveals that the resolution limit of SLcam® can go down to nearly 5µm. Several real sample examples of measurements carried out at the laboratory, synchrotron, and particle-induced X-ray emission beamlines are shown. This is the first time SLcam® is used as particle-induced X-ray emission detector. KW - X-ray KW - Color X-ray camera KW - CXC KW - Synchrotron radiation KW - BESSY KW - BAMline PY - 2015 DO - https://doi.org/10.1002/xrs.2590 SN - 0049-8246 VL - 44 IS - 3 SP - 135 EP - 140 PB - Wiley & Sons, Ltd. CY - Chichester AN - OPUS4-33170 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pogány, A. A1 - Balslev-Harder, D. A1 - Braban, Ch. F. A1 - Cassidy, N. A1 - Ebert, V. A1 - Ferracci, V. A1 - Hieta, T. A1 - Leuenberger, D. A1 - Martin, N. A. A1 - Pascale, C. A1 - Peltola, J. A1 - Persijn, S. A1 - Tiebe, Carlo A1 - Twigg, M. M. A1 - Vaittinen, Olavi A1 - van Wijk, J. A1 - Wirtz, K. A1 - Niederhauser, B. T1 - A metrological approach to improve accuracy and reliability of ammonia measurements in ambient air JF - Measurement Science and Technology N2 - The environmental impacts of ammonia (NH3) in ambient air have become more evident in the recent decades, leading to intensifying research in this field. A number of novel analytical techniques and monitoring instruments have been developed, and the quality and availability of reference gas mixtures used for the calibration of measuring instruments has also increased significantly. However, recent inter-comparison measurements show significant discrepancies, indicating that the majority of the newly developed devices and reference materials require further thorough validation. There is a clear need for more intensive metrological research focusing on quality assurance, intercomparability and validations. MetNH3 (Metrology for ammonia in ambient air) is a three-year project within the framework of the European Metrology Research Programme (EMRP), which aims to bring metrological traceability to ambient ammonia measurements in the 0.5–500 nmol mol−1 amount fraction range. This is addressed by working in three areas: (1) improving accuracy and stability of static and dynamic reference gas mixtures, (2) developing an optical transfer standard and (3) establishing the link between high-accuracy metrological standards and field measurements. In this article we describe the concept, aims and first results of the project. KW - Ammonia in ambient air KW - Traceability KW - Reference gas standards KW - Optical transfer standard KW - Validation and testing infrastructure PY - 2016 DO - https://doi.org/10.1088/0957-0233/27/11/115012 SN - 0957-0233 VL - 27 IS - 11 SP - 115012 EP - 115026 PB - IOP Publishing Ltd. AN - OPUS4-39130 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Wiesler, F. A1 - Hund-Rinke, K. A1 - George, E. A1 - Greef, J.-M. A1 - Holz, F. A1 - Hölze, L.E. A1 - Hülsbergen, K.-J. A1 - Martin, S. A1 - Severin, K. A1 - Spielvogel, S. A1 - Geiger, P. A1 - Nawotke, C. A1 - Kehlenbeck, H. A1 - Schenkel, H. A1 - Adam, Christian A1 - Bloem, E. A1 - Frank, D. A1 - Goldbach, H.E. A1 - Heene, M. A1 - Kratz, S. A1 - Kruse, A. A1 - Möller, K. A1 - Pinnekamp, J. A1 - Schoumans, O.F. A1 - Vogel, Christian A1 - Wulf, S. T1 - Recyclingphosphate in der Düngung – Nutzen und Grenzen N2 - Weltweit werden etwa 80–85 % aller abgebauten Rohphosphate für die Produktion von Düngemitteln verwendet. Bei noch steigendem Bedarf an Phosphor (P) geht man derzeit davon aus, dass die weltweiten P-Reserven noch über 200 Jahre ausreichen. Um den P-Vorrat langfristig abzusichern, sollte der in Reststoffen enthaltene Phosphor möglichst umfänglich genutzt werden. Dieser Forderung trägt das von der Bundesregierung 2012 erstmals beschlossene Deutsche Ressourceneffizienzprogramm ProgRess Rechnung. Rohphosphat wird auch seitens der Europäischen Kommission aufgrundseiner ökonomischen Bedeutung und des unsicheren Angebots als „kritischer Rohstoff“ eingestuft. Vor diesem Hintergrund hat die Bundesregierung in der Verordnung zur Neuordnung der Klärschlammverwertung vom 27. September 2017 in Deutschland eine verpflichtende technische Rückgewinnung von Phosphor für Abwasserbehandlungsanlagen ab einer Ausbaugröße von 100.000 Einwohnerwerten (12 Jahre nach Inkrafttreten der Verordnung) bzw. ab einer Ausbaugröße von über 50.000 Einwohnerwerten (15 Jahre nach Inkrafttreten der Verordnung) vorgeschrieben. Die Verordnung enthält keine Vorgaben hinsichtlich der anzuwendenden Technologie bei der Phosphorrückgewinnung. Ausgenommen von der Rückgewinnungspflicht sind Klärschlämme mit niedrigen Phosphorgehalten (weniger als 20 Gramm Phosphor je Kilogramm Klärschlamm-Trockenmasse). Auch die im Jahre 2017 verabschiedeten neuen Rechtsvorschriften für die Düngung verlangen zukünftig einen nachhaltigen und ressourceneffizienten Umgang mit Nährstoffen bei der landwirtschaftlichen Erzeugung und schränken die P-Zufuhr insbesondere auf hoch versorgten Böden ein (Düngeverordnung vom 26. Mai 2017). Dies wird zu einem mehr am Pflanzenbedarf orientierten und ggf. vermehrt überbetrieblichen Einsatz von wirtschaftseigenen Düngern führen. Um den politischen und gesetzlichen Anforderungen gerecht zu werden, müssen einerseits wirksame und kosteneffiziente technische Verfahren zum P-Recycling (weiter)entwickelt werden. Andererseits müssen die Recyclingprodukte die Anforderungen für eine direkte Verwendung in der Landwirtschaft oder als Rohstoff für die Herstellung von Düngemitteln erfüllen. In dem vorliegenden Standpunkt wird zunächst der potenzielle Beitrag von Reststoffen zur Deckung des P-Bedarfs in der deutschen Pflanzenproduktion geschätzt. Für die wichtigsten Reststoffe werden technische Verfahren zur P-Rückgewinnung bzw. Aufarbeitung skizziert. Auf Basis der Anforderungen der Landwirtschaft bzw. der Düngemittelindustrie an die P-Recyclingprodukte werden deren Herstellungsverfahren bewertet. Schließlich wird der Regelungs- und Forschungsbedarf formuliert. KW - Phosphor KW - Düngemittel KW - Diffusive Gradients in thin films (DGT) PY - 2020 SP - 1 EP - 19 PB - Bundesministerium für Ernährung und Landwirtschaft (BMEL) CY - Berlin AN - OPUS4-51011 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nowak, S.H. A1 - Bjeoumikhov, A. A1 - Von Borany, J. A1 - Buchriegler, J. A1 - Munnik, F. A1 - Petric, M. A1 - Radtke, Martin A1 - Renno, A.D. A1 - Reinholz, Uwe A1 - Scharf, O. A1 - Wedell, R. T1 - Sub-pixel resolution with a color X-ray camera JF - Journal of analytical atomic spectrometry N2 - The color X-ray camera SLcam® is a full-field, single photon detector providing scanning-free, energy and spatially resolved X-ray imaging. Spatial resolution is achieved with the use of polycapillary optics guiding X-ray photons from small regions on a sample to distinct energy dispersive pixels on a charged-coupled device detector. Applying sub-pixel resolution, signals from individual capillary channels can be distinguished. Therefore, the SLcam® spatial resolution, which is normally limited to the pixel size of the charge-coupled device, can be improved to the size of individual polycapillary channels. In this work a new approach to a sub-pixel resolution algorithm comprising photon events also from the pixel centers is proposed. The details of the employed numerical method and several sub-pixel resolution examples are presented and discussed. KW - Color X-ray camera KW - Sub pixel analysis PY - 2015 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-334948 DO - https://doi.org/10.1039/c5ja00028a SN - 0267-9477 SN - 1364-5544 SP - 1890 EP - 1897 PB - Royal Society of Chemistry CY - London AN - OPUS4-33494 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Fittschen, U.E.A. A1 - Möckel, R. A1 - Schreiner, M. A1 - klinger, M. A1 - Radtke, Martin A1 - Meyer, B. A1 - Guhl, S. A1 - Renno, A. A1 - Godinho, J. A1 - Gloaguen, R. A1 - Gutzmer, J. T1 - Bundling analytical capacities to understand phase formation in recycling of functional materials JF - Materials Science Forum N2 - Transitioning from combustion engine-driven transportation to e-mobility demands a paradigm shift – from a system geared to maximize energy efficiency (i.e. fuel consumption) to a system that may be constrained by the availability of high technology (critical) metals required for electrical energy storage systems and drives. In the wake of these developments efforts in securing new resources of these metals from recycling of end-of-life products are increasing steadily. Recycling of Li-Ion batteries has recently been evaluated. The results pinpoint to a critical need for understanding slag Formation and its dependence on metal components like Mn under extreme conditions. This will allow researchers to predict optimal Operation setting and to react quickly to changing market demands (which may be Li or Co at one point but may also shift to Ni or rare earth elements (REE)). The long-term goal is to control the formation of specific phases in slags allowing for a Maximum yield of elements of interest and optimal recovery in the separation processes that follows. The combination of data on the physical micro structure and local chemistry of the multi-Phase products during and after processing will help to understand and derive thermodynamic and kinetic data on its formation. In this paper we are giving an overview on the analytical challenges and approaches to provide robust data on local element concentration and species (especially Mn which is a common component of next generation Li-ion batteries cathodes), spanning the dimensions from the nanometer scale to the bulk material. The complementary interactions of X-rays and electrons make them ideal probes to collect Interface and “in-depth” information. Before- and -after studies as well as in situ structural changes and Phase (trans)formation, changes in elemental and elemental species (e.g. oxidation state) distribution may be tracked by X-ray diffraction (XRD), X-ray fluorescence microscopy and X-ray Absorption spectroscopy. The application of such advanced analytical tools will not only provide essential clues during early lab-based experiments towards the development of new recycling technologies, but may also be deployed for on-line and in-line monitoring of industrial processes. KW - Synchrotron KW - XANES KW - Slags KW - Battery PY - 2019 DO - https://doi.org/10.4028/www.scientific.net/MSF.959.183 SN - 1662-9752 VL - 959 SP - 183 EP - 190 PB - Trans Tech Publ. AN - OPUS4-48900 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zakel, S. A1 - Schröder, Volkmar A1 - Askar, Enis A1 - Gabel, D. A1 - Hirsch, W. A1 - Kleinert, J. A1 - Krause, U. A1 - Krietsch, Arne A1 - Meistes, J. A1 - Sachtleben, A. A1 - Schmidt, Martin T1 - Sicherheitstechnische Kenngrößen des Explosionsschutzes von hybriden Stoffgemischen - Normungsfähige Bestimmungsverfahren T2 - Tagungsband der 14. Fachtagung Anlagen-, Arbeits- und Umweltsicherheit N2 - In diesem Verbundvorhaben werden standardisierte Messverfahren für hybride Gemische erarbeitet, die der Bestimmung sicherheitstechnischer Kenngrößen des Explosionsschutzes dienen. Unter einem hybriden Gemisch wird dabei ein mehrphasiges System aus Brenngas oder brennbarem Dampf, sowie Luft und brennbarem Staub verstanden. Die Veröffentlichung der Ergebnisse erfolgt in einem Abschlussbericht und als DIN-Spezifikation (DIN SPEC). Diese DIN SPEC versetzt Prüfinstitute und Industrie in die Lage, Explosionsgefahren beim Betrieb technischer Anlagen mit hybriden Gemischen einzuschätzen und damit Prozesse sowohl sicherer als auch effizienter zu steuern. Dieses Projekt wird im Rahmen des WIPANOProgramms (Wissens- und Technologietransfer durch Patente und Normen) vom BMWi gefördert. T2 - 14. Fachtagung Anlagen-, Arbeits- und Umweltsicherheit CY - Köthen, Germany DA - 07.11.2019 KW - Explosionsschutz KW - Sicherheitstechnische Kenngrößen KW - Hybride Gemische KW - Normung PY - 2019 SN - 978-3-89746-220-5 SP - 73 CY - Frankfurt am Main AN - OPUS4-49954 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rauwolf, M. A1 - Turyanskaya, A. A1 - Roschger, A. A1 - Prost, J. A1 - Simon, R. A1 - Scharf, O. A1 - Radtke, Martin A1 - Schoonjans, Tom A1 - de Oliveira Guilherme Buzanich, Ana A1 - Klaushofer, K. A1 - Wobrauschek, P. A1 - Hofstaetter, J. G. A1 - Roschger, P. A1 - Streli, C. T1 - Synchrotron radiation micro X-ray fluorescence spectroscopy of thin structures in bone samples: comparison of confocal and color X-ray camera setups JF - Journal of Synchrotron Radiation N2 - In the quest for finding the ideal synchrotron-radiation-induced imaging method for the investigation of trace element distributions in human bone samples, experiments were performed using both a scanning confocal synchrotron radiation micro X-ray fluorescence (SR-mXRF) (FLUO beamline at ANKA) setup and a full-field color X-ray camera (BAMline at BESSY-II) setup. As zinc is a trace element of special interest in bone, the setups were optimized for its detection. The setups were compared with respect to count rate, required measurement time and spatial resolution. It was demonstrated that the ideal method depends on the element of interest. Although for Ca (a major constituent of the bone with a low energy of 3.69 keV for its K alpha XRF line) the color X-ray camera provided a higher resolution in the plane, for Zn (a trace element in bone) only the confocal SR-µXRF setup was able to sufficiently image the distribution. KW - Synchrotron KW - BAMline KW - BESSY KW - XRF KW - X-ray Color Camera PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-391944 DO - https://doi.org/10.1107/S1600577516017057 SN - 1600-5775 VL - 24 SP - 307 EP - 311 PB - International Union of Crystallography AN - OPUS4-39194 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Emamverdi, Farnaz A1 - Huang, J. A1 - Szymoniak, Paulina A1 - Bojdys, M. J. A1 - Böhning, Martin A1 - Schönhals, Andreas T1 - Structure and molecular mobility of phosphinine-based covalent organic frameworks – glass transition of amorphous COFs JF - Materials Advances N2 - Two-dimensional covalent organic frameworks (COFs) based on phosphinine and thiophene building blocks have been synthesized with two different side groups. The materials are denoted as CPSF-MeO and CPSF-EtO where CxxF correspond to the covalent framework, whereas P and S are related to heteroatoms phosphorous and sulfur. MeO and EtO indicate the substituents, i.e. methoxy and ethoxy. Their morphologies were studied by scanning electron microcopy and X-ray scattering. The absence of crystalline reflexes in the X-ray pattern reveal that both materials are amorphous and can be considered as glasses. Furthermore, N2 adsorption measurements indicate substantial Brunauer–Emmett–Teller (BET) surface area values pointing to the formation of three-dimensional pores by stacking of the aromatic 2D layer. An analysis of the porosity of both COFs showed a mean radius of the pores to be of ca. 4 nm, consistent with their chemical structure. The COFs form nanoparticles with a radius of around 100 nm. The thermal behavior of the COFs was further investigated by fast scanning calorimetry. These investigations showed that both COFs undergo a glass transition. The glass transition temperature of CPSF-EtO is found to be ca. 100 K higher than that for CPSF-MeO. This large difference in the glass transition is discussed to be due to a change in the interaction of the COF sheets induced by the longer ethoxy group. It might be assumed that for CPSF-EtO more individual COF sheets assemble to larger stacks than for CPSF-MeO. This agrees with the much larger surface area value found for CPSF-EtO compared to CPSF-MeO. To corroborate the results obtained be fast scanning calorimetry dielectric measurements were conducted which confirm the occurrence of a dynamic glass transition. The estimated temperature dependence of the relaxation rates of the dielectric relaxation and their absolute values agrees well with the data obtained by fast scanning calorimetry. Considering the fragility approach to the glass transition, it was further found that CPSF-MeO is a fragile glass former whereas CPSF-EtO behaves as a strong glass forming material. This difference in the fragility points also to distinct differences in the interaction between the 2D COF molecules in both materials. KW - Covalent Organic frameworks PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-596770 DO - https://doi.org/10.1039/d3ma01123b SP - 1 EP - 10 PB - Royal Society of Chemistry (RSC) AN - OPUS4-59677 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Emamverdi, Farnaz A1 - Huang, J. A1 - Mosane Razavi, Negar A1 - Bojdys, M. J. A1 - Forster, A. B. A1 - Budd, P. M. A1 - Böhning, Martin A1 - Schönhals, Andreas T1 - Molecular Mobility and Gas Transport Properties of Mixed Matrix Membranes Based on PIM‑1 and a Phosphinine Containing Covalent Organic Framework JF - Macromolecules N2 - Polymers with intrinsic microporosity (PIMs) are gaining attention as gas separation membranes. Nevertheless, they face limitations due to pronounced physical aging. In this study a covalent organic framework containing λ5-phosphinine moieties, CPSF-EtO were incorporated as a nanofiller (concentration range 0-10 wt%) into a PIM-1 matrix forming dense films with a thickness of ca. 100 μm. The aim of the investigation was to investigate possible enhancements of gas transport properties and mitigating effects on physical aging. The incorporation of the nanofiller occurred on aggregate level with domains up to 100 nm as observed by T-SEM and confirmed by X-ray scattering. Moreover, the X-ray data show that the structure of the microporous network of the PIM-1 matrix is changed by the nanofiller. As the molecular mobility is fundamental for gas transport as well as for physical aging, the study includes dielectric investigations of pure PIM-1 and PIM-1/CPSF-EtO mixed matrix membranes to establish a correlation between the molecular mobility and the gas transport properties. Using the time-lag method the gas permeability and the permselectivity were determined for N2, O2, CH4 and CO2 for samples with variation in filler content. A significant increase in the permeability of CH4 and CO2 (50 % increase compared to pure PIM-1) was observed for a concentration of 5 wt% of the nanofiller. Furthermore, the most pronounced change in the permselectivity was found for the gas pair CO2/N2 at a filler concentration of 7 wt%. KW - Polymers of Intrinsic Microporosity KW - Nanocomposites PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-595031 DO - https://doi.org/10.1021/acs.macromol.3c02419 SN - 0024-9297 VL - 57 IS - 4 SP - 1829 EP - 1845 PB - ACS Publications AN - OPUS4-59503 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Braymer, Joseph J. A1 - Stehling, Oliver A1 - Stümpfig, Martin A1 - Rösser, Ralf A1 - Spantgar, Farah A1 - Blinn, Catharina M. A1 - Mühlenhoff, Ulrich A1 - Pierik, Antonio J. A1 - Lill, Roland T1 - Requirements for the biogenesis of [2Fe-2S] proteins in the human and yeast cytosol JF - Proceedings of the National Academy of Sciences N2 - The biogenesis of iron–sulfur (Fe/S) proteins entails the synthesis and trafficking of Fe/S clusters, followed by their insertion into target apoproteins. In eukaryotes, the multiple steps of biogenesis are accomplished by complex protein machineries in both mitochondria and cytosol. The underlying biochemical pathways have been elucidated over the past decades, yet the mechanisms of cytosolic [2Fe-2S] protein assembly have remained ill-defined. Similarly, the precise site of glutathione (GSH) requirement in cytosolic and nuclear Fe/S protein biogenesis is unclear, as is the molecular role of the GSH-dependent cytosolic monothiol glutaredoxins (cGrxs). Here, we investigated these questions in human and yeast cells by various in vivo approaches. [2Fe-2S] cluster assembly of cytosolic target apoproteins required the mitochondrial ISC machinery, the mitochondrial transporter Atm1/ABCB7 and GSH, yet occurred independently of both the CIA system and cGrxs. This mechanism was strikingly different from the ISC-, Atm1/ABCB7-, GSH-, and CIA-dependent assembly of cytosolic–nuclear [4Fe-4S] proteins. One notable exception to this cytosolic [2Fe-2S] protein maturation pathway defined here was yeast Apd1 which used the CIA system via binding to the CIA targeting complex through its C-terminal tryptophan. cGrxs, although attributed as [2Fe-2S] cluster chaperones or trafficking proteins, were not essential in vivo for delivering [2Fe-2S] clusters to either CIA components or target apoproteins. Finally, the most critical GSH requirement was assigned to Atm1-dependent export, i.e. a step before GSH-dependent cGrxs function. Our findings extend the general model of eukaryotic Fe/S protein biogenesis by adding the molecular requirements for cytosolic [2Fe-2S] protein maturation. KW - Biokorrosion KW - Hydrogenasen KW - Microbially Induced Corrosion PY - 2024 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-602328 DO - https://doi.org/10.1073/pnas.2400740121 VL - 121 IS - 21 SP - 1 EP - 12 PB - Proceedings of the National Academy of Sciences CY - Washington D.C. AN - OPUS4-60232 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tuma, Dirk A1 - Moreau, A. A1 - Polishuk, I. A1 - Segovia, J. J. A1 - Vega-Maza, D. A1 - Martín, M. C. T1 - Measurements and predictions of densities and viscosities in CO2 + hydrocarbon mixtures at high pressures and temperatures: CO2 + n-pentane and CO2 + n-hexane blends JF - Journal of Molecular Liquids N2 - This work reports new experimental data on densities and viscosities of (CO2 + n-pentane) and (CO2 + n-hexane) mixtures at high pressures and temperatures. The densities were measured by a vibrating-tube densimeter with an expanded uncertainty (k = 2) smaller than 1.8 kg/m3 at six isotherms (from 273.15 K to 373.15 K), twelve pressures starting at 5 MPa up to 100 MPa, and at six CO2 molar compositions (from 0 to 0.6). The viscosities were measured by a vibrating-wire viscometer with the corresponding relative expanded uncertainty (k = 2) smaller than 0.016 at five isotherms (from 273.15 K to 373.15 K), twelve pressures (from 5 MPa up to 100 MPa), and at two CO2 molar compositions (0.1 and 0.3). The densities were fitted by the semiempirical Tammann-Tait equation for density data and the Vogel-Fulcher-Tammann (VFT) equation for viscosity data, respectively. The Groupe Européen de Recherches Gazières (GERG-2008) equation of state was also applied for modelling the densities. Over-all robustness and reliability of the Perturbed-Chain Statistical Association Fluid Theory (PC-SAFT) and its critical point-based modification (CP-PC-SAFT) were examined. Accuracies of the Modified Yarranton-Satyro (MYS) coupled with CP-PC-SAFT and the NIST Reference Fluid Thermodynamic and Transport Properties Database (REFPROP 10) in predicting the viscosities were evaluated. KW - CO2 + n-alkanes KW - thermophysical properties KW - Perturbed-Chain Statistical Association Fluid Theory PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-555728 DO - https://doi.org/10.1016/j.molliq.2022.119518 SN - 0167-7322 VL - 360 SP - 1 EP - 15 PB - Elsevier CY - Amsterdam AN - OPUS4-55572 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Spickermann, J. A1 - Martin, K. A1 - Räder, H.J. A1 - Müllen, K. A1 - Schlaad, H. A1 - Müller, A. H. E. A1 - Krüger, Ralph-Peter T1 - Quantitative analysis of broad molecular weight distributions obtained by MALDI-TOF mass spectrometry JF - European journal of mass spectrometry PY - 1996 SN - 1469-0667 SN - 1356-1049 SN - 1365-0718 IS - 2 SP - 161 EP - 165 PB - IM Publications CY - Chichester AN - OPUS4-2153 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Guilherme, A. A1 - Buzanich, Günter A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Coroado, J. A1 - Dos Santos, J.M.F. A1 - Carvalho, M.L. T1 - Synchrotron micro-XRF with compound refractive lenses (CRLs) for tracing key elements on Portuguese glazed ceramics JF - Journal of analytical atomic spectrometry N2 - Several glazed ceramic fragments (XVIth to XVIIIth centuries) from two production centers in Portugal (Coimbra and Lisbon) were the object of this study. The ones from Coimbra comprise two sets of samples: faiences and tiles. The ones from Lisbon are only tiles (azulejos, in Portuguese). The three main divisions of such pieces are the ceramic support (body), glaze and surface decoration. The system decoration/glaze is not easy to investigate, due to the high heterogeneity resulting from the mixing procedures and firing temperatures used. Moreover, the ability of the pigment to diffuse into the base glaze varies depending on the composition of both the pigment and the glaze in terms of fusibility. In order to raster these effects, high resolution techniques are required. In this work, synchrotron micro-X-ray fluorescence (µ-XRF) analysis was performed to monitor the profiles of the characteristic elements from the colors used and the glaze in well prepared cross-sections of the samples. Key elements are: Co for blue, Mn for purple, Cu for green, Sb for yellow, Pb for the glaze and Fe for the body. The major difference observed is that faiences have glaze thicknesses between 150 and 200 µm and tiles have glaze thicknesses between 350 and 400 µm. Furthermore, in faiences all the pigments except the yellow ones are well dispersed into the glassy matrix, while in tiles, all of them are just partially diffused throughout the glaze. However, differences between the tiles from Coimbra and Lisbon were observed. In the samples from Lisbon, a higher intake from the pigment throughout the glaze is observed. KW - Synchrotron micro-XRF KW - Compound refractive lenses (CRLs) KW - Portuguese glazed ceramics PY - 2012 DO - https://doi.org/10.1039/c2ja30030c SN - 0267-9477 SN - 1364-5544 VL - 27 IS - 6 SP - 966 EP - 974 PB - Royal Society of Chemistry CY - London AN - OPUS4-26789 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wilhelm, Stefan A1 - Kaiser, Martin A1 - Würth, Christian A1 - Heiland, J. A1 - Carrillo-Carrion, C. A1 - Muhr, V. A1 - Wolfbeis, Otto S. A1 - Parak, W.J. A1 - Resch-Genger, Ute A1 - Hirsch, T. T1 - Water dispersible upconverting nanoparticles: effects of surface modification on their luminescence and colloidal stability JF - Nanoscale N2 - We present a systematic study on the effect of surface ligands on the luminescence properties and colloidal stability of β-NaYF4:Yb3+,Er3+ upconversion nanoparticles (UCNPs), comparing nine different surface coatings to render these UCNPs water-dispersible and bioconjugatable. A prerequisite for this study was a large-scale synthetic method that yields ~2 g per batch of monodisperse oleate-capped UCNPs providing identical core particles. These ~23 nm sized UCNPs display an upconversion quantum yield of ~0.35% when dispersed in cyclohexane and excited with a power density of 150 W cm-2, underlining their high quality. A comparison of the colloidal stability and luminescence properties of these UCNPs, subsequently surface modified with ligand exchange or encapsulation protocols, revealed that the ratio of the green (545 nm) and red (658 nm) emission bands determined at a constant excitation power density clearly depends on the surface chemistry. Modifications relying on the deposition of additional (amphiphilic) layer coatings, where the initial oleate coating is retained, show reduced non-radiative quenching by water as compared to UCNPs that are rendered water-dispersible via ligand exchange. Moreover, we could demonstrate that the brightness of the upconversion luminescence of the UCNPs is strongly affected by the type of surface modification, i.e., ligand exchange or encapsulation, yet hardly by the chemical nature of the ligand. KW - upconverting nanoparticles (UCNPs) KW - Luminescence KW - surface modification PY - 2015 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-324071 DO - https://doi.org/10.1039/c4nr05954a SN - 2040-3364 SN - 2040-3372 VL - 7 IS - 4 SP - 1403 EP - 1410 PB - RSC Publ. CY - Cambridge AN - OPUS4-32407 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Krause, Martin A1 - Bärmann, R. A1 - Frielinghaus, R. A1 - Kreschmar, F. A1 - Krogge, O. A1 - Langenberg, K. A1 - Maierhofer, Christiane A1 - Müller, W. A1 - Neisecke, J. A1 - Schickert, M. A1 - Schmitz, V. A1 - Wiggenhauser, Herbert A1 - Wollbold, F. ED - Schickert, G. T1 - Comparison of pulse-echo-methods for testing concrete T2 - Proceedings - International Symposium Non-Destructive Testing in Civil Engineering (NDT-CE) T2 - International Symposium Non-Destructive Testing in Civil Engineering (NDT-CE) CY - Berlin, Germany DA - 1995-09-26 KW - Beton KW - Radar KW - Aufprallecho KW - Ultraschall KW - Prüfung PY - 1995 SN - 3-931381-02-1 N1 - Serientitel: BB / DGZfP – Series title: BB / DGZfP SP - 281 EP - 295 PB - DGZfP, Dt. Ges. für Zerstörungsfreie Prüfung e.V. CY - Berlin AN - OPUS4-593 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stadthaus, Meinhard A1 - Thomas, Hans-Martin A1 - König, W. A1 - Baugatz, J. A1 - Migoun, N. A1 - Gnusin, A. T1 - Ermittlung der Eignung von Prüfmitteln für die Eindring- und Magnetpulverprüfung nach dem europäischen Normwerk T2 - ZfP in Anwendung, Entwicklung und Forschung - Jahrestagung 2001 T2 - Jahrestagung Zerstörungsfreie Materialprüfung 2001 CY - Berlin, Deutschland DA - 2001-05-21 PY - 2001 UR - http://www.ndt.net/article/dgzfp01/papers/p39/p39.htm N1 - Serientitel: Berichtsband / Deutsche Gesellschaft für zerstörungsfreie Prüfung e. V. – Series title: Berichtsband / Deutsche Gesellschaft für zerstörungsfreie Prüfung e. V. IS - 75-CD PB - DGZfP CY - Berlin AN - OPUS4-1302 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Berger, Achim A1 - Görner, Wolf A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riesemeier, Heinrich A1 - Reiche, I. A1 - Riederer, J. T1 - A closer look at Albrecht Dürer's drawings (1471-1528) T2 - BESSY highlights 2001 PY - 2002 UR - http://www.helmholtz-berlin.de/media/media/oea/web/pr_webseite/druckschriften/infos/bessy/highlights2001.pdf#page=32 SN - 0179-4159 SP - 32 EP - 33 PB - Berliner Elektronenspeicherring-Gesellschaft für Synchrotronstrahlung CY - Berlin AN - OPUS4-1323 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Berger, Achim A1 - Görner, Wolf A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riesemeier, Heinrich A1 - Reiche, I. A1 - Riederer, J. T1 - Non-destructive investigations of Dürer's silver point drawings by Sy-XRF T2 - BESSY highlights - annual report 2001 PY - 2002 UR - http://www.helmholtz-berlin.de/media/media/oea/web/pr_webseite/druckschriften/berichte/bessy/annualreport2001.pdf#page=292 SN - 0179-4159 SP - 292 EP - 293 PB - Berliner Elektronenspeicherring-Gesellschaft für Synchrotronstrahlung CY - Berlin AN - OPUS4-1324 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Krause, Martin A1 - Wiggenhauser, Herbert A1 - Krieger, J. T1 - Materialtechnische Untersuchung beim Abbruch der Talbrücke Haiger - Durchführung von Ultraschall- und Impakt-Echo-Messungen T2 - Berichte der Bundesanstalt für Straßenwesen, Reihe B (Brücken- und Ingenieurbau) PY - 2002 SN - 0943-9293 IS - 38 SP - 1 EP - 111 PB - Wirtschaftsverl. NW CY - Bremerhaven AN - OPUS4-2217 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Wiggenhauser, Herbert A1 - Krause, Martin A1 - Krieger, J. ED - Medlock, R. T1 - Tests and assessments of NDT methods for concrete bridges T2 - Structural materials technology III N2 - A research project is described involving a comparison of different non-destructive test methods for concrete bridges. A cooperative test series was started with the aim to compare and evaluate the performance and benefits of the latest technical developments in this field. For this purpose test specimens with localized defects were produced. Different modifications of radar, ultrasonic-echo and impact-echo methods were investigated. Including two- and three- dimensional reconstruction models. The experiments were accompanied by numerical simulation of the propagation of sound waves and microwaves. The results showed that the radar and the ultrasonic methods were efficient tools to locate the tendon ducts accurately if the reinforcing bars were not to narrowly spaced. The ultrasonic imaging methods were capable of identifying injection and compaction faults in a blind test. The good performance of the impact-echo method with regard to locating tendon ducts which was claimed in several publications could not be validated in the present investigations. The simulation models provided valuable information on how to improve the experimental test program and its evaluation. T2 - Structural materials technology III CY - San Antonio, TX, USA DA - 1998-03-31 KW - Non-destructive testing in civil engineering KW - concrete bridges KW - tendons KW - ducts KW - injection faults KW - compaction faults KW - round robin test KW - ultrasonic testing KW - pulse radar KW - impact-echo KW - reconstruction calculation KW - synthetic aperture focusing technique (SAFT) KW - magnetic stray field KW - ruptures in prestressing reinforcement PY - 1999 SN - 0-8194-2849-3 DO - https://doi.org/10.1117/12.300098 N1 - Serientitel: SPIE proceedings series – Series title: SPIE proceedings series VL - 3400 SP - 258 EP - 269 PB - SPIE CY - Bellingham, Wash. AN - OPUS4-829 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kautek, Wolfgang A1 - Hertwig, Andreas A1 - Martin, Sven A1 - Krüger, Jörg A1 - Lenzner, Matthias A1 - Spielmann, C. A1 - Lenner, M. A1 - Bunte, J. A1 - Puester, T. A1 - Burmester, T. A1 - Fiedler, A. A1 - Heberer, E. A1 - Brose, M. A1 - Stingl, A. A1 - Kiehl, P. A1 - Hönigsmann, H. A1 - Trautinger, F. A1 - Grabner, G. T1 - Safety in Femtosecond Laser Technology - Recent Results of a European Research Project (406) T2 - Conference proceedings & program of the International Laser Safety Conference T2 - International Laser Safety Conference 2003 ; ILSC 2003 CY - Jacksonville, FL, USA DA - 2003-03-10 PY - 2003 SN - 0-912035-38-2 SP - 1(?) EP - 10(?) PB - Laser Institute of America CY - Orlando, Fla. AN - OPUS4-2259 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Reiche, I. A1 - Berger, Achim A1 - Buck, St. A1 - Görner, Wolf A1 - Ketelsen, Th. A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich T1 - BAMline meets Dürer and van Eyck - Multi-disciplinary investigation of Renaissance silver point drawings by µ-SR-XRF T2 - BESSY highlights - annual report 2002 N2 - - http://www.bessy.de/publications/05.annual_reports/files/AnnualReport2002.pdf - PY - 2003 UR - http://www.helmholtz-berlin.de/media/media/oea/web/pr_webseite/druckschriften/berichte/bessy/annualreport2002.pdf#page=416 SN - 0179-4159 SP - 416 EP - 418 PB - Berliner Elektronenspeicherring-Gesellschaft für Synchrotronstrahlung CY - Berlin AN - OPUS4-2496 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Krause, Martin A1 - Wiggenhauser, Herbert A1 - Krieger, J. T1 - NDE of a Post Tensioned Concrete Bridge Girder Using Ultrasonic Pulse Echo and Impact Echo T2 - Structural materials technology V T2 - 5th Structural Materials Technology NDT Conference CY - Cincinnati, OH, USA DA - 2002-09-10 PY - 2002 SN - 1-571-17094-4 VL - 5 SP - 386 EP - 395 PB - American Society for Nondestructive Testing CY - Columbus, Ohio AN - OPUS4-1978 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schönhals, Andreas A1 - Goering, Harald A1 - Böhning, Martin A1 - Fritz, Andreas A1 - Rübner, J. T1 - Structure Analysis of Polymeric Nanomaterials by Relaxation Spectroscopy T2 - Polydays 2002 T2 - Polydays 2002 CY - Berlin, Germany DA - 2002-09-30 PY - 2002 SP - 1(?) AN - OPUS4-2044 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hieronymus, Hartmut A1 - Hofmann, Martin A1 - Bender, Josef A1 - Henschen, Philipp A1 - Wendler, Reinhold A1 - Plewinsky, Bodo A1 - Steinbach, J. T1 - Characterization of surface explosions JF - Archivum combustionis PY - 2001 SN - 0208-4198 VL - 21 IS - 2 SP - 117 EP - 125 PB - Wydawn. Naukowe PWN CY - Warszawa AN - OPUS4-1213 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reiche, I. A1 - Berger, Achim A1 - Görner, Wolf A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich T1 - Dürer's chemischer Fingerprint - Untersuchungen mittels Synchrotron-induzierter Röntgenfluoreszenzanalyse T2 - 5. Erfurter Fachtage für Konservierung und Restaurierung (rescon) T2 - 5. Erfurter Fachtage für Konservierung und Restaurierung CY - Erfurt, Germany DA - 2002-11-28 PY - 2002 AN - OPUS4-2123 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hofmann, Martin A1 - Bender, Josef A1 - Plewinsky, Bodo A1 - Hieronymus, Hartmut A1 - Steinbach, J. T1 - Influence of Obstacles on Surface Detonations T2 - Proceedings of the 2nd Internet Conference on Process Safety T2 - 2nd Internet Conference on Process Safety CY - --- DA - 2000-03-20 PY - 2000 AN - OPUS4-2125 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Radtke, Martin A1 - Reiche, I. A1 - Berger, Achim A1 - Merchel, Silke A1 - Riesemeier, Heinrich A1 - Görner, Wolf A1 - Riederer, J. A1 - Roth, M. ED - Simionovici, A. T1 - BAMline meets Dürer and Van Eyck - Spatially resolved SR-XRF analyses of silver point drawings and their mysterious inscriptions T2 - 17th International Conference on X-Ray Optics and Microanalysis T2 - 17th International Conference on X-Ray Optics and Microanalysis ; 17th ICXOM CY - Chamonix, France DA - 2003-09-22 PY - 2003 N1 - Serientitel: Spectrochimica acta : Part B, Atomic spectroscopy – Series title: Spectrochimica acta : Part B, Atomic spectroscopy IS - 59.2004,10/11 SP - 48 PB - Elsevier CY - Amsterdam AN - OPUS4-2690 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reiche, I. A1 - Berger, Achim A1 - Görner, Wolf A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich T1 - Silberstiftzeichnungen - Zerstörungsfreie Spurenanalyse mit Synchrotronstrahlung JF - PapierRestaurierung T2 - 10. IADA-Kongress (Internationale Arbeitsgemeinschaft der Archiv-, Bibliotheks- und Graphikrestauratoren) CY - Göttingen, Deutschland DA - 2003-09-21 PY - 2003 SN - 1563-2628 VL - 4 PB - Foto Text Verl. CY - Stuttgart AN - OPUS4-2663 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Wilde, L. A1 - Radnik, J. A1 - Schneider, M. A1 - Herein, D. A1 - Riesemeier, Heinrich A1 - Radtke, Martin T1 - In situ TEY cell for XAS measurements at the BAMline T2 - BESSY highlights - annual report 2003 PY - 2004 UR - http://www.helmholtz-berlin.de/media/media/oea/web/pr_webseite/druckschriften/berichte/bessy/annualreport2003.pdf#page=283 SN - 0179-4159 SP - 283 EP - 285 PB - Berliner Elektronenspeicherring-Gesellschaft für Synchrotronstrahlung CY - Berlin AN - OPUS4-3508 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reiche, I. A1 - Berger, Achim A1 - Duval, A. A1 - Görner, Wolf A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich T1 - Metallstiftzeichnungen Albrecht Dürers JF - PapierRestaurierung KW - Synchrotron KW - XRF analysis KW - Drawings KW - Archaeometry KW - Röntgenfluoreszenzanalyse (RFA) KW - Zeichnungen KW - Archäometrie KW - Albrecht Dürer PY - 2004 SN - 1563-2628 VL - 5 IS - 2 SP - 30 EP - 38 PB - Foto Text Verl. CY - Stuttgart AN - OPUS4-3570 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stadthaus, Meinhard A1 - Thomas, Hans-Martin A1 - Migoun, N.P. A1 - Gnusin, A.B. A1 - Baugatz, J. A1 - König, W. T1 - Sensitivity of penetrant and magnetic particle testing - Performance testing of detection media for penetrant and magnetic particle testing (PT and MT) JF - Materialprüfung = Materials testing N2 - Die Empfindlichkeit von Eindring- und Magnetpulverprüfungen (PT, MT) hängt unter anderem von der Eignung und der Qualität der Prüfmittel ab (für PT bezeichnet als Eindringsystem). Die Ermittlung der Empfindlichkeit erfolgt an Kontrollkörpern mit natürlichen und künstlichen Inhomogenitäten durch Ermittlung der Anzeigenerkennbarkeit als Maß für die Eignung. Die europäischen Normen spezifizieren die Anforderungen an die Prüfmittel für Typen-, Chargen- und Betriebsprüfungen nach pr EN ISO 3452-2 für PT und EN ISO 9934-2 für MT. Dieser Beitrag beschreibt die Ermittlung der Empfindlichkeit von Prüfmitteln sowie deren Qualifizierung bei der Typenprüfung. Die vorgeschlagenen Verfahren wurden durch experimentelle Untersuchungen validiert, bei denen ein Bildverarbeitungssystem zur Ermittlung der Anzeigenerkennbarkeit verwendet wurde. Im Hinblick auf die Qualifizierung der Prüfmittel wird die Zuverlässigkeit der Verfahren diskutiert. PY - 2004 DO - https://doi.org/10.3139/120.100591 SN - 0025-5300 VL - 46 IS - 6 SP - 320 EP - 326 PB - Carl Hanser Verlag CY - München AN - OPUS4-3574 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Stadthaus, Meinhard A1 - Thomas, Hans-Martin A1 - Baugatz, J. A1 - König, W. A1 - Migoun, N. A1 - Gnusin, A. T1 - Performance testing of detection media for magnetic particle and penetrant testing following the European standards T2 - Contrôles non destructifs T2 - Congrès COFREND 2001 CY - Reims, France DA - 2001-04-24 PY - 2001 SP - 1(?) EP - 6(?) PB - COFREND CY - Paris AN - OPUS4-1123 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Hieronymus, Hartmut A1 - Henschen, Philipp A1 - Hofmann, Martin A1 - Bender, Josef A1 - Wendler, Reinhold A1 - Plewinsky, Bodo A1 - Steinbach, J. ED - Pasman, H. T1 - Hazards of surface explosions T2 - Loss prevention and safety promotion in the process industries T2 - 10th International Conference: Loss prevention and safety promotion in the process industries ; 620th Event of the European Federation of Chemical Engineering CY - Stockholm, Sweden DA - 2001-06-19 PY - 2001 SN - 0-444-50699-3 N1 - Serientitel: EFCE event – Series title: EFCE event IS - 620 SP - 897 EP - 908 PB - Elsevier CY - Amsterdam AN - OPUS4-1156 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Thomas, Hans-Martin A1 - Stadthaus, Meinhard A1 - Baugatz, J. A1 - König, W. A1 - Migoun, N. P. A1 - Prokhorenko, P. P. A1 - Gnusin, A. B. T1 - Reproducibility Problem for the Procedure of Type Testing of Liquid Penetrants T2 - Proceedings of the 8th ECNDT N2 - Apparently that the type testing procedure should be conducted under the conditions ensuring reproducibility of its outcomes. We investigated various factors effecting upon the reproducibility. To obtain quantitative characteristics of indication’s visibility the image-processing hard-and software were used. It was established that there are two main groups of these factors. The first depends on the differences between various test panels, which are used for type testing. The second one concerns the reproducibility of some stages of penetrant testing procedure (excess penetrant removing and developer application). The recommendations to increase the reproducibility of type testing are developed and illustrated experimentally. The determination of penetrant system sensitivity as a part of type testing should be conducted ensuring reproducibility of the result. We investigated some factors effecting the reproducibility. To obtain quantitative characteristics of indication’s visibility, an image processing system was used [1]. We used 3 different sets of reference blocks (rb1, rb2, rb3) corresponding to type 1 of EN ISO 3452-3 [2]. Two fluorescent penetrants with different sensitivities and the same wet solvent developer were used. It was established that the reproducibility of type testing is influenced by mainly two principal factors. First there are the differences between reference blocks. Second one concerns the reproducibility of penetrant testing procedure, especially excess penetrant removal and developer application. According to EN ISO 3452-3 a reference block for determination of sensitivity level of fluorescent penetrants consists of a set of three nickel-chrome plated panels with 10, 20 and 30 µm plating thickness. Transverse cracks are made in each panel by stretching the panels in the longitudinal direction and width to depth ratio of the cracks should be approximately 1/20. Each panel presents a certain sensitivity level, which is characterised by the level of visibility of the indication. The highest level 3 corresponds to the panel with 10 µm thickness plating. Each panel is cut longitudinally (perpendicular to the crack) so that 2 sheets (panels A and B) with nearly the same cracks will be produced. These panels A and B of a reference block are used for relative evaluation, for example to compare sensitivities of two penetrants. It is considered that the application of the same penetrant to both panels with subsequent adequate development results in the same visibility of the indications on these panels. Quantitative correlations between the abilities of the reference blocks used for determining of the sensitivity were obtained in our investigations. We used the relations between the measured values of light-fluxes from the indications of similar comparing areas on two panels. These indications correspond to certain cracks’ parts of the same total length on both comparing areas. The relations of the steps between the panel are responsible for the definition of the sensitivity groups. From our investigations it follows that the steps of the different sets are different. Besides it was established that the indication‘s visibility for the same penetrant applied on different reference blocks might have a considerable difference depending on the penetrant sensitivity: the higher penetrant’ sensitivity, the smaller is such a difference between the steps 30/20 and 20/10. For example, for rb3 the relations 30/20 and 20/10 for lower sensitive penetrant (I1) reached factor 3 comparing with factor 2 for higher sensitive penetrant (I2). Some results of the comparison between the 3 sets (rb1, rb2, rb3) investigations are summarised in Table 1 with rb1 as a reference. T2 - 8th ECNDT CY - Barcelona, Spain DA - 2002-06-17 PY - 2002 UR - http://www.ndt.net/article/ecndt02/199/199.htm VL - 8 SP - 1(?) EP - 5(?) PB - European Federation for Non-Destructive Testing CY - Barcelona AN - OPUS4-1396 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Radtke, Martin A1 - Berger, Achim A1 - Görner, Wolf A1 - Merchel, Silke A1 - Reiche, I. A1 - Riederer, J. A1 - Riesemeier, H. T1 - Spatial Resolved Trace Analysis of Dürer's Silver Point Drawings by Means of SR-XRF T2 - Proceedings of the European Conference on Energy Dispersive X-Ray Spectrometry T2 - European Conference on Energy Dispersive X-Ray Spectrometry (EDXRS) CY - Berlin, Germany DA - 2002-06-16 PY - 2002 SP - 158 AN - OPUS4-1397 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Merchel, Silke A1 - Berger, Achim A1 - Görner, Wolf A1 - Radtke, Martin A1 - Riesemeier, Heinrich A1 - Reiche, I. A1 - Riederer, J. A1 - Duval, A. A1 - Guicharnaud, H. T1 - Non-Destructive Investigations of Dürer's Silver Point Drawings by Pixe and SY-XRF T2 - Proceedings of the 7th International Conference on Non-destructive testing and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage T2 - 7th International Conference on Non-destructive testing and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage ; art 2002 CY - Antwerp, Belgium DA - 2002-06-02 PY - 2002 UR - http://srs.dl.ac.uk/arch/publications/reiche/reiche_fullcorr.pdf SP - 82 AN - OPUS4-1400 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Reiche, I. A1 - Berger, Achim A1 - Duval, A. A1 - Görner, Wolf A1 - Guicharnaud, H. A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich A1 - Roth, M. ED - Röhrs, S. T1 - Auf den Spuren Albrecht Dürers - Zerstörungsfreie Untersuchung von Silberstiftzeichnungen mittels Mikro-PIXE und Synchrotron-induzierter Mikro-RFA T2 - Archäometrie und Denkmalpflege (Jahrestagung ... / AK Archäometrie in der GDCh 2003) T2 - Jahrestagung 2003 im Ethnologischen Museum Berlin-Dahlem CY - Berlin, Deutschland DA - 2003-03-12 PY - 2003 SN - 3-00-014223-1 SN - 0949-4057 SP - 118 EP - 120 CY - [Frankfurt am Main] AN - OPUS4-2356 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Langenberg, K. J. A1 - Marklein, R. A1 - Mayer, K. A1 - Krylow, T. A1 - Ampha, P. A1 - Streicher, Doreen A1 - Krause, Martin ED - Pinto, I. M. T1 - Wavefield inversion in nondestructive testing T2 - Electromagnetics in a complex world T2 - Workshop/Minisymposium on "Electromagnetics in a Complex World: Challenges and Perspectives" CY - Benevento, Italy DA - 2003-02-20 PY - 2003 SN - 3-540-20235-8 SN - 0930-8989 N1 - Serientitel: Springer proceedings in physics – Series title: Springer proceedings in physics IS - 96 SP - 1 EP - 10(?) PB - Springer CY - Berlin AN - OPUS4-2357 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reiche, I. A1 - Berger, Achim A1 - Duval, A. A1 - Görner, Wolf A1 - Guicharnaud, H. A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich A1 - Roth, M. ED - Marabelli, M. ED - Tabaso, M. T1 - Spatially resolved SR-XRF analyses of complex drawings of the Holbein family T2 - Proceedings of the 8th International Conference on "Non-Destructive Investigations and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage" T2 - 8th International Conference on "Non-Destructive Investigations and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage" CY - Lecce, Italy DA - 2005-05-15 KW - X-ray spectrometry KW - XRF KW - Röntgenfluoreszenzanalyse KW - RFA KW - Silverpoint drawing KW - Silberstiftzeichnung PY - 2005 SP - 7 pages PB - Italian Society of Non Destructive Testing CY - Lecce AN - OPUS4-7677 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Hasenstab, Andreas A1 - Krause, Martin A1 - Lutz, J. A1 - Hillemeier, B. A1 - Rieck, C. T1 - Niederfrequente Ultraschall-Echo-Verfahren und Bohrwiderstandsmessung zur Untersuchung von Holzbauteilen T2 - ZfP in Forschung, Entwicklung und Anwendung - Jahrestagung 2005 T2 - DGZfP Jahrestagung CY - Rostock, Deutschland DA - 2005-05-02 KW - ZfP an Holzbauteilen KW - Fehlstellen KW - Minderdicken KW - Ultraschallecho-Experimente an Probekörpern KW - Ultraschall-Echo KW - Fäulnis KW - Bauwesen PY - 2005 SN - 3-931381-64-1 N1 - Serientitel: Berichtsband / Deutsche Gesellschaft für zerstörungsfreie Prüfung e. V. – Series title: Berichtsband / Deutsche Gesellschaft für zerstörungsfreie Prüfung e. V. IS - 94-CD SP - 1(?) EP - 11(?) PB - DGZfP CY - Berlin AN - OPUS4-11960 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lohrer, Christian A1 - Schmidt, Martin A1 - Malow, Marcus A1 - Krause, Ulrich A1 - Steinbach, J. T1 - Einfluss von Feuchte und Konvektionsströmung auf das Selbstentzündungsverhalten von Feststoffschüttungen JF - Chemie - Ingenieur - Technik KW - Selbstentzündung KW - Konvektion KW - Feuchte PY - 2005 DO - https://doi.org/10.1002/cite.200590078 SN - 0009-286X SN - 1522-2640 VL - 77 IS - 8 SP - 1141 PB - Wiley-VCH Verl. CY - Weinheim AN - OPUS4-10847 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dengel, Jörg A1 - Wendler, Reinhold A1 - Denzer, Wolfgang A1 - Buchholz, Joachim A1 - Kluge, Martin A1 - Steinbach, J. A1 - Plewinsky, Bodo A1 - Hieronymus, Hartmut T1 - Explosions Near the Surface of Organic Liquids JF - Process safety and environmental protection KW - Heterogeneous explosions KW - Detonation KW - Deflagration KW - Explosion ranges PY - 2005 SN - 0957-5820 SN - 1744-3598 N1 - Geburtsname von Kluge, Martin: Beckmann-Kluge, M. - Birth name of Kluge, Martin: Beckmann-Kluge, M. VL - 83 IS - B5 SP - 452 EP - 458 PB - Elsevier CY - Amsterdam AN - OPUS4-11176 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Reiche, I. A1 - Berger, Achim A1 - Duval, A. A1 - Görner, Wolf A1 - Guicharnaud, H. A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich T1 - Traces of Albrecht Dürer: Non-destructive analyses of Renaissance silverpoint drawings T2 - Analytical applications of nuclear techniques KW - Nuclear industry KW - Nuclear medicine PY - 2004 SN - 92-0-114703-1 SN - 0074-1876 IS - 1181 SP - 138 EP - 142 PB - IAEA CY - Vienna AN - OPUS4-5548 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wondraczek, L. A1 - Reinsch, Stefan A1 - Gaber, Martin A1 - Deubener, J. A1 - Müller, Ralf A1 - Komatsu, T. T1 - Nano-crystalline germanate glass-ceramics T2 - Kurzreferate / 78. Glastechnische Tagung T2 - 78. Glastechnische Tagung CY - Nürnberg, Deutschland DA - 2004-06-07 PY - 2004 SP - 37 EP - 40 PB - Deutsche Glastechnische Gesellschaft CY - Offenbach AN - OPUS4-6953 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bär, S. A1 - Huber, G. A1 - Gonzalo, J. A1 - Perea, A. A1 - Munz, Martin T1 - Pulsed laser deposition of EU - Y2O3 thin films on (0001) alpha-Al2O3 JF - Applied physics A N2 - This paper focuses on the preparation and characterization of crystalline thin films of rare-earth-doped sesquioxides (Y2O3, Lu2O3) grown by pulsed laser deposition on single-crystal (0001) sapphire substrates. X-ray diffraction measurements show that the films with thicknesses between 1 nm and 500 nm were highly textured along the 111 direction. Using Rutherford backscattering analysis, the correct stoichiometric composition of the films was established. The emission and excitation spectra of europium-doped films with a thickness 100 nm look similar to those of the corresponding crystalline bulk material, whereas films with a thickness 20 nm show a completely different emission behavior. KW - Pulsed laser deposition KW - Integrated optical devices KW - X-ray diffraction KW - Atomic force microscopy KW - Luminescence PY - 2004 UR - http://www.sciencedirect.com/science/journal/0926860X DO - https://doi.org/10.1007/s00339-004-3029-8 SN - 0947-8396 VL - 80 IS - 2 SP - 209 EP - 216 PB - Springer CY - Berlin AN - OPUS4-5990 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Horn, J. A1 - Dohle, H. A1 - Gersonde, Martin T1 - Schutzsalzverteilung in mechanisch vorbehandelten Fichtenmasten nach Kesseldrucktränkung JF - Holz als Roh- und Werkstoff PY - 1977 SN - 0018-3768 VL - 35 SP - 67 EP - 73 PB - Springer CY - Berlin AN - OPUS4-8725 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bunte, J. A1 - Barcikowski, S. A1 - Burmester, T. A1 - Püster, T. A1 - Hertwig, Andreas A1 - Kautek, Wolfgang A1 - Krüger, Jörg A1 - Martin, Sven A1 - Spielmann, C. A1 - Lenner, M. A1 - Brose, M. T1 - Sicherer Umgang mit Ultrakurzpuls-Lasern, Teil 2: Sekundäre Gefährdungen JF - Laser-Magazin PY - 2005 SN - 0945-8875 IS - 4 SP - 13 EP - 18 PB - Magazin-Verl. CY - Bad Nenndorf AN - OPUS4-11002 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bunte, J. A1 - Barcikowski, S. A1 - Burmester, T. A1 - Püster, T. A1 - Hertwig, Andreas A1 - Kautek, Wolfgang A1 - Krüger, Jörg A1 - Martin, Sven A1 - Spielmann, C. A1 - Lenner, M. A1 - Brose, M. T1 - Sicherer Umgang mit Ultrakurzpuls-Lasern, Teil 1: Primäre Gefährdungen JF - Laser-Magazin PY - 2005 SN - 0945-8875 IS - 2 SP - 6 EP - 11 PB - Magazin-Verl. CY - Bad Nenndorf AN - OPUS4-11001 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lenke, Karoline A1 - Schmidt, R. A1 - Märtin, J. A1 - Hoffmann, G. A1 - Cherif, C. T1 - Simulation of the yarn transportation dynamics in a warp knitting machine JF - Textile Research Journal N2 - To date, in the textile manufacturing process of warp knitting, trouble-shooting and process optimization mainly rely on empirical knowledge and experiments. This factor limits the achievable increase in productivity and quality. On the other hand, using simulations, different phenomena that affect the quality of the knitted fabric and the knitting process can be clarified in the run-up of the experiments. Consequently, an increase in quality and flexibility can be reached with reduced experimental effort. This paper presents a process simulation of the warp thread dynamics in the thread feeding system of a warp knitting machine. For this purpose, a continuum model of the warp thread that includes the spatial dynamics of the thread and the axial transport movement has been developed. KW - Simulation of yarn transportation KW - Yarn transportation model KW - Warp knitting machine KW - Continuum model KW - Process optimization KW - Knitting PY - 2013 DO - https://doi.org/10.1177/0040517512470197 SN - 0040-5175 N1 - Geburtsname von Lenke, Karoline: Metzkes, K. - Birth name of Lenke, Karoline: Metzkes, K. VL - 83 IS - 12 SP - 1251 EP - 1262 PB - Sage Publ. CY - London AN - OPUS4-28381 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kaiser, J. A1 - Szczerba, Wojciech A1 - Riesemeier, Heinrich A1 - Reinholz, Uwe A1 - Radtke, Martin A1 - Albrecht, M. A1 - Lu, Y. A1 - Ballauff, M. T1 - The structure of AuPd nanoalloys anchored on spherical polyelectrolyte brushes determined by x-ray absorption spectroscopy JF - Faraday discussions N2 - Well-defined and facetted bimetallic gold–palladium nanoalloys have been synthesized and anchored in spherical polyelectrolyte brushes (SPB) as composite particles (AuPd@SPB). These particles are better catalysts in aqueous phase than the pure metals. The atomistic arrangement of these nanoalloys has been analysed by extended X-ray absorption fine structure (EXAFS) spectroscopy at the Au–L3 and the Pd–K absorption edge. The samples with high amounts of gold appear as almost statistically mixed random alloys. Alloy compositions with less gold show slight enrichment of Pd at the surface of the particle. In addition, signals of non-metallic palladium appear at the Pd–K edge which indicate the presence of the Pd2+ species in addition to metallic palladium. The relation of these structural features to the catalytic activity is discussed. KW - EXAFS KW - Nanoalloys KW - Gold KW - Palladium KW - K-edge KW - L3-edge KW - HR-TEM KW - Synchrotron radiation KW - BAMline PY - 2013 DO - https://doi.org/10.1039/c3fd20132e SN - 1359-6640 SN - 1364-5498 VL - 162 SP - 45 EP - 55 PB - Soc. CY - Cambridge [u.a.] AN - OPUS4-28300 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rodrigues, M. A1 - Schreiner, M. A1 - Melcher, M. A1 - Guerra, M. A1 - Salomon, J. A1 - Radtke, Martin A1 - Alram, M. A1 - Schindel, N. T1 - Characterization of the silver coins of the Hoard of Becin by x-ray based methods JF - Nuclear instruments and methods in physics research B N2 - Four hundred sixteen silver coins stemming from the Ottoman Empire (16th and 17th centuries) were analyzed in order to confirm the fineness of the coinage as well as to study the provenance of the alloy used for the coins. As most of the coins showed the typical green patina on their surfaces due to corrosion processes which have led to the depletion of copper in the near-surface domains of the silver coins in comparison to their core composition, small samples by cutting splinters from the coins had to be taken, embedded in synthetic resin and cross-sectioned in order to investigate the true-heart metal composition. The type of the alloy was investigated as well as if coins minted in different locations demonstrated homogeneous traits concerning the predominant impurities which could suggest a common ore. Several X-ray based techniques (µ-XRF, µ-SRXRF and µ-PIXE) could be applied in order to determine the silver contents as well as the minor and trace elements. Finally, SEM/EDX was applied in order to study the homogeneity/heterogeneity of the coins and the presence of surface enrichments. In general, the silver content of the analyzed specimen varies between 90% and 95%. These outcomes have not supported the historical interpretations, which predict that during the period studied a debasement of approximately 44% of the silver content of the coins should have occurred. KW - PIXE KW - SRXRF KW - SEM/EDX KW - Silver coins PY - 2011 DO - https://doi.org/10.1016/j.nimb.2011.04.068 SN - 0168-583X SN - 1872-9584 VL - 269 IS - 24 SP - 3041 EP - 3045 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-25289 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Baytekin, H. Tarik A1 - Oran, Umut A1 - Theisen, J. A1 - Schmidt, Martin A1 - Unger, Wolfgang ED - Weckenmann, A. T1 - Validierte Messverfahren für die nichtgeometrische Größe Hydrophilie - Anwendung in der Mikrofluidik T2 - Abschlussbericht DFG Schwerpunktprogramm 1159 - Neue Strategien der Mess- und Prüftechnik für die Produktion von Mikrosystemen und Nanostrukturen T2 - Abschlusskolloquium DFG Schwerpunktprogramm 1159 - Neue Strategien der Mess- und Prüftechnik für die Produktion von Mikrosystemen und Nanostrukturen CY - Erlangen, Deutschland DA - 2010-10-06 PY - 2011 SN - 978-3-8440-0358-1 SN - 0945-0769 SP - 163 EP - 172 PB - Shaker Verlag GmbH AN - OPUS4-24827 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rodrigues, M. A1 - Schreiner, M. A1 - Melcher, M. A1 - Guerra, M. A1 - Salomon, J. A1 - Radtke, Martin A1 - Alram, M. A1 - Schindel, N. T1 - Analysis of the hoard of Becin using X-ray-based techniques JF - X-ray spectrometry N2 - Four hundred and sixteen silver coins stemming from the Ottoman Empire (16th and 17th centuries) were analyzed to confirm the fineness of the coinage as well as to study the provenance of the alloy used for the coins. As most of the coins showed the typical green patina on their surfaces due to corrosion processes that have led to the depletion of copper in the near surface domains of the silver coins in comparison to their core composition, small samples had to be taken, embedded in synthetic resin, and cross sectioned to investigate the true-heart metal composition. µ-synchrotron micro X-ray fluorescence analysis and µ-proton-induced X-ray emission were applied to determine the silver contents as well as the minor and trace elements. The type of the alloy was investigated as well as if coins minted in different locations demonstrated homogeneous traits concerning the predominant impurities (Au and Bi), which could suggest a common ore. Finally, energy-dispersive microanalysis in a scanning electron microscope was applied to study the homogeneity/heterogeneity of the coins and the presence of surface enrichments and to explain differences between the µ-synchrotron micro X-ray fluorescence analysis and µ-proton-induced X-ray emission measurements concerning the main component. In general, the silver content of the analyzed specimen varies between 90 and 95%. These outcomes have not supported the historical interpretations, which predict that during the period studied, a debasement of approximately 44% of the silver content of the coins should have occurred. KW - SRXRF KW - Silber KW - BAMline PY - 2012 DO - https://doi.org/10.1002/xrs.2415 SN - 0049-8246 VL - 41 IS - 6 SP - 416 EP - 424 PB - Wiley CY - Chichester AN - OPUS4-27723 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Constantinescu, B. A1 - Bugoi, R. A1 - Cojocaru, V. A1 - Radtke, Martin A1 - Calligaro, T. A1 - Salomon, J. A1 - Pichon, L. A1 - Röhrs, S. A1 - Ceccato, D. A1 - Oberländer-Târnoveanu, E. T1 - Micro-SR-XRF and micro-PIXE studies for archaeological gold identification - The case of Carpathian (Transylvanian) gold and of Dacian bracelets JF - Nuclear instruments and methods in physics research B N2 - Trace-elements are more significant for provenancing archaeological metallic artifacts than the main components. For gold, the most promising elements are platinum group elements (PGE), Sn, Te, Sb, Hg and Pb. Several small fragments of natural Transylvanian gold – placer and primary – were studied by using micro-PIXE technique at the Legnaro National Laboratory AN2000 microbeam facility, Italy and at the AGLAE accelerator, C2RMF, Paris, France and by using micro synchrotron radiation X-ray fluorescence (micro-SR-XRF) at BESSY synchrotron, Berlin, Germany. The goal of the study was to identify the trace-elements, especially Sn, Sb and Te. A spectacular application to five Dacian gold bracelets authentication is presented (Sn and Sb traces). KW - Micro-PIXE KW - Micro-SR-XRF KW - Gold KW - Dacian bracelets KW - Transylvania PY - 2008 DO - https://doi.org/10.1016/j.nimb.2008.03.054 SN - 0168-583X SN - 1872-9584 VL - 266 IS - 10 SP - 2325 EP - 2328 PB - Elsevier CY - Amsterdam AN - OPUS4-17736 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Schoßig, Jörg A1 - Schmidt, Martin A1 - Krause, Ulrich A1 - Steinbach, J. T1 - Validierung von formalkinetischen Größen aus der adiabaten Warmlagerung T2 - 9. Fachtagung Anlagen-, Arbeits- und Umweltsicherheit T2 - 9. Fachtagung "Anlagen-, Arbeits- und Umweltsicherheit" CY - Köthen, Deutschland DA - 2008-11-06 KW - Anlagensicherheit KW - Umweltschutz KW - Sicherheitstechnik KW - Explosionsschutz PY - 2008 SN - 978-3-89746-099-7 SP - 1 EP - 3 PB - VDI, Hallescher Bezirksverein CY - Halle AN - OPUS4-18427 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Reiche, I. A1 - Berger, Achim A1 - Duval, A. A1 - Görner, Wolf A1 - Guicharnaud, H. A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich A1 - Roth, M. ED - Denker, A. ED - Adriaens, A. ED - Dowsett, M. ED - Giumlia-Mair, A. T1 - Synchrotron radiation and protons on the traces of famous artists - Non-destructive analyses of silverpoint drawings by Albrecht Dürer T2 - COST Action G8 KW - X-ray spectrometry KW - XRF KW - Röntgenfluoreszenzanalyse KW - RFA KW - Silverpoint drawing KW - Silberstiftzeichnung PY - 2006 SN - 3-8167-7178-5 SP - 91 EP - 101 PB - Fraunhofer-IRB-Verl. CY - Stuttgart AN - OPUS4-14190 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Görner, Wolf A1 - Berger, Achim A1 - Merchel, Silke A1 - Pernicka, E. A1 - Radtke, Martin A1 - Reiche, I. A1 - Reinholz, Uwe A1 - Riederer, J. A1 - Riesemeier, Heinrich A1 - Wunderlich, C. H. T1 - Kunst- und Kulturgüter unter "Beschuss" T2 - ZfP in Forschung, Entwicklung und Anwendung - Jahrestagung 2004 T2 - Jahrestagung Zerstörungsfreie Materialprüfung 2004 CY - Salzburg, Österreich DA - 2004-05-17 KW - SY-RFA KW - PIXE KW - PIGE KW - PAA KW - Zerstörungsfreie Analyse KW - Silberstiftzeichnungen KW - Himmelsscheibe von Nebra KW - Indische Moghulmalereien PY - 2004 UR - http://www.ndt.net/article/dgzfp04/papers/p46/p46.htm SN - 3-931381-55-2 SP - 1(?) EP - 11(?) PB - DGZfP CY - Berlin AN - OPUS4-6897 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reiche, I. A1 - Berger, Achim A1 - Görner, Wolf A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich A1 - Roth, M. T1 - Following the traces of Albrecht Dürer: analysis of silverpoint drawings by spatially resolved synchrotron-induced X-ray fluorescence analysis JF - Nuclear instruments and methods in physics research B N2 - Spatially resolved X-ray fluorescence analysis using synchrotron radiation (SR-XRF) at the wavelength shifter beamline, BAMline, at BESSY was used to investigate Renaissance silverpoint drawings as it is extremely sensitive, non-destructive and can be carried out in air using an excitation spot in the hundred micrometer range. This paper deals with first results of the study of silverpoint drawings of Albrecht Dürer (1471–1528) belonging to the sketchbook that Albrecht Dürer used during a travel to the Netherlands in 1520/21. These results are compared to a PIXE study performed on drawings from the same sketchbook. The minor element composition of the silverpoint used for the drawings in the sketchbook was (10.6 ± 3.5) wt.% of Cu and traces of Zn. Mercury was found in the marks but does not belong to the initial composition of the silverpoint as it is attributed to an alteration phenomenon. One drawing of the sketchbook represents an exception. It consists of silver marks containing an additional minor element, Zn, in the marks and was, therefore, created with another silverpoint, probably at a different time than the other drawings. KW - Synchrotron KW - SR-XRF analysis KW - Drawing KW - Silverpoint KW - Albrecht Dürer PY - 2004 DO - https://doi.org/10.1016/j.nimb.2004.03.081 SN - 0168-583X SN - 1872-9584 VL - 226 IS - 1-2 SP - 83 EP - 91 PB - Elsevier CY - Amsterdam AN - OPUS4-4574 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reiche, I. A1 - Radtke, Martin A1 - Berger, Achim A1 - Görner, Wolf A1 - Ketelsen, T. A1 - Merchel, Silke A1 - Riederer, J. A1 - Riesemeier, Heinrich A1 - Roth, M. T1 - Spatially resolved synchrotron-induced X-ray fluorescence analyses of metal point drawings and their mysterious inscriptions JF - Spectrochimica acta B N2 - Synchrotron-induced X-ray fluorescence (Sy-XRF) analysis was used to study the chemical composition of precious Renaissance silverpoint drawings. Drawings by famous artists such as Albrecht Dürer (1471–1528) and Jan van Eyck (approximately 1395–1441) must be investigated non-destructively. Moreover, extremely sensitive synchrotron- or accelerator-based techniques are needed since only small quantities of silver are deposited on the paper. New criteria for attributing these works to a particular artist could be established based on the analysis of the chemical composition of the metal points used. We illustrate how analysis can give new art historical information by means of two case studies. Two particular drawings, one of Albrecht Dürer, showing a profile portrait of his closest friend, “Willibald Pirckheimer” (1503), and a second one attributed to Jan van Eyck, showing a “Portrait of an elderly man”, often named “Niccolò Albergati”, are the object of intense art historical controversy. Both drawings show inscriptions next to the figures. Analyses by Sy-XRF could reveal the same kind of silverpoint for the Pirckheimer portrait and its mysterious Greek inscription, contrary to the drawing by Van Eyck where at least three different metal points were applied. Two different types of silver marks were found in this portrait. Silver containing gold marks were detected in the inscriptions and over-subscriptions. This is the first evidence of the use of gold points for metal point drawings in the Middle Ages. KW - Sy-XRF analysis KW - Drawing KW - Metal point KW - Albrecht Dürer KW - Jan van Eyck KW - Renaissance PY - 2004 DO - https://doi.org/10.1016/j.sab.2004.07.023 SN - 0584-8547 SN - 0038-6987 VL - 59 IS - 10-11 SP - 1657 EP - 1662 PB - Elsevier CY - Amsterdam AN - OPUS4-4575 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Reiche, I. A1 - Berger, Achim A1 - Bevers, H. A1 - Dupuis, G. A1 - Duval, A. A1 - Görner, Wolf A1 - Guicharnaud, H. A1 - Merchel, Silke A1 - Radtke, Martin A1 - Riederer, J. A1 - Riesemeier, Heinrich A1 - Roth, M. T1 - Spatially resolved SR-XRF analyses of complex drawings by the Holbein family and silverpoint drawings by Rembrandt T2 - BESSY highlights - annual report 2004 KW - X-ray spectrometry KW - XRF KW - Röntgenfluoreszenzanalyse KW - RFA KW - Silverpoint drawing KW - Silberstiftzeichnung PY - 2005 UR - http://www.helmholtz-berlin.de/media/media/oea/web/pr_webseite/druckschriften/berichte/bessy/annualreport2004.pdf#page=491 SN - 0179-4159 SP - 491 EP - 493 PB - Berliner Elektronenspeicherring-Gesellschaft für Synchrotronstrahlung CY - Berlin AN - OPUS4-7380 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kluge, Martin A1 - Krause, Heike A1 - Schröder, Volkmar A1 - Acikalin, Hatice Aydan A1 - Steinbach, J. T1 - Study of a self heating process of tetrafluoroethylene by the exothermic dimerization reaction to octafluorocyclobutane T2 - COMSOL Conference, November 4-6, 2008, Hannover, Germany (Proceedings) T2 - COMSOL Conference CY - Hannover, Germany DA - 2008-11-04 KW - Self heating KW - Free convection KW - Reactive flow KW - Gas reaction PY - 2008 SN - 978-09766792-8-8 N1 - Geburtsname von Kluge, Martin: Beckmann-Kluge, M. - Birth name of Kluge, Martin: Beckmann-Kluge, M. SP - 1 EP - 7 AN - OPUS4-18611 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Everard, C.D. A1 - Finnan, J. A1 - McDonnell, K.P. A1 - Schmidt, Martin T1 - Evaluation of self-heating in Miscanthus x giganteus energy crop clamps and the implications for harvesting time JF - Energy N2 - Miscanthus x giganteus energy crop grown in Ireland was harvested on 21st of February and 28th of March 2012 to examine the effects of harvesting time on self-heating during storage of Miscanthus chips in clamps (98 m³) under weather sheltered conditions. There was a relatively large difference in moisture content, of 21.4%, between Miscanthus crop harvested in February and March (41.6 and 20.2%, respectively). Temperature evolution over a storage period of up to 125 days was monitored at different heights and distances from the centre within the clamps. Maximum temperature in the February constructed clamp reached 69 °C compared to 28 °C in the March constructed clamp. Microbial activity was monitored via carbon dioxide and oxygen gas measurements. The high moisture clamp showed higher microbial activity and a volume yield loss of 4.3% due to decomposition in the top section of the clamp. Quality indices post-storage were also assessed. Calorific values from Miscanthus sampled 1 m below the top surface were similar after storage for both February and March constructed clamps, i.e. 18.52 and 18.70 MJ kg-1, respectively. A reliable assessment of self-heating in Miscanthus chip clamps has important consequences for both self-ignition risk and biomass quality. KW - Self-heating KW - Miscanthus x giganteus KW - Biomass storage KW - Self-ignition KW - Biomass quality PY - 2013 DO - https://doi.org/10.1016/j.energy.2013.06.022 SN - 0360-5442 VL - 58 SP - 350 EP - 356 PB - Elsevier CY - Amsterdam [u.a.] AN - OPUS4-29054 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bentrup, U. A1 - Radnik, J. A1 - Armbruster, U. A1 - Martin, A. A1 - Leiterer, Jork A1 - Emmerling, Franziska A1 - Brückner, A. T1 - Linking simultaneous in situ WAXS/SAXS/Raman with Raman/ATR/UV-vis spectroscopy: comprehensive insight into the synthesis of molybdate catalyst precursors JF - Topics in catalysis N2 - A new setup is presented which enables simultaneous wide- and small-angle X-ray scattering (WAXS/SAXS) and Raman spectroscopic experiments during the synthesis of Mo-based mixed oxide catalyst precursors at the µ-spot beamline at the Berliner Elektronenspeicherring-Gesellschaft für Synchrotronstrahlung (BESSY). Furthermore, we report about the separate monitoring of the same reactions under comparable conditions by simultaneous combined ATR/UV–vis/Raman spectroscopic measurements. For testing the performance of both experimental setups two syntheses were described comprising the precipitation of metal molybdates by mixing solutions of metal nitrates and ammonium heptamolybdate. Additionally, the effect of H3PO4 admixture on precipitation was investigated. The combined evaluation of spectroscopic and WAXS/SAXS data allows the discrimination between different molybdate species appearing in solution and precipitate. Furthermore, these molybdate species could be assigned to separate phases of different crystallinity. KW - In situ KW - WAXS/SAXS KW - Raman KW - ATR KW - UV-vis KW - Mixed oxide catalyst KW - Synthesis PY - 2009 DO - https://doi.org/10.1007/s11244-009-9309-y SN - 1022-5528 VL - 52 IS - 10 SP - 1350 EP - 1359 PB - Springer Science + Business Media CY - Dordrecht AN - OPUS4-19794 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Brücher, M. A1 - von Bohlen, A. A1 - Jacob, P. A1 - Franzke, J. A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Müller, Bernd R. A1 - Scharf, Oliver A1 - Hergenröder, R. T1 - The charge of solid-liquid interfaces measured by X-ray standing waves and streaming current JF - ChemPhysChem : a European journal of chemical physics and physical chemistry N2 - Measurements of ion distributions at a charged solid–liquid interface using X-ray standing waves (XSW) are presented. High energy synchrotron radiation (17.48 keV) is used to produce an XSW pattern inside a thin water film on a silicon wafer. The liquid phase is an aqueous solution containing Br and Rb ions. The surface charge is adjusted by titration. Measurements are performed over a pH range from 2.2–9, using the native Si oxide layer and functional (amine) groups as surface charge. The Debye length, indicating the extension of the diffuse layer, could be measured with values varying between 1–4 nm. For functionalized wafers, the pH dependent change from attraction to repulsion of an ion species could be detected, indicating the isoelectric point. In combination with the measurement of the streaming current, the surface charge of the sample could be quantified. KW - Interfacial charge KW - Solid/liquid interfaces KW - Surface analysis KW - Surface functionalization KW - X-ray spectrometry KW - X-ray KW - Standing waves KW - XSW KW - Streaming current KW - Synchrotron radiation PY - 2010 DO - https://doi.org/10.1002/cphc.201000166 SN - 1439-4235 SN - 1439-7641 VL - 11 IS - 10 SP - 2118 EP - 2123 PB - Wiley-VCH Verl. CY - Weinheim AN - OPUS4-22057 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rodrigues, M. A1 - Schreiner, M. A1 - Mäder, M. A1 - Melcher, M. A1 - Guerra, M. A1 - Salomon, J. A1 - Radtke, Martin A1 - Alram, M. A1 - Schindel, N. T1 - The hoard of Becin - non-destructive analysis of the silver coins JF - Applied physics A N2 - We report the results of an analytical investigation on 416 silver-copper coins stemming from the Ottoman Empire (end of 16th and beginning of 17th centuries), using synchrotron micro X-ray fluorescence analysis (SRXRF). In the past, analyses had already been conducted with energy dispersive X-ray fluorescence analysis (EDXRF), scanning electron microscopy with energy dispersive X-ray spectrometry (SEM/EDX) and proton induced X-ray emission spectroscopy (PIXE).With this combination of techniques it was possible to confirm the fineness of the coinage as well as to study the provenance of the alloy used for the coins. For the interpretation of the data statistical analysis (principal component analysis—PCA) has been performed. A definite local assignment was explored and significant clustering was obtained regarding the minor and trace elements composing the coin alloys. KW - SRXRF KW - Silber KW - Archaeometrie PY - 2010 DO - https://doi.org/10.1007/s00339-010-5627-y SN - 0947-8396 VL - 99 IS - 2 SP - 351 EP - 356 PB - Springer CY - Berlin AN - OPUS4-23170 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Constantinescu, B. A1 - Bugoi, R. A1 - Cojocaru, V. A1 - Radtke, Martin A1 - Calligaro, T. A1 - Salomon, J. A1 - Pichon, L. A1 - Röhrs, S. A1 - Ceccato, D. A1 - Oberländer-Târnoveanu, E. A1 - Ionescu, C. A1 - Pop, D. T1 - Dacian bracelets and Transylvanian gold: ancient history and modern analyses JF - ArcheoSciences KW - SRXRF KW - Gold KW - Archaeometrie KW - Authentication KW - Provenance KW - XRF KW - Micro-PIXE KW - Micro SR-XRF KW - Or KW - Authentification KW - FX PY - 2009 SN - 0399-1237 VL - 33 SP - 221 EP - 225 PB - Groupe CY - Rennes AN - OPUS4-23172 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Williams, S. H. A1 - Hilger, A. A1 - Kardjilov, N. A1 - Manke, I. A1 - Strobl, M. A1 - Douissard, P.A. A1 - Martin, T. A1 - Riesemeier, Heinrich A1 - Banhart, J. T1 - Detection system for microimaging with neutrons JF - Journal of Instrumentation N2 - A new high-resolution detector setup for neutron imaging has been developed based on infinity-corrected optics with high light collection, combined with customized mounting hardware. The system can easily be installed, handled and fitted to any existing facility, avoiding the necessity of complex optical systems or further improved electronics (CCD). This is the first time optical magnification higher than 1:1 has been used with scintillator-based neutron detectors, as well as the first implementation of infinity corrected optics for neutron imaging, achieving the smallest yet reported effective pixel size of 3.375 µm. A novel transparent crystal scintillator (GGG crystal) has been implemented with neutrons for the first time to overcome limitations of traditional powder scintillators (Li6/ZnS, Gadox). The standardized procedure for resolution measurements with the Modulation Transfer Function (MTF) is summarized to facilitate comparison between instruments and facilities. Using this new detector setup, a resolution of 14.8 µm with a field of view of 6 mm × 6 mm has been achieved while maintaining reasonable count times. These advances open a wide range of new possible research applications and allow the potential for additional future developments. KW - Instrumentation for neutron sources KW - Neutron radiography KW - Neutron detectors (cold, thermal, fast neutrons) PY - 2012 DO - https://doi.org/10.1088/1748-0221/7/02/P02014 SN - 1748-0221 VL - 7 IS - P02014 SP - 1 EP - 26 PB - Inst. of Physics Publ. CY - London AN - OPUS4-26433 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lilensten, L. A1 - Provost, K. A1 - Perrière, L. A1 - Fonda, E. A1 - Couzinié, J. A1 - Amman, F. A1 - Radtke, Martin A1 - Dirras, G. A1 - Guillot, I. T1 - Experimental investigation of the local environment and lattice distortion in refractory medium entropy alloys JF - Scripta Materialia N2 - EXAFS analysis of pure elements, binary and ternary equiatomic refractory alloys within the Nb-Zr-Ti-Hf- Ta system is performed at the Nb and Zr K-edges to analyze the evolution of the chemical local environ- ment and the lattice distortion. A good mixing of the elements is found at the atomic scale. For some compounds, a distribution of distances between the central atom and its neighbors suggests a distortion of the structure. Finally, analysis of the Debye-Waller parameters shows some correlation with the lat- tice distortion parameter δ², and allows to quantify experimentally the static disorder in medium entropy alloys. KW - BAMline KW - Refractory alloys KW - EXAFS KW - Debye-Waller parameter PY - 2022 DO - https://doi.org/10.1016/j.scriptamat.2022.114532 SN - 1359-6462 VL - 211 SP - 1 EP - 6 PB - Elsevier Ltd. AN - OPUS4-55287 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Margreiter, R. A1 - Baumann, J. A1 - Mantouvalou, I. A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Strub, E. T1 - Investigations on fire-gilding JF - Archaeometry N2 - Fire-gilding is a historic technique for the application of golden layers on a number of different base materials utilizing a gold amalgam. This technique leaves a significant amount of Hg in the golden layer, giving archeometrists a reliable indicator to identify firegildings. Recent findings on presumably fire-gilded objects have shown in several cases significantly lower Hg content than previously studied objects. This prompted a synchrotron-based X-ray fluorescence investigation into the Hg distribution along the material–gilding interface, as well as a series of measurements regarding the Hg content development in fire-gilded samples during artificial aging. This work presents findings on laboratory-prepared fire-gildings, indicating an Hg enrichment at the interface of firegilded silver samples. Notably, such an enrichment is missing in fire-gilded copper samples. Further, it is confirmed that fire-gilded layers typically do not undercut an Hg bulk content of 5%. In this light, it seems improbable that ancient samples that contain <5% Hg are fire-gilded. The results presented in this study might lead to a non-destructive method to identify the Hg enrichment at the interface. This might be obtained by a combination of different non-destructive measurements and might also work unambiguously in samples in which the gold top layer is altered. KW - BAMline KW - X-Ray Fluorescence KW - Gilding KW - Depth profile KW - Archaeometry PY - 2022 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-552885 DO - https://doi.org/10.1111/arcm.12797 SN - 0003-813X SP - 1 EP - 14 PB - Wiley online library AN - OPUS4-55288 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Emamverdi, Farnaz A1 - Yin, Huajie A1 - Smales, Glen Jacob A1 - Harrison, W. J. A1 - Budd, P. M. A1 - Böhning, Martin A1 - Schönhals, Andreas T1 - Polymers of intrinsic microporosity - Molecular mobility and physical aging revisited by dielectric spectroscopy and X‑ray scattering JF - Macromolecules N2 - Polymers of intrinsic microporosity (PIMs) are promising candidates for the active layer in gas separation membranes due to their high permeability and reasonable permselectivity. These appealing properties originate from a microporous structure as a result of inefficient segment packing in the condensed state due to a combination of a ladder-like rigid backbone and sites of contortion. However, this class of polymers suffers from a significant decrease in the permeability with time due to physical aging, whereby typically, the permselectivity increases. The initial microporous structures approach a denser state via local rearrangements, leading to the reduction of the permeability. Hence, a detailed characterization of the molecular mobility in such materials can provide valuable information on physical aging. In this work, the dielectric behavior of PIM-1 films and their behavior upon heating (aging) were revisited by isothermal frequency scans during different heating/cooling cycles over a broad temperature range between 133 and 523 K (−140 to 250 °C). In addition, the obtained results were compared with data of samples that were annealed at ambient temperatures over different time scales. Multiple dielectric processes were observed: several relaxation processes due to local fluctuations and a Maxwell−Wagner−Sillars polarization effect related to the microporosity. The temperature dependence of the rates of all processes follows the Arrhenius law where the estimated activation energy depends on the nature of the process. The influence of the thermal history (aging) on the processes is discussed in detail. KW - Polymers of intrinsic microporosity PY - 2022 DO - https://doi.org/10.1021/acs.macromol.2c00934 VL - 55 SP - 7340 EP - 7350 PB - American Chemical Society CY - Washington, DC AN - OPUS4-55485 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ried, Peter A1 - Gaber, Martin A1 - Müller, Ralf A1 - Deubener, J. T1 - Hydrogen permeability of a barium-aluminoborosilicate glass - A methodical approach JF - Journal of non-crystalline solids N2 - The H2 effusion from H2 saturated glass powders, H2 permeation through the wall of blown glass bulbs, and H2 permeation through the wall of glass capillaries were applied to evaluate the permeability of hydrogen gas in a barium-aluminoborosilicate (BABS) glass. To validate these methods, two commercial glasses (vitreous silica and borosilicate) were used as a reference. Permeation values obtained from the different experiments agreed within a factor of 3 or less. The H2 permeability of BABS glass at temperatures close to ambient was found to be at least 3 orders of magnitude below that of borosilicate and silica glasses. The powder method, which requires minimal sample preparation efforts, turned out to provide easy access to the measurement of H2 permeability of glasses down to P = 3.9 × 10- 21 mol s- 1 Pa- 1 m- 1. KW - Hydrogen gas KW - Permeability KW - Solubility KW - Diffusivity KW - Aluminoborosilicate glass PY - 2014 DO - https://doi.org/10.1016/j.jnoncrysol.2014.04.006 SN - 0022-3093 VL - 394-395 SP - 43 EP - 49 PB - North-Holland Publ. Co. CY - Amsterdam AN - OPUS4-30720 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Krause, Martin A1 - Dackermann, U. A1 - Li, J. T1 - Elastic wave modes for the assessment of structural timber: ultrasonic echo for building elements and guided waves for pole and pile structures JF - Journal of civil structural health monitoring N2 - This paper presents the state-of-the-art of using non-destructive testing (NDT) methods based on elastic waves for the condition assessment of structural timber. Two very promising approaches based on the propagation and reflections of elastic waves are described. While the first approach uses ultrasonic echoes for the testing of wooden building elements, the second approach uses guided waves (GW) for the testing of timber pole and pile structures. The basic principle behind both approaches is that elastic waves induced in a timber structure will propagate through its material until they encounter a change in stiffness, cross-sectional area or density, at which point they will reflect back. By measuring the wave echoes, it is possible to determine geometric properties of the tested structures such as the back wall of timber elements or the underground length of timber poles or piles. In addition, the internal state of the tested structures can be assessed since damage and defects such as rot, fungi or termite attacks will cause early reflections of the elastic waves as well as it can result in changes in wave velocity, wave attenuation and wave mode conversion. In the paper, the principles and theory of using elastic wave propagation for the assessment of wooden building elements and timber pole/pile structures are described. The state-of-the-art in testing equipment and procedures is presented and detailed examples are given on the practical application of both testing approaches. Recent encouraging developments of cutting edge research are presented along with challenges for future research. KW - Elastic wave KW - Ultrasonic echo KW - SAFT (synthetic aperture focusing technique) KW - Guided wave KW - Timber structure KW - Timber pole KW - Impulse response KW - Condition assessment KW - Timber KW - Non-destructive testing KW - Ultrasouind PY - 2014 DO - https://doi.org/10.1007/s13349-014-0087-2 SN - 2190-5452 SN - 2190-5479 VL - 5 IS - 2 SP - 221 EP - 249 PB - Springer CY - Berlin; Heidelberg AN - OPUS4-31867 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Matthies, Klaus A1 - Erhard, Anton A1 - Ernst, h. A1 - Hübschen, G. A1 - Just, Tilman A1 - Völz, Uwe A1 - Wessels, J. A1 - Boehm, Rainer A1 - Gebhardt, W. A1 - Mrasek, Heinz A1 - Neumann, Eberhard A1 - Redmer, Bernhard A1 - Schmitz, V. A1 - Thomas, Hans-Martin A1 - Walte, F. T1 - Ultraschallprüfung von austenitischen Werkstoffen T2 - Ultraschallprüfung von austenitischen Werkstoffen PY - 2009 SN - 978-3-87155-988-4 IS - 1. Aufl. SP - 1 EP - 464 PB - DVS-Verl. CY - Berlin AN - OPUS4-19897 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - García, O. A1 - Rz-Maribona, I. A1 - Gardei, André A1 - Riedl, Martin A1 - Vanhellemont, Y. A1 - Santarelli, M.L. A1 - Strupi Suput, J. T1 - Comparative study of the variation or the hydric properties and aspect of natural stone and brick after the application of 4 types of anti-graffiti JF - Materiales de construcción N2 - In this article a comparative study of the behaviour of different commercial anti-graffiti on natural stone and brick is presented. 8 different European substrates were selected and 4 commercial anti-graffiti of different chemical nature were applied on these substrates. The variations of their hydric properties and aspect (colour and gloss) with regard to the untreated substrates were later studied in the laboratory. The results obtained permitted to assess the suitability of 4 of the main types of chemical formulations employed to be used as anti-graffiti. This study concludes that the sacrificial anti-graffiti with polymeric paraffins in its composition presents the lowest reductions of the hydric properties of the studied substrates, being also the variations in colour the least perceptible. KW - Graffiti KW - Sandstone KW - Limestone KW - Natural stone KW - Brick KW - Anti-graffiti KW - Porous substrates KW - Surface treatments KW - Anti-graffiti coatings KW - Hydric properties KW - Colour KW - Gloss PY - 2010 DO - https://doi.org/10.3989/mc.2010.45507 SN - 0465-2746 N1 - Sprachen: Spanisch/Englisch - Languages: Spanish/English VL - 60 IS - 297 SP - 1 EP - 14 CY - Madrid AN - OPUS4-21087 LA - mul AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kus, J. A1 - Kaufhold, S. A1 - Klosa, D. A1 - Jianwei, M. A1 - Schmidt, Martin A1 - Suhendra, Suhendra T1 - Coal fire geothermometer: Controlling the extent and temperature field of underground coal fire zones T2 - Latest developments in coal fire research - Bridging the science, economics, and politics of a global disaster / ICCFR2 T2 - 2nd International conference on coal fire research (ICCFR2) CY - Berlin, Germany DA - 2010-05-19 KW - Coal fires KW - Coal petrography KW - Coal mineralogy PY - 2010 SN - 978-3-86012-397-3 IS - Part 2 - Geosciences SP - 75 EP - 85 AN - OPUS4-21459 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Fischer, C. A1 - Wu, J. A1 - Meyer, U. A1 - Kong, B. A1 - Schmidt, Martin A1 - Wuttke, M. A1 - Drebenstedt, C. A1 - Barth, Uli A1 - Rüter, H. T1 - Eight years of successful bilateral cooperation: Milestones of sino-german research T2 - Latest developments in coal fire research - Bridging the science, economics, and politics of a global disaster / ICCFR2 T2 - 2nd International conference on coal fire research (ICCFR2) CY - Berlin, Germany DA - 2010-05-19 KW - Underground coal fires KW - Sino-german cooperation PY - 2010 SN - 978-3-86012-397-3 IS - Introduction SP - 3 EP - 18 AN - OPUS4-21460 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Schoßig, Jörg A1 - Schmidt, Martin A1 - Krause, Ulrich A1 - Steinbach, J. T1 - Beurteilung des Selbstentzündungsverhaltens brennbarer Stäube mit Hilfe adiabatischer Warmlagerung T2 - 10. Fachtagung Anlagen-, Arbeits- und Umweltsicherheit T2 - 10. Fachtagung Anlagen-, Arbeits- und Umweltsicherheit CY - Köthen, Deutschland DA - 2010-11-04 KW - Anlagensicherheit KW - Umweltschutz KW - Sicherheitstechnik KW - Explosionsschutz PY - 2010 SN - 978-3-89746-119-2 SP - 1 EP - 7(?) CY - Frankfurt/M. AN - OPUS4-22621 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kluge, Martin A1 - Ferrero, Fabio A1 - Schröder, Volkmar A1 - Acikalin, Hatice Aydan A1 - Steinbach, J. T1 - Modellazione del processo di autoaccensione del TFE JF - ICP - Rivista dell'industria chimica KW - Convezione naturale (free convention) KW - Trasporto reattivo (reactive flow) KW - Reazione in fase gas (gas reaction) KW - Autoignizione (self-ignition) PY - 2011 SN - 0390-2358 N1 - Geburtsname von Kluge, Martin: Beckmann-Kluge, M. - Birth name of Kluge, Martin: Beckmann-Kluge, M. VL - 6 SP - 84 EP - 90 PB - ERIS CY - Milan AN - OPUS4-24094 LA - ita AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kluge, Martin A1 - Ferrero, Fabio A1 - Schröder, Volkmar A1 - Acikalin, Hatice Aydan A1 - Steinbach, J. T1 - Improvements in the modeling of the self ignition of tetrafluoroethylene T2 - COMSOL Conference 2010 (Proceedings) N2 - In order to prevent incidents in the industrial production of Teflon® from Tetrafluoroethylene (TFE), the safety related aspects of the self-heating process of TFE must be taken into account. Simulations of this self heating process were performed with COMSOL Reaction Engineering Lab® and COMSOL® COMSOL Multiphysics®. A complex reaction net was employed, resulting in a model allows for a good agreement with experimentally achieved results. T2 - COMSOL Conference 2010 CY - Paris, France DA - 2010-11-17 KW - Heating KW - Free convection KW - Reactive flow KW - Gas reaction KW - Self ignition PY - 2010 N1 - Geburtsname von Kluge, Martin: Beckmann-Kluge, M. - Birth name of Kluge, Martin: Beckmann-Kluge, M. SP - 1 EP - 7 AN - OPUS4-24174 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Martin A1 - Wu, D. A1 - Norman, F. A1 - Vanierschot, M. A1 - Verplaetsen, F. A1 - Berghmans, J. A1 - van den Bulck, E. T1 - Numerical investigation on the self-ignition behaviour of coal dust accumulations: The roles of oxygen, diluent gas and dust volume JF - FUEL 188 N2 - Self-ignition of coal dust deposits poses a higher risk of fires in oxygen-enriched oxy-fuel combustion systems. In this work, we develop a numerical method, using the commercial software COMSOL Multiphysics, to investigate self-ignition behaviour of coal dust accumulations with a main emphasis on the roles of oxygen, diluent gas and dust volume. A one-step 2nd-order reaction kinetic model considering both coal density and oxygen density is used to estimate reaction rate using the kinetic parameters from previously conducted hot-oven tests. This model is validated to predict the transient temperature and concentration profiles of South African coal dusts until ignition. The computed self-ignition temperatures of dust volumes show a good agreement with experimental results. In addition, it is found that the inhibiting effect of carbon dioxide is comparatively small and oxygen consumption increases dramatically after ignition. Parameter analysis shows that the heating value and kinetic parameters have a comparatively pronounced effect on self-ignition temperature. The model provides a satisfactory explanation for the dependence of self-ignition behaviour on gas atmospheres, thus helping to further understand the fire risk of self-ignition in oxy-fuel combustion systems. KW - Ignition temperature KW - Oxy-fuel combustion KW - Fire safety KW - Self-ignition KW - Numerical simulation PY - 2017 DO - https://doi.org/10.1016/j.fuel.2016.10.063 SN - 0016-2361 SP - 500 EP - 510 AN - OPUS4-37885 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Seewald, J.S. A1 - Reeves, E.P. A1 - Bach, W. A1 - Saccocia, P.J. A1 - Craddock, P.R. A1 - Shanks III, W.C. A1 - Sylva, S.P. A1 - Pichler, T. A1 - Rosner, Martin A1 - Walsh, E. T1 - Submarine venting of magmatic volatiles in the Eastern Manus Basin, Papua New Guinea JF - Geochimica et cosmochimica acta N2 - The SuSu Knolls and DESMOS hydrothermal fields are located in the back-arc extensional transform zone of the Eastern Manus Basin. In 2006, highly acidic and ΣSO4-rich vent fluids were collected at both sites and analyzed for the chemical and isotopic composition of major and trace species. Fluids exiting the seafloor have measured temperatures from 48 to 215 °C and are milky white in appearance due to precipitation of elemental S0. Vent fluid concentrations of Na, K, and Mg are depleted by as much as 30% relative to seawater, but have the same relative abundance. In contrast, the fluids are highly enriched in dissolved ΣCO2, Cl, SiO2(aq), Fe, and Al relative to seawater. Measured pH (25 °C) ranged from 0.95 to 1.87 and aqueous ΣSO4 ranged from 35 to 135 mmol/kg. The chemical and isotopic composition points to formation via subsurface mixing of seawater with a Na-, K-, Mg-, and Ca-free, volatile-rich magmatic fluid exsolved from subsurface magma bodies during a process analogous to subaerial fumarole discharge. Estimates of the magmatic end-member composition indicate a fluid phase where H2O > SO2 > CO2 ≈ Cl > F. The hydrogen and oxygen isotopic composition of H2O and carbon isotopic composition of ΣCO2 in the vent fluids strongly suggest a contribution of slab-derived H2O and CO2 to melts generated in the mantle beneath the Eastern Manus volcanic zone. Abundant magmatically-derived SO2 undergoes disproportionation during cooling in upflow zones and contributes abundant acidity, SO42-, and S0 to the venting fluids. Interaction of these highly acidic fluids with highly altered mineral assemblages in the upflow zone are responsible for extensive aqueous mobilization of SiO2(aq), Fe, and Al. Temporal variability in the speciation and abundance of aqueous S species between 1995 and 2006 at the DESMOS vent field suggests an increase in the relative abundance of SO2 in the magmatic end-member that has mixed with seawater in the subsurface. Results of this study constrain processes responsible for the formation of hot-spring fluids in magmatically active back-arc environments and the resulting chemical exchange between the lithosphere and water column. PY - 2015 DO - https://doi.org/10.1016/j.gca.2015.04.023 SN - 0016-7037 SN - 1872-9533 VL - 163 SP - 178 EP - 199 PB - Elsevier Science CY - New York, NY AN - OPUS4-33433 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Becker, D. A1 - Konnertz, Nora A1 - Böhning, Martin A1 - Schmidt, J. A1 - Thomas, A. T1 - Light-switchable polymers of intrinsic microporosity JF - Chemistry of Materials N2 - The interest in (micro)porous systems is greater than ever before with microporous polymers finding application in areas such as gas storage/separation and catalysis. In contrast to the vast majority of publications on microporous polymers seeking ever higher values for surface area or uptake capacity for a particular gas, this work presents a means to render a microporous system responsive to electromagnetic stimuli. The incorporation of a diarylethene (DAE) derivative in the backbone of a polymer of intrinsic microporosity (PIM) produces a microporous system that exhibits photochromism as proven by UV–vis absorption and NMR studies. In the resulting DAE-PIM, surface area is not a fixed unalterable property but can be influenced by the external and nondestructive stimulus light in a reversible manner. Furthermore, in combination with Matrimid, free-standing membranes can be produced that display light-switchable diffusivity and permeability for carbon dioxide and oxygen. In this way, material scientists are offered the potential to employ only one system that can assume several states with different properties for each. KW - Gaspermeation KW - Diffusion KW - Polymer intrinsischer Mikroporosität KW - UV-VIS PY - 2016 DO - https://doi.org/10.1021/acs.chemmater.6b02619 SN - 0897-4756 VL - 28 IS - 23 SP - 8523 EP - 8529 PB - ACS CY - Whashington,DC AN - OPUS4-38735 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nikolic, Nela A1 - Dal Co, Alma A1 - Kiviet, Daniel J. A1 - Bergmiller, Tobias A1 - Littmann, Sten A1 - Kuypers, Marcel M. M. A1 - Ackermann, Martin A1 - Schreiber, Frank T1 - Cell-to-cell variation and specialization in sugar metabolism in clonal bacterial populations JF - PLoS Genetics N2 - While we have good understanding of bacterial metabolism at the population level, we know little about the metabolic behavior of individual cells: do single cells in clonal populations sometimes specialize on different metabolic pathways? Such metabolic specialization could be driven by stochastic gene expression and could provide individual cells with growth benefits of specialization. We measured the degree of phenotypic specialization in two parallel metabolic pathways, the assimilation of glucose and arabinose. We grew Escherichia coli in chemostats, and used isotope-labeled sugars in combination with nanometer-scale secondary ion mass spectrometry and mathematical modeling to quantify sugar assimilation at the single-cell level. We found large variation in metabolic activities between single cells, both in absolute assimilation and in the degree to which individual cells specialize in the assimilation of different sugars. Analysis of transcriptional reporters indicated that this variation was at least partially based on cell-to-cell variation in gene expression. Metabolic differences between cells in clonal populations could potentially reduce metabolic incompatibilities between different pathways, and increase the rate at which parallel reactions can be performed. KW - Metabolism KW - Escherichia coli KW - Phenotypic diversity KW - Phenotypic heterogeneity PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-438873 UR - http://journals.plos.org/plosgenetics/article?id=10.1371/journal.pgen.1007122 DO - https://doi.org/10.1371/journal.pgen.1007122 SN - 1553-7404 VL - 13 IS - 12 SP - e1007122, 1 EP - e1007122, 24 PB - Public Library of Science CY - Cambridge, United Kingdom AN - OPUS4-43887 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Martin-Sanchez, Pedro Maria A1 - Gebhardt, Christopher A1 - Toepel, Jörg A1 - Barry, J. A1 - Munzke, N. A1 - Günster, Jens A1 - Gorbushina, Anna T1 - Monitoring microbial soiling in photovoltaic systems: A qPCR-based approach JF - International Biodeterioration & Biodegradation N2 - Soiling of photovoltaic (PV) systems compromises their performance causing a significant power loss and demanding periodical cleaning actions. This phenomenon raises great concerns in the solar energy field, thus leading to notable research efforts over the last decades. Soiling is caused by a dual action of dust deposition and biofouling. However, surprisingly, the microbiological contribution to PV soiling is often overlooked or underestimated. In this study, a variety of qPCR-based methods have been developed to quantify the microbial load of fungi, bacteria and phototrophs on PV panels. These protocols were evaluated by comparison with culturedependent methods, and were implemented with real solar plants for two years. The results show that the developed molecular methods are highly sensitive and reliable to monitor the microbial component of the soiling. Fungal biomass was clearly dominant in all analysed PV modules, while bacteria and phototrophs showed much lower abundance. Light microscopy and qPCR results revealed that melanised microcolonial fungi and phototrophs are the main biofilm-forming microorganisms on the studied solar panels. In particular, the fungal qPCR protocol is proposed as a useful tool for monitoring of PV soiling, and investigating the microbial contribution to specific soiling cases. KW - Solar panels KW - PV modules KW - Real-time qPCR KW - Bacteria KW - Fungi KW - Phototrophs PY - 2018 DO - https://doi.org/10.1016/j.ibiod.2017.12.008 SN - 0964-8305 VL - 129 SP - 13 EP - 22 PB - Elsevier Science AN - OPUS4-43892 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Everard, C.D. A1 - Schmidt, Martin A1 - McDonnell, K.P. A1 - Finnan, J. T1 - Heating processes during storage of Miscanthus chip piles and numerical simulations to predict self-ignition JF - Journal of loss prevention in the process industries N2 - Miscanthus x Giganteus (Miscanthus) energy crop was examined at laboratory scale to assess its self-heating and self-ignition risks during storage. Chipped Miscanthus (18 mm) from February and March harvests, in 2012, were assessed as well as ground Miscanthus (3 mm) from the March harvest. February and March crops had moisture contents of 41.6 and 20.2%, respectively. Self-ignition temperatures were independent of moisture although moisture did affect the time from the beginning of storage until storage temperature was reached. Ground Miscanthus had lower self-ignition temperatures than chipped Miscanthus. Isothermal respirometric tests carried out showed increase risk of self-heating in the February crop compared to the March crop due to increased microbial activity. Numerical simulations were used to determine critical enhanced start temperatures, e.g. caused by microbial decomposition, of the stored Miscanthus. Safe storage conditions have been derived from the investigations. The numerical simulations demonstrated that self-ignition was possible in Miscanthus chip piles with a height greater than 6 m if there was significant heat release from microbiological activity. Reliable assessment of self-heating and self-ignition risks in large scale Miscanthus energy crop clamps or piles are required to prevent losses due to decomposition and fire damage. KW - Miscanthus x Giganteus KW - Hot storage test KW - Respirometric rates KW - Self-heating KW - Self-ignition KW - Numerical simulations KW - Biomass storage PY - 2014 DO - https://doi.org/10.1016/j.jlp.2014.06.003 SN - 0950-4230 SN - 1873-3352 VL - 30 SP - 188 EP - 196 PB - Butterworth CY - Guildford, Surrey AN - OPUS4-31149 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - De Samber, B. A1 - Scharf, Oliver A1 - Buzanich, Günter A1 - Garrevoet, J. A1 - Tack, P. A1 - Radtke, Martin A1 - Riesemeier, Heinrich A1 - Reinholz, Uwe A1 - Evens, R. A1 - De Schamphelaere, K. A1 - Falkenberg, G. A1 - Janssen, C. A1 - Vincze, L. T1 - Three-dimensional X-ray fluorescence imaging modes for biological specimens using a full-field energy dispersive CCD camera JF - Journal of analytical atomic spectrometry N2 - Besides conventional scanning X-ray fluorescence imaging at synchrotron sources, full-field X-ray fluorescence (FF-XRF) imaging techniques that do not implicitly require spatial scanning of the sample have become available. FF-XRF has become achievable thanks to the development of a new type of energy dispersive CCD-based 2D detector, also referred to as a 'color X-ray camera (CXC)' or 'SLcam'. We report on different imaging schemes for biological samples using FF-XRF imaging: (a) 2D 'zoom' imaging with pinhole optics using the 'camera obscura' principle; (b) 2D 'fixed magnification' imaging using magnifying polycapillary optics; and (c) 3D-FF-XRF imaging using an X-ray sheet beam or computed tomography (CT). The different FF-XRF imaging modes are illustrated using the crustacean Daphnia magna, a model organism for investigating the effects of metals on organism/ecosystem health, and foraminifera, a class of amoeboid protist. Detailed analytical characterization of the set-up is performed through analyzing various reference materials in order to determine limits of detection (LODs) and sensitivities. Experiments were performed using the BAMline at the BESSY synchrotron (Berlin, Germany) and using the P06 Hard X-ray Microprobe at the PETRAIII synchrotron (Hamburg, Germany). KW - CXC KW - BAMline KW - Maia detector KW - Synchrotron PY - 2019 DO - https://doi.org/10.1039/c9ja00198k VL - 34 IS - 10 SP - 2083 EP - 2093 PB - Royal Society of Chemistry CY - Cambridge, United Kingdom AN - OPUS4-49359 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Neumann, Patrick P. A1 - Kohlhoff, Harald A1 - Hüllmann, Dino A1 - Krentel, Daniel A1 - Kluge, Martin A1 - Dzierliński, M. A1 - Lilienthal, A. J. A1 - Bartholmai, Matthias T1 - Aerial-based gas tomography – from single beams to complex gas distributions JF - European Journal of Remote Sensing N2 - In this paper, we present and validate the concept of an autonomous aerial robot to reconstruct tomographic 2D slices of gas plumes in outdoor environments. Our platform, the so-called Unmanned Aerial Vehicle for Remote Gas Sensing (UAV-REGAS), combines a lightweight Tunable Diode Laser Absorption Spectroscopy (TDLAS) gas sensor with a 3-axis aerial stabilization gimbal for aiming at a versatile octocopter. While the TDLAS sensor provides integral gas concentration measurements, it does not measure the distance traveled by the laser diode’s beam nor the distribution of gas along the optical path. Thus, we complement the set-up with a laser rangefinder and apply principles of Computed Tomography (CT) to create a model of the spatial gas distribution from a set of integral concentration measurements. To allow for a fundamental ground truth evaluation of the applied gas tomography algorithm, we set up a unique outdoor test environment based on two 3D ultrasonic anemometers and a distributed array of 10 infrared gas transmitters. We present results showing its performance characteristics and 2D plume reconstruction capabilities under realistic conditions. The proposed system can be deployed in scenarios that cannot be addressed by currently available robots and thus constitutes a significant step forward for the field of Mobile Robot Olfaction (MRO). KW - Aerial robot olfaction KW - Mobile robot olfaction KW - Gas tomography KW - TDLAS KW - Plume PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-487843 DO - https://doi.org/10.1080/22797254.2019.1640078 SP - 1 EP - 16 PB - Taylor & Francis CY - London AN - OPUS4-48784 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - De la Rosa, J. M. A1 - Martin-Sanchez, Pedro Maria A1 - Santiago-Cortes, S. A1 - Hermosin, B. A1 - Knicker, H. A1 - Saiz-Jimenez, C. ED - De la Rosa, J. M. T1 - Structure of melanins from the fungi Ochroconis lascauxensis and Ochroconis anomala contaminating rock art in the Lascaux Cave JF - Scientific Reports N2 - Two novel species of the fungal genus Ochroconis, O. lascauxensis and O. anomala have been isolated from the walls of the Lascaux Cave, France. The interest in these fungi and their melanins lies in the formation of black stains on the walls and rock art which threatens the integrity of the paintings. Here we report solid-state cross polarization magic-angle spinning 13C and 15N nuclear magnetic resonance (NMR) spectroscopy and surface-enhanced Raman spectroscopy (SERS) of the melanins extracted from the mycelia of O. lascauxensis and O. anomala in order to known their chemical structure. The melanins from these two species were compared with those from other fungi. The melanins from the Ochroconis species have similar SERS and 13C and 15N NMR spectra. Their chemical structures as suggested by the data are not related to 3,4-dihydroxyphenylalanine, 5,6-dihydroxyindole or 1,8-dihydroxynaphthalene precursors and likely the building blocks from the melanins have to be based on other phenols that react with the N-terminal amino acid of proteins. The analytical pyrolysis of the acid hydrolysed melanin from O. lascauxensis supports this assumption. KW - Microbiology KW - Biodeterioration KW - Melanins KW - Fungi PY - 2017 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-435345 DO - https://doi.org/10.1038/s41598-017-13862-7 SN - 2045-2322 VL - 7 SP - 13441, 1 EP - 13441, 11 PB - Nature AN - OPUS4-43534 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Martin A1 - Wu, D. A1 - Berghmans, J. T1 - Spontaneous ignition behaviour of coal dust accumulations: A comparison of extrapolation methods from lab-scale to industrial-scale JF - Proceedings of the Combustion Institute N2 - Smouldering fires and explosions arising from self-ignition of coal dust deposits represent a serious hazard for human being, environment and industry. It is essential for plant operators to know the conditions (temperature, duration and quantity) at which storage will be safe. In this work, self-ignition behaviour of three bituminous coal dusts in large scales are theoretically studied, based on the experimental data via a standardized hot-basket apparatus. A comprehensive 2-D transient model is developed, using a 2nd-order reaction kinetics considering both coal and oxygen consumptions, to investigate self-ignition parameters of coal dust accumulations. The numerical model shows a less conservative prediction compared with the steady-state methods. The computational self-ignition temperature and ignition delay time show a satisfaction agreement with lab-scale experimental results. In addition, the influences of ambient temperature and moisture content are analysed. The result shows that the moisture content delays the ignition and a small variation of the ambient temperature nearby the critical condition will lead to a large difference of the ignition delay time. KW - Spontanious ignition KW - Self-ignition KW - Extrapolation methods PY - 2019 DO - https://doi.org/10.1016/j.proci.2018.05.140 SN - 1540-7489 VL - 37 IS - 3 SP - 4181 EP - 4191 PB - Elsevier AN - OPUS4-47291 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Loewer, M. A1 - Guenther, T. A1 - Igel, J. A1 - Kruschwitz, Sabine A1 - Martin, T. A1 - Wagner, N. T1 - Ultra-broad-band electrical spctroscopy of soils and sediments - a combined permittivity and conductivity model JF - Geophsical Journal International N2 - We combined two completely different methods measuring the frequency-dependent electrical properties of moist porous materials in order to receive an extraordinary large frequency spectrum. In the low-frequency (LF) range, complex electrical resistivity between 1 mHz and 45 kHz was measured for three different soils and sandstone, using the spectral induced polarization (SIP) method with a four electrode cell. In the high-frequency (HF) radio to microwave range, complex dielectric permittivity was measured between 1MHz and 10 GHz for the same samples using dielectric spectroscopy by means of the coaxial transmission line technique. The combined data sets cover 13 orders of magnitude and were transferred into their equivalent expressions: the complex effective dielectric permittivity and the complex effective electrical conductivity.We applied the Kramers-Kronig relation in order to justify the validity of the data combination. A new phenomenological model that consists of both dielectric permittivity and electrical conductivity terms in a Debye- and Cole–Cole-type manner was fitted to the spectra. The combined permittivity and conductivity model accounts for the most common representations of the physical quantities with respect to the individual measuring method. A maximum number of four relaxation processes was identified in the analysed frequency range. Among these are the free water and different interfacial relaxation processes, the Maxwell-Wagner effect, the counterion relaxation in the electrical double layer and the direct-current electrical conductivity. There is evidence that free water relaxation does not affect the electrical response in the SIP range. Moreover, direct current conductivity contribution (bulk and interface) dominates the losses in the HF range. Interfacial relaxation processes with relaxations in the HF range are broadly distributed down to the LF range. The slowest observed process in the LF range has a minor contribution to the HF response. KW - Electrical properties KW - Permeability KW - Porosity KW - Hydrogeophysics PY - 2017 DO - https://doi.org/10.1093/gji/ggx242 VL - 210 IS - 3 SP - 1360 EP - 1373 PB - Oxford University Press CY - Oxford AN - OPUS4-42598 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neumann, Patrick P. A1 - Hüllmann, Dino A1 - Krentel, Daniel A1 - Kluge, Martin A1 - Kohlhoff, Harald A1 - Lilienthal, A. J. T1 - Gas Tomography Up In The Air! T2 - Proceedings of the IEEE Sensors 2018 N2 - In this paper, we present an autonomous aerial robot to reconstruct tomographic 2D slices of gas plumes in outdoor environments. Our platform, the so-called Unmanned Aerial Vehicle for Remote Gas Sensing (UAV-REGAS) combines a lightweight Tunable Diode Laser Absorption Spectroscopy (TDLAS) sensor with a 3-axis aerial stabilization gimbal for aiming on a versatile octocopter. The TDLAS sensor provides integral gas concentration measurements but no information regarding the distance traveled by the laser diode's beam or the distribution of the gas along the optical path. We complemented the set-up with a laser rangefinder and apply principles of Computed Tomography (CT) to create a model of the spatial gas distribution from these integral concentration measurements. To allow for a rudimentary ground truth evaluation of the applied gas tomography algorithm, we set up a unique outdoor test environment based on two 3D ultrasonic anemometers and a distributed array of 10 infrared gas transmitters. We present first results showing the 2D plume reconstruction capabilities of the system under realistic conditions. T2 - IEEE Sensors 2018 CY - New Delhi, India DA - 28.10.2018 KW - Aerial robot KW - TDLAS KW - Gas tomography KW - Plume PY - 2018 SN - 978-1-5386-4707-3 SP - 396 EP - 398 PB - IEEE AN - OPUS4-46477 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Zoega, A. A1 - Krause, Martin A1 - Kurz, J. A1 - Maack, Stefan A1 - Küttenbaum, Stefan A1 - Boßmann, N. T1 - Ultraschalluntersuchungen zur Rissdetektion an Spannbetonschwellen JF - Messtechnik im Bauwesen N2 - Im deutschen Eisenbahnnetz sind ca. 80 Millionen Spannbetonschwellen verbaut. Analog zu anderen Bauwerken werden Wpannbetonschwellen regelmäßig visuell inspiziert. Die Rissbildung ist bei diesen Inspektionen ein Kriterium für die Schädigung einer Spannbetonschwelle. Durch Rissbildung kann es passieren, dass Betonschwellen ihre Nutzungsdauer nicht erreichen. KW - ZfPBau KW - Spannbeton PY - 2017 VL - März 2017 IS - Ernst & Sohn Special 2017 SP - 20 EP - 22 PB - Ernst & Sohn Verlag für Architektur und technische Wissenschaften GmbH & Co. KG CY - Berlin AN - OPUS4-48112 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bornemann-Pfeiffer, Martin A1 - Meyer, Klas A1 - Lademann, J. A1 - Kraume, M. A1 - Maiwald, Michael T1 - Contributions towards variable temperature shielding for compact NMR instruments JF - Magnetic Resonance in Chemistry N2 - The application of compact NMR instruments to hot flowing samples or exothermically reacting mixtures is limited by the temperature sensitivity of permanent magnets. Typically, such temperature effects directly influence the achievable magnetic field homogeneity and hence measurement quality. The internal-temperature control loop of the magnet and instruments is not designed for such temperature compensation. Passive insulation is restricted by the small dimensions within the magnet borehole. Here, we present a design approach for active heat shielding with the aim of variable temperature control of NMR samples for benchtop NMR instruments using a compressed airstream which is variable in flow and temperature. Based on the system identification and surface temperature measurements through thermography, a model predictive control was set up to minimise any disturbance effect on the permanent magnet from the probe or sample temperature. This methodology will facilitate the application of variable-temperature shielding and, therefore, extend the application of compact NMR instruments to flowing sample temperatures that differ from the magnet temperature. KW - Benchtop NMR KW - Continuous Processes KW - Inline Analytics KW - Model Predictive Control KW - Process Analytical Tecnology KW - Temperature Control PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-579219 DO - https://doi.org/10.1002/mrc.5379 SN - 1097-458X SP - 1 EP - 10 PB - John Wiley & Sons Ltd. AN - OPUS4-57921 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Krause, Martin A1 - Dérobert, X. A1 - Hugenschmidt, J. A1 - Moczko, A. A1 - Niederleithinger, Ernst A1 - Taffe, Alexander ED - L. Binda, ED - M. di Prisco, ED - R. Felicetti, T1 - Benchmark for thickness measurement of concrete elements T2 - 1st International RILEM Conference - on Site Assessment of Concrete, Masonry and Timber Structures (SACoMaTiS 2008), Proceedings T2 - 1st International RILEM Conference, on Site Assessment of Concrete, Masonry and Timber Structures (SACoMaTiS 2008) CY - Varenna, Italy DA - 2008-09-01 KW - Thickness measurement KW - Radar KW - Ultrasonic Echo KW - Impact-Echo and Low Strain Techniques PY - 2008 SN - 978-2-35158-062-2 VL - 1 IS - PRO 59 SP - 357 EP - 366 PB - RILEM Publications AN - OPUS4-18030 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Wilrich, Cordula A1 - Schröder, Volkmar A1 - Brandes, E. A1 - Schmidt, Martin A1 - Wandrey, Peter-Andreas A1 - Mix, K.-H. A1 - Wehrstedt, Klaus-Dieter A1 - Bender, H. A1 - Stephan, U. A1 - Eberz, A. A1 - Steinbach, J. A1 - Stoessel, F. T1 - Plant and process safety - 2. Hazardous materials and process conditions T2 - Ullmann's encyclopedia of industrial chemistry N2 - "Ullmann's Encyclopedia of Industrial Chemistry" is the benchmark reference in chemistry and chemical and life science engineering, covering inorganic and organic chemicals, advanced materials, pharmaceuticals, polymers and plastics, metals and alloys, biotechnology and biotechnological products, food chemistry, process engineering and unit operations, analytical methods, environmental protection, and much more. The present article is part of the topic collection "Environmental Protection and Industrial Safety". It covers plant and process safety, focusing on hazardous materials and process conditions. KW - Flammable gases and vapors KW - Combustibility of liquids KW - Dust explosions KW - Explosive condensed substances KW - Harmful effects of substances KW - Exothermic and pressure-inducing chemical reactions PY - 2012 SN - 978-3-527-30673-2 DO - https://doi.org/10.1002/14356007.q20_q01 SP - 1 EP - 50 PB - Wiley-VCH CY - Weinheim AN - OPUS4-58108 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schnell, A. A1 - Rübner, Katrin A1 - Seher, Julia A1 - Müller, A. A1 - Liebezeit, S. A1 - Fenner, J. A1 - Martin, F. A1 - Pniok, N. T1 - REALight ‐ Leichtgranulate und REA‐Gips aus feinkörnigen sulfatbelasteten Bau‐ und Abbruchabfällen JF - ce/papers - Proceedings in Civil Engineering N2 - Ziel des Projekts REALight ist die Entwicklung einer Referenzanlage zur Herstellung von Leichtgranulaten (leichte Gesteinskörnungen) aus Bau‐ und Abbruchabfällen und zur Gipsrückgewinnung. Als Rohstoffe werden bisher ungenutzte oder auf niedrigem Niveau eingesetzte Bau‐ und Abbruchabfälle und industrielle Nebenprodukte verwendet. Als Produkte werden leichte Gesteinskörnungen hergestellt. Die Sulfatabtrennung durch eine thermische Zersetzung bildet die Grundlage für die zusätzliche Gewinnung von Rauchgasentschwefelungs‐Gips (REA‐Gips). Das Projekt wird im Rahmen der Fördermaßnahme „Ressourceneffiziente Kreislaufwirtschaft – Bauen und Mineralische Stoffkreisläufe (ReMin)” gefördert. ReMin ist eine Maßnahme zur Umsetzung des BMBF‐Forschungskonzepts „Ressourceneffiziente Kreislaufwirtschaft” als Teil der BMBF Strategie „Forschung für nachhaltige Entwicklung – FONA”. Ziel der Förderung ist es, den Ausbau der Kreislaufwirtschaft voranzutreiben. Im Mittelpunkt steht dabei die Bauwirtschaft mit ihrer hohen Nachfrage nach Rohstoffen und gleichzeitig großen Mengen an anfallenden mineralischen Abfällen. Am Projekt REALight sind 12 Partner aus verschiedenen Bereichen der Baustoffherstellung und ‐anwendung, Abfallaufbereitung, Verfahrenstechnik sowie Forschung und Entwicklung beteiligt. T2 - 21. Internationale Baustofftagung (ibausil) CY - Weimar, Germany DA - 13.09.2023 KW - Baustoffrecycling KW - Leichtgranulate KW - Gips KW - Leichte Gesteinskörnungen KW - Drehrohrofen KW - Recycling KW - Mauerwerkbruch KW - Infraleichtbeton PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-591708 DO - https://doi.org/10.1002/cepa.2840 SN - 2509-7075 VL - 6 IS - 6 SP - 530 EP - 536 PB - Ernst & Sohn CY - Berlin AN - OPUS4-59170 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sanchez-Martin, Pedro A1 - Becker, Roland A1 - Toepel, J. A1 - Gorbushina, Anna T1 - An improved test for the evaluation of hydrocarbon degradation capacities of diesel-contaminating microorganisms JF - International Biodeterioration & Biodegradation N2 - The development of a test to evaluate the degradation of semi-volatile fuels as diesel by microorganisms is presented. This method is based on the principles described in the CEC-L-103 Standard procedure that is exclusively meant for testing the biodegradability of non-volatile lubricants. Therefore, significant modifications involve aseptic conditions for testing specific microorganisms and conducting the test in closed vessels avoiding evaporation losses, while fuel quantification using gas chromatography-flame ionization detection (GC-FID) is retained. It is suggested that the modified procedure should enable routine application for semi-volatile hydrocarbon-based fuels. GC-FID provides additionally valuable information on the alteration of fuel component patterns during biodegradation. The procedure was successfully tested using two bacteria (Pseudomonas aeruginosa and Sphingomonas sp.) and two yeasts (Moesziomyces sp. and Candida sp.) isolated from real diesel contamination cases. All tested microorganisms caused a significant degradation of diesel fuel achieving hydrocarbon degradation percentages ranging from 23% to 35%. Specific aspects on the test modification and prospects for further modification regarding targeted investigations in the field of fuel contamination by microorganisms are briefly discussed. KW - Biofouling KW - Bacteria KW - Fungi KW - CEC-L-103 KW - GC-FID KW - Reference organisms PY - 2018 DO - https://doi.org/10.1016/j.ibiod.2018.01.009 SN - 0964-8305 VL - 129 SP - 89 EP - 94 PB - Elsevier AN - OPUS4-44524 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lenz, J. A1 - Pospiech, D. A1 - Paven, M. A1 - Albach, R. W. A1 - Günther, Martin A1 - Schartel, Bernhard A1 - Voit, B. T1 - Improving the Flame Retardance of Polyisocyanurate Foams by Dibenzo[d,f][1,3,2]dioxaphosphepine 6-Oxide-Containing Additives JF - Polymers N2 - A series of new flame retardants (FR) based on dibenzo[d,f][1,3,2]dioxaphosphepine 6-oxide (BPPO) incorporating acrylates and benzoquinone were developed previously. In this study, we examine the fire behavior of the new flame retardants in polyisocyanurate (PIR) foams. The foam characteristics, thermal decomposition, and fire behavior are investigated. The fire properties of the foams containing BPPO-based derivatives were found to depend on the chemical structure of the substituents. We also compare our results to state-of-the-art non-halogenated FR such as triphenylphosphate and chemically similar phosphinate, i.e. 9,10-dihydro-9-oxa-10- phosphaphenanthrene-10-oxide (DOPO), based derivatives to discuss the role of the phosphorus oxidation state. KW - Polyisocyanurate KW - Dibenzo[d,f][1,3,2]dioxaphosphepine 6-oxide KW - Phospha-Michael addition KW - Flame retardant KW - Foams PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-485590 DO - https://doi.org/10.3390/polym11081242 SN - 2073-4360 VL - 11 IS - 8 SP - Article 1242 PB - MDPI AN - OPUS4-48559 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lenz, J. U. A1 - Pospiech, D. A1 - Komber, H. A1 - Korwitz, A. A1 - Kobsch, O. A1 - Paven, M. A1 - Albach, R. W. A1 - Günther, Martin A1 - Schartel, Bernhard T1 - Effective halogen-free flame-retardant additives for crosslinked rigid polyisocyanurate foams: Comparison of chemical structures JF - Materials N2 - The impact of phosphorus-containing flame retardants (FR) on rigid polyisocyanurate (PIR) foams is studied by systematic variation of the chemical structure of the FR, including non-NCO-reactive and NCO-reactive dibenzo[d,f][1,3,2]dioxaphosphepine 6-oxide (BPPO)- and 9,10 dihydro-9-oxa-10 phosphaphenanthrene-10-oxide (DOPO)-containing compounds, among them a number of compounds not reported so far. These PIR foams are compared with PIR foams without FR and with standard FRs with respect to foam properties, thermal decomposition, and fire behavior. Although BPPO and DOPO differ by just one oxygen atom, the impact on the FR properties is very significant: when the FR is a filler or a dangling (dead) end in the PIR polymer network, DOPO is more effective than BPPO. When the FR is a subunit of a diol and it is fully incorporated in the PIR network, BPPO delivers superior results. KW - Flame retardant; KW - Dibenzo[d,f][1,3,2]dioxaphosphepine 6-oxide; BPPO KW - 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide; DOPO KW - Polyisocyanurate; PIR KW - Rigid foam KW - Cone calorimeter KW - Pudovik reaction PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-567712 DO - https://doi.org/10.3390/ma16010172 SN - 1996-1944 VL - 16 IS - 1 SP - 1 EP - 22 PB - MDPI CY - Basel AN - OPUS4-56771 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Dilz, K. A1 - Pohl, J. A1 - Rühe, S. A1 - Thomas, Hans-Martin A1 - Casperson, Ralf T1 - Online-Schweißnahterkennung von Schienenprüfzügen mittels Wirbelstromverfahren T2 - ZfP in Forschung, Entwicklung und Anwendung - Jahrestagung 2003 N2 - Zur Detektion von Schweißnähten an verlegten Schienen gehört deren Identifikation und Lokalisation. Die Aufgabe, Schweißnähte derart zu detektieren, stellt sich bei der Prüfung eines Gleisnetzes auf Schädigungen, aber auch unabhängig davon. T2 - Jahrestagung Zerstörungsfreie Materialprüfung 2003 CY - Mainz, Deutschland DA - 26.05.2003 PY - 2003 UR - http://www.ndt.net/article/dgzfp03/papers/v07/v07.htm SN - 3-931381-47-1 N1 - Serientitel: Berichtsband / Deutsche Gesellschaft für zerstörungsfreie Prüfung e. V. – Series title: Berichtsband / Deutsche Gesellschaft für zerstörungsfreie Prüfung e. V. IS - 83-CD SP - 1 EP - 4 PB - DGZfP CY - Berlin AN - OPUS4-3491 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dippong, Martin A1 - Carl, Peter A1 - Lenz, C. A1 - Schenk, J. A. A1 - Hoffmann, Katrin A1 - Schwaar, Timm A1 - Schneider, Rudolf A1 - Kuhne, Maren T1 - Hapten-specific single-cell selection of hybridoma clones by fluorescence-activated cell sorting for the generation of monoclonal antibodies JF - Analytical Chemistry N2 - The conventional hybridoma screening and subcloning process is generally considered to be one of the most critical steps in hapten-specific antibody production. It is time-consuming, monoclonality is not guaranteed, and the number of clones that can be screened is limited. Our approach employs a novel hapten-specific labeling technique of hybridoma cells. This allows for fluorescence-activated cell sorting (FACS) and single-cell deposition and thereby eliminates the above-mentioned problems. A two-step staining approach is used to detect antigen specificity and antibody expression: in order to detect antigen specificity, hybridoma cells are incubated with a hapten−horseradish peroxidase conjugate (hapten−HRP), which is subsequently incubated with a fluorophore-labeled polyclonal anti-peroxidase antibody (anti-HRP−Alexa Fluor 488). To characterize the expression of membrane-bound immunoglobulin G (IgG), a fluorophore-labeled anti-mouse IgG antibody (anti-IgG−Alexa Fluor 647) is used. Hundreds of labeled hybridoma cells producing monoclonal antibodies (mAbs) specific for a hapten were rapidly isolated and deposited from a fusion mixture as single-cell clones via FACS. Enzyme-linked immunosorbent assay (ELISA) measurements of the supernatants of the sorted hybridoma clones revealed that all hapten-specific hybridoma clones secrete antibodies against the target. There are significant improvements using this high-throughput technique for the generation of mAbs including increased yield of antibody-producing hybridoma clones, ensured monoclonality of sorted cells, and reduced development times. KW - Monoclonal antibodies KW - FACS KW - Hybridoma cells PY - 2017 DO - https://doi.org/10.1021/acs.analchem.6b04569 SN - 0003-2700 SN - 1520-6882 VL - 89 IS - 7 SP - 4007 EP - 4012 PB - ACS Publications AN - OPUS4-40320 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Fortes Martin, R. A1 - Thünemann, Andreas A1 - Stockmann, Jörg M. A1 - Radnik, Jörg A1 - Koetz, J. T1 - From Nanoparticle Heteroclusters to Filament Networks by Self-Assembly at the Water–Oil Interface of Reverse Microemulsions JF - Langmuir N2 - Surface self-assembly of spherical nanoparticles of sizes below 10 nm into hierarchical heterostructures is under arising development despite the inherent difficulties of obtaining complex ordering patterns on a larger scale. Due to template-mediated interactions between oil-dispersible superparamagnetic nanoparticles (MNPs) and polyethylenimine-stabilized gold nanoparticles (Au(PEI)NPs) at the water–oil interface of microemulsions, complex nanostructured films can be formed. Characterization of the reverse microemulsion phase by UV–vis absorption revealed the formation of heteroclusters from Winsor type II phases (WPII) using Aerosol-OT (AOT) as the surfactant. SAXS measurements verify the mechanism of initial nanoparticle clustering in defined dimensions. XPS suggested an influence of AOT at the MNP surface. Further, cryo-SEM and TEM visualization demonstrated the elongation of the reverse microemulsions into cylindrical, wormlike structures, which subsequently build up larger nanoparticle superstructure arrangements. Such WPII phases are thus proven to be a new form of soft template, mediating the self-assembly of different nanoparticles in hierarchical network-like filaments over a substrate during solvent evaporation. KW - Small-angle X-ray scattering KW - SAXS KW - Nanoparticle KW - Nano structure PY - 2021 DO - https://doi.org/10.1021/acs.langmuir.1c01348 VL - 37 IS - 29 SP - 8876 EP - 8885 PB - American Chemical Society AN - OPUS4-53034 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Colla, Camilla A1 - Krause, Martin A1 - Maierhofer, Christiane A1 - Höhberger, H.-J. A1 - Sommer, H. T1 - Combination of NDT techniques for site investigation of non-ballasted railway tracks JF - NDT & E international N2 - Today's civil engineering NDT needs are for quantitative, fast to apply and easy to interpret methods. They are required on site both for evaluation of existing structures/infrastructure and for quality control in new construction. With this purpose, BAM has carried out in-situ feasibility studies, using radar, impact-echo and ultrasonic-echo methods. Two examples are given of their combined application on different railway slab–track constructions, using high frequency radar, scanning impact-echo and ultrasonic array methods. The aim was to evaluate limitations and advantages, comparability and complementarity of these methods. The on-site measurements demonstrated the possibility to investigate, with good accuracy via NDT, the bonding conditions between sleepers and slab, to locate voids and measure layer thickness. The acoustic and electromagnetic methods used, were found to be complementary. KW - Concrete KW - NDT KW - Impact echo KW - Ultrasonics KW - Radar KW - Railway PY - 2002 DO - https://doi.org/10.1016/S0963-8695(01)00033-0 SN - 0963-8695 VL - 35 SP - 95 EP - 105 PB - Butterworth-Heinemann CY - Oxford AN - OPUS4-1858 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mero, M. A1 - Clapp, B. A1 - Jasapara, J.C. A1 - Rudolph, W. A1 - Ristau, D. A1 - Starke, K. A1 - Krüger, Jörg A1 - Martin, Sven A1 - Kautek, Wolfgang T1 - On the damage behavior of dielectric films when illuminated with multiple femtosecond laser pulses JF - Optical engineering N2 - The physical effects reducing the damage threshold of dielectric films when exposed to multiple femtosecond pulses are investigated. The measured temperature increase of a Ta2O5 film scales exponentially with the pulse fluence. A polarized luminescence signal is observed that depends quadratically on the pulse fluence and is attributed to twophoton excitation of self-trapped excitons that form after band-to-band excitation. The damage fluence decreases with increasing pulse number, but is independent of the repetition rate from 1 Hz to 1 kHz at a constant pulse number. The repetition rate dependence of the breakdown threshold is also measured for TiO2 , HfO2, Al2O3, and SiO2 films. A theoretical model is presented that explains these findings. KW - Laser-induced damage KW - Laser materials KW - Ultrafast phenomena KW - Coatings PY - 2005 DO - https://doi.org/10.1117/1.1905343 SN - 0892-354X VL - 44 IS - 5 SP - 051107-1-051107-7 PB - Dekker CY - New York, NY AN - OPUS4-7406 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bothe, Martin A1 - Mya, K.Y. A1 - Lin, E.M.J. A1 - Yeo, C. C. A1 - Lu, X. A1 - He, C. A1 - Pretsch, Thorsten T1 - Triple-shape properties of star-shaped POSS-polycaprolactone polyurethane networks JF - Soft matter N2 - Here, we present an investigation of the triple-shape properties of star-shaped polyhedral oligomeric silsesquioxane-poly(ε-caprolactone) polyurethanes (SPOSS-PUs), which have three-dimensional network structures. In a typical 'triple-shape functionalization process', mostly consisting of two tensile deformations at different temperatures, chain immobilization of the polymer network component poly(ε-caprolactone) (PCL) was successfully realized first through crystallization and then through vitrification. Subsequently, large parts of the respective strains were released under stress-free recovery conditions. The two-fold fixed ('programmed') specimens responded to heating with two independent length contractions (switching steps); the first shape change was associated with PCL devitrification and the second one with the melting of hitherto crystalline PCL. It was revealed that the triple-shape properties of SPOSS-PU networks considerably depend on PCL network chain length. When applying exactly the same 'triple-shape creation procedure', larger strain releases were detected in the first transition for polymers with a higher PCL network chain length, whereas the second transition was more accentuated for SPOSS-PU networks with a shorter PCL chain length. In the course of thermo-mechanical cycling, the formation of a neck during the second tensile deformation was repeatedly detected for SPOSS-PUs with higher PCL network chain length; in the subsequent recovery process the specimens even exhibited the highest total strain recoverability. Finally, gradual strain release could be achieved at temperatures below the PCL melting transition through the selection of up to four temperature holding steps, at which every time stable shapes were formed. KW - Shape memory polymer KW - Active polymer KW - Triple-shape polymer KW - Hybrid star-shaped polymer KW - POSS-polycaprolactone polyurethanes KW - Thermo-mechanical properties PY - 2012 DO - https://doi.org/10.1039/c1sm06474f SN - 1744-683X VL - 8 IS - 4 SP - 965 EP - 972 PB - RSC Publ. CY - Cambridge AN - OPUS4-25260 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Haardt, P. A1 - Krause, Martin A1 - Streicher, Doreen A1 - Krause, H.-J. ED - Watanabe, E. ED - Frangopol, D. T1 - Scanning NDT-Methods for the Inspection of Highway Structures T2 - Bridge maintenance, safety, management and cost T2 - 2nd International Conference on Bridge Maintenance, Safety and Management CY - Kyoto, Japan DA - 2004-10-19 KW - ZfPBau KW - Ingenieurbauwerke KW - Automatisierung KW - Laserscanner KW - Ultraschallecho KW - Impuls Radar KW - Impact-Echo PY - 2004 SN - 90-5809-680-7 SP - 8 pages PB - Balkema CY - Leiden AN - OPUS4-5201 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mayer, K. A1 - Langenberg, K.-J. A1 - Krause, Martin A1 - Milmann, Boris A1 - Mielentz, Frank T1 - Characterization of reflector types by phase-sensitive ultrasonic data processing and imaging JF - Journal of nondestructive evaluation N2 - Ultrasonic and radar imaging techniques are limited in resolution by the wavelength in the material, yet information beyond those limits is hidden in complex frequency dependent reflection coefficients. The analysis of the phase of complex reflection coefficients together with the properties of imaging algorithms can help to characterize and to classify indications of defects in concrete buildings. This paper describes a method to extract phase information from measurements and SAFT reconstructed images. The influencing factors like material properties, transducer characteristics, and imaging algorithms based on Born or Physical Optics approximations are elaborated. Simulated and experimental results are briefly discussed. KW - NDT KW - Imaging KW - Flaw characterization KW - Tendon ducts KW - Phase analysis KW - Ultrasonic echo KW - SAFT KW - FT-SAFT KW - EFIT-modeling KW - Modellierung KW - EFIT KW - Spannbeton KW - Ultraschallecho KW - Spannkanäle KW - Verpressfehler KW - Zerstörungsfreie Prüfung im Bauwesen KW - ZfP-Bau PY - 2008 DO - https://doi.org/10.1007/s10921-008-0035-3 SN - 0195-9298 SN - 1573-4862 VL - 27 IS - 1-3 SP - 35 EP - 45 PB - Plenum Press CY - New York, NY AN - OPUS4-17926 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Krause, Martin A1 - Milmann, Boris A1 - Mielentz, Frank A1 - Streicher, Doreen A1 - Redmer, Bernhard A1 - Mayer, K. A1 - Langenberg, K.-J. A1 - Schickert, M. T1 - Ultrasonic Imaging Methods for Investigation of Post-tensioned Concrete Structures: A Study of Interfaces at Artificial Grouting Faults and Its Verification JF - Journal of nondestructive evaluation N2 - This paper presents the progress of successful location of grouting faults in tendon ducts with ultrasonic imaging. The examples were obtained in the research group FOR 384 funded by DFG (German Research Foundation). The co-operation of experimental research and modeling allowed imaging and identification of grouted and ungrouted areas of tendon ducts (including strands) in a large test specimen (40 m²). In addition to the criteria for indicating grouting faults in post-tensioned ducts known until now the phase evaluation of reflected ultrasonic pulses is described. Experiments and modeling of wave propagation are presented for reflections at metal plates in concrete (thickness range 0.5 mm to 40 mm) and for tendon ducts including strands. The main part of the progress was achieved by automated measurements using dry contact transducers, 3D-SAFT reconstruction including phase evaluation and modeling considering wave propagation for typical elastic parameters and exact experimental site conditions. The results for shear waves as well as for pressure waves are compared in the frequency range from 50 kHz to 120 kHz. KW - Non-destructive testing KW - Tendons KW - Prestressed concrete bridges KW - Ultrasonic echo KW - Reconstruction calculation KW - 3D-SAFT KW - Modeling (EFIT) PY - 2008 DO - https://doi.org/10.1007/s10921-008-0033-5 SN - 0195-9298 SN - 1573-4862 VL - 27 IS - 1-3 SP - 67 EP - 82 PB - Plenum Press CY - New York, NY AN - OPUS4-17922 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mayer, K. A1 - Langenberg, K.-J. A1 - Krause, Martin A1 - Maierhofer, Christiane A1 - Milmann, Boris A1 - Kohl, Christoph T1 - Characterization of ultrasonic and radar reflector types in concrete by phase evaluation of the signal and the reconstructed image T2 - 9th European Conference on NDT T2 - 9th European Conference on NDT CY - Berlin, Germany DA - 2006-09-25 KW - NDT-CE KW - Ultrasonic echo KW - Radar KW - Phase evaluation KW - Modeling of wave propagation KW - Reconstruction calculation PY - 2006 SN - 3-931381-86-2 SP - 1 EP - 8(?) PB - European Federation for Non-Destructive Testing CY - Berlin AN - OPUS4-14225 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kroggel, O. A1 - Krause, Martin A1 - Schickert, M. A1 - Langenberg, K.-J. T1 - Moderne Verfahren der Bauwerksdiagnose, Entwicklung und Anwendung - Die DFG-Forschergruppe FOR384 stellt ihre Ergebnisse vor - Ultraschall T2 - Fachtagung des Deutschen Ausschusses für Stahlbeton 2005 - Zerstörungsfreie Prüfverfahren und Bauwerksdiagnose im Betonbau T2 - Fachtagung 2005 des Deutschen Ausschusses für Stahlbeton in Zusammenarbeit mit der Bundesanstalt für Materialforschung und -prüfung "Zerstörungsfreie Prüfverfahren und Bauwerksdiagnose im Betonbau" CY - Berlin, Deutschland DA - 2005-03-10 KW - Ultraschallecho-Verfahren KW - Beton KW - Fundamente KW - Erhärtungsverhalten KW - Tomographie PY - 2005 SP - A5 EP - A10 PB - BAM CY - Berlin AN - OPUS4-11718 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Gardei, André A1 - Garcia, O. A1 - Riedl, Martin A1 - Vanhellemond, I. A1 - Suput, J.S. A1 - Santarelli, M.-L. A1 - Rodríguez-Maribona, I. A1 - Müller, Urs ED - Jadwiga W. Lukaszewicz, ED - Piotr Niemcewicz, T1 - Performance and durability of a new antigraffiti system for cultural heritage - the EC project GRAFFITAGE T2 - 11th International Congress on Deterioration and Conservation of Stone, September 15-20, 2008, Torun, Poland (Proceedings) T2 - 11th International Congress on Deterioration and Conservation of Stone CY - Torun, Poland DA - 2008-09-15 KW - Cultural heritage KW - Antigraffiti system KW - Sandstone KW - Limestone KW - Brick KW - Monument KW - Cleaning KW - Historische Baustoffe PY - 2008 SN - 978-83-231-2237-1 VL - II SP - 889 EP - 897 PB - Nicolaus Copernicus University Press CY - Torun, Poland AN - OPUS4-18844 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mayer, K. A1 - Chinta, P.K. A1 - Langenberg, K.-J. A1 - Krause, Martin T1 - Ultrasonic imaging of defects in known anisotropic and inmomogeneous structures with fast synthetic aperture methodes T2 - 18th WCNDT - World conference on nondestructive testing (Proceedings) T2 - 18th WCNDT - World conference on nondestructive testing CY - Durban, South Africa DA - 2012-04-16 KW - SAFT KW - Pulse echo technique KW - Back propagation KW - Inverse scattering KW - Imaging PY - 2012 SN - 978-0-620-52872-6 SP - 1 EP - 20 AN - OPUS4-35101 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ballier, G. A1 - Mayer, K. A1 - Langenberg, K.-J. A1 - Schulze, Sebastian A1 - Krause, Martin T1 - Improvement on tendon duct examination by modelling and imaging with synthetic aperture and one-way inverse methods T2 - 18th WCNDT - World conference on nondestructive testing (Proceedings) T2 - 18th WCNDT - World conference on nondestructive testing CY - Durban, South Africa DA - 2012-04-16 KW - SAFT KW - Ultrasonic NDT KW - Concrete KW - One way KW - AFIT KW - Time reversal PY - 2012 SN - 978-0-620-52872-6 SP - 1 EP - 8 AN - OPUS4-35102 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Konnertz, Nora A1 - Ding, Yi A1 - Harrison, W.J. A1 - Budd, P.M. A1 - Schönhals, Andreas A1 - Böhning, Martin T1 - Molecular mobility and gas transport properties of nanocomposites based on PIM-1 and polyhedral oligomeric phenethyl-silsesquioxanes (POSS) JF - Journal of Membrane Science N2 - Polymers with intrinsic microporosity (PIMs) are of great interest in the field of gas separation membranes. Already the first synthesized PIM-1 shows extraordinary permeability and selectivity. Unfortunately, PIM-1 is susceptible to physical aging and thus gradually loses its outstanding properties. In this study a polyhedral oligomeric silsesquioxane with phenethyl substituents (PhenethylPOSS) was used as a nanofiller (0–40 wt%) in the PIM-1 matrix to potentially improve the gas transport properties and prevent physical aging. The molecular mobility of the solution-cast nanocomposite films was analyzed by Broadband Dielectric Spectroscopy (BDS). Furthermore, gas permeability was determined with the time lag method (0–20 bar upstream pressure) at 35 °C for N2, O2, CH4 and CO2. KW - Broadband Dielectric Spectroscopy KW - Gas separation KW - Gas permeation KW - Polymers of intrinsic microporosity KW - Nanocomposite KW - POSS KW - PIM-1 PY - 2017 DO - https://doi.org/10.1016/j.memsci.2017.02.007 SN - 0376-7388 SN - 1873-3123 VL - 529 SP - 274 EP - 285 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-39169 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reifschneider, O. A1 - Vennemann, A. A1 - Buzanich, Günter A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Riesemeier, Heinrich A1 - Hogeback, J A1 - Köppen, C. A1 - Großgarten, M. A1 - Sperling, M. A1 - Wiemann, M. A1 - Karst, U. T1 - Revealing Silver Nanoparticle Uptake by Macrophages Using SR-μXRF and LA-ICP-MS JF - Chemical Research in Toxicology N2 - To better study the impact of nanoparticles on both in vitro and in vivo models, tissue distribution and cellular doses need to be described more closely. Here silver nanoparticles were visualized in alveolar macrophages by means of synchrotron radiation micro X-ray fluorescence spectroscopy (SR-μXRF) with high spatial resolution of 3 × 3 μm2. For the spatial allocation of silver signals to cells and tissue structures, additional elemental labeling was carried out by staining with eosin, which binds to protein and can be detected as bromine signal with SR-μXRF. The method was compatible with immunostaining of macrophage antigens. We found that the silver distribution obtained with SR-μXRF was largely congruent with distribution maps from a subsequent laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) of the same tissue sites. The study shows a predominant, though not exclusive uptake of silver into alveolar macrophages in the rat lung, which can be modeled by a similar uptake in cultured alveolar macrophages. Advantages and limitations of the different strategies for measuring nanoparticle uptake at the single cell level are discussed. KW - Synchrotron KW - BAMline KW - XRF KW - Nanoparticle KW - Macrophagen PY - 2020 DO - https://doi.org/10.1021/acs.chemrestox.9b00507 VL - 33 IS - 5 SP - 1250 EP - 1255 PB - American Chemical Society AN - OPUS4-50855 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Konnertz, Nora A1 - Ding, Yi A1 - Harrison, W.J. A1 - Budd, P.M. A1 - Schönhals, Andreas A1 - Böhning, Martin T1 - Molecular mobility of the high performance membrane polymer PIM-1 as investigated by dielectric spectroscopy JF - ACS Macro Letters N2 - The increasing demand for energy efficient separation processes fosters the development of new high performance polymers as selective separation layers for membranes. PIM-1 is the archetypal representative of the class of polymers of intrinsic microporosity (PIM) which are considered most promising in this sector, especially for gas separations. Since their introduction, PIMs stimulated a vast amount of research in this field and meanwhile evolved to the state of the art in membrane technology for gas separation. The major obstacle for extending the practical membrane application is their strong tendency to physical aging. For the first time, investigations by broadband dielectric spectroscopy (BDS) addressing molecular dynamics and conductivity in PIM 1 are presented. As chain packing during film formation from the casting solution and physical aging are key factors determining the separation performance of PIMs as membrane materials, characterization of the molecular mobility in such materials as revealed by BDS will provide valuable information for further development and optimization. KW - PIM-1 KW - BDS broadband dielectric spectroscopy KW - Relaxation KW - Membrane PY - 2016 DO - https://doi.org/10.1021/acsmacrolett.6b00209 SN - 2161-1653 VL - 5 IS - 4 SP - 528 EP - 532 PB - ACS American Chemical Society CY - Washington, DC, USA AN - OPUS4-35798 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krause, Martin A1 - Kurz, J.H. A1 - Lanata, F. A1 - Krstevska, L. A1 - Cavalli, A. T1 - Needs for further developing monitoring- and NDT-methods for timber structures T2 - SHATIS 2015 - 3rd International conference on structural health assessment of timber structures N2 - For the assessmentand for monitoring of timber structures there are numerous promising methods that enable the quantitative description of the current condition of construction elements or parts of a structure. This concerns material properties like modulus of elasticity, moisture content and density as well as structural properties like dynamic characteristics, localization of inhomogeneities, cracks, and biological attack. During the work in COST Action FP 1101, since 2012 the capability of experimental methods are discussed and compared. This covers electrical and electromagnetic wave methods (resistivity, microwave, Radar, X-Ray), elastic waves (ultrasound, pile testing) and mechanical testing (static and dynamic). Describing and collecting the use of the experimental methods for monitoring purposes was the objective of working group 3 "Monitoring of Timber Structures" of the COST Action. Monitoring capabilities will extend the use of timber structures to further applications in civil engineering. So far, no standard exists but collections of application examples and review papers representing the state of the art. From there needs for further developments regarding monitoring and NDT methods for timber structures can be identified and these are described in this paper. T2 - SHATIS 2015 - 3rd International conference on structural health assessment of timber structures CY - Wroclaw, Poland DA - 09.09.2015 KW - Holz Konstruktionen KW - Monitoring KW - Langzeitverhalten KW - Erdbebensicherheit KW - Historische Bauwerke KW - Ultrasonic echo imaging KW - Historical timber structures KW - Seismic investigation KW - Dynamic tests KW - Anisotropic wave propagation KW - Extending service life PY - 2015 VL - 1 SP - 1 EP - 12 AN - OPUS4-35178 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Fittschen, U.E.A. A1 - Menzel, M. A1 - Scharf, O. A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Buzanich, Günter A1 - Lopez, V.M. A1 - McIntosh, K. A1 - Streli, C. A1 - Havrilla, G.J. T1 - Observation of X-ray shadings in synchrotron radiation-total reflection X-ray fluorescence using a color X-ray camera JF - Spectrochimica acta B N2 - Absorption effects and the impact of specimen shape on TXRF analysis has been discussed intensively. Model calculations indicated that ring shaped specimens should give better results in terms of higher counts per mass signals than filled rectangle or circle shaped specimens. One major reason for the difference in signal is shading effects. Full field micro-XRF with a color X-ray camera (CXC) was used to investigate shading, which occurs when working with small angles of excitation as in TXRF. The device allows monitoring the illuminated parts of the sample and the shaded parts at the same time. It is expected that sample material hit first by the primary beam shade material behind it. Using the CXC shading could be directly visualized for the high concentration specimens. In order to compare the experimental results with calculation of the shading effect the generation of controlled specimens is crucial. This was achieved by 'drop on demand' technology. It allows generating uniform, microscopic deposits of elements. The experimentally measured shadings match well with those expected from calculation. KW - TXRF KW - Full field micro-XRF KW - Color X-ray camera PY - 2014 DO - https://doi.org/10.1016/j.sab.2014.06.025 SN - 0584-8547 SN - 0038-6987 VL - 99 SP - 179 EP - 184 PB - Elsevier CY - Amsterdam AN - OPUS4-31180 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neumann, Patrick P. A1 - Kohlhoff, Harald A1 - Hüllmann, Dino A1 - Lilienthal, A.J. A1 - Kluge, Martin T1 - Bringing Mobile Robot Olfaction to the Next Dimension – UAV-based Remote Sensing of Gas Clouds and Source Localization T2 - Proceedings of the 2017 IEEE International Conference on Robotics and Automation (ICRA) N2 - This paper introduces a novel robotic platform for aerial remote gas sensing. Spectroscopic measurement methods for remote sensing of selected gases lend themselves for use on mini-copters, which offer a number of advantages for inspection and surveillance. No direct contact with the target gas is needed and thus the influence of the aerial platform on the measured gas plume can be kept to a minimum. This allows to overcome one of the major issues with gas-sensitive mini-copters. On the other hand, remote gas sensors, most prominently Tunable Diode Laser Absorption Spectroscopy (TDLAS) sensors have been too bulky given the payload and energy restrictions of mini-copters. Here, we introduce and present the Unmanned Aerial Vehicle for Remote Gas Sensing (UAV-REGAS), which combines a novel lightweight TDLAS sensor with a 3-axis aerial stabilization gimbal for aiming on a versatile hexacopter. The proposed system can be deployed in scenarios that cannot be addressed by currently available robots and thus constitutes a significant step forward for the field of Mobile Robot Olfaction (MRO). It enables tomographic reconstruction of gas plumes and a localization of gas sources. We also present first results showing the gas sensing and aiming capabilities under realistic conditions. T2 - IEEE International Conference on Robotics and Automation (ICRA) CY - Singapore DA - 29.05.2017 KW - Tunable Diode Laser Absorption Spectroscopy (TDLAS) KW - 3-axis gimbal KW - Mobile Robot Olfaction KW - Tomographic reconstruction of gas plumes KW - Localization of gas sources KW - Aerial platform PY - 2017 SN - 978-1-5090-4632-4 SP - 3910 EP - 3916 PB - IEEE AN - OPUS4-40545 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kuhne, Maren A1 - Dippong, Martin A1 - Flemig, Sabine A1 - Hoffmann, Katrin A1 - Petsch, K. A1 - Schenk, J.A. A1 - Kunte, Hans-Jörg A1 - Schneider, Rudolf T1 - Comparative characterization of mAb producing hapten-specific hybridoma cells by flow cytometric analysis and ELISA JF - Journal of immunological methods N2 - A novel method that optimizes the screening for antibody-secreting hapten-specific hybridoma cells by using flow cytometry is described. Cell clones specific for five different haptens were analyzed. We selectively double stained and analyzed fixed hybridoma cells with fluorophore-labeled haptens to demonstrate the target-selectivity, and with a fluorophore-labeled anti-mouse IgG antibody to characterize the level of surface expression of membrane-bound IgGs. ELISA measurements with the supernatants of the individual hybridoma clones revealed that antibodies from those cells, which showed the highest fluorescence intensities in the flow cytometric analysis, also displayed the highest affinities for the target antigens. The fluorescence intensity of antibody-producing cells corresponded well with the produced antibodies' affinities toward their respective antigens. Immunohistochemical staining verified the successful double labeling of the cells. Our method makes it possible to perform a high-throughput screening for hybridoma cells, which have both an adequate IgG production rate and a high target affinity. KW - Immunization KW - Hapten KW - Monoclonal antibodies KW - Hybridoma KW - Flow cytometry KW - ELISA KW - Estradiol KW - Estrone KW - Digoxigenin KW - Zearalenone KW - Aflatoxin KW - CLSM PY - 2014 DO - https://doi.org/10.1016/j.jim.2014.07.004 SN - 0022-1759 SN - 1872-7905 VL - 413 SP - 45 EP - 56 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-32322 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -