TY - JOUR A1 - Vogel, Christian A1 - Sekine, R. A1 - Steckenmesser, D. A1 - Lombi, E. A1 - Herzel, Hannes A1 - Zuin, L. A1 - Wang, D. A1 - Felix, R. A1 - Adam, Christian T1 - Combining diffusive gradients in thin films (DGT) and spectroscopic techniques for the determination of phosphorus species in soils N2 - A wide range of methods are used to estimate the plant-availability of soil phosphorus (P). Published research has shown that the diffusive gradients in thin films (DGT) technique has a superior correlation to plant-available P in soils compared to standard chemical extraction tests. In order to identify the plantavailable soil P species, we combined DGT with infrared and P K- and L2,3-edge X-ray adsorption near edge structure (XANES) spectroscopy. This was achieved by spectroscopically investigating the dried binding layer of DGT devices after soil deployment. All three spectroscopic methods were able to distinguish between different kinds of phosphates (poly-, trimeta-, pyro- and orthophosphate) on the DGT binding layer. However, infrared spectroscopy was most sensitive to distinguish between different types of adsorbed inorganic and organic phosphates. Furthermore, intermediates of the time-resolved hydrolysis of trimetaphosphate in soil could be analyzed. KW - Phosphorus plant-availability KW - X-ray adsorption near-edge structure (XANES) spectroscopy KW - Infrared spectroscopy KW - Diffusive gradients in thin films (DGT) PY - 2019 DO - https://doi.org/10.1016/j.aca.2019.01.037 SN - 0003-2670 VL - 1057 SP - 80 EP - 87 PB - Elsevier AN - OPUS4-47471 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Vogl, Jochen A1 - Yim, Y.-H. A1 - Lee, K.-S. A1 - Goenaga-Infante, H A1 - Malinovskiy, D. A1 - Hill, S. A1 - Ren, T. A1 - Wang, J. A1 - Vocke, R. D. A1 - Murphy, K. E. A1 - Nonose, N. A1 - Rienitz, O. A1 - Noordmann, J. T1 - Certification of ERM-EB400, the first matrix reference material for lead isotope amount ratios, and ERM-AE142, a lead solution providing a lead isotopic composition at the edge of natural variation N2 - Lead isotope amount ratios are commonly used in diverse fields such as archaeometry, geochemistry and forensic science. Currently, five reference materials with certified lead isotope amount ratios are available, namely NIST SRM 981, 982 and 983, GBW-04442 and NMIJ 3681-a. Only NIST SRM 981 and NMIJ 3681-a have approximately natural isotopic compositions, and NIST SRM 981 is predominantly used for correcting mass discrimination/mass fractionation in the applied mass spectrometric procedures. Consequently, there is no other certified reference material available to be used for validation and/or quality control of the analytical procedures applied to lead isotope amount ratio measurements. To fill this gap, two new reference materials have been produced and certified for their lead isotope amount ratios. For both certified reference materials, complete uncertainty budgets have been calculated and SI traceability has been established. This provides the users with independent means for validating and verifying their analytical procedures and for conducting quality control measures. ERM-EB400 is a bronze material with a nominal lead mass fraction of 45 mg kg-1 and certified lead isotope amount ratios of n(206Pb)/n(204Pb) = 18.072(17) mol mol-1, n(207Pb)/n(204Pb) = 15.578(18) mol mol-1 and n(208Pb)/n(204Pb) = 38.075(46) mol mol-1 with the associated expanded uncertainties (k = 2) given in brackets. ERM-AE142 is a high-purity solution of lead in 2% nitric acid with a nominal mass fraction of 100 mg kg-1 and certified Pb isotope amount ratios of n(206Pb)/n(204Pb) = 21.114(17) mol mol-1, n(207Pb)/n(204Pb) = 15.944(17) mol mol-1 and n(208Pb)/n(204Pb) = 39.850(44) mol mol-1 with the associated expanded uncertainties (k = 2) given in brackets. Both materials are specifically designed to fall within the natural lead isotopic variation and to assist users with the validation and verification of their analytical procedures. Note that while one of these reference materials requires the chemical separation of Pb from its matrix (ERM-EB400), the other does not (ERM-AE142). As additional information, δ208/206PbNIST SRM981 values are provided for both materials. For ERM-AE142, a delta value of δ208/206PbNIST SRM981 = -28.21(30) ‰ was obtained, and for ERM-EB400, a delta value of δ208/206PbNIST SRM981 = -129.47(38) ‰ was obtained, with the associated expanded uncertainties (k = 2) given in brackets. KW - Lead isotope variations KW - Radiogenic isotopes KW - Isotope reference material KW - Metrology in chemistry KW - Measurement uncertainty PY - 2019 DO - https://doi.org/10.1111/ggr.12253 SN - 1751-908X SN - 1639-4488 VL - 43 IS - 1 SP - 23 EP - 37 PB - John Wiley & Sons AN - OPUS4-47383 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Abraham, O. A1 - Niederleithinger, Ernst A1 - Chapeleau, X. A1 - Klikowicz, P. A1 - Brühwiler, E. A1 - Bassil, A. A1 - Wang, Xin A1 - Chakraborty, J. A1 - Bayane, I. A1 - Leduc, D. A1 - Salamak, M. A1 - Katunin, A. A1 - Sørensen, J.D. T1 - Addressing the need to monitor concrete fatigue with nondestructive testing: Results of infrastar European project N2 - Fatigue is one of the most prevalent issues, which directly influences the service life expectancy of concrete structures. Fatigue has been investigated for years for steel structures. However, recent findings suggest that concrete structures may also be significantly subjected to fatigue phenomena that could lead to premature failure of certain structural elements. To date, fatigue of reinforced concrete has been given little focus. Knowledge on the influence factors and durability/capacity effects on this material should be improved. Current technological means to measure fatigue in civil structures like bridges and wind turbines (both onshore and offshore) are outdated, imprecise and inappropriate. Meanwhile, this topic has got much more attention as time-variant loading on concrete structures plays an increasing role, e.g. in bridges with increasing traffic and heavier trucks, and for wind turbines for renewable energy production, e.g. for offshore wind turbine support structures affected by wind and waves. The European Innovative Training Networks (ITN) Marie Skłodowska-Curie Actions project INFRASTAR (Innovation and Networking for Fatigue and Reliability Analysis of Structures - Training for Assessment of Risk) provides research training for 12 PhD students. The project aims to improve knowledge for optimizing the design of new structures as well as for more realistic verification of structural safety and more accurate prediction of the remaining fatigue lifetime of existing concrete structures. First, the INFRASTAR research framework is detailed. Then it will be exemplified through the presentation of the major results of the four PhD students involved in the work package dealing with auscultation and monitoring. This includes the development and improvement of Fiber Optics (FO) and Coda Wave Interferometry (CWI) for crack sizing and imagery, new sensor technologies and integration, information management, monitoring strategy for fatigue damage investigation and lifetime prediction. T2 - SMT and NDT-CE 2018 CY - New Brunswick, NJ, USA DA - 27.08.2018 KW - Concrete KW - Fatigue KW - Crack KW - Monitoring KW - Non-destructive testing PY - 2019 UR - https://asnt.org/smt18papers SN - 978-1-57117-456-7 VL - 11/19 SP - 2 EP - 13 PB - The American Society for Nondestructive Testing, Inc. CY - Columbus, OH, USA AN - OPUS4-47237 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Gao, S. A1 - Hou, J. A1 - Deng, Z. A1 - Wang, T. A1 - Beyer, Sebastian A1 - de Oliveira Guilherme Buzanich, Ana A1 - Richardson, J. J. A1 - Rawal, A. A1 - Seidel, R. A1 - Zulkifli, M. Y. A1 - Li, W. A1 - Bennett, T. D. A1 - Cheetham, A. K. A1 - Liang, K. T1 - Improving the Acidic Stability of Zeolitic Imidazolate Frameworks by Biofunctional Molecules N2 - Zeolitic imidazolate frameworks (ZIFs) have been widely investigated for their use in separation, gas adsorption, catalysis, and biotechnology. Their practical applications, however, can be hampered by their structural instability in humid acidic conditions. Here, guided by density functional theory calculations, we demonstrate that the acidic stability of two polymorphic ZIFs (i.e., ZIF-8 and ZIF-L) can be enhanced by the incorporation of functional groups on polypeptides or DNA. A range of complementary synchrotron investigations into the local chemical structure and bonding environment suggest that the enhanced acidic stability arises from the newly established coordinative interactions between the Zn centers and the inserted carboxylate (for polypeptides) or phosphate (for DNA) groups, both of which have lower pKas than the imidazolate ligand. With functional biomolecular homologs (i.e., enzymes), we demonstrate a symbiotic stability reinforcement effect, i.e., the encapsulated biomolecules stabilize the ZIF matrix while the ZIF exoskeleton protects the enzyme from denaturation. KW - Zeolitic Imidazolate Frameworks KW - Biofunctional Molecules KW - X-ray Absorption Spectroscopy PY - 2019 DO - https://doi.org/10.1016/j.chempr.2019.03.025 VL - 5 IS - 6 SP - 1597 EP - 1608 PB - Elsevier Inc. AN - OPUS4-48702 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bassil, A. A1 - Wang, Xin A1 - Chapeleau, X. A1 - Niederleithinger, Ernst A1 - Abraham, O. A1 - Leduc, D. T1 - Distributed fiber optics sensing and coda wave interferometry techniques for damage monitoring in concrete structures N2 - The assessment of Coda Wave Interferometry (CWI) and Distributed Fiber Optics Sensing (DFOS) techniques for the detection of damages in a laboratory size reinforced concrete beam is presented in this paper. The sensitivity of these two novel techniques to micro cracks is discussed and compared to standard traditional sensors. Moreover, the capacity of a DFOS technique to localize cracks and quantify crack openings is also assessed. The results show that the implementation of CWI and DFOS techniques allow the detection of early subtle changes in reinforced concrete structures until crack formation. With their ability to quantify the crack opening, following early detection and localization, DFOS techniques can achieve more effective monitoring of reinforced concrete structures. Contrary to discrete sensors, CWI and DFOS techniques cover larger areas and thus provide more efficient infrastructures asset management and maintenance operations throughout the lifetime of the structure. KW - Distributed fiber optic sensors KW - Coda wave interferometry KW - Reinforced concrete KW - Cracks KW - Damage detection KW - Structural health monitoring PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-472549 DO - https://doi.org/10.3390/s19020356 SN - 1424-8220 VL - 19 IS - 2 SP - 356, 1 EP - 15 PB - MDPI AN - OPUS4-47254 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Szymoniak, Paulina A1 - Li, Z. A1 - Wang, D.-Y. A1 - Schoenhals, Andreas T1 - Dielectric and flash DSC investigations on an epoxy based nanocomposite system with MgAl layered double hydroxide as nanofiller N2 - Nanocomposites based on MgAL layered double hydroxides (LDH) and an epoxy resin were prepared and investigated by a combination of complementary methods. As epoxy resin Bisphenol A diglycidyl ether (DGEBA) was used with Diethylenetriamine as curing agent. The LDH was modified with taurine, which acts as an additional crosslinking agent due to its amine groups. The epoxy resin was cured in a presence of the nanofiller, which was added to the system in various concentrations. X-ray scattering, by combination of SAXS and WAXS was used to characterize the morphology of the obtained nanocomposites. These investigations show that the filler is distributed in the matrix as small stacks of ca. 10 layers. The molecular dynamics of the system, as probe for structure, was investigated by broadband dielectric spectroscopy. In addition to the - and -relaxation (dynamic glass transition), characteristic for the unfilled materials, a further process was found which was assigned to localized fluctuations of segments physically adsorbed or chemically bonded to the nanoparticles. The dielectric -relaxation is shifted to higher temperatures for the nanocomposites in comparison to the pure material but depends weakly on the content of nanoparticles. Further, for the first time Flash DSC was employed to a thermosetting system to investigate the glass transition behavior of the nanocomposites. The heating rates were converted in to relaxation rates. For low concentrations of the nanofiller the thermal data overlap more or less with that of the pure epoxy. For higher concentrations the thermal data are shifted significantly to higher temperatures. This is discussed in terms the cooperativity approach to the glass transition. KW - Nanocomposites KW - Broadband dielectric spectroscopy KW - Flash DSC PY - 2019 DO - https://doi.org/10.1016/j.tca.2019.01.010 SN - 0040-6031 VL - 677 SP - 151 EP - 161 PB - Elsevier AN - OPUS4-48218 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Leng, Jing A1 - Szymoniak, Paulina A1 - Kang, N.-J. A1 - Wang, D-Y A1 - Wurm, A. A1 - Schick, C. A1 - Schönhals, Andreas T1 - Influence of interfaces on the crystallization behavior and the rigid amorphous phase of poly(l-lactide)-based nanocomposites with different layered doubled hydroxides as nanofiller N2 - Based on the three-phase model of semi-crystalline polymers, we determined all phase fractions of the NiAl-LDH/PLLA nanocomposites in dependence on the concentration of the nanofiller. Moreover, the rigid amorphous fraction (RAF) was separated into the RAFcrystal and the RAFfiller unbiasedly. A detailed comparison to the related nanocomposite system MgAl-LDH/PLLA was made considering that Mg and Ni have different atomic weights. As a first result is was found that NiAl-LDH/PLLA displays a higher crystallization rate compared to MgAl-LDH/PLLA, which is related to the different morphologies of the two nanocomposite systems. For both systems RAFcrystal increases with increasing concentration of the nanofiller. This means in the case of the nanocomposite not each crystal produces the same amount of RAF, as often assumed. Also, RAFfiller increases with the concentration for both systems but in a different way. This is discussed considering again the different morphologies of both nanocomposites. KW - Polymer-based nanocomposites KW - Temperature modulated differential scanning calorimetry PY - 2019 DO - https://doi.org/10.1016/j.polymer.2019.121929 VL - 184 SP - 121929 PB - Elesevier Ltd. AN - OPUS4-49557 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -