TY - JOUR A1 - Schmidt, Wolfram A1 - Wend, Dirk A1 - Kühne, Hans-Carsten A1 - Meng, Birgit T1 - Einfluss der Fließmittelmdoifikation auf Prozesse während der frühen Hydratation von selbstverdichtenden Bindemitteln N2 - Selbstverdichtender Beton (SVB) unterscheidet sich wesentlich von Normalbeton in der Höhe der Fließmitteldosierung. Die Funktionsweise von Fließmitteln auf Basis der für SVB üblichen Polycarboxylatether-Fließmittel (PCE) ist heutzutage in der bauchemischen Forschung sehr gut verstanden, allerdings dringt die Kenntnis über die Zusammenhänge nicht immer gleichermaßen umfangreich in die Praxis durch. Anders als frühere Fließmittelwirkgruppen, die auch heute noch einen wesentlichen Anteil am Fließmittelmarkt haben, sind PCEs äußerst vielgestaltig. Die Polymergeometrien können individuell auf die geforderten Leistungseigenschaften für bestimmte Anwendungen abgestimmt werden. Allerdings kann die Auswahl eines Fließmittels für spezifizierte rheologische Eigenschaften gleichsam den anschließenden Hydratationsprozess sehr stark beeinflussen. Der Ladungsdichte des verwendeten PCEs kommt dabei im Zusammenhang mit der Rheologie als auch der frühen Hydratation eine Schlüsselrolle zu. KW - Rheologie KW - Frühe Zementhydratation KW - Polycarboxylatether KW - Vicat KW - Schwinden PY - 2012 SN - 1439-7706 VL - 4 SP - 66 EP - 71 PB - ad-media-Verl. CY - Köln AN - OPUS4-26356 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Priebe, Nsesheye Susan A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten T1 - The SPIN project N2 - Globally, cement and concrete experts are at the cutting-edge to sustainable, green, healthy but nonetheless high-performance concrete. In the present age, concrete is not yet well established in Africa, which öfters the unique opportunity to build up a cement and concrete market based on the highest available state of technology. As this industry needs high level expertise, a central issue in implementation of skilled technology is cross-linking research institutions and laboratories. It should not be neglected that concrete is a product with comparably low transport ranges, which means that an improved concrete market will mainly support the local economy without exceeding financial drains to the international market, thus fostering the fight against poverty, which is an urgent need in most African countries. The SPIN project highlights recent developments in the field of cement and concrete research with impact on the local and global economy. Challenges, future developments and opportunities for the African construction industry are in the focus. The SPIN project is funded by the European Commission (EC) and supported by the African, Caribbean and Pacific (ACP) Group of States under the project body of the ACP Science and Technology Programme. SPIN is acronym for “Spearhead network for Innovative, Clean and Safe Cement and Concrete Technologies”. The project aims to cross-link experts with industry and policy making bodies, aiming to establish sustainable cement and concrete construction in Africa. T2 - Workshop cement and concrete for Africa CY - Berlin, Germany DA - 17.08.2011 PY - 2011 SN - 978-3-9814281-4-8 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. SP - 5 EP - 9 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-24778 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Priebe, Nsesheye Susan A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten ED - Rogge, A. ED - Meng, B. T1 - Cement and concrete development in Africa: the role of the SPIN project T2 - 52. DAfStb-Forschungskolloquium CY - Berlin, Deutschland DA - 2011-11-07 PY - 2011 SN - 978-3-9814281-0-0 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. SP - 339 EP - 344 PB - BAM Bundesanstalt für Materialforschung und -prüfung CY - Berlin AN - OPUS4-25172 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Meng, Birgit A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten ED - Rogge, A. ED - Meng, B. T1 - Aktuelle Forschungsansätze zur Rheologie von Frischbeton T2 - 52. DAfStb-Forschungskolloquium CY - Berlin, Deutschland DA - 2011-11-07 KW - Baustoffe KW - Beton KW - Frischbeton KW - Rheologie PY - 2011 SN - 978-3-9814281-0-0 SP - 33 EP - 39 PB - BAM Bundesanstalt für Materialforschung und -prüfung CY - Berlin AN - OPUS4-25195 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten A1 - Meng, Birgit T1 - Zum Einfluss des Mischungsentwurfs und des Fließmittels auf temperaturbedingte Veränderungen der Rheologie von SVB T2 - 52. DAfStb-Forschungskolloquium, BAM CY - Berlin, Germany DA - 2011-11-07 PY - 2011 AN - OPUS4-25129 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Priebe, Nsesheye Susan A1 - Kühne, Hans-Carsten ED - Alexander, M. G. ED - Beushausen, H.-D. ED - Dehn, F. ED - Moyo, P. T1 - Robustness improvement of fresh concrete and mortar performance for challenging casting environments with focus on sub-Saharan Africa N2 - For various concrete applications, the early properties are a major specification, determining the functioning, the mechanical properties, and the durability of structures. The rheological properties of cementitious systems are depending on the water-cement interaction as well as on interactions of chemical admixtures with the cement hydration. The cement hydration, however, is strongly affected by the environmental boundary conditions, such as the climate or the available equipment for the proportioning and dispersion of concrete. This paper presents strategies for the robustness improvement of fresh properties of cementitious systems for challenging and particularly warm climate conditions. After explaining the basic mechanisms affecting the workability, practical conclusions are drawn with special attention on the circumstances of sub-Saharan Africa, where the climatic conditions are difficult and the casting technology is often limited. Solutions are suggested, how despite the disadvantageous circumstances, highly elaborate engineered concrete and mortar can be applied safely and with consistent quality. T2 - 3rd International conference on concrete repair, rehabilitation and retrofitting III CY - Cape Town, South Africa DA - 03.09.2012 PY - 2012 SN - 978-0-415-89952-9 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. IS - Theme 4 SP - 1324 EP - 1329 PB - CRC Press CY - London, UK AN - OPUS4-26503 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Uzoegbo, H.C. A1 - Priebe, Nsesheye Susan A1 - Kühne, Hans-Carsten A1 - Rogge, Andreas ED - Uzoegbo, H.C. ED - Schmidt, Wolfram T1 - Experiences in an African-European-cooperation project: strengthening research capacity in cement and concrete in Africa N2 - This report is based on a three-year experience as coordinator of the ACP-EU funded SPIN project. The project involved eight African and three European partners. Practical and unforeseeable problems are addressed that occurred during the project implementation and ways how they were successfully solved are reported. The major problems in many African institutions were administrations that are not used to work in multi-national consortia and a lack of institutional support for the African researchers. In Europe a misjudgement of the African boundary conditions as well as inflexible administrations caused problems. Finally the funding scheme did not always allow to easily overcome the high number of unexpected practical problems. A major deficit identified during the project was a general trend in Africa to underestimate the role of research for the development of the continent. Most universities focus on teaching applied sciences, which is without doubt important to cover the market need for qualified staff in the rapidly growing African industries. However, this makes it unattractive for highly qualified performers to conduct research on the continent. Furthermore this leads to the situation that the curricula can only contain second hand knowledge. In order to attract international high level researchers, it is suggested to install multi-national regional excellence research centres that only promote PhD and post-doc research on a level that can cope with highest international excellence. High level research is often perceived as not capable of focusing on immediate actual problems that many African economies have to cope with.. However, it is considered to be very sustainable in terms of autonomy and mastering future challenges. T2 - ACCTA - International conference on advances in cement and concrete technology in Africa 2013 CY - Johannesburg, South Africa DA - 28.01.2013 PY - 2013 SN - 978-3-9815360-3-4 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. SP - 1177 EP - 1184 AN - OPUS4-27762 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ramge, Peter A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten ED - Uzoegbo, H.C. ED - Schmidt, Wolfram T1 - Effect of the storage of cement on early properties of cementitious systems N2 - As soon as cement is mixed with water, the hydration reaction starts to set of. The progression of the hydration process is governed by the amount and the availability of water and its possibility to access the unhydrated cement grain surfaces. For a total hydration cement theoretically requires water amounting approximately 0.38 of its own mass. Nevertheless, due to the cement’s highly hygroscopic nature, already the moisture in the ambient air can cause first hydration reactions to set in upon the cement grain surfaces. Such pre-hydration processes have an effect on the cement's properties. Dpending on the specific conditions during the storage the significance of the impact on certain properties can vary. If cement is consumed soon after production and is transported only short distances in a silo wagon to its final destination for immediate use without further stock transfer, the effects are rather negligible. However, if cement is delivered in bags, transported over long distances, shifted serval times and stored for longer time periods until it is finally consumend, these effects can be quite severe. Due to the actual logistical situation with comparably few cement plants, large delivery distances and partially less developed infrastructures, the latter scenario pictures the situation for the most cases in Africa quite well. In order to verify the relevance of the pre-hydation for practical application, a series of tests was conducted at the German Federal Institute for Materials Research and Testing (BAM). The influence of the cement storage on gresh and hardened concrete properties was investigated for different concrete and mortar types. The investigations show that the impact of the storage conditions is more pronounced for specialized concretes with high sophisticated optimized mixture compositions containing admixtures. Nevertheless, the effects also occur for ordinary concrete and should not be ignored. T2 - ACCTA - International conference on advances in cement and concrete technology in Africa 2013 CY - Johannesburg, South Africa DA - 28.01.2013 KW - Cement KW - Storage KW - Ambient conditions KW - Hydration KW - Pre-hydration KW - Atmospheric humidity PY - 2013 SN - 978-3-9815360-3-4 SP - 339 EP - 347 AN - OPUS4-27757 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Wolfram A1 - Brouwers, H.J.H. A1 - Kühne, Hans-Carsten A1 - Meng, Birgit T1 - The working mechanism of starch and diutan gum in cementitious and limestone dispersions in presence of polycarboxylate ether superplasticizers N2 - Polysaccharides provide high potential to be used as rheology modifying admixtures in mineral binder systems for the construction industry such as concrete or mortar. Since superplasticizers have become state of technology, today, concrete is more and more adjusted to flowable consistencies. This often goes along with the risk of segregation, which can be effectively avoided by adding stabilising agents supplementary to superplasticizers. Stabilising agents are typically based on polysaccharides such as cellulose, sphingan gum, or starch. Starch clearly distinguishes in its effect on rheology from other polysaccharides, mainly due to the strong influence of amylopectin on the dispersion and stabilisation of particles. Based on rheometric investigations on cementitious and limestone based dispersions with different volumetric water to solid ratios, the mode of operation of modified potato starch is explained in comparison to a sphingan gum. It is shown that the stabilising effect of starch in a coarsely dispersed system is mainly depending upon the water to solid ratio and that above a certain particle volume threshold starch mainly affects the dynamic yield stress of dispersions, while plastic viscosity is affected only to a minor degree. Sphingans operate more independent of the particle volume in a coarsely dispersed system and show significantly higher effect on the plastic viscosity than on the yield stress. In systems incorporating superplasticizers, influences of both stabilising agents on yield stress retreat into the background, while both observed polysaccharides maintain their effect on the plastic viscosity. KW - Cement KW - Limestone KW - Rheology KW - Stabilising agent KW - Coarsely dispersed systems KW - Diutan gum KW - Starch ether PY - 2013 DO - https://doi.org/10.3933/ApplRheol-23-52903 SN - 1430-6395 SN - 0939-5059 VL - 23 IS - 5 SP - 52903-1 EP - 52903-12 PB - Kerschensteiner CY - Lappersdorf AN - OPUS4-29932 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Barthel, Maria A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten T1 - Mitigation of the urban heat island effect by self-cooling concrete pavers N2 - Worldwide an increasing migration from rural to urban regions can be observed. Hence cities are growing and as a result the building density and the land sealing rise. Concrete as commonly used building material in urban structures provides a high heat storage capacity. Therefore the microclimate in cities has become warmer than in the surrounding areas. This phenomenon is called Urban Heat Island Effect. To mitigate this situation a large scale application of self-cooling concrete pavers is an approach to reduce the urban heat island effect. Making use of evaporation enthalpy, this new type of pavements counterbalances the absorption of solar radiation and the subsequent transfer of heat to the surrounding environment. The typical double-layer structure of concrete paving stones can be maintained. The mass concrete acts as a water storage layer and is covered by a permeable face concrete. As the different requirements of these layers demand different concrete mixtures, they are developed and optimised for their respective functions. This paper presents some suitable no-slump concrete mixtures that combine a sufficient compressive strength as well as good water transportation properties for the above mentioned approach. KW - Pavement KW - Urban heat island KW - No slump concrete KW - Fibers PY - 2013 SN - 2225-0514 SN - 2224-5790 VL - 4 SP - 35 EP - 39 PB - International Institute for Conservation of Historic and Artistic Works CY - New York, NY, USA AN - OPUS4-29931 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Brouwers, H.J.H. A1 - Kühne, Hans-Carsten A1 - Meng, Birgit T1 - Interactions between PCE and different polysaccharides and influences on the early hydration of cement N2 - ln order to observe the influence of stabilising agents (STA) based on starch and diutan gum, rheometric experiments and setting tests were conducted on cement pastes with and without PCE superpiasticizers. The results show that with regard to yield stress both STAs show differing behaviours in Systems without PCE. In presence of PCE, yield stress infiuences of the STAs retreat into the background. The Vicat results exhibit that STAs can reduce the retard ing effect of PCE. T2 - 1st International conference on the chemistry of construction materials CY - Berlin, Germany DA - 07.10.2013 PY - 2013 SN - 978-3-936028-75-1 N1 - Serientitel: GDCh-Monographien – Series title: GDCh-Monographien VL - 46 SP - 49 EP - 52 AN - OPUS4-30045 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Vasilic, Ksenija A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten A1 - Roussel, N. T1 - Numerical modelling of SCC flow through reinforced sections T1 - Numerische Simulation des Fließverhaltens von SVB durch bewehrte Querschnitte N2 - The study introduces the porous medium model for the simulation of concrete flow through highly-reinforced sections. It shows that numerical simulations can predict concrete behavior during casting and help to avoid expensive mistakes. N2 - Bei der hier dargestellten Untersuchung wird das Modell des porösen Mediums auf die Simulation des Fließverhaltens von Beton durch Querschnitte mit hohem Bewehrungsgrad angewandt. Dabei zeigt sich, dass mit Hilfe numerischer Simulationen das Verhalten des Betons während der Betonage prognostiziert und kostspielige Fehler vermieden werden können. PY - 2015 SN - 0373-4331 SN - 1865-6528 N1 - Sprachen: Deutsch/Englisch - Languages: German/English VL - 81 IS - 03 SP - 50 EP - 55 PB - Bauverl. CY - Gütersloh AN - OPUS4-33151 LA - mul AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Olonade, Kolawole Adisa A1 - Tchetgnia Ngassam, Ines Leana A1 - Mbugua, Rose A1 - Athman Mwende, Carol A1 - Kühne, Hans-Carsten ED - Ludwig, Horst-Michael T1 - Pflanzenbasierte Betonzusatzmittel für Hochleistungsbeton N2 - Während für die Bauwirtschaft in den meisten Ländern der nördlichen Halbkugel die Instandhaltung bestehender Strukturen und Infrastruktur im Vordergrund steht, geht es in vielen Ländern der Südhalbkugel in der Hauptsache um die Schaffung von Bauwerken und Infrastruktur zur Verwirklichung angemessener Lebensbedingungen, was wiederum das schnelle Wirtschaftswachstum weiter befeuert. Beton ist als Massenbaustoff, trotz landläufig anderer Bewertung, aufgrund seines im Vergleich zu anderen Baustoffen günstigen CO2-Footprints und der globalen Verfügbarkeit hierbei aktuell ohne Alternative. Allerdings ist Beton nach Wasser das am zweithäufigsten genutzte Produkt auf Erden [1] und die globale Nachfrage und Produktion steigt dramatisch. Dies hat Konsequenzen für das globale Klima, denn gerade die als Bindemittel eingesetzten Portlandzemente verursachen bei ihrer Herstellung selbst unter modernsten Produktionsbedingungen große Mengen an CO2. Deshalb müssen für zukünftige nachhaltigere Technologien neuartige Betone entwickelt werden, die bei gleicher oder verbesserter Leistungsfähigkeit, einen geringeren Bedarf an Portlandzement aufweisen. Um den CO2-Ausstoß, der mit der Betonherstellung verbunden ist zu minimieren, müssen Anteile an Portlandzement im Bindemittel reduziert und durch nachhaltigere Ersatzstoffe ausgetauscht werden. Darüber hinaus muss das eingesetzte Bindemittel im Beton so effizient wie möglich ausgenutzt werden. Das heißt, ein Bauteil oder Bauwerk sollte gerade so viel Bindemittel enthalten, wie für die Tragfähigkeit und Dauerhaftigkeit erforderlich ist. Hierfür erscheint der Einsatz von leistungsfähigen bauchemischen Produkten unumgänglich. Diese können zum einen die veränderten Verarbeitungseigenschaften, die Zementersatzstoffe mit sich bringen, ausgleichen und gleichzeitig helfen, den Gesamtwassergehalt zu minimieren, so dass das Bindemittel seine maximale Leistungsfähigkeit erzielt. Fließmittel sind aktuell die wichtigsten Zusatzmittel für Beton. Sie reduzieren den Wasserbedarf und ermöglichen, Zement im Beton effizienter auszunutzen. Darüber hinaus sind Stabilisierer wichtig zur Erhöhung der Robustheit, insbesondere im Hinblick auf die bautechnischen Herausforderungen der Zukunft – vom Pumpen über weite Distanzen, dem Spritzen, dem Betonieren bei extremen Klimabedingungen bis hin zum 3D-Druck. T2 - ibausil CY - Weimar, Germany DA - 12.09.2018 KW - Bauchemie KW - Zusatzmittel KW - Rheologie KW - Polysaccharide KW - Akaziengummi KW - Triumfetta Pendrata A. Rich PY - 2018 SN - 978-3-00-059950-7 VL - 20 SP - 1-874 EP - 1-885 CY - Weimar AN - OPUS4-47048 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Leinitz, Sarah A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten ED - Priebe, Nsesheye Susan T1 - Influence of stabilising agents on limestone filler and cement pastes N2 - The paper showed that the STA behave completely different in pastes with LSF and cement, respectively, as well as with or without PCE. While STA can affect plastic viscosity and yield stress in LSF and cement pastes, the addition of PCE causes that the STA have mainly an impact on plastic viscosity, except DGUM and ST-low. The performance of STA in LSF and cementitious systems can vary greatly due to different ionic strengths of the liquid phase. The charges due to modification of the starches have an intense influence on the rheological properties in pastes. The combined use of PCE and STA can lead to a significant increase of the plastic viscosity without a strong effect to the yield stress. For the evaluation of the effectivity of STA the ionic strength of the liquid phase and the solid volume fraction of the binder have to be taken into account. Further influences can arise from grain size and aggregate content as well as the temperature, which were not discussed in this paper. T2 - 3rd Symposium on Knowledge Exchange for Young Scientists (KEYS) CY - Johannesburg, South Africa DA - 26.06.2017 KW - Stabilising agent KW - Limestone filler KW - Cement PY - 2017 SN - 978-3-9818270-7-1 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. VL - 3 SP - 143 EP - 146 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-41000 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Wolfram A1 - Brouwers, H.J.H. A1 - Kühne, Hans-Carsten A1 - Meng, Birgit T1 - Effects of the characteristics of high range water reducing agents and the water to powder ratio on rheological and setting behavior of self-consolidating concrete N2 - To design robust self-consolidating concrete (SCC) for various environmental conditions, it is essential to understand the relevant mechanisms that control the flow performance. This paper depicts how high range water reducing agents (HRWRAs) interact with clinker and hydration phases, and it discusses the important role of the charge density of polycarboxylic HRWRAs in the way the rheology is affected. Based on the rheometric investigations on SCC mixture compositions with different water to powder ratios (w/p) and observations of their pastes' Vicat setting times, the study shows that increasing charge densities of the HRWRA and decreasing w/p reduce the flow retention and have lesser retarding effect on the setting. Based on the test results and discussions optimization procedures for the mixture composition and the HRWRA modification are suggested to achieve optimized performance for varying environmental situations and highest robustness for specific conditions. KW - Polycarboxylate KW - HRWRA KW - Robustness KW - Rheology KW - Self-consolidating concrete PY - 2014 DO - https://doi.org/10.1520/ACEM20130094 SN - 2165-3984 VL - 3 IS - 2 SP - 1 EP - 15 PB - ASTM International CY - West Conshohocken, Pa., USA AN - OPUS4-30388 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten T1 - Verbesserung der Verarbeitungseigenschaften fließfähiger Betone bei veränderlichen Temperaturen T2 - Rheologie Workshop und Kolloquium CY - Regensburg, Germany DA - 2010-03-10 PY - 2010 AN - OPUS4-21935 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Wolfram A1 - Brouwers, H.J.H. A1 - Kühne, Hans-Carsten A1 - Meng, Birgit T1 - Influences of superplasticizer modification and mixture composition on the performance of self-compacting concrete at varied ambient temperatures N2 - The fresh behaviour of self-compacting concrete (SCC) at varying temperatures differs from that of normal vibrated concrete. This is because the rheology of SCC depends not only on degree of cement hydration, but also on the adsorption of superplasticizers – mostly polycarboxylate based polymers (PCE) -, which is affected by the time and hydration progress. Due to the variety of PCEs and mixture compositions for SCC a prediction of the rheology at varying temperatures is complicated. The charge densities of PCEs as well as the water to solid ratio in the paste are identified to be the main decisive parameters for robust fresh concrete properties. Rheometric concrete investigations with different SCC mixture compositions and varied anionic charge densities of the PCE were conducted. SCC which is rich in powder components showed robust performance at low temperatures while SCC with low powder content was favourable at high temperatures. High charge density PCE pointed out to be very robust at low temperatures but at high temperatures it significantly reduced the flow retention. Low charge density PCE could not generate self-compacting properties at low temperatures but retained the flow performance over sufficiently long time. Based on considerations about particle interactions and adsorption mechanisms of PCEs, the relevant processes are explained and options for the development of robust mixture compositions for individual temperature ranges are itemised. KW - Polycarboxylate ether KW - Temperature KW - Rheology KW - Mixture composition KW - Self-compacting concrete PY - 2014 DO - https://doi.org/10.1016/j.cemconcomp.2013.12.004 SN - 0958-9465 SN - 1873-393X VL - 49 SP - 111 EP - 126 PB - Elsevier Ltd. CY - Barking, Essex AN - OPUS4-30552 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Priebe, Nsesheye Susan A1 - Kühne, Hans-Carsten ED - Uzoegbo, H.C. ED - Schmidt, Wolfram T1 - Rheological optimisation for flowable mixture compositions specified for African boundary conditions N2 - To date concrete technology is not yet well established in sub-Saharan Africa but considering the construction technological challenges of the region, without doubt, concrete will play a major role in future. The social, economic, and geographic boundary conditions distinguish greatly from those that can be found in many other regions of the world, where concrete is considerably well established. Düring the last decades, concrete technology underwent a rapid evolution process, but in most countries, where concrete is already well established, innovations are difficult to be brought into practice, Africa, currently has the opportunity and potential, of directly establishing the best available practice in concrete technology. The conclusion is drawn that self-compacting concrete (SCC) or highly flowable concrete is a reasonable solution for African construction sites. Since on most African construction sites the disadvantageous concreting environment is the most crucial factor for the concrete quality, the outstanding workability properties outweigh any disadvantages of SCC. Based on this consideration, concepts are developed, how to bring about robust SCC cost-efficiently and reliably into practice as pre-mixed dry compound under consideration of local materials such as rice husk ashes, bagasse ashes, natural pozzolans, cassava starch and lignosulphonate. T2 - ACCTA - International conference on advances in cement and concrete technology in Africa 2013 CY - Johannesburg, South Africa DA - 28.01.2013 KW - Mixture composition KW - Rheology KW - Climatic conditions KW - Admixtures KW - Additions PY - 2013 SN - 978-3-9815360-3-4 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. SP - 359 EP - 366 AN - OPUS4-27764 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Vasiliou, Eleni A1 - Schmidt, Wolfram A1 - Stefanidou, Maria A1 - Kühne, Hans-Carsten A1 - Rogge, Andreas ED - Amziane, Sofiane ED - Sonebi, Mohammed ED - Charlet, Karine T1 - Effectiveness of starch ethers as rheology modifying admixtures for cement based systems N2 - Polysaccharides are important rheology modifying admixtures in the building material sector. The use of starch is becoming increasingly important, due to many ecological and economic advantages. In the construction sector, starch ethers are being used as thickeners and as means to increase the yield stress. The starch ethers that are available on the market differ in their behaviour, which can vary greatly depending upon the binder system and mortar composition, e.g. solid volume content, binder type, additional admixtures. In view of the limited knowledge about the influence of molecular modifications associated with cement based systems, some fundamental rheological functional mechanisms were analysed in this study. The differently modified starch ethers used were derived from potatoes. They varied in their charges and degrees of hydroxypropylation. The setting and the flow behaviour of all examined variations of starch ethers were analysed in cement pastes. In order to illustrate the effects of the starch ethers that were used, the water-cement ratio (w/c) was held constant in all the mixtures [Schmidt 2012]. The results indicated significant differences in setting and flow behaviour. T2 - Second International RILEM Conference on Bio-based Building Materials CY - Clermont-Ferrand, France DA - 21.06.2017 KW - Rheology KW - Polysaccharides KW - Cement KW - Concrete KW - Starch KW - Polycarboxylate PY - 2017 SN - 978-2-35158-192-6 SP - 81 EP - 85 PB - RILEM S.A.R.L CY - Paris, France AN - OPUS4-43548 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Wolfram A1 - Brouwers, H.J.H. A1 - Kühne, Hans-Carsten A1 - Meng, Birgit T1 - Interactions of polysaccharide stabilising agents with early cement hydration without and in the presence of superplasticizers N2 - Polysaccharides are incorporated into cement based Systems in order to modify the rheological properties. Typically, cellulose ethers, sphingan gums, guar gum or starch ethers are applied. Depending upon their chemistry, molecular architecture, and adsorption tendency, polysaccharides interact differently with the entire cementitious system. Some stabilising agents like diutan gum mainly affect the cementitious paste; other stabilising agents like starch tend to interact with the sand fraction and even with the coarse aggregates. Cellulose and guar gum shows more diverse performances. Typically stabilising admixtures like polysaccharides are used, when sophisticated rheological properties are adjusted. Therefore, polysaccharides are often used in combination with superplasticisers, which are added to reduce the yield stress of concrete. This can cause interactions, particularly when the stabilising Agent shows a strong tendency to adsorb on particle surfaces. Adsorptive stabilising agents may reduce the amount of adsorbed superplasticisers, thus affecting both viscosity and yield stress, while non-adsorptive stabilising agents mainly affect the plastic viscosity independently of the superplasticiser. Due to the strong influence of superplasticisers on the yield stress, influences of the stabilising agent on the yield stress retreat into the background, so that their major effect is an increase of the plastic viscosity. The paper provides a comprehensive overview of how different polysaccharide superplasticisers affect cementitious flowable systems and points out the challenges of the combined use of polysaccharides and superplasticisers. Based on rheometric experiments and observations of the hydration process, time dependent effects on the workability as well as of the hydration of cement are presented and discussed. KW - Concrete KW - Polysaccharides KW - Rheology KW - Stabilising agents KW - Starch KW - Sphingan PY - 2017 DO - https://doi.org/10.1016/j.conbuildmat.2016.11.022 SN - 0950-0618 SN - 1879-0526 VL - 139 SP - 584 EP - 593 PB - Elsevier AN - OPUS4-40597 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -