TY - JOUR A1 - Belsey, N. A. A1 - Cant, D. J. H. A1 - Minelli, C. A1 - Araujo, J. R. A1 - Bock, B. A1 - Brüner, P. A1 - Castner, D. G. A1 - Ceccone, G. A1 - Counsell, J. D. P. A1 - Dietrich, Paul M. A1 - Engelhardt, M. H. A1 - Fearn, S. A1 - Galhardo, C. E. A1 - Kalbe, H. A1 - Kim, J. W. A1 - Lartundo-Rojas, L. A1 - Luftman, H. S. A1 - Nunney, T. S. A1 - Pseiner, J. A1 - Smith, E. F. A1 - Spampinato, V. A1 - Sturm, J. M. A1 - Thomas, A. G. A1 - Treacy, J. P. W. A1 - Veith, L. A1 - Wagstaffe, M. A1 - Wang, H. A1 - Wang, M. A1 - Wang, Y.-C. A1 - Werner, W. A1 - Yang, L. A1 - Shard, A. G. T1 - Versailles Project on Advanced Materials and Standards Interlaboratory Study on Measuring the Thickness and Chemistry of Nanoparticle Coatings Using XPS and LEIS JF - The Journal of Physical Chemistry C N2 - We report the results of a Versailles Project on Advanced Materials and Standards (VAMAS) interlaboratory study on the measurement of the shell thickness and chemistry of nanoparticle coatings. Peptide-coated gold particles were supplied to laboratories in two forms: a colloidal suspension in pure water and particles dried onto a silicon wafer. Participants prepared and analyzed these samples using either X-ray photoelectron spectroscopy (XPS) or low energy ion scattering (LEIS). Careful data analysis revealed some significant sources of discrepancy, particularly for XPS. Degradation during transportation, storage, or sample preparation resulted in a variability in thickness of 53%. The calculation method chosen by XPS participants contributed a variability of 67%. However, variability of 12% was achieved for the samples deposited using a single method and by choosing photoelectron peaks that were not adversely affected by instrumental transmission effects. The study identified a need for more consistency in instrumental transmission functions and relative sensitivity factors since this contributed a variability of 33%. The results from the LEIS participants were more consistent, with variability of less than 10% in thickness, and this is mostly due to a common method of data analysis. The calculation was performed using a model developed for uniform, flat films, and some participants employed a correction factor to account for the sample geometry, which appears warranted based upon a simulation of LEIS data from one of the participants and comparison to the XPS results. KW - VAMAS KW - Interlaboratory Study KW - Nanoparticle coating KW - XPS KW - LEIS KW - shell thicknss and chemistry PY - 2016 UR - http://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.6b06713 DO - https://doi.org/10.1021/acs.jpcc.6b06713 IS - 120 SP - 24070 EP - 24079 PB - ACS Publications AN - OPUS4-38428 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reed, B. P. A1 - Cant, D.J.H. A1 - Spencer, J. A1 - Carmona-Carmona, A. J. A1 - Bushell, A. A1 - Herrara-Gómez, A. A1 - Kurokawa, A. A1 - Thissen, A. A1 - Thomas, A.G. A1 - Britton, A.J. A1 - Bernasik, A. A1 - Fuchs, A. A1 - Baddorf, A. P. A1 - Bock, B. A1 - Thellacker, B. A1 - Cheng, B. A1 - Castner, D.G. A1 - Morgan, D.J. A1 - Valley, D. A1 - Willneff, E.A. A1 - Smith, E.F. A1 - Nolot, E. A1 - Xie, F. A1 - Zorn, G. A1 - Smith, G.C. A1 - Yasukufu, H. A1 - Fenton, J. L. A1 - Chen, J. A1 - Counsell, J..D.P. A1 - Radnik, Jörg A1 - Gaskell, K.J. A1 - Artyushkova, K. A1 - Yang, L. A1 - Zhang, L. A1 - Eguchi, M. A1 - Walker, M. A1 - Hajdyla, M. A1 - Marzec, M.M. A1 - Linford, M.R. A1 - Kubota, N. A1 - Cartazar-Martínez, O. A1 - Dietrich, P. A1 - Satoh, R. A1 - Schroeder, S.L.M. A1 - Avval, T.G. A1 - Nagatomi, T. A1 - Fernandez, V. A1 - Lake, W. A1 - Azuma, Y. A1 - Yoshikawa, Y. A1 - Shard, A.G. T1 - Versailles Project on Advanced Materials and Standards interlaboratory study on intensity calibration for x-ray photoelectron spectroscopy instruments using low-density polyethylene JF - Journal of Vacuum Science & Technology A N2 - We report the results of a Versailles Project on Advanced Materials and Standards interlaboratory study on the intensity scale calibration of x-ray photoelectron spectrometers using low-density polyethylene (LDPE) as an alternative material to gold, silver, and copper. An improved set of LDPE reference spectra, corrected for different instrument geometries using a quartz-monochromated Al Kα x-ray source, was developed using data provided by participants in this study. Using these new reference spectra, a transmission function was calculated for each dataset that participants provided. When compared to a similar calibration procedure using the NPL reference spectra for gold, the LDPE intensity calibration method achieves an absolute offset of ∼3.0% and a systematic deviation of ±6.5% on average across all participants. For spectra recorded at high pass energies (≥90 eV), values of absolute offset and systematic deviation are ∼5.8% and ±5.7%, respectively, whereas for spectra collected at lower pass energies (<90 eV), values of absolute offset and systematic deviation are ∼4.9% and ±8.8%, respectively; low pass energy spectra perform worse than the global average, in terms of systematic deviations, due to diminished count rates and signal-to-noise ratio. Differences in absolute offset are attributed to the surface roughness of the LDPE induced by sample preparation. We further assess the usability of LDPE as a secondary reference material and comment on its performance in the presence of issues such as variable dark noise, x-ray warm up times, inaccuracy at low count rates, and underlying spectrometer problems. In response to participant feedback and the results of the study, we provide an updated LDPE intensity calibration protocol to address the issues highlighted in the interlaboratory study. We also comment on the lack of implementation of a consistent and traceable intensity calibration method across the community of x-ray photoelectron spectroscopy (XPS) users and, therefore, propose a route to achieving this with the assistance of instrument manufacturers, metrology laboratories, and experts leading to an international standard for XPS intensity scale calibration. KW - X-ray photoelectron spectroscopy KW - Transmission function KW - Intensity scale calibration KW - Reference spectra KW - Low-density polyethylene (LDPE) PY - 2020 DO - https://doi.org/10.1116/6.0000577 VL - 38 IS - 6 SP - 063208 AN - OPUS4-51655 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Reed, B. P. A1 - Cant, D.J.H. A1 - Spencer, S.J. A1 - Carmona-Carmona, A. J. A1 - Bushell, A. A1 - Herrara-Gómez, A. A1 - Kurokawa, A. A1 - Thissen, A. A1 - Thomas, A.G. A1 - Britton, A.J. A1 - Bernasik, A. A1 - Fuchs, A. A1 - Baddorf, A.P. A1 - Bock, B. A1 - Thellacker, B. A1 - Cheng, B. A1 - Castner, D.G. A1 - Morgan, D.J. A1 - Valley, D. A1 - Willneff, E.A. A1 - Smith, E.P. A1 - Nolot, E. A1 - Xie, F. A1 - Zorn, G. A1 - Smith, G.C. A1 - Yasukufu, H. A1 - Fenton, J.L. A1 - Chen, J. A1 - Counsell, J.D.P. A1 - Radnik, Jörg A1 - Gaskell, K.J. A1 - Artyushkova, K. A1 - Yang, L. A1 - Zhang, L. A1 - Eguchi, M. A1 - Walker, M. A1 - Hajdyla, M. A1 - Marzec, M.M. A1 - Linford, M.R. A1 - Kubota, N. A1 - Cortazar-Martinez, O. A1 - Dietrich, P. A1 - Satoh, R. A1 - Schroeder, S.L.M. A1 - Avval, T.G. A1 - Nagatomi, T. A1 - Fernandez, V. A1 - Lake, W. A1 - Azuma, Y. A1 - Yoshikawa, Y. A1 - Compean-Gonzalez, C.L. A1 - Ceccone, G. A1 - Shard, A.G. T1 - ERRATUM: “Versailles project on advanced materials and standards interlaboratory study on intensity calibration for x-ray photoelectron spectroscopy instruments using low-density polyethylene” [J. Vac. Sci. Technol. A 38, 063208 (2020)] JF - Journal of Vacuum Science & Technology A N2 - The lead authors failed to name two collaborators as co-authors. The authors listed should include: Miss Claudia L. Compean-Gonzalez (ORCID: 0000-0002-2367-8450) and Dr. Giacomo Ceccone (ORCID: 0000-0003-4637-0771). These co-authors participated in VAMAS project A27, provided data that were analyzed and presented in this publication (and supporting information), and reviewed the manuscript before submission. KW - X-ray photoelectron spectroscopy KW - Transmission function KW - Low-density polyethylene PY - 2021 DO - https://doi.org/10.1116/6.0000907 VL - 39 IS - 2 SP - 027001 PB - American Vacuum Society AN - OPUS4-52380 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mozetic, M. A1 - Ostrikov, K. A1 - Ruzic, D.N. A1 - Curreli, D. A1 - Cvelbar, U. A1 - Vesel, A. A1 - Primc, G. A1 - Leisch, M. A1 - Jousten, K. A1 - Malyshev, O.B. A1 - Hendricks, J.H. A1 - Kövér, L. A1 - Tagliaferro, A. A1 - Conde, O. A1 - Silvestre, A.J. A1 - Giapintzakis, J. A1 - Buljan, M. A1 - Radic, N. A1 - Drazic, G. A1 - Bernstorff, S. A1 - Biedermann, H. A1 - Kylián, O. A1 - Hanus, J. A1 - Milosevic, S. A1 - Galtayries, A. A1 - Dietrich, Paul A1 - Unger, Wolfgang A1 - Lehocky, M. A1 - Sedlarik, V. A1 - Stana-Kleinschek, K. A1 - Drmota-Petric, A. A1 - Pireaux, J.J. A1 - Rogers, J.W. A1 - Anderle, M. T1 - Recent advances in vacuum sciences and applications JF - Journal of physics D N2 - Recent advances in vacuum sciences and applications are reviewed. Novel optical interferometer cavity devices enable pressure measurements with ppm accuracy. The innovative dynamic vacuum standard allows for pressure measurements with temporal resolution of 2 ms. Vacuum issues in the construction of huge ultra-high vacuum devices worldwide are reviewed. Recent advances in surface science and thin films include new phenomena observed in electron transport near solid surfaces as well as novel results on the properties of carbon nanomaterials. Precise techniques for surface and thin-film characterization have been applied in the conservation technology of cultural heritage objects and recent advances in the characterization of biointerfaces are presented. The combination of various vacuum and atmospheric-pressure techniques enables an insight into the complex phenomena of protein and other biomolecule conformations on solid surfaces. Studying these phenomena at solid–liquid interfaces is regarded as the main issue in the development of alternative techniques for drug delivery, tissue engineering and thus the development of innovative techniques for curing cancer and cardiovascular diseases. A review on recent advances in plasma medicine is presented as well as novel hypotheses on cell apoptosis upon treatment with gaseous plasma. Finally, recent advances in plasma nanoscience are illustrated with several examples and a roadmap for future activities is presented. KW - Vacuum KW - Surface KW - Plasma KW - Interface KW - Nanoscience PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-304884 DO - https://doi.org/10.1088/0022-3727/47/15/153001 SN - 0022-3727 SN - 1361-6463 VL - 47 IS - 15 SP - 153001-1 EP - 153001-23 PB - IOP Publ. CY - Bristol AN - OPUS4-30488 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Frenz, Holger A1 - Gruhn, B. A1 - Dietrich, C. A1 - Lehmann, J. A1 - Krämer, E. A1 - Glaubitz, Steffen A1 - Wimmer, J. A1 - Rehmer, Birgit A1 - Kühn, Hans-Dieter A1 - Breitkreutz, Konrad A1 - Portella, Pedro Dolabella A1 - Hoffmann, E. A1 - Ziebs, Josef T1 - Sphäroguß als Werkstoff für Behälter zur Beförderung, Zwischen- und Endlagerung radioaktiver Stoffe; Untersuchung zu alternativen Eignungsnachweisen - Fachband 3: Werkstoffuntersuchungen, 1989 - 1992 T2 - BAM Forschungsvorhaben 01507 N2 - Gußeisen mit Kugelgraphit und ferritischer bzw. ferritisch-perlitischer Matrix gehören zu einer Werkstoffgruppe, die ausreichende Festigkeiten mit hohen Duktilitäten verbindet. Mit der vorliegenden Arbeit wurden die Kenntnisse über die Zusammenhänge zwischen der chemischen Zusammensetzung, der Gefügeausbildung und den mechanischen Eigenschaften erweitert. Dabei wurden sowohl unterschiedliche Gießverfahren (Sand- und Kokillenguß) in der Herstellung, als auch die Auswirkungen von Umwandlungsprozessen im Gefüge infolge von Wärmebehandlungen diskutiert. Die statistische Auswertung von Einzelergebnissen aus der qualitätssichernden Begutachtung von Lager- und Transportbehältern für radioaktive Stoffe wurden durch mechanische und bruchmechanische Untersuchungen an 24 Werkstoffsorten aus Gußeisen mit Kugelgraphit ergänzt. KW - Eignungsnachweis KW - Endlagerung KW - Lagerbehälter KW - Radioaktiver Stoff KW - Sphäroguß (GGG-40) KW - Transportbehälter KW - Zwischenlagerung PY - 1992 N1 - Das Projekt wurde gefördert vom Bundesminister für Forschung und Technologie (BMFT); Förderkennzeichen: KWA 79052. SP - 1 EP - 178 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-59950 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Protasov, E A1 - Noah, J O A1 - Kästle Silva, J O A1 - Mies, U S A1 - Hervé, V A1 - Dietrich, C A1 - Lang, K A1 - Mikulski, L A1 - Platt, K A1 - Poehlein, A A1 - Köhler-Ramm, T A1 - Miambi, E A1 - Boga, H I A1 - Feldewert, C A1 - Ngugi, G K A1 - Plarre, Rüdiger A1 - Sillam-Dussès, D A1 - Šobotník, J A1 - Daniel, R A1 - Brune, A T1 - Diversity and taxonomic revision of methanogens and other archaea in the intestinal tract of terrestrial arthropods JF - Frontiers in Microbiology N2 - Methane emission by terrestrial invertebrates is restricted to millipedes, termites, cockroaches, and scarab beetles. The arthropod-associated archaea known to date belong to the orders Methanobacteriales, Methanomassiliicoccales, Methanomicrobiales, and Methanosarcinales, and in a few cases also to nonmethanogenic Nitrososphaerales and Bathyarchaeales. However, all major host groups are severely undersampled, and the taxonomy of existing lineages is not well developed. Full-length 16S rRNA gene sequences and genomes of arthropod-associated archaea are scarce, reference databases lack resolution, and the names of many taxa are either not validly published or under-classified and require revision. Here, we investigated the diversity of archaea in a wide range of methane-emitting arthropods, combining phylogenomic analysis of isolates and metagenome-assembled genomes (MAGs) with amplicon sequencing of full-length 16S rRNA genes. Our results allowed us to describe numerous new species in hitherto undescribed taxa among the orders Methanobacteriales (Methanacia, Methanarmilla, Methanobaculum, Methanobinarius, Methanocatella, Methanoflexus, Methanorudis, and Methanovirga, all gen. nova), Methanomicrobiales (Methanofilum and Methanorbis, both gen. nova), Methanosarcinales (Methanofrustulum and Methanolapillus, both gen. nova), Methanomassiliicoccales (Methanomethylophilaceae fam. nov., Methanarcanum, Methanogranum, Methanomethylophilus, Methanomicula, Methanoplasma, Methanoprimaticola, all gen. nova), and the new family Bathycorpusculaceae (Bathycorpusculum gen. nov.). Reclassification of amplicon libraries from this and previous studies using this new taxonomic framework revealed that arthropods harbor only CO2 and methyl-reducing hydrogenotrophic methanogens. Numerous genus-level lineages appear to be present exclusively in arthropods,suggesting long evolutionary trajectories with their termite, cockroach, and millipede hosts, and a radiation into various microhabitats and ecological nichesprovided by their digestive tracts (e.g., hindgut compartments, gut wall, or anaerobic protists). The distribution patterns among the different host groups are often complex, indicating a mixed mode of transmission and a parallel evolution of invertebrate and vertebrate-associated lineages. KW - Nitrososphaerales KW - Archaea KW - Methanogens KW - Gut microbiota KW - Termites KW - Cockroaches KW - Millipedes KW - Bathyarchaeia PY - 2023 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-588230 DO - https://doi.org/10.3389/fmicb.2023.1281628 SN - 1664-302X VL - 14 SP - 1 EP - 21 PB - Frontiers AN - OPUS4-58823 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Goebbels, Jürgen A1 - Klobes, Peter A1 - Bartels, J. A1 - Dietrich, H.-G. T1 - Analyse natürlicher Wegsamkeiten und ihrer Stimulationsmöglichkeiten in einem zementierten Aquifer durch Kombination von Röntgen-CT mit Quecksilberporosimetrie JF - Zeitschrift für angewandte Geologie KW - Quecksilberporosimetrie KW - Computertomographie KW - Geothermie KW - Stimulation KW - Anhydritzement KW - Rhätsandstein KW - Allermöhe PY - 2000 SN - 0044-2259 N1 - Sprachen: Deutsch/Englisch - Languages: German/English VL - 46 IS - 3 SP - 153 EP - 156 PB - Schweizerbart CY - Stuttgart AN - OPUS4-1037 LA - mul AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Witke, Klaus A1 - Dietrich, D. A1 - Marx, G. A1 - Götze, J. A1 - Rößler, R. T1 - Cathodoluminescence and RAMAN studies on permineralisations of medullosa sp. T2 - Kurzreferateband der 11. Tagung Festkörperanalytik T2 - 11. Tagung Festkörperanalytik CY - Chemnitz, Germany DA - 2001-06-25 PY - 2001 PB - GDCh CY - Frankfurt am Main AN - OPUS4-1057 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Witke, Klaus A1 - Dietrich, D. A1 - Götze, J. A1 - Rößler, R. A1 - Marx, G. T1 - Cathodoluminescence microscopy and micro-RAMAN spectroscopy on Medullos stellata v. COTTA - a contribution to the study of the permineralisation process JF - Fresenius' journal of analytical chemistry KW - CL microscopy KW - CL Spectroscopy KW - RAMAN spectroscopy KW - Permineralisation PY - 2001 SN - 0937-0633 PB - Springer CY - Berlin AN - OPUS4-1079 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Darlatt, Erik A1 - Nefedov, A. A1 - Traulsen, C.H.-H. A1 - Poppenberg, J. A1 - Richter, S. A1 - Dietrich, Paul A1 - Lippitz, Andreas A1 - Illgen, René A1 - Kühn, Julius A1 - Schalley, C.A. A1 - Wöll, Ch. A1 - Unger, Wolfgang T1 - Interperetation of experimental N K NEXAFS of azide, 1,2,3-triazole and terpyridyl groups by DFT spectrum simulations JF - Journal of electron spectroscopy and related phenomena N2 - Experimental N K-edge NEXAFS data of surface immobilized azide, 1,2,3-triazole and terpyridyl groups are interpreted with the help of DFT spectrum simulations. Assignments of π* resonances in experimental N K-edge NEXAFS spectra to nitrogen atoms within these functional groups have been made. The azide was immobilized on gold as the head group of a thiol SAM, 1,2,3-triazole was formed on this SAM by click reaction and terpyridyl groups were introduced as substituents of the acetylene used for the click reaction. For azide-terminated molecules, DFT spectrum simulations are found to be useful to find measurement conditions delivering experimental N K-edge NEXAFS data with negligible X-ray damage. The 1,2,3-triazole group is found to be rather stable under X-ray irradiation. KW - N K-edge NEXAFS KW - XANES KW - Surface click chemistry KW - Density functional theory KW - Azide KW - 1,2,3-Triazole PY - 2012 DO - https://doi.org/10.1016/j.elspec.2012.09.008 SN - 0368-2048 SN - 1873-2526 VL - 185 IS - 12 SP - 621 EP - 624 PB - Elsevier CY - Amsterdam AN - OPUS4-27774 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Peplinski, Burkhard A1 - Wenzel, J. A1 - Schultze, Dietrich T1 - Certification of the phase composition of a BAM reference material by an interlaboratory comparison applying X-ray and neutron diffraction T2 - Symposium "Reference Materials for Technologies in the New Millenium" T2 - Symposium "Reference Materials for Technologies in the New Millenium" CY - Berlin, BAM, Germany DA - 2000-05-22 PY - 2000 SP - 1(?) EP - 13(?) AN - OPUS4-12600 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Witke, Klaus A1 - Götze, J. A1 - Rößler, R. A1 - Dietrich, D. A1 - Marx, G. T1 - Raman and cathodoluminescence spectroscopic investigations on Permian fossil wood from Chemnitz - a contribution to the study of the permineralisation process JF - Spectrochimica acta B N2 - Samples of different three-dimensionally preserved fossil plants (Medullosa sp., Dadoxylon sp., Calamodendron striatum, Psaronius sp.) from the Lower Permian petrified forest of Chemnitz were examined with regard to their chemical composition and structural order. Raman spectroscopy and cathodoluminescence microscopy are shown to be powerful tools for such investigations. Silicified wood from Chemnitz–Hilbersdorf generally shows yellow cathodoluminescence (CL) of the cell walls and only weak yellow-brownish CL of the cell lumina. By time-resolved cathodoluminescence spectroscopy, a secondary mineralisation of hydrothermal origin was recognized. The latter is shown by short-lived blue CL at the cell walls extinguishing the yellow signal. Therefore, after the primary silicification step a secondary mineralisation step initiated by hydrothermal processes, seems to have taken place at probably slightly higher temperatures. The resulting silica matrix consists of phanerocrystalline and microcrystalline a-quartz as well as microcrystalline moganite, both partially associated with iron oxides. Dadoxylon sp. is a prominent example for parallel permineralisation by a-quartz and fluorspar, which is outstanding for the Chemnitz Petrified Forest. CL on this samples shows parallel silicification and fluoritisation, followed by infiltration of iron oxides. Permineralised samples show very low percentage of original organic remains. The seed fern Medullosa, for example, shows dispersed carbon, which is mainly restricted to the centres of the typical star-shaped vascular bundles. Raman spectroscopy revealed that these carbonaceous particles are of an anthracite structure. For experimental confirmation coal samples of different rank, especially anthracite from different geological times and localities, were studied by means of Raman spectroscopy. The remaining pith of the vascular bundles is white-coloured and consists of a-quartz and moganite, whereas surrounding tracheides exhibit white and reddish coloured parts. The reddish parts, mainly found in the rays, additionally contain a-Fe2O3 and Fe3O4 among the SiO2 polymorphs of a-quartz and moganite. Sometimes iron oxides could have dominated permineralisation processes as the peak intensities of distinct parts of the samples suggest. KW - Raman spectroscopy KW - Cathodoluminescence microscopy KW - Petrified wood KW - Permineralisation KW - Anthracite PY - 2004 UR - http://www.sciencedirect.com/science?_ob=PublicationURL&_cdi=5287&_pubType=J&_auth=y&_acct=C000049503&_version=1&_urlVersion=0&_userid=963821&md5=ebfde1a480f4ae6a3eb0052a1b8e7c2a&jchunk=60#60 DO - https://doi.org/10.1016/j.saa.2003.12.045 SN - 0584-8547 SN - 0038-6987 VL - 60 IS - 12 SP - 2903 EP - 2912 PB - Elsevier CY - Amsterdam AN - OPUS4-4122 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dietrich, J. A1 - Wünsche von Leupoldt, A. A1 - Grabolle, Markus A1 - Resch-Genger, Ute A1 - Heinze, K. T1 - Thermal and photoinduced electron transfer in directional bis(terpyridine)ruthenium(II)-(bipyridine)-platinum(II) complexes JF - European journal of inorganic chemistry N2 - Metalloligands L1 and L2 consisting of directional bis(terpyridine)ruthenium(II) units and bipyridine moieties were constructed by amide formation. From these metalloligands two Ru–Pt heterobimetallic complexes 1 and 2 were derived by a building-block method by means of platination with [PtCl2(dmso)2]. Both bimetallic complexes 1 and 2 feature metal-to-ligand charge transfer (MLCT) absorptions, and emission occurs at room temperature in fluid solution from ³MLCT(Ru) states in all cases. Energy transfer from platinum to ruthenium is observed in 2 but not in 1 (light harvesting). The one-electron-reduced species [1]– and [2]– were prepared by reduction of 1 and 2 with decamethylcobaltocene. EPR spectra and DFT calculations reveal that the spin density is localized at the tpy–CO/Ru (tpy = terpyridine) site in [1]–, whereas it is centered at bpy–CO/Pt (bpy = 2,2'-bipyridine) in [2]–. Efficient photoinduced electron transfer from triethanolamine to 1 and 2 is feasible by excitation at 500 nm [MLCT(Ru)]. KW - Electron transfer KW - Luminescence KW - Platinum KW - Ruthenium KW - N ligands PY - 2013 DO - https://doi.org/10.1002/ejic.201201531 SN - 1434-1948 SN - 1099-0682 VL - 2013 IS - 17 SP - 3009 EP - 3019 PB - Wiley-VCH Verl. CY - Weinheim AN - OPUS4-29301 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Heinrich, Thomas A1 - Traulsen, Christoph Hans-Henning A1 - Darlatt, Erik A1 - Richter, S. A1 - Poppenberg, J. A1 - Traulsen, N.L. A1 - Linder, I. A1 - Lippitz, Andreas A1 - Dietrich, Paul A1 - Dib, B. A1 - Unger, Wolfgang A1 - Schalley, C.A. T1 - The versatility of 'Click' reactions at surfaces: Molecular recognition at interfaces JF - RSC Advances N2 - In order to investigate molecular recognition on surfaces, an azide-functionalized monolayer was deposited on gold. The monolayer was characterized by X-ray photoelectron spectroscopy (XPS) and angle-resolved near-edge X-ray absorption fine structure (NEXAFS) experiments and the decomposition of the azide upon irradiation with X-ray beams was investigated. Subsequently, various alkyne-functionalized host and guest molecules were attached to the azide by 1,3-dipolar cycloaddition. These modified surfaces and their host–guest chemistry were analysed by XPS and angle-resolved NEXAFS. The reversibility of guest binding was shown for one example as a proof of principle. KW - 'Click' reaction KW - Azide-terminated surfaces KW - SAMs KW - Host guest molecules KW - Molecular recognition at interfaces PY - 2014 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-306463 DO - https://doi.org/10.1039/C4RA01730G SN - 2046-2069 VL - 4 IS - 34 SP - 17694 EP - 17702 PB - RSC Publishing CY - London AN - OPUS4-30646 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lohrer, Christian A1 - Eckhardt, Dietrich A1 - Blum, J. T1 - Normenreihe DIN EN 15947 über Feuerwerkskörper JF - DIN-Mitteilungen + Elektronorm N2 - Der vorliegende Bericht gibt einen Überblick über die neue Normenreihe DIN EN 15947 über „Pyrotechnische Gegenstände - Feuerwerkskörper, Kategorien 1, 2 und 3". Es werden der Anwendungsbereich aufgezeigt und wesentliche Änderungen im Vergleich zu der zurückgezogenen und ersetzten Normenreihe DIN EN 14035 über „Feuerwerkskörper" vorgestellt. Die Normenreihe DIN EN 15947 besteht aus den fünf Teilen „Begriffe", „Kategorien und Feuerwerkstypen", „Mindestanforderungen an die Kennzeichnung", „Prüfverfahren" und „Anforderungen an Konstruktion und Funktion" und wurde im Dezember 2010 veröffentlicht. KW - Pyrotechnische Gegenstände KW - Kategorien KW - Prüfverfahren KW - DIN EN 14035 PY - 2011 SN - 0722-2912 SN - 0011-4952 VL - 7 SP - 21 EP - 26 PB - Beuth CY - Berlin AN - OPUS4-23992 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lohrer, Christian A1 - Eckhardt, Dietrich A1 - Blum, J. T1 - Normenreihen DIN EN 16261 für Großfeuerwerk und DIN EN 16256 für Bühnenpyrotechnik JF - DIN-Mitteilungen N2 - Der vorliegende Bericht gibt einen Überblick über die Normenreihen DIN EN 16261 'Pyrotechnische Gegenstände - Feuerwerkskörper, Kategorie 4' und DIN EN 16256 'Pyrotechnische Gegenstände - Pyrotechnische Gegenstände für Bühne und Theater'. Neben der Vorstellung der jeweiligen Anwendungsbereiche werden die wesentlichen Anforderungen an Konstruktion, Funktion und Kennzeichnung aufgezeigt. Des Weiteren werden die Prüf- und Bewertungsmethoden dieser pyrotechnischen Gegenstände dargestellt und miteinander verglichen. Die Normenreihe DIN EN 16261 besteht aus 4 Teilen 'Begriffe', 'Anforderungen', 'Prüfverfahren' und 'Mindestanforderungen an die Kennzeichnung und Gebrauchsanweisung'. Die Normenreihe DIN EN 16256 ist strukturell vergleichbar aufgebaut enthält aber im Vergleich zur Normenreihe DIN EN 16261 einen weiteren Teil zur Unterscheidung der Kategorien T1 und T2. KW - Pyrotechnische Gegenstände KW - Prüfung KW - Bewertung PY - 2015 SN - 0011-4952 IS - März SP - 17 EP - 25 PB - Beuth-Vertrieb CY - Berlin AN - OPUS4-32796 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Dietrich, P. A1 - Beblo-Vranesevic, K. A1 - Kjærvik, Marit A1 - Unger, Wolfgang A1 - Schwibbert, Karin A1 - Hardie, K. A1 - Brown, J. T1 - XPS surface analysis of bacterial samples N2 - This application note presents how EnviroESCA can be used to analyze bacterial samples under near ambient pressure conditions in various states of hydration using different levels of humidity. Such investigations of bacterial cell wall surfaces in their hydrated state are essential for studying biological interfaces at work. The use of innovative near-ambient pressure (NAP-)XPS instrumentation allows the detailed analysis of irregularly-surfaced biofilms. NAP-XPS enables the surface analysis of bacterial samples in their natural hydrated state without complex sample preparation techniques such as freeze-drying or fast-freezing, which are needed for XPS analysis in ultrahigh vacuum. KW - Near ambient pressure XPS KW - Biofilms PY - 2018 UR - http://www.enviroai.com/uploads/1/0/2/8/102861712/xps_surface_analysis_of_bacillus_subtilis_biofilms_final.pdf IS - Application Note #000399 SP - 1 EP - 5 CY - Berlin AN - OPUS4-44588 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stösser, R. A1 - Scholz, G. A1 - Buzaré, J.-Y. A1 - Silly, G. A1 - Nofz, Marianne A1 - Schultze, Dietrich T1 - A magnetic resonance investigation of the process of corundum formation starting from sol-gel precursors JF - Journal of the American ceramic society PY - 2005 SN - 0002-7820 SN - 1551-2916 VL - 88 IS - 10 SP - 2913 EP - 2922 PB - Blackwell Publishing CY - Malden AN - OPUS4-11888 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Nolze, Gert A1 - Dietrich, D. A1 - Lampke, T. A1 - Del-Solar-Velarde, N. A1 - Nickel, D. A1 - Chapoulie, R. A1 - Castillo Butters, L.J. T1 - The potential of EBSD and EDS for ceramics investigations - Case studies on sherds of pre-Columbian pottery JF - archaeometry N2 - The work focuses on the potential of structural and chemical examinations by scanning electron microscopy based methods for archaeometric studies on ceramics. Achieved by a single preparation technique (polished block sections), the feasibility and benefits of electron backscatter diffraction are demonstrated as case studies using polychrome examples of pre-Columbian pottery (Wari, Moche and Cajamarca). Elemental and phase maps allow for separate consideration of clay and temper. Identification of mineral phases and intergrowths of temper particles provide information for clarifying clay procurement and firing techniques with respect to local versus non-local pottery to enlighten trade relations, technological transfer and shared heritage of pre-Columbian cultures. KW - SEM–EDS/EBSD KW - Pre-Columbian ceramics KW - Temper KW - Pseudobrookite KW - Titanite PY - 2017 VL - 60 IS - 3 SP - 489 EP - 501 AN - OPUS4-45096 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -